reliance industries limited -...

Reliance Industries Limited

Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai

RELIANCE INDUSTRIES LIMITED

Multi-Purpose Chemical Terminal

Chennai, Tamil Nadu

Pre-Feasibility Report

For

Proposed Expansion of Multi-Purpose Chemical Terminal (MCT) from

86928 KL to 108950 KL

August 2017



Contents

Section Description Page

Executive Summary 3

1. Introduction 4

2. Site Information 7

3. Project Description 9

4. Environment Control Measures 13

5. Project Implementation 15

6. Regional Brief 17

Annexure

I Topo sheet showing MCT Chennai 19

II Plot Plan 20

III Material Safety Data Sheet 21



EXECUTIVE SUMMARY

The Multipurpose Chemical Terminal (MCT), Chennai of Reliance Industries Limited (RIL)

was set up in year 2004 with the aim of receiving, storing and distribution of finished

Petroleum Products (i.e. Motor Sprit, High Speed Diesel & Ethanol) to the RIL Retail outlet

network for the state of Tamilnadu, Andhra Pradesh. The present capacity of this terminal is

86928 KL.

The terminal is located in the Notified Special & Hazardous Industrial use zone classified by

Chennai Metropolitan Development Authority (CMDA) at Vallur Village, about ~20 km aerial

distance from Chennai city. The terminal is easily accessible by road. The nearest airport of

Chennai Airport located at an aerial distance of ~40 km. The total area of the terminal facility

is ~33 acres and includes the tank farm, truck loading bays, office space and the associated

facilities.

It is now proposed to expand this multipurpose chemical terminal to 108950 KL. In the

proposed expansion, the terminal will increase storage of Class A products such as Motor

Spirit (MS), Naphtha & Ethanol and Class B products such as High Speed Diesel (HSD),

Superior Kerosene Oil (SKO), Aviation Turbine Fuel (ATF) by setting up new tanks and also

explore possibilities to increase the current storage level of existing tanks in-line with the

approvals from concerned statutory authorities. The dispatch of the petroleum products will

be through the existing 16 bays tank truck gantry.

The power supply to the terminal is from Tamilnadu Electricity Board (TNEB) at 11 KV.

During emergency, DG sets will also be used. The existing water requirement for the terminal

operation is ~ 18 KLD sourced from Chennai metropolitan water supply and sewerage

board/other local water supply by tankers. Additional water requirement of ~ 5 KLD for the

proposed project shall also be sourced from same.

The only source of air emissions from the terminal operations are DG sets which are operated

during emergencies and negligible. An Oily Water Separator (OWS) of a capacity of 300 KL

is provided to separate oil and adeqaute to handle the proposed project load also. The

hazardous & non-hazardous wastes generated in terminal shall be segregated and disposed

of through authorized agency as per Hazardous waste rules as per the existing practice. The

terminal has adequate safety & firefighting systems in line with the requirements of OISD

117/ Petroleum Rules 2002 to control any untoward incidents.

The existing manpower at the terminal is ~ 65 personal and may need additional ~ 12 people

during operation. The proposed project will lead to employment generation of ~ 50 people

during construction phase. Local manpower will be preferred. The Capex of the project is ~20

Cores & scheduled to be commissioned in stages starting within one year after the EC is

granted.



1. INTRODUCTION

Reliance Industries Limited (RIL) is one of the world leaders in the energy sector and has diversified in areas such as Exploration & Production (E&P) of Oil & Gas (O&G), Refining, manufacturing and marketing of petroleum and petrochemical products. The hydrocarbon retail & marketing arm of RIL has Multipurpose Chemical Terminal (MCT) at Chennai, which was set up in year 2004 for receiving, storing and distribution of finished Petroleum Products (i.e. Motor Sprit, High Speed Diesel & Ethanol) to the RIL & other oil companies retail outlet network in the state of Tamilnadu & Andhra Pradesh.

Presently MCT, Chennai receives the petroleum product from RIL, Jamnagar Refinery through Ennore port and is supplied by ~9 km pipeline from port to the terminal. The products stored in the existing tank farm and sold to the retail outlets, Industrial Customers and other Oil Marketing Companies by tank-trucks based on demand. A schematic diagram showing the project is given below:

The petroleum product storage capacity of the existing terminal is 86928 KL and with a 16 bay tank-truck loading gantry rack for filling the products in truck-tankers for dispatch to retail outlets. Associated facilities of the terminal include 2 DG sets of 325 KVA capacity for power back up and an electrical substation. The power required to operate the terminal is supplied by TNEB at 11 KV.

The terminal is also equipped with a laboratory for batch formation tests. A comprehensive firefighting facility has also been set up at the terminal to meet any untoward incidents. The firefighting capability comprises of fire engines with a hydrant network of 33 hydrants and 21 monitors along with cooling water Sprinklers and Foam Pourer System covering the entire tank farm area.



MCT, Chennai now proposes to expand its storage capacity from 86928 KL to 108950 KL within the existing MCT facility.

Project Justification

With an annual increase of ~ 6% in the consumption of petroleum products in the country and also due to the growing clientele of the company, the need for increasing the storage facilities has been felt by the company. This will help the company in expanding its business prospects and meet the future requirement of petroleum products in the state. No additional land is required as the expansion will be implemented within the existing terminal facility, Moreover, this will also provide edge by utilisation of the infrastructure already developed for existing in the facility to meet the proposed expansion. The rationale for the proposed expansion is as below;

Availability of requisite infrastructure facilities

Availability of land for the proposed expansion project within the premises of existing terminal

Lower capital cost compared to the grass root project.

Optimization of existing power and utilities assets

Due to the optimisation and use of available infrastructure and associated utilities for the proposed project activity, the environmental impacts are also reduced

MCT, Chennai has a well-established Integrated Management System, conforming to ISO 14001, 9001 & 18001 standards which will be strengthened and will cover this proposed project as well

Meeting the gap in demand and supply of petroleum products in Southern States in the country

Business Case

The MCT, Chennai is currently selling on an average 27691 KL per month of High Speed Diesel & 11460 KL per month of Motor Spirit with maximum daily sales of 1800 KL & 1200 KL respectively in single shift operation. With the augmentation in tankage, the designed throughput at the terminal would be 2455 KL/day for Class “B” & 1500 KL/day for Class “A” The expected increase in demand per day is:

Product ~ peak

sales/ day

~ Expected Peak sales / day after 3

years

Class B 1500 KL 2455 KL

Class A 1200 KL 1500 KL

The proposed project activity is Expansion of Multipurpose Chemical Terminal from 86928 KL to 108950 KL



As per the Environment Impact Assessment (EIA) Notification, 2006 the project falls under 'Category 6b - Isolated Storage & Handling of Hazardous Chemicals’ (As per threshold planning quantity indicated in column 3 of Schedule 2 & 3 of MSIHC Rules 1989 amended 2000), which requires Environment Clearance (EC) from SEIAA . This report is the prefeasibility report of the expansion project submitted to obtain terms of Reference (ToR) for carrying out the environment impact assessment studies and prepare an Environmental Impact Assessment (EIA) Report.



2. SITE INFORMATION

Site Location & Connectivity

The MCT, Chennai is located at Vallur Village, Ponneri Taluka, Tiruvallur Dist, Tamil Nadu ~20 km aerial distance from Chennai city. The MCT is located in the Notified Special & Hazardous Industrial use zone classified by Chennai Metropolitan Development Authority (CMDA). The area of the terminal facility is 33 acres and includes the tank farm, truck loading bays, office space and the associated facilities. The nearest airport is at Chennai located at an aerial distance of ~40 Km. The major road connectivity is from Manali- Minjur State Highway (SH-56) which is at an aerial distance of ~1.5 km. The Chennai- Sulurpetta- Nellore rail line is on the North East of the terminal and the nearest railway station is Athipattu Pudhunagar which is at an aerial distance of ~ 2 km. The site location map is shown below, the toposheet showing the MCT is given in Annexure-I.

Location Map of MCT Chennai

Latitude Longitude

13°13'59.28"N 80°17'13.65"E

13°14'6.95"N 80°17'14.99"E

13°14'11.66"N 80°17'14.30"E

13°14'13.28"N 80°17'15.54"E

13°14'12.79"N 80°17'18.30"E

13°14'13.21"N 80°17'18.72"E

13°14'12.92"N 80°17'21.84"E

13°14'11.28"N 80°17'21.62"E

13°14'11.39"N 80°17'20.28"E

13°14'9.19"N 80°17'19.60"E

13°14'8.69"N 80°17'22.63"E

13°14'6.29"N 80°17'22.08"E

13°14'5.53"N 80°17'24.88"E

13°13'58.83"N 80°17'24.12"E

13°13'57.78"N 80°17'26.09"E

13°13'54.57"N 80°17'25.66"E



Land use and ownership

The proposed expansion will be carried out within the existing facility of the terminal. Hence, no alternate sites were considered for the project. The land use is industrial and no new land acquisition is required for the project. The land required for the expansion of the terminal facilities is already in possession of RIL. There are other terminal being operated around the terminal of the proposed project such as IOCL, HPCL etc. The survey numbers of the terminal are 1194, 1191, 1190, 1192, 1193, 1189/2, 1184, 1185, 1183, and 1177.

Land Area Details

The MCT is spread out in an area of 33 Acres. The proposed expansion will utilise existing

facilities and will not need additional area.

Area break-up

Description of Facility Area

(~Acres)

Existing Facilities

Storage Tanks, Roads, Open space, Loading Gantry 19.6 TT parking 1.54 Built-up area: Substation, DG Room, Admin Building, Security & Load Office, Workshop & Lab, Fire Water Pump House & Truck Driver Canteen 0.28

Proposed Project Storage Tanks 1.08 Green belt 10.5 Total Area 33

General Climate features

The project location has a humid subtropical climate, with cool, dry winters, a hot summer and a humid monsoon season. Summers start in late March and go on till mid-June, the average temperature being around 35 °C , with the peak of summer in May, when the highs regularly exceed 45 °C. The monsoon starts in late June and ends in late September.

http://en.wikipedia.org/wiki/Humid_subtropical_climate



3. PROJECT DESCRIPTION

The facility at MCT, Chennai is designed in accordance with statutory requirements and International standards. MCT has its own HSSE management system which incorporates all the relevant statutory requirements and standards. The terminal receives refined petroleum products from Jamnagar refinery by Ocean tanker. The finished product is received into the storage tanks by 24” Jetty Pipeline. The terminal receives the product in their pure form. The clean products are loaded into dedicated tanks, and stored at atmospheric pressure. The storage tanks are contained in a single dyke area, segregated by firewalls in accordance with the provisions of the OISD-117 & Petroleum Rules 2002. The below table lists the details of existing storage capacities and the proposed expansion in storage capacities

Details of Storage Capacity Existing as well as Proposed Flammability

Class

Product Existing Capacity

(KL)

Proposed Expansion

Operational Capacity

(KL)

Total

Operational

Capacity

(KL) Safe

Storage

Capacity

(CCoE

Approved)

Operating

Storage

Capacity

Augmentation of

Capacity in

existing Tanks

Storage in

New

Tanks

Class A

Motor

Spirit*/Naphtha

34648

(6 tanks)

30301 4347 -- 34648

Ethanol* 40

(1 tank)

40 -- 80

(2 tanks)

120

Class B

High Speed

Diesel*

64512

(6 tanks)

56587 7925 -- 64512

Aviation

Turbine Fuel/

Superior

Kerosene Oil

-- -- -- 9670

(2 tanks)

9670

Total 86928 108950

-- Power

(DG set)

2 x 325

KvA

1 x 500

KvA

1150

KvA

Note: *Products stored at present

Product Receipt

The finished petroleum products are received at the Ennore jetty from the RIL Jamnagar Refinery. The products are transported to the MCT through a ~9 km pipeline. No modifications are envisaged in the pipeline during this proposed project. The pipeline has all the required statutory approvals in place and the same pipeline shall be used during the proposed project as well. The pipeline is provided with pigging facility, the pig launch facility is provided at jetty whereas the receiving facility is provided at the terminal with depressuring system.



Dispatch facilities

Products are transferred to the Gantry by dedicated product pumps. There are 16 bays within the gantry, all the bays are designed for top loading through loading arms of 3 inch diameter. All the bays are also designed for bottom unloading through 3 inch unloading hoses. The products are delivered at minimum rate of 300 LPM & maximum rate of 1150 LPM per arm for the products. In the proposed expansion requires no additional dispatch facilities envisaged and the existing facility shall be used.

Loading Facilities

The loading of the Truck-Tankers (TT) operation is fully automated through the Terminal Automation System (TAS). The gantry area is classified as a Zone 1 hazard area and all electrical equipment used in the area are of intrinsically safe type. All TT are also inspected to ensure the electrical wirings and electrical equipment (e.g. lightings) is safe and properly secured. The top loading bays are also fitted with additional safety feature for working at height

Swing platform which provide access from the platform to the TT;

Safety harness to protect drivers from falling from TT to the ground;

Easily accessed staircases situated at each platform. The height of the platform is 3.4 meters and made of anti-slip gratings.

The terminal plot plan showing the facilities is provided in Annexure-II. The table below provides an overview of the terminal facilities.

Terminal Facility Overview

Description Item Description

General Distribution of product is via TT using gantry facility Gantry operations from 0900 to 2200 hours

Products handled Receipt: MS (Grade - MS BSIV), HSD (Grade -HSD BSIV) & Delivery: MS,HSD

Pipeline within Terminal

Ocean Tanker receipt line:, 24” for HSD & MS Delivery line from tanks: 14” for HSD, 10”&12” for MS

Loading arm type Aluminium alloy 3” loading arm with spring loaded Dead-man Valve for all products & Over spill Sensors

Firefighting facilities

Fire water tanks (designed for 4 hours of the 150% of maximum fire water demand based on different emergency scenarios) Pressurised fire water network designed to provide a minimum residual pressure of 10.5 kg/cm2 at the most hydraulically remote point when the maximum fire water as per demand is being discharged midway of the fire water network. The network consists of



single/double hydrants, water cum foam monitors & water monitors. Hydrant valves are designed for operating at a pressure of 10.5 kg/cm2. Pressure is maintained by 2 jockey pump and 6 diesel fired water pumps Jockey pumps & Firewater pumps automatically start at set pressures as per the design philosophy. Jockeys stop automatically at set pressure while the firewater pumps are stopped manually. Fixed foam pourers for all tanks, manually activated Water sprinklers for all product storage tanks Water cum foam monitors at gantry and Tank Farm

Utilities

The details of the existing utilities such as power, instrumentation, water etc are given below;

Power

Power supply (main and standby) at MCT is through Tamilnadu Electricity Board (TNEB) at 11 KV. This is stepped down to 415V and utilized in the terminal. 11 KV overhead transmission line from Napalayam Substation of TNEB has been installed to provide required electrical power supply for the operations and illumination at the terminal. Bi-pole structure is provided to support outdoor equipment. To measure electrical energy consumed, electronic meter has been installed in TNEB switchyard. 11 KV/433 Volt / 1600 KVA Transformer is provided to step down electrical power and its output is connected to Power and Motor Control Center (PMCC) from where power distributed to equipment through Motor control Centers (MCC’s). The PMCC and MCC’s are housed in electric substation along with relay panel and other control panels. 2 x 325 KVA, 415 Volt DG sets are installed to cater to the power requirement in case of TNEB power supply failure for uninterrupted operations at terminal. 2 x 20 KVA UPS modules have been installed to provide uninterrupted power supply to Terminal automation System and Computers for safe shut down of terminal equipment. During the proposed expansion additional DG set with capacity 1 x 500 KVA will be included.

Instrumentation & Automation Instrumentation and Automation will be provided through the following:

Terminal Automation System (TAS – Road loading pumps /gantries. Also included is Ocean tanker receipt system)

Tank Farm Management System (TIS- Product receipt and storage)

Programmable Logic Controller (PLC - Safety logic & ESD)



Water

The water required for the terminal such as operation, domestic, fire water etc. The existing water usage at the terminal is ~ 18 KLD supplied by Chennai metropolitan water supply and sewerage board, through pipeline. During the proposed project an additional water quantity of ~ 5 KLD is envisaged which will be supplied by Chennai metropolitan water supply and sewerage board which has already allotted ~ 20 KLD of water and also the water will be sourced locally, supplied through tankers on need basis. Fire water make-up is purchased locally and supplied through tankers on need basis. Firewater quantity is based on OISD 117. The below table provides the details on the water storage and requirement.

Water Requirement

Activity Existing (KLD) After Proposed

Expansion (KLD)

Source

Domestic 10 12 Metro Water /

Purchased from local

water suppliers through

tankers for fire water

make-up

Operation 3 4

Green belt 5 7

Fire fighting Used only during

emergency

12836 KL (Stored Capacity)

Used only during

emergency

19254 KL (Stored

Capacity)

Purchased from local

water suppliers through

tankers for fire water

make-up



4. ENVIRONMENT CONTROL MEASURES

The proposed expansion involves receipt, storage and distribution of petroleum products only. No manufacturing is involved and hence, no significant emissions are envisaged from the proposed expansion except from DG sets, which are used only during emergencies. Emissions from the DG sets shall be vented out through stack as per statutory norms and will be monitored. Fugitive emission from the proposed project is envisaged during construction and from storage tanks. Construction in the proposed project is a shortterm activity and fugitive emission from this activity is negligible and controlled. Adequate control measures such as seals, roof design are in place in the storage tanks to control fugitive emissions. Periodic monitoring is being carried out to detect & control such fugitive emissions and the same shall be strergthened during the proposed project. There will be no effluent generated from this project. However, an Oily Water Separator (OWS) is provided for separation of oily water mixture. The exisitng OWS system of capacity 300 KL for the separation of water oil mixture drained from storage tanks, gantry drains and other operating areas. In case of any spillage of oil during gantry operation or from tankage area shall be sent to OWS. The TPI in the OWS helps in further separation of oil from water up to 10ppm oil in water. The water from OWS/TPI will be reused for dust suppression during truck movement. Separate storm water drains are provided at the terminal. This drains carry storm water from tank dykes/other areas outside the terminal premises in a controlled manner. Plans are in place to utilise this water for green belt development.

The terminal is completely paved in operational areas. In case of leak/spill, the product to be retrieved with the help of adsorbents to reduce loss and prevent environmental damage. The product retrieved shall be subjected to laboratory test for reuse into storage tanks or disposed of as per HWM rules. While loading road tankers, the leak/spill is contained and recovered to minimize the loss and prevent soil contamination. A drum/trays are used to collect any leakage/spillage around pumps areas and the bailed out oil from the drum/trays are taken back to respective tanks. In case of strainer cleaning of pumps & filter, arrangement are made to ensure complete draining of oil in trays/drums. Sampling drums are used for collection during sampling and are periodically emptied out in unloading line and taken to respective tank. Spillages of grease/oil are minimized during overhauling/maintenance of equipment. Arrangements are made for collection of excess oil/grease used. Adequate quantity of adsorption material (cotton waste, rags etc.) is kept handy while carrying out the maintenance. All containers/boxes of grease/oil stored in containers in workshop are covered at all times and protected from fall during storage, to avoid spillage.

Sewage from the administrative building is routed to the septic tanks and the sludge generated from septic tanks will be dried and used a manure in the green belt. Other solid waste generated in terminal from operational activities are classified as hazardous & non-hazardous material & it is safely disposed of through authorized agency as per statutory norms. The below table provides the details of the Solid waste that generated during the existing project as well during the proposed expansion. These wastes are generated only during maintenance activities.



Details of Waste generated

Type of Waste Existing Quantity

(Tons/Year)

~Expected Quantity

(Tons/Year)

Used Oil 1.5 2.5

Fuel Filters 0.5 1

Oily Sludge 1.4 2.8

Contaminated drums 6 9

The terminal has a green belt of ~10.5 Acers which shall be strengthened during the proposed

expansion.

Safety at Terminal

The following safety measure are provided to ensure that the safety standards are in line with

the applicable regulations & current best industry practices.

Remote operated valves are provided in each pipe connecting to the tank inlet & outlet.

Tank level gauging instrumentation, alarm and safety interlock system are provided

using independent guided wave radar type & level transmitters type gauging

instruments

Fixed water spray system are provided for storage tanks as per OISD 117 guidelines.

Semi-fixed foam system with suitable heat detection and alarm system to ensure

timely application of foam to prevent escalation of rim seal & tank pool fires.

Emergency push buttons stations to stop all operations and isolating the product

storage tanks are provided at safe locations in the Terminal to prevent any fuel

released in case of a leak.

Fire protection facilities are provided fully meeting the requirements of Oil Industry Safety

Directorate Standard (OISD-117). These include the following:

Fire water storage tanks to meet 2 simultaneous largest fire contingencies in the

terminal: 6418 KL x 2 tanks

Main fire water pumps and jockey pump:- 3 jockey pumps & 6 fire water pumps

Fire water network with hydrants (33 Nos), monitors (21 Nos) and medium-velocity

sprinkler systems (all storage tanks);

Fixed foam system (all storage tanks), foam storage: 16000 litres

Mobile firefighting equipment : 83 Nos of 9 kg extinguishers, 10 Nos. of 25 kg

extinguishers, 5 Nos. of 75 kg extinguishers, 14 Nos of CO2 type extinguishers

Portable fire extinguishers: 5 Nos of 200 litres foam trolley;

Fire detection & alarm system including manual call points (37 points); and

Hydrocarbon carbon detectors are provided in the MS tanks dyke and pump bay with

Audio Visual Alarm at field and Control room in case of hydrocarbon leak.

An Emergency Management System has been provided in operation management and in emergency, on operating ESD switch, all operation in the terminal will stop the pumps and close the motor operated valves at the tank outlets.

The MSDS of the products being stored is provided in Annexure-III



5. PROJECT IMPLEMENTATION

Execution Strategy

Execution of the project includes engineering, procurement, construction, installation and start-up the facilities and it will follow the disciplined and orderly project management approach. Established Project management processes and procedures of RIL shall be adopted to complete the project safely within approved Budget, Schedule and Quality. Basic engineering shall be executed by the Terminal team, Detailed Engineering for this project shall be executed by Detail Engineering Consultant i.e. Mumbai Engineering Group (MEG) Detail engineering activities includes development of overall engineering deliverables for all disciplines. Procurement shall be done with the help of Procurement and Contracts department. Engineering deliverables for procurement such as SOQ for construction contracts, MRs for all tagged equipment and PR for all bulk items shall be developed by MEG. Commissioning and Start-up of the plant shall be joint responsibility of MEG and MCT Site operations. After successful start-up and handover of facilities, Maintenance and Operation of the facility will be performed by the MCT Operations with routine inspections and surveillance throughout the design basis life cycle.

Project Schedule

The proposed project is scheduled to be commissioned in stages starting within one year after EC is granted. Following are the major activities which will be scheduled based on logical interdependencies in order to complete this project as per schedule:- Engineering:

Basic Engineering design package (Process description, PFD, P&ID, PDS etc.)

Detail Engineering of the project (P&ID, HAZOP, 3D model, MRs, SOQ, MTO, Layouts, SLD, Loop diagrams etc)

Procurement:

Long lead items (Booster Pumps, etc)

Other Tag items i.e. Electrical Switchgears, Instruments, Control Valves

Bulk materials (piping, cables, trays, Instrument panels , Electrical Panel, valves etc)

Project Management

An experienced and well-equipped project management team shall be deployed to execute, monitor and control the project throughout the engineering, procurement phases till start-up. Major activities in project management includes the following:-

Interface with various internal and external stakeholders supporting the project

Ensuring compliance with all regulatory requirements

Coordinating the development of “Basic Engineering design package”

Leading the detailed engineering phase and directing detail engineering consultant (MEC) for development of engineering deliverables to enable procurement and construction activities



Timely communication (review meetings, written communication, reports etc) with all stakeholders

Enabling procurement activities by providing necessary inputs i.e. MR for long lead items, SOQs for contracts, bids/ tender evaluation, contract award etc.

Materials Management & Quality Assurance

Co-ordination for overall activities at site

Project Control activities such as planning, scheduling, monitoring/ controlling, cost control, variance analysis etc

Reporting of project progress

Co-ordination for commissioning and start-up activities to ensure successful “performance guarantee test run” of the project

Handover of plant to Asset owner and Close-out of the project

Manpower

The existing manpower at the terminal is ~ 65 personal. The proposed project will lead to

employment generation of ~ 50 people during construction phase. Local manpower will be

preferred. During the operation phase of the proposed expansion additional ~ 12 people will

be employed on a continuous basis.

Project Schedule & Cost

The proposed project is scheduled to be commissioned in stages starting within one year after

EC is granted. The estimated cost of the project ~ 20 Cores.



6. REGIONAL BRIEF

The followings sections provide a brief on the regional setting.

Type of industries, habitations, facilities, transportation etc.

The study area is fast industrialising taking advantage of the nearby Ennore Port (Kamarajar Port Limited) which is located about ~7 kms to the East of the RIL MCT Facility. The port is being developed as an Energy Port and at present is the 12th largest major port in India. Taking advantage of the port, the study area is developing as a logistic and storage hub with several other facilities storing petroleum based products. Existing industrial facilities falling in the vicinity of MCT are NTECL TPP, Ashok Leyland, North Chennai Thermal Power Station, HPCL Ennore Terminal, IOC Petronas LPG Terminal, EID Parry Fertilizer Factory, Zuari Cements, India Cements, etc. Several other heavy/manufacturing industries are also located to the immediate south of the 10 kms study area and they form a part of the Manali industrial region. There are habitations within the 10 km radius area such as Ennore town, Minjur, Manali new town, Ponneri, Cholavaram, Vichoor, and other small villages.

Demographic Structure

As per the 2011 census, the 10 km study area around the facility comprises of a population of 47,40,388 individuals. The percentage of males and females are 50.27% and 49.72% respectively with the sex ratio being 989. The prevailing literacy level is 79%. About 1.83% population belong to Scheduled Tribes (ST) and 47.83% Scheduled Castes (SC) indicating that about 49.67% of the population in the study area belongs to socially weaker sections.

Ecological Setting

There are no declared National Parks or Sanctuaries located within 10 km radius of the MCT.

There are water bodies located within 10 km such as Kosatalayar river, Buckingum canal,

Puzhal lake, Cholavaram lake, retteri lake etc.

Assessment of Infrastructure Demand (Physical and Social)

The infrastructure resource base of the area with reference to education, medical facilities, water supply, post and telegraph, transportation and communication facilities and power supply etc. are briefly described below: Education: The villages and sub-urban towns located within the 10 km study area have access to 49 govt. primary schools, 22 middle schools, 7 secondary schools and 2 senior secondary schools. Other than that, there are several private educational facilities imparting education from primary to higher education lying within the Chennai Municipal Corporation area. Communities within the study area are mostly dependent on Chennai for fulfilling the needs of higher education.



Drinking Water: As per Census 2011 data, tap water supplies from treated sources are available in the entire study area and people depend on this source both for drinking and daily household uses. Other than that several tube wells are also present within the study area. However, being close to the coastal area, the water in saline.

Communication and Transportation:

State Highway 56 which is aligned from north to south within the study area is the main arterial road / highway servicing the area. The highway also acts as the key road linkage to the Ennore Port through the Athipattu Main Road. All weather roads are present in all neighbouring villages and regular bus / auto services are available in almost all the villages. The Southern Railway main line which runs through the Coromandel Coast also traverses though the study area and connects to Chennai city. Two nearby railway stations are Nadiyampakkam and Attipattu which have EMU local train services, in addition to long distance express train plying through them. A Post office/sub-post offices are present 7 villages within the study area. Post offices are also present in nearest urban areas. Telephone and cell phone connectivity is available in the entire area.

Power Supply: Power supply is available in all of the villages and sub-urban areas within the study area.

Medical/Primary Health Care: 8 Primary health sub-centres are present and 7 primary health centres is present in study area villages. Several hospitals are present in neighbouring Chennai city which are regularly accessed by people of the area.



Annexure-I

Toposheet showing MCT Chennai



Annexure-II

Plot Plan

Proposed Tanks



Annexure-III

Material Safety Data Sheets

(Material)Safety Data Sheet Issue Date: Jan. 01, 2016 AVIATION TURBINE FUEL/JET A-1 Supercedes: Aug. 01, 2013

Page 1 of 10

Section-1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE

AND OF THE COMPANY/UNDERTAKING

1.1 Identification of the substance/mixture:

Commercial name: AVIATION TURBINE FUEL/JET A-1

Chemical name: AVIATION TURBINE FUEL/JET A-1 Synonyms: F-35, Avtur, Aviation turbine fuel.

1.2 Use of the substance /mixture:

Industrial/professional use only. Fuel for aviation turbine engine fitted to aircraft.

1.3 MANUFACTURER & SUPPLIER: Reliance Industries Limited

Emergency Coordination Centre contact details:

Jamnagar Mfg. Division

Village Meghpar / Padana, Taluka Lalpur, Dist. Jamnagar, Gujarat

SSM Office

+ 91 288 6612400

Mobile 9998007989

+ 91 288 6611190/1/6

SSM: Site Shift Manager

Section 2 – HAZARD IDENTIFICATION

2.1 Classification of the substance/mixture: Hazard class and category

code.

GHS Category: Health Environmental Physical Aspiration toxicity Category: 1

Aquatic Toxicity – Category- NA

Flammable – Category 3 Flammable

NA: Not available Data reference: Official Journal of the European Union regarding EU GHS GHS Category table for reference: Study/hazard statement

Category 1 Category 2 Category 3 Category 4 Category 5

Acute Oral LD50

< 5 mg/kg Fatal if swallowed

> 5 < 50 mg/kg Fatal if swallowed

> 50 < 300 mg/kg Toxic if swallowed

> 300 < 2000 mg/kg Harmful if swallowed

> 2000 < 5000mg/kg May be harmful if swallowed

Acute Dermal LD50

< 50 mg/kg Fatal in contact with skin

> 50 < 200 mg/kg Fatal in contact with skin

> 200 < 1000 mg/kg Toxic in contact with skin

> 1000 < 2000 mg/kg Harmful in contact with skin

> 2000 < 5000 mg/kg May be harmful in contact with skin

Acute Inhalation Dust LC50 Gases LC50 Vapours LC50

< 0.05 mg/L < 100 ppm/V <0.5 mg/L Fatal if inhaled

> 0.05 < 0.5 mg/L > 100 < 500 ppm/V >0.5 < 2.0 mg/L Fatal if inhaled

> 0.5 < 1.0 mg/L > 500 < 2500 ppm/V > 2.0 < 10 mg/L Toxic if inhaled

> 1.0 < 5 mg/L >2500 < 20000 ppm/V > 10 < 20 mg/L Harmful if inhaled

See footnote below this table

Flammable liquids

Flash point < 23 degrees C and initial boiling point < 35 degrees C. Extremely flammable liquid and vapour

Flash point < 23 degrees C and initial boiling point > 35 degrees C. Highly flammable liquid and vapour

Flash point > 23 degrees C< 60 degrees C. Flammable liquid and vapour

Flash point > 60 degrees C < 93 degrees C. Combustible liquid

Not Applicable

Note: Gases concentration are expressed in parts per million per volume (ppmV). NOTE 1: Category 5 is for mixtures which are of relatively low acute toxicity but which under certain circumstances may pose a hazard to vulnerable populations. These mixtures are anticipated to have an oral or dermal LD50 value in the range of 2000-5000 mg/kg bodyweight or equivalent dose for other routes of exposure. In light of animal welfare considerations, testing in animals in Category 5 ranges is discouraged and should only be considered when there is a strong likelihood that results of such testing would have a direct relevance for protecting human health.


Page 2 of 10

NOTE 2: These values are designed to be used in the calculation of the ATE for classification of a mixture based on its ingredients and do not represent test results. The values are conservatively set at the lower end of the range of Categories 1 and 2, and at a point approximately 1/10th from the lower end of the range for Categories 3 – 5. GHS Category table for reference: Continued

Study/hazard statement

Category 1 Category 2 Category 3

Eye Irritation

Effects on the cornea, iris or conjunctiva that are not expected to reverse or that have not fully reversed within 21 days. Causes severe eye damage.

2A: Effects on the cornea, iris or conjunctiva that fully reverse within 21 days. Causes severe eye irritation. 2B : Effects on the cornea, iris or conjunctiva that fully reverse within 7 days. Causes eye irritation.

Not applicable

Skin Irritation

Destruction of skin tissue, with sub categorization based on exposure of up to 3 minutes (A), 1 hour (B), or 4 hours (C). Causes severe skin burns and eye damage.

Mean value of >2.3 > 4.0 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed); inflammation that persists to end of the (normally 14-day) observation period. Causes skin irritation.

Mean value of >1.5 < 2.3 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed). Causes mild skin irritation.

Environment: Acute Toxicity Category

96 hr LC50 (fish) <1 mg/L 48 hr EC50 (crustacea) < 1 mg/L, 72/96 hr ErC50 (aquatic plants) < 1 mg/L Very toxic to aquatic life

96 hr LC50 (fish) >1< 10 mg/L 48 hr EC50 (crustacea) >1< 10 mg/L 72/96 hr ErC50 (aquatic plants) >1< 10 mg/L Toxic to aquatic life

96 hr LC50 (fish) >10< 100 mg/L 48 hr EC50 (crustacea) >10< 100 mg/L 72/96 hr ErC50 (aquatic plants) >10< 100 mg/L Harmful to aquatic life

Flammable Aerosol

Extremely flammable aerosol Flammable aerosol Not Applicable

Flammable solids

Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time < 5 minutes Flammable solid

Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire for at least 4 minutes and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time > 5 < 10 minutes Flammable solid

Not Applicable

Flammable gases

Gases, which at 20 degrees C and a standard pressure of 101.3 kPA: (a) are ignitable when in a mixture of 13% or less by volume in air; or (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Extremely flammable gas

Gases, other than those of category 1, which, at 20 degrees C and a standard pressure of 101.3 kPA, have a flammable range while mixed in air. Flammable gas

Not Applicable

GHS Label: GHS08: Carcinogen

Signal word: Danger

Details of Statements:

Hazard Statements

H304: May be fatal if swallowed and enters airways. H226: Flammable liquid and vapour.

Precautionary Statement Prevention

P102: Keep out of reach of children. P103: Read label before use. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P280: Wear protective gloves/protective clothing/eye protection/face protection*.

Precautionary Statement Response

P101: If medical advice is needed, have product container or label at hand. P301 IF SWALLOWED: P310: IF SWELLOWED: Immediately call a POISON CENTER or doctor/physician.


Page 3 of 10

P331: Do not induce vomiting. P303 +P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378: In case of fire: Use foam or water fog for extinction

Precautionary Statement

Storage

P405: Store locked up. P403 + P235: Store in a well-ventilated place. Keep cool.

Precautionary Statement Disposal

Follow local regulation

Data reference: Official Journal of the European Union regarding EU GHS Hazard ratings:

NFPA HAZARD CODES RATINGS SYSTEM

HEALTH: 2 0 = No Hazard

FLAMMABILITY: 2 1 = Slight Hazard

INSTABILITY: 0 2 = Moderate Hazard

3 = Serious Hazard

4 = Severe Hazard

Data Reference: http://ecb.jrc.ec.europa.eu/esis/index.

2.2 Information pertaining to particular dangers for human: Ingestion The swallowing of small amounts is unlikely to have adverse effects; larger amounts may cause irritation with diarrhoea and vomiting. Skin Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause dermatitis which could eventually lead to irreversible skin disorders. Injection of fuel under pressure through the skin may have serious effects which at first may not seem serious but, within hours, may become very painful. Eyes May cause irritation with short-term redness and stinging. Inhalation Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness leading to loss of consciousness.

2.3 Information pertaining to particular dangers for the environment: NA

2.4 Other adverse effects: There are small concentrations of cetane no. improvers, flow improvers, anti-foam and detergent additives and marker/dye that are not considered to represent a health risk. Injection of fuel under the skin may have serious medical effects. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.

DATA REFERENCE: http://toxnet.nlm.nih.gov/cgibin/sis/search.

Health hazards:

Source NTP listed? IARC cancer review group? OSHA Regulated?

Carcinogenicity No No No

DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health

Administration (OSHA) carcinogen, National Toxicological program (NTP), International

Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-bin/sis/search.

Section 3 – COMPOSITION & INFORMATION ON INGREDIENTS

Skin Contact Skin Absorption Eye Contact Inhalation Ingestion

Yes Yes Yes Yes Yes

http://toxnet.nlm.nih.gov/cgi%1fbin/sis/search

http://toxnet.nlm.nih.gov/cgi-bin/sis/search


Page 4 of 10

Ingredients CAS No. EINECS No. Percentage

Kerosine (Petroleum) 8008-20-6 232-366-4 0-100%

Kerosine (Petroleum),

Hydrodesulphurised

64742-81-0 265-184-9 0-100%

Kerosine (Petroleum)

Sweetened

91770-15-9 294-799-5 0-100%

NA: Data not available

Data reference: http://ecb.jrc.ec.europa.eu/esis/, http://toxnet.nlm.nih.gov/cgi-

bin/sis/search/

Section 4 – FIRST AID MEASURES

4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilised position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation If inhalation of vapour causes irritation or drowsiness remove to fresh air. Get medical advice if the symptoms continue.

4.3 Skin contact Wash skin as soon as possible with water. Change contaminated clothing and launder before reuse. Get medical advice if irritation persists. Any injection of fuel under the skin should be considered an EMERGENCY - get Medical Advice URGENTLY. 4.4 Eye contact Wash out thoroughly with large amounts of water. If redness and/or irritation continues get medical advice. 4.5 Swallowing Wash mouth out with water and give water to drink. If a large amount has been swallowed get medical advice. DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.

Section 5 – FIRE FIGHTING MEASURES

5.1 Suitable extinguishing media Extinguish with Dry Powder, Foam or Water Fog. For small fires use CO2 5.2 Extinguishing media to be avoided Do not use water jets

5.3 Caution about specific danger in case of fire and fire-fighting

procedures Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters

http://ecb.jrc.ec.europa.eu/esis/

http://toxnet.nlm.nih.gov/cgi-bin/sis/search/

http://toxnet.nlm.nih.gov/cgi-bin/sis/search/


Page 5 of 10

Wear full protective fire-resistant clothing and self-contained breathing apparatus.

Section 6 –ACCIDENTAL RELEASE MEASURES

6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or containers, inform water consumers immediately. 6.3 Recommended methods for cleaning and disposal Contain spillage - do not wash spillage down drain. Absorb using absorbent clay, or other suitable absorbent.

Section 7 –HANDLING AND STORAGE

7.1 Information for safe handling Its derivatives are designed to be used in closed systems. Avoid skin contact when refueling vehicles or working on fuel system components. Where exposure is likely PROTECTIVE CLOTHING should be worn including impervious GLOVES and EYE PROTECTION. Ensure good ventilation. 7.2 Information for storage Drums should be stored on their sides on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should be taken to avoid over-stacking. 7.3 Information for specific use: NA.

Section 8 –EXPOSURE CONTROL & PERSONAL PROTECTION

8.1 Occupational Exposure Limits: Material Source Type ppm mg/m3 Notation

Kerosine (Petroleum)

ACGIH TWA NA 200 Skin;A3 ACGIH STEL NA NA ACGIH SKIN_DES TWA NA NA NIOSH IDLH OSHA TWA OSHA STEL


8.2 Occupational exposure controls

Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In cases, where the workplace exposure control limits cannot be observed with the help of technical equipment or where it is not possible to ensure that the respiratory system exposure does not


Page 6 of 10

represent a health hazard for the personnel, adequate respiratory protection have to be kept at disposition. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):

HANDS EYES BODY RESPIRATORY

Respiratory protection: Unlikely to be required in normal use but ensure good ventilation. Eye protection: Eye protection is recommended at all times Hand protection: Wear gloves of impervious material.

Body protection: Hand and skin protection recommended at all times. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

8.3 Environmental exposure controls: Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Section 9 –PHYSICAL AND CHEMICAL PROPERTIES

Appearance Almost colourless or Pale yellow, liquid Odour Characteristic not disagreeable odour Solubility in water Insoluble Relative Density (H2O=1) 0 .8 Boiling Point °C 175 – 325°C Melting Point °C -48°C Relative Vapour Density (Air=1) >5 Flash point °C 35°C – 65°C (depending upon composition). Auto ignition °C 210°C Vapour pressure (mmHg) @ 20 °C 0.480 Molecular weight NA Explosive limits in air % by volume LEL 0.5% UEL 5.0% pH NA Viscosity mm2/Sec@40 °C NA Pour point NA Evaporation rate (water=1) NA Octanol/water partition coefficient log Kow

NA


Page 7 of 10

% volatile NA NA: NOT AVAILABLE DATA REFERENCE: http://toxnet.nlm.nih.gov/cgi-bin/sis/search:

Section 10 –CHEMICAL STABILITY AND REACTIVITY INFORMATION

10.1 Conditions to avoid: Heat.

10.2 Material to avoid: May react with strong oxidising materials. 10.3 Hazardous decomposition products With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.

Section 11 –TOXICOLOGICAL INFORMATION

11.1 Acute effects Acute toxicity data:

Parameter Route Species Values Exposure period LD50 Oral Rat 28000 mg/kg Not applicable LC50 Inhalation Rat >5.28 mg/l 4h LD50 Dermal Rabbit >2000 mg/kg 24h Data Reference: http://toxnet.nlm.nih.gov/cgibin/sis/search.; http://java.epa.gov/chemview# 11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin irritation. 11.3 Sensitisation May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction) CAS No. 8008-20-6: showed carcinogenicity (tumor promotion) in mice. Substance does not have mutagenic effects. Substance dose not have adverse effect on reproduction. 11.5 Toxicokinetics, metabolism, distribution: NA.

Section 12 –ECOLOGICAL INFORMATION

12.1 Ecotoxicity data: NA


12.2 Mobility

Moderate to Low mobility in soil

12.3 Persistence and degradability

Kerosene (8008-20-6)

Persistence: P1 (Low) - P2 (Moderate)

Degradability: This product is inherently biodegradable. 12.4 Bio accumulative potential



Page 8 of 10

B1 (Low) to B3 (High) 12.5 Results of PBT assessment Persistence and Degradation: The rate of photo oxidation is expected to be slow to rapid for most components of the category. 12.6 Other adverse effects May bio accumulate; films formed on water may affect oxygen transfer and damage organisms. Likely to biodegrade slowly. Environmental Fate: If released to soil, it is expected to biodegrade under both aerobic and anaerobic conditions.

Section 13– DISPOSAL CONSIDERATION

Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.

13.1 Recommended disposal methods for the substance / mixture

Product reuse or disposal in accordance with valid waste legislative regulations.

13.2 Recommended disposal methods for contaminated packaging

Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment

Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.

Section 14– TRANSPORT INFORMATION

Proper Shipping Name: Aviation Turbine Fuel/Jet A-1

Hazard Class: 3

UN Number: 1863

Packaging Group: III

Emergency Action Code: 3YE

Section 15– REGULATORY INFORMATION

(M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives


Page 9 of 10

Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council

*RISK PHRASES: R10: Flammable, R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, R65 - Harmful: May cause lung damage if swallowed, R67: Vapours may cause drowsiness and dizziness.

*SAFETY PHRASES: S2: Keep out of the reach of children, S24: Avoid contact with skin, S43: In case of fire, use: Extinguish with carbon dioxide, dry chemical, foam or water spray. Do not use water jet or water spray, S61: Avoid release to the environment. Refer to special instructions/Safety Data Sheets, S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label *These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations - Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Materials) Safety Data Sheets to identify potential hazards and offer safe handling advice.

Section 16 – OTHER INFORMATION

Training instructions Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Tremcard details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630, . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html, Data reference: Official Journal of the European Union regarding EU GHS (M)SDS Revision Status:

Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 2 NFPA Hazard statement Sep. 01, 2011 Jan.01,2016 Section 2,11,12,15 Aug. 01, 2013

This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited.


http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630

http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein

http://www.cdc.gov/niosh/npg/npgd0049.html


Page 10 of 10

Contact Details: For any enquiry/comment regarding this (Material) Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected] Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

End of (M)SDS

(Material) Safety Data Sheet Issue Date: Mar. 01, 2016 GAS OIL

Supercedes: Aug. 01, 2013

Page 1 of 10

Section-1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1. Identification of the substance/preparation: Commercial name: High Speed Diesel Chemical name: 1. Fuels, diesel 2. Distillates (petroleum), hydrodesulfurized middle

Synonyms: 1. Fuels, diesel

2. Distillates (petroleum) Hydrodesulfurized middle

1.2 Use of the substance /preparation: Automotive gas oil, Industrial Fuel, Fuel for road diesel-powered engine. 1.3 MANUFACTURER & SUPPLIER: Reliance Industries Limited

Emergency Coordination Centre contact details: Jamnagar Mfg. Division


SSM Office

+ 91 288 6612400

Mobile 9998007989

+ 91 288 6611190/1/6



2.1 Classification of the substance/preparation: Hazard class and category code.

GHS Category: Health Environmental Physical Carcinogenic category: 1B


Flammable – Category NA

NA: Not available GHS Category table for reference: Study/hazard statement


Acute Oral LD50






Acute Dermal LD50





> 2000 < 5000mg/kg May be harmful in contact with skin






Dose equivalent to oral or dermal LC50 of 2000-5000 mg/kg Maybe harmful if inhaled

Flammable liquids





Not Applicable



Page 2 of 10

GHS Category table for reference: Continued Study/hazard statement


Eye Irritation



Not applicable

Skin Irritation








Flammable Aerosol


Flammable solids



Not Applicable

Flammable gases



Not Applicable

GHS Label: GHS08: Carcinogen, GHS 02: Flammables, GHS 09: Environmental hazard

Signal word: Danger.

Details of statements: Hazard Statements H350: May cause cancer

H304: May be fatal if swallowed and enters airways. H225: Highly flammable liquid and vapour. H340: May cause genetic defects H411: Toxic to aquatic life with long lasting effects.


P103 Read label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking P260: Do not breathe /fume/gas/mist/vapours/spray. P 243: Take precautionary measures against static discharge. P281 Use personal protective equipment as required


P308 IF exposed or concerned P313 Get medical advice/attention. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting.

Precautionary P405 Store locked up



Page 3 of 10

Statement Storage Precautionary

Statement Disposal Follow local regulation

2.2 Information pertaining to particular dangers for human: Ingestion Given the nature of gas oil and the fact that it is normally handled hot, its ingestion must be regarded as highly improbable. However, in the unlikely event of it happening, spontaneous vomiting would be expected to occur. There could also be irritation of the gastro-intestinal tract. Skin Because of the high handling temperatures, particularly with the heavy grades, a major hazard is the possibility of skin burns. However, this possibility, together with the unpleasant smell and colour of the fuel, provides a deterrent against direct skin contact. Nevertheless, where exposure arises and precautions and personal hygiene are poor, there is the possibility firstly of skin and eye irritation of a relatively mild nature, and secondly of dermatitis on more prolonged contact either directly on the skin or via fuel-soaked clothing. Prolonged or repeated skin contact, particularly under conditions of poor personal hygiene, may lead to effects ranging from dry skin with irritation to oil acne and oil folliculitis. Some individuals may be particularly susceptible to skin cracking and dermatitis. With exposure under such conditions, in rare cases serious disorders such as skin cancer could eventually occur. Eyes Eye contact from splashes or high mist levels is likely to cause irritation. Inhalation Mist and vapours will be evolved from gas oils at the elevated temperatures encountered in storage and use and these are likely to cause eye and respiratory irritation. However, such exposure is minimal under normal use conditions and significant exposure is most likely during maintenance operations, adequate personal protective equipment must be worn.

2.3 Information pertaining to particular dangers for the environment: NA.

2.4 Other adverse effects: Hydrogen sulphide may be evolved from gas oils under certain conditions such as elevated temperatures. It is highly toxic, causing effects which include eye irritation, nervousness, nausea, headache, insomnia and, in severe cases, unconsciousness and death. Hydrogen sulphide can also paralyse the olfactory system, making it inadvisable to rely on detecting its odour as a warning of its presence. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.

Data reference: http://ecb.jrc.ec.europa.eu/esis/ Health hazards:

Carcinogenicity NTP listed? IARC cancer review group? OSHA Regulated?

Data yes yes yes

DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and

Health Administration (OSHA) carcinogen, National Toxicological program (NTP),

International Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-

bin/sis/search.


Yes Yes Yes Yes Yes






Page 4 of 10


Ingredients / Hazardous CAS No. EINECS No. Percentage

Distillates (petroleum), hydrodesulfurized middle; /Yes

64742-80-9 265-183-3 0-100 %

Fuels, diesel/yes 68334-30-5 269-822-7 0-100 %

Gas oils (petroleum), hydrodesulfurized; Gasoil /Yes

64742-79-6 265-182-8 0-100 %

Fuels, diesel, No 2; Gasoil /Yes 68476-34-6 270-676-1 0-100 %

Data reference: http://ecb.jrc.ec.europa.eu/esis/


4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilised position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation Remove to fresh air. If breathing but unconscious, place in the recovery position. If breathing has stopped, apply artificial respiration. If heartbeat absent give external cardiac compression. Monitor breathing and pulse. OBTAIN MEDICAL ATTENTION IMMEDIATELY.

4.3 Skin contact If high pressure injection injuries occur, obtain medical attention immediately. In the case of burns, wash skin thoroughly with water. Contaminated clothing must be removed as soon as possible. It must be laundered before reuse. If persistent irritation occurs, obtain medical attention. 4.4 Eye contact Flush eye with water. If persistent irritation occurs or if there is any suspicion of damage from hot product, obtain medical attention immediately. 4.5 Swallowing

Do not induce vomiting. Protect the airway if vomiting begins. Give nothing by mouth. If breathing but unconscious, place in the recovery position. If breathing has stopped, apply artificial respiration. DO NOT DELAY, OBTAIN MEDICAL ATTENTION IMMEDIATELY.


5.1 Suitable extinguishing media




Page 5 of 10

Extinguish with Dry Powder, Foam or Water Fog. For small fires use CO2 5.2 Extinguishing media to be avoided Do not use water jets


procedures Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters Wear full protective fire-resistant clothing and self-contained breathing apparatus.


6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or water containers, inform water consumers immediately, stop service and exploitation of water. 6.3 Recommended methods for cleaning and disposal When it is required to dispose of gas oil, for example, following a spillage or tank cleaning operations, this should be done through a recognised waste contractor. In marine applications, all waste gas oil should be collected and disposed of on land in accordance with local regulations.


7.1 Information for safe handling In the event of a spillage, absorb or contain liquid with sand, earth or other spill control material. Prevent from entering drains, ditches or waterways. If this cannot be done, inform local authorities. 7.2 Information for storage Storage tanks in land based applications should be surrounded by oil tight bund walls to prevent escape of gas oil into the environment in the event of a major spillage or tank failure. Precautions should be taken to avoid skin burns from unprotected pipelines and equipment components. 7.3 Information for specific use: NA.



High Speed Diesel

*Shell UK Limited, Landon

TWA NA 500

* Shell UK Limited, Landon

STEL NA 1000



Page 6 of 10

NA: Data not available, Shell UK Limited, Landon



Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In cases, where the workplace exposure control limits cannot be observed with the help of technical equipment or where it is not possible to ensure that the respiratory system exposure does not represent a health hazard for the personnel, adequate respiratory protection have to be kept at disposition. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE): HANDS EYES BODY RESPIRATORY


Body protection: Hand and skin protection recommended at all times. Where exposure is likely protective clothing must be worn, including nitrile gloves. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

8.3 Environmental exposure controls Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.




Page 7 of 10

Section 9 –PHYSICAL AND CHEMICAL PROPERTIES Appearance Colourless, Liquid Odour Characteristic Solubility in water Negligible Relative Density (H2O=1) @ 15°C 0.82 - 0.87 Boiling Point °C 160–400°C Melting Point °C -12°C in winter & -3 °C in summer Relative Vapour Density (Air=1) NA Flash point °C > 66°C, Closed cup Auto ignition °C 220°C Vapour pressure (hPa) @ 40 °C 4 Molecular weight NA Explosive limits in air % by volume LEL 1.4 % UEL 7.6% PH NA Viscosity cSt @40 °C 1.5 – 5.7 Pour point NA Evaporation rate (ether=1) NA Octanol/water partition coefficient 3.9– 6 % volatile NA NA: NOT AVAILABLE



10.1 Conditions to avoid: Heat

10.2 Material to avoid: May react with strong oxidising materials.

10.3 Hazardous decomposition products With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.


11.1 Acute effects When gas oils contain cracked components they are classified as carcinogens. With the use of good occupational and hygiene practices any risk will be minimal. Acute toxicity data:

Parameter Route Species Values Exposure period LD50 Oral Rat 7.5 g/kg Not applicable

Data Reference: Health Compendium of Chemical Hazards for Diesel

11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin cancer. 11.3 Sensitisation: May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction): Substance is carcinogenic 11.5 Toxicokinetics, metabolism, distribution: NA.




Page 8 of 10


12.1 Ecotoxicity data:

Parameter Route Species Values Exposure period

Condition of bioassay

LC50 Inhalation

Jordenella floridae(fresh water fish)

54 mg/l 96 hours Not specified

Data Reference: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein

12.2 Mobility: Expected to have high mobility in soil.

12.3 Persistence and degradability: Substance is biodegradable.

12.4 Bio accumulative potential: Studies of the accidental and intentional release of fuel oils to the aquatic environment indicate that aquatic organisms are able to bio accumulate some hydrocarbon fractions, particularly PAHs (Farrington et al. 1982b); however, depuration does occur if the source of the contamination is removed (Cox et al. 1975; Williams et al. 1989). 12.5 Results of PBT assessment Persistence and Degradation: Photo-degrade in air. 12.6 Other adverse effects Expected to harm aquatic organisms, may cause long-term effects in the aquatic environment. May bioaccumulate; films formed on water may affect oxygen transfer and damage organisms. Likely to biodegrade slowly. Environmental Fate: Expected to have high mobility in soil.

Section 13– DISPOSAL CONSIDERATION Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.

13.1 Recommended disposal methods for the substance / preparation Product reuse or disposal in accordance with valid waste legislative regulations. 13.2 Recommended disposal methods for contaminated packaging Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.

Section 14– TRANSPORT INFORMATION International Transport Regulation:

Gas oil, Flammable liquid UN Number: 1202 Packing Group: III Packing Instructions: P001, IBC03, LP01 Portable Tanks: T2/TP1



Page 9 of 10

IMDG Hazard Class: 3 IATA Hazard Class: 3 Emergency Action code: 3Y

14.2 Special transport precautionary measures ADR/RID Hazard Class: 3

Section 15– REGULATORY INFORMATION (M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council *RISK PHRASES: R10: Flammable, R45: May cause cancer, R46: May cause heritable genetic damage, R65: Harmful: may cause lung damage if swallowed, R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment *SAFETY PHRASES: S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible), S53: Avoid exposure - obtain special instructions before use, S61: Avoid release to the environment. refer to special instructions/ safety data sheets, S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. *These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations – Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Materials) Safety Data Sheets to identify potential hazards and offer safe handling advice.


Training instructions



Page 10 of 10

Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Tremcard details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630, . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html, Official Journal of the European Union regarding EU GHS (M)SDS Revision Status:

Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 1.3 Sep. 01, 2011 Mar.01,2016 Section 11,12,14 Aug. 01, 2013

This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this (Material )Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected] Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

End of (M)SDS





mailto:[email protected]

(Material) Safety Data Sheet Issue Date: Feb. 01, 2016 GASOLINE Supercedes: Aug. 01, 2013

Page 1 of 11




Commercial name: Gasoline Chemical name: 1. Motor spirit 2. Petrol

Synonyms:

1. Motor spirit 2. Petrol

1.2 Use of the substance /mixture: Automotive gasoline (unleaded), Fuel, Fuel for road petrol-powered engine. As fuel in internal combustion engines of the spark-ignited & reciprocating.

1.3 MANUFACTURER & SUPPLIER: Reliance Industries Limited Emergency Coordination Centre contact details:

Jamnagar Mfg. Division Village Meghpar / Padana, Taluka Lalpur, Dist. Jamnagar, Gujarat

SSM Office

+ 91 288 6612400 Mobile 9998007989 + 91 288 6611190/1/6




code.

GHS Category:

Health Environmental Physical Carcinogenicity – Category 1B Aquatic Toxicity –

Category- 1 Flammable – Category 1

NA: Not available GHS Category table for reference:



Acute Oral LD50






Acute Dermal LD50












Flammable liquids





Not Applicable

Note: Gases concentration are expressed in parts per million per volume (ppmV). NOTE 1: Category 5 is for mixtures which are of relatively low acute toxicity but which under certain circumstances may pose a hazard to vulnerable populations. These mixtures are anticipated to have an oral or dermal LD50 value in the range of 2000-5000 mg/kg bodyweight or equivalent dose for other routes of exposure. In light of animal welfare considerations,


Page 2 of 11

testing in animals in Category 5 ranges is discouraged and should only be considered when there is a strong likelihood that results of such testing would have a direct relevance for protecting human health. NOTE 2: These values are designed to be used in the calculation of the ATE for classification of a mixture based on its ingredients and do not represent test results. The values are conservatively set at the lower end of the range of Categories 1 and 2, and at a point approximately 1/10th from the lower end of the range for Categories 3 – 5.



Eye Irritation



Not applicable

Skin Irritation








Flammable Aerosol


Flammable solids



Not Applicable

Flammable gases



Not Applicable

GHS Label: GHS 02: Flammables, GHS08: Carcinogen, GHS 09: Environmental Hazard

Signal word: Danger

Details of Statements: Hazard

Statements H350: May cause cancer H304: May be fatal if swallowed and enters airways.

H225: Highly flammable liquid and vapour. H340: May cause genetic defects H372: Causes damage to organs H319: Causes serious eye irritation. H315: Causes skin irritation.


P 102: Keep out of reach of children. P 103: Read label before use. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and


Page 3 of 11

understood. P210: Keep away from heat/sparks/open flames/hot surfaces* No smoking. P 233: Keep container tightly closed. P 240: Ground/bond container and receiving equipment. P 241: Use explosion-proof electrical/ventilating/lighting/ equipment. P 242: Use only non-sparking tools. P 243: Take precautionary measures against static discharge. P 260: Do not breathe dust/fume/gas/mist/vapours/spray*. P 264: Wash thoroughly after handling. P 270: Do not eat, drink or smoke when using this product. P 280: Wear protective gloves/protective clothing/eye protection/face protection*. P281: Use personal protective equipment as required.


P 101: If medical advice is needed, have product container or label at hand. P 301: IF SWALLOWED: P 302: IF ON SKIN: P 303: IF ON SKIN (or hair): P 305: IF IN EYES: P308: IF ON CLOTHING: P 310: Immediately call a POISON CENTER or doctor/physician. P313: Get medical advice/attention. P 314: Get medical advice/attention if you feel unwell. P 321: Specific treatment (see on this label).* P 331: Do NOT induce vomiting. P 332: If skin irritation occurs: P 337: If eye irritation persists: P 338: Remove contact lenses, if present and easy to do. Continue rinsing. P 351: Rinse cautiously with water for several minutes. P 352: Wash with plenty of soap and water. P 353: Rinse skin with water/shower. P 361: Remove/Take off immediately all contaminated clothing. P 362: Take off contaminated clothing and wash before re-use. P 370: In case of fire: P 378: Use for extinction. H411: Toxic to aquatic life with long lasting effects.


Storage

P235 Keep cool. P403: Store in a well-ventilated place. P405: Store locked up.



Hazard ratings:

NFPA HAZARD CODES RATINGS SYSTEM

HEALTH: 2 0 = No Hazard

FLAMMABILITY: 3 1 = Slight Hazard

INSTABILITY: 0 2 = Moderate Hazard

3 = Serious Hazard

4 = Severe Hazard

Data Reference: http://ecb.jrc.ec.europa.eu/esis/index

2.2 Information pertaining to particular dangers for human: Ingestion The swallowing of small amounts is unlikely to have adverse effects; larger amounts may cause irritation with diarrhoea and vomiting. Skin


Page 4 of 11

Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause dermatitis which could eventually lead to irreversible skin disorders. Injection of fuel under pressure through the skin may have serious effects which at first may not seem serious but, within hours, may become very painful. Eyes May cause irritation with short-term redness and stinging. Inhalation Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness leading to loss of consciousness. 2.3 Information pertaining to particular dangers for the environment: Classified as dangerous for the environment. 2.4 Other adverse effects: Exposure to gases generated due to the burning of this product in an area without adequate ventilation may result in unconsciousness and suffocation. Injection of fuel under the skin may have serious medical effects. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.

DATA REFERENCE: http://toxnet.nlm.nih.gov/cgibin/sis/search.

Health hazards: Due to Benzene content

Source NTP listed? IARC cancer

review group?

OSHA Regulated?

Carcinogenicity Chemical is

known to be

carcinogenic

Carcinogenic to

humans

Chemical appears at 29

CFR part 1910 subpartZ.

DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health Administration (OSHA) carcinogen, National Toxicological program (NTP), International Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-bin/sis/search.


Ingredients / Hazardous CAS No. EC No. Percentage

Gasoline 86290-81-5 289-220-8 98.5% min.

Benzene 71-43-2 200-753-7 1.5% max.

A complex blend of petrolem derived normal and branched chain alkanes,

cycloalkanes, alkenes and aromatic hydrocarbons may contain antioxidant and

multifunction additives. Oxygeneted gasoline will have required ammount of

oxygenets.




Yes Yes Yes Yes Yes

http://toxnet.nlm.nih.gov/cgi%1fbin/sis/search





Page 5 of 11

4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilized position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation If inhalation of vapour causes irritation or drowsiness remove to fresh air. Get Medical advice if the symptoms continue.

4.3 Skin contact

Wash skin as soon as possible with water. Change contaminated clothing and launder before reuse. Get medical advice if irritation persists. Any injection of fuel under the skin should be considered an EMERGENCY - get Medical Advice URGENTLY. 4.4 Eye contact Wash out thoroughly with large amounts of water. If redness and/or irritation continues get medical advice. 4.5 Swallowing Wash mouth out with water and give water to drink. If a large amount has been swallowed get medical advice. DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.


5.1 Suitable extinguishing media

Extinguish with Dry Powder, Foam or Water Fog. For small fires use CO2

5.2 Extinguishing media to be avoided: Do not use water jets


procedures: Fires in closed or confined spaces should be tackled by trained

personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters: Wear full protective fire-resistant clothing and self-contained breathing apparatus.


6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or water containers, inform water consumers immediately, stop service and exploitation of water. 6.3 Recommended methods for cleaning and disposal


Page 6 of 11

Contain spillage - do not wash spillage down drain. Absorb using absorbent clay, diatomaceous clay or other suitable absorbent.


7.1 Information for safe handling Product is designed to be used in closed systems. Electrostatic generation takes place while during product transfer and flow. Take precautionary measures against static discharges. Avoid skin contact when working on fuel system components. Where exposure is likely PROTECTIVE CLOTHING should be worn including impervious GLOVES and EYE PROTECTION. Ensure good ventilation. 7.2 Information for storage Drums should be stored on their sides on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should be taken to avoid over-stacking. 7.3 Information for specific use: NA.


8.1 Occupational Exposure Limits: NA NA: Data not available Provide adequate ventilation when using the material and follow the principles of good occupational hygiene to control personal exposure. Recommended determination method in the work place atmosphere: gas chromatography, detector tube.


Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):


Respiratory protection: Unlikely to be required in normal use but ensure good ventilation. Eye protection: Eye protection is recommended at all times

Hand protection: Wear gloves of impervious material.

Body protection: Hand and skin protection recommended at all times. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

8.3 Environmental exposure controls


Page 7 of 11

Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.


Appearance Liquid, colourless Odour Typical gasoline odour Solubility in water Negligible Relative Density (H2O=1) @ 15°C 0.68 - 0.79 Boiling Point °C 20 - 200°C Melting Point °C -90.5°C to -95.4°C Relative Vapour Density (Air=1) 3.5 Flash point °C -30°C min. Closed cup Auto ignition °C 280 °C Vapour pressure (kPa) @ 37.8 °C <107 Molecular weight NA Explosive limits in air % by volume LEL 1.4 % UEL 7.6% PH NA Viscosity cst @40 °C <1 Pour point NA Evaporation rate (ether=1) NA Octanol/water partition coefficient 2.1 - 6 % volatile NA NA: NOT AVAILABLE DATA REFERENCE http://toxnet.nlm.nih.gov/cgi-bin/sis/search


10.1 Conditions to avoid: Heat 10.2 Material to avoid: May react with strong oxidizing materials. 10.3 Hazardous decomposition products: With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.


11.1 Acute effects Over exposure (orally, dermally or by inhalation) to product is harmful. With the use of good occupational and hygiene practices any risk will be minimal. Acute toxicity data: For Gasoline

Parameter Route Species Values Exposure period LD50 Oral Rat 18.75 mL/kg Not applicable



Page 8 of 11

LD50 Dermal Rabbit >5 mL/kg Not applicable For Benzene Parameter Route Species Values Exposure period

LD50 Oral Rat 3306 mg/Kg Not applicable LD50 Dermal Rabbit >8260 mg/kg Not applicable

LC50 Inhalation Rat 10000 ppm 7 hours

Data Reference: http://toxnet.nlm.nih.gov/cgibin/sis/search. 11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin cancer. 11.3 Sensitisation May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction) Substance is carcinogenic, mutagenic, and reproductive toxin. 11.5 Toxicokinetics, metabolism, distribution Not applicable.


12.1 Eco toxicity data: For Gasoline



LC50 Inhalation

Oncorhynchus my kiss

(Rainbow trout)

16 mg/L 96 hours static

EC50 Inhalation Daphnia

magna (water flea)

12 mg/L 48 Hours static

For Benzene Parameter Route Species Values Exposure

period Condition of bioassay

LC50 Inhalation

Palaemonetes pugio (grass

shrimp)

27 ppm 96 hours Not specified

LC50 Inhalation Carassius auratus

(goldfish)

46 mg/l 24 hours Not specified

LC50 Inhalation Crangon franciscorum

(shrimp);

20 ppm 96 hours Not specified

Data Reference: http://toxnet.nlm.nih.gov/cgi-bin/sis/search

12.2 Mobility: Expected to have high mobility in soil.

12.3 Persistence and degradability:

Hydrolysis: Substance is not expected to be an important environmental fate process since gasoline does not contain any constituents with hydrolyzable functional groups

Substance is biodegradable.

12.4 Bio accumulative potential: The bio concentration potential of the major components

of gasoline range from low to high.



Page 9 of 11

12.5 Results of PBT assessment Persistence and Degradation: Not considered to be a

PBT or v PvB.

12.6 Other adverse effects: NA Environmental Fate: Expected to have high mobility in soil.



13.1 Recommended disposal methods for the substance / mixture

Product reuse or disposal in accordance with valid waste legislative regulations.

13.2 Recommended disposal methods for contaminated packaging

Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment

Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation

Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.


International Transport Regulation:

14.2 Special transport precautionary measures Shipping name: Gasoline, Flammable liquid UN Number 1203 Packing Group: II Packaging Instruction: P001/IBC002 Portable Tank: T4/TP1 IMO Hazard Class: 3 IATA Hazard Class 3 Emergency Action Code: 3YE

14.2 Special transport precautionary measures ADR/RID Hazard Class: 3


(M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements


Page 10 of 11

United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council *RISK PHRASES: R10: Flammable Toxic, R45: may cause cancer, R46: May cause heritable genetic damage, R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment, R61: May cause harm to the unborn child, R65: Harmful: may cause lung damage if swallowed.

*SAFETY PHRASES: S45: In case of accident or if you feel unwell, seek medical advice immediately, S53: Avoid exposure - obtain special instructions before use, S61: Avoid release to the environment, refer to special instructions/ safety data sheets, S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

*These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations - Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Materials) Safety Data Sheets to identify potential hazards and offer safe handling advice.


Training instructions Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Trem card details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630 . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html (M)SDS Revision Status:

Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 2 NFPA Hazard statement Sep. 01, 2011






Page 11 of 11

Feb.01,2016 Section 11,12,14 Aug. 01, 2013 This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this (Material) Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected] Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

End of (M)SDS


(Material) Safety Data Sheet Issue Date: Jan. 01, 2017 NAPHTHA Supercedes: Aug. 01, 2013

Page 1 of 10




Commercial name: Naphtha Chemical name: Naphtha Synonyms: Naphtha

1.2 Use of the substance /mixture: Fuel and raw material of petrochemicals

1.3 MANUFACTURER & SUPPLIER: Reliance Industries Limited

Emergency Coordination Centre contact details:

Jamnagar Mfg. Division


SSM Office

+ 91 288 6612400

Mobile 9998007989

+ 91 288 6611190/1/6




code. Hazard Category: Health Environmental Physical Aspiration Toxicity Category: 1 Carcinogenicity – Category 1B


Flammable – Category 1

NA: Not available Data reference: http://ecb.jrc.ec.europa.eu/esis/, Data reference: Official Journal of the European Union regarding EU GHS GHS Category table for reference:



Acute Oral LD50






Acute Dermal LD50












Flammable liquids





Not Applicable

Note: Gases concentration are expressed in parts per million per volume (ppmV). NOTE 1: Category 5 is for mixtures which are of relatively low acute toxicity but which under certain circumstances may pose a hazard to vulnerable populations. These mixtures are anticipated to have an oral or dermal LD50 value in the range of 2000-5000 mg/kg bodyweight or equivalent dose for other routes of exposure. In light of animal welfare considerations, testing in animals in Category 5 ranges is discouraged and should only be considered when there is a strong likelihood that results of such testing would have a direct relevance for protecting human health. NOTE 2: These values are designed to be used in the calculation of the ATE for classification of a mixture based on its ingredients and do not represent test results. The values are conservatively set at the lower end of the range of Categories 1



Page 2 of 10

and 2, and at a point approximately 1/10th from the lower end of the range for Categories 3 – 5.



Eye Irritation



Not applicable

Skin Irritation








Flammable Aerosol


Flammable solids



Not Applicable

Flammable gases



Not Applicable

GHS Label: GHS02: Flammables; GHS08: Carcinogen.

Signal Word: Danger. Details of statements:

Hazard Statements

H224: Extremely flammable liquid and vapour. H350: May cause cancer H304: May be fatal if swallowed and enters airways.


P102: Keep out of reach of children. P 103: Read label before use. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge.


Page 3 of 10

P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required.


P101: If medical advice is needed, have product container or label at hand. P308: IF ON CLOTHING: P313: Get medical advice/attention. P301 IF SWALLOWED: P310 Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P303 +P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378: In case of fire: Use Dry chemical Powder, Foam or Water Fog for extinction.


Storage

P405: Store locked up. P403 + P235: Store in a well-ventilated place. Keep cool.



Data reference: Official Journal of the European Union regarding EU GHS

2.2 Information pertaining to particular dangers for human: Ingestion The swallowing of small amounts is unlikely to have adverse effects; larger amounts may cause irritation with diarrhea and vomiting. Skin Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause dermatitis which could eventually lead to irreversible skin disorders. Eyes May cause irritation with short-term redness and stinging. Inhalation Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness leading to loss of consciousness.

2.3 Information pertaining to particular dangers for the environment: NA.

2.4 Other adverse effects: NA. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.


2.1 Health hazards:

Source NTP listed? IARC cancer review

group?

OSHA

Regulated?

Carcinogenicity Yes Yes Yes

DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health

Administration (OSHA) carcinogen, National Toxicological program (NTP), International

Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-bin/sis/search.


Yes Yes Yes Yes Yes




Page 4 of 10


Ingredients /

Hazardous CAS No. EC No.

Percentage

Naphtha/Yes

64742-73-0 64741-46-4 64741-63-5 64741-84-0 64741-41-9 68783-12-0 64741-42-0 64741-69-1 64741-78-2 85116-60-5 92045-60-8 93165-19-6

265-178-6 265-046-8 265-065-1 265-086-6 265-041-0 272-186-3 265-042-6 265-071-4 265-079-8 285-511-9 295-442-6 296-903-4

0 to 99.0% (Any component)



4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION, EXPOSURE OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilized position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation If inhalation of vapour causes irritation or drowsiness remove to fresh air. Get Medical advice if the symptoms continue.

4.3 Skin contact Wash skin as soon as possible with water. Change contaminated clothing and launder before reuse. Get medical advice if irritation persists. Any injection of fuel under the skin should be considered an EMERGENCY - get Medical Advice URGENTLY. 4.4 Eye contact Wash out thoroughly with large amounts of water. If redness and/or irritation continues get medical advice. 4.5 Swallowing Wash mouth with water and give water to drink. If a large amount has been swallowed get medical advice. DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.


5.1 Suitable extinguishing media Extinguish with Dry chemical Powder, Foam or Water Fog. For small fires use CO2 5.2 Extinguishing media to be avoided Do not use water jets



Page 5 of 10


procedures Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters Wear full protective fire-resistant clothing and self-contained breathing apparatus.


6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or water containers, inform water consumers immediately, stop service and exploitation of water. 6.3 Recommended methods for cleaning and disposal Contain spillage - do not wash spillage down drain. Absorb using absorbent clay or other suitable absorbent.


7.1 Information for safe handling Avoid skin contact when working on fuel system components. Where exposure is likely PROTECTIVE CLOTHING should be worn including impervious GLOVES and EYE PROTECTION. Ensure good ventilation. 7.2 Information for storage Drums should be stored on their sides on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should be taken to avoid over-stacking. 7.3 Information for specific use: Nil.



Naphtha US TWA NA 1370

US STEL NA NA NA: Data not available, US: REPSOL PETROLEO



Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In cases, where the workplace



Page 6 of 10

exposure control limits cannot be observed with the help of technical equipment or where it is not possible to ensure that the respiratory system exposure does not represent a health hazard for the personnel, adequate respiratory protection have to be kept at disposition. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):



Body protection: Hand and skin protection recommended at all times. Where exposure is likely protective clothing must be worn, including nitrile gloves approved. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

8.3 Environmental exposure controls Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.


Appearance Liquid, colourless or brown Odour Characteristic Solubility in water Negligible Relative Density (H2O=1) @ 15°C 0.74 - 0.87 Boiling Point °C 27 - 233°C Melting Point °C <-50 Deg C Relative Vapour Density (Air=1) NA Flash point °C 20 Auto ignition °C 232 Vapour pressure (hpa) @ 37.8 °C 6.9-760 Molecular weight NA Explosive limits in air % by volume LEL 1%,UEL 6% PH NA Viscosity cSt @40 °C NA Pour point NA Evaporation rate (ether=1) NA Octanol/water partition coefficient 2.1-6


Page 7 of 10

% volatile NA NA: NOT AVAILABLE



10.1 Conditions to avoid: Heat

10.2 Material to avoid: May react with strong oxidizing materials. 10.3 Hazardous decomposition products With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.


11.1 Acute effects Acute toxicity data:

Parameter Route Species Values Exposure period LD50 Oral Rat > 5000 mg/kg Not applicable

Data Reference: : http://ecb.jrc.ec.europa.eu/esis/ 11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin cancer. 11.3 Sensitisation: May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction) Substance is carcinogen 11.5 Toxicokinetics, metabolism, distribution: NA.


12.1 Eco toxicity data:



LC50 Inhalation

Crangon crangon

4.3 mg/L 96 hours Not specified


12.2 Mobility: High mobility in soil

12.3 Persistence and degradability: Substance is biodegradable. 12.4 Bio accumulative potential: NA. 12.5 Results of PBT assessment Persistence and Degradation: Photo-degrade in air. 12.6 Other adverse effects Expected to harm aquatic organisms, films formed on water may affect oxygen transfer and damage organisms. Likely to biodegrade slowly. Environmental Fate: Expected to have high mobility in soil. Is expected to biodegrade in soils.






Page 8 of 10


13.1 Recommended disposal methods for the substance / mixture Product reuse or disposal in accordance with valid waste legislative regulations. 13.2 Recommended disposal methods for contaminated packaging Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.


14.1 International Transport Regulation: Shipping name: PETROLEUM DISTILLATES, N.O.S. UN Number: 1268 Packaging Group: I Packaging Instruction: P001 Portable Containers: T11 (Special Instruction: TP1, TP8) IATA class: 3 IMDG: 3 Emergency Action Code: 3YE

14.2 Special transport precautionary measures ADR Classification Code: F1


(M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council


Page 9 of 10

*RISK PHRASES: R12 Extremely flammable R45 may cause cancer, R65 Harmful: may cause lung damage if swallowed.

*SAFETY PHRASES: S2: Keep out of reach of children, S9: Keep container in a well-ventilated place, S16: Keep away from sources of ignition - No Smoking! , S33: Take precautionary measures against static discharges, S45 In case of accident or if you feel unwell, seek medical advice immediately, S53 Avoid exposure – obtain special instruction before use. May cause cancer, flammable, Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.

*These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations - Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Material) Safety Data Sheets to identify potential hazards and offer safe handling advice.


Training instructions Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Tremcard details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630, . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html (M)SDS Revision Status:

Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 1.3 Sep. 01, 2011 Jan.01,2017 Section 2.1,9,14,15 Aug. 01, 2013

This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this (Material) Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected]







Page 10 of 10

Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

End of (M)SDS

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Material Safety Data SheetKerosene MSDS

Section 1: Chemical Product and Company Identification

Product Name: Kerosene

Catalog Codes: SLK1048

CAS#: 8008-20-6 or 64742-81-0

RTECS: OA5500000

TSCA: TSCA 8(b) inventory: Kerosene

CI#: Not available.

Synonym: Astral Oil; Coal Oil, Fuel Oil No. 5, Deobase,Astral Oil, Jet A Fuel; Jet Fuel JP-1; JP-5 Navy Fuel;Kerosine, petroleum; Range Oil; K1 Kerosene; Kerosene,hydrodesulfurized; Kerosine

Chemical Name: Kerosene

Chemical Formula: Not available.

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Kerosene 8008-20-6 or 100

64742-81-0

Toxicological Data on Ingredients: Kerosene: ORAL (LD50): Acute: 15000 mg/kg [Rat]. 20000 mg/kg [Guinea pig]. 2835mg/kg [Rabbit].

Section 3: Hazards Identification

Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case ofskin contact (permeator). Severe over-exposure can result in death.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available.The substance is toxic to the nervous system. The substance may be toxic to blood, kidneys, liver, central nervous system(CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.

http://www.sciencelab.com/

p. 2

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention.

Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:If swallowed, do NOT induce vomiting. If swallowed, do not induce vomiting unless directed to do so by medical personnel.Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Getmedical attention immediately.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 210°C (410°F)

Flash Points: CLOSED CUP: 38°C (100.4°F). (Tagliabue.)

Flammable Limits: LOWER: 0.7% UPPER: 5% - 7%

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Flammable in presence of open flames and sparks, of heat.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.

Fire Fighting Media and Instructions:Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Coolcontaining vessels with water jet in order to prevent pressure build-up, autoignition or explosion.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:

p. 3

Toxic flammable liquid, insoluble or very slightly soluble in water. Poisonous liquid. Keep away from heat. Keep away fromsources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get waterinside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements orconfined areas; dike if needed. Call for assistance on disposal.

Section 7: Handling and Storage

Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents.

Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid. (Oily liquid.)

Odor: Not available.

Taste: Not available.

Molecular Weight: Not available.

Color: Yellow. Clear (Light.)

pH (1% soln/water): Not applicable.

Boiling Point: 149°C (300.2°F) - 325 C

Melting Point: Not available.

Critical Temperature: Not available.

Specific Gravity: 0.775 - .840(Water = 1)

Vapor Pressure: 0.1 kPa (@ 20°C)

Vapor Density: 4.5 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

p. 4

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: Not available.

Solubility:Insoluble in cold water, hot water. Miscible with other petroleum solvents

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, ignition sources (sparks, flames), incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents.

Corrosivity: Not considered to be corrosive for metals and glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact.

Toxicity to Animals: Acute oral toxicity (LD50): 2835 mg/kg [Rabbit].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. Causes damage to the following organs: the nervous system.May cause damage to the following organs: blood, kidneys, liver, central nervous system (CNS).

Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardous in case of skin contact(permeator).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes moderate to severe skin irritation. It can cause defatting dermatitis. Eyes:May cause eye irritation. Inhalation: May cause respiratory tract and mucous membrane irritation and a burning sensationin the chest. Because of its relatively low volatility, overexposure by inhalation is uncommon, but it can occur in poorlyventilated areas or by inhalation of mists or aerosols. Symptoms of inhalation overexposure include central nevous system(CNS) depression (transient euphora, headache, irritability, excitement, ringing in the ears, weakness, incoordination,confusion, disorientation, drowsiness, tremor, somnolence, hallucinations, seizures, coma, death). May affect the heart(cardiac arrythmias), liver, kidneys, and respiration( asphyxia, apnea, acute pulmonary edema, dyspnea, fibrosis, or cyanosis)Ingestion: Causes gastrointestinal tract irritation with burning sensation in mouth, esophagus, and stomach, a b d o m i n a l pa i n , n a u s e a , v o m i t i n g , h y p e r m o t i l i t y , d i a r r h e a , h e a d a c h e , m a l a i s e . M a y a f f e c t respiration/trachea/bronchi through accidental pulmonary aspiration which can cause hypoxia, chemical pneumonitis, and noncardiogenicpulmonary edema, pulmonary hemmorrhage, coughing, breathing difficulty, acute or chronic pulmonary edema, emphysema,respiratory stimulation. It may also affect the heart (dysrrhythmias, myocardial depression, tachycardia), liver, endocrinesystem (pancreas - hypoglycemia), behavior/central nervous system (symptoms similar to that of inhalation). Chronic PotentialHealth Effects: Inhalation: Repeated or prolonged inhalation may cause respiratory tract irritation and affect behavior/centralnervous system with symptoms similar to that of acute inhalation. It may also affect the blood (changes in white blood cellcount, changes in serum compositon, pigmented or nucleated red blood cells, leukopenia, normocytic anemia) , cardiovascular

p. 5

system, respiratory system (trachea, bronchi), and may cause kidney damage. Ingestion: Repeated or prolonged ingestionmay affect the liver, endocrine system (adrenal gland, pancreas, spleen), and metabolism (weight loss), and blood. Skin:Repeated or prolonged skin contact may cause defatting dermatitis, erythema, and eczema-like skin lesions, drying andcracking of the skin, and possible burns.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: Not available.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.

Identification: : Kerosene UNNA: 1223 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:Connecticut hazardous material survey.: Kerosene Rhode Island RTK hazardous substances: Kerosene Pennsylvania RTK:Kerosene Massachusetts RTK: Kerosene Massachusetts spill list: Kerosene New Jersey: Kerosene TSCA 8(b) inventory:Kerosene

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2B: Material causingother toxic effects (TOXIC).

DSCL (EEC):R10- Flammable. R65- Harmful: may cause lung damage if swallowed. S23- Do not breathe gas/fumes/vapour/spray S24-Avoid contact with skin. S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this containeror label.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

p. 6

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 0

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 05:54 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

MATERIAL SAFETY DATA SHEET

PRODUCT: ETHANOL, Date of Issue: December 2010

1. IDENTIFICATION OF CHEMICAL PRODUCT AND SUPPLIER

PRODUCT IDENTIFICATION:

Product Names: Supplier’s Product Code:

Ethanol, denatured

Other Names: Nil

Recommended Use: General chemical

Formula:

Chemical family Alcohol

Supplier: Formula Chemicals (N.S.W.) Pty Ltd

Address: 86 Hermitage Rd West Ryde NSW 2114

Telephone Number: (02) 9807 4266

Emergency Telephone: (02) 9807 4266 or Poisons Information Centre 131126

ACN: 001 129 406

2. HAZARDS IDENTIFICATION

NON-HAZARDOUS SUBSTANCE. DANGEROUS GOODS Not classified as hazardous according to the criteria of NOHSC.

Hazard Category: F+ Highly flammable.

Risk phrases: R11 Highly flammable.

Safety phrases: S7 Keep container tightly closed. S16 Keep away from sources of ignition.

SUSDP Classification: Nil

ADG Classification: Class 3 Flammable

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms: Nil

Appearance: Clear colourless liquid, alcohol odour

Ingredients:

Chemical Name, CAS No Proportion Risk Phrases

Ethanol, 64-17-5 91 - 95 % nil

Isopropanol, 67-63-0 5 %

Water to make total of 100%

All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).

Date of Issue: December 2010

4. FIRST AID MEASURES

Poison Information Centres in each state can provide additional assistance for scheduled poisons. Phone 131126 from

anywhere in Australia.

Ingestion:

Give water to drink. Induce vomiting in a conscious person by giving Ipecac syrup if possible. Give further water to

achieve effective dilution. Keep head below hip level to reduce possibility of aspiration pneumonitis. Seek medical

attention. Never attempt to give anything by mouth to an unconscious person.

Eye Contact:

Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for AT LEAST 15 minutes, by the

clock, holding the eyelid(s) open. Remove clothing if contaminated and wash skin. If irritation occurs seek medical

attention.

Skin Contact:

Wash contaminated skin with plenty of water. Remove contaminated clothing and wash before re-use. If irritation

persists, seek medical advice.

Inhalation:

Remove victim to fresh air - avoid becoming a casualty. If breathing is difficult, administer oxygen. If breathing has

stopped, apply artificial respiration. Seek medical attention.

Other First Aid:

Provide general supportive measures (comfort, warmth, rest). Consult a physician and/or the nearest Poison

Information Centre.

Notes to physician:

Treat symptomatically as for alcohol poisoning.

5. FIRE FIGHTING MEASURES

Specific hazards:

Highly flammable.

Fire fighting further advice:

Flammable. Do not spray near ignition sources. May form explosive mixtures with air. Keep away from heat, sparks

or naked flames. Heating may cause explosion. Avoid all ignition sources. Flameproof equipment necessary. Earth

nearby equipment. Firefighters must wear self-contained breathing apparatus with full-face mask and protective

clothing.

Suitable Extinguishing media:

Water fog (or if unavailable fine water mist or spray), foam, dry agent (carbon dioxide, dry chemical powder).

6. ACCIDENTAL RELEASE MEASURES

Small Spills: Eliminate all sources of ignition. Prevent static discharges. Contain using sand or diatomaceous earth.

Collect and seal in properly labelled drums. Wash remaining area with large volumes of water.

Large Spills: PRECAUTIONS Restrict access to area. Clear area of unprotected personnel. Eliminate all sources of ignition.

Prevent static discharges. Provide adequate protective equipment and ventilation. Remove chemicals which can react

with the spilled material.

CLEANUP Contain spill or leak. Do not allow entry into sewers or waterways.

Spilled solutions should be contained by dyking with inert material, such as sand or earth. Solutions can be recovered

or carefully diluted with water.

DISPOSAL Federal, state and local regulations should be reviewed prior to disposal. May be possible to dilute and

flush the material into a sewer. May be possible to atomise dilute solutions in an approved combustion chamber. May

be harmful to aquatic life in high concentrations.

7. HANDLING AND STORAGE

HANDLING Avoid generating mist or spray. Label containers. Keep containers closed when not in use.

STORAGE CONDITIONS Store in suitable labelled containers. Keep containers tightly closed when not in use and

when empty. Protect from damage Store in cool dry place and out of direct sunlight. Store in well-ventilated area.

Store away from strong oxidisers, peroxides, acids, acid chlorides, acid anhydrides, alkali metals and ammonia. Do

not store in aluminium containers. Keep containers closed at all times. Keep containers securely sealed and protected

against physical damage. Do not store in pits or basements where vapours may become entrapped. Store away from

sources of heat or ignition. Not to be loaded with Class 1, 2.1, 2.3, 4.2, 5.1, 5.2, 6*, 7. (* where flammable liquid is

nitromethane).

..


8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Standards: Ethyl Alcohol TLV/TWA: 1900 mg/m3, 1000 ppm; NOHSC Australia.

Engineering Controls: Use with adequate ventilation. Avoid generating and inhaling mist. Local exhaust ventilation

system may be required. DO NOT enter confined spaces where vapour may have collected. Use in well ventilated area.

Keep containers closed when not in use.

Personal Protection: Use good personal and industrial hygiene. Wash hands and face before eating, drinking or

smoking. Avoid direct contact with the product, wear appropriate protective clothing. If ventilation inadequate use

approved respirator.

9. PHYSICAL & CHEMICAL PROPERTIES

Appearance: Clear colourless liquid, characteristic odour

Odour threshold: Not available

Boiling point Approximately 78 0C (ethanol)

Vapour pressure 44 mm Hg @ 200C

Specific gravity 0.8

Flash point 13 0C

Flammability Limits Lower 3.5%, Upper 19.0%

Solubility in water Soluble

10. STABILITY AND REACTIVITY

Reactivity Data:

STABILITY: Stable

INCOMPATIBILITY: Strong oxidisers.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon dioxide.

HAZARDOUS POLYMERISATION: Will not occur.

Fire/Explosion Hazard:

Vapour or mist will form flammable mixtures in air. Flashback along vapour trail may occur.

Extinguish fire with the following:

Water spray, carbon dioxide, foam, dry chemical.

Firefighters to wear full protective clothing with breathing apparatus.

11. TOXICOLOGICAL INFORMATION

Acute Effects:

Ingestion:

Moderately toxic. May lead to CNS depression. Ingestion can result in nausea. May cause gastric irritation,

headache and dizziness.

Eye contact: Moderate to severe irritation. May cause watering of eyes. High concentrations of vapours will cause irritation.

Skin contact:

Moderate to severe irritation, drying, de-fatting.

Inhalation:

Inhalation of mists or aerosols can produce respiratory irritation, could be anaesthetic and have central nervous

system effects .

Long term Effects:

Possible liver and kidney disorders. Repeated or prolonged skin contact can cause chronic dermatitis. Chronic

exposure to vapour may result in headache and symptoms of central nervous system depression. Absorbed

into the body by inhalation and ingestion. Excessive acute absorption may cause central nervous system

depression. Excessive chronic absorption may result in liver injury. Excessive ingestions can lead to alcoholism.

Ethanol is generally regarded as one of the safest industrial solvents. Although it possesses narcotic properties,

vapour concentrations sufficient to produce this effect are rarely, if ever, reached in industry.

Toxicity Data:

Oral Lowest Lethal Dose(human): 1400 mg/kg Inhalation LC50(rat): 20000 ppm/ 10 hr Oral Lowest Lethal

Dose(child): 2000 mg/kg. 250 ppm/6hr/goldfish/lethal/fresh water.


12. ECOLOGICAL INFORMATION

Avoid contaminating waterways.

13. DISPOSAL CONSIDERATIONS

Refer to State Land Waste Management Authority. Decontaminate empty containers before disposal, by triple rinsing

with water, using rinse water in further processing or neutralize rinse water.

14. TRANSPORT INFORMATION

UN No: 1170

Proper Shipping Name: ETHANOL SOLUTION

Class: 3

Packing Group: 2

Hazchem Code: 2[Y]E

EPG Nil

Segregation Dangerous Goods Not to be loaded with Class 1, 2.1, 2.3, 4.2, 5.1, 5.2, 6*, 7. (* where

flammable liquid is nitromethane).

15. REGULATORY INFORMATION

Not classified as hazardous according to the criteria of NOHSC, Not scheduled per SUSDP, Dangerous goods according

to ADG code

R-phrases: R11 Highly flammable.

S-phrases: S7 Keep container tightly closed. S16 Keep away from sources of ignition.

16. OTHER INFORMATION

References:

(1) National Code of Practice for the preparation of MSDS [NOHSC:2011(2003), (2) List of Designated Hazardous

Substances [NOHSC:10005:1999] (3) ADG Code 6th Edition

Contact Point: Quality Assurance Manager Tel (02) 9807 4266

DISCLAIMER: All information given in this data sheet and by the company's technical staff is compiled from the best information currently available to the company. The

company accepts no responsibility whatsoever for its accuracy or for any results which may be obtained by customers. Any customer who relies upon any advice or

information given in this data sheet by the company or by its technical staff does so entirely at its own risk, and the company will not be liable for any loss or damage thereby

suffered notwithstanding any want of care on the part of the company or its staff in compiling or giving the advice or information.

reliance industries limited -...

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