quantum phase transitions: from mott insulators to the cuprate...

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Quantum phase transitions: from Mott insulators to the cuprate superconductors Colloquium article in Reviews of Modern Physics 75, 913 (2003) Leon Balents (UCSB) Eugene Demler (Harvard) Matthew Fisher (UCSB) Kwon Park (Maryland) Anatoli Polkovnikov (Harvard) T. Senthil (MIT) Ashvin Vishwanath (MIT) Matthias Vojta (Karlsruhe) Ying Zhang (Maryland)

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Page 1: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum phase transitions: from Mott insulators

to the cuprate superconductors

Colloquium article in Reviews of Modern Physics 75, 913 (2003)

Leon Balents (UCSB) Eugene Demler (Harvard) Matthew Fisher (UCSB) Kwon Park (Maryland) Anatoli Polkovnikov (Harvard) T. Senthil (MIT) Ashvin Vishwanath (MIT) Matthias Vojta (Karlsruhe) Ying Zhang (Maryland)

Page 2: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Parent compound of the high temperature superconductors: 2 4La CuO

Cu

O

La

Band theory

k

( )kε

Half-filled band of Cu 3d orbitals –ground state is predicted by band theory to be a metal.

However, La2CuO4 is a very good insulator

Page 3: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Parent compound of the high temperature superconductors: 2 4La CuO

A Mott insulator

spin operator withangular momentum =1/2

ij i jij

i

H J S S

SS

=

∑ i

Ground state has long-range spin density wave (Néel) order at wavevector K= (π,π)

0 ϕ ≠spin density wave order parameter:

; 1 on two sublatticesii i

SS

ϕ η η= = ±

Page 4: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Parent compound of the high temperature superconductors: 2 4La CuO

A Mott insulator

spin operator withangular momentum =1/2

ij i jij

i

H J S S

SS

=

∑ i

Ground state has long-range spin density wave (Néel) order at wavevector K= (π,π)

0 ϕ ≠spin density wave order parameter:

; 1 on two sublatticesii i

SS

ϕ η η= = ±

Page 5: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Parent compound of the high temperature superconductors: 2 4La CuO

A Mott insulator

spin operator withangular momentum =1/2

ij i jij

i

H J S S

SS

=

∑ i

Ground state has long-range spin density wave (Néel) order at wavevector K= (π,π)

0 ϕ ≠spin density wave order parameter:

; 1 on two sublatticesii i

SS

ϕ η η= = ±

Page 6: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

BCS

Doped state is a paramagnet with 0 and also a high temperature superconductor with the BCS pairing order parameter 0

With increasing , there must be one or more qua

.

nt

ϕ

δ

=

Ψ ≠

BCS

um phase transitions involving ( ) onset of a non-zero ( ) restoration of spin rotation invariance by a transition from 0 to 0

iii

ϕ ϕ

Ψ

≠ =

Introduce mobile carriers of density δby substitutional doping of out-of-plane

ions e.g. 2 4La Sr CuOδ δ−

Superconductivity in a doped Mott insulator

First study magnetic transition in Mott insulators………….

Page 7: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

OutlineOutlineA. Magnetic quantum phase transitions in “dimerized”

Mott insulatorsLandau-Ginzburg-Wilson (LGW) theory

B. Mott insulators with spin S=1/2 per unit cellBerry phases, bond order, and the breakdown of the LGW paradigm

C. Cuprate SuperconductorsCompeting orders and recent experiments

Page 8: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Magnetic quantum phase tranitions in “dimerized” Mott insulators:

Landau-Ginzburg-Wilson (LGW) theory:Second-order phase transitions described by

fluctuations of an order parameterassociated with a broken symmetry

Page 9: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

TlCuCl3

M. Matsumoto, B. Normand, T.M. Rice, and M. Sigrist, cond-mat/0309440.

Page 10: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Coupled Dimer AntiferromagnetM. P. Gelfand, R. R. P. Singh, and D. A. Huse, Phys. Rev. B 40, 10801-10809 (1989).N. Katoh and M. Imada, J. Phys. Soc. Jpn. 63, 4529 (1994).J. Tworzydlo, O. Y. Osman, C. N. A. van Duin, J. Zaanen, Phys. Rev. B 59, 115 (1999).M. Matsumoto, C. Yasuda, S. Todo, and H. Takayama, Phys. Rev. B 65, 014407 (2002).

S=1/2 spins on coupled dimers

JλJ

jiij

ij SSJH ⋅= ∑><

10 ≤≤ λ

Page 11: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell
Page 12: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

Page 13: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

0, 0iS ϕ= =Paramagnetic ground state

( )↓↑−↑↓=2

1

Page 14: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

( )↓↑−↑↓=2

1

Excitation: S=1 triplon

Page 15: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

( )↓↑−↑↓=2

1

Excitation: S=1 triplon

Page 16: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

( )↓↑−↑↓=2

1

Excitation: S=1 triplon

Page 17: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

( )↓↑−↑↓=2

1

Excitation: S=1 triplon

Page 18: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

( )↓↑−↑↓=2

1

Excitation: S=1 triplon

Page 19: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 0λ Weakly coupled dimers

( )↓↑−↑↓=2

1

Excitation: S=1 triplon(exciton, spin collective mode)

Energy dispersion away fromantiferromagnetic wavevector

2 2 2 2

2x x y y

p

c p c pε

+= ∆ +

∆spin gap∆ →

Page 20: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

TlCuCl3

N. Cavadini, G. Heigold, W. Henggeler, A. Furrer, H.-U. Güdel, K. Krämer and H. Mutka, Phys. Rev. B 63 172414 (2001).

“triplon”

/

For quasi-one-dimensional systems, the triplon linewidth takesthe exact universal value 1.20 at low TBk T

Bk Te−∆=K. Damle and S. Sachdev, Phys. Rev. B 57, 8307 (1998)

This result is in good agreement with observations in CsNiCl3 (M. Kenzelmann, R. A. Cowley, W. J. L. Buyers, R. Coldea, M. Enderle, and D. F. McMorrow Phys. Rev. B 66, 174412 (2002)) and Y2NiBaO5 (G. Xu, C. Broholm, G. Aeppli, J. F. DiTusa, T.Ito, K. Oka, and H. Takagi, preprint).

Page 21: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Coupled Dimer Antiferromagnet

Page 22: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 1λ Weakly dimerized square lattice

Page 23: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

close to 1λ Weakly dimerized square lattice

Excitations: 2 spin waves (magnons)

2 2 2 2p x x y yc p c pε = +

Ground state has long-range spin density wave (Néel) order at wavevector K= (π,π)

0 ϕ ≠

spin density wave order parameter: ; 1 on two sublatticesii i

SS

ϕ η η= = ±

Page 24: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

TlCuCl3

J. Phys. Soc. Jpn 72, 1026 (2003)

Page 25: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

λc = 0.52337(3)M. Matsumoto, C. Yasuda, S. Todo, and H. Takayama,

Phys. Rev. B 65, 014407 (2002)T=0

λ 1 cλ Pressure in TlCuCl3

Quantum paramagnetNéel state

0ϕ ≠ 0ϕ =

The method of bond operators (S. Sachdev and R.N. Bhatt, Phys. Rev. B 41, 9323 (1990)) provides a quantitative description of spin excitations in TlCuCl3 across the quantum phase transition (M. Matsumoto, B. Normand, T.M. Rice, and M. Sigrist,

Phys. Rev. Lett. 89, 077203 (2002))

Page 26: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

λc = 0.52337(3)M. Matsumoto, C. Yasuda, S. Todo, and H. Takayama,

Phys. Rev. B 65, 014407 (2002)T=0

λ 1 cλ δ in cuprates ?

Quantum paramagnet

0ϕ ≠ 0ϕ =

Néel state

Magnetic order as in La2CuO4 Electrons in charge-localized Cooper pairs

The method of bond operators (S. Sachdev and R.N. Bhatt, Phys. Rev. B 41, 9323 (1990)) provides a quantitative description of spin excitations in TlCuCl3 across the quantum phase transition (M. Matsumoto, B. Normand, T.M. Rice, and M. Sigrist,

Phys. Rev. Lett. 89, 077203 (2002))

Page 27: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

LGW theory for quantum criticalitywrite down an effective action

for the antiferromagnetic order parameter by expanding in powers of and its spatial and temporal d

Landau-Ginzburg-Wilson theor

erivatives, while preserving

y:

all s

ϕϕ

ymmetries of the microscopic Hamiltonian

( ) ( ) ( ) ( )22 22 2 22

1 12 4!x c

ud xdc

Sϕ ττ ϕ ϕ λ λ ϕ ϕ⎡ ⎛ ⎞ ⎤= ∇ + ∂ + − +⎜ ⎟⎢ ⎥⎝ ⎠ ⎦⎣∫

S. Chakravarty, B.I. Halperin, and D.R. Nelson, Phys. Rev. B 39, 2344 (1989)

~3∆

( )2 2

; 2 c

c pp cε λ λ= ∆ + ∆ = −∆

( )For oscillations of about 0 lead to the following structure in the dynamic structure factor ,

c

S pλ λ ϕ ϕ

ω< =

ω

( ),S p ω

( )( )Z pδ ω ε−

Three triplon continuumTriplon pole

Structure holds to all orders in u

A.V. Chubukov, S. Sachdev, and J.Ye, Phys.

Rev. B 49, 11919 (1994)

Page 28: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulators with spin S=1/2 per unit cell:

Berry phases, bond order, and the breakdown of the LGW paradigm

Page 29: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with two S=1/2 spins per unit cell

Page 30: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

Page 31: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

Ground state has Neel order with 0ϕ ≠

Page 32: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

Destroy Neel order by perturbations which preserve full square lattice symmetry e.g. second-neighbor or ring exchange.The strength of this perturbation is measured by a coupling g.

Small ground state has Neel order with 0

Large paramagnetic ground state with 0

g

g

ϕ

ϕ

⇒ ≠

⇒ =

Page 33: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

Destroy Neel order by perturbations which preserve full square lattice symmetry e.g. second-neighbor or ring exchange.The strength of this perturbation is measured by a coupling g.

Small ground state has Neel order with 0

Large paramagnetic ground state with 0

g

g

ϕ

ϕ

⇒ ≠

⇒ =

Page 34: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 35: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bond bond

Such a state breaks the symmetry of rotations by / 2 about lattice sites,and has 0, where is the

nπΨ ≠ Ψ bond order parameter

Page 36: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bond bond

Such a state breaks the symmetry of rotations by / 2 about lattice sites,and has 0, where is the

nπΨ ≠ Ψ bond order parameter

bondΨ

ossible large paramagnetic gr Class ound state ( ) with 0A g ϕ =P

Page 37: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bond bond

Such a state breaks the symmetry of rotations by / 2 about lattice sites,and has 0, where is the

nπΨ ≠ Ψ bond order parameter

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 38: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bond bond

Such a state breaks the symmetry of rotations by / 2 about lattice sites,and has 0, where is the

nπΨ ≠ Ψ bond order parameter

Page 39: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

bond bond

Such a state breaks the symmetry of rotations by / 2 about lattice sites,and has 0, where is the

nπΨ ≠ Ψ bond order parameter

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

Page 40: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bond bond

Another state breaking the symmetry of rotations by / 2 about lattice sites,which also has 0, where is the

nπΨ ≠ Ψ bond order parameter

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 41: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bond bond

Another state breaking the symmetry of rotations by / 2 about lattice sites,which also has 0, where is the

nπΨ ≠ Ψ bond order parameter

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 42: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bond bond

Another state breaking the symmetry of rotations by / 2 about lattice sites,which also has 0, where is the

nπΨ ≠ Ψ bond order parameter

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 43: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bond bond

Another state breaking the symmetry of rotations by / 2 about lattice sites,which also has 0, where is the

nπΨ ≠ Ψ bond order parameter

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 44: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulator with one S=1/2 spin per unit cell

bond bond

Another state breaking the symmetry of rotations by / 2 about lattice sites,which also has 0, where is the

nπΨ ≠ Ψ bond order parameter

( ) ( )arond

cb

tan j iii j

iji S S e −Ψ = ∑ i r r

bondΨ

Possible large paramagnetic gr Class ound state ( ) with 0A g ϕ =

Page 45: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Resonating valence bonds

bond

Different valence bond pairings resonate with each other, leading to Cl

a resoass B

nating valenparamagnet)

ce bond , ( with 0

liquidΨ =

P. Fazekas and P.W. Anderson, Phil Mag 30, 23 (1974); P.W. Anderson 1987

Such states are associated with non-collinear spin correlations, Z2 gauge theory, and topological order.N. Read and S. Sachdev, Phys. Rev. Lett. 66, 1773 (1991); X. G. Wen, Phys. Rev. B 44, 2664 (1991).

Resonance in benzene leads to a symmetric configuration of valence

bonds (F. Kekulé, L. Pauling)

Page 46: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠

Page 47: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠

Page 48: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠

Page 49: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠

Page 50: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠

Page 51: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠

S=1/2 spinons, , are confined into a S=1

triplon, ϕ*~ z zα αβ βϕ σ

Page 52: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠ bond 0; Class BΨ =

S=1/2 spinons, , are confined into a S=1

triplon, ϕ*~ z zα αβ βϕ σ

Page 53: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠ bond 0; Class BΨ =

S=1/2 spinons, , are confined into a S=1

triplon, ϕ*~ z zα αβ βϕ σ

Page 54: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠ bond 0; Class BΨ =

S=1/2 spinons, , are confined into a S=1

triplon, ϕ*~ z zα αβ βϕ σ

Page 55: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Excitations of the paramagnet with non-zero spin

bond 0; Class AΨ ≠ bond 0; Class BΨ =

S=1/2 spinons, , are confined into a S=1

triplon, ϕ*~ z zα αβ βϕ σ

zα S=1/2 spinons can propagate

independently across the lattice

Page 56: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel order

Ingredient missing from LGW theory: Ingredient missing from LGW theory: Spin Berry PhasesSpin Berry Phases

AiSAe

Page 57: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel order

Ingredient missing from LGW theory: Ingredient missing from LGW theory: Spin Berry PhasesSpin Berry Phases

AiSAe

Page 58: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel order

Page 59: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points a

Page 60: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

( ), ,x yµ τ=

Page 61: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

a a+ 0

oriented area of spherical triangle

formed by and an arbitrary reference , poi, nta hA alfµ

µϕ ϕ ϕ

2 aA µ

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 62: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

a a+ 0

oriented area of spherical triangle

formed by and an arbitrary reference , poi, nta hA alfµ

µϕ ϕ ϕ

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 63: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

a a+ 0

oriented area of spherical triangle

formed by and an arbitrary reference , poi, nta hA alfµ

µϕ ϕ ϕ

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 64: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

a µγ +

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

a a+ 0

oriented area of spherical triangle

formed by and an arbitrary reference , poi, nta hA alfµ

µϕ ϕ ϕ

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 65: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

a µγ +

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

a a+ 0

oriented area of spherical triangle

formed by and an arbitrary reference , poi, nta hA alfµ

µϕ ϕ ϕ

Change in choice of is like a “gauge transformation”

2 2a a a aA Aµ µ µγ γ+→ − +

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 66: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

a µγ +

Quantum theory for destruction of Neel orderDiscretize imaginary time: path integral is over fields on the

sites of a cubic lattice of points aa a

a

Recall = (0,0,1) in classical Neel state; 1 on two

square subl

2attices ;

a aSϕ η ϕη

→→ ±=

a+µϕ

a a+ 0

oriented area of spherical triangle

formed by and an arbitrary reference , poi, nta hA alfµ

µϕ ϕ ϕ

Change in choice of is like a “gauge transformation”

2 2a a a aA Aµ µ µγ γ+→ − +

The area of the triangle is uncertain modulo 4π, and the action has to be invariant under 2a aA Aµ µ π→ +

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 67: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel order

Ingredient missing from LGW theory: Ingredient missing from LGW theory: Spin Berry PhasesSpin Berry Phases

exp a aa

i A τη⎛ ⎞⎜ ⎟⎝ ⎠

∑Sum of Berry phases of all spins on the square lattice.

, exp

with "current" of

charges 1 on sublattices

a aa

a

i J A

J

static

µ µµ

µ

⎛ ⎞= ⎜ ⎟

⎝ ⎠

±

Page 68: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum theory for destruction of Neel order

( )2

,

11 expa a a a a aa aa

Z d i Ag µ τ

µ

ϕ δ ϕ ϕ ϕ η+

⎛ ⎞= − ⋅ +⎜ ⎟

⎝ ⎠∑ ∑∏∫

Partition function on cubic lattice

Modulus of weights in partition function: those of a classical ferromagnet at a “temperature” g

Small ground state has Neel order with 0

Large paramagnetic ground state with 0 Berry phases lead to large cancellations between different time histories need an effective action for a

g

g

A

ϕ

ϕ

⇒ ≠

⇒ =

→ at large gµ

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 69: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Simplest large g effective action for the Aaµ

( )2

2 2

,

withThis is compact QED in 3 spacetime dimensions with

static charges 1 on

1exp c

two sublat

tices.

o2

~

sa a a a aaa

Z dA A A i Ae

e g

µ µ ν ν µ τµ

η⎛ ⎞= ∆ − ∆ +⎜ ⎟⎝ ⎠

±

∑ ∑∏∫

bond (Class A paramaAnalysis by a duality mapping shows that this theoryis in a phase with 0 The gauge theory is in a phase (spinons are confinedand only =1 triplons propagate

gnet).alwaysconfining

S

Ψ ≠

Proliferation of monopoles in the presence of Berry phases.

).

N. Read and S. Sachdev, Phys. Rev. Lett. 62, 1694 (1989).S. Sachdev and R. Jalabert, Mod. Phys. Lett. B 4, 1043 (1990).

S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002)

Page 70: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 71: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 72: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 73: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 74: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 75: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 76: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 77: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 78: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Ordering by quantum fluctuations

Page 79: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

( )2

,

11 expa a a a a aa aa

Z d i Ag µ τ

µ

ϕ δ ϕ ϕ ϕ η+

⎛ ⎞= − ⋅ +⎜ ⎟

⎝ ⎠∑ ∑∏∫

g0

Neel order 0ϕ ≠

?bond

Bond order0

Not present in LGW theory of orderϕ

Ψ ≠

or

Page 80: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Naïve approach: add bond order parameter to LGW theory “by hand”

First order

transitionbond

Neel order0, 0ϕ ≠ Ψ = bond

Bond order0, 0ϕ = Ψ ≠

g

gbond

Coexistence0,

0

ϕ ≠

Ψ ≠bond

Neel order0, 0ϕ ≠ Ψ = bond

Bond order0, 0ϕ = Ψ ≠

gbond

"disordered"0,

0

ϕ =

Ψ =bond

Neel order0, 0ϕ ≠ Ψ =

bond

Bond order0, 0ϕ = Ψ ≠

Page 81: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Bond order in a frustrated S=1/2 XY magnet

A. W. Sandvik, S. Daul, R. R. P. Singh, and D. J. Scalapino, Phys. Rev. Lett. 89, 247201 (2002)

First large scale (> 8000 spins) numerical study of the destruction of Neel order in a S=1/2 antiferromagnet with full square lattice symmetry

( ) ( )2 x x y yi j i j i j k l i j k l

ij ijklH J S S S S K S S S S S S S S+ − + − − + − +

= + − +∑ ∑g=

Page 82: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

( )2

,

11 expa a a a a aa aa

Z d i Ag µ τ

µ

ϕ δ ϕ ϕ ϕ η+

⎛ ⎞= − ⋅ +⎜ ⎟

⎝ ⎠∑ ∑∏∫

g0

Neel order 0ϕ ≠

?bond

Bond order0

Not present in LGW theory of orderϕ

Ψ ≠

or

Page 83: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

S. Sachdev and R. Jalabert, Mod. Phys. Lett. B 4, 1043 (1990); G. Murthy and S. Sachdev, Nuclear Physics B 344, 557 (1990); C. Lannert, M.P.A. Fisher, and T. Senthil, Phys. Rev. B 63, 134510 (2001); S. Sachdev and K. Park, Annals of Physics, 298, 58 (2002); O. Motrunich and A. Vishwanath, cond-mat/0311222.

Theory of a second-order quantum phase transition between Neel and bond-ordered phases

*

At the quantum critical point: +2 periodicity can be ignored

(Monopoles interfere destructively and are dangerously irrelevant). =1/2 , with ~ , are globally

pro

A A

S spinons z z z

µ µ

α α αβ β

π

ϕ σ

• →

pagating degrees of freedom.

Second-order critical point described by emergent fractionalized degrees of freedom (Aµ and zα );

Order parameters (ϕ and Ψbond ) are “composites” and of secondary importance

Second-order critical point described by emergent fractionalized degrees of freedom (Aµ and zα );

Order parameters (ϕ and Ψbond ) are “composites” and of secondary importance

T. Senthil, A. Vishwanath, L. Balents, S. Sachdev and M.P.A. Fisher, Science 303, 1490 (2004).

Page 84: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Phase diagram of S=1/2 square lattice antiferromagnet

g*

Neel order

~ 0z zα αβ βϕ σ ≠

(associated with condensation of monopoles in ),Aµ

or

bondBond order 0Ψ ≠

1/ 2 spinons confined, 1 triplon excitations

S zS

α==

T. Senthil, A. Vishwanath, L. Balents, S. Sachdev and M.P.A. Fisher, Science 303, 1490 (2004). S. Sachdev cond-mat/0401041.

Page 85: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Mott insulators with spin S=1/2 per unit cell:

Berry phases, bond order, and the breakdown of the LGW paradigm

Order parameters/broken symmetry+

Emergent gauge excitations, fractionalization.

Page 86: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Cuprate superconductors:Competing orders and recent experiments

Page 87: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Magnetic Mott Insulator

Magnetic Superconductor

Paramagnetic Mott Insulator

Superconductor

BCS , 00 = ϕ = Ψ

2 4La CuO

Quantum phasetransitions

High temperaturesuperconductor

BCS , 00 = ϕ ≠ ΨBCS , 0 0ϕ ≠ Ψ ≠

BCS , 0 0ϕ = Ψ ≠

BCSMinimal LGW phase diagram with and ϕ Ψ

Page 88: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Magnetic Mott Insulator

Magnetic Superconductor

Paramagnetic Mott Insulator

Superconductor

BCS , 00 = ϕ = Ψ

2 4La CuO

Quantum phasetransitions

BCS , 00 = ϕ ≠ ΨBCS , 0 0ϕ ≠ Ψ ≠

BCS , 0 0ϕ = Ψ ≠

( )Spin density wave order ,K π π≠Spirals……Shraiman, SiggiaStripes……..Zaanen, Kivelson…..

BCSMinimal LGW phase diagram with and ϕ ΨHigh temperaturesuperconductor

Page 89: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Quantum phasetransitions

Paramagnetic Mott Insulator

BCS , 00 = ϕ = Ψ

BCS , 00 = ϕ ≠ Ψ

Magnetic Mott Insulator

2 4La CuO

Page 90: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Magnetic Mott Insulator

Paramagnetic Mott Insulator

BCS , 00 = ϕ = Ψ

2 4La CuO

Quantum phasetransitions

BCS , 00 = ϕ ≠ Ψ

g

Neel order

Bond order

La2CuO4

or

Page 91: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

g

Neel order

Bond order

La2CuO4

or

δHole density

Large N limit of a theory with Sp(2N) symmetry: yields

existence of bond order and d-wave superconductivity

S. Sachdev and N. Read, Int. J. Mod. Phys. B 5, 219 (1991); M. Vojta and S. Sachdev, Phys. Rev. Lett. 83, 3916 (1999); M. Vojta, Phys. Rev. B 66, 104505 (2002).

Localized holes

Page 92: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Magnetic, bondand super-conducting

order

g

Neel order

Bond order

La2CuO4

or

δHole density

Large N limit of a theory with Sp(2N) symmetry: yields

existence of bond order and d-wave superconductivity

S. Sachdev and N. Read, Int. J. Mod. Phys. B 5, 219 (1991); M. Vojta and S. Sachdev, Phys. Rev. Lett. 83, 3916 (1999); M. Vojta, Phys. Rev. B 66, 104505 (2002).

Localized holes

Page 93: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Neutron scattering measurements of La15/8Ba1/8CuO4 (Zurich oxide)

xy

( )Scattering off spin density wave order with

cos

1 1 1 1 1 1 2 , and 2 ,2 2 8 2 8 2

At higher energies, semiclassical theory predictsthat peaks lead to spin-wave ("light")

i iS N α

π π

= +

⎛ ⎞ ⎛ ⎞± ±⎜ ⎟ ⎜ ⎟⎝ ⎠ ⎝ ⎠

iQ r

Q =

cones.

Page 94: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Neutron scattering measurements of La15/8Ba1/8CuO4 (Zurich oxide)

( )Scattering off spin density wave order with

cos

1 1 1 1 1 1 2 , and 2 ,2 2 8 2 8 2

At higher energies, semiclassical theory predictsthat peaks lead to spin-wave ("light")

i iS N α

π π

= +

⎛ ⎞ ⎛ ⎞± ±⎜ ⎟ ⎜ ⎟⎝ ⎠ ⎝ ⎠

iQ r

Q =

cones.

xy

A. T. Boothroyd, D. Prabhakaran, P. G. Freeman, S.J.S. Lister, M. Enderle, A. Hiess, and J. Kulda, Phys. Rev. B 67, 100407 (2003).

La5/3Sr1/3NiO4

1 1 1 1Ni has 1; 2 ,2 6 2 6

S π ⎛ ⎞= = ± ±⎜ ⎟⎝ ⎠

Q

Page 95: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Neutron scattering measurements of La15/8Ba1/8CuO4 (Zurich oxide)

( )Scattering off spin density wave order with

cos

1 1 1 1 1 1 2 , and 2 ,2 2 8 2 8 2

At higher energies, semiclassical theory predictsthat peaks lead to spin-wave ("light")

i iS N α

π π

= +

⎛ ⎞ ⎛ ⎞± ±⎜ ⎟ ⎜ ⎟⎝ ⎠ ⎝ ⎠

iQ r

Q =

cones.

xy

A. T. Boothroyd, D. Prabhakaran, P. G. Freeman, S.J.S. Lister, M. Enderle, A. Hiess, and J. Kulda, Phys. Rev. B 67, 100407 (2003).

La5/3Sr1/3NiO4

Spin waves: J=15 meV, J’=7.5meV

Page 96: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

( )Scattering off spin density wave order with

cos

1 1 1 1 1 1 2 , and 2 ,2 2 8 2 8 2

At higher energies, semiclassical theory predictsthat peaks lead to spin-wave ("light")

i iS N α

π π

= +

⎛ ⎞ ⎛ ⎞± ±⎜ ⎟ ⎜ ⎟⎝ ⎠ ⎝ ⎠

iQ r

Q =

cones.

xy

A. T. Boothroyd, D. Prabhakaran, P. G. Freeman, S.J.S. Lister, M. Enderle, A. Hiess, and J. Kulda, Phys. Rev. B 67, 100407 (2003).

La5/3Sr1/3NiO4

Spin waves: J=15 meV, J’=7.5meV

Neutron scattering measurements of La15/8Ba1/8CuO4 (Zurich oxide)

Page 97: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Observations in La15/8Ba1/8CuO4 are very different and do not obey

spin-wave model.

Similar spectra are seen in most hole-doped cuprates.

xy

“Resonance peak”

Page 98: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Red lines: triplonexcitation of a 2 leg

ladder with exchange J=100 meV

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Page 99: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Red lines: triplonexcitation of a 2 leg

ladder with exchange J=100 meV

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Page 100: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Red lines: triplonexcitation of a 2 leg

ladder with exchange J=100 meV

J. M. Tranquada, H. Woo, T. G. Perring, H. Goka, G. D. Gu, G. Xu, M. Fujita, and K. Yamada, cond-mat/0401621

Page 101: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

xy

Spectrum of a two-leg ladderJ. M. Tranquada et al., cond-mat/0401621

Page 102: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Proposals of• M. Vojta and T. Ulbricht, cond-mat/0402377• G.S. Uhrig, K.P. Schmidt, and M. Grüninger, cond-mat/0402659• M. Vojta and S. Sachdev, to appear.

Magnetic excitations display a crossover from spin-waves (at low energies) to

triplons (at high energies), and main features can be described by proximity to a magnetic quantum phase transition in the presence of

period 4, static, bond order.

Magnetic excitations display a crossover from spin-waves (at low energies) to

triplons (at high energies), and main features can be described by proximity to a magnetic quantum phase transition in the presence of

period 4, static, bond order.

( )LGW action for magnetic order parameter ( , ) :iii ie Sϕ π π= =iK r K

( ) ( )( ) ( )

( ) ( ){ }

222 2 2

2

12 4!

,

i c i ii

i j i jij

ud c g g

d P i j

Sϕ ττ ϕ ϕ ϕ

τ ϕ ϕ ϕ ϕ

⎧ ⎫= ∂ + − +⎨ ⎬⎩ ⎭

+ − −

∑∫

∑∫ i( )

bond( , ) c.c.i jiP i j e += Ψ +iQ r r

Page 103: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

Possible simple microscopic model of bond order

G.S. Uhrig, K.P. Schmidt, and M. Grüninger, cond-mat/0402659

Spin waves

Triplons

“Resonance peak”

Page 104: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

G.S. Uhrig, K.P. Schmidt, and M. Grüninger, cond-mat/0402659

Page 105: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada et al., cond-mat/0401621

xy

Bond operator (S. Sachdev and R.N. Bhatt, Phys. Rev.B 41, 9323 (1990)) theory of coupled-ladder model,

M. Vojta and T. Ulbricht, cond-mat/0402377

Page 106: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada et al., cond-mat/0401621

xy

Numerical study of coupled ladder model, G.S. Uhrig, K.P. Schmidt, and M. Grüninger,

cond-mat/0402659

Page 107: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

J. M. Tranquada et al., cond-mat/0401621

xy

LGW theory of magnetic criticality in the presence of static bond order, M. Vojta and S. Sachdev, to appear.

Page 108: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

ConclusionsI. Theory of quantum phase transitions between magnetically

ordered and paramagnetic states of Mott insulators:

A. Dimerized Mott insulators: Landau-Ginzburg-Wilson theory of fluctuating magnetic order parameter.

B. S=1/2 square lattice: Berry phases induce bond order, and LGW theory breaks down. Critical theory is expressed in terms of emergent fractionalized modes, and the order parameters are secondary.

ConclusionsI. Theory of quantum phase transitions between magnetically

ordered and paramagnetic states of Mott insulators:

A. Dimerized Mott insulators: Landau-Ginzburg-Wilson theory of fluctuating magnetic order parameter.

B. S=1/2 square lattice: Berry phases induce bond order, and LGW theory breaks down. Critical theory is expressed in terms of emergent fractionalized modes, and the order parameters are secondary.

Page 109: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

ConclusionsII. Competing spin-density-wave/bond/superconducting orders in

the hole-doped cuprates.• Main features of spectrum of excitations in LBCO modeled by LGW theory of quantum critical fluctuations in the presence of static bond order across a wide energy range.

• Predicted magnetic field dependence of spin-density-wave order observed by neutron scattering in LSCO. E. Demler, S. Sachdev, and Y. Zhang, Phys.Rev. Lett. 87, 067202 (2001); B. Lake et al. Nature, 415, 299 (2002); B. Khaykhovich et al.Phys. Rev. B 66, 014528 (2002).

• Predicted pinned bond order in vortex halo consistent with STM observations in BSCCO. K. Park and S. Sachdev Phys. Rev. B 64, 184510 (2001); Y. Zhang, E. Demler and S. Sachdev, Phys. Rev. B 66, 094501 (2002); J.E. Hoffman et al. Science 295, 466 (2002).

• Energy dependence of LDOS modulations in BSCCO best modeled by modulations in bond variables. M. Vojta, Phys. Rev. B 66, 104505 (2002); D. Podolsky, E. Demler, K. Damle, and B.I. Halperin, Phys. Rev. B 67, 094514 (2003); C. Howald, H. Eisaki, N. Kaneko, and A. Kapitulnik, Phys. Rev. B 67, 014533 (2003).

ConclusionsII. Competing spin-density-wave/bond/superconducting orders in

the hole-doped cuprates.• Main features of spectrum of excitations in LBCO modeled by LGW theory of quantum critical fluctuations in the presence of static bond order across a wide energy range.

• Predicted magnetic field dependence of spin-density-wave order observed by neutron scattering in LSCO. E. Demler, S. Sachdev, and Y. Zhang, Phys.Rev. Lett. 87, 067202 (2001); B. Lake et al. Nature, 415, 299 (2002); B. Khaykhovich et al.Phys. Rev. B 66, 014528 (2002).

• Predicted pinned bond order in vortex halo consistent with STM observations in BSCCO. K. Park and S. Sachdev Phys. Rev. B 64, 184510 (2001); Y. Zhang, E. Demler and S. Sachdev, Phys. Rev. B 66, 094501 (2002); J.E. Hoffman et al. Science 295, 466 (2002).

• Energy dependence of LDOS modulations in BSCCO best modeled by modulations in bond variables. M. Vojta, Phys. Rev. B 66, 104505 (2002); D. Podolsky, E. Demler, K. Damle, and B.I. Halperin, Phys. Rev. B 67, 094514 (2003); C. Howald, H. Eisaki, N. Kaneko, and A. Kapitulnik, Phys. Rev. B 67, 014533 (2003).

Page 110: Quantum phase transitions: from Mott insulators to the cuprate …qpt.physics.harvard.edu/talks/harvard2004.pdf · 2004-05-06 · Mott insulator with one S=1/2 spin per unit cell

ConclusionsIII. Breakdown of LGW theory of quantum phase transitions with

magnetic/bond/superconducting orders in doped Mott insulators ?

ConclusionsIII. Breakdown of LGW theory of quantum phase transitions with

magnetic/bond/superconducting orders in doped Mott insulators ?