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Rare Earth Permanent Magnets: Raw Materials, Magnets and Opportunities S. R. Trout

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Page 1: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Permanent Magnets:

Raw Materials, Magnets and

Opportunities

S. R. Trout

Page 2: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth
Page 3: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Outline

• Background

• Raw Materials

• Rare Earth Magnets

• Applications

• Final Thoughts

Page 4: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Background

SmCo5

Page 5: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Background

• 1976 Pittsburgh

• 1979 New York

• 1980 Boston

• 1981 Grenoble

• 1982 Montréal

• 1983 Philadelphia

• 1985 St. Paul

• 1986 Phoenix

• 1987 Tokyo

• 1989 Washington D.C.

• 1991 Pittsburgh

• 1994 Albuquerque

• 1995 San Antonio

• 2000 Toronto

• 2001 San Antonio

Previous Intermag Conferences

Page 6: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

Sc Y La

Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

Page 7: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

• Ores contain all rare earths except Pm

• There is no shortage of ore

– Most rare earths are not rare

• Most ores are rich in Ce, La, Nd and Pr

• The rare earths are chemically very similar

• Producers try to balance supply and demand

Page 8: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

• Ores contain all rare earths except Pm

• There is no shortage of ore

– Most rare earths are not rare

• Most ores are rich in Ce, La, Nd and Pr

• The rare earths are chemically very similar

• Producers try to balance supply and demand

– And are rarely successful!

Page 9: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Bayan Obo mine ,near Baotou, China

Photo from Google Earth

1 km

Page 10: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Mountain Pass, CAPhoto from Molycorp

~1 km

Page 11: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

Nd19%

Pr6%

La23%

Ce50%

Others2%

Bastnasite

Page 12: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

Catalyst20%

Glass9%

Polishing12%

Metal Alloys20%

Magnets20%

Ceramics5% Others

7%

Markets

Phosphors7%

Page 13: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

010,00020,00030,00040,00050,00060,000

70,00080,00090,000

100,000110,000120,000130,000

1956 1966 1976 1986 1996 2006

Other USA China

Raw MaterialsP

rod

uct

ion

, met

ric

ton

s

Source: U.S. Geological Survey

Page 14: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

• Active mines

– China

• Baotou

• Ionic Ores

• Mines in transition

– USA

• Mountain Pass, CA

• Inactive mines or deposits

– Australia

• Mt. Weld

• Nolan’s Bore

– Canada

• Hoidas Lake

• Thor Lake

– India

– Brazil

– Vietnam

– Russia

Page 15: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

Source: Dudley Kingsnorth, IMCOA, 2009

Page 16: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Raw Materials

• Lack of viable ores

– Most rare earths are not rare

• Shortage of Neodymium

– A self-regulating market• Price

• Design

• Application

• Dysprosium and Terbium

– Constrained

• Abrupt changes are extremely disruptive

– Upsets balance

– Capital intensive industry

– Lengthy recovery

Issues

Page 17: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

Materials

• Sm-Co– SmCo5

– 2-17, Sm2(Co,Fe,Cu,Zr/Hf)17

• Nd-Fe-B– (Nd,Dy)2(Fe, Co)14B

Questions

• When?

• Who?

• Where used?

• Speed of implementation?

Page 18: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

• Unfinished business

– The Hci of Nd-Fe-B• Why do Dy and Tb Increase Hci?

• Updating the 1985 explanation

Page 19: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth MagnetsSource: Livingston 1985

Page 20: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

Nd2-xDyxFe14B Nd2Fe14B

Source: NeomaxIncreasing x

Increasing x

Page 21: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

• Unfinished business

– The Hci of Nd-Fe-B• Why do Dy and Tb Increase Hci?

• Updating the 1985 explanation

• Controlling β, the temp. coefficient of Hci

• Wiser use of Dy and Tb

– Anisotropic bonded Nd-Fe-B

– Recycling, reuse

– Lower cost

Page 22: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

• Hard drive

– Voice Coil Motor (VCM)

– Spindle motors

ApplicationsSource: Western Digital

Page 23: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

• Automotive

– Current

Applications

Cruise Control

Mirror MotorsTailgate

MotorDoor Lock

MotorFour

Wheel Steering

Anti-skidSensor and

Motor

WindowLift

Motor

SuspensionSystem

FuelPumpMotor

Seat Belt

MotorSeat

AdjustMotors Antenna

LiftMotor

TractionControl

Heater-A/C Blower Throttle

and Crankshaft

PositionSensors

WindshieldWiperMotor

StarterMotor

CoolantFan

Motor

IgnitionSystems

HeadlightDoor

Motor

Economy and

PollutionControl

LiquidLevel

Indicators

WindshieldWasherPump

Gauges

CDPlayer

HeadRest

MotorSunRoof

Motor

ElectricPower

Steering and Sensor

Lumbar Support

AutomaticTemperature

Control

DoorGasket

DefoggerMotor

Speakers

Source: Magnequench

Page 24: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

• Automotive

– Hybrids

Applications

Source: Toyota

Page 25: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

• Wind Turbine

– Magnet vs. asynchronous

– One tonne of magnet per turbine

– The future?

ApplicationsSource: Vestas AS

Page 26: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Rare Earth Magnets

The Dy Issue

Source: MagnequenchHci (kOe)

(BH

) max

(MG

Oe)

Page 27: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Final Thoughts

Raw Materials

• Issues– Dysprosium

– Sudden changes

• Opportunities– Green technologies

• Magnets

• Ni-metal hydride batteries

• Lighting phosphors

Rare Earth Magnets

• Issues– Dysprosium

• What does it really do?

• How can we use less of it?

– Limited production outside China

• Opportunities– Hybrid vehicles

– Wind turbines

– Recycling

Page 28: Rare Earth Permanent Magnets: Raw Materials, …spontaneousmaterials.com/Papers/Plenary2009.pdfRare Earth Permanent Magnets: Raw Materials, ... Dudley Kingsnorth, IMCOA, ... Rare Earth

Final Thoughts

Presentation will be available on

www.spontaneousmaterials.com