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Rate of Change (Trend) PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical Services Inc. IEEE Transformer Committee Fall 2013 Meeting C57.104 St-Louis, October 20 – 24, 2013

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Page 1: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Rate of Change (Trend)

∆ PPM, PPM/day or PPM/Year

What make sense?

C. Beauchemin

TJH2b Analytical Services Inc.

IEEE Transformer Committee

Fall 2013 Meeting

C57.104

St-Louis, October 20 – 24, 2013

Page 2: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Fall 2012

• Luiz Cheim presentation (On the Web)

• Review of work done to date

• Review of factors influencing limits

• Presentation also covered various aspect

of rate computation

Page 3: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Rate of Gas Increase (ppm/year) vs Sampling

Interval???

Page 4: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Rate of Gas Increase (ppm/year) vs Sampling

Interval???

Page 5: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Food for Thought…

Rate of Gas Increase (ppm/year) vs Sampling

Interval???

Page 6: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Further work to clarify this question

• Study of a new set of data

• Single source (one lab)

• North America

• Mix of industrial and utilities

Page 7: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Data set

• One source

• 123 469 DGA

• 44 266 Transformers

• Delta computed between actual and

previous DGA

• 78 660 pairs of DGA

• All Gas + TDCG

Page 8: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Sampling Interval

Time between sampling

0

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 200 400 600 800 1000 1200 1400

Sampling Interval Days

De

ns

ity

26 D

ays

91 D

ays

186 D

ays365 Days

735 D

ays

942 D

ays

1107 D

ays

551 D

ays

Page 9: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Sampling Interval

Time between sampling

0

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 200 400 600 800 1000 1200 1400

Sampling Interval Days

De

ns

ity

1 M

on

th

3 M

on

ths

6 M

on

ths

1 Year

2 Y

ears

2.5

Ye

ars

3 Y

ears

1.5

Ye

ars

Page 10: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Data set

• Table 3 use TDCG rates of 10 - 30 ppm/day

• ppm/year or ml/day is also used to evaluate

gassing rate

• Preliminary study (last meeting) has been

done in ppm/year

• 1 ppm/day = 365 ppm/year

• 10 ppm/day = 3650 ppm/year

• 30 ppm/day = 10950 ppm/year

Page 11: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

DGA “Noise”

• Oil sampling, transport and analysis do

introduce DGA variations from one sample

to the next

• The same difference between two samples

could give different ppm/day (or ppm/year)

depending of the period between samples

• It is of particular importance for on-line data

• How that affect interpretation?

Page 12: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

An Example: CH4

• The data set was splits in 8 Groups

corresponding to 8 different average

sampling periods

• Week, Month, Quarter, Half-Year, Year,

2 Years, 3 Years and > 4 years

• For each DGA, ppm/year was computed

• For each groups, a standard statistic study

was performed

Page 13: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Time between sampling

0

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 200 400 600 800 1000 1200 1400

Sampling Interval Days

De

ns

ity

Month

Quart

er

Half Y

ea

r1 Year

2 Y

ears

3 Y

ears

Long

Week

Sampling Interval

Page 14: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Data SetSampling Intervals

2% 5%7%

11%

57%

10%

4%

4%

Week

Month

Quarter

Half Year

1 Year

2 Years

3 Years

Long

Page 15: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Some Definitions

95 Percentile: 95% of the samples are below that value

Absolute Change (Delta) Delta PPM = PPMnow – PPMlast sample

Normalised Change (Trend)Trend = Delta PPM / (Datenow – Datelast sample)

in PPM/Day

in PPM/Year (PPM/Day * 365)

BoxPlot Graph

Page 16: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

BoxPlot Graph

First Quartile (25%)

Third Quartile (75%)

Median50% of

Population

Q1 - 1.5 IQR

Q3 + 1.5 IQR

Outliers

Outliers

Inter Quartile

Range

Page 17: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

BoxPlot Graph

• Usefully to visually evaluate a group of

data

– Spread of data

– Middle Value

– Symmetry of distribution

– Outliers

• Easy to compare several groups of data

• So, what do we have with trend data ?

Page 18: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Normalised RateCH4

PP

M / Y

ea

r

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 19: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4

PP

M / Y

ea

r

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

CH4 Normalised Rate

Page 20: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4

PP

M / Y

ea

r

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

CH4 Normalised Rate

Page 21: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

95 Percentile Rate VS Sampling Interval

0

500

1000

1500

2000

2500

3000

3500

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

95

Pe

rce

nti

le R

ate

(p

pm

/ye

ar)

CH4 Normalised Rate

Page 22: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

From Last Presentation

Page 23: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Normalised Rate

A ratio of 463 between “weekly” and “long term” sampling !!

Sampling Period PPM/Year PPM/Day

Week 3115 8.5

Month 1028 2.8

Quarter 235 0.64

Half Year 55 0.15

1 Year 19 0.052

2 Years 12 0.033

3 Years 8.3 0.023

Long 6.7 0.018

95 Percentile of Rate

Page 24: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Normalised Rate

• If we want to use PPM/year (or PPM/Day)

we obviously need a method to handle this

spread

• Should we have a table for each period?

• Which periods ?

• How many ?

• How complex ?

• Added to the “other” complexities ?

Page 25: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Normalised Rate and noise

• Maybe we are looking at it the wrong way ?

• If we have noise in the data, it would

probably be the same for short and long

period

• If we divide a fixed value by an increasing

period, we will obtain a log like curve

• As an example, let take 25 ppm / 1 day,

/7 days, /14 days … to ppm / year…..

• Then:

Page 26: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Simulation of a Constant PPM Delta

Example of Fixed Delta / Increasing Sampling Period

0

1000

2000

3000

4000

5000

6000

7000

< 3 3 - 5 5 - 10 10 -

15

15 -

30

30 -

60

60 -

90

90 -

120

120 -

180

180 -

240

240 -

365

> 365

Sampling Period Days

PP

M / Y

ea

r

Page 27: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Simulation of a Constant PPM Delta

Example of Fixed Delta / Increasing Sampling Period

1

10

100

1000

10000

< 3 3 - 5 5 - 10 10 -

15

15 -

30

30 -

60

60 -

90

90 -

120

120 -

180

180 -

240

240 -

365

> 365

Sampling Period Days

PP

M / Y

ea

r

Page 28: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

From Previous Presentation

Page 29: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Change of Perspective

• So, let try to drop the notion of normalised

rate (Trend) (PPM/day or PPM/year)

• Let look at the ABSOLUTE difference (in PPM) between two samples (Delta)

• Let group results by sampling period, as a

few slides before

• What do we have ?

Page 30: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Absolute ChangeCH4

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 31: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

All samples

Page 32: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Absolute Change

• Ratio has been reduced by a factor of 100

• A lot more manageable !!

• The use of absolute variation between

consecutive samples, without day or year

normalisation, give more uniform results and

is simpler to use

• What else could we learn from this data set ?

Page 33: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Gas Level in PPM

90 Percentile PPM

0

50

100

150

200

250

300

350

400

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

90

Pe

rce

nti

le P

PM

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

All samples

Page 34: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Gas Level in PPM

Percentage of Samples above condition 4

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

Page 35: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

95 Percentile Absolute Change and % of Samples above

Condition 4

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

CH4 Absolute Change

Percentage of points

With CH4 in Condition 4

PPM Change between samples

Page 36: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CH4 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

All Points

Points Condition 4

Removed

Page 37: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

95 Percentile Absolute Change VS Sampling Interval

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

) CH4 Absolute Change

All Points

Points Condition 4

Removed

Points Condition 3 & 4

Removed

Page 38: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

95 Percentile Absolute Change VS Sampling Interval

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

) CH4 Absolute Change

All Points

Points Condition 4

Removed

Points Condition 3 & 4

Removed

Points Condition 2 & 3 & 4 Removed

Page 39: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Other Gas

• H2, C2H4 and C2H2 have the same type of

distribution

• CO and CO2 form a different group

• C2H6 and TDCG are between the two groups

Page 40: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Other Gas

• “Type I”

• Short Term Rate Higher than long term

• Short Term Level Higher than long term

– Hydrogen

– Methane

– Eyhylene

– Acethylene

Page 41: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

H2 Absolute ChangeH2

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 42: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

H2 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

50

100

150

200

250

300

350

400

450

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

Page 43: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

C2H4 Absolute ChangeC2H4

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 44: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

C2H4 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

20

40

60

80

100

120

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

2

4

6

8

10

12

14

% S

am

ple

s >

Co

nd

itio

n 4

Page 45: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

C2H2 Absolute ChangeC2H2

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 46: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

C2H2 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

0.5

1

1.5

2

2.5

3

3.5

4

4.5

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

Page 47: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Other Gas

• “Type II”

• Short Term Rate Lower than long term

• Short Term Level similar to long term

– Carbon Monoxide

– Carbon Dioxide

Page 48: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CO Absolute ChangeCO

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 49: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CO Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

100

200

300

400

500

600

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

Page 50: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CO2 Absolute ChangeCO2

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 51: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

CO2 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

500

1000

1500

2000

2500

3000

3500

4000

4500

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

Page 52: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Other Gas

• “Type III”

• Middle Term Rate Lower than shorth

and long term

• Short Term Level lower than long term

– Ethane

– TDCG

Page 53: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

C2H6 Absolute ChangeC2H6

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 54: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

C2H6 Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

5

10

15

20

25

30

35

40

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

2

4

6

8

10

12

14

% S

am

ple

s >

Co

nd

itio

n 4

Page 55: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

TDCG Absolute ChangeTDCG

De

lta

PP

M

We

ek

Mo

nth

Qu

art

er

Ha

lf Y

ea

r

Ye

ar

2 Y

ea

rs

3 Y

ea

rs

Lo

ng

Page 56: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

TDCG Absolute Change

95 Percentile Absolute Change VS Sampling Interval

0

100

200

300

400

500

600

700

800

900

1000

Week Month Quarter Half Year 1 Year 2 Years 3 Years Long

Sampling Interval

De

lta

(p

pm

)

0

1

2

3

4

5

6

7

8

9

10

% S

am

ple

s >

Co

nd

itio

n 4

Page 57: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Conclusion

• Use Delta PPM directly without

Normalisation (no ppm/day)

• Use 90 or 95 Percentile of the whole population (maybe excluding > cond X ?)

• Determine sampling frequency on actual

level ppm value (Similar to actual Table 3)

• Adjust Value per period for CO, CO2 and

maybe for C2H6 and TDCG

Page 58: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Conclusion

• A possible table could look like:

Period: <= 1.5 Year 1.5 - 2.5 Years >= 2.5 Years

H2

CH4

C2H4

C2H2

C2H6 15 25 30

CO 200 300 400

CO2 2000 2500 3000

TDCG 300 400 500

Maximum PPM variation between sample

40

25

15

1

Page 59: Rate of Change (Trend) - IEEEgrouper.ieee.org/.../fluids/C57.104/...Beauchemin.pdf · Rate of Change (Trend) ∆PPM, PPM/day or PPM/Year What make sense? C. Beauchemin TJH2b Analytical

Questions ?

• To Be continued….