report of trace metals analyses water · 2017. 7. 13. · case narrative shipping and receiving on...

3958 6th Ave. NW Seattle WA 98107

P: 206-632-6206 F: 206-632-6017

E: [email protected] www.brooksrand.com

Report of Trace Metals Analyses Water Project: Great Salt Lake Water Quality Sampling Plan Samples Collected: October 31, 2012 Report Date: January 16, 2013 Prepared for: Jodi Gardberg Utah Department of Environmental Protection 195 North 1950 West, Third Floor Salt Lake City, UT 84116 Brooks Rand Labs Project ID: UDE-SL1201

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Table of Contents

Case Narrative ................................................................................................................ 3

Report Information........................................................................................................... 7

Sample Information ......................................................................................................... 8

Batch Summary ............................................................................................................... 8

Sample Results ............................................................................................................... 9

Accuracy & Precision Summary .................................................................................... 11

Method Blanks & Reporting Limits ................................................................................ 16

Instrument Calibration ................................................................................................... 21

Sample Containers ........................................................................................................ 29

Shipping Containers ...................................................................................................... 31

Chain-of-Custody Form(s) ............................................................................................. 32

Waybill(s) ...................................................................................................................... 34

Mercury Data Sequence 1200884, Batch B122125 ...................................................... 35

Monomethyl Mercury Data Sequence 1200901, Batch B122151 .................................. 95

Trace Metals Data Sequence 1200911, Batch B122318............................................. 217



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Case Narrative

Shipping and Receiving On November 7, 2012, Brooks Rand Labs (BRL) received four (4) water samples accompanied by sixteen containers at 09:00 A.M. in one (1) cooler with ice all at the temperature of than 1.3 °C. The chain-of-custody (COC) forms requested analysis for mercury (Hg), monomethyl mercury (MeHg), and trace metals [arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), selenium (Se), and thallium (Tl)]. The samples were received and stored securely according to BRL standard operating procedures (SOP) and EPA methodology.

Preservation and Holding Time All method and SOP requirements for preservation and holding time were satisfied.

Total Mercury in Water by EPA Method 1631 (SOP BR-0006) All samples are prepared and analyzed in accordance with EPA Method 1631. Samples are oxidized with bromine monochloride (BrCl) and then analyzed with stannous chloride (SnCl2) reduction, single gold amalgamation, and cold vapor atomic fluorescence spectroscopy (CVAFS) detection using a BRL Model III CVAFS Mercury Analyzer.

The results were method blank-corrected as described in the calculations section of the relevant BRL SOP(s) and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, and other details.

Sequence 1200884 Instrument calibration, meeting all quality control criteria, was successfully achieved on the day of sample analysis.

Batch B122125 All data was reported without qualification and all associated quality control sample results met the acceptance criteria.

Methylmercury in Water by EPA Method 1630 (SOP BR-0011) Water samples are prepared by distillation. Distillates are analyzed by ethylation, Tenax trap collection, gas chromatography separation, isothermal decomposition, and cold vapor fluorescence spectroscopy (CVAFS).

The results were method blank-corrected as described in the calculations section of the relevant BRL SOP(s) and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, and other details.

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Sequence 1200901 The instrument disconnected after continuing calibration blank (CCB3). After instrument was reconnected, three rinses were analyzed and the analysis was restarted at CCB4. The original Analysis Benchsheet, with the hand written analyzed volume, was included along with the typed benchsheet listing the correct analysis run numbers.

The analysis of continuing calibration blanks CCB1 and CCB2 returned detectable results due to carryover. However, no sample results were bracketed and no further corrective action was necessary.

Several instrument peaks were manually integrated. These were reviewed and approved by BRL’s Quality Assurance Department. The corrected peaks printouts were included before the Analysis Benchsheet.

Instrument calibration, meeting all quality control criteria, was successfully achieved on the day of sample analysis.


ICP-MS Analysis by EPA Draft Method 1640, Mod. (BRL SOP BR-0066) Samples are preserved to 0.2% (v/v) with pre-tested concentrated HNO3 and then prepared by reductive precipitation (RP) according to EPA Method 1640. The procedure concentrates the samples by a factor of four and is a useful method for achieving a low level of detection for brackish waters and seawaters.

This method involves a reductive precipitation of all metals by sodium borohydride (NaBH4) followed by a filtration of the precipitate through a pre-cleaned 0.2-μm filter. The majority of the saltwater matrix remains in the filtrate. The metals on the filter are then digested and oxidized with nitric acid (HNO3) and hydrogen peroxide (H2O2).

Sample aliquots for Column chelation were adjusted to a pH of 1% (v/v) HNO3. Sample extracts are then analyzed by inductively coupled plasma — mass spectrometry (ICP-MS) according to EPA Method 1640.

Aliquots of prepared sample were analyzed with a Perkin Elmer ELAN with internal standardization. Briefly, this method incorporates ionization of the sample in inductively coupled RF plasma, with detection of the resulting ions by mass spectrometer on the basis of their mass-to-charge ratio.

When the native sample concentration was a non-detect (reported as ND) and/or the corresponding method duplicate (DUP) was also a non-detect, the relative percent difference (RPD) was reported as ‘N/C’.

The recoveries of the matrix spike or matrix spike duplicates (MS/MSD) were not reported (NR) when spiked at a concentration less than 25% of the native sample value.

Sequence 1200911 (RP) The calibration standard (CAL1) recovered outside of acceptance criteria for Se analysis and was not used in the calibration; however reporting limit did not need to be elevated.


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Batch B122318 The SRM SLEW-3 was not reported for Se and Tl since the SRM was not certified for either of these analytes.

Quality control sample MS5 is seawater samples collected in Puget Sound and spiked with analytes of a known concentration.

The Se analysis of method duplicate (DUP3) met the secondary acceptance criteria as the results were less than 5x the MRL and within 1x MRL value of each other.

All data was reported without qualification and all associated quality control sample results met the acceptance criteria.

Sequence 1200980 (Column Chelation) The CAL7 recovered outside of acceptance criteria for Pb and was not used in the calibration curve.

The Pb analysis of continuing calibration verification, -CCV8, recovered outside of criteria. Additionally, Cd and Pb analysis of –CCV9 and –CCVA also recovered outside of criteria. No samples were bracketed by these CCVs and no further corrective action was warranted.



Sequence 1300016 (Column Chelation) The Cu analysis of initial calibration blank ICB2 produced a result greater than CAL1. However, no client samples were bracketed and no further corrective action is warranted.

Worth noting the results of CCB2, CCB5, and CCB6 were less than 10x the concentration of the MDL and were not reflective of contamination.


Batch B130014 The analysis of –CCV2, -CCV3, and –CCV4 recovers outside of acceptance criteria. No samples are bracketed by –CCV2 and –CCV3, however, batch quality control (DUP/MS/MSD) samples were bracketed by –CCV4. Following analysis of –CCV4, the batch method blanks were analyzed and produced non-detectable results, demonstrating any possible contamination which could have caused the elevated CCVs recoveries was successfully rinsed out of the system. No client samples were bracketed by this CCV and no further corrective action was warranted.

All data was reported without qualification and all associated quality control sample results met the acceptance criteria.

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We certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. BRL, an accredited laboratory, certifies that the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details, please see the Report Information page in your report. Please feel free to contact us if you have any questions regarding this report.

___________________________ Tiffany Stillwater Project Manager

[email protected]

___________________________ Mi Sun Um

Data Manager [email protected]

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Project ID: UDE-SL1201

PM: Tiffany Stilwater

Client PM: Jodi Gardberg

Client PO: SS12208

Definition of Data Qualifiers(Effective 9/23/09)

Laboratory AccreditationBRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida

Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is

also certified by many other states to perform environmental analyses. For a current list of our accreditations /certifications,

please visit our website at . Results reported relate only to the

samples listed in the report.

Report Information

BLK

BRL

BS

CAL

CCV

CRM

D

DUP

ICV

MSD

ND

NR

PS

REC

RPD

RSD

SCV

SOP

method blank

Brooks Rand Labs

laboratory fortified blank

calibration standard

continuing calibration verification

certified reference material

dissolved fraction

duplicate

initial calibration verification

matrix spike duplicate

non-detect

non-reportable

post preparation spike

percent recovery

relative percent difference

relative standard deviation

secondary calibration verification

standard operating procedure

MDL

MRL

MS

method detection limit

method reporting limit

matrix spike

SRM

T

COC

standard reference material

total recoverable fraction

chain of custody record

Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand Labs, those found in the EPA SOW ILM03.0,

Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic

Superfund Data Review; USEPA; January 2010. These supersede all previous qualifiers ever employed by BRL.

Detected by the instrument, the result is > the MDL but ≤ the MRL. Result is reported and considered an estimate.B

E An estimated value due to the presence of interferences. A full explanation is presented in the narrative.

H Holding time and/or preservation requirements not met. Result is estimated.

J Estimated value. A full explanation is presented in the narrative.

J-M Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated.

J-N Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated.

M Duplicate precision (RPD) was not within acceptance criteria. Result is estimated.

N Spike recovery was not within acceptance criteria. Result is estimated.

R Rejected, unusable value. A full explanation is presented in the narrative.

U Result is ≤ the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL.

X Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch.

Result is estimated.

Field Quality Control SamplesPlease be notified that certain EPA methods require the collection of field quality control samples of an appropriate type

and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be

done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field

quality control samples.

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · [email protected] · www.brooksrand.com

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Client PO: SS12208

Sample Information

Report Matrix Type ReceivedSampledSample Lab ID

1245020-01Site #9 Upper 10/31/2012 11/07/2012SampleGreat Salt Lake




1245020-05Site #9 Lower 10/31/2012 11/07/2012SampleGreat Salt Lake












Batch Summary

Analyte Prepared Analyzed SequenceBatchLab Matrix Method

B12231812/08/2012 12/08/2012 1200911Water EPA 1640 RPAs

B12243911/20/2012 12/31/2012 1200980Water EPA 1640 ColumnCd

B13001411/20/2012 01/06/2013 1300016Water EPA 1640 ColumnCu

B12212511/20/2012 11/26/2012 1200884Water EPA 1631Hg

B12215112/04/2012 12/06/2012 1200901Water EPA 1630MeHg

B12243911/20/2012 12/31/2012 1200980Water EPA 1640 ColumnPb

B12231812/08/2012 12/08/2012 1200911Water EPA 1640 RPSe

B12231812/08/2012 12/08/2012 1200911Water EPA 1640 RPTl


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Client PO: SS12208

Sample Results

Sample Sequence Result MDL MRL Unit BatchQualifierAnalyte BasisReport Matrix

Site #10 Lower

34.0T 1200911B122318Great Salt Lake 0.500.151245020-15 As µg/L

0.0101T U 1200980B122439Great Salt Lake 0.1010.01011245020-16 Cd µg/L

1.37T 1300016B130014Great Salt Lake 0.2020.04041245020-16 Cu µg/L

3.84T 1200884B122125Great Salt Lake 0.410.151245020-14 Hg ng/L

0.993T 1200901B122151Great Salt Lake 0.2490.1001245020-13 MeHg ng/L

0.627T 1200980B122439Great Salt Lake 0.1010.01011245020-16 Pb µg/L

0.348T U 1200911B122318Great Salt Lake 1.040.3481245020-15 Se µg/L

0.010T U 1200911B122318Great Salt Lake 0.0500.0101245020-15 Tl µg/L

Site #10 Upper









Site #9 Lower










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Client PO: SS12208

Sample Results

Sample Sequence Result MDL MRL Unit BatchQualifierAnalyte BasisReport Matrix

Site #9 Upper







0.606T B 1200911B122318Great Salt Lake 1.050.3501245020-03 Se µg/L



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Client PO: SS12208

Accuracy & Precision Summary

Batch: B122125

Analyte Result UnitsNative Spike REC & Limits RPD & Limits

Method: EPA 1631

Lab Matrix: Water

Sample

Certified Reference Material (1245026, NIST 1641d 1000x dilution)B122125-SRM1

15.68 101%ng/L 85-115Hg 15.90

Matrix Spike (1245020-06)B122125-MS4

29.99 85%ng/L 71-125Hg 29.494.08

Matrix Spike Duplicate (1245020-06)B122125-MSD4

30.90 79%ng/L 71-125 243%Hg 28.554.08


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Client PO: SS12208


Batch: B122151


Method: EPA 1630

Lab Matrix: Water

Sample

Laboratory Fortified Blank (1245063)B122151-BS1

0.9933 86%ng/L 67-133MeHg 0.854


0.9885 93%ng/L 67-133MeHg 0.921

Matrix Spike (1245020-05)B122151-MS1

3.393 97%ng/L 65-135MeHg 3.7710.489


3.425 95%ng/L 65-135 351%MeHg 3.7330.489


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Client PO: SS12208


Batch: B122318


Method: EPA 1640 RP

Lab Matrix: Water

Sample


9.950 73%µg/L 70-130As 7.28

2.488 99%µg/L 70-130Se 2.465

0.09950 92%µg/L 70-130Tl 0.092

Certified Reference Material (1238007, SLEW-3)B122318-SRM1

1.360 93%µg/L 75-125As 1.27

Matrix Spike (0944029-99)B122318-MS5

10.00 91%µg/L 70-130As 10.401.26

2.500 88%µg/L 70-130Se 2.4050.198

0.1000 92%µg/L 70-130Tl 0.1030.011

Duplicate (1245020-03)B122318-DUP3

µg/L 3012%As 36.5641.38

µg/L 3045%Se 0.3810.606

µg/L 30N/CTl NDND

Matrix Spike (1245020-03)B122318-MS3

49.14 74%µg/L 70-130As 77.7441.38

12.29 81%µg/L 70-130Se 10.550.606

0.4914 92%µg/L 70-130Tl 0.450ND


50.00 80%µg/L 70-130 305%As 81.3641.38

12.50 78%µg/L 70-130 303%Se 10.290.606

0.5000 95%µg/L 70-130 305%Tl 0.473ND


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Client PO: SS12208


Batch: B122439


Method: EPA 1640 Column

Lab Matrix: Water

Sample


0.2020 122%µg/L 75-125Cd 0.2470

0.5051 106%µg/L 75-125Pb 0.5368


0.04800 102%µg/L 75-125Cd 0.0487

0.009000 79%µg/L 75-125Pb 0.0071

Certified Reference Material (1238005, CASS-5)B122439-SRM2

0.02150 75%µg/L 75-125Cd 0.0161

0.01100 81%µg/L 75-125Pb 0.0089

Duplicate (1245020-04)B122439-DUP3

µg/L 20N/CCd NDND

µg/L 203%Pb 0.47100.4831

Matrix Spike (1245020-04)B122439-MS3

30.30 110%µg/L 75-125Cd 33.22ND

30.30 124%µg/L 75-125Pb 38.110.4831


30.30 109%µg/L 75-125 200.3%Cd 33.13ND

30.30 124%µg/L 75-125 200.4%Pb 37.970.4831


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Client PO: SS12208


Batch: B130014



Lab Matrix: Water

Sample


2.020 109%µg/L 75-125Cu 2.208


1.550 80%µg/L 75-125Cu 1.233

Certified Reference Material (1238005, CASS-5)B130014-SRM2

0.3800 89%µg/L 75-125Cu 0.3391

Duplicate (1245020-04)B130014-DUP2

µg/L 204%Cu 1.4111.466

Matrix Spike (1245020-04)B130014-MS2

30.30 103%µg/L 75-125Cu 32.531.466


30.30 101%µg/L 75-125 202%Cu 31.991.466


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Client PO: SS12208

Method Blanks & Reporting Limits

Batch: B122125

Method: EPA 1631

Matrix: Water

Analyte: Hg

Result UnitsSample

B122125-BLK1 ng/L0.10

B122125-BLK2 ng/L0.09

B122125-BLK3 ng/L0.10

B122125-BLK4 ng/L0.10

MDL: 0.15Average: 0.10 Standard Deviation: 0.01

Limit: 0.10Limit: 0.50 MRL: 0.40


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Client PO: SS12208


Batch: B122151

Method: EPA 1630

Matrix: Water

Analyte: MeHg

Result UnitsSample

B122151-BLK1 ng/L0.007

B122151-BLK2 ng/L0.004

B122151-BLK3 ng/L0.004

B122151-BLK4 ng/L0.006


Limit: 0.015Limit: 0.045 MRL: 0.051


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Client PO: SS12208


Batch: B122318

Method: EPA 1640 RP

Matrix: Water

Analyte: As 75

Result UnitsSample

B122318-BLK1 µg/L0.01

B122318-BLK2 µg/L0.008

B122318-BLK3 µg/L0.03

B122318-BLK4 µg/L0.02


Limit: 0.03Limit: 0.10 MRL: 0.10

Analyte: Se 82

Result UnitsSample

B122318-BLK1 µg/L-0.052

B122318-BLK2 µg/L-0.076

B122318-BLK3 µg/L-0.021

B122318-BLK4 µg/L-0.034

MDL: 0.070Average: -0.046 Standard Deviation: 0.024

Limit: 0.070Limit: 0.210 MRL: 0.210

Analyte: Tl

Result UnitsSample

B122318-BLK1 µg/L-0.000004

B122318-BLK2 µg/L-0.0001

B122318-BLK3 µg/L-0.0001

B122318-BLK4 µg/L0.000002


Limit: 0.002Limit: 0.010 MRL: 0.010


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Client PO: SS12208


Batch: B122439


Matrix: Water

Analyte: Cd 114

Result UnitsSample

B122439-BLK1 µg/L0.0008

B122439-BLK2 µg/L0.0008

B122439-BLK3 µg/L0.0008

B122439-BLK4 µg/L0.0008


Limit: 0.0010Limit: 0.0101 MRL: 0.0101

Analyte: Pb

Result UnitsSample

B122439-BLK1 µg/L0.0006

B122439-BLK2 µg/L0.0007

B122439-BLK3 µg/L0.0009

B122439-BLK4 µg/L0.0009


Limit: 0.0010Limit: 0.0101 MRL: 0.0101


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Client PO: SS12208


Batch: B130014


Matrix: Water

Analyte: Cu 65

Result UnitsSample

B130014-BLK1 µg/L0.0004

B130014-BLK2 µg/L-0.0014

B130014-BLK3 µg/L-0.0029

B130014-BLK4 µg/L-0.0030

MDL: 0.0040Average: -0.0017 Standard Deviation: 0.0016

Limit: 0.0040Limit: 0.0202 MRL: 0.0202


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Client PO: SS12208

Instrument Calibration

Sequence: 1200884

Method: EPA 1631Instrument: THG-05

Date: 11/26/2012

Total Mercury and Mercury Speciation by CVAFS

Analyte: Hg

REC & LimitsResultTrue ValueLab ID Units1200884-IBL1 2.05 pg of Hg

1200884-IBL2 4.46 pg of Hg

1200884-IBL3 4.03 pg of Hg

1200884-IBL4 4.39 pg of Hg

1200884-CAL1 10.00 9.93 pg of Hg 99%

1200884-CAL2 25.00 25.49 pg of Hg 102%

1200884-CAL3 100.0 97.50 pg of Hg 97%

1200884-CAL4 500.0 479.9 pg of Hg 96%

1200884-CAL5 2500 2603 pg of Hg 104%

1200884-CAL6 10000 10160 pg of Hg 102%

1200884-ICV1 1568 1590 pg of Hg 101% 85-115

1200884-CCB1 8.21 pg of Hg

1200884-CCV1 500.0 529.5 pg of Hg 106% 77-123

1200884-CCB2 4.98 pg of Hg

1200884-CCB3 4.10 pg of Hg

1200884-CCB4 4.36 pg of Hg

1200884-CCV2 500.0 510.9 pg of Hg 102% 77-123

1200884-CCB5 6.48 pg of Hg

1200884-CCV3 500.0 535.4 pg of Hg 107% 77-123

1200884-CCB6 4.51 pg of Hg

1200884-CCV4 500.0 548.3 pg of Hg 110% 77-123

1200884-CCB7 4.14 pg of Hg

1200884-CCV5 500.0 542.6 pg of Hg 109% 77-123

1200884-CCB8 4.33 pg of Hg

1200884-CCV6 500.0 538.5 pg of Hg 108% 77-123

1200884-CCB9 4.26 pg of Hg

1200884-CCV7 500.0 534.2 pg of Hg 107% 77-123

1200884-CCBA 4.58 pg of Hg

1200884-CCV8 500.0 531.9 pg of Hg 106% 77-123

1200884-CCBB 4.40 pg of Hg

1200884-CCV9 500.0 540.0 pg of Hg 108% 77-123

1200884-CCBC 4.56 pg of Hg

1200884-CCVA 500.0 535.5 pg of Hg 107% 77-123

1200884-CCBD 5.26 pg of Hg

1200884-CCVB 500.0 538.2 pg of Hg 108% 77-123

1200884-CCBE 4.16 pg of Hg

1200884-CCVC 500.0 542.7 pg of Hg 109% 77-123

1200884-CCBF 3.74 pg of Hg

1200884-CCVD 500.0 541.2 pg of Hg 108% 77-123

1200884-CCBG 4.35 pg of Hg


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Client PO: SS12208


Sequence: 1200901

Method: EPA 1630Instrument: MMHG-09

Date: 12/06/2012

Total Mercury and Mercury Speciation by CVAFS

Analyte: MeHg

REC & LimitsResultTrue ValueLab ID Units1200901-IBL1 0.044 pg MeHg

1200901-IBL2 0.000 pg MeHg

1200901-IBL3 0.020 pg MeHg

1200901-CAL1 0.5000 0.469 pg MeHg 94%

1200901-CAL2 1.000 0.991 pg MeHg 99%

1200901-CAL3 2.000 2.040 pg MeHg 102%

1200901-CAL4 10.00 10.06 pg MeHg 101%

1200901-CAL5 50.00 48.73 pg MeHg 97%

1200901-CAL6 250.0 254.3 pg MeHg 102%

1200901-CAL7 1000 1061 pg MeHg 106%

1200901-CCB1 0.546 pg MeHg

1200901-ICV1 99.99 101.3 pg MeHg 101% 80-120

1200901-CCB2 0.762 pg MeHg

1200901-CCV1 25.00 23.95 pg MeHg 96% 67-133

1200901-CCB3 0.167 pg MeHg

1200901-CCB4 0.183 pg MeHg

1200901-CCB5 0.056 pg MeHg

1200901-CCV2 25.00 24.23 pg MeHg 97% 67-133

1200901-CCB6 0.052 pg MeHg

1200901-CCV3 25.00 24.60 pg MeHg 98% 67-133

1200901-CCB7 0.084 pg MeHg

1200901-CCV4 25.00 23.69 pg MeHg 95% 67-133

1200901-CCB8 0.00 pg MeHg

1200901-CCV5 25.00 22.70 pg MeHg 91% 67-133

1200901-CCB9 0.040 pg MeHg

1200901-CCV6 25.00 23.55 pg MeHg 94% 67-133

1200901-CCBA 0.064 pg MeHg

1200901-CCV7 25.00 23.21 pg MeHg 93% 67-133

1200901-CCBB 0.100 pg MeHg

1200901-CCV8 25.00 24.12 pg MeHg 96% 67-133

1200901-CCBC 0.080 pg MeHg


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Client PO: SS12208


Sequence: 1200911

Method: EPA 1640 RPInstrument: ICP-MS-2

Date: 12/08/2012

Trace Metals by ICP-MS

Analyte: As 75

REC & LimitsResultTrue ValueLab ID Units1200911-ICB1 0.00 µg/L

1200911-CAL1 0.2000 0.22 µg/L 108%

1200911-CAL2 0.4000 0.34 µg/L 85%

1200911-CAL3 2.000 1.97 µg/L 98%

1200911-CAL4 5.000 4.94 µg/L 99%

1200911-CAL5 10.00 10.48 µg/L 105%

1200911-CAL6 50.00 50.68 µg/L 101%

1200911-CAL7 100.0 102.5 µg/L 103%

1200911-CAL8 200.0 203.6 µg/L 102%

1200911-ICB2 -0.05 µg/L

1200911-ICV1 5.000 4.82 µg/L 96% 85-115

1200911-ICB3 -0.15 µg/L

1200911-IBL1 -0.12 µg/L

1200911-IBL2 -0.02 µg/L

1200911-IBL3 0.06 µg/L

1200911-IBL4 -0.01 µg/L

1200911-SCV1 60.45 59.67 µg/L 99% 75-125

1200911-CCV1 5.000 5.18 µg/L 104% 75-125

1200911-CCB1 0.08 µg/L

1200911-CCV2 5.000 5.15 µg/L 103% 75-125

1200911-CCB2 -0.22 µg/L

1200911-CCV3 5.000 4.99 µg/L 100% 75-125

1200911-CCB3 -0.03 µg/L

1200911-CCV4 5.000 5.06 µg/L 101% 75-125

1200911-CCB4 -0.15 µg/L

1200911-CCV5 5.000 5.15 µg/L 103% 75-125

1200911-CCB5 -0.07 µg/L

1200911-CCV6 5.000 5.24 µg/L 105% 75-125

1200911-CCB6 -0.17 µg/L

1200911-CCV7 10.00 10.91 µg/L 109% 75-125

1200911-CCB7 -0.05 µg/L

1200911-CCV8 10.00 10.75 µg/L 108% 75-125

1200911-CCB8 0.04 µg/L

1200911-CCV9 10.00 10.79 µg/L 108% 75-125

1200911-CCB9 0.06 µg/L


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Client PO: SS12208


Sequence: 1200911


Date: 12/08/2012


Analyte: Se 82


1200911-CAL2 0.4000 0.396 µg/L 99%

1200911-CAL3 2.000 2.098 µg/L 105%

1200911-CAL4 10.00 9.978 µg/L 100%

1200911-CAL5 20.00 19.78 µg/L 99%

1200911-CAL6 40.00 39.72 µg/L 99%

1200911-CAL7 100.0 99.27 µg/L 99%

1200911-CAL8 200.0 197.6 µg/L 99%

1200911-ICB2 0.350 µg/L

1200911-ICV1 10.00 9.251 µg/L 93% 85-115

1200911-ICB3 0.075 µg/L

1200911-IBL1 -0.110 µg/L

1200911-IBL2 -0.017 µg/L

1200911-IBL3 -0.121 µg/L

1200911-IBL4 -0.126 µg/L

1200911-SCV1 11.97 11.27 µg/L 94% 75-125

1200911-CCV1 10.00 10.26 µg/L 103% 75-125

1200911-CCB1 0.192 µg/L

1200911-CCV2 10.00 9.840 µg/L 98% 75-125

1200911-CCB2 0.136 µg/L

1200911-CCV3 10.00 10.06 µg/L 101% 75-125

1200911-CCB3 0.081 µg/L

1200911-CCV4 10.00 9.520 µg/L 95% 75-125

1200911-CCB4 -0.193 µg/L

1200911-CCV5 10.00 10.01 µg/L 100% 75-125

1200911-CCB5 -0.080 µg/L

1200911-CCV6 10.00 10.49 µg/L 105% 75-125

1200911-CCB6 -0.147 µg/L

1200911-CCV7 20.00 20.14 µg/L 101% 75-125

1200911-CCB7 -0.114 µg/L

1200911-CCV8 20.00 19.77 µg/L 99% 75-125

1200911-CCB8 0.024 µg/L

1200911-CCV9 20.00 19.78 µg/L 99% 75-125

1200911-CCB9 -0.057 µg/L


BRL Report 1245020

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Client PO: SS12208


Sequence: 1200911


Date: 12/08/2012


Analyte: Tl


1200911-CAL1 0.01000 0.010 µg/L 100%

1200911-CAL2 0.02000 0.020 µg/L 99%

1200911-CAL3 0.1000 0.100 µg/L 100%

1200911-CAL4 0.2500 0.257 µg/L 103%

1200911-CAL5 0.5000 0.506 µg/L 101%

1200911-CAL6 2.500 2.490 µg/L 100%

1200911-CAL7 5.000 4.947 µg/L 99%

1200911-CAL8 10.00 9.815 µg/L 98%

1200911-ICB2 0.0002 µg/L

1200911-ICV1 0.2500 0.238 µg/L 95% 85-115

1200911-ICB3 -0.0005 µg/L

1200911-IBL1 -0.0004 µg/L

1200911-IBL2 -0.001 µg/L

1200911-IBL3 -0.0005 µg/L

1200911-IBL4 -0.0009 µg/L

1200911-SCV1 7.445 7.557 µg/L 102% 75-125

1200911-CCV1 0.2500 0.263 µg/L 105% 75-125

1200911-CCB1 -0.0009 µg/L

1200911-CCV2 0.2500 0.258 µg/L 103% 75-125

1200911-CCB2 -0.001 µg/L

1200911-CCV3 0.2500 0.255 µg/L 102% 75-125

1200911-CCB3 -0.0009 µg/L

1200911-CCV4 0.2500 0.249 µg/L 100% 75-125

1200911-CCB4 -0.0006 µg/L

1200911-CCV5 0.2500 0.259 µg/L 104% 75-125

1200911-CCB5 -0.001 µg/L

1200911-CCV6 0.2500 0.259 µg/L 103% 75-125

1200911-CCB6 -0.0005 µg/L

1200911-CCV7 0.5000 0.516 µg/L 103% 75-125

1200911-CCB7 -0.0008 µg/L

1200911-CCV8 0.5000 0.509 µg/L 102% 75-125

1200911-CCB8 -0.0006 µg/L

1200911-CCV9 0.5000 0.516 µg/L 103% 75-125

1200911-CCB9 -0.0003 µg/L


BRL Report 1245020

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Client PO: SS12208


Sequence: 1200980

Method: EPA 1640 ColumnInstrument: ICP-MS-2

Date: 12/31/2012


Analyte: Cd 114

REC & LimitsResultTrue ValueLab ID Units1200980-ICB1 0.000 ng/L

1200980-CAL1 10.00 10.10 ng/L 101%

1200980-CAL2 20.00 19.77 ng/L 99%

1200980-CAL3 50.00 48.89 ng/L 98%

1200980-CAL4 100.0 100.4 ng/L 100%

1200980-CAL5 500.0 505.2 ng/L 101%

1200980-CAL6 1000 1014 ng/L 101%

1200980-CAL7 5000 4979 ng/L 100%

1200980-ICB2 6.177 ng/L

1200980-ICV1 50.00 56.77 ng/L 114% 85-115

1200980-ICB3 1.206 ng/L

1200980-IBL1 0.8324 ng/L

1200980-IBL2 0.7773 ng/L

1200980-IBL3 0.7528 ng/L

1200980-IBL4 0.7975 ng/L

1200980-SCV1 48.00 49.55 ng/L 103% 75-125

1200980-SCV2 21.50 16.89 ng/L 79% 75-125

1200980-CCV1 100.0 104.5 ng/L 104% 75-125

1200980-CCB1 0.8443 ng/L

1200980-CCV2 100.0 107.5 ng/L 107% 75-125

1200980-CCB2 1.292 ng/L

1200980-CCV3 100.0 107.0 ng/L 107% 75-125

1200980-CCB3 0.9485 ng/L

1200980-CCV4 100.0 108.6 ng/L 109% 75-125

1200980-CCB4 0.9286 ng/L

1200980-CCV5 100.0 105.4 ng/L 105% 75-125

1200980-CCB5 0.8685 ng/L

1200980-CCV6 100.0 119.7 ng/L 120% 75-125

1200980-CCB6 0.8738 ng/L

1200980-CCV7 500.0 587.2 ng/L 117% 75-125

1200980-CCB7 0.9000 ng/L


BRL Report 1245020

26 of 1040




Client PO: SS12208


Sequence: 1200980


Date: 12/31/2012


Analyte: Pb


1200980-CAL1 10.00 10.00 ng/L 100%

1200980-CAL2 20.00 19.86 ng/L 99%

1200980-CAL3 50.00 50.82 ng/L 102%

1200980-CAL4 100.0 100.2 ng/L 100%

1200980-CAL5 500.0 499.9 ng/L 100%

1200980-CAL6 1000 988.9 ng/L 99%

1200980-ICB2 9.948 ng/L

1200980-ICV1 250.0 260.5 ng/L 104% 85-115

1200980-ICB3 2.056 ng/L

1200980-IBL1 0.3237 ng/L

1200980-IBL2 0.5323 ng/L

1200980-IBL3 0.4962 ng/L

1200980-IBL4 0.5760 ng/L

1200980-SCV1 9.000 7.848 ng/L 87% 75-125

1200980-SCV2 11.00 9.645 ng/L 88% 75-125

1200980-CCV1 100.0 103.3 ng/L 103% 75-125

1200980-CCB1 2.058 ng/L

1200980-CCV2 100.0 106.6 ng/L 107% 75-125

1200980-CCB2 2.097 ng/L

1200980-CCV3 100.0 105.0 ng/L 105% 75-125

1200980-CCB3 1.860 ng/L

1200980-CCV4 100.0 108.2 ng/L 108% 75-125

1200980-CCB4 3.031 ng/L

1200980-CCV5 100.0 109.8 ng/L 110% 75-125

1200980-CCB5 3.182 ng/L

1200980-CCV6 100.0 122.4 ng/L 122% 75-125

1200980-CCB6 3.276 ng/L

1200980-CCV7 500.0 589.4 ng/L 118% 75-125

1200980-CCB7 3.039 ng/L


BRL Report 1245020

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Client PO: SS12208


Sequence: 1300016


Date: 01/06/2013


Analyte: Cu 65


1300016-CAL1 10.00 9.824 ng/L 98%

1300016-CAL2 20.00 21.13 ng/L 106%

1300016-CAL3 50.00 48.43 ng/L 97%

1300016-CAL4 100.0 96.37 ng/L 96%

1300016-CAL5 500.0 477.6 ng/L 96%

1300016-CAL6 1000 1020 ng/L 102%

1300016-CAL7 5000 5268 ng/L 105%

1300016-ICB2 203.7 ng/L

1300016-ICV1 500.0 537.3 ng/L 107% 85-115

1300016-ICB3 6.162 ng/L

1300016-IBL1 0.0072 ng/L

1300016-IBL2 -1.060 ng/L

1300016-IBL3 -2.705 ng/L

1300016-IBL4 -2.973 ng/L

1300016-SCV1 1550 1232 ng/L 79% 75-125

1300016-SCV2 380.0 337.4 ng/L 89% 75-125

1300016-CCV1 100.0 115.8 ng/L 116% 75-125

1300016-CCB1 5.536 ng/L

1300016-CCV2 100.0 173.2 ng/L 173% 75-125

1300016-CCB2 18.19 ng/L

1300016-CCV3 100.0 125.5 ng/L 126% 75-125

1300016-CCB3 3.045 ng/L

1300016-CCV4 100.0 127.3 ng/L 127% 75-125

1300016-CCB4 3.410 ng/L

1300016-CCV5 500.0 534.5 ng/L 107% 75-125

1300016-CCB5 13.35 ng/L

1300016-CCV6 500.0 592.5 ng/L 119% 75-125

1300016-CCB6 12.82 ng/L

1300016-CCV7 500.0 546.5 ng/L 109% 75-125

1300016-CCB7 7.067 ng/L

1300016-CCV8 500.0 586.5 ng/L 117% 75-125

1300016-CCB8 3.185 ng/L

1300016-CCV9 500.0 540.5 ng/L 108% 75-125

1300016-CCB9 1.548 ng/L


BRL Report 1245020

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Client PO: SS12208

Sample Containers

Lab ID: 1245020-01 Report Matrix: Great Salt Lake

Sample Type: Sample Received: 11/07/2012Sample: Site #9 Upper

Collected: 10/31/2012

Ship. Cont.pHP-LotPreservationLotSizeContainerDesA 71659890

20

Cooler1 mL 9N H2SO4 (PP) 1237045




Client PO: SS12208

Sample Containers


Sample Type: Sample Received: 11/07/2012Sample: Site #9 Lower


Ship. Cont.pHP-LotPreservationLotSizeContainerDesA 12-199 Cooler1% HNO3 1237106




Client PO: SS12208

Sample Containers


Sample Type: Sample Received: 11/07/2012Sample: Site #10 Lower


Ship. Cont.pHP-LotPreservationLotSizeContainerDesA 12-196 Cooler0.2% HNO3 1237106

BRL Report 1245020

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BRL Report 1245020

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BRL Report 1245020

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ANALYSIS SEQUENCE

Analysis STD ID CommentsDueOrder BRL Project #Lab Number

1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs

1200884-IBL1 QC 11200884 -

1200884-IBL2 QC 21200884 -

1200884-IBL3 QC 31200884 -

1200884-IBL4 QC 41200884 -

1200884-CAL1 QC 5 12450341200884 -

1200884-CAL2 QC 6 12450331200884 -

1200884-CAL3 QC 7 12450321200884 -

1200884-CAL4 QC 8 12450311200884 -

1200884-CAL5 QC 9 12450301200884 -

1200884-CAL6 QC 10 12450291200884 -

1200884-ICV1 QC 11 12450271200884 -

B122125-SRM1 QC 12B122125 -

B122176-SRM1 QC 13B122176 -

1200884-CCB1 QC 141200884 -

1200884-CCV1 QC 15 12450281200884 -

1200884-CCB2 QC 161200884 -

1200884-CCB3 QC 171200884 -

1200884-CCB4 QC 181200884 -

B122143-SRM3 QC 19B122143 -

1246013-09RE1 Hg-B-70:30-MERX-CVAFS 20 Added 11/26/2012 by MLHB122143 KLE-BE1201 11/26/2012

B122143-DUP4 QC 21B122143 1246013-09RE1

B122143-MS4 QC 22B122143 1246013-09RE1

B122143-MSD4 QC 23B122143 1246013-09RE1

1200884-CCV2 QC 24 12450281200884 -

1200884-CCB5 QC 251200884 -

1245015-02RE1 Hg-S-AR-MERX-CVAFS 26 Added 11/26/2012 by MLHB122128 AEC-AS1201 11/30/2012

Page 1 of 7Printed: 11/28/2012 3:51:09PM

BRL Report 1245020

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ANALYSIS SEQUENCE


1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs

B122128-DUP2 QC 27B122128 1245015-02RE1

B122128-MS2 QC 28B122128 1245015-02RE1

B122128-MSD2 QC 29B122128 1245015-02RE1

1245015-05RE1 Hg-S-AR-MERX-CVAFS 30 Added 11/26/2012 by MLHB122128 AEC-AS1201 11/30/2012

1246019-01RE1 Hg-S-AR-MERX-CVAFS 31 Added 11/26/2012 by MLHB122128 PSC-CL1201 12/3/2012

1246019-02RE1 Hg-S-AR-MERX-CVAFS 32 Added 11/26/2012 by MLHB122128 PSC-CL1201 12/3/2012

1200884-CCV3 QC 33 12450281200884 -

1200884-CCB6 QC 341200884 -

1244013-06RE2 Hg-W-BrCl-MERX-Diss 35 Added 11/27/2012 by ATCB122071 MAX-CA1202 1/1/1980

1244013-06RE2 Hg-W-BrCl-MERX-TR 36 Added 11/26/2012 by MLHB122071 MAX-CA1202 11/12/2012

B122071-MS8 QC 37B122071 1244013-06RE2

B122071-MSD8 QC 38B122071 1244013-06RE2

1200884-CCV4 QC 39 12450281200884 -

1200884-CCB7 QC 401200884 -

B122176-BLK1 QC 41B122176 -

B122176-BLK2 QC 42B122176 -

B122176-BLK3 QC 43B122176 -

B122176-BLK4 QC 44B122176 -

1247007-03 Hg-W-BrCl-MERX-TR 45B122176 DUK-HV1201 12/3/2012

1247007-04 Hg-W-BrCl-MERX-Diss 46B122176 DUK-HV1201 12/3/2012





1200884-CCV5 QC 51 12450281200884 -

1200884-CCB8 QC 521200884 -


BRL Report 1245020

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ANALYSIS SEQUENCE


1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs




1247007-01 Hg-W-BrCl-MERX-Diss 56 BatchQCB122176 DUK-HV1201 1/1/1980


B122176-MS1 QC 58B122176 1247007-01

B122176-MSD1 QC 59B122176 1247007-01



1200884-CCV6 QC 62 12450281200884 -

1200884-CCB9 QC 631200884 -

B122125-BLK1 QC 64B122125 -

B122125-BLK2 QC 65B122125 -

B122125-BLK3 QC 66B122125 -

B122125-BLK4 QC 67B122125 -

1246021-09 Hg-W-BrCl-MERX-TR 68B122125 DBE-RK1201 12/7/2012

1245005-26 Hg-W-BrCl-MERX-TR 69B122125 UDE-SL1201 12/20/2012

1246033-05 Hg-W-BrCl-MERX-NoMB-TR 70B122125 USA-AB1201 11/28/2012

1246033-05 Hg-W-BrCl-MERX-TR 71B122125 USA-AB1201 11/28/2012

1246032-02 Hg-W-BrCl-MERX-NoMB-TR 72 BatchQCB122125 CGP-GP1001 1/1/1980

1246032-02 Hg-W-BrCl-MERX-TR 73B122125 CGP-GP1001 12/11/2012

B122125-MS1 QC 74B122125 1246032-02

B122125-MSD1 QC 75B122125 1246032-02

1200884-CCV7 QC 76 12450281200884 -

1200884-CCBA QC 771200884 -



BRL Report 1245020

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ANALYSIS SEQUENCE


1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs

1246021-01 Hg-W-BrCl-MERX-NoMB-TR 79 BatchQCB122125 DBE-RK1201 1/1/1980


B122125-MS2 QC 81B122125 1246021-01

B122125-MSD2 QC 82B122125 1246021-01







1200884-CCV8 QC 89 12450281200884 -

1200884-CCBB QC 901200884 -


1245005-11 Hg-W-BrCl-MERX-NoMB-TR 92 BatchQCB122125 UDE-SL1201 1/1/1980


B122125-MS3 QC 94B122125 1245005-11

B122125-MSD3 QC 95B122125 1245005-11







1200884-CCV9 QC 102 12450281200884 -

1200884-CCBC QC 1031200884 -



BRL Report 1245020

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ANALYSIS SEQUENCE


1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs









1245020-06 Hg-W-BrCl-MERX-NoMB-TR 113 BatchQCB122125 UDE-SL1201 1/1/1980


1200884-CCVA QC 115 12450281200884 -

1200884-CCBD QC 1161200884 -

B122125-MS4 QC 117B122125 1245020-06

B122125-MSD4 QC 118B122125 1245020-06














BRL Report 1245020

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ANALYSIS SEQUENCE


1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs

B122125-MS5 QC 131B122125 1246033-06

1200884-CCVB QC 132 12450281200884 -

1200884-CCBE QC 1331200884 -

B122125-MSD5 QC 134B122125 1246033-06



















1200884-CCVC QC 153 12450281200884 -

1200884-CCBF QC 1541200884 -


1200884-CCVD QC 156 12450281200884 -


BRL Report 1245020

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ANALYSIS SEQUENCE


1200884

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs

1200884-CCBG QC 1571200884 -


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Peak ReportBatch Number: B122143, 2128, 2176, 2125

Method Number: CVAFS BR-0006Project Number(s): 1200884 Date Analyzed: 11/26/12Instrument ID: THG-05 Analyst Name: MLH

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes1 X S RINSE 1 11,473 -2.52 0.00 < HS accept

Notes

Date:Time:

11/26/1211:24 AM

Peak rt Area1 1.10 11,473

0

200

400

600

800

1,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes2 Y S RINSE 1 13,474 -2.32 0.00 < HS accept

Notes

Date:Time:

11/26/1211:31 AM


0

200

400

600

800

1,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes3 X IBL SEQ-IBL1 1 19,968 2.05 2.05 < 10 accept

Notes

Date:Time:

11/26/1211:38 AM


0

200

400

600

800

1,000

0 1 2

1

Page 1 of 46 (Peak Report)

Mercury Guru ver 4.6 © 1995-2011 Brooks Rand LLC

BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes4 Y IBL SEQ-IBL2 1 42,979 4.41 4.41 < 10 accept

Notes

Date:Time:

11/26/1211:45 AM


0

200

400

600

800

1,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes5 X IBL SEQ-IBL3 1 38,807 3.98 3.98 < 10 accept

Notes

Date:Time:

11/26/1211:52 AM


0

200

400

600

800

1,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes6 Y IBL SEQ-IBL4 1 42,373 4.35 4.35 < 10 accept

Notes

Date:Time:

11/26/1211:59 AM


0

200

400

600

800

1,000

0 1 2

1



BRL Report 1245020

50 of 1040



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes7 X STD SEQ-CAL1 1 132,747 9.93 99.3 75-125 accept

Notes

Date:Time:

11/26/1212:06 PM

Peak rt Area1 1.04 132,747

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes8 Y STD SEQ-CAL2 1 284,224 25.5 102 75-125 accept

Notes

Date:Time:

11/26/1212:13 PM

Peak rt Area1 1.04 284,224

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes9 X STD SEQ-CAL3 1 985,522 97.5 97.5 75-125 accept

Notes

Date:Time:

11/26/1212:20 PM

Peak rt Area1 1.04 985,522

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes10 Y STD SEQ-CAL4 1 4,709,213 480. 96.0 75-125 accept

Notes

Date:Time:

11/26/1212:27 PM

Peak rt Area1 1.04 4,709,213

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes11 X STD SEQ-CAL5 1 25,388,100 2,600 104 75-125 accept

Notes

Date:Time:

11/26/1212:34 PM

Peak rt Area1 1.03 25,388,100

0

100,000

200,000

300,000

400,000

500,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes12 Y STD SEQ-CAL6 1 98,996,648 10,200 102 75-125 accept

Notes

Date:Time:

11/26/1212:41 PM

Peak rt Area1 1.00 98,996,648

0

400,000

800,000

1,200,000

1,600,000

2,000,000

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes13 X ICV SEQ-ICV1 1 15,517,142 1,590 101 85-115 accept

Notes

Date:Time:

11/26/1212:48 PM

Peak rt Area1 1.04 15,517,142

0

100,000

200,000

300,000

400,000

500,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes14 Y CCB SEQ-CCB 1 79,958 8.21 8.21 < 10 accept

Notes

Date:Time:

11/26/1212:55 PM


-100

100

300

500

700

900

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes15 X CCV SEQ-CCV 1 5,192,671 530. 106 77-123 accept

Notes

Date:Time:

11/26/121:02 PM

Peak rt Area1 1.04 5,192,671

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/121:09 PM


-100

100

300

500

700

900

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes17 X CCB SEQ-CCB 1 39,898 4.10 4.10 < 10 accept

Notes

Date:Time:

11/26/121:16 PM


-100

100

300

500

700

900

0 1 2

1


Notes

Date:Time:

11/26/121:23 PM


-100

100

300

500

700

900

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes19 X S B122143-SRM3 1 20,145,781 2,060 0.00 < HS accept

Notes

Date:Time:

11/26/121:30 PM

Peak rt Area1 1.03 20,145,781

0

100,000

200,000

300,000

400,000

500,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes20 Y S 1246013-09RE1 1 640,340 62.1 0.00 < HS accept

Notes

Date:Time:

11/26/121:37 PM

Peak rt Area1 1.04 640,340

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes21 X S B122143-DUP4 1 627,670 60.8 0.00 < HS accept

Notes

Date:Time:

11/26/121:44 PM

Peak rt Area1 1.05 627,670

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1



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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes22 Y S B122143-MS4 1 44,783,524 4,590 0.00 < HS accept

Notes

Date:Time:

11/26/121:51 PM

Peak rt Area1 1.02 44,783,524

0

100,000

200,000

300,000

400,000

500,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes23 X S B122143-MSD4 1 41,658,296 4,270 0.00 < HS accept

Notes

Date:Time:

11/26/121:58 PM

Peak rt Area1 1.02 41,658,296

0

100,000

200,000

300,000

400,000

500,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes24 Y CCV SEQ-CCV 1 5,011,102 511 102 77-123 accept

Notes

Date:Time:

11/26/122:05 PM

Peak rt Area1 1.05 5,011,102

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/122:12 PM


-200

0

200

400

600

800

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes26 Y S 1245015-02RE1 1 1,614,723 162 0.00 < HS accept

Notes

Date:Time:

11/26/122:19 PM

Peak rt Area1 1.05 1,614,723

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes27 X S B122128-DUP2 1 1,545,458 155 0.00 < HS accept

Notes

Date:Time:

11/26/122:26 PM

Peak rt Area1 1.04 1,545,458

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes28 Y S B122128-MS2 1 1,761,864 177 0.00 < HS accept

Notes

Date:Time:

11/26/122:33 PM

Peak rt Area1 1.04 1,761,864

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes29 X S B122128-MSD2 1 1,653,988 166 0.00 < HS accept

Notes

Date:Time:

11/26/122:40 PM

Peak rt Area1 1.05 1,653,988

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes30 Y S 1245015-05RE1 1 4,842,089 494 0.00 < HS accept

Notes

Date:Time:

11/26/122:47 PM

Peak rt Area1 1.04 4,842,089

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes31 X S 1246019-01RE1 1 582,976 56.2 0.00 < HS accept

Notes

Date:Time:

11/26/122:54 PM

Peak rt Area1 1.05 582,976

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes32 Y S 1246019-02RE1 1 375,953 34.9 0.00 < HS accept

Notes

Date:Time:

11/26/123:01 PM

Peak rt Area1 1.06 375,953

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes33 X CCV SEQ-CCV 1 5,250,548 535 107 77-123 accept

Notes

Date:Time:

11/26/123:08 PM

Peak rt Area1 1.05 5,250,548

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/123:15 PM


-300

-100

100

300

500

700

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes35 X S 1244013-06RE2 1 70,226 3.51 0.00 < HS accept

Notes

Date:Time:

11/26/123:22 PM


-300

-100

100

300

500

700

0 1 2

1


Notes

Date:Time:

11/26/123:29 PM

Peak rt Area1 1.04 2,114,784

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/123:36 PM

Peak rt Area1 1.05 2,112,120

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes38 Y CCV SEQ-CCV 1 5,375,340 548 110. 77-123 accept

Notes

Date:Time:

11/26/123:43 PM

Peak rt Area1 1.04 5,375,340

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1


Notes

Date:Time:

11/26/123:50 PM


-300

-100

100

300

500

700

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes40 Y S B122176-BLK1 1 58,991 2.36 0.00 < HS accept

Notes

Date:Time:

11/26/123:57 PM


-300

-100

100

300

500

700

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes41 X S B122176-BLK2 1 53,520 1.80 0.00 < HS accept

Notes

Date:Time:

11/26/124:04 PM


-300

-100

100

300

500

700

0 1 2

1


Notes

Date:Time:

11/26/124:11 PM


-300

-100

100

300

500

700

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/124:18 PM


-300

-100

100

300

500

700

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes44 Y S 1247007-03 1 57,797 2.23 0.00 < HS accept

Notes

Date:Time:

11/26/124:25 PM


-300

-100

100

300

500

700

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes45 X S 1247007-04 1 54,623 1.91 0.00 < HS accept

Notes

Date:Time:

11/26/124:32 PM


-300

-100

100

300

500

700

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/124:39 PM


-300

-100

100

300

500

700

0 1 2

1


Notes

Date:Time:

11/26/124:46 PM


-300

-100

100

300

500

700

0 1 2

1


Notes

Date:Time:

11/26/124:53 PM


-300

-100

100

300

500

700

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/125:00 PM


-300

-100

100

300

500

700

0 1 2

1


Notes

Date:Time:

11/26/125:07 PM

Peak rt Area1 1.04 5,319,827

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1


Notes

Date:Time:

11/26/125:14 PM


-300

-100

100

300

500

700

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes52 Y S 1247007-09 1 1,558,321 156 0.00 < HS accept

Notes

Date:Time:

11/26/125:21 PM

Peak rt Area1 1.04 1,558,321

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1


Notes

Date:Time:

11/26/125:28 PM

Peak rt Area1 1.04 264,311

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1


Notes

Date:Time:

11/26/125:35 PM

Peak rt Area1 1.04 786,262

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes55 X S 1247007-01 1 1,188,404 118 0.00 < HS accept

Notes

Date:Time:

11/26/125:42 PM

Peak rt Area1 1.03 1,188,404

0

5,000

10,000

15,000

20,000

25,000

0 1 2

1


Notes

Date:Time:

11/26/125:49 PM

Peak rt Area1 1.02 6,421,980

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1


Notes

Date:Time:

11/26/125:56 PM

Peak rt Area1 1.02 6,423,519

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes58 Y S 1247007-02 1 3,430,018 349 0.00 < HS accept

Notes

Date:Time:

11/26/126:03 PM

Peak rt Area1 1.03 3,430,018

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes59 X S 1247007-05 1 3,243,064 329 0.00 < HS accept

Notes

Date:Time:

11/26/126:10 PM

Peak rt Area1 1.02 3,243,064

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes60 Y ICV SEQ-CCV 1 5,280,088 538 108 85-115 accept

Notes

Date:Time:

11/26/126:17 PM

Peak rt Area1 1.02 5,280,088

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/126:24 PM


-200

0

200

400

600

800

0 1 2

1


Notes

Date:Time:

11/26/126:31 PM


-200

0

200

400

600

800

0 1 2

1


Notes

Date:Time:

11/26/126:38 PM


-200

0

200

400

600

800

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/126:45 PM


-200

0

200

400

600

800

0 1 2

1


Notes

Date:Time:

11/26/126:52 PM


-200

0

200

400

600

800

0 1 2

1


Notes

Date:Time:

11/26/126:59 PM


-200

0

200

400

600

800

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/127:06 PM

Peak rt Area1 1.03 137,946

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1


Notes

Date:Time:

11/26/127:13 PM

Peak rt Area1 1.03 172,771

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1


Notes

Date:Time:

11/26/127:20 PM

Peak rt Area1 1.03 274,330

0

1,000

2,000

3,000

4,000

5,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/127:27 PM

Peak rt Area1 1.03 6,450,644

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1


Notes

Date:Time:

11/26/127:34 PM

Peak rt Area1 1.02 6,438,335

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1


Notes

Date:Time:

11/26/127:41 PM

Peak rt Area1 1.02 5,238,779

0

20,000

40,000

60,000

80,000

100,000

0 1 2

1



BRL Report 1245020

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Notes

Date:Time:

11/26/127:48 PM


-200

0

200

400

600

800

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes74 Y S 1246032-03 1 29,405,240 3,020 0.00 < HS accept

Notes

Date:Time:

11/26/127:55 PM

Peak rt Area1 1.01 29,405,240

0

100,000

200,000

300,000

400,000

500,000

0 1 2

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Fina

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