Revision Date 17/03/2014Revision 1

SAFETY DATA SHEET RO IM C346

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name RO IM C346

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Corrosion Inhibitor

1.3. Details of the supplier of the safety data sheet

Trading & Development Co. for Machinery And Equipment

Supplier

Factory for ChemicalsDammam 2nd Industrial CityP.O Box: 2923, Al Khobar 31952Kingdom of Saudi Arabia(+96613) 812 7775(+96613) 812 1715www.redaoilfield.com

1.4. Emergency telephone number

+44 (0)1224 937888

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)Physical and Chemical Hazards Flam. Liq. 3 - H226Human health Acute Tox. 4 - H302;Acute Tox. 4 - H312;Acute Tox. 4 - H332;Eye Irrit. 2 -

H319;Skin Sens. 1 - H317;Carc. 2 - H351Environment Aquatic Chronic 2 - H411

Classification (1999/45/EEC) Xn;R20/21/22. Carc. Cat. 3;R40. Xi;R36. R43. N;R51/53. R10.The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

2.2. Label elements

Contains FUEL, DIESEL NO 2; GASOIL - UNSPECIFIED

1H-Imidazole-1-ethanamine,4,5-dihydro-,2-(C7-17 and c7-17-unsatd. alkyl) derivs

2-MercaptoethanolLabel In Accordance With (EC) No. 1272/2008

Signal Word WarningHazard Statements

H226 Flammable liquid and vapour.H302 Harmful if swallowed.H312 Harmful in contact with skin.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H332 Harmful if inhaled.H351 Suspected of causing cancer.

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RO IM C346H411 Toxic to aquatic life with long lasting effects.

Precautionary StatementsP501 Dispose of contents/container in accordance with local regulations.

Supplementary Precautionary StatementsP201 Obtain special instructions before use.P202 Do not handle until all safety precautions have been read and understood.P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.P233 Keep container tightly closed.P240 Ground/bond container and receiving equipment.P241 Use explosion-proof electrical equipment.P242 Use only non-sparking tools.P243 Take precautionary measures against static discharge.P270 Do not eat, drink or smoke when using this product.P271 Use only outdoors or in a well-ventilated area.P272 Contaminated work clothing should not be allowed out of the workplace.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing/eye protection/face protection.P281 Use personal protective equipment as required.P261 Avoid breathing vapour/spray.P264 Wash contaminated skin thoroughly after handling.P370+378 In case of fire: Use foam, carbon dioxide, dry powder or water fog for

extinction.P301+312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel

unwell.P302+352 IF ON SKIN: Wash with plenty of soap and water.P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated

clothing. Rinse skin with water/shower.P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position

comfortable for breathing.P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.P308+313 IF exposed or concerned: Get medical advice/attention.P312 Call a POISON CENTER or doctor/physician if you feel unwell.P330 Rinse mouth.P333+313 If skin irritation or rash occurs: Get medical advice/attention.P363 Wash contaminated clothing before reuse.P391 Collect spillage.P403+235 Store in a well-ventilated place. Keep cool.P405 Store locked up.

2.3. Other hazards

This product does not contain any PBT or vPvB substances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

FUEL, DIESEL NO 2; GASOIL - UNSPECIFIED 60-100%

CAS-No.: 68476-34-6 EC No.: 270-676-1

Classification (67/548/EEC)Carc. Cat. 3;R40

Classification (EC 1272/2008)Carc. 2 - H351

1H-Imidazole-1-ethanamine,4,5-dihydro-,2-(C7-17 and c7-17-unsatd. alkyl) derivs 10-30%

CAS-No.: 90411-92-0 EC No.: 291-471-3

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RO IM C346Classification (67/548/EEC)Xi;R36/38.R43,R52/53.

Classification (EC 1272/2008)Skin Irrit. 2 - H315Eye Irrit. 2 - H319Skin Sens. 1 - H317Aquatic Chronic 3 - H412

2-Mercaptoethanol 5-10%

CAS-No.: 60-24-2 EC No.: 200-464-6

Classification (67/548/EEC)T;R23/24/25. Xn;R48/22. Xi;R38,R41. N;R50/53.R43.

Classification (EC 1272/2008)Acute Tox. 3 - H301Acute Tox. 3 - H311Acute Tox. 2 - H330Skin Irrit. 2 - H315Eye Dam. 1 - H318Skin Sens. 1 - H317STOT RE 2 - H373Aquatic Acute 1 - H400Aquatic Chronic 1 - H410

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Composition CommentsThe data shown are in accordance with the latest EC Directives.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General informationGet medical attention. Perform artificial respiration if breathing has stopped. Show this safety data sheet to the doctor in attendance.InhalationRemove victim immediately from source of exposure. Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. If breathing stops, provide artificial respiration.IngestionDO NOT INDUCE VOMITING! If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Never give liquid to an unconscious person. Get medical attention.Skin contactRemove contaminated clothing and flush with plenty of water until pain disappears. If discomfort persists transport to hospital and bring these instructions.Eye contactImmediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Immediately transport to hospital or eye specialist.

4.2. Most important symptoms and effects, both acute and delayed

General informationIf adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.InhalationRespiratory irritant effects that impair function with symptoms such as cough, pain, choking, and breathing difficulties.IngestionHarmful if swallowed.Skin contactSkin irritation. Prolonged or repeated contact with used oil may cause serious skin diseases, such as dermatitis.Eye contactMay cause severe irritation to eyes.

4.3. Indication of any immediate medical attention and special treatment needed

No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

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RO IM C346Extinguishing mediaExtinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.Unsuitable extinguishing mediaWater jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion productsDuring fire, toxic gases (CO, CO2) are formed. Sulphurous gases (SOx).Unusual Fire & Explosion HazardsFLAMMABLE.Specific hazardsWhen heated and in case of fire, harmful vapours/gases may be formed. Closed containers can burst violently when heated, due to excess pressure build-up.

5.3. Advice for firefighters

Special Fire Fighting ProceduresSpillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.Protective equipment for fire-fightersSelf contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

For personal protection, see section 8. Do not breathe vapour. Do not smoke, use open fire or other sources of ignition. Take precautionary measures against static discharges.

6.2. Environmental precautions

Do not allow ANY environmental contamination. Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material. Use appropriate containment to avoid environmental contamination. Ensure electrical continuity by bonding and grounding (earthing) all equipment.

6.3. Methods and material for containment and cleaning up

Contain spillage with sand or earth. Self-contained breathing apparatus with full facepiece. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Do not flush road with water. Contain contaminated water/ firefighting water For waste disposal, see section 13.

6.4. Reference to other sections

For personal protection, see section 8. For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Avoid spilling, skin and eye contact. Flammable/combustible material.

7.2. Conditions for safe storage, including any incompatibilities

Avoid inhalation of vapours and contact with skin and eyes. Store in tightly closed original container in a dry, cool and well-ventilated place. Drums should be stacked to a maximum of three high. Store in a demarcated bunded area to prevent release to drains and/or watercourses. Vapours are heavier than air and may travel along the floor and in the bottom of containers. Contaminated rags and cloths must be put in fireproof containers for disposal. Avoid exposure to high temperatures or direct sunlight. Do not use compressed air or oxygen for filling, discharging or handling. May explode in a fire. Keep containers tightly closed. Suitable containers: mild steel, stainless steel. Do NOT use container made of: Rubber, neoprene or PVC. Do not subject to grinding/shock/friction.Storage ClassFlammable liquid storage.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

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RO IM C346Contains no substances with occupational exposure limit values.

8.2. Exposure controls

Protective equipment

Process conditionsUse engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station.Engineering measuresProvide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.Respiratory equipmentIn case of inadequate ventilation and work of brief duration, use suitable respiratory equipment.Hand protectionNeoprene, nitrile, polyethylene or PVC. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable.Eye protectionGoggles/face shield are recommended. Contact lenses should not be worn when working with this chemical!Other ProtectionWear suitable protective clothing as protection against splashing or contamination.Hygiene measuresObserve good chemical hygiene practices.Skin protectionWear apron or protective clothing in case of splashes.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Dark coloured liquid.Colour Yellow. to Dark. Amber.Odour Characteristic.Solubility Insoluble in water Soluble in: Hydrocarbons. Miscible with waterInitial boiling point and boiling range (C)Not determined.Melting point (C)Not available.Relative density 0.82 - 0.90 at 20CVapour density (air=1)Not available.Vapour pressureNot available.Evaporation rateNot available.pH-Value, Conc. SolutionNot applicable.pH-Value, Diluted SolutionNot available.ViscosityNot available.Decomposition temperature (C)Not available.Odour Threshold, LowerNot available.Odour Threshold, UpperNot available.Flash point (C) >52.0C minimum CC (Closed cup).Auto Ignition Temperature (C) 257C

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RO IM C346Flammability Limit - Lower(%)Not available.Flammability Limit - Upper(%)Not available.Partition Coefficient (N-Octanol/Water)Not available.Explosive propertiesNot available.Oxidising propertiesNot available.

9.2. Other information

No information required.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.

10.3. Possibility of hazardous reactions

No hazardous reactions when stored and handled according to instructions.Hazardous PolymerisationWill not polymerise.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials

Materials To AvoidStrong oxidising substances.

10.6. Hazardous decomposition products

During fire, toxic gases (CO, CO2) are formed.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity:Acute Toxicity (Oral LD50)> 490.0 mg/kg Rat

Acute Toxicity (Dermal LD50)> 2500.0 mg/kg Rabbit

Acute Toxicity (Inhalation LC50)> 340.0 mg/l (vapours) Rat 1 hour

SECTION 12: ECOLOGICAL INFORMATION

EcotoxicityThe product is mildly toxic to aquatic organisms.

12.1. Toxicity

Acute Fish ToxicityToxic to aquatic organisms.Acute Toxicity - FishLC50 96 hours ~ 35.0 mg/l Pimephales promelas (Fat-head Minnow)

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RO IM C346EC 50, 48 Hrs, Daphnia, mg/l No data available.IC 50, 72 Hrs, Algae, mg/l No data available.

12.2. Persistence and degradability

DegradabilityThere are no data on the degradability of this product.

12.3. Bioaccumulative potential

Bioaccumulative potentialThe product contains potentially bioaccumulating substances.Partition coefficientNot available.

12.4. Mobility in soil

Mobility:No data available.

12.5. Results of PBT and vPvB assessment

This product does not contain any PBT or vPvB substances.

12.6. Other adverse effects

Not applicable.

SECTION 13: DISPOSAL CONSIDERATIONS

General informationWaste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements. Hazardous waste landfill in sealed containers. Environmental manager must be informed of all major spillages.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

UN No. (ADR/RID/ADN) 1268

UN No. (IMDG) 1268

UN No. (ICAO) 1268

14.2. UN proper shipping name

Proper Shipping Name PETROLEUM DISTILLATES, N.O.S., or PETROLEUM PRODUCTS, N.O.S. (Diesel, Fuel)

14.3. Transport hazard class(es)

ADR/RID/ADN Class 3

ADR/RID/ADN Class Class 3: Flammable liquids.

ADR Label No. 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels

FLAMMABLELIQUID

3

14.4. Packing group

ADR/RID/ADN Packing group III

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RO IM C346IMDG Packing group III

ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-E, S-E

Emergency Action Code 3Y

Hazard No. (ADR) 30

Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

No information required.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Uk Regulatory ReferencesHealth and Safety at Work Act 1974. The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.Guidance NotesWorkplace Exposure Limits EH40. CHIP for everyone HSG(108).EU LegislationRegulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Issued By HS&E Manager.Revision Date 17/03/2014Revision 1

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RO IM C346Risk Phrases In Full

Flammable.R10Harmful by inhalation, in contact with skin and if swallowed.R20/21/22Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R52/53Harmful: danger of serious damage to health by prolonged exposure if swallowed.R48/22Irritating to eyes and skin.R36/38Irritating to eyes.R36Irritating to skin.R38Limited evidence of a carcinogenic effect.R40May cause sensitisation by skin contact.R43Risk of serious damage to eyes.R41Toxic by inhalation, in contact with skin and if swallowed.R23/24/25Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R51/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R50/53

Hazard Statements In FullCauses serious eye damage.H318Causes serious eye irritation.H319Causes skin irritation.H315Fatal if inhaled.H330Flammable liquid and vapour.H226Harmful if inhaled.H332Harmful if swallowed.H302Harmful in contact with skin.H312Harmful to aquatic life with long lasting effects.H412May cause an allergic skin reaction.H317May cause damage to organs through prolonged or repeated exposure.H373Suspected of causing cancer.H351Toxic if swallowed.H301Toxic in contact with skin.H311Toxic to aquatic life with long lasting effects.H411Very toxic to aquatic life with long lasting effects.H410Very toxic to aquatic life.H400

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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