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California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
Collector's Name:Site of Sampling:
DAN ZIARLOWSKI/ESSLAVA CAP MINE14501 LAVA CAP MINENEVADA CITY 95959
RECORDS CTR
4112-00006HML f: 970U24 tc
970029
SOMSDocID 88217743
Auth. NO.: EMM3306Activity I 8MBDate Collected:|D7/08/97Date Received: 07/11/09
AnalyticalProcedure:EPA-SW 846
Method:
Samples are digested with 1:1 EN03 (and 30% H202, and 1:1 HCl,if applicable) over a hot plate. Digests are cooled, filteredand made to final volume with deionized E2O. Metal analysis ofthe digests is by ICPAES (EPA #6010). Units are Big/kg.
3050* for solids; 3010 for liquids; 3005 for clean vater.
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTl-ThalliumV-VanadiumZn-Zinc
970028
WETLAND-01SEDIMENT
175068.30.180.658.79<1.6015.9<1.506.045.16<3.00<6.004.9456.3
970029
WETLAND-08SEDIMENT
2644310.791.1014.426.457.9
<3.7515.216.8
<7.50<15.076.359.3
Notes: < » below detection limit of method.
ICP AnalystMerlyn
Jah.Chemist's SignatureFatima Hussain, Chemist
Date
California Department of I oxic Substances ControlHazardous Materials LaboratoryInorganic Section — ... . -» . . ——
Quality Assurance Summary for ICP
HML Number:to
9/0022970029•
Element
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
Element
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SelentumTI-ThalliumV-VanadiumZn-Zinc
HML Soil QC Sample
mg/kg
found
67.748.322.426.721.864.937.831.037.434.274.5132
42.949.1
known
63.344.721.525.520.759.637.730.335.431.072.8125
40.946.3
%
107108104105105109100102106110102106105106
HML Liquid QC Sample
mg/kg
found known %
MethodBlank
mg/L
<0.10< 0.005<0.003<0.009<0.05<0.08<0.05<0.08<0.05<0.10<0.15<0.30<0.06<0.05
ReagentBlank
mg/L<0.10< 0.005<0.003< 0.009<0.05<0.08<0.05' <0.08<0.05<0.10<0.15<0.30<0.06<0.05
Calibration VerificationStandard
mg/L
found
10.610.12.0310.510.610.410.210.310.610.510.210.510.310.5
known
10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0
%
106101102105106104102103106105102105103105
Inorganic VenturesReference Standard
mg/Lfound
1.061.010.201.041.031.061.011.011.051.021.041.041.021.03
known
1.001.000.201.001.001.001.00.00.00.00.00.00.00.00
%
106101100104
103
106101101105102104104102103
Duplicate Spiked Sample
Spike Results mg/kg
A:
511528102485494524563473517569509478512605
B:
528550104501511543562490537554521492530618
RPD
3.854.411.943.253.733.590.963.533.832.841.942.893.632.87
Duplicate Spiked Sample
Spike Results mg/kg
A: B: RPD
^
HML No.: 970020
UnspikedResult(mg/kg}
<5.0039.80.320.777.4331.840.0<3.7531.134.8<7.50<15.025.189.1
HML No.:
UnspikedResult(mg/kg)
^7^
SpikeAdded(mg/kgl
500500100500500500500500500500500500500500
SpikeAdded(mg/kg)
s *
Matrix: SEDIMENT
% Recovery
A:
10297.6102
96.897.398.4105
94,697.2107102
95.697.4103
B:
106102104100101102104
98.0101104104
98.4101106
Matrix:
% Recovery
A: B:
ICP Analyst's Signature:Chemist: Fatima HussaiDate Analyzed: 07/15/97
Milad S. Iskander, Supervi Date:
State if California-California Environmental Protection Agency Oapartmant of Toxic Substances ControlHazardous Materials Laboratory
HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
1. Authorization Number
o To2. Page
of
3. Requester:Address (To Receive Results):
4. Phone )*-Sf - 5. Priority Level: 1
a. Authorized by
6. Date Sampled •j-.g- 7. Time Sampled Hours
9. Activity. Q SEB Q FPB FMB HQ OTHER
8. Codes (fill in all applicable codes)
a.STC
10. SAMPLING LOCATION
b. Site
a. EPA ID No.
c. Address.
11. SAMPLES
a. ID
9lrMt
b. Collector's No.
/ L
H
c. Lab No.
MlCrr?J
Dty
Sampled. Type
Zip
Container
g. County
e. Type f. Size\ L,
g. Field Information
12. ANALYSIS REQUESTED
b.Scan
c. r~\ Metals(Spec)
d.
f. D VOA-8020
g. D VOA-H/S .
h. Q VOA-8240
i. n VOA-8260
FlashPoint
m.Q C1 -Pes-ticides
n. OP-Pes-ticides
j. SVO-8270
VOA-8010Diesel/
k. [J Gasoline
o.Q
P.D
q.Q
13. SPECIAL REMARKS:
MMM/Trtt* tncluuv* O«M
16. LAB REMARKS:
<Fomi»rlv OHS 8002»Oriflirnl-Lib • Ouolicat>-Fil« • Triplic«te-l>Mp«ctor NLY (HMU
•*>
4112-00006California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, Ca. 94704Tel No. (510) 540-3003
HMU;970022tp:970029
Date Sampled;07/08/97Date Recieved;07/11/97
LABORATORY REPORT
Collector's Name: Dan ZiarkowskiLocation: Lava Cap Mine
14501 Lava Cap Mine Rd.Nevada Citv 95959
Activity: 8MBCollector's *;LL797-Ol
to:Wetland-02Authorization*:HMN3306
AnalyticalProcedure:
Samples were extracted with 0.2M citrate buffer atpH 5 for 48 hours. The extracts were centrifucred and filtered.Analysis is done bv ICPAES. Results in rog/L,
Extraction: HML Method #910.
Analysis: EPA Method #6010A.
Analysis Results:
HMLNo.
970028961413
Collector'sSample No.
Wetland-01Wetland-02
Type ofPbSample
SedimentSediment
As
2437.37
Signatures:
Fatima HussainAnalyst
Datfe DateSupervisor
California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, Ca. 94704Tel No: (510) 540-3003
Inorganic Quality Assurance
Collector's Name: Dan ZiarkowskiSample Location: Lava Cap Mine
14501 Lava Cap Mine RdNevada Citv 95959
HML#;970022to;970029
Collector's#;LL797-01to:Wetland-02
Activity ; SMB
Analytical Procedure Used:Concentration units: mg/L
WET extraction and analysis bv ICPAESHML Method #910
1. InitialCalibrationVerification
2 . ContinuingCalibrationVerification
SpikeDuplicateResult
SpikeRecoveryResult
ReferenceStandard
Source: IVLot#:M-MEB69013Exp'date:7/98
Determinat ion
Found
True
Recovery
Method Blank
StandardSolutionSource: IVLot#:M-MEB69013
Found
True
% Recovery
Preparation Blank
Sample No.HML #970029
Matrix:Extract
Sample No.HML #970029
Matrix:Extract
Spike ResultA
Spike Results
Spike Added
Samp Result
% Recovery A
% Recovery B
% RPD
As
1.05
1.00
105
<0.10
10.6
10.0
106
<0.10
62.2
62.2
50.0
7.37
110
110
0.00
Signatures:
Fatima HussainAnalyst
DateSupervisor
State of California-California Environmental Protection Agency Department of Toxic Substances ControlHazardous Materials Laboratory
HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
1. Authorization Number
iA To
2. Page
of
.-3. Requester:Address (To Receive Results):
4. Phone (lit 5. Priority Level: 1
a. Authorized by
6. Date Sampled "J— 7. Time Sampled •lours
9. Activity: SEB ELSMB FpB D LT3 HQ Q OTHER
8. Codes (fill in all applicable codes)
a.STC
10. SAMPLING LOCATION
b. Site
a. EPA ID No.
c. Address.UiimK.r~ 'Numotr
11. SAMPLES
a. ID b. Collector's No.
Strwt City j I
B
H
c. Lab No.Sampled. Type
Zip
Container
g. County
e. Type f. Size g. Field Information
12. ANALYSIS REQUESTED
a.
b. ra Metal ^Scan
c.
d.
Metals(Spec)
g.
h.
i.
j.
VOA-8020
VOA-H/S .
VOA-8240
VOA-8260
SVO-8270
VOA-8010Diesel/
k. (_] Gasoline
n.
o.Q
P.Dq-D
Point
C1 -Pes-ticides
OP-Pes-ticides
13. SPECIAL REMARKS:
err7*' r. "!*'>*' :"14. SUPPLEMENTAL,. REQUESTS
Sigiutur* Ntnw/Titl* lnelu«m DIIM
16. LAB REMARKS: Toa,
PJSC 1116/REV. 1/94> Ongin*l-Lib • Duplicatt-Fito • Tnpliote-tnstMctor NLY(HML)
4112-00006California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML f: 961327 to961335
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINES14501 LAVA CAPNEVADA, 95959
Auth. NO.: EMM3246Activity : 8MB ,Date Collected:I/19/97Date Received: 5/21/97
Analytical Samples are extracted in 0.2 M Citrate buffer, pH 5.0 vith constantProcedure: agitation for 48 hours, followed by filtration through a 0.45 micros
membrane filter. Ratio of buffer to sample is 100 ml->!0 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.
Method: HML S.O.P. 910 California Wast* Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-Vanadium2n-Zinc
961327
WC-01SOIL
33.54.100.010.091.24<0.304.45<0.302.640.92<0.80<1.50<0.258.18
961328
WC-02SOIL
59.64.460.010.151.80<0.305.86<0.303.591.43
<0.80<1.50<0.2513.1
961329
WC-03SOIL
63.82.810.010.121.51<0.304.74<0.302.731.89<0.80<1.50<0.259.69
961330
WC-04SOIL
13200.18<0.010.840.890.932.89<0.302.58<0.50<0.80<1.500.3037.3
961331
WC-05SOIL
16.60.570.01 .0.160.84<0.301.98<0.300.990.76<0.80<1.500.337.44
Notes: < » below detection limit of method.
> » beyond standard calibration curve;(to be confirmed; an additional report will follow)
M
ate emist's Sigtfatjjdre DateZaida R. liejay, Chemist
er, Supervisor Date '
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML #: 961327 to961335
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINES14501 LAVA CAPNEVADA, 95959
Auth. No.: KMM3246Activity : 8MBDate Collected:5/19/97Date Received: 5/21/97
AnalyticalProcedure:
Method:
Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micro:membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ZCPAES (EPA #6010). Units are mg/L.
HML 8.0.P. 910 California Waste Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
961332
WC-06SOIL
4.661.50<0.010.211.50<0.301.92<0.303.65<0.50<0.80<1.50<0.257.53
961333
WC-07SOIL
13.81.10<0.010.350.55<0.301.91<0.300.930.82
<0.80<1.50<0.2519.2
961334
WC-08SOIL
47.12.46<0.010.09<0.201.37<0.10<0.300.952.02
<0.80<1.50<0.251.65
961335
WC-09SOIL
70.82.12<0.010.140.31<0.300.52<0.301.084.28
<0.80<1.50<0.25
4.37
Notes: < " below detection limit of method.
•fc &v—ICP Analyst, " jft»JHerlyn
Date
Milad S. Is Date
phemist's Sigfta ture DateZaida R. Ilejay, Chemist
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML f: 961327 to961335
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKZLAVA CAP MINES14501 LAVA CAPNEVADA, 95959
Auth. NO.: EMM3246Activity : 8MBDate Collected:5/19/97Date Received: 5/21/97
AnalyticalProcedure:
Method:
Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micronmembrane filter. Ratio of buffer to sample is 100 ml->!0 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.
HML 8.O.P. 910 California Waste Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
961327
WC-01SOIL
0.360.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.03
961328
WC-02SOIL
0.390.030.0010.01<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.04
961329
WC-03SOIL
0.610.01<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.02
961330
WC-04SOIL
32.70.040.010.500.920.211.30<0.032.36<0.05<0.08<0.15<0.0344.1
961331
WC-05SOIL
<0.040.05<0.001<0.0040.03<0.03<0.01<0.03<0.03<9 >50.15<0.15<0.030.02
Notes: < - below detection limit of method.
Samples were extracted with deionized water in place of citrate buffer.
ICP Analyst,Merlyn 4e*T5Uzman
jfemist's Signature Datelida R. Ilejay, Chemist
upervisor Date
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML f: 961327 to961335
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINES14501 LAVA CAPNEVADA, 95959
Auth. No.: HMM3246Activity : 8MBDate Collected:5/19/97Date Received: 5/21/97
AnalyticalProcedure:
Method:
Samples are extracted in 0.2 M Citrate buffer, pB 5.0 vith constantagitation for 48 hours, followed by filtration through a 0.45 micro:membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.
HML 8.O.P. 910 California Waste Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
961332
WC-06SOIL
<0.040.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
961333
WC-07SOIL
0.190.01
<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.06
961334
WC-08SOIL
0.070.03<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
961335
WC-09SOIL
0.050.03<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
Notes: < « below detection limit of method.
Samples were extracted with deionized water in place of citrate buffer.
Date (Chemist's Sig^a^ure DateZaida R. Ilejay, Chemist
Milad S. Iskander, Supervisor Date
CA Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, CA 94704
HML No.:To:'
961327961335
LABORATORY REPORT
Collector's Name: Daniel ZiarkowskiSite or Location: Lava Cap Mines
14501 Lava Cap Mine Rd.Nevada City
Auth. Number HMM3246Activity: SMB
Date Sampled: S/19/97Date Received: 5/21/97
Analytical Extracts are digested with 1:1 HNO3 (and 30% HjOj, and 1:1 HCI, If applicable) over ahot plate.Procedure Used: Digest are cooled, filtered amd made to final volume with deionized H2O. Metal analysis of
the digests is by ICPAES (EPA # 6010). Units are mg/kg.
Reference: EPA Methods 3050 & 6010
Analysis Results:
HMLNumber
961330
Collector'sSample No.:
WC-04
SampleType
SOIL
As-Arsenic
15400
Signatures:
jda R. IlejayChemist
Date Milad IskanderSupervisor
Date
California Department of Toxic Substances ControlHazardous Materials Laboratory
inorganic section Quality Assurance Summary for ICP
HML Number: 961327.t0 961335
Bement
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SelenhimTI-ThalliumV-VanadiumZn-Zinc
Element
As-ArsenicBa-BariumBe-BervllhjmCd-CadmiumCo-CobaltCr-ChromiumCu-CoooerMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
HML Sofl QC Sample
mg/kg
found known %
HML Uqukf QC Samp**
mg/kg
found known %
MethodBlank
rrtfl/L<0.040.012<0.001< 0.004<0.02<0.03<0.010<0.03<0.03<0.05<0.08<0.15<0.03<0.015
ReagentBlank
mg/L<0.04<0.002<0.001< 0.004<0.02<0.030.04<0.03<0.03<0.05<0.08<0.15<0.03<0.015
Calibration VerificationStandard
mg/Lfound
10.110.12.0810.410.310.210.310.110.310.110.410.510.110.4
known
10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0
Inorganic VenturesReference Standart
mgfound
1.031.000.201.081.071.051.001.051.071.061.041.061.011.06
known
1.001.000.201.001.001.00.00.00.00.00.00.00.00.00
%101101104104103102103101103101104105101104
1%
103100100108107105100105107106104106101106
Duplicate Spiked Sample
Spike Results mg/kg
A: B: RPD
Duplicate Spiked Sample
Spike Results mg/kg
A:
14499.120.3104103101106101103104123101
98.0115
B:
14499.120.2104103101105101104105123101
98.0116
RPD
0.000.000.000.000.000.000.990.001.000.970.000.000.00^-W&/>
HML No.:
UnspikedResult(mg/kg)
SpikeAdded(mg/kg)
HML No.: 961327
UnspikedResult(mg/kg)
33.54.100.010.091.24<0.304.45<0.302.640.92<0.80<1.50<0.25
7 8.18
SpikeAdded(mg/kg)
100100
20.0100100100100100100100100100100ft V
Matrix:
% Recovery
A: B:
Matrix: SOIL .
% Recovery
A:
11095.0101104102101102101100103123101
98.0107
B:
11095.0101104102101101101101104123101
98.0108
ICP Analyst's Signature:Chemist: Zatda llejDate Analyzed: 06/26/97
Milad S. Iskander, Supervisor Date; £/$} 7/4*7
I ••...?..,.".State of California-California Environmental Protection Agency Department of Toxic Substances Control
Hazardous Materials Laboratory
HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
1. Authorization Number HML No.
To
2. Page
3. Requester VJP^ I U Address {To Receive Results): jolS \
. Phone filfe ) XiS*Mft A^CYc ,y,
5. Priority Level: 1
a. Authorized by
6. Date Sampled 5"-\1-et"7 7. Time Sampled Hours 8. Codes (fill in alj'applicable codes)
9. Activity: D SEB • [&SMB Q FPB Q FMB Q HQ Q OTHER
10. SAMPLING LOCATION
b. Site
c. Addr
11. SAMPLES
a. ID b. Collector's No.
B
H
c. Lab No.Sampled. Type e. Type f. Size g. Field Information
12. ANALYSIS REQUESTED
a. l pH ft;ft,C,Q,6//
b. fi,
c. [51 Metals(Spec)
d. n W.E.T.
• ft
f. D VOA-8020
L. g. D VOA-H/S .
Jl h. D VOA-8240
i. QVOA-8260
F'»shPoint
VOA-8010
SVO-8270
Diesel/Gasoli
13. SPECIAL REMARKS:
m.n Cl-Pes-ticides
n. D OP-Pes-ticides
0. [MT"»
P.D
q-D
; f\ fe^Cj b.F P C. H
Sigiwtiirt
/ / - VHwM/TM*
V . /
16. LAB REMARKS:
OTSC 1116 (REV. 1/84) Ori«inal-Ub • Dupticatt-Fito • Triptic«»-ln»p«aor
I fState of California-California Environmental Protection Agency Department of Toxic Substances Control
Hazardous Materials Laboratory
1. Authorization NumberHAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
/OTSC 4. Phone (3. RequesienJJftrJ^V. 5. Priority Level: 1
a. Authorized byAddress (To Receive Results): \Q { $ \
8. Codes (fill in all applicable codes)7. Time Sampled6. Date Sampled £—\*\ ~<)-,
Q «»B Q FMB . Q HQ Q OTHER
10. SAMPLING LOCATION
LAVA
-7 , 1 S? S1c. Arirfr«« \ H
11. SAMPLES
a. ID b. Collector'sSample'd. Type fl. Field Information
I. D FlashPoint
12. ANALYSIS REQUESTED
Scan
Metals(Spec) V
d. [BXW.E.T.
i. Q VOA-8260
Diesel/k. [J Gasoline
13. SPECIAL REMARKS:
15. CHAIN OF GUSTO
*j>^>^ .\J if <
16. LAB REMARKS:
i
California Environmental Protection Agency .Department of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Wayf Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
4H2-00006HML /: 961327 to
961335
Collector's Name:Site of Sampling:
DANIEL ZIARROWSKILAVA CAP MINE14501 LAVA CAP MINE ROADNEVADA CITY 95959
Auth. NO.: EMM3246Activity : 8MB —Date Collected£p5/19/97Date Received: TD5/21/97
AnalyticalProcedure:EPA-SW 846
Method:
Samples are digested with Itl ENO3 (and 30% H202, and 1:1 HC1,if applicable) over a hot plate. Digests are cooled, filteredand made to final volume with deionized E2O. Metal analysis ofthe digests is by ICPAES (EPA #6010). Units are mg/kg.
3050 for solids; 3010 for liquids; 3005 for clean water.#«£3 '
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
961327
WC-01SOIL
16701400.873.8619.317.7121<3.7559.746.28.74<15.023.8192
961328
WC-02SOIL
319097.50.664.6021.78.55121<3.7557.760.89.59<15.015.8197
961329
WC-03SOIL
284077.30.804.2321.111.1119<3.7548.760.511.3<15.023.8198
961330
WC-04SOIL
>1600037.70.3914.68.8728.7122<3.7526.858718.6<15.015.9723
961331
WC-05SOIL
10601010.705.2612.720.776.8<3.7526.067.012.6<15.047.9140
Notes: < « below detection limit of method.
> » beyond standard calibration curve;(to be confirmed; an additional report will follow)
fafaA ' Chemist's sigjfcljpre Date
Zaida R. Ilejay, Chemist
Milad S. Sskander", Supervisor Date
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML f: 961327 to961335
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE ROADNEVADA CITY 95959
Auth. NO.: EMM3246Activity : 8MBDate Collected:05/19/97Date Received: 05/21/97
AnalyticalProcedure:EPA-SW 846
Method:
Samples are digested with Isl ENO3 (and 30% H202, and 1:1 HCl,if applicable) over a hot plate. Digests are cooled/ filteredand made to final volume with deionized E2O. Metal analysis ofthe digests is by ZCPAES (EPA #6010). Units are mg/kg.
3050 for solids; 3010 for liquids; 3005 for clean vater.
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
961332
WC-06SOIL
101087.71.047.0025.118.287.55.8786.244.715.4<15.037.5239
961333
WC-07SOIL
118040.00.414.987.309.6850.4<3.7517.558.5<7.50<15.018.9312
961334
WC-08SOIL
66971.90.504.624.3079.429.5<3.7515.231.1<7.50<15.018.6257
961335
WC-09SOIL
116066.40.594.244.6616.523.8<3.7516.353.3<7.50<15.024.9193
Notes: < - below detection limit of method.
ICP Analyst,Merlyn
Date t smist's Signgt\4re Datelida R. Ilejay, Chemist
California Department of Toxic Substances ControlHazardous Materials Laboratory
section Quality Assurance Summary for ICP
HML Number:to
961327961335
Element
As-ArsenicBa-BariumBe-BerylliumCd-Cadmfum
Co-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
IDcrnent
As-ArsenicBa-BariumBe-BervlHumCd-CadmiumCo-CobaltCr-ChromiumCu-CooperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
HML Soil QC Sample
mg/kgfound
61.041.320.224.519.151.736.127.533.029.373.5122
35.141.6
known
63.344.721.525.520.759.637.730.335.431.072.8125
40.946.3
%
96.492.494.096.192.386.795.890.893.294.5101
97.685.889.8
HML UquW QC Sample
mg/kg
found
2.823.100.843.032.375.3629.91.964.7210.13.3610.22.5654.6*
known
3.013.010.852.472.435.3929.01.974.9610.23.4710.12.4957.1
%
93.7103
98.8123
97.599.4103
99.595.299.096.8101103
95.6
MethodBlank
ma/L<0.10<0.005< 0.003< 0.009<0.05<0.08<0.05<0.08<0.05<0.10<0.15<0.30<0.06<0.05
ReagentBlank
ma/L<0.10<0.005< 0.003<0.009<0.05<0.08<0.05<0.08<0.05<0.10<0.15<0.30<0.06<0.05
Calibration VerificationStandard
mg/Lfound
10.39.892.0810.410.410.310.310.210.410.310.610.210.210.6
known
10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0
%103
98.9104104104103103102104103106102102106
Inorganic VenturesReference Standard
mg/Lfound
1.041.010.211.071.061.040.991.05.06.05.03.05.01.06
known
1.001.000.20.00.00.00.00.00
1.001.001.001.001.001.00
%
104101105107106104
99.0105106105103105101106
Duplicate Spiked Sample
Spike Results mg/kg
A:
43661798.3455470494537467487505475424560552
B:
42358594.4445457469503447470495457427504529
RPD
3.035.773.972.282.875.427.304.383.792.273.860.7111.65.29
Duplicate Spiked Sample
Spike Results mg/kg
A: B: RPD• •••• •••• •••• *••• •••• •••• •••• •••• •••• •••• •••• • ••• •••• •••^
HML No.: 961331
UnspikedResult(mg/kg)
<5.0080.5
0.7511.210.420.354.6<3.7529.460.1<7.50<15.058.9106
HML No.:
UnspikedResult(mg/kg)
'7j?
SpikeAdded(mg/kg)
500500100500500500500500500500500500500500
SpikeAdded(mg/kg)
/*
Matrix: SOIL
% Recovery
A:
87.210797.588.891.994.796.593.491.589.095.084.810089.2
B:
84.610193.786.889.389.789.789.488.187.091.485.489.084.6
Matrix:
% Recovery
A: B:
ICP Analyst's Signature:Chemist: Zaida R. lleiav Chemist's Signature;Date Analyzed: 06/19/97
Milad S. Iskander, Supervisor: Date;
California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, CA 94704(510) 540-3003
LABORATORY REPORT
Collector's Name: Daniel Ziarskawski
HML #: 961327To: 961335
Location: Lava Cap Mines14501 Lava Cap Mine RdNevada City 95957
Auth. No.:Activity:
HMM3246SMB
Date Sampled;5/19/97Date Received:5/21/97
Analytical Procedure Used: pH determined using Accumet 825MP pH metercalibrated with pH buffers 1, 4, 1, 10 and 13.
Reference: EPA Methods 9040 & 9045
Analysis Results:
HMLNO.
961327961328961329961330961331961332961333961334961335
COLLECTOR'SSAMPLE NO.
WC-01WC-01WC-03WC-04WC-05WC-06WC-07WC-08WC-09
TYPE OFSAMPLE
SOILSOILSOILSOILSOILSOILSOILSOILSOIL
pH
8.87859332
6.908.148.288.126.94
Signatures:
SupervisorDate
California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, Ca 94704
Quality AssurancepH
Procedure: pH by electrometric method
I. Calibration Standard Data
Reference: EPA 9040 & 9045
ID VendorPN
FISHER
FISHER
FISHER
EM SCIENCE
LotNo.
960128-24
960985-24
955105-24
34119
Exp.Date
8/97
2/98
11/97
BufferType
SOL'N
SOL'N
SOL'N
SQL'N
PHBuffer
4.0
7.0
10.0
13.0
mvReading
38.2
-138.4
-316.2
-482.9
Efficiency
1.0204
1.0245
0.95513
Calibration for 961330
FISHER
VWR
960285-18
9508152
7/97
8/97
SOL'N
SOL'N
1.00
7.00
-140.8
204.2
II. Laboratory Control Sample
PHBuffer
4.00
7.00
1.00
13.00
LotNo.
9510098
9508152
960285-18
34119
Source
VWR
VWR
FISHER
EM SCI
ExpectedResult
4.00
7.00
1.00
13.00
ObservedResult
4.004
€.97
0.998
13.003
AbsoluteDiff.
0.004
0.03
0.002
0.003
pH of DI H20 used in dilution 6.78
III. Laboratory Duplicate Sample Results
HMLNo.
961327
961330
SampleType
SOIL
SOIL
SampleResult
8.874
2.315
Dupl.Result
8.877
2.317
AbsoluteDifference
0.003
0.002
Analyst:lida
Supervisor:
Date;
Date:
State of California-California Environmental Protection Agency Department of Toxic Substances ControlHazardous Materials Laboratory
HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
1. Authorization Number
r^v
HML No.To
2. Page
3. Requester: U^»*J i U "Address (To Receive Results): |oVS V
Phone (Ufe ) "15$ - 3C X°l, /-vTe $,****</ ,
t
5. Priority Level: 1
a. Authorized by
6. Date Sampled 5"*"\ct-el"7 7. Time Sampled Hours
9. Activity: Q SEB E£SMB D PPB Q FMB Q HQ Q OTHER
10. SAMPLING LOCATION
b. Site _
a. EPA ID No.
c. Address.Numlxr
8. Codes (fill in alj applicable codes)
a.STC
b. Region
c. INDEX
d.PCA
•.MPC
I.SITE
g. County
11. SAMPLES
a. ID b. Collector's No.
B
u>C-o5
UP 6-0*0H
c. Lab No.
^5(330
' Cny
Sample -d. Type
Zip
Containere. Type f. Size g. Field Information
6JSu>v>e</
12. ANALYSIS REQUESTED
a.
b.
c.
. 6ScanMetals(Spec)
d. n W.E.T.
vw*. ft
VOA-8010
f- D VOA-8020
g. D VOA-H/S .
h. n VOA-8240
i. D VOA-8260
j. D SVO-8270_ Diesel/
k. [J Gasolin
I. D FlashPoint
n.
C1-Pes- .ticides
OP-Pes-ticides
. H
P.Q
13. SPECIAL REMARKS:
15. CHAIN OF OUSTODY
d.Sifnmurt MwiwDMM
16. LAB REMARKS:
>T5C 1116 (REV. Drioin»l-L»b e TripUeet NLY(HMU
Stata of California-California Environmental Protection Agency Department of Toxic Substances ControlHazardous Materials Laboratory
HAZARDOUS MATERIALSI SAMPLE ANALYSIS REQUEST
1. Authorization Number
i\ rv\To
2. Page
3. Requesten^rvKfi^Address (To Receive Results):^oi£\
4. Phone 5. Priority Level:
a. Authorized by
,' 6. Date Sampled g — \ <\ —,
7. Time Sampled , • Hours 8. Codes (fill in all applicable codes)
9. Activity: SEB JF^SMB D FpB D FMB D HQ Q OTHER
10. SAMPLING LOCATION
CVp
a. EPA ID No.
c. Address i±LS£lNumber SUMt
11. SAMPLES
a. ID b. Collector's No.
B
H
c. Lab No.
City I f
Sample"d. Type*G>] U.
Z»
Containere. Type f. Size g. Field Information
12. ANALYSIS REQUESTED
b. MetalScan
~~ (Spec) V
d. [&W.E.T. J .
« W
f. U VOA-E
g.D
h. ni. n VOA-8260
«. n VOA-8010Diesel/Gasoline
13. SPECIAL REMARKS:
n. I I
o. [J0
P-D
q-D
Flash _Point
d-Pes- .ticides
OP-Pes-ticides
c.Slfwttir*
Stgn«tura InclwmOdM
16. LAB REMARKS:
Ml V fUMt t
4112-00006California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML #: 960957 to960966
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959
Auth. NO.: HMM3163SActivity : SMB „Date Collected:J/14/97Date Received: 3/18/97
Analytical Samples are extracted in 0.2 M citrate buffer, pH 5.0 with constantProcedure: agitation for 48 hours, followed by filtration through a 0.45 micron
membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.
Method:
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
960957
LCS-1SOIL
11.70.980.010.08
<0.20<0.300.27<0.300.472.08
<0.80<1.50<0.252.92
960958
LCS-2SOIL
11.81.06<0.010.07<0.20<0.300.14<0.300.432.23
<0.80<1.50<0.252.92
960959
LCS-3SOIL
12.51.28<0.010.070.22<0.300.32<0.300.371.67<0.80<1.50<0.253.67
960960
LCS-4SOIL
9.776.490.020.080.77
<0.300.91<0.300.480.88<0.80<1.501.095.52
960961
LCS-5SOIL
28.12.12<0.010.060.22<0.300.25<0.300.361.12<0.80<1.50<0.253.99
Notes: < - below detection limit of method.
o&sICP Analyst,Merlyn de
Date
Milad S. Iskander,'Supervisor ate
Chemist's SignatureFatima Hussain, Chemist
tltifDat<i
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML fl 960957 to960966
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959
Auth. No.: HMM3163SActivity : 8MBDate Collected:3/14/97Date Received: 3/18/97
AnalyticalProcedure:
Method:
Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micronmembrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA i6010). Units are mg/L.
HML 8.0.P. 910 California Waste Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
960962
LCS-6SOIL
19.22.750.010.110.46
<0.300.76
<0.300.751.89
<0.80<1.50
0.276.20
960963
LCS-7SOIL
9.507.230.030.090.84
<0.301.13
<0.300.690.92
<0.80<1.50
1.294.82
960964
LCS-8SOIL
6.206.120.020.061.44
<0.300.79
<0.303.140.80
<0.80<1.50
0.883.46
960965
LCS-9Sediment
24.84.040.020.100.29
<0.300.70
<0.300.682.05
<0.80<1.50
0.466.12
960966
LCS-10Sfediment
29.33.760.010.100.35
<0.300.54
<0.300.582.00
<0.80<1.50
0.517.02
Notes: < - below detection limit of method.
CP Attalyst,Merlyn de
Mi lad S. Iskander, Supervisor Date
Chemist's SignatureFatima Hussain, Chemist
Date
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML 960957 to960966
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959
Auth. No. : HMM31633Activity : 8MBDate Collected:3/14/97Date Received: 3/18/97
AnalyticalProcedure:
Method:
Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micronmembrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.
HML S.O.P. 910 California Waste Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
960957
LCS-1SOIL
0.08<0.002<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.02
960958
LCS-2SOIL
0.270.010.0020.01<0.02<0.030.010.04
<0.03<0.05<0.08<0.15<0.030.02
960959
LCS-3SOIL
0.20<0.002<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
960960
LCS-4SOIL
<0.040.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
960961
LCS-5SOIL
0.110.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
Notes: < « below detection limit of method.
Camples were extracted with rteionized ureter instead JDf-£.2M citrate buffer,
ICP Arfelyst,Merlyn
/f 7ate Chemist's Signature /Date
Fatima Hussain, Chemist
Milad S. Iskander,'SupervisorW7/97Date
California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571-3003
HML f: 960957 to960966
Collector's Name:Site of Sampling:
DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959
Auth. NO.: EMMS163SActivity : 8MBDate Collected:3/14/97Date Received: 3/18/97
AnalyticalProcedure:
Method:
Samples are extracted in 0.2 M citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micro:membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ZCPAES (EPA #6010). units are mg/L.
HML S.O.P. 910 California Waste Extraction Test
HML Number:Collector'sSample No.:Sample Type:
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
960962
LCS-6SOIL
0.090.01<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
960963
LCS-7SOIL
<0.040.04<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
960964
LCS-8SOIL
<0.040.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
960965
LCS-9Sbediroent
0.090.07<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
960966
LCS-10Sodiraent
0.070.07<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01
Notes: < » below detection limit of method.
Samples were extracted with deionized water instead of 0.2M citrate buffer.
ICP Analyst,Merlyn de G
Chemist's Signature /DateFatima Hussain, Chemist
Milad S. Iskahder, 'Supervisor Date
California Department of Toxic Substances ControlHazardous Materials LaboratoryInorganic Section —. ... A _ *• i i-»
Quality Assurance Summary for ICP
HML Number: 960957 ;'to 960966"
Element
As-ArsenteBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
Element
As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc
HML Sod QC Sample
mg/kgfound known %
HML Liquid QC Sample
mg/kg
found known %
MethodBlank
ma/L<0.04< 0.002<0.001<0.004<0.02<0.03<0.010<0.03<0.03<0.05<0.08<0.15<0.03<0.015
ReagentBlank
mg/L
<0.04<0.002< 0.001<0.004<0.02<0.030.03<0.03<0.03<0.05<0.08<0.15<0.03<0.015
Calibration VerificationStandard
mg/Lfound
10.110.02.0310.310.310.110.110.210.310.210.310.29.9910.3
known
10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0
%101100102103103101101102103102103102
99.9103
Inorganic VenturesReference Standard
mg/L
found
1.021.010.201.031.031.021.051.011.041.021.031.021.001.03
known
1.001.000.201.001.001.001.001.001.001.001.001.001.001.00
%
102101100103103102105101104102103102100103
Duplicate Spiked Sample
Spike Results mg/L
A:
67.849.910.152.752.251.651.152.452.655.261.551.550.0 .57.5
B:
67.549.810.152.151.651.051.051.851.954.661.350.549.657.1
RPD
0.00.250.000.961.161.170.000.970.970.950.331.960.800.92
Duplicate Spiked Sample
Spike Results mg/L
A:
5.294.981.025.265.185.084.995.095.215.245.475.144.935.39
B:
5.344.971.025.325.265.154.975.175.265.325.515.204.975.46
RPD
0.240.050.000.001.150.150.100.390.240.380.180.290.200.32^
HML No.: 960957
UnspikedResult(mg/L)
11.70.980.010.08<0.20<0.300.27<0.300.472.08<0.80<1.50<0.252.92
HML No.:
UnspikedResult{mg/U
0.08<0.002<0.001< 0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03
t532
SpikeAdded(mg/L)
50.050.010.050.050.050.050.050.050.050.050.050.050.050.0960957
SpikeAddedImg/L)
5.005.001.005.005.005.005.005.005.005.005.005.005.005/ 0
Matrix: Extract
% Recovery
A:
11297.8101105104103102104104106123103100109
1 B:
"11297.610110410310210210310310512310199.2108
Matrix: ExtractWater
% Recovery
A:
10410010210510210410010210410510910398.6107
B:
10599.410210510610399.4.10310510611010499.4109
»CP Analyst's Signature:Chemist: Fatima HDate Analyzed: 04/16/97
Milad S. Iskander, Supervisor: Date; (f//7/?7
•Gt«et of £alftcmia-C»liforni8 Environmenta Department of Toxic Substances ControlHazardous Materials Laboratory
HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
1. Authorization Number;3
HML No.
To
2. Page
^ - -
3. Requester: \>V\J tWC^n^A /G"i~>K 4. Phone (M6 ) T_5^ - 36Address (To Receive Results): \p|S|
- - - -
5. Priority Level:
a. Authorized
6. Date Sampled 7. Time Sampled Hours
9. Activity: Q SEB jtf SMB Q FPB Q FMB Q HQ Q-OTHER
10. SAMPLING LOCATION
b. Site UvJA
8. Codes (fill in all applicable codes)
a.STC
b. Region
a. EPA ID No.
c. Address
11. SAMPLES
a. ID
Number Suwt'
b. Collector's No.LCS-t
B
H LCT-V
c. Lab No.
C«y
Sampled. Type
Containere. Type f. Size g. Field Information
12. ANALYSIS REQUESTED
a.
. 0.Metal V\6,C,0 P..Ef firsn 7 1 J
C.
d.
(Spec)
W.E.T.
f. Q VOA-8020
g. D VOA-H/S .
h. D VOA-8240
i. D VOA-8260
FlashPoint
j. SVO-8270
e. Q VOA-8010Diesel/
k. [j Gasoline
n. 1_J
p-D
q-D
C1-Pes-ticides
OP-Pes-ticides
13. SPECIAL REMARKS:
18. CHAIN Of CUSTODYILH. V I f f
orsrc rrrefffev. i/-94j(Formerly DHS 8002) Original-Lab • Dupltcatt-File • Triplicate-Inspector TJfFl NLY(HML)
State pf California-California Environmental Protection Agency,._
7 Department of .Toxie~S• ,• Hazardous Materials''' -
HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST
1. Authorization Number
tv\3. Requester:
Address (To Receive Results): lO|s-|- Phone (q,L6°) 1X5" -vOyf Svtte.1 CrO
5. Priority Level:
a. Authorized b
6. Date Sampled S -JH" 7. Time Sampled •lours
9. Activity: D SEB Q n FMB n HQ D OTHER
10. SAMPLING LOCATION
b. sitea. EPA ID No.
Mwe
c. Address.
8. Codes (fill in alj applicable codes)*<•$.''*
a.STC
b. Region
c. INDEX
d. PCA
e.MPC
f. SITE
g. County]Numtxr
11. SAMPLES
a. ID b. Collector's No.
StTMI
B L C S -lo
H
c. Lab No.Sampled. Type
Containere. Type f. Size g. Field Information
PLASTIC
12. ANALYSIS REQUESTED
a. n pH
b.TX
c. fift Metals^Spec)
d. D W.E.T.
f. n VOA-8020
g; n VOA-H/S .
Point
MetalScan
H^
fe,E]i h. D VOA-8240
_ i. D VOA-8260
j. SVO-8270
e. n VOA-8010Diesel/
k. [J Gasoline
n.
o.
P.Dq.Q
C1-Pes-ticides
OP-Pes-ticides
13. SPECIAL REMARKS:
15. CHAIN OfACl/SJODY
3 V /H /T7
CigrwAjr*
Sipniiur*
~~" Indimv* Dim
/ / . / /Nwnt/TiU*
Signnurt
Induclvt Ottu
/ / - / /lndu»iv« D>lu
16. LAB REMARKS&k
Y
DISC 1116 (REV. 1/94){Formerly PHS 8O02)
Original-Lab • Ouplica»-Ble • Triplicat»-lnsp«cior NLY(HML)
-03-19-91 03:02PM FROM DTSC REGION i SACTO. TO 914157441916 P009
i 12:04 FAX 8106403616 HML AQ. PARK
4112California EAviroxmental Protection AgencyDepartment of Toxic Substances Controlaaz&rdous ftaterlals Lauorarory (inorganic sect ion j2151 Berlcelay Nay, Berkeley, CA 94704
Phone: (510) 540-3003 or (ATSS) 571*3003
Coll«cst:or«« Nwn«n CAM aiARXOWCKISite of Caioplingj lAVA CAP MINE
14501 LAVA. CAP MINE RDNEVADA CITY
i!02
ft 960813 to960820
HO.;Activity : 5MBDate Collected; 1/31/97Data Received: 2/4/97
AnalyticalProcedure:1PA-SW 846
Kethod:
HMLCollector ' sSample No. :Sample Type:
As-ArsenicBa-BariunBe-BerylliumGel-CadmiumCo-cobaltCr-ChromiumCu-copperMo-Molybdenum
Sanples are digested with 1:1 10703 [and 30% H202, and 1:1 HCl,if applicable) over a hot plate. Digests are cooled, filteredand »adia to final volume with deioni.zed H2O. Ketal analysis orthe digests is by ICPAES (EPA feoio). units are mg/kg.
305O for solids; 3O10 for liquids; 3DOS £oxr clean wator.
9610813 960814 O6O815 . 96O816 96O817
Tl-ttialliumv-vanadiua
LLWWATER
<1.00<0.05<O.O3<0.09<0.50<0.80<0.50<0*TS14.2
<1.00-Cl.SOo.oo<0.60
2,32
•HRSSOII.
55226.00.222.484.135.8515.3
0.7510.229.7
<7,50
13.2155
DAMSSOIJu
39216.30.181.783.544.6814.9
<3.758.7427.7
<7.50<15.0
8.85116
Notes: <£ » bo low datac^lon limit of
Chemislr * sr SignatureAt if H. K
Date
R-95X 5105403615 02-26"87 P002
03/19/97 WED 14:27 [TX/RX NO 8507]
03-19-91 03:02PM FROM DTSC REGION 1 SACTO. TO 914151441916
. 02/&/B7 12:04 FAX 5105403815 HML AQ. PARK
P010
[fi 03
California Environmental Protection Agency&epaxrfcst«mt: of Toxxo Subvbanooc controlHaaardouo Materials Laboratory (inorganic Section)2151 BerVfelay Way. Berkeley, CA 94704
Phone: (51O) 540-3O03 or (AT58) 571-3003
collector's Name: DAN ZIARKOWSXISite of Sampling: XAVA CAP KIKE
14501 IAVA CAP MINE RDNEVADA CITY
HML *: 960813 to960820
AUth. WO.: HMM3126Activity : sx&Date Collected: 1/31/97Date Received: 2/4/97
AnalyticalProcedure:SPA-SW 846
Methods
EML Number:collector ' sSample No. :Sample Type:
As-ArsenicBa-BariumBe-Bery 11 iumCd-Cad&iimCo-Cobaltcr-ChromiumCu-CopperMo-«olybdenurojri-NickelPb-LeadSis-Selenium
sanples are digested with 1:1 HNO3 (and 301; H202, and iti Hci,if applicable) over a hot plate. Digests are cooled, filteredand aade to final volume with deionized B2O. Metal analysis ofthe digests is by ICPAES (EPA 46010). Units are mg/kg.
30SO for solides 3010 for liquids; 3005 for clean water.
960818 960819 960820
V-VanadixunZn-Zinc
DAHWWATER
<1.OO0.07
<O.O3<O.09<O.SO<O.BO<0.50<0»75<0.50<1.00<1.SO<3.00<O_6O<O,50
LCRHSSOIL
51141.80.27a. 664.977.8113.2
<3.7S11.826.0<7-50<15.014.5161
LCRHWHATER
<1.00<0. 05<0.03<O.O9•CO. 50<O.80<0.50<0.75<0.50<i.OO<1.SO<3.00<O.6O<O.5O
KTotes: < — below dot notion limit of aethed.
Date_
SionatureAt if R. loziaan, Chemist
Date
Milad s. iskand r, supervisor Date
5105403615 02-36-97 12:40PM P003 If0 J
03/19/97 WED 14:27 [TX/RX NO 8507]
03-19:91 03-.02PM FROM DTSC REGION 1 SACTO. TO 914151441916 P01
SOIL/WATER SAMPLE LOCATIONS
LAVA CAP MINE/LITTLE CLIPPER CREEK
Samples collected 1-31-97
SAMPLE #
LLW
LLS
HRW
HRG
DAMS
DAMW
LCRMS
LCRMW
LOCATION DESCRIPTION
Lost Lake water
Lost Lake soil
Water sample collected @Greenhorn Rd and LittleClipper Creek
Soil sample collected SGreenhorn Road andLittle Clipper Creek
Soil collected near thedam breach at Lava Cap Mine
Pore water from DAMS soil
Soil sample coJ 1 untied @Raccoon Mountain Road soiland Little Clipper Creek
Water sample collected @Raccoon Mountain Road andLittle Clipper Creek
sample results attached
03/19/97 WED 14:27 [TX/RX NO 8507]