r critchley - materials that fight back
TRANSCRIPT
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Materials that fight
backR. Critchley, I. Corni, K. Stokes, J. Wharton, F. Walsh, R. Wood
22 April 2010 TriboUK Imperial College London
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Outline
Current problems
Proposed solution
The outer hierarchical coating Inner auxetic foam
Where the project is heading
htt ://hermes52.deviantart.com/art/U-S-Arm -Soldier-34508852
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Body armour: problems and requirements
Lightweight (now the body armour is 13 kg)
Flexible wear and allowing mobility
Low cost
Stop projectile penetration
Diffuse the impact energy to reduce behind armour blunttrauma (BABT)
http://cn1.kaboodle.com/hi/img/2/0/0/c0/e/AAAAAhTx1z0AAAAAAMDr-A.jpg
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htt ://www.com uterweekl .com/PhotoGalleries/235075/757_30_Hi-tech-bod -armour.JPG
How it works
HybridSandwichStructure
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Outer layer: a laminate compositestructure to diffuse the energy of theimpact and to resist to deeperpenetrations
Armoursubstrate
Inner layer: auxetic foamstructure acting as small airbagsto protect the body from BABT
Schematic structure
1mm
5 mm
10 mm
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Outer hierarchicalcoating
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The outer hierarchical coating
It is well-known that biological materials present optimized structure andexcellent mechanical properties.
The challenge is to deposit a hierarchical hard and tough ceramic-metal
multilayered coating that mimics nature (e.g. nacre (mother of pearl),mollusc shell and ancient fish armour).
The initial coatings have been deposited by CVD (W3C and B13C2) andPVD (Ti-V-Zr and Ti-V-Zr nitride):
CVD is a high temperature process (1000C for B13C2) and thereforejust few substrate are compatible.
PVD coatings can be deposited on CVD films but the opposite is notalways true e.g. we experienced decomposition of the PVD filmsin the atmosphere needed for CVD deposition.
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Nacre (mother of pearl)
Nacre is a ceramic laminate composite made of aragonite tablet layersseparated by thin layers of an organic material (polymer).
Nacre resists impact by dissipating the impact energy through nano andmicron cracks, plastic deformation and elastic responses.
Barthelat, et al. Experimental Mechanics 2007
Materials Research to Meet 21st Century Defence Needs, 2003.
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Vent gastropod shell
Ortiz et al. PNAS 2010.
The hardness and Young modulus reported to be higher in the twoexternal layers (with the inner layer presenting the higher value) and lowerin the middle layer (ML).
The outer layer (OL) behaves as a sacrificial layer and helps to dissipatethe impact energy through localized micro-cracking and delamination.
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Ancient fish armour
Each layer had a specific deformation and energy dissipation mechanism:
The stiff outer layer transferred the energy of an applied load to the layersbelow
The stratified isopedine layer hinders deeper penetrations and preventscatastrophic cracking through micro-cracking in the sub-layers.
Bruet et al.Nature
Materials,2008.
Young modulus andhardness increase(inside to outside ofthe armour)
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Improved ballistic performanceof coated plates
Ozsahin and Tolun, Materials & Design 2010; Ozsahin and Tolun, Materials & Design, In Press.
zsahin and Tolun studied the ballistic performance against a highvelocity (> 350 m/s) impact 9 mm bullet of aluminium alloy plates with andwithout 0.762 mm thick cobalt-molybdenum-chromium or Zirconia plasmaspray coatings.
Penetration depth on the front face of the plate and the bulging on the
rear face of the plate were compared for plates with and without coatings.
The coatings improved theballistic resistance of the plateswith an increase in non-perforating projectile velocityand a decrease in penetrationdepth and bulging.
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Inner auxetic
foam
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Auxetic Materials What are they ?
Conventional materials have a positive Poissons ratio
Auxetic materials have a negative Poissons ratio - grow fatterwhen stretched
Evans and Alderson, Advanced Materials, 2000.
Poissons Ratio = _Change in X
Change in Y
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Auxetic Materials - Background
Auxetic materials have been known for approximately 100years
Field only started to be studied in 1987 by Rod Lakes
The term auxetic was coined by Ken Evans - derived fromthe Greek word auxetikos which means that tends toincrease
Surge in interest since the late1980s
htt ://www.imeche.or /NR/rdonl res/4CB11B44-DB9A-44D0-B94C-662AE7A93740/517/meshauxeticfoam94. n
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Auxetic Materials How they work
Fabricated through a compression, heating and coolingprocess
Foam cell structure determines the overall properties
Conventional Cell Structure Auxetic Random Rib Structure
Evans and Alderson, Advanced Materials, 2000.
x25x10
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Conventional Foam AuxeticFoam
x5 x5
Alicona InfiniteFocus
optical 3D measurement device
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Scanning Electron Microscopy (SEM)
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Testing Methods Indentation test
Falling drop impact test
High energy particleerosion test (350 m/s)
Ballistic test
Other Testing Methods: Compressive test
Tensile test
Shear test
3 point bending test Quasi-static cyclic loading
htt ://www.m mtechnolo ies.com/ima es/Batter Im actTest_med.http://english.ymhiten.com.tw/image/E-003a.jpghttp://www.worldoftest.com/img/products/Q250.jpg
http://www.tc.umn.edu/~seong001/web%20image/7R009r1.jpg
Increasei
n
strainr
a
te
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Where project is heading
Select a standard polymer foam most likely polyurethane
Determine optimum conditions for the selected foam
Characterise the foam
Test the foam in a numberof different situations
htt ://reasonsoflife.files.word ress.com/2008/08/success2. n ?w=317&h=320
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Acknowledgements
The author would liketo acknowledgeEPSRC and DSTL forproviding funding andopportunity for thisproject, and my projectsupervisors for all theirdirection and support.
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THE END
Any Questions ?
htt ://croak .deviantart.com/art/Universal-Soldier-19082158
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Understanding the threat - Bullets