research needs in subsurface science · mary lou zoback, u.s. geological survey, menlo park,...
TRANSCRIPT
U.S. Department of Energy’sEnvironmental Management Science Program
Board on Radioactive Waste ManagementWater Science and Technology Board
National Research Council
NATIONAL ACADEMY PRESSWashington, D.C.
i
RREESSEEAARRCCHH NNEEEEDDSS IINN
SSUUBBSSUURRFFAACCEE SSCCIIEENNCCEE
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
NOTICE: The project that is the subject of this report was approved by theGoverning Board of the National Research Council, whose members are drawnfrom the councils of the National Academy of Sciences, the National Academyof Engineering, and the Institute of Medicine. The members of the committeeresponsible for the report were chosen for their special competences and withregard for appropriate balance.
This study was supported by Contract/Grant No DE-FC01-94EW54069/Rbetween the National Academy of Sciences and The U.S. Department ofEnergy. Any opinions, findings, conclusions, or recommendations expressed inthis publication are those of the author(s) and do not necessarily reflect theviews of the organizations or agencies that provided support for the project.
International Standard Book Number 0-309-06646-8
Additional copies of this report are available from National Academy Press,2101 Constitution Avenue, N.W., Lockbox 285, Washington, D.C. 20055; (800)624-6242 or (202) 334-3313 (in the Washington metropolitan area); Internet:http://www.nap.edu
COVER IMAGE: Mercury contamination in soil at the Y-12 plant at the OakRidge Reservation. The mercury is visible as small droplets in the dark layernear the center of the photograph. SOURCE: Oak Ridge Reservation.
Printed in the United States of America
Copyright 2000 by the National Academy of Sciences. All rights reserved.
iiCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
The National Academy of Sciences is a private, nonprofit, self-perpetuating soci-ety of distinguished scholars engaged in scientific and engineering research, ded-icated to the furtherance of science and technology and to their use for the gen-eral welfare. Upon the authority of the charter granted to it by the Congress in1863, the Academy has a mandate that requires it to advise the federal govern-ment on scientific and technical matters. Dr. Bruce M. Alberts is president of theNational Academy of Sciences.
The National Academy of Engineering was established in 1964, under the char-ter of the National Academy of Sciences, as a parallel organization of outstand-ing engineers. It is autonomous in its administration and in the selection of itsmembers, sharing with the National Academy of Sciences the responsibility foradvising the federal government. The National Academy of Engineering alsosponsors engineering programs aimed at meeting national needs, encourageseducation and research, and recognizes the superior achievements of engineers.Dr. William A. Wulf is president of the National Academy of Engineering.
The Institute of Medicine was established in 1970 by the National Academy ofSciences to secure the services of eminent members of appropriate professions inthe examination of policy matters pertaining to the health of the public. TheInstitute acts under the responsibility given to the National Academy of Sciencesby its congressional charter to be an adviser to the federal government and, uponits own initiative, to identify issues of medical care, research, and education. Dr.Kenneth I. Shine is president of the Institute of Medicine.
The National Research Council was organized by the National Academy ofSciences in 1916 to associate the broad community of science and technologywith the Academy’s purposes of furthering knowledge and advising the federalgovernment. Functioning in accordance with general policies determined by theAcademy, the Council has become the principal operating agency of both theNational Academy of Sciences and the National Academy of Engineering in pro-viding services to the government, the public, and the scientific and engineeringcommunities. The Council is administered jointly by both Academies and theInstitute of Medicine. Dr. Bruce M. Alberts and Dr. William A. Wulf are chairmanand vice chairman, respectively, of the National Research Council.
iii
National Academy of SciencesNational Academy of EngineeringInstitute of MedicineNational Research Council
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
COMMITTEE ON SUBSURFACE CONTAMINATION AT DOE COMPLEX SITES
JANE C. S. LONG, Chair, University of Nevada, RenoJAMES K. MITCHELL, Vice-Chair, Virginia Polytechnic Institute and State
University, BlacksburgRANDALL J. CHARBENEAU, University of Texas, AustinJEFFREY J. DANIELS, Ohio State University, ColumbusJOHN N. FISCHER, Hydrologic Consultant, Oakton, VirginiaTISSA H. ILLANGASEKARE, Colorado School of Mines, GoldenAARON L. MILLS, University of Virginia, CharlottesvilleDONALD T. REED, Argonne National Laboratory, Chicago, IllinoisJEROME SACKS, National Institute of Statistical Sciences, Research Triangle
Park, North CarolinaBRIDGET R. SCANLON, University of Texas, AustinLEON T. SILVER, California Institute of Technology, PasadenaCLAIRE WELTY, Drexel University, Philadelphia, Pennsylvania
STAFF
KEVIN D. CROWLEY, Study DirectorSTEPHEN D. PARKER, Director, Water Science and Technology Board SUSAN B. MOCKLER, Research AssociatePATRICIA A. JONES, Senior Project Assistant
ivCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
BOARD ON RADIOACTIVE WASTE MANAGEMENT
MICHAEL C. KAVANAUGH, Chair, Malcolm Pirnie, Inc., Oakland, CaliforniaJOHN F. AHEARNE, Co-Chair, Sigma Xi and Duke University, Research
Triangle Park, North CarolinaCHARLES MCCOMBIE, Vice-Chair, Gipf-Oberfrick, SwitzerlandROBERT J. BUDNITZ, Future Resources Associates, Inc., Berkeley, CaliforniaMARY R. ENGLISH, University of Tennessee, Knoxville, TennesseeDARLEANE C. HOFFMAN, Lawrence Berkeley National Laboratory, Oakland,
CaliforniaJAMES H. JOHNSON, JR., Howard University, Washington, D.C.ROGER E. KASPERSON, Clark University, Worcester, MassachusettsJAMES O. LECKIE, Stanford University, Stanford, CaliforniaJANE C. S. LONG, Mackay School of Mines, University of Nevada, RenoCHARLES MCCOMBIE, Consultant, Gipf-Oberfrick, SwitzerlandWILLIAM A. MILLS, Oak Ridge Associated Universities (retired), Olney,
MarylandD. WARNER NORTH, NorthWorks, Inc., Mountain View, CaliforniaMARTIN J. STEINDLER, Argonne National Laboratories (retired), Argonne,
IllinoisJOHN J. TAYLOR, Electric Power Research Institute (retired), Palo Alto,
CaliforniaMARY LOU ZOBACK, U.S. Geological Survey, Menlo Park, California
STAFF
KEVIN D. CROWLEY, DirectorROBERT S. ANDREWS, Senior Staff OfficerTHOMAS KIESS, Senior Staff OfficerGREGORY H. SYMMES, Senior Staff OfficerJOHN R. WILEY, Senior Staff OfficerSUSAN B. MOCKLER, Research AssociateTONI GREENLEAF, Administrative AssistantLATRICIA C. BAILEY, Senior Project AssistantPATRICIA A. JONES, Senior Project AssistantANGELA R. TAYLOR, Senior Project Assistant LATRICIA C. BAILEY, Project AssistantMATTHEW BAXTER-PARROT, Project AssistantLAURA D. LLANOS, Project Assistant
vCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
WATER SCIENCE AND TECHNOLOGY BOARD
HENRY J. VAUX, JR., Chair, University of California, RiversideCAROL A. JOHNSTON, Vice -Chair, University of Minnesota, DuluthRICHELLE M. ALLEN-KING, Washington State University, PullmanGREGORY B. BAECHER, University of Maryland, College ParkJOHN S. BOYER, University of Delaware, LewesJOHN BRISCOE, The World Bank, Washington, D.C.DENISE FORT, University of New Mexico, AlbuquerqueSTEVEN P. GLOSS, University of Wyoming, LaramieEVILLE GORHAM, University of Minnesota, St. PaulWILLIAM A. JURY, University of California, RiversideGARY S. LOGSDON, Black & Veatch, Cincinnati, OhioRICHARD G. LUTHY, Carnegie Mellon University, Pittsburgh, PennsylvaniaJOHN W. MORRIS, J. W. Morris, Arlington, VirginiaPHILLIP A. PALMER, DuPont Engineering, Wilmington, DelawareREBECCA T. PARKIN, The George Washington University, Washington, D.C.JOAN B. ROSE, University of South Florida, St. PetersburgRHODES TRUSSELL, Montgomery Watson, Inc., Pasadena, CaliforniaERIC F. WOOD, Princeton University, Princeton, New Jersey
STAFF
STEPHEN D. PARKER, DirectorJACQUELINE MACDONALD, Associate DirectorCHRIS ELFRING, Senior Staff OfficerLAURA EHLERS, Senior Staff OfficerJEFFREY W. JACOBS, Staff OfficerWILLIAM S. LOGAN, Staff OfficerJEANNE AQUILINO, Administrative AssociateMARK GIBSON, Research AssociateANITA A. HALL, Administrative AssistantELLEN de GUZMAN, Senior Project AssistantANIKÉ L. JOHNSON, Project Assistant
viCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
COMMISSION ON GEOSCIENCES, ENVIRONMENT, AND RESOURCES
GEORGE M. HORNBERGER, Chair, University of Virginia, CharlottesvilleRICHARD A. CONWAY, Union Carbide Corporation (retired), S. Charleston,
West VirginiaLYNN GOLDMAN, Johns Hopkins School of Hygiene and Public Health,
Baltimore, MarylandTHOMAS E. GRAEDEL, Yale University, New Haven, ConnecticutTHOMAS J. GRAFF, Environmental Defense Fund, Oakland, CaliforniaEUGENIA KALNAY, University of Maryland, College ParkDEBRA KNOPMAN, Progressive Policy Institute, Washington, D.C.BRAD MOONEY, J. Brad Mooney Associates, Ltd., Arlington, VirginiaHUGH C. MORRIS, El Dorado Gold Corporation, Vancouver, British
ColumbiaH. RONALD PULLIAM, University of Georgia, AthensMILTON RUSSELL, Joint Institute for Energy and Environment and University
of Tennessee (Emeritus),KnoxvilleROBERT J. SERAFIN, National Center for Atmospheric Research, Boulder,
ColoradoANDREW R. SOLOW, Woods Hole Oceanographic Institution, Woods Hole,
Massachusetts E-AN ZEN, University of Maryland, College ParkMARY LOU ZOBACK, U.S. Geological Survey, Menlo Park, California
STAFF
ROBERT M. HAMILTON, Executive DirectorGREGORY H. SYMMES, Associate Executive DirectorJEANETTE SPOON, Administrative and Financial OfficerDAVID FEARY, Scientific Reports OfficerSANDI FITZPATRICK, Administrative AssociateMARQUITA SMITH, Administrative Assistant/Technology Analyst
viiCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
viiiCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Preface
The development of this report has provided an opportunity forcommittee members to examine and obtain an overview of a majornational environmental issue—subsurface contamination in the DOEcomplex. The committee faced a daunting task in making recommen-dations to the Environmental Management Science Program aboutfuture research emphases to address DOE’s subsurface contaminationproblems. To do this, we needed to obtain an overview of the problemsand a detailed understanding of the major clean-up issues. In addition,we needed to understand how the Environmental Management ScienceProgram had developed so far, whether it related well to the problemsas we understood them, and its relationship to environmental remedia-tion research done elsewhere. Finally, we were to complete this task inapproximately one year with a limited number of site visits.
Clearly, we could never have accomplished this task without thecomplete cooperation of the DOE and National Laboratory staff. Weowe major thanks to a large number of persons (see Appendix B) whoprepared presentations and organized visits that informed our process.A great deal of effort was spent to support us, and I would like to thankall of these people for their frankness and insights. I would especiallylike to recognize the efforts of Mark Gilbertson and Roland Hirsch fromDOE headquarters; Roy Gephart, John Zacara, and Karl Fecht fromHanford; Tom Williams from the Idaho National Engineering andEnvironmental Laboratory; and Tom Hicks and Tom Temples fromSavannah River for their support of the committee.
I have served on a number of excellent National Research Councilcommittees, but I found the support provided by committee staff on thisstudy was beyond any level of service I have ever experienced. Studydirector Kevin Crowley made this difficult task possible. Without hisunderstanding, sense of group dynamics, and very significant level ofeffort there would have been no possibility of finishing this report. Wewere also provided excellent research and logistical support by the staffof the Board on Radioactive Waste Management and Water Science
P r e f a c e
ixCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
and Technology Board, most notably Steve Parker, Patricia Jones, andSusan Mockler.
We were greatly privileged to have Jim Mitchell serve as the com-mittee’s vice-chair. Jim was the conscience of the committee andplayed a critical role in keeping us on course throughout our delibera-tions. His careful analysis, insight, and review provided quality to ourproduct. It was a great treat to work with Jim.
Normal committee dynamics are such that a few people do a dis-proportionate share of the work. This committee was an exception tothat rule; the members all contributed and all did the assignments wegave them. The committee was unusually productive and creative, andits members contributed not only their knowledge and understanding,but they also listened to others and incorporated this information into aconsensus. I learned a great deal from my committee colleagues, andmy sense is that the entire committee found the process beneficial.
The committee’s review left some very clear impressions concerningthe scope of DOE’s subsurface contamination problems. As noted inChapter 2 of this report, the committee concluded that much of thecontamination that is now in the subsurface at major DOE sites will notbe removed by any active remediation efforts. The huge scale of the“environmental insult” (to quote committee member Lee Silver) and theextraction of contamination on the scales required would require amajor decrease in entropy and would simply not be possible. Thismeans that a major focus of coming to terms with the problem has tobe understanding, predicting, and containing the subsurface contamina-tion. These issues are paramount in site closure. They have receivedinsufficient attention from the EMSP in the past and are a major focusof this report.
Secondly, the committee recognized that the amount of contamina-tion that is contained in surface and near-surface facilities at DOE sitesis massive compared to that which has already leaked into the subsur-face. Millions of gallons of waste and millions of curies of radioactivityare currently in storage at DOE sites and, if this waste is not managedcorrectly, it could potentially become a major source of future sub-surface contamination. Clearly, an important lesson DOE can learnfrom its current subsurface contamination problems is to not repeat themistakes of the past. It is true that DOE no longer places high-levelnuclear waste in barrels that are dumped into topographic lows (seeSidebar 2.5), but DOE is placing new land disposal facilities in regionsthat have generated massive contaminant plumes in the past (see, forexample, Sidebar 2.9). During the course of this study, the committeesaw no institutional process to address the question, “How should theresults and impacts of what was done in the past inform the decisions
S U B S U R F A C E S C I E N C E
xCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
of the future?” The committee recognizes that DOE cannot changewhat was done in the past. DOE can, however, make better decisionsin the future. The committee believes that a very important role forresearch sponsored by the Environmental Management ScienceProgram is to provide the information DOE will need to make techni-cally sound and responsible waste management decisions in the future.
Jane C. S. Long, Chair
xi
P r e f a c eCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
xiiCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
List of Report Reviewers
This report has been reviewed in draft form by individuals chosenfor their diverse perspectives and technical expertise, in accordancewith procedures approved by the NRC’s Report Review Committee. Thepurpose of this independent review is to provide candid and criticalcomments that will assist the institution in making the published reportas sound as possible and to ensure that the report meets institutionalstandards for objectivity, evidence, and responsiveness to the studycharge. The review comments and draft manuscript remain confidentialto protect the integrity of the deliberative process. We wish to thank thefollowing individuals for their participation in the review of this report:
Susan Brantley, Pennsylvania State UniversityHelen Dawson, U.S. Environmental Protection AgencyJohn Fountain, State University of New YorkRobert Huggett, Michigan State UniversityPhilip Palmer, DuPont (retired)Frank Schwartz, Ohio State UniversityJohn Taylor, Electric Power Research Institute (retired)Peter Wierenga, University of Arizona
Although the reviewers listed above have provided many construc-tive comments and suggestions, they were not asked to endorse theconclusions or recommendations, nor did they see the final draft of thereport before its release. The review of this report was overseen byGeorge Hornberger, appointed by the Commission on Geosciences,Environment, and Resources, and Paul Barton, appointed by the ReportReview Committee, who were responsible for making certain that anindependent examination of this report was carried out in accordancewith NRC procedures and that all review comments were carefully con-sidered. Responsibility for the final content of this report rests entirelywith the authoring committee and the NRC.
xiii
L i s t o f R e p o r t R e v i e w e r sCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Contents
Summary 1
1 Introduction and Task 11
2 Subsurface Contamination in the DOE Complex 15
3 Assessment of the EM Science Program Portfolio 47
4 Research Programs in Other Agencies of Government 59
5 Knowledge Gaps and Research Needs 93
6 Recommendations for a Long-Term Research Program 115
References 131
AppendixesA Description of the Environmental Management Science Program 137B List of Presentations 139C Biographical Sketches of Committee Members 141D Additional Resources 145E Interim Report 149F Acronym List 159
C o n t e n t s
xvCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
xvii
RREESSEEAARRCCHH NNEEEEDDSS IINN SSUUBBSSUURRFFAACCEE SSCCIIEENNCCEE
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
xviiiCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Summary
In the spring of 1998, the U.S. Department of Energy (DOE) request-ed that the National Academies convene a committee of experts to pro-vide recommendations on the formulation of a long-term basic researchprogram to address subsurface contamination problems at DOE sites(see Sidebar 1.1 in Chapter 1). In response to this request, a committeewith expertise in basic research and research management was formedunder the joint auspices of the National Research Council’s Board onRadioactive Waste Management and Water Science and TechnologyBoard. A summary of the committee’s information-gathering activitiesand its conclusions and recommendations are presented in this report.
The report provides an overview of the subsurface contaminationproblems across the DOE complex and shows by examples from the sixlargest DOE sites (Hanford Site, Idaho Engineering and EnvironmentalLaboratory, Nevada Test Site, Oak Ridge Reservation, Rocky FlatsEnvironmental Technology Site, and Savannah River Site) how advancesin scientific and engineering knowledge can improve the effectivenessof the cleanup effort (see Chapter 2). The committee analyzed the cur-rent Environmental Management (EM) Science Program portfolio of sub-surface research projects (see Chapter 3) to assess the extent to whichthe program is focused on DOE’s contamination problems. This analy-sis employs an organizing scheme that provides a direct linkagebetween basic research in the EM Science Program and applied tech-nology development in DOE’s Subsurface Contaminants Focus Area.The committee also reviewed related research programs in other DOEoffices and other federal agencies (see Chapter 4) to determine theextent to which they are focused on DOE’s subsurface contaminationproblems. On the basis of these analyses, the report singles out thehighly significant subsurface contamination knowledge gaps andresearch needs that the EM Science Program must address if the DOEcleanup program is to succeed.
S u m m a r y
1Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Subsur face Contaminat ion at DOE S i tesNuclear weapons production has resulted in the contamination of
the large DOE sites. This contamination exists today in a wide range offorms and locations—including contaminated waste burial grounds;contaminated soil, sediment, and rock; and contaminated groundwa-ter—and is frequently difficult to locate, characterize, and remediate.Significant amounts of subsurface contaminants are likely to remaineven after DOE’s cleanup program is completed.
The committee concluded that subsurface contamination is an enor-mously difficult cleanup problem that represents a potentially largefuture mortgage for the nation. This mortgage could, however, bereduced significantly through the development and application of newand improved technologies. The development of such technologies willrequire advances in basic understanding of the complex natural systemsat DOE sites and the nature of the contaminants there. Given the long-term nature of the cleanup mission and its projected cost—the programis planned to last until 2070 and cost on the order of $200 billion—thecommittee believes that DOE has sufficient time to do the basicresearch required to support the development and deployment of newcleanup technologies.
EM Sc ience Program Research Por t fo l ioSince its establishment by Congress, the program has held four pro-
posal competitions and has awarded about $225 million in funding,which puts it among the largest environmental research efforts in thefederal government. The program has supported research projects rele-vant to many aspects of DOE’s cleanup program, including subsurfacecontamination, high-level waste, and deactivation and decommission-ing. The committee reviewed the research portfolio for fiscal years1996 and 1997 and identified 91 projects that were relevant to DOE’ssubsurface contamination problems. The committee’s review revealedsome significant areas of strength. Fifty projects address organic conta-mination problems and 38 projects use a combination of field-, labora-tory-, and modeling-based approaches. There appears to be a criticalmass of projects covering remediation of subsurface contamination,especially treatment and destruction of organic contaminants throughphysical, chemical, and biological processes.
S U B S U R F A C E S C I E N C E
2
Significant amounts of subsurface contami-nants are likely toremain even after DOE’scleanup program iscompleted.
Given the long-termnature of the cleanupmission and its project-ed cost . . . the commit-tee believes that DOEhas sufficient time todo the basic researchrequired to support the development anddeployment of newcleanup technologies.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
The most notable gaps in the current portfolio concern containmentand validation.1 These are two of the most significant problem areas inthe DOE complex, because it is inevitable that DOE will have to man-age much of its subsurface contamination in place. There also appearto be relatively few projects that address radionuclide and metal conta-mination problems.
Research Programs in O therGovernment Agencies
The committee gathered information on research programs in otherDOE offices and other federal agencies to assess how they might con-tribute to solving DOE’s subsurface contamination problems. The com-mittee made the following observations in Chapter 4:
• The federal government is a major sponsor of basic research thatis related either directly or indirectly to environmental problems.The committee identified almost 50 such programs in its survey(see Table 4.1).
• A large number and variety of programs across the federal gov-ernment support research of direct relevance to the EM ScienceProgram and DOE cleanup. The committee identified 18 suchprograms, many of which are focused on hazardous chemicals,especially volatile organic contaminants and non-aqueous phaseliquids, and to a lesser extent on heavy metals. Many of these pro-grams are also focused on remediation, especially bioremediation.
• With some notable exceptions, there appears to be significantoverlap in scope among these 18 programs. It does not appear tothe committee that these programs are being coordinated effec-tively among the agencies.
The committee concluded that there would be value-added to theEM Science Program and, ultimately, to DOE’s cleanup efforts if therewere better interagency coordination among these 18 research pro-grams. The committee sees an opportunity for EM Science Programmanagers to promote and foster such coordination.
3
S u m m a r y
1The term "validation" is used to describe processes for testing a conceptual orpredictive model to determine whether it adequately represents the system behaviorof interest, and it is also applied to monitoring and testing to confirm the effective-ness of remediation actions. See Chapter 5.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Formulat ion of a Long-Term ResearchProgram
The committee’s recommendations for a long-term basic researchprogram on subsurface contamination address the following issues:
• program vision,• research emphases, and • implementation.
The principal conclusions and recommendations are summarizedbelow. Additional details can be found in Chapters 5 and 6.
Program VisionThe EM Science Program has been in existence for almost four
years, but there does not appear to be a clear and agreed-upon visionfor this program within DOE. If the program is to remain viable overthe long term and to have a significant impact on the DOE cleanupmission, program managers must articulate a vision for the program thatis supported both programmatically and financially by DOE uppermanagement. The committee recommends that this vision include thefollowing four elements:
1. The program objective should be to generate new knowledge tosupport DOE’s mission to clean up its contaminated sites.
2. The program should be well connected to DOE’s difficultcleanup problems.
3. A major focus of the program should continue to be on researchto resolve DOE’s subsurface contamination problems.
4. The program should have a long-term, multidisciplinary basicresearch2 focus.
The committee defines “long term” as long enough to set ambitiousgoals to fill the knowledge gaps identified in Chapter 5 and to have rea-sonable expectations that those goals can be attained. In the commit-tee’s judgment, a time horizon on the order of a decade will berequired to make cumulative progress on the knowledge gaps identifiedin Chapter 5, although shorter-term results of use to DOE’s cleanup pro-gram will almost certainly be obtained over the lifetimes of individualresearch projects.
S U B S U R F A C E S C I E N C E
4
2Basic research creates new generic knowledge and is focused on long-term,rather than short-term, problems. See Sidebar 1.1 in Chapter 1.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Research EmphasesThere are significant impediments to the successful completion of
DOE’s cleanup mission that can be removed through a focused, sus-tained, and adequately funded basic research program. Based on theanalysis of DOE’s subsurface contamination problems in Chapters 2and 5, the committee recommends that the subsurface component ofthe EM Science Program have the following four research emphases:
1. Location and characterization of subsurface contaminants andcharacterization of the subsurface. Basic research that supportsadvances in capabilities to locate and characterize subsurfacecontamination and elucidate relevant subsurface conditions willhelp DOE to better assess the potential hazards of its contamina-tion problems and to design and implement appropriate correc-tive action strategies. Moreover, research on subsurface hetero-geneity in geology, geochemistry, hydrology, and microbiologywill provide a framework for assessing the fate and transport ofcontaminants. The committee believes that basic research isneeded to support the development of the following capabilities:
• improved capabilities for characterizing the physical, chemi-cal, and biological properties of the subsurface;
• improved capabilities for characterizing physical, chemical,and biological heterogeneity, especially at the scales thatcontrol contaminant fate and transport behavior;
• improved capabilities for measuring contaminant migrationand system properties that control contaminant movement;
• methods to integrate data collected at different spatial andtemporal scales to better estimate contaminant and subsur-face properties and processes; and
• methods to integrate such data into conceptual models.
2. Conceptual modeling.3 Basic research on the fundamentalapproaches and assumptions underlying conceptual modeldevelopment could produce a “tool box” of methodologies thatcan be applied to contaminated sites both inside and outside the DOE complex. This research should focus on the followingtopics:
S u m m a r y
5
3A conceptual model is a description of the subsurface as estimated fromknowledge of the known site geology and hydrology and the physical, chemical,and biological processes that govern contaminant behavior. See Chapter 5.
The committee recom-mends that the subsur-face component of theEM Science Programhave the following fourresearch emphases: 1.Location and character-ization of subsurfacecontaminants and characterization of the subsurface. . . .2. Conceptual model-ing. . . . 3. Containmentand stabilization. . . .4. Monitoring and vali-dation.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
• new observational and experimental approaches and toolsfor developing conceptual models that apply to complex sub-surface environments;
• new approaches for incorporating geological, hydrological,chemical, and biological subsurface heterogeneity into con-ceptual model formulations at scales that dominate flow andtransport behavior;
• development of coupled-process models through experimen-tal studies at variable scales and complexities that accountfor the interacting physical, chemical, and biological process-es that govern contaminant fate and transport behavior;
• methods to integrate process knowledge from small-scaletests and observations into model formulations;
• methods to measure and predict the scale dependency ofparameter values; and
• approaches for establishing bounds on the accuracy of para-meters and conceptual model estimates from field and exper-imental data.
3. Containment and stabilization. Increasing reliance is beingplaced on containment and stabilization because DOE recog-nizes that cleanup at some sites is technically infeasible, or thatcontamination at some sites does not pose a high risk to humansor the environment. Basic research that supports the develop-ment of new waste containment and stabilization technologiescould lower the cost, accelerate regulatory approvals, andincrease public confidence in solving subsurface contaminationproblems. Research focused on the following topics is especiallyneeded:
• mechanisms and kinetics of chemically and biologicallymediated reactions that can be applied to new stabilizationand containment approaches or that can be used to under-stand the long-term reversibility of chemical and biologicalstabilization methods;
• physical, chemical, and biological reactions that occuramong contaminants, soils, and barrier components so thatmore compatible and durable materials for containment andstabilization systems can be developed;
• fluid transport behavior in conventional barrier systems; and • development of methods for assessing the long-term durabili-
ty of containment and stabilization systems.
S U B S U R F A C E S C I E N C E
6Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
4. Monitoring and validation. Basic research leading to improve-ments in capabilities to monitor and validate contaminant loca-tions and perform remedial actions will greatly enhance thetechnical success of DOE’s efforts to remediate or contain andstabilize contamination. Many of the research opportunities formonitoring and validation have been covered in the researchemphases discussed above. In addition, the committee believesthat basic research is needed on the following topics:
• development of methods for designing monitoring systems todetect both current conditions and changes in system behav-iors;
• development of validation processes.• determining the key measurements that are required to vali-
date models and system behaviors, the spatial and temporalresolutions at which such measurements must be obtained,and the extent to which surrogate data can be used in valida-tion efforts; and
• research to support the development of methods to monitorfluid and gaseous fluxes through the unsaturated zone, andfor differentiating diurnal and seasonal changes from longer-term secular changes.
Within these four emphases, the committee further recom-mends that the EM Science Program encourage research on met-als and radionuclides, which is generally not receiving muchattention in other federal research programs. There should, how-ever, be sufficient flexibility in the program so that support canbe provided for high-risk but potentially high-payoff researchideas that intersect with these recommended research emphases.
The committee’s recommendation of these four researchemphases does not mean that the subsurface research in the cur-rent program portfolio is inappropriate or misdirected. Rather,the recommended emphases represent areas where moreresearch clearly is needed.
ImplementationThe EM Science Program is a basic research program focused on
very real DOE problems. The program’s success will be measured bothby its impact on advancing the science needed for site remediation andits impact on DOE site cleanup. To be successful, the program must notonly be focused on the right problems but it also must encourageresearchers to do the right work; and it must be structured so that
S u m m a r y
7Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
research results can be handed off to technology developers and prob-lem holders at DOE sites. The committee concluded that the followingactions would help ensure the long-term success of the program inmeeting the first two of these objectives:4
1. Program Integration. Program managers must encourage andsupport program-wide integration activities to optimize impactsof advances in subsurface science on DOE site cleanup. To thisend, the program’s implementation strategy should contain thefollowing integrative elements:
• Continue to reach beyond the usual group of DOE researchersto pull in new and novel ideas to address DOE-specificproblems.
• Continue to encourage multidisciplinary research anduniversity-national laboratory-industry collaborations that willpromote new insights into the very complex subsurfaceproblems at DOE sites.
• Integrate existing data and ideas—both from DOE sites andbasic research programs outside DOE—to promote advance-ments in subsurface science and improvements in capabili-ties for addressing DOE’s subsurface contamination prob-lems.
2. Field Sites. The committee recommends that program managersexamine the feasibility of developing field research sites as oneprogram component. Such sites could attract new researchers tothe program, encourage both formal and informal multidiscipli-nary collaborations among the researchers, and facilitate thetransfer of research results into application. These field sitescould include contaminated or uncontaminated areas at majorDOE sites; analog uncontaminated sites that have subsurfacecharacteristics similar to those at contaminated DOE sites; andeven virtual sites comprised of data on historical and contempo-rary contamination problems. These sites could be establishedby the program itself or in cooperation with other research pro-grams.
The establishment of field research sites is potentially expen-sive, especially if the sites are located in contaminated areas.Consequently, the establishment of such sites will require addi-
S U B S U R F A C E S C I E N C E
8
4The third objective on moving science into application, although extremelyimportant, is beyond the statement of task for the present study.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
tional budget support beyond that required to fund individualresearch projects, and well beyond the amount of funding avail-able to the program for new starts in fiscal year 1999. Moreover,the use of such sites will have to be evaluated periodically todetermine whether they are adding value to the research effort,particularly given the cost of such sites relative to the total sizeof the program budget.
3. Program Funding. The issue of program funding has received agreat deal of attention from a previous NRC committee (NRC,1997b), which concluded that the “program must be largeenough to support a significant number of ‘new starts’ (i.e., newprojects or competitive renewals) each year if it is to be success-ful in attracting innovative proposals from outstandingresearchers ….” New starts will help establish a cadre of knowl-edgeable and committed investigators—undergraduates, gradu-ates, postdocs, and professionals—who can be called on byDOE in the years ahead for help with its most difficult contami-nation problems. New starts also are needed to maintain conti-nuity in the research effort since the advancement of scientificknowledge is a cumulative effort involving many scientists overlong periods of time. This effort is set back significantly eachtime program funding is interrupted.
It is the committee’s strong impression that the current levelof program funding is not sufficient to support the researchemphases outlined in this report, especially since subsurfaceresearch is just one of many research areas supported by theprogram. The committee has no basis on which to recommend aspecific funding level, and such a recommendation would bewell beyond the committee’s statement of task. The committeebelieves that it is the responsibility of program managers toestimate the amount of funding required to provide adequatesupport for a research program focused on the knowledge gapspresented in Chapter 5. One approach for estimating the annualbudget needed to support the recommended research is to esti-mate the number of projects needed to attain a critical mass ofresearch on each technical challenge area discussed earlier, andthen to multiply that number by the average annual grant size.Such estimates could be used to justify future and possibly largerbudget requests to upper DOE management and Congress, espe-cially if the estimates are reviewed and validated by DOE’sinternal and external advisory committees. Future budgetrequests are likely to be seen in an increasingly more favorablelight as the program becomes more firmly connected to EM’scleanup problems.
S u m m a r y
9
It is the committee’sstrong impression thatthe current level of program funding is not sufficient to sup-port the researchemphases outlined inthis report . . . .
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Concluding RemarksThe basic research supported by the EM Science Program and other
relevant federal research programs will have little if any impact on DOEcleanup unless research results are transferred into technology develop-ment programs in EM and to problem holders at DOE sites. Programmanagers have a responsibility to ensure that the handoff from researchto development is timely and effective, both for research results devel-oped in its programs and from other relevant federal programs.
There must be strong scientific, technical, and management leader-ship at all levels, from the EM Science Program up to and including theassistant secretary for environmental management if significant progresson closing knowledge gaps is to be made in the next decade and theresearch results are to be applied effectively to the DOE cleanup pro-gram. The development of this leadership is a continuing challenge—and a significant opportunity—for the EM Science Program and DOE.
S U B S U R F A C E S C I E N C E
10
There must be strongscientific, technical, andmanagement leader-ship at all levels ... if sig-nificant progress onclosing the knowledgegaps is to be made inthe next decade andthe research results areto be applied effective-ly to the DOE cleanupprogram.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
1
Introduction and Task
The Department of Energy’s (DOE’s) Environmental Management(EM) Science Program was created by the 104th Congress1 to bring thenation’s basic science infrastructure to bear on the massive environ-mental cleanup effort now underway in the DOE complex. The objec-tives of the program are to
• provide scientific knowledge that will revolutionize technologiesand cleanup approaches to significantly reduce future costs,schedules, and risks;
• bridge the gap between broad fundamental research and needs-driven applied technology; and
• focus the nation’s science infrastructure on critical DOE environ-mental management problems.
To meet these objectives, the EM Science Program provides three-year awards to investigators in industry, national laboratories, and uni-versities to undertake research on problems relevant to DOE cleanupefforts. Project awards are competitive and are made on the basis ofmerit and relevance reviews managed through a partnership betweenthe DOE Office of Environmental Management, which has the primaryresponsibility for the cleanup mission, and the DOE Office of Science,2
which manages DOE basic research programs. A more detailed descrip-tion of the program is provided in Appendix A.
Since its establishment by Congress, the program has held four pro-posal competitions and has awarded about $225 million in funding,which puts it among the largest environmental research efforts in thefederal government (see Chapter 4). The first two proposal competitions
C h a p t e r 1
11
1Public Law 104-46, 1995.2Formerly the Office of Energy Research.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
were completed in fiscal years 1996 and 1997 and resulted in 202awards totaling about $160 million. These awards covered a wide rangeof problems related to cleanup of the defense complex, including sub-surface contamination problems.3 The third proposal competition wascompleted in fiscal year 1998 and resulted in 30 awards totaling about$30 million. These awards provided funding for projects primarily relat-ed to high-level radioactive waste and deactivation and decommission-ing. The fourth proposal competition was completed in fiscal year 1999,while this report was in the end stages of completion, and focused pri-marily on subsurface contamination and low dose radiation.4
Shortly after the program was established, DOE requested advicefrom the National Academies on its structure and management. Inresponse, the National Academies established the Committee onBuilding an Effective Environmental Management Science Program,which operated from May 1996 through March 1997 and producedthree reports.5 One of the primary recommendations made by thiscommittee was that DOE should
develop a science plan for the EMSP [Environmental ManagementScience Program]. This science plan should provide a compre-hensive list of significant cleanup problems in the nation’s nuclearweapons complex that can be addressed through basic researchand a strategy for addressing them. (NRC, 1997b, p. 3)
This committee also recommended a near-term and a long-termprocess for developing this science plan: For the near term, programmanagers should develop a science plan from existing DOE docu-ments. For the longer term, DOE should consult with its problem hold-ers (i.e., site technical staff, managers, and stakeholder advisory groupswho have knowledge of the cleanup issues) about cleanup problemsthat cannot be resolved practically or efficiently with current knowl-edge or technologies.
S U B S U R F A C E S C I E N C E
12
3An analysis of the program’s subsurface science portfolio for fiscal years 1996and 1997 is provided in Chapter 3.
4Thirty-one awards totaling $25 million were made for projects related to sub-surface contamination research, and eight awards totaling about $8 million weremade for low dose radiation research in cooperation with the DOE Office ofScience’s Low Dose Radiation Research Program. The committee did not have anopportunity to review the fiscal year 1999 projects.
5Building an Effective Environmental Management Science Program: InitialAssessment (NRC, 1996a); Letter Report on the Environmental ManagementScience Program (NRC, 1996b); and Building an Effective EnvironmentalManagement Science Program: Final Assessment (NRC, 1997b). All three reportscan be viewed at the National Academy Press Web site (http://books.nap.edu/catalog/5557.html).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
In the spring of 1998, Gerald Boyd, the then-acting director (nowdirector) of the Office of Science and Technology, requested that theNational Academies convene another committee of experts to adviseDOE on its first science plan for the EM Science Program, which DOEhad decided would address subsurface contamination. In response, thecurrent committee was formed under the joint auspices of the Board onRadioactive Waste Management and Water Science and TechnologyBoard. This committee has expertise in basic research and researchmanagement in the scientific disciplines relevant to subsurface contam-ination problems at DOE sites.6
The statement of task for this study (see Sidebar 1.1) charged thecommittee to provide recommendations for a science research programfor subsurface contamination problems at DOE sites, and especially toidentify areas of research where the program could make significantcontributions to DOE’s cleanup efforts and add to scientific knowledgegenerally. The committee held six meetings between October 1998 andJuly 1999 to gather information on subsurface contamination and relat-ed problems at six major DOE sites and to develop this report.7 Thecommittee also produced an interim report to advise DOE on the fiscalyear 1999 proposal call. That report is given in Appendix E.
The committee received briefings on subsurface contaminationproblems at the Hanford Site (Washington), Idaho National Engineeringand Environmental Laboratory, Nevada Test Site, Oak Ridge Site
13
C h a p t e r 1
6Biographical sketches of committee members are given in Appendix C.7See Appendix B for a summary of the information-gathering activities.
SIDEBAR 1.1 STATEMENT OF TASK
The objective of this study is to provide recommendations to DOE’s EM Science Program on the formu-
lation of a long-term basic research1 program to address subsurface contamination problems at DOE
sites. These recommendations will take into account significant subsurface contamination problems at
major DOE sites that cannot be addressed with current technologies and science knowledge gaps rele-
vant to these problems. The recommendations also will take into account the research already com-
pleted and currently in progress by other federal and state agencies and will identify areas of research
where the EM Science Program can make significant contributions to address DOE’s subsurface conta-
mination problems and to add scientific knowledge generally.
1Scientific research comprises a spectrum of investigative activities that are frequently classified usingartificial groupings such as basic and applied (e.g., Pielke and Byerly, 1998). In the committee's view, basicresearch is defined as research that creates new generic knowledge and is focused on long-term, rather thanshort-term, problems. See also NRC (1995).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
(Tennessee), and Savannah River Site (South Carolina). The committeetoured the Hanford Site and Savannah River Site to make direct obser-vations of the problems and obtain briefings from site personnel, and itreviewed DOE and other documents concerning the subsurface conta-mination problems at these sites and at the Rocky Flats Site inColorado. The committee did not request briefings on the Rocky FlatsSite because of time constraints and because DOE advised that itsplanned cleanup activities of this site would be completed by 2006(e.g., DOE, 1998a).
The committee focused primarily on the scientific issues in keepingwith its collective basic-research expertise. The committee hasreviewed the subsurface contamination problems at major DOE sites(see Chapter 2) and provides recommendations on a research agenda toaddress these problems (see Chapter 5). The committee also consideredthe research being sponsored by other federal programs (see Chapter 4)as well as the projects supported in the current EM Science Programportfolio (see Chapter 3), so that unnecessary duplication of effort canbe minimized.
In Chapter 6, the committee recommends a strategy for implement-ing a research agenda, but it has refrained from making recommenda-tions on program management, which is largely beyond its collectiveexpertise and was covered in detail by a previous National Academiescommittee (NRC, 1997b). The committee also comments on the levelof effort (both in time and funding) that will be required to make signifi-cant progress on the research agenda. The committee believes that thesuccess of the EM Science Program will depend both on the nature ofthe problems addressed and on the effort sustained in solving them.
S U B S U R F A C E S C I E N C E
14Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
2
Subsurface Contamination in the DOE Complex
Over the last five decades, the United States has created a massiveindustrial complex to develop, test, manufacture, and maintain nuclearweapons for national security purposes. The U.S. Army Corps of Engi-neers, Manhattan Engineering District, started constructing the complexduring the Second World War. The complex was expanded during theensuing Cold War by the Atomic Energy Commission, the EnergyResearch and Development Authority, and starting in 1977, the Depart-ment of Energy (DOE). The DOE complex, as it has come to be known,encompasses 134 distinct geographic sites in 31 states and one territorywith a total area of over two million acres (DOE, 1998a). The individ-ual sites range in size from several hundred square miles to less thanone square mile; these sites host a variety of defense-related activitiesranging from uranium mining and milling to nuclear weapons testing(see Figure 2.1).
The production and testing of nuclear weapons has created a legacyof significant environmental contamination, as described in some detaillater in this chapter. In 1989, Congress created the Office of Environ-mental Management (EM) in DOE to reduce threats to health and safetyposed by the environmental contamination at DOE sites. To meet thisobjective, EM has undertaken a major cleanup effort, which, accordingto DOE, is the largest environmental cleanup in the world. This is cer-tainly true from a cost standpoint: EM is now spending about $5.8 bil-lion per year on its cleanup program and has spent over $50 billionsince 1990. It expects to spend another $147 billion between 1997 and2070 (DOE, 1998a), but this estimate is uncertain because the magni-tude of contamination and the level of cleanup effort required at somesites are still poorly understood.
In this chapter, the committee provides an overview of the subsur-face contamination problems around the DOE complex and shows by
C h a p t e r 2
15Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
example how advances in scientific and engineering knowledge canimprove cleanup effectiveness. The chapter is organized into three sec-tions. The first provides an overview of the DOE complex and its mis-sion and describes the legacy of contamination from weapons produc-tion and related activities. The second section illustrates the range ofsubsurface problems that exist across the complex today and what DOEis doing to correct them. The examples are taken from the six largestDOE sites: Hanford, Idaho, Nevada, Oak Ridge, Rocky Flats, andSavannah River (see Sidebar 2.1). In the third section, the committeediscusses how scientific and engineering research can improve theeffectiveness of DOE’s mission to tackle these contamination problems.
S U B S U R F A C E S C I E N C E
16
Hanford
Idaho National Engineeringand Environmental Laboratory
NevadaTest SiteRocky FlatsEnvironmental Technology Site
FIGURE 2.1 Location of DOE
complex sites. The major
sites are labeled by name on
the figure. The locations of
other sites are indicated by
closed circles. SOURCE: DOE.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
This discussion will be used to support the recommendations inChapters 5 and 6.
Past Prac t ices and ConsequencesNuclear weapons production during the Cold War was a highly
industrialized enterprise that involved a vast complex of mines andindustrial sites across the United States. The front end of the processwas focused on the production of uranium, which was then used toproduce other weapons materials, particularly plutonium and tritium.
17
C h a p t e r 2
Oak Ridge Reservation
Savannah River Site
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
The back end was focused on the fabrication and testing of nucleardevices. The major production steps and waste byproducts aredescribed in Sidebar 2.2.
The United States is no longer producing plutonium and tritium1 for
S U B S U R F A C E S C I E N C E
18
SIDEBAR 2.1 THE DOE COMPLEX
Although the DOE complex encompasses over 100 distinct sites, much of the major defense-related
activities were conducted at the six largest DOE sites (see Figure 2.1) described below.
The Hanford Site is located in southeastern Washington state and covers an area of about 1,450 square
kilometers (560 square miles). Production of materials for nuclear weapons took place here from the
1940s until mid-1989. The site contains several production reactors, chemical separations plants, and
solid and liquid waste storage sites.
The Idaho National Engineering and Environmental Laboratory, first established as the Nuclear Reactor
Testing Station and then the Idaho National Engineering Laboratory, occupies 2,300 square kilometers
(890 square miles) in a remote desert area along the western edge of the upper Snake River plain. The
site was established as a building, testing, and operating station for various types of nuclear reactors
and propulsion systems, and the site also manages spent fuel from the naval reactor program.
The Nevada Test Site, which occupies about 3,500 square kilometers (1,350 square miles) in southern
Nevada, was the primary location for atmospheric and underground testing of the nation’s nuclear
weapons starting in 1951.
The Oak Ridge Reservation covers an area of approximately 155 square kilometers (60 square miles)
and is located about 10 kilometers (6 miles) west of Knoxville, Tennessee. The reservation has three
major operating facilities: the Oak Ridge National Laboratory, the Y-12 Plant, and the K-25 Plant. The
laboratory was originally constructed as a research and development facility to support plutonium
production technology. The Y-12 Plant was built to produce highly enriched uranium by electromag-
netic separation; and the K-25 Plant, formerly known as the Oak Ridge Gaseous Diffusion Plant, also
was created to produce highly enriched uranium for nuclear weapons.
The Rocky Flats Environmental Technology Site is situated on about 140 hectares (~350 acres) near
Denver, Colorado, and has more than 400 manufacturing, chemical processing, laboratory, and support
facilities that were used to produce nuclear weapons components. Production activities once included
metalworking, fabrication and component assembly, and plutonium recovery and purification.
Operations at the site ceased in 1989.
The Savannah River Site, located near Aiken, South Carolina, covers an area of about 800 square kilo-
meters (300 square miles). The site was established in 1950 to produce special radioactive isotopes
(e.g., plutonium and tritium) for use in the production of nuclear weapons. The site contains produc-
tion reactors, chemical processing plants, and solid and liquid waste storage sites.
1The secretary of energy has announced that DOE may produce tritium in thefuture to replenish current stocks of nuclear weapons.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
nuclear weapons, and a large part of the DOE complex has been shutdown or placed on standby. All of DOE’s production reactors havebeen shut down, and only two reprocessing facilities (the F and Hcanyons at Savannah River) continue to operate. These are scheduledto be phased out during the next decade. The weapons design andassembly facilities also continue to operate, but their mission nowincludes the disassembly of surplus nuclear weapons. The Nevada TestSite remains open, but only subcritical nuclear tests have been con-ducted there since 1992.
During the last decade, a large part of the DOE complex, includingsome of the sites discussed in Sidebar 2.1, have taken on a new mis-sion: namely, remediation of the environmental contamination resultingfrom weapons production. This mission is formidable, because itinvolves cleanup of a wide variety of hazardous chemicals and radioac-tive materials introduced into the environment during five decades ofweapons production and testing (see Sidebar 2.3). The contaminantsinclude dense non-aqueous phase liquids (DNAPLs; see Sidebar 2.4);toxic metals such as lead, chromium, and mercury; and radionuclidessuch as plutonium, cesium, strontium, and tritium (see Table 2.1).
These contaminants were introduced into the environment througha variety of pathways, including intentional disposal into the groundthrough injection wells, disposal pits, and settling ponds; and throughaccidental spills and leaks from storage tanks and waste transfer lines.In some cases, there is little information available on either the timingor magnitude of contaminant releases to the environment, or the fate of
C h a p t e r 2
19
TABLE 2.1 Principal Dense Non-Aqueous Phase Liquid (DNAPL), Metal, andRadionuclide Contaminants in the DOE Complex
DNAPLs Metals Radionuclides
Trichloroethylene Lead Plutonium
Dichloroethylene Chromium (VI) Strontium-90
Tetrachloroethylene Mercury Cesium-137
Perchloroethylene Zinc Uranium (various isotopes)
Chloroform Beryllium Tritium
Dichloromethane Arsenic Thorium
Polychlorinated Biphenyls Cadmium Technetium-99
Copper Radium
Iodine-129
SOURCE: EPA (1977); INEEL (1997); Riley and Zachara (1992).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
contaminants in the subsurface after release. Moreover, DOE sites arelocated in a variety of climatic zones and have complex subsurfacecharacteristics (see Table 2.2), which makes it difficult to predict thelocation, transport, and fate of contaminants once they are released intothe environment. As discussed in some detail in other NationalResearch Council reports (NRC, 1997a, 1999), technologies to effec-tively remediate many subsurface DNAPL, metal, and radionuclidecontamination problems are either lacking or are unproven for large-scale site remediation.
Although subsurface contamination is generally acknowledged to be
S U B S U R F A C E S C I E N C E
20
SIDEBAR 2.2 NUCLEAR FUEL CYCLE AND NUCLEAR WEAPONS PRODUCTION
The production of nuclear
weapons is a technically com-
plex and highly industrialized
process. The major production
steps and waste byproducts
of this process are described
below.
Mining and milling. Uranium ore
was mined at over 400 sites in
the United States and processed
in mills to produce uranium
oxide. These processes produced
large volumes of mine and mill tailings that contained heavy metals and radioactive radium and thori-
um. This waste is being managed through the Uranium Mill Tailings Radiation Control Act program.
Uranium enrichment. Elaborate chemical processes were used to concentrate the fissile isotope uranium-
235 from the milled ore. Uranium enrichment facilities were built at Oak Ridge (Y-12 and K-25 Plants),
Ohio (Portsmouth Plant), and Kentucky (Paducah Plant). The waste streams from the enrichment process
include depleted uranium (i.e., depleted in U-235 relative to U-238), uranium-contaminated scrap metal,
polychlorinated biphenyl-contaminated waste, and a variety of organic solvents. Separation of lithium
isotopes at the Oak Ridge Y-12 plant also produced large amounts of mercury waste.
Fuel and target fabrication. The enriched uranium was converted to metal at the Fernald Plant in Ohio
and then fabricated into reactor fuel or targets for plutonium production at Hanford and Savannah
River. These processes produced uranium dust and a variety of chemical wastes.
Plutonium production. The United States produced about 100 metric tons of plutonium between 1944
and 1988 at 14 reactors at the Hanford and the Savannah River sites. The reactors at Savannah River
also produced tritium. Thousands of tons of uranium fuel were processed through the reactors during
their four decades of operation. The waste streams from these operations include solid and liquid
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
a significant problem across the DOE complex, estimates of the magni-tude of the problem vary considerably, as shown in Table 2.3. Accord-ing to recent DOE estimates (DOE, 1998a) there are about 6.4 billioncubic meters (226 billion cubic feet) of contaminated soil, groundwater,
C h a p t e r 2
21
radioactive waste, acids, and solvents. The cooling water from the reactors contained some radionu-
clides, most notably tritium.
Plutonium Separation. Plutonium and other special isotopes were separated from the irradiated fuel by
a variety of chemical processes. Chemical separations plants were located at the Hanford, Savannah
River, and Idaho sites. Operation of the separations plants produced significant volumes of highly
radioactive and hazardous chemical waste and water containing low levels of radionuclides and haz-
ardous chemicals.
Weapons design, fabrication, and assembly. Weapons design was the responsibility of the Los Alamos
and Lawrence Livermore National Laboratories. Weapons components were produced at several sites
in the United States, and final assembly took place at the Pantex Plant in Texas. The fabrication process
produced several waste streams, including scrap uranium and plutonium metal and solvents.
Weapons testing. The United States has conducted more than a thousand nuclear weapons tests in the
atmosphere, under water, and underground, and most have occurred at the Nevada Test Site. This test-
ing resulted in the contamination of surface and subsurface sites with radioactive materials, including
tritium, plutonium, and fission products.
2The subsurface contamination estimates provided in this chapter are compiledfrom various DOE documents. The committee cannot evaluate the accuracy ofany of these estimates, but believes based on the briefings and documents itreceived during the course of this study that the estimates are likely to have verylarge uncertainties.
Figure Source: DOE
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
and related environmental media at its sites.2 Most of this contamina-tion is at two sites, the Hanford Site in eastern Washington and theIdaho National Engineering and Environmental Laboratory in south-central Idaho (see Figure 2.1). At these two sites alone, EM cleanup isnot expected to be completed before 2050, and after cleanup is “com-plete” EM does not know how much contamination will remain in theground to be managed through surveillance and containment.
EM’s current cleanup plans, which also are given in the Paths toClosure report (DOE, 1998a), anticipate expenditures on the order of
S U B S U R F A C E S C I E N C E
22
TABLE 2.2 Geologic and Climatologic Variability Across the DOE Weapons Complex
DOE Site Climate Geology and Hydrogeology Surface Waters Depth to Groundwater (m)
Savannah River Humid, subtropical Atlantic Coastal Plain with clay soils. Savannah River 0-38a
Site The strata are deeply dissected by creeks, and most groundwater eventually seeps into and is diluted by the creeks.
Hanford Site Arid, cool; mild Alluvial plain of bedded sediments Columbia River 60-90b
winters and warm with sands and gravels. Groundwater summers; average flows toward the Columbia River.annual rainfall 16 cm (6.3 in.)
Oak Ridge Humid, typical of Valley and ridge province bordering Clinch River 6-37c
Reservation the southern the Cumberland Plateau. Primary Appalachian region; porosity is low, but fracture porosity average annual is present. High clay content.precipitation Shallow water table.138 cm (54.4 in.)
Rocky Flats Temperate, semiarid, Colorado Piedmont section of the Several streams 0-9d
Environmental and continental Plains physiographic province. occur on or near Technology temperatures; average Alluvial deposits cover the site. the facilitySite annual rainfall just
under 40 cm (15 in.)
Idaho National Semiarid with Near the northern margin of the Big Lost River and 60-240Engineering and sagebrush-steppe Eastern Snake River plain, a low-lying other ephemeral Environmental characteristics located area of late Tertiary and Quaternary streamsLaboratory in a belt of prevailing volcanism and sedimentation.
western winds; Basalt covers three-quarters of its average annual rainfall surface.22 cm (8.5 in.)
aMichelle Ewart, SRS, personal communication, 2000.bGephart and Lundgren (1998).cGrover Chamberlain, DOE-HQ, personal communication, 2000.dChristine Gelles, DOE-HQ, personal communication, 2000.
SOURCE: Adapted from Sandia National Laboratories (1996), except where noted.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
$57 billion between 1997 and 2006 to complete cleanup at all but 10of its sites, including the major sites shown in Table 2.3. DOE expectsan additional expenditure of $79 billion to clean up those remaining 10
C h a p t e r 2
23
SIDEBAR 2.3 A PRIMER ON RADIOACTIVE WASTE
Radioactive wastes are the unwanted byproducts of the nuclear fuel cycle (see Sidebar 2.2) and may
contain both radioactive isotopes and hazardous chemicals. In the United States, radioactive waste is
classified and managed by its source of production rather than by its physical, chemical, or radioactive
properties. Consequently, different classes of waste can contain many of the same radioactive isotopes,
and even “low-level” waste can contain certain long-lived radioactive isotopes.
In general, nuclear fuel cycle wastes are grouped into the following broad classes for purposes of man-
agement and disposal:
• Mill tailings are wastes resulting from the processing of ore to extract uranium and thorium.
• Spent nuclear fuel is fuel that has been irradiated in a nuclear reactor, and for the purposes of dis-
posal may include cladding and other structural components.
• High-level waste is the primary waste produced from chemical processing of spent nuclear fuel. This
waste is usually liquid in form and contains a wide range of radioactive and chemical constituents.
Spent nuclear fuel is often referred to as high-level waste in nuclear waste management terminolo-
gy although it is defined differently in the regulations.
• Transuranic waste excludes high-level waste as defined above and includes waste that contains
alpha-emitting transuranium (i.e., atomic number greater than 92) isotopes with half lives greater
than 20 years and concentrations greater than 100 nanocuries per gram. DOE also includes U-233
in its definition of transuranic waste. This waste usually consists of contaminated materials like
clothing and tools resulting from the manufacture of nuclear weapons.
• Low-level waste is radioactive waste that does not meet one of the definitions given previously.
There are two other classes of materials that DOE sometimes manages as waste:
• Nuclear materials, such as plutonium and special-use isotopes, that may be declared as surplus and
disposed of as waste.
• Contaminated environmental media, such as contaminated soil and groundwater, that may fall
under the Environmental Protection Agency’s Comprehensive Environmental Response,
Compensation and Liability Act. The cleanup of this contamination may generate additional
radioactive and chemical waste streams that must be treated and managed.
In the United States, the federal government regulates the management and disposal of most types of
radioactive waste. Federal regulations seek to reduce to reasonably achievable levels the exposure of
workers and other members of the public to this waste. The guiding philosophy for waste management
is sequestration, that is, to isolate the waste from human populations and the environment, either
through long-term storage or disposal in an underground facility until it no longer poses a hazard.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
sites between 2007 and 2070. About $14 billion will be incurred forremedial action, which is defined by DOE as the characterization andcleanup of sites where contaminants or contaminated materials werereleased into the environment. The cleanup of these sites will involvethe recovery and treatment of abandoned materials; remediation of soil,groundwater and surface water; and monitoring where contaminationcannot be cleaned up to unrestricted release standards.
According to EM, site cleanup will be considered “complete” when,among other things, releases to the environment have been cleaned up
S U B S U R F A C E S C I E N C E
24
TABLE 2.3 Projected Magnitude, Timing, and Cost of DOE Cleanup Activities
DOE Site Projected Completion Soil, Pre-2006 Post-2006 Residual Residual End State(s)a Date of Groundwater, Life-Cycle Life-Cycle Conta- Conta-
Planned and Other Costs Costs minants minants Cleanup Media Requiring (1998 $B) (1998 $B)b in Soil in WaterProjects Remedial Action
(106 m3)
Hanford IM, other TBD 2046 1,400 13 37.4 � � � � �
Idaho UR, RR, IM 2050 4,700 5.1 11.3 � � � � � �
Nevada RR, IM, 2014 3.1d 0.92 1.3 � � �
Test Site other TBD& Other Associated Sitesc
Oak Ridge & UR, RR, IM 2013 31 5.4 7.7 � � � � � �
Associated Sitese
Rocky Flats UR, RR, IM 2006-2010 0.79 5.3 0.96 � � � � �
Savannah IM, other TBD 2038 172 12 17.7 � � � � � �
River
Other Sites UR, RR, IM, 1999-2038 120 7.8 2.8 � � � � � �
other TBD
Totals 6,400 50 79
aUR = unrestricted release; RR = restricted release; IM = long-term institutional management; TBD = to be determined.bPost-2006 cost estimates include some but not all costs for long-term institutional management.cIncludes the Nevada Test Site and eight off-site locations in five states (Alaska, Colorado, Mississippi, Nevada, and New Mexico) where under-
ground nuclear tests were conducted.dEstimate does not include groundwater contaminated by nuclear testing.eIncludes the Oak Ridge Reservation, the Paducah and Portsmith Gaseous Diffusion Plants in Kentucky and Ohio, respectively, and the Weldon
Spring Site in Missouri.
SOURCE: Compiled from DOE (1998a, 1999).
Met
als
Rad
s
Org
anic
s
Met
als
Rad
s
Org
anic
s
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
in accordance with agreed standards and groundwater contaminationhas been contained or long-term treatment or monitoring has been putin place (DOE, 1998a, p. 1-7). In other words, even after EM has com-pleted its cleanup projects there will still be contaminants left in thesubsurface and in surface land-disposal facilities that will require long-term management and possibly future actions to prevent furtherspread.
Examples of Subsur face Contaminat ionProblems at Major DOE S i tes
The committee received several briefings on soil and groundwater
C h a p t e r 2
25
SIDEBAR 2.4 NON-AQUEOUS PHASE LIQUIDS IN HETEROGENEOUS FORMATIONS
Non-aqueous phase liquids (NAPLs) are a common class of subsurface contaminants at many DOE
sites. Dense non-aqueous phase liquids (or DNAPLs) are organic chemicals such as trichloroethylene,
tetrachloroethylene, and polychlorinated biphenyls that have densities greater than water (i.e., > 1.0
gram per cubic centimeter) at standard temperature and pressure and have low solubilities. Their rela-
tively high density causes them to migrate downward through soils and groundwater under the influ-
ence of gravity. When they encounter a low-permeability layer, they may pool or move laterally.
Because of their low solubilities, NAPLs remain as a separate phase and may provide a long-term
source of groundwater contamination.
The detection, characterization, and remediation of DNAPL contamination is generally difficult for a
number of reasons, including geological heterogeneity; complex physical, chemical, and biological
interactions; lack of efficient and cost effective field characterization techniques; and limitations and
unavailability of properly validated modeling tools for the design and evaluation of remediation tech-
niques. Experimental studies (e.g., Schwille, 1988; Kueper and Frind, 1991; Illangasekare and others,
1995) have shown that geologic heterogeneity can cause lateral spreading, preferential flow, and
DNAPL pooling. In fact, such heterogeneities may be the major factor in controlling the entrapment
distribution of DNAPLs in the subsurface. The DNAPL may exist as discontinuous, stable pore-scale
masses trapped in soils under capillary forces, but it may also exist as an immobile continuous phase
trapped by various heterogeneity features.
Researchers (e.g., Pfannkuch, 1984; Schwille, 1988) have identified two geometries associated with
subsurface DNAPL contamination: (1) cylinders or fingers, and (2) pools on impermeable layers or
bedrock. The experimental work by Illangasekare and others (1995) and the conceptual studies by
Hunt and others (1986a,b) demonstrate that other geometries are possible as well, including zones of
high saturation trapped in coarse lenses below the water table; thin pools trapped in coarse sand lay-
ers; and suspended pools trapped on top of fine sand or clay layers.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
contamination problems and remediation activities at five of the sixmajor DOE sites (see Sidebar 2.1): Idaho, Hanford, Nevada, Oak Ridge,and Savannah River.3 These sites are in different parts of the country(see Figure 2.1), are characterized by a wide range of geological andclimatic conditions (see Table 2.2), and have a wide range of contami-nation histories.
In this section, the committee presents a snapshot of some of thesites’ subsurface contamination problems to illustrate both the range ofcontamination problems and the remediation challenges. These exam-ples are illustrative and do not necessarily represent the only significantcontamination problems at the sites or across the DOE complex.Readers who wish additional information should consult the referencescited in this section as well as the references given in Appendix D.
As will be shown in the following discussion, there are many simi-larities among the contamination problems at the major DOE sites. Tohighlight this fact, the committee has organized the discussion arounddifferent contaminant settings: waste burial ground contamination, soilcontamination, unsaturated zone contamination, and saturated zonecontamination. These are illustrated schematically in Figure 2.2.
Waste Burial Grounds“Waste burial ground” is applied rather loosely to a wide array of
S U B S U R F A C E S C I E N C E
26
FIGURE 2.2 Schematic illus-
tration of historical waste
management practices in
the DOE complex and con-
taminant pathways to the
environment. SOURCE: DOE.
3As noted in Chapter 1, the committee did not obtain a briefing on the RockyFlats site because of time constraints and because of DOE’s plans to complete sitecleanup by 2006. However, one of the committee members was familiar with thesite, and the committee was able to obtain additional written information todevelop the example used in this chapter.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
disposal sites around the complex, ranging from auger holes to disposalpits and trenches. Waste burial grounds were used at all the major DOEsites to dispose of solid and liquid wastes, with many disposal practicesnow considered unacceptable by today’s standards (see Sidebar 2.5):pits and trenches were unlined and frequently unmarked after closureand little thought was given to the stability or durability of waste thatwent into them. Consequently, there has been significant leakage frommany waste burial grounds in the DOE complex, contaminatinggroundwater and surface water with metals, radionuclides, and haz-ardous chemicals. Efforts are now being made at some sites to excavateand remove the contaminants from these burial grounds or to coverthem with low-permeability barriers to inhibit the further spread of con-tamination.
Burial Ground Complex at Savannah RiverThe Burial Ground Complex covers an area of about 80 hectares
(195 acres) in the central part of the Savannah River Site and was usedbetween 1952 and 1995 to dispose of low-level radioactive waste,mixed waste (i.e., radioactive and chemical waste), and intermediate-level radioactive wastes (see Plate 1). Contamination from these burialgrounds has leaked to the underlying groundwater, producing fourplumes consisting of various chemicals, metals, and radionuclides. TheBurial Ground Complex represents one of the Savannah River Site’shighest long-term risks to human health and environment and has beenidentified by the site’s restoration division as its highest cleanup priority(Westinghouse Savannah River Co., 1998).
Plans to remediate this site have not been finalized but they willprobably include several actions, including the removal or stabilizationof highly contaminated zones in the southern part of the burial ground;installation of a multilayer surface barrier or cap consisting of naturaland synthetic materials to impede water infiltration (see Plate 1); andlong-term surveillance. DOE has relatively little experience with long-term caps, covers, and monitoring, but these containment approaches,if successful, are likely to find wide application for stabilization ofwaste burial grounds around the complex.
Radioactive Waste Management Complex at IdahoThe Radioactive Waste Management Complex was established in
1952 for disposal of solid low-level radioactive waste generated on site.Waste from other DOE sites was also buried here, including transuranicwaste from Rocky Flats. After 1970, shallow land disposal of transuran-ic waste was discontinued, and above-ground storage on asphalt padsbegan to be used. Wastes were disposed in pits, trenches, soil vaults, anabove-ground disposal pad, a transuranic storage area release site, andthree septic tanks (DOE, 1996).
C h a p t e r 2
27Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
The Idaho site is located in a semiarid environment and is underlainby a thick unsaturated zone (see Table 2.2), which was thought to pro-vide a barrier to contaminant migration to the underlying groundwater.However, low levels of plutonium have been found in groundwaterbeneath the Radioactive Waste Management Complex, and recentmodeling work suggests that contaminant travel times to groundwaterare only on the order of a few decades (see Sidebar 2.6), much shorterthan anticipated when the complex was established in the 1950s.
One of the trenches contained in the complex is Pit 9, a one-acresite that was used for waste disposal primarily from Rocky Flatsbetween 1967 and 1969. DOE estimates that Pit 9 contains about7,100 cubic meters (250,000 cubic feet) of sludge and solids contami-nated with plutonium and americium. Pit 9 was to serve as a demon-stration for cleanup technologies that could be applied elsewhere onthe site. However, the project has been plagued by significant delays
S U B S U R F A C E S C I E N C E
28
SIDEBAR 2.5 HISTORICAL WASTE MANAGEMENT PRACTICES IN THE DOE COMPLEX
The Manhattan Project to develop nuclear weapons was a first-of-a-kind engineering effort that pro-duced a variety of “exotic” (by the standards of the day) radioactive and chemical wastes, frequently invery large volumes. During the ensuing Cold War, U.S. (and Soviet) defense efforts were focused on theproduction of nuclear warheads, and less attention was given to the management and disposal ofassociated radioactive and chemical wastes, resulting in significant environmental contamination asillustrated by the examples in this chapter.
This April 1962 photograph
was taken a few days after
rapid melting and rain
caused flooding of a pit in
what is now the Radioactive
Waste Management
Complex at the Idaho site.
Barrels and boxes contain-
ing mixed (radioactive and
hazardous) waste can be
seen floating in the pit.
Source: Idaho National
Engineering and
Environmental Laboratory.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
and cost overruns and recent concerns that drilling to retrieve wastesamples could cause an explosion or fire. Remediation efforts currentlyare on hold awaiting a safety assessment by a team of independentexperts.
The remediation of buried waste grounds like the Radioactive WasteManagement Complex presents several challenges to DOE and its con-tractors, including locating and characterizing the buried waste, deter-mining the amount of surrounding contamination, and treating thewaste either by in situ or extractive technologies. The problems at thispit provides perhaps a worst-case illustration of the kinds of problemsthat DOE is likely to face as it tackles other waste burial groundsaround the complex.
Burial Grounds at Oak Ridge National LaboratoryThe original mission of the Oak Ridge National Laboratory was to
produce and chemically separate plutonium, and later to produce iso-
C h a p t e r 2
29
The reprocessing of spent fuel to recover uranium and plutonium for warheads produced very large
volumes of highly radioactive liquid wastes at the Hanford, Savannah River, and Idaho sites, ranging
from radioactive or chemically contaminated reactor effluent discharges into groundwater or surface
water and soil to high-level waste discharges into the subsurface. The Hanford Site, for example, could
not build enough tanks to hold all the waste from reprocessing operations. Consequently, during the
1940s some high-level waste was discharged directly into the ground; and until the 1970s millions of
liters of high-level waste supernatant liquids were discharged into the ground through drainage
basins and cribs.
One of the guiding philosophies of waste management throughout the DOE complex, especially prior
to the 1980s, can perhaps best be characterized as “out of sight, out of mind.” Such radioactive and
chemical wastes as tritium, chromium, mercury, lubricating oils, solvents, and raw sewage were dis-
charged directly into surface waters, surface drainage basins, or directly into aquifers through injec-
tion wells. Solid and liquid radioactive and chemical wastes were also buried in shallow pits and
trenches, which are now known by the somewhat euphemistic term “burial grounds.” Some of these
trenches filled with water during periods of high rainfall, which promoted migration of chemicals and
radionuclides into the subsurface.
Many of these waste management practices seem reckless by today’s standards, but it is important to
recognize that DOE’s (and its predecessor agencies) practices were not substantially different from
those employed elsewhere in the public and private sectors. In some cases, waste management deci-
sions were made with an incomplete understanding of their consequences. In other cases, waste man-
agement practices judged to be appropriate by the standards of the day are now understood to be
inadequate in light of our improved understanding of natural processes and our greater sensitivity to
environmental quality. Such practices have resulted in a significant legacy of environmental contami-
nation that will take decades and tens to hundreds of billions of dollars to correct.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
topes and undertake research on radioactive and hazardous materials.Much of the radioactive and hazardous wastes from these activities isburied at the site in the Melton Valley Area (DOE, 1996). For example,
S U B S U R F A C E S C I E N C E
30
SIDEBAR 2.6 CONTAMINANT TRAVEL TIMES AT THE RADIOACTIVE WASTE MANAGEMENT COMPLEX
Low levels of plutonium
and other contaminants
were detected recently in
groundwater monitoring
wells near the Radioactive
Waste Management
Complex at the Idaho Site,
indicating that contami-
nants had traveled from the
complex, through the
unsaturated zone, and into
the Snake River plain
aquifer. This discovery was
unexpected by DOE, since
its conceptual models treat-
ed the unsaturated zone as
a barrier to contaminant
migration, and numerical
models based on conventional flow and transport theory did not predict this degree of migration.
Travel time from the complex to the underlying Snake River plain aquifer has been the subject of
intense debate spanning several decades. Because of site aridity, it was initially assumed that the thick
unsaturated zone beneath the complex afforded a high degree of contaminant retardation, but even
40 years ago concerns were raised about the assumption of a long travel time. A National Research
Council committee visited the Idaho Site (then the National Reactor Testing Station) and the Hanford
Site in the 1960s and prepared a report to the Atomic Energy Commission (NRC, 1966). That committee
made the following statement in its report (p. 5):
The protection afforded by aridity can lead to overconfidence: at both sites it seemed to be
assumed that no water from surface precipitation percolates downward to the water table,
whereas there appears to be as yet no conclusive evidence that this is the case, especially dur-
ing periods of low evapotranspiration and heavier-than-average precipitation, as when winter
snows are melted.
Travel time estimates developed over the last several decades have borne out that committee’s con-
cerns. As shown in the figure, travel time estimates have decreased from tens of thousands to a few
tens of years. The uncertainty of these estimates is attributed to several factors, including incorrect
conceptualizations of the hydrogeologic system, improper simplifying assumptions, incorrect trans-
port parameters, and overlooked transport phenomena.
1960 1965 1970 1975 1980 1985 1990 1995 20001
10
100
1,000
10,000
100,000
Est
imat
e of
Tra
vel T
ime
to G
roun
dwat
er T
able
, in
year
sTime to aquifer
Year
Source: Idaho National Engineering and Environmental Laboratory.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
the Waste Area Grouping 4, which is located about one-half milesouthwest of the main plant, is contaminated with strontium-90, tritium,cesium-137, and a small amount of cobalt-60. Significant amounts oftritium have migrated into White Oak Creek, which drains the site(DOE, 1996). About 70 percent of the strontium-90 discharge from thiswaste area group has been attributed to seepage during waste trenchflooding.
There are no cost-effective methods for locating and characterizingthese highly concentrated zones of contaminants (known as “hotspots”) prior to extraction and treatment. Since waste that must beexcavated and moved poses added hazards to workers, most of theburied waste will remain in its current location until more effectivetechnologies become available. Caps and other types of barriers will beused for short-term stabilization and containment, with long-term moni-toring to validate the effectiveness of the containment systems. Thelong-term performance of these containment systems and methods forvalidating their long-term effectiveness are not well understood.
Soil4 ContaminationContamination of surface and near-surface environments is a perva-
sive problem at all of the major DOE sites. This contamination includesmetals, radionuclides, and hazardous chemicals and is the result ofpoor waste management practices, such as those illustrated below.
Plutonium Contamination at Rocky FlatsAs discussed in Sidebar 2.1, the Rocky Flats Environmental
Technology Site was responsible for fabrication and component assem-bly for nuclear weapons. Materials used in these activities includedboth plutonium and enriched uranium metals and oxides. At present,the Rocky Flats site contains approximately 12.9 metric tons of plutoni-um and 6.7 metric tons of highly enriched uranium in nuclear weaponsparts, materials, process residues, and wastes. Much of the material hasbeen stored in temporary packaging, and about 30,000 liters (~8,000gallons) of plutonium solutions and 2,700 liters (~710 gallons) of highlyenriched uranium acid solutions are being held in tanks that were notdesigned for long-term storage (DOE, 1996).
Poor storage and disposal practices have resulted in extensive sur-face and groundwater contamination at the site and on an adjoiningproperty (see Plate 2). The principal types of soil contaminants includeamericium, plutonium, and uranium. DOE plans several environmental
C h a p t e r 2
31
4The term “soil” is used here in the engineering sense to include unconsolidat-ed materials in near-surface environments, typically several meters to 10 or someters in thickness in both saturated and unsaturated states.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
cleanup activities at the site, including removal of contaminant sources,where possible; stabilization, including installation of caps and barriers,where contamination cannot be removed; and continuous environmen-tal monitoring. DOE has announced plans to complete cleanup of thesite by 2006, but even after cleanup is completed there will be a con-tinuing surveillance mission to monitor the remaining contamination(DOE, 1998a).
Mercury and Cesium Contamination at Oak Ridge Because of poor operational and waste management practices, the
streams and rivers on part of the Oak Ridge site have been extensivelycontaminated with mercury and radioactive cesium. The mercury con-tamination is from the Y-12 plant, where mercury was used to separatelithium isotopes. DOE estimates that between 108,000 and 212,000kilograms (~240,000 to 470,000 pounds) of mercury were released intoEast Fork Poplar Creek between 1953 and 1983 (DOE, 1996). Minoramounts of mercury continue to be released into the creek from sec-ondary sources. The cesium contamination is the result of seepage intostreams from old waste storage pits and trenches. These streams draininto the Clinch River, which in turn drains into the Watts Bar Reservoir
S U B S U R F A C E S C I E N C E
32
Oak Ridge ReservationTennessee
Watts Bar Lake
Clinch
Rive
r
FIGURE 2.3 Plan view of
Oak Ridge site and adjacent
waterways to Watts Bar
Reservoir showing major
areas of mercury and
cesium contamination.
SOURCE: Oak Ridge
National Laboratory.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
downstream of the site. The Clinch River and Watts Bar Reservoir com-prise about 120 river miles (193 kilometers) and 18,000 hectares(44,000 acres) and are used for municipal and industrial water supplies,recreation, and residential development (see Figure 2.3 and Plate 5).
Studies by Olsen and others (1992) suggest that about 335 curies ofcesium-137 were released into the river system between 1949 and1986 and that over 300 curies of cesium now reside in the Clinch Riverand Watts Bar Reservoir sediments. It has been estimated that about 76metric tons of mercury have accumulated in the sediments of the WattsBar Reservoir system. Other contaminants found in the river and reser-voir system include metals (lead, arsenic, selenium, and chromium),organics (polychlorinated biphenyls and dioxin) and radionuclides(cobalt-60, tritium, and strontium-90).
DOE plans to excavate and dispose of some of the contaminatedsoils at the Y-12 site. However, there are no plans at present to remedi-ate the river or reservoir, in large part because the contamination is dif-ficult to locate and remediation would be expensive and potentiallyhazardous to workers, the public, and the environment.
Surface Contamination at Nevada Test SiteThere is a significant amount of surface and shallow surface soil
contamination that resulted from above-ground and near-surfacenuclear detonations, safety shot tests, rocket engine development, andunderground nuclear testing at the Nevada Test Site. The primary conta-minants include americium, plutonium, depleted uranium, and metalssuch as lead. The contamination is found on parts of the test site, theTonopoh Test Range, and the Nellis Air Force Range (see Figure 2.4).The safety shot tests resulted in dispersion of contaminants in excess of40 picocuries per gram over more than 1,200 hectares (3,000 acres).This contaminated acreage increases to 11,000 hectares (27,000 acres)when atmospheric and near-surface tests are included (DOE, 1996).
When warranted, cleanup of the Soils Sites Area will consist ofexcavation and disposal elsewhere on the site. Few of these sites havebeen characterized because of funding constraints.
Contamination in the Unsaturated ZoneThe unsaturated zone is that part of the subsurface above the water
table. It contains liquid water under less than atmospheric pressures(e.g., water held by capillary and adsorptive forces), but most of thepore spaces in the rock or soil are filled with air. The unsaturated zoneexists at all of the major DOE sites, but as shown in Table 2.2 its thick-ness varies significantly among sites. The unsaturated zone tends to bethe thickest at the arid western sites—at Hanford, for example, theunsaturated zone is up to about 90 meters (~300 feet) thick—and
C h a p t e r 2
33Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
thinnest at the more humid eastern sites.
Radionuclide Contamination in the 200 Area at HanfordThe 200 Area is located on what is known as the central plateau of
the Hanford Site and covers about 2,400 hectares (6,000 acres; seePlate 3). This area contains chemical processing facilities for extractinguranium and plutonium from irradiated reactor fuel and associatedwaste storage and facilities. The waste disposal facilities include surfacesettling basins and underground drainage cribs constructed for disposalof low-activity liquid wastes, as well as solid waste burial pits andtrenches. The waste storage facilities include 18 tank farms that contain177 underground storage tanks containing about 200 million liters (54million gallons) and about 200 million curies of high-level waste fromthe separations process. The tanks range in size from about 210,000
S U B S U R F A C E S C I E N C E
34
Clean SlatesI, II, IIIDouble
Tracks
Tonopah TestRange
Nellis Air Force Range
Area 13Cabriolet
EventLittle
FellersYuccaFlat
Buggy Event
FrenchmanFlat
NevadaTest Site
GMX Event
PlutoniumValley
SmallBoy
Danny Boy Event
SchoonerEvent
0
0
23 miles
37 kilometers
N
NevadaTest Site
Nevada
FIGURE 2.4 Plan view of
Nevada Test Site show-
ing areas of surface
contamination from
nuclear testing.
SOURCE: Nevada
Operations Office.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
liters (55,000 gallons) to about 4.5 million liters (1.2 million gallons)and consist of one or two carbon steel liners surrounded by reinforcedconcrete (DOE, 1996).
DOE estimates that about 1.3 trillion liters (346 billion gallons) ofwater contaminated with radionuclides were intentionally dischargedinto the ground through settling ponds and other subsurface drainagestructures from chemical processing operations (DOE, 1997a).Additionally, DOE estimates that 67 of the underground storage tankshave leaked at least 3.8 million liters (1 million gallons) of high-levelwaste into the subsurface. Recent work by Agnew and others (1997),however, suggest that these estimates may be low.
Most of the discharged wastes were supernatant liquids that wereproduced by gravity-induced settling by allowing the high-level wasteto cascade through a series of tanks. These liquids contain such fissionproducts as cesium, strontium, and technetium, as well as short-livedradionuclides like tritium. Later, tank waste evaporators were installedto further reduce waste volumes, and the radionuclide-bearing evapora-tor sediments were discharged into the soil.
The decisions to dispose of this waste to the soil were based in parton assumptions about the capacity of the unsaturated zone to trap andhold radionuclides through physical and geochemical processes. Theunsaturated zone beneath the 200 Area is thick (60 to 90 meters, or200-300 feet) and contains sand, silt, and gravel above a layer of vol-canic rock that was thought to be highly sorptive of radionuclides.Given the small amount of precipitation and high evaporation rates, itwas assumed that it would take a long period of time for the contami-nants to migrate through the unsaturated zone and into the groundwa-ter (DOE, 1998b).
Technetium-99 well in excess of drinking water standards has beendetected in the groundwater beneath the 200 Area, and boreholes havedetected possible cesium and strontium at depth beneath several tankfarms, most prominently the SX Tank Farm (see Plate 4). This discoverycame as a surprise to DOE, because cesium and strontium wereassumed to be immobile in the unsaturated zone, and DOE’s models ofthe unsaturated zone predicted that these radionuclides would notmigrate significantly. This finding has prompted a reorganization of the
C h a p t e r 2
35
5As a result of this discovery and at the prompting of Congress, DOE created anew organization (Office of River Protection) and the Groundwater/Vadose ZoneIntegration Project to coordinate the cleanup activities at the Hanford Site. Theproject will take an integrated approach to solving the groundwater and vadosezone contamination problems to provide a scientific basis for site decisions (DOE, 1998b).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
cleanup work and a greater effort to integrate science into cleanupactivities at Hanford.5
Significant uncertainties in understanding of the inventory, distribu-tion, and movement of contaminants in the unsaturated zone exist atHanford. Further, attempts to model contaminant fate and transportthere have met with mixed success. Inaccurate models can have disas-trous consequences when they mislead treatment or containment strate-gies. Therefore, improved models for predicting contaminant migrationare needed to evaluate the impact of such releases into the environ-ment. These models must be based on a good understanding of the
S U B S U R F A C E S C I E N C E
36
SIDEBAR 2.7 EFFECTS OF SUBSURFACE HETEROGENEITY ON FATE AND TRANSPORT MODELING ANDREMEDIATION
Lawrence Livermore National Laboratory, a DOE facility in California, overlies groundwater contami-
nated with volatile organic chemicals originating from land disposal of chemicals when the site was
used as a naval airfield in the 1940s. There are multiple contamination zones corresponding to differ-
ent disposal locations, consisting primarily of dissolved trichloroethylene and perchloroethylene
groundwater contaminant plumes. The western-most plume stretches for over a mile and is of concern
because it is migrating slowly toward municipal water supply wells in the city of Livermore. For over 10
years the site has been subject to intensive hydrogeologic investigation and remedial action (Thorpe
and others, 1990). As a result, hundreds of monitoring wells have been installed to provide for geologic
characterization of the site, monitor the composition and flow of groundwater, and support the design
and implementation of remediation technologies.
To more clearly understand the role and effects of geologic heterogeneity on remediation, Tompson
and others (1998) used hydraulic conductivity data from 240 of these monitoring wells to construct a
statistical distribution depicting the heterogeneous aquifer beneath the site. For a given realization of
this distribution, together with various boundary conditions used to reflect remedial (associated with
a remedial pumping well) or ambient conditions, groundwater flow paths can be produced using a
finite difference flow model.
To illustrate the effects of the fine-scale heterogeneity on contaminant transport and remedial recov-
ery, hypothetical contaminant pulses were released in each model realization to evaluate plausible
migration scenarios over 40 years of ambient conditions and then over 200 additional years of remedi-
al pumping from a well located 1,000 meters from the original source. Model runs indicated a wide
range of possible outcomes from one realization to the next. When the total pumping time was
allowed to run for 200 years, in some cases most of the contaminant mass was recovered from the
model domain, whereas in other realizations as little as one-third of the input mass was recovered. This
indicates the drastic effect that spatial variability of aquifer materials—the exact distribution of which
is never known in precise detail—can have on predictions of contaminant transport. The variation in
the results is indicative of the real uncertainty that would be expected for the behavior of a natural
system.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
subsurface features that control contaminant fate and transport (e.g., seeSidebar 2.7), as well as important transport processes.
Metal and Radionuclide Contamination at IdahoAn important mission at the Idaho site was chemical processing of
spent fuel from research and naval reactor programs. After chemicalprocessing, the high-level liquid waste was stored in undergroundtanks. Idaho managers recognized early on that tank storage spacewould be insufficient, so the site developed a facility to convert thewaste into a powdered ceramic, or calcine, that could be more safelyhandled and stored. Consequently, Idaho was able to avoid the inten-tional discharge of high-level liquid wastes into the subsurface.
There have nevertheless been several releases of radionuclides andmetals from the single tank farm that supported the site’s chemical pro-cessing facility. An underground waste transfer line was accidentallyruptured by drilling, and up to 13,700 liters (~3,600 gallons) of high-level waste with a total activity of over 32,000 curies was released intothe unsaturated zone between 1956 and 1974. In 1972, another leak inthe tank farm released about 52,900 liters (~14,000 gallons) with a totalactivity of about 28,000 curies. The major contaminants includechromium, mercury, cesium, strontium, plutonium, and iodine. Some ofthis waste is located in a perched water zone beneath the tank farm,but the extent of waste migration is poorly known.
The Idaho site is characterized by a thick unsaturated zone (seeTable 2.2), but this zone overlies one of the largest aquifers in the west-ern United States, the Snake River aquifer, which covers an area ofabout 26,000 square kilometers (10,000 square miles). This aquifer sup-plies water to most of central Idaho and provides a major source ofrecharge to the Snake River. Protection of the aquifer and the river is ahigh priority at the Idaho site and is driving many of the site’s remedia-tion decisions. Decisions about remediation of the radionuclide conta-mination beneath the tank farms is hampered by a lack of informationabout the distribution of contamination, as well as the physical andchemical characteristics of the unsaturated zone.6
Contamination in the Saturated ZoneThe saturated zone is defined as that part of the subsurface where
pore spaces are filled with water. In unconfined aquifers, the top of thesaturated zone defines the groundwater table. The principal saturated
C h a p t e r 2
37
6The committee was told that the least expensive remediation alternativewould cost about $600 million and would involve removal of the perched waterzone and pump-and-treat remediation of the underlying aquifer.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
zone contamination problem across the DOE complex are contaminatedgroundwater plumes (i.e., large volumes of groundwater contaminatedwith dissolved and complexed chemicals, metals, and radionuclides).These plumes have been formed by the injection or migration of wasteinto moving groundwater and have length scales on the order of kilo-meters to tens of kilometers, depending on the nature of the source andthe rate and direction of groundwater movement.
All of the major DOE sites contain contaminated groundwaterplumes, and in some cases these plumes have migrated off site or aredischarging into surface waters. The following examples from theSavannah River, Nevada, Hanford, and Idaho sites are illustrative ofplume-related problems across the DOE complex.
DNAPL Plumes at Savannah RiverThe Savannah River Site contains dozens of groundwater plumes
containing DNAPLs, metals, and radionuclides, but the DNAPL plumein the Administrative and Materials Manufacturing Area is perhaps mostinteresting because of its size and location. That area comprises about140 hectares (350 acres) in the northern portion of the Savannah RiverSite and is located less than a mile from the site boundary. Currently aresearch and development center, the area was first established for themanufacture of production reactor components, including target assem-blies and fuel rods (Westinghouse Savannah River Co., 1995).
From the 1950s through the early 1980s, contaminated wastewaterfrom fuel and target manufacturing was pumped through an under-ground line into a settling basin, which had a capacity of about 30 mil-lion liters (8 million gallons). The basin overflowed periodically into anatural seepage area and a shallow depression known as Lost Lake andreleased approximately 1.6 million kilograms (3.5 million pounds) ofsolvents (principally trichloroethylene and tetrachloroethylene) andheavy metals to the environment. DOE believes that most of the heavymetals were trapped in the soil and about half of the solvents evaporat-ed, while the remainder migrated downward from the seepage areasinto the groundwater (Westinghouse Savannah River Co., 1995). In thispart of the site the groundwater moves at rates ranging from a few cen-timeters to about 90 meters per year.
DOE has installed some 400 monitoring wells since 1981 to trackthe spread of contamination, and based on these monitoring data andmodeling studies, scientists at the Savannah River Technology Centerhave created a three-dimensional representation of the plume. DOE hasinstalled a pump-and-treat system at the downstream toe of the plumeto halt its further spread. DOE has been unable to locate or remove theDNAPL sources that are feeding this plume or to apply effective reme-
S U B S U R F A C E S C I E N C E
38Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
diation technologies to the plume itself; it therefore faces the prospectof long-term institutional management of this contamination, includingpump-and-treat remediation.
Radionuclide Contamination at the Nevada Test SiteOver 925 nuclear tests were conducted at the Nevada Test Site
between 1951 and 1992 and resulted in the emplacement into the sub-surface of several hundred million curies of radioactivity, including significant quantities of tritium, plutonium, and fission products (seeTable 2.4). Many of these tests were conducted at or below the ground-water table. Nevada officials contend that the site contains more conta-minated media than any other site in the DOE complex (Walker andLiebendorfer, 1998). DOE notes in Paths to Closure (DOE, 1998a,
C h a p t e r 2
39
TABLE 2.4 Isotope Inventories from Underground Testing at the Nevada Test Site
Location Isotope Inventory (106 curies)(Numbers are rounded)
Pahute Mesaa Tritium 69.9Cesium-137 1.95Strontium-90 1.56Krypton-85 0.13Plutonium-241 0.09Samarium-151 0.07Europium-152 0.03Plutonium-239 0.02Europium-154 0.02Others (34 isotopes) 0.05
Total Pahute Mesa 73.8
Non-Pahute Mesa Tritium 30.7Potassium-40 24.7Cesium-137 1.48Strontium-90 1.19Plutonium-241 0.10Krypton-85 0.09Europium-152 0.06Samarium-151 0.05Europium-154 0.05Plutonium-238 0.03Plutonium-239 0.01Others (32 isotopes) 0.04
Total Non-Pahute Mesa 58.5
aSee Figure 2.5 for locations.
SOURCE: Presentation to the committee by Robert Bangerter, DOE-Nevada Operations Office,December 15, 1998.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
p. E-56) that it has no plans to remediate the subsurface in and aroundthe underground tests because “cost-effective remediation technologieshave not yet been demonstrated.”
Tritium is very mobile in groundwater, and large plumes of tritiumhave been detected from many of the underground tests. It has longbeen argued that most other radionuclides, and especially plutonium,are relatively immobile due to their low solubilities in groundwater andstrong sorption onto mineral surfaces. As discussed in Sidebar 2.8,however, recently published work challenges this conventional view.
Mixed Contaminant Plumes at Test Area NorthTest Area North at the Idaho National Engineering and Environmental
Laboratory covers about 50 hectares (125 acres) in the northern part ofthe site and was used to support the Aircraft Nuclear PropulsionProgram between 1954 and 1961. From 1960 through the 1970s, thearea housed the Loss-of-Fluid Test Facility, which was used for reactorsafety testing and behavior studies. The primary source of the contami-nated groundwater plume is the Technical Support Facility injection
S U B S U R F A C E S C I E N C E
40
SIDEBAR 2.8 PLUTONIUM MIGRATION AT NEVADA TEST SITE?
A potentially significant example of the deficiency in understanding subsurface radionuclide transport
processes was provided by Karsting and others (1999), who reported that they had detected plutoni-
um in groundwater at the Nevada Test Site. The plutonium was detected in water collected from moni-
toring wells on Pahute Mesa, near the northwestern border of the test site (Figure 2.5). The plutonium
was apparently being carried on colloids. The origin of the colloids and the plutonium geochemistry is
still uncertain.
Karsting and others were able to trace the plutonium to the Benham Test, which was detonated in 1968
in zeolitized bedded tuff at a depth below the surface of about 1,400 meters. This test is located about
1.3 km laterally and up to 600 meters below the monitoring wells. The origin of the plutonium was
identified from its 240Pu/239Pu isotopic ratio, which is distinctive for each underground test. The pluto-
nium ratio is recorded in the melt-glass collected from the underground test cavities. No evidence was
found for migration of plutonium from other nearby tests.
The suggested transport of plutonium at the test site has potentially significant implications for DOE’s
plans to passively manage contaminants there, especially if plutonium transport proves to be more
pervasive than is currently recognized. This discovery also has potentially significant implications for
the underground disposal of nuclear waste. Conventional wisdom suggests that plutonium is relatively
immobile in oxidizing subsurface environments like at the test site and has strong sorbing tendencies.
Indeed, underground tests at the test site were believed to demonstrate the effective fixation of pluto-
nium in subsurface environments. The work by Karsting and others has demonstrated that the concep-
tual models for plutonium migration are incomplete; it also suggests that additional basic research on
the geochemical behavior of plutonium is required.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
well, which was used from 1953 to 1972 to inject liquid wastes directlyinto the Snake River plain aquifer. The contaminants included rawsewage, trichloroethylene, tritium, strontium-90, and cesium-137.
Although the source area for this plume—the injection well—isknown, the source term is not. Moreover, the subsurface in this regionconsists of highly fractured rock, which makes it difficult to locate andcharacterize the contamination. Characterization of the extent of conta-mination began in 1988, and recent data suggest that most of the con-tamination probably occurred as entrained sludge in two major fracturezones (see Figure 2.6).
Contaminant Plumes at the Hanford SiteDOE estimates that groundwater under more than 220 square kilo-
meters (85 square miles) of the Hanford Site is contaminated above cur-rent standards, mostly from operations in the 100 and 200 Areas (Plate3). The 100 Area is located on about 6,900 hectares (17,000 acres) inthe northern section of the Hanford site and contains nine productionreactors and several waste burial sites (DOE, 1996). The main sourcesof subsurface contamination in the 100 Area are from radionuclide(mainly tritium) contaminated reactor cooling water and metal andDNAPL contaminants from operations and disposal. Contamination inthe 200 Area was discussed in the section on the unsaturated zone ear-lier in this chapter.
Disposal of supernatant liquids into the ground and leaks from thehigh-level waste tanks have produced significant contamination of thesaturated zone in the 200 Area (Gephart and Lundgren, 1998).Groundwater plumes of the following contaminants exist at levelsexceeding current drinking water standards at the 200 Area: tritium,
C h a p t e r 2
41
FIGURE 2.5 Plan view of
Pahute Mesa with location
of the Benham Test and
groundwater collection well
cluster ER-20-5. SOURCE:
Karsting and others (1999).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
strontium-90, technetium-99, iodine-129, carbon tetrachloride, chromi-um, and uranium. The plumes are flowing northeast toward theColumbia River at several tens of meters per year (see Figure 2.7).
DOE has established an extensive network of monitoring wells totrack the movement of the groundwater plumes, but very little remedia-tion work is being done at present. DOE has established a groundwaterextraction well network to intercept a chromium plume in the 100Area. The chromium is extracted using ion exchange and the treatedwater is returned to the aquifer. Pump-and-treat systems also have beenestablished in the 200 Area to contain the highest concentrations of auranium and technetium-99 plume and a carbon tetrachloride plume(DOE, 1998b).
DOE has a very poor understanding of the source areas, amounts,and timing of contaminant discharges into the subsurface at Hanford.DOE is beginning to support “forensic” investigations of past wastereleases to the subsurface (e.g., Agnew and others, 1997), but addition-al work will be needed to improve the knowledge of the extent andmagnitude of subsurface contamination at the Hanford site. Improve-ments in understanding and modeling fate and transport processes inthe subsurface is also needed to provide long-term predictive capabili-
S U B S U R F A C E S C I E N C E
42
FIGURE 2.6 Conceptual
model for subsurface conta-
mination at Test Area North
at the Idaho Site. Dense
non-aqueous phase liquids
(DNAPLs) may be entrained
in fractures and perched on
dense basalt flows and sedi-
mentary interbeds. SOURCE:
Idaho Engineering and
Environmental Laboratory.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
ties.
C h a p t e r 2
43
FIGURE 2.7 Plan view show-
ing the fast spread of tritium
plumes from the 200 East
Area at the Hanford Site to
the Columbia River. SOURCE:
Richland Operations Office.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Conclus ionsThe examples provided in this chapter illustrate that subsurface con-
S U B S U R F A C E S C I E N C E
44
SIDEBAR 2.9 BASIC SCIENCE CAN IMPROVE ENVIRONMENTAL MANAGEMENT
Basic scientific research can provide several benefits to waste management efforts if it is properly
focused on difficult cleanup problems (see Chapter 6). Basic research can produce new scientific knowl-
edge and engineering tools to improve the effectiveness of cleanup efforts, lower cleanup costs,
reduce risks to worker and public health, and improve environmental quality. Equally important, basic
research can help improve current waste management practices and thereby reduce the likelihood of
future environmental insults. Scientific studies in the 200 Area at Hanford provide a simple yet com-
pelling illustration of the potential benefits for environmental management.
The 200 Area is comprised of two major operating zones (200 East and 200 West) that contain a variety
of waste disposal and waste storage facilities (see Plate 3). These facilities, which include drainage
cribs, settling basins, and underground tanks, are major contributors to the site’s groundwater contam-
ination. As discussed elsewhere in this chapter, groundwater contaminant plumes have formed
beneath both areas, but the plumes originating from the 200 East Area are significantly larger in size,
extending some 15 kilometers (9 miles) to the Columbia River (see Figure 2.7).
Basic geological research conducted at Hanford (see Reidel and others [1992] and DOE [1998b] for a
summary of the Hanford geology) suggests that plume size is controlled to a large extent by the physi-
cal and chemical properties of the geological formations underlying the 200 Area. The 200 East Area is
underlain by the Hanford Formation, which is comprised of permeable sands and gravels that provide
relatively direct pathways to the groundwater some 100 meters below the surface. The 200 West Area,
on the other hand, is underlain by the Ringold Formation, which consists of less permeable sands, grav-
els, and clays that provide a barrier to widespread contaminant migration.
These findings provide a compelling demonstration that “geology counts” in waste management and
site remediation, and that locating disposal facilities must take account of subsurface properties as
part of a defense-in-depth waste containment strategy.1 DOE is constructing and operating several
facilities in the 200 Area to dispose of a variety of cleanup and defense wastes. It recently sited a large
land disposal facility (the Environmental Restoration Disposal Facility) in 200 West to manage certain
types of chemically and radioactively hazardous cleanup wastes from other parts of the Hanford Site.
At least two other disposal facilities have been constructed or are planned for the 200 East Area: the
Naval Reactor Disposal Facility, which contains nuclear reactors from decommissioned U.S. Navy sub-
marines, and the planned Immobilized Low-Activity Waste Disposal Facility, which will take low-activity
waste generated during processing of high-level waste from the Hanford tanks. If the past is a guide to
the future, the disposal facilities in the 200 East Area may create new site contamination problems that
will require additional remediation efforts.
1A defense-in-depth waste containment strategy uses multiple artificial or natural barriers to improve thelong-term performance of the containment system.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
tamination is an enormously difficult cleanup problem as well as a sig-nificant challenge to science. Much of the subsurface contamination atDOE sites is poorly characterized and widely dispersed in the environ-ment, making it very expensive or technically impractical to treat effec-tively with current technologies. Moreover, the contamination that can-not be removed or effectively isolated from the environment willrequire long-term management, which represents a potentially largefuture mortgage for the nation.
The committee believes that this future mortgage could be reducedsignificantly through the development of new and improved technolo-gies to locate, remove or contain, and monitor subsurface contamina-tion at DOE sites. However, the development of such technologies willrequire advances in basic understanding of the complex natural systemsat DOE sites and also in understanding the nature of contaminant“insults” to those systems. The report of the NRC Committee onBuilding an Effective Environmental Management Science Program(NRC, 1997b, p. 22) concluded that “new technologies are required todeal with EM’s most difficult problems, and new technologies requirenew science.” The present committee agrees with this statement andnotes that, given the long-term nature of the cleanup mission and itsprojected cost (see Chapter 1), DOE has necessary cause and time todo the required basic research to support the development of theseneeded technologies (see Sidebar 2.9).
C h a p t e r 2
45Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
46Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
3
Assessment of the EM Science Program Portfolio
The Environmental Management (EM) Science Program1 has been in existence for about four years and has completed four proposal com-petitions.2 The program has supported research projects relevant tomany aspects of DOE’s cleanup program, for example, research onsubsurface contamination, high-level waste, and deactivation anddecommissioning. In its 1998 report to Congress (DOE, 1998g), DOEidentified 82 EM Science Program projects with a total investment ofapproximately $70 million3 that address the remedial action problemarea, which focuses on the cleanup of soil, surface water, and ground-water at sites where contaminants or contaminated materials have beenspilled, dumped, disposed, or abandoned (DOE, 1998a, p. 2-9).
The first two proposal calls did not provide detailed descriptions ofDOE’s cleanup problems, and the proposal review process (seeAppendix A) focused first and foremost on identifying scientifically mer-itorious projects for funding. Relevance to DOE’s problems was consid-ered only for those projects that were deemed to be of high scientificquality. Thus, as this committee began to address its task statement toprovide advice on a subsurface research agenda (see Chapter 1), itasked itself the following two questions, which provide a focus for thecurrent chapter of this report:
C h a p t e r 3
47
1As discussed in Chapter 1, the current program was established by Congressin fiscal year 1996. Previously, the Office of Science and the Office ofEnvironmental Management (EM) jointly managed a one-year pilot project thatawarded about $5 million in 3-year grants for research on EM-related projects.
2The four completed competitions were held in fiscal years 1996, 1997, 1998,and 1999. The 1999 competition was completed while this report was in review.
3Many of the awards are being funded over multiple years and are thereforesubject to future congressional appropriations.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
1. To what extent does the EM Science Program research portfoliofor fiscal years 1996 and 1997 address DOE’s significant subsur-face contamination problems?
2. In light of these current investments, are there any particular sub-surface problems that should be emphasized in future proposalcalls?
The committee reviewed all projects awarded funding during thefirst two proposal competitions (in fiscal years 1996 and 1997) andattempted to assess the extent to which these projects addressed thecleanup problems identified in Chapter 2. The word “attempted” isused advisedly, because these projects were still in progress at the timeof the committee’s review and therefore the research results wereincomplete. Moreover, the committee did not review research resultsfor scientific merit in the way that one would review papers submittedto refereed journals, so it cannot comment on the quality of the workresulting from these projects. The committee’s assessment is based on areview of project titles, principal investigator experience and affilia-tions, project abstracts as provided in DOE’s 1998 report to Congress(DOE, 1998g), and on a review of progress reports provided by theprincipal investigators, which were published in the proceedings vol-ume of the Environmental Management Science Program Workshop
S U B S U R F A C E S C I E N C E
48
TABLE 3.1 Summary of the EM Science Program Portfolio for Fiscal Years 1996 and 1997 and Pilot Projects Fundedin Fiscal Year 1995
Category Projects Research Focus Methodology Number of Fundeda Multiple
Investigator Projects
Identify 30 1 12 3 16 23 12 19 21
Contain 6 3 1 4 NA 1 4 2 3
Remediate 37 14 24 10 NA 5 35 6 17
Remove 7 6 1 0 NA 1 7 0 1
Validate 9 1 4 2 3 4 5 3 5
Other 16 6 8 7 NA 4 13 2 6
aThis column sums to 105 projects, because some projects were included in more than one category.There are 91 separate projects represented
by the data in this table.bProjects that focused on characterization of the site rather than on specific contaminants.
SOURCE: DOE (1998c,g).
Met
als
Org
anic
s
Rad
ionu
clid
es
Site
b
Fiel
d
Lab
orat
ory
Mod
elin
g/T
heor
y
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
(DOE, 1998c). This workshop was held in Chicago, Illinois on July 27-30, 1998. These analyses are summarized in Table 3.1 and Figure 3.1.
The committee spent a considerable amount of time during its firsttwo meetings discussing the merits of various organizing schemes forthis assessment and eventually adopted a slightly modified form of anapproach that is used by DOE’s Subsurface Contaminants Focus Area4
to organize its technology development programs (see Figure 3.2). Thisorganizational scheme comprises a five-point technical strategy that isbased on what the focus area refers to as “the accepted process for theremediation of contaminated sites” (DOE, 1997b). This scheme consid-ers the generic processes that must be employed to remediate a site(e.g., locate the waste, treat the waste, validate the treatment process)without reference to the specific technologies that will be employed toaccomplish these processes. The committee adopted the focus area’s
49
C h a p t e r 3
0
5
10
15
20
25
30
35
40
Contain Remove Validate Other Identify Remediate
6
79
16
30
37
Num
ber
of P
roje
cts
Fun
ded
FIGURE 3.1 Distribution of
subsurface research projects
in the EM Science Program
portfolio for fiscal years
1996 and 1997. The num-
bers in the graph are the
number of projects funded
in each topical area.
FIGURE 3.2. Flow chart
for remediation of subsur-
face contamination (DOE,
1998d, p. 4).
4The Subsurface Contaminants Focus Area is part of the Office of Science andTechnology, which is responsible for developing technologies for cleanup of theDOE complex. The EM Science Program is also part of this office.
Contain
RemediateIdentify Validate
Remove
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
function names, slightly modified some of the function descriptions,and added an additional category (“Other”) to its analysis to containthose projects that do not fit readily into one of the focus area’s categories.
The resulting organizing scheme used for the committee’s assess-ment is shown below:
• Identify—Locate and quantify suburface contamination. • Contain—Contain or stabilize mobile contaminants and locally
elevated contaminant concentrations (i.e., contaminant hotspots) in situ.
• Remediate—Treat to reduce mobility or destroy mobile contami-nants in situ.
• Remove—Extract contaminant hot spots that are not amenable toin situ treatment.
• Validate—Verify conceptual models and the performance ofremediation processes or strategies.
• Other—Projects that address subsurface contamination prob-lems, but do not fit into one of the preceding categories.
The committee adopted this scheme for organizing its assessmentmainly for convenience, but also because this scheme could provide adirect linkage between basic research in the EM Science Program andapplied technology development in the Subsurface Contaminants FocusArea. As will be discussed in Chapter 6, moving the results of basicresearch from the EM Science Program into application at the sites is amajor challenge confronting DOE. The committee hopes this organiz-ing scheme will provide a useful mechanism for identifying potentiallyfruitful application paths for EM Science Program-sponsored research.
A summary of the committee’s assessment of the current programportfolio is provided in the following sections. A concluding sectionprovides a brief discussion of the two questions posed at the beginningof this chapter.
Ident i fyThe radioactive and hazardous subsurface contaminants of concern
at DOE sites (see Chapter 2) have entered the soil and groundwaterthrough accidental spills, poor waste management practices, and failureof storage and containment systems. Even in cases where the points ofcontaminant entry into the subsurface are known, information on tim-ing of entry and contaminant quantities may be lacking. Once intro-
S U B S U R F A C E S C I E N C E
50Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
duced into the subsurface, the contaminants are subject to a number of physical and chemical processes or biological degradation. Sub-surface heterogeneities may make it difficult to predict contaminantmovement away from release sites. Successful remediation of contami-nated subsurface sites depends first and foremost on the ability tolocate and quantify the nature and extent of contamination, the focus of this category.
The committee found 30 projects relevant to the “Identify” categoryin the portfolio (see Table 3.1). These projects encompass a wide rangeof topics and approaches, but in general focus on the following: (1)location and spatial distribution of contaminants in saturated and unsat-urated environments; (2) methods to estimate quantitatively the extentof such contamination; and (3) methods to monitor the movement ofsubsurface contaminants.
The projects in this portfolio address a wide range of contaminanttypes and site characterization problems. Organic contaminants (espe-cially non-aqueous phase liquids) are the subject of 12 projects, com-pared to three for radionuclides and one for metals; 16 projects focuson site characterization without regard to contaminant type. A majority(23 projects) involve field investigations at contaminated sites. In termsof project objectives, three focus on elucidating contaminant properties,four on elucidating subsurface properties, 13 on the development ofinvasive characterization techniques, and 12 on the development ofnoninvasive techniques.
The projects in this portfolio address many of the subsurface prob-lems described in Chapter 2, including aspects of the following topicalareas:
• development and testing of noninvasive techniques to identifythe distribution of non-aqueous phase liquids in the subsurface;
• development and validation of analytical and modeling tools to be used in subsurface process representation and characteri-zation;
• development of techniques and instruments to determine subsur-face parameters that describe flow of water and contaminanttransport in the subsurface; and
• noninvasive geophysical techniques and associated analyticaltechniques to determine subsurface physical parameters.
The portfolio is heavily weighted toward organic contaminants, andthere are relatively few projects on metals and radionuclides, which aresignificant problems at most of the large DOE sites. There are also veryfew projects that deal with the behavior and transport of contaminants
C h a p t e r 3
51Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
in fractured systems, primarily under unsaturated conditions, or thebehavior and transport of contaminants under near-surface conditions(e.g., in near-surface release sites).
Contain The removal and treatment of contaminants from waste burial
grounds is technically difficult, expensive, and could expose workers toradiation and hazardous chemicals. For these reasons, DOE does notplan to fully remediate subsurface contamination at some of its sites.Instead, DOE plans to contain the waste at such sites with surface capsand subsurface barriers to minimize water infiltration and contaminantmovement. Remediation of contaminated soil and groundwater at manyDOE sites is technically impracticable with current technologies, soDOE plans to monitor this contamination and treat it where necessary,using technologies such as pump-and-treat systems to prevent its furtherspread.5 Thus, the availability of robust containment and stabilizationtechnologies will be a key factor in the success of DOE’s strategy tomanage subsurface contamination.
Given the importance of containment and stabilization technologiesto contamination management strategy, the committee would haveexpected to see a large number of projects on this topic; however, thecommittee was able to identify only six relevant projects in the portfo-lio (see Table 3.1). In general, these projects are concerned largely withmetals and radionuclides and the kinetics and mechanisms of contami-nant retention and release through various processes. Five of the sixprojects focus on chemical stabilization, one on biological stabilization,and one on physical stabilization.6 Only one of the six projects has asignificant field component.
The committee concluded that there are significant research gaps inthe portfolio in this category. These gaps7 include basic research on the
S U B S U R F A C E S C I E N C E
52
5Pump-and-treat systems are used frequently to remediate contaminatedgroundwater. It involves pumping the contaminated water to the surface for treat-ment and then reinjecting it. See NRC (1994) for a discussion of this technology.
6The current portfolio supports several projects on phytoremediation. These arediscussed under the "Remove" category elsewhere in this chapter.
7In the context of this analysis, the committee defines a research gap as a defi-ciency in the number or scope of research projects that address the difficult DOEcleanup problems identified in Chapter 2. The identification of gaps involves asignificant element of judgment, especially in interpreting the significance of thesubsurface contamination problems now at DOE sites. These cleanup problemsand associated knowledge gaps are discussed more fully in Chapter 5.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
design, performance, or effectiveness of engineered surface or subsur-face barriers, including capillary or resistive barriers, reactive barriers,or hybrid barriers that incorporate biological materials; and research onsubsurface processes that address the potential effectiveness of naturalbarriers in contaminated areas, particularly in the vadose zone.
RemediateTechnologies for in situ treatment and destruction involve the use of
engineered or artificially manipulated natural processes to promote theconversion of subsurface contaminants to nonhazardous or less haz-ardous forms. The committee identified 37 projects in the portfolio (seeTable 3.1) that address a wide range of chemical, physical, and biologi-cal treatment and destruction processes, including the following:
• bioremediation,8 including biological interactions, genetic engi-neering studies, and toxicity studies;
• in situ physical and chemical treatment, including electrochemi-cal processes; filtration; sorption; and reactive subsurface barri-ers such as metal (Fe, Mn) oxide barriers, including passive orlow-maintenance barriers;
• coupled chemical, physical, and biological treatment processesused in parallel or series; and
• elucidation of fundamental subsurface processes that govern theeffectiveness of in situ treatment or destruction (e.g., evaluationof the effect of soil heterogeneities on treatment processes).
Projects on organic contaminants comprise the majority of the port-folio (24 of 37 projects), whereas only 10 projects address treatment ofradionuclides and 14 address treatment of metals.9 The committee wasable to group the projects into one or more of the following five the-matic areas: (1) development of new genetic materials to degrade oralter the chemical composition of DOE’s most problematic wastes,including mixed wastes containing radionuclides, heavy metals, and
C h a p t e r 3
53
8Bioremediation generally refers to the removal of contaminants from soil orwater through the metabolic action of living organisms, and the term is commonlyused to indicate situations in which humans have interceded to bring about orhasten the biodegradation of contaminant compounds. Although bioremediationcan be carried out by any living organisms (e.g., as in phytoremediation), it is usu-ally considered to be a product of the metabolism of microorganisms such as bac-teria or fungi.
9Some projects address more than one contaminant type.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
solvents; (2) elucidation of molecular-level biochemical, geochemical,and biogeochemical processes to degrade or transform selected wastecomponents; (3) taking basic science results to the technology imple-mentation level to develop in situ engineered systems; (4) developmentof improved analytical methods to allow evaluation of the effectivenessof in situ treatment or destruction; and (5) development of improvedunderstanding of transport processes at all scales in heterogeneous sys-tems that affect the movement of contaminants in the subsurface.
The portfolio defines a fairly coherent research program on in situtreatment and destruction, but there are a number of significant gaps asoutlined below, and for some research topics there appears to be dupli-cation of effort. The following observations are, in the committee’sview, most significant:
• There is a predominance of projects that address bioremediationrelative to projects that address chemical and physical processes.
• Research on treatment and destruction in the vadose zone isunderrepresented.
• Research on sensors is bio-oriented and much of it is aimed attracking the biological “health” of subsurface systems.
• In the bioremediation area, there is an absence of projects cover-ing (1) alternate electron acceptors, including iron and nitrate,and aerobes (the issue of aerobic degradation is important forvadose zone applications); (2) toxicity of some chemical conta-minants found at DOE sites to bacteria that could potentiallydegrade other contaminants; and (3) cellular mechanisms andprocesses important to the bioremediation of radionuclide andorganic contaminants, including the byproducts of microbialdegradation activity.
• Understanding what controls the availability of many contami-nants to degrading organisms or to reacting chemicals is needed.
RemoveDOE uses the term “hot spot” to refer to significant contaminant
source terms in the subsurface that cannot be treated by in situ methods(DOE, 1998d). In lay terms, a hot spot is a distinct high-concentrationcontaminant anomaly in the subsurface (e.g., a pool of non-aqueousphase liquids trapped in a waste burial ground or a buried 55-gallondrum filled with plutonium-bearing scrap metal). Removal of hot spotsinvolves the physical extraction of the contaminant from the subsurfacefor ex situ treatment or disposal.
S U B S U R F A C E S C I E N C E
54Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
None of the projects in the EM Science Program portfolio have aspecific focus on hot spots, however there are seven projects (see Table3.1) on phytoremediation, an intensely pursued approach to soilcleanup and extractive technology for treatment of hot spots. Researchprojects include the study of genetic factors controlling the uptake ofheavy metals by plants, transport of heavy metals across plant cells,and the ability of plants (poplar trees) to take up and degrade chlorinat-ed hydrocarbons.
Moreover, many of the projects are relevant to improved decisionmaking about whether to contain, stabilize in situ, or extract hot spotsfor above-ground treatment. For example, some of the projects in the“Other” category discussed later in this chapter are relevant in thisregard. Some of the studies in the portfolio on removal and neutraliza-tion of contaminants in tank wastes may lead to results useful for treat-ment of extracted hot spot materials.
Similarly, research projects on locating and quantifying contamina-tion, which were discussed earlier, could make the location and defini-tion of hot spots easier, faster, more accurate, and more economical.Moreover, there are projects in the portfolio that address reactive barri-ers, bioremediation, in situ vitrification, waste treatment and extractionusing electrokinetics, non-aqueous phase liquid migration and pooling,surfactants, adsorption-desorption reactions, and contaminant transport.Many of these projects fall into the “Other” category discussed later inthis chapter. The challenge to DOE is to understand and apply theresults of this research in dealing with hot spots in reliable and cost-effective ways.
Val idateThe Subsurface Contaminants Focus Area defines “Validate” as “val-
idate and verify system performance for regulators and stakeholders”(DOE, 1998d, p. 4). The committee has adopted a somewhat moreexpansive description that includes confirmation of the effectiveness ofremediation processes or strategies. The committee also includes in itsdefinition the validation of conceptual models and the performance ofquantitative models of contaminant fate and transport. Under the com-mittee’s expanded definition, performance validation is a major factorin regulatory acceptance. It underpins all of DOE’s site remediationactivities and provides tools and methods to assess the effectiveness ofcleanup efforts.
The committee identified nine projects that address the problems inthis category (see Table 3.1). Two of these projects address validation of
C h a p t e r 3
55Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
contaminant detection and characterization, three address the valida-tion of fate and transport (i.e., performance of models for fluid flow),and four address remediation effectiveness (i.e., validation of in situbiodegradation or immobilization efforts). The portfolio does not, how-ever, represent a coherent research program in the validate perfor-mance area. Notably absent are projects to validate long-term perfor-mance of containment systems, including containment barriers. Alsomissing from the portfolio are projects to develop protocols for valida-tion of conceptual and numerical models of contaminants in the sub-surface. The committee believes that validation is a key area for futurework by the EM Science Program, as explained in Chapter 5.
O therThe portfolio includes several projects that have indirect but poten-
tially very significant applications to DOE’s subsurface contaminationproblems. In particular, the program is supporting several projects onthe biological effects of radiation and hazardous chemicals, includingimpacts on health and risk (see Table 3.1).10 Relevant projects fall intothe following four thematic areas:
1. effects of radiation and hazardous chemicals on human healthand risk (seven projects);
2. effects of contaminants on ecology and ecological risk (threeprojects);
3. genetic or molecular basis for contaminant effects (four projects);and
4. assessment of monitoring techniques for environmental contami-nants (two projects).
None of these projects addresses explicitly the remediation of sub-surface contamination, but they are nevertheless relevant to subsurfacecleanup efforts because they contribute to the body of science that reg-ulatory agencies use to set cleanup standards and levels.
These projects do not define a coherent research program on bio-logical effects and, in fact, the portfolio of projects could be character-ized as meager, given the potential significance of this area on DOE’scleanup efforts.
S U B S U R F A C E S C I E N C E
56
10As noted in Chapter 1, the EM Science Program awarded funds for researchon low dose radiation in fiscal year 1999.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Discuss ion And Conclus ionsThe EM Science Program is by design a “bottoms-up” program in
which investigators are encouraged to submit their research ideas toaddress cleanup problems. In this respect, the program is not unlikeother basic research programs operated in DOE’s Office of Science andother federal agencies, like the National Science Foundation. Fundingdecisions are based on the scientific merit of the research proposal andits relevance to DOE problems (see Appendix A). The selection processhas resulted in many scientifically meritorious and relevant projects,but there has been a limited opportunity to build coherence. The com-mittee discusses ways to increase coherence in Chapter 5.
The EM Science Program is nevertheless supporting 91 projectsfocused on subsurface contamination problems11 and on health andrisk effects that are potentially relevant to these problems. It is notunreasonable to expect that the program will attain a critical mass ofprojects in some problem areas. The purpose of the assessment in thischapter is to determine where these critical masses are present and toidentify important gaps in the portfolio that DOE should fill in futurecompetitions. Of course, the committee recognizes that some of thegaps identified may in fact be addressed in other federal research pro-grams and in more recent EM Science Program proposal awards. A dis-cussion of other federal programs is provided in Chapter 4.
The program portfolio in subsurface research has some significantareas of strength. For example, the portfolio has a good selection ofprojects that address organic contamination problems (50 projects) andthat use field-based approaches or a combination, of field-, laboratory-,and modeling-based approaches (38 projects). There appears to be acritical mass of projects in the “Remediation” category, especially fortreatment and destruction of organic contaminants through physical,chemical, and biological processes. The committee did observe gaps inthe portfolio in this problem area, as noted previously, but these areminor in comparison to gaps in other categories.
The most notable gaps in the portfolio are in the “Contain” and“Validate” categories, two of the most significant problem areas forDOE given its plans to manage much of its subsurface contamination inplace. In the “Contain” category the gaps include research on thedesign, performance, or effectiveness of engineered surface or subsur-face barriers. The portfolio in the “Validate” category (9 projects) is lim-
C h a p t e r 3
57
11There are 105 projects listed as funded in Table 3.1, but some projects werecounted in more than one category. There are 91 separate projects represented bythe data in that table.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
ited both in terms of depth and breadth of topical coverage. The mostnotable gaps include research to validate long-term performance ofcontainment systems, including reactive barriers and cover perfor-mance, and research to address the validation of conceptual andnumerical models of the subsurface and contaminant fate and transport.As noted elsewhere in this report, these are key problems for DOEbecause they underpin efforts to confirm the effectiveness of and obtainregulatory acceptance for its remediation actions.
There also appears to be a gap in the number of research projectscovering radionuclide and metal contamination problems (26 and 31projects, respectively). As noted in Chapter 2, radionuclide, especiallytransuranic, contamination is a significant problem, and transuraniccontamination is almost exclusively a DOE-owned problem. As willbecome apparent in the following chapter, these contaminants arereceiving relatively little attention in other federal research programsand therefore deserve to be emphasized in future EM Science Programcompetitions.
S U B S U R F A C E S C I E N C E
58Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
4
Research Programs in Other Agencies of Government
As part of its task to formulate recommendations for a long-termresearch program to address the U.S. Department of Energy’s (DOE’s)subsurface contamination problems, the committee was asked to con-sider research already completed or in progress by other federal andstate agencies and to identify areas where the Environmental Manage-ment (EM) Science Program could make significant contributions (seeSidebar 1.1). The committee partially addressed this task in Chapter 3by reviewing research that was completed or underway in the programitself. In this chapter, this task is completed by examining research pro-grams in other agencies of government.1
The committee gathered information for this review from a varietyof sources. The committee received briefings on research programs infive federal agencies at its fourth information-gathering meeting (seeAppendix B): Department of Defense (DOD), DOE, EnvironmentalProtection Agency (EPA), National Science Foundation (NSF), and theU.S. Geological Survey (USGS). The purpose of these briefings was toprovide an overview of the research programs and to give the commit-tee an opportunity to assess how well these programs were being coor-dinated. The committee then conducted additional research on theseand other programs through electronic searches,2 followed by contactswith selected program managers.
The committee’s initial plan was to summarize the information onother research programs using the organizing scheme shown in Figure
C h a p t e r 4
59
1Although the statement of task explicitly directs the committee to examineresearch in "other federal" agencies, the committee has interpreted its mandate toinclude research in other parts of DOE, especially the Office of Science.
2Searches were conducted using the Internet, specifically research databasessuch as the Federal Information Exchange at http://web.fie.com/fedix/.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
3.2, which depicts the Subsurface Contaminants Focus Area’s approachto organizing its technology development programs. However, it quick-ly became clear that such an approach was impractical. In general, thecommittee found that most other research programs could not neatly becategorized into one or two of the boxes shown in Figure 3.2. In fact,many of the research programs were quite broad in scope, and it wasnot possible to obtain an accurate picture of the research being spon-sored without a detailed review of project portfolios, much like thecommittee provided in Chapter 3 for the EM Science Program. Theresimply was not enough time available in this study to do that kind ofreview for all of the programs discussed in this chapter.
The committee was surprised by the large number of programs thatdeal either directly or indirectly with subsurface contaminationresearch. Indeed, the committee identified almost 50 programs thatcould be related at least indirectly to the work of the EM ScienceProgram, not including the programs on health and health effects spon-sored by the National Institutes of Health.3 Thus, to address its taskstatement, the committee decided to summarize the scope and objec-tives of these related research programs and to use these descriptions toformulate recommendations for the EM Science Program.
The description of these related research programs is provided inTable 4.1 (located at the end of this chapter), which groups them byagency, and then by program within each agency. The table provides ashort description of program scope and objectives;4 recent funding levelsif available;5 a notation showing whether the program provides intra-mural or extramural funding;6 and a web address (if available) whereadditional information can be obtained. The programs in Table 4.1 are
S U B S U R F A C E S C I E N C E
60
3The committee decided to exclude health-related research programs mainlybecause health research has not been an important component of the EM ScienceProgram. However, the program did focus part of its fiscal year 1999 program com-petition on low-dose radiation, in cooperation with the DOE-Office of Science’sLow Dose Radiation Research Program. This competition was completed while thecommittee’s report was in review. The results from these and other related researchprograms may have a significant impact on DOE’s cleanup program, specifically inestablishing the adequacy of DOE’s cleanup and containment efforts.
4Program information was derived from descriptions provided by the agenciesin their program announcements or at their web sites.
5Funding amounts are for the entire research programs; only a fraction of theamount listed may be for support of subsurface contamination projects. In mostcases it was not possible to separate the subsurface research component.
6That is, funding for research conducted within the agency by agency investi-gators (intramural funding), or funding for research conducted outside of theagency (extramural funding). Extramural funding is typically provided to investiga-tors in academia, national laboratories, industry, or other federal agencies throughgrants, contracts, and cooperative agreements.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
for federal agencies only; the committee was unable to find any signifi-cant state-funded basic research programs.7
The remainder of this chapter consists of three sections. In the firstsection, the committee provides a brief review of those research pro-grams that appear to be closely related in terms of scope and objectivesto the EM Science Program. The second section provides a short discus-sion of other programs, and the final section provides some concludingobservations.
Closely Related Research ProgramsThe committee’s selection of a research program as closely related
to the EM Science Program is based on two somewhat qualitative crite-ria: (1) the degree to which the program sponsors basic research, ascompared to other activities like technology development; and (2) thedegree to which the program sponsors research that addresses the top-ics shown in Figure 3.2. The committee included those programs that itjudged had a good match with both criteria.
Of the programs shown in Table 4.1, the committee judges that thefollowing 18 programs in eight federal agencies are closely related interms of scope and objectives to the EM Science Program:
• U.S. Department of Agriculture. The Environmental ChemistryLaboratory sponsors intramural and cooperative research onphytoremediation and accelerated microbial degradation of organic compounds and has an annual budget of about $2 million.8
• U.S. Department of Defense. The Army’s Terrestrial ScienceProgram sponsors extramural research on experimental, theoreti-cal, and numerical studies on fluid flow and contaminant trans-port processes in heterogeneous porous media. It has an annualbudget of about $1 million.
The Naval Research Laboratory sponsors research on in situremediation, microbial degradation processes, and environmen-tal monitoring.
The Strategic Environmental Research and Development
61
C h a p t e r 4
7The committee recognizes that individual states may provide research fundingto state agencies and universities for environmental-related basic research, but thecommittee was unable to identify any state programs that provide state taxpayerdollars at the levels commensurate with the federal agencies listed in Table 4.1.
8Unless otherwise noted, the budget numbers given in this chapter are for fiscalyear 1999.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Program sponsors extramural research on cleanup, compliance,conservation, and pollution prevention. The program is managedin cooperation with DOE and the EPA and has an annual budgetof $59.4 million. About $18.4 million of this budget is directedto cleanup-related research.
• U.S. Department of Energy. In DOE’s Office of Science, there areseveral programs in basic energy sciences that sponsor extramur-al research to understand fundamental physical, chemical, bio-logical, and geological processes (see Table 4.1). Some researchsponsored by these programs is relevant to environmentalcleanup, but none is focused explicitly on the topical areasshown in Figure 3.2. There appear, however, to be at least twoprograms in the Office of Science that are directly relevant to theEM Science Program. The Office of Biological andEnvironmental Research’s Natural and AcceleratedBioremediation Program sponsors extramural research to under-stand and apply natural processes to accelerate the biologicallyenhanced immobilization or degradation of contaminated soiland groundwater.
In DOE’s Office of Environmental Management, the Office ofScience and Technology supports a number of applied research,technology development, and technology deployment programs.The overall objective of these programs is to bring new andimproved technologies to bear on cleanup of the DOE complex.
DOE also supports numerous user facilities at several nationallaboratories (see Table 4.2). Many of these support environmen-tal-related research funded by DOE and other research programs.
• U.S. Department of Interior. The U.S. Geological Survey’s ToxicSubstances Hydrology Program funds intramural research onpoint source contamination in the environment. This programhas sponsored 10 field sites around the country (see Sidebar 4.1)to encourage collaborative research among USGS and outsidescientists on problems ranging from landfill leachates to minetailings waste. The use of field sites encourages research collabo-rations and spreads the costs of expensive monitoring and otherobservational facilities. The program has an annual budget ofabout $10 million, and the field sites themselves are made avail-able at no cost to scientists outside the USGS. These scientistsmust obtain additional funding from their organizations or fromother research programs to support the costs of their researchprojects.
• U.S. Environmental Protection Agency. The Office of Researchand Development finances a large number of research programsthat are directly relevant to the EM Science Program. Almost all
S U B S U R F A C E S C I E N C E
62Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
C h a p t e r 4
63
Table 4.2 U.S. Department of Energy User Facilities
Maintained by Basic Energy Sciences, Division of Materials Sciences
Advanced Light Source, Lawrence Berkeley National Laboratory
Advanced Photon Source, Argonne National Laboratory
Intense Pulsed Neutron Source, Argonne National Laboratory
National Synchrotron Light Source, Brookhaven National Laboratory
Los Alamos Neutron Scattering Center
High Flux Isotope Reactor, Oak Ridge National Laboratory
Stanford Synchrotron Radiation Laboratory, Stanford Linear Accelerator Center
High Flux Beam Reactor, Brookhaven National Laboratory
Materials Preparation Center, Ames Laboratory
Electron Microscopy Center, Argonne National Laboratory
Center for Microanalysis, University of Illinois
National Center for Electron Microscopy, Lawrence Berkeley National Laboratory
Shared Research Equipment Program, Oak Ridge National Laboratory
Surface Modification and Characterization Research Center, Oak Ridge National Laboratory
Combustion Research Facility, Sandia National Laboratory, Livermore, California
Maintained by Basic Energy Sciences, Division of Chemical Sciences
National Synchrotron Light Source, Brookhaven National Laboratory
High Flux Isotope Reactor, Oak Ridge National Laboratory
Radiochemical Engineering Development Center, Oak Ridge National Laboratory
Combustion Research Facility, Sandia National Laboratories, Livermore, California
Stanford Synchrotron Radiation Laboratory, Stanford University
Maintained by the Office of Biological and Environmental Research
The Atmospheric Radiation Measurement Observation Sites (Southern Great Plains, TropicalWestern Pacific, and the North Slope of Alaska)
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory
Production Sequencing Facility, Joint Genome Institute, University of California
Mouse Genetics Research Facility, Oak Ridge National Laboratory
Office of Biological and Environmental Research conducts research at the followinguser facilities
Advanced Light Source, Protein Crystallography Program, Lawrence Berkeley National Laboratory
Advanced Light Source, Soft X-ray Spectroscopy Program, Lawrence Berkeley National Laboratory
Brookhaven High Flux Beam Reactor (neutron crystallography and scattering), BrookhavenNational Laboratory
Los Alamos Neutron Science Center (protein crystallography with neutrons), Los AlamosNational Laboratory
National Synchrotron Light Source (X-ray crystallography of biological macromolecules and UV spectroscopy), Brookhaven National Laboratory
Oak Ridge High Flux Isotope Reactor (neutron crystallography), Oak Ridge National Laboratory
Stanford Synchrotron Radiation Laboratory (crystallography, spectroscopy, and small-anglescattering of biological molecules), Stanford University
Structural Biology Center (crystallography of biological macromolecules), Argonne NationalLaboratory
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
these programs are addressing problems of hazardous wastemanagement and cleanup in the nation’s civilian sector. TheNational Exposure Research Laboratory, in Research TrianglePark, North Carolina, sponsors research to improve capabilitiesto locate, characterize, and remediate volatile organic com-pounds, including dense non-aqueous phase liquids, in subsur-face environments. The annual budget is about $3.8 million.
The National Risk Management Research Laboratory, inCincinnati, Ohio, sponsors intramural research on contaminatedgroundwater and soil and on containment systems. The ground-water research program focuses on source characterization,remediation, and modeling of organic compounds and such met-als as arsenic. The annual budget is about $4.2 million. The soilresearch program covers in situ remediation, including biotreat-ment, of persistent organic and metal (lead and cadmium) conta-minants in soils, sediments, and unsaturated subsurface environ-
S U B S U R F A C E S C I E N C E
64
SIDEBAR 4.1 LONG-TERM RESEARCH SITES
The U.S. Geological Survey (USGS) maintains a number of long-term research sites for the study of
point source contaminants in the environment. The sites serve as natural laboratories at which scien-
tists conduct experiments and long-term observation. They have proven to be ideal settings for the
development of scientific knowledge about the fate and transport of contaminants.
Examples of sites and contaminants studied include tritium from a low-level radioactive waste disposal
site in Nevada; sewage effluent from ponds in Massachusetts; oil from a petroleum pipeline break in
Minnesota; oxygenated gasoline from buried tanks in South Carolina; creosote effluent from a cre-
osote facility in Florida; mining tailings pond leachate in Arizona; leachate from a landfill in Oklahoma;
and organic contaminants from an arsenal in New Jersey. An uncontaminated site in New Hampshire
was established to study fracture flow. Some of these sites have been in existence for over a decade.
Work at several of the sites was curtailed when scientific interest was satisfied.
Each site is managed by a USGS field scientist who lives and works nearby. This person is responsible
for maintaining a stable research site by maintaining good working relations with the land owner,
scheduling field research, facilitating the research by helping to provide the technical infrastructure,
ensuring that research projects do not interfere with one another, and maintaining the site data base.
A USGS research coordinator is assigned to work with the site manager and to serve as the link
between the site and the research community. Knowledgeable about the site environment and the par-
ticular contaminant, the coordinator is responsible for making the existence of the site known in the
appropriate research communities and to assist the site manager in coordinating science at the site.
The sites have provided fertile environments for scientific study. The prospects of a long-term site with
stable scientific management, field assistance, and a long-term database have attracted top scientists
in multiple disciplines from academia, government, and the private sector.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
ments. The annual program budget is about $5.6 million. Thecontainment research program aims to develop new materialsand methods for containment of contaminated groundwater andsoil; the annual budget is about $1.9 million.
The National Center for Environmental Research andQuality Assurance in Washington, D.C., sponsors five hazardoussubstance research centers in cooperation with universitiesacross the United States. These centers were established underthe Comprehensive Environmental Response, Compensation,and Liability Act (the Superfund Act), and their primary fundingcomes from the EPA (about $8.9 million in fiscal year 1999),with additional funding from other federal agencies, universities,state agencies, and the private sector. These centers haveresearch foci that are related directly to the EM Science Program:
1. The Great Lakes/Mid-Atlantic Center sponsors research onremediation of hazardous organic compounds found in soilsand groundwater. The University of Michigan leads the three-institution consortium.
2. The Great Plains/Rocky Mountain Center sponsors researchon soils and mining wastes contaminated with organic chem-icals and heavy metals. Kansas State University leads a four-teen-institution consortium.
3. The South/Southwest Center sponsors research on in situdetection, mobilization, and remediation of contaminatedsediments. Louisiana State University leads the three-institu-tion consortium.
4. The Western Center sponsors research on groundwatercleanup and site remediation for organic solvents, hydrocar-bons and derivatives, and heavy metals. The center is acooperative activity involving Oregon State University andStanford University.
5. The Gulf Coast Center sponsors research on hazardous sub-stance response and waste management. The center is acooperative activity involving eight universities.
The National Center for Environmental Research and QualityAssurance, in collaboration with DOE, the Office of NavalResearch, and NSF, also sponsors a program in bioremediationthat seeks to understand the chemical, physical, and biologicalprocesses that influence the bioavailability and release of chemi-cals in soil, sediments, and groundwater. The annual funding forthis program is about $1 million.
C h a p t e r 4
65Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
• U.S. Department of Health and Human Services. The NationalInstitute of Environmental Health Sciences sponsors a joint pro-gram with the EPA on the Superfund Hazardous SubstancesBasic Research Program, which has an annual budget of about$37 million. This program supports research to understand haz-ardous waste exposure risks and to support the development ofsite remediation technologies.
• National Science Foundation. Like DOE’s Office of Science, theNSF sponsors several extramural research programs to under-stand fundamental physical, chemical, biological, and geologicalprocesses (see Table 4.1). Some of these programs sponsorresearch that is directly relevant to environmental cleanup, butnone is focused explicitly on the topical areas shown in Figure3.2. There are at least two programs in the NSF that appear to bedirectly relevant to the EM Science Program. The Civil andMechanical Systems Program sponsors basic engineeringresearch, including geotechnical research on materials, contain-ment systems, remediation, and modeling. The annual fundingfor this program is about $59.5 million.9 The NSF also sponsorsa cross-directorate program on Environmental Geochemistry andBiogeochemistry, whose goal is to improve fundamental knowl-edge of chemical processes that control the behavior and distrib-ution of inorganic and organic materials in the environment. Theannual funding for this program is about $4.8 million.
• U.S. Nuclear Regulatory Commission. This agency is chargedwith regulating the production, use, and disposal of radioactivebyproduct materials; it sponsors research through the Center forNuclear Waste Regulatory Analysis in San Antonio, Texas. TheGeohydrology and Geochemistry Section in this center sponsorsresearch on surface and subsurface hydrology related to thetransport and fate of contaminants.
O ther Research ProgramsTable 4.1 lists a number of other programs that sponsor research that
is less directly relevant to the EM Science Program; nevertheless, theseprograms support research that may in the long term support the DOEcleanup effort. The basic research programs in DOE’s Office of Scienceand the National Science Foundation, which were mentioned in the
S U B S U R F A C E S C I E N C E
66
9Only a portion of this total is for geotechnology-related research.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
last section, are good examples. They sponsor research that willincrease the basic knowledge pool that can be accessed by the EMScience Program and its researchers. Many of the researchers whoreceive EM Science Program funding are also being or have been sup-ported by one or more basic research programs in DOE and NSF.
There is another group of programs in Table 4.1 that has some rele-vance for the EM Science Program and DOE’s overall cleanup efforts,namely, the programs that support risk analysis and risk assessmentresearch. Risk assessment is an important step in the remediationprocess, as will be shown in Chapter 5, and the EM Science Program isnow supporting several projects that address risk-related topics (seeChapter 3). There are several research programs in Table 4.1 thataddress various aspects of hazard and risk assessment:
• The EPA’s National Center for Environmental Assessment spon-sors two research programs in this area, one on Superfundhealth risk assessment, with an annual budget of $2.1 million,and a second on Superfund ecological risk assessment, whichhas an annual budget of $1.0 million.
• The EPA’s National Center for Environmental Research andQuality Assurance, in cooperation with the National Institute ofEnvironmental Health Sciences, sponsors a program on complexmixtures that focuses on the mechanistic basis for chemicalinteractions on biological systems. The annual budget is about$2.7 million.
• As mentioned in the last section, the National Institute ofEnvironmental Health Sciences sponsors a joint program withEPA on the Superfund hazardous basic research. One of theobjectives of this program is to understand hazardous wasteexposure risks.
Discuss ionIn responding to its statement of task, the committee attempted to
survey research completed or underway in other federal or state agen-cies that it could use in formulating a long-term research agenda for theEM Science Program. The committee attempted to identify thoseresearch programs that seemed to be most closely related to the EMScience Program and to gain a general understanding of researchobjectives. The committee believes that this review has providedenough information to make the following five observations that will beused to formulate recommendations for the long-term research agendapresented in Chapter 6.
C h a p t e r 4
67Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
1. The federal government is a major sponsor of basic research relat-ed either directly or indirectly to environmental problems. Thecommittee identified almost 50 research programs in its survey(see Table 4.1). If health-related research programs were includedin the committee’s survey, the number would be much higher.
2. There are a large number and variety of programs across the fed-eral government that support research of direct relevance to theEM Science Program and DOE’s cleanup problems. The commit-tee identified 18 such research programs.
3. There appears to be significant overlap in scope among some ofthe programs identified in this analysis, judging from the pro-gram descriptions given in Table 4.1. Overlap is not necessarilyundesirable, but it is not clear whether there is an effectivemechanism to coordinate these programs. There are somenotable exceptions to this generalization, especially for thoseprograms listed in Table 4.1 that are jointly managed by severalagencies (e.g., the Strategic Environmental Research andDevelopment Program, which is managed by the DOD in coop-eration with DOE and the EPA.).
4. Many of the 18 directly relevant programs identified in point 2above focus on hazardous chemicals, and to a lesser extent onheavy metals. There appear to be few programs that addressradionuclide contamination outside DOE.
5. Many of the 18 directly relevant programs also focus on remedi-ation, and especially bioremediation. Other remediationapproaches and other important research topics related to envi-ronmental cleanup (e.g., contaminant location and characteriza-tion in the subsurface) appear to be receiving less attention.
The committee believes there would be value added to the federalgovernment’s basic research on environmental problems if there wasbetter coordination among its research programs, especially the mis-sion-directed programs. The committee sees an opportunity for EMScience Program managers to promote and foster such coordination.
There are many good coordinating mechanisms that have been usedelsewhere in the federal government that could be adapted to coordi-nate these mission-directed environmental research programs. Theserange from formal coordinating mechanisms like the Federal Remedi-
S U B S U R F A C E S C I E N C E
68
10The Federal Remediation Technologies Roundtable is an interagency coordi-nating group comprising representatives of federal agencies with hazardous wastecleanup responsibilities. The roundtable provides a forum for information
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
ation Technologies Roundtable10 to more informal mechanisms likeperiodic meetings of interested program managers, or even joint spon-sorship of field research sites to address specific contamination prob-lems. Regardless of the mechanisms, however, the objective should beto improve communication among federal program managers, reduceunnecessary duplication and overlap among programs, and help pro-gram managers focus their resources on those problems that providethe greatest challenges to the nation’s environmental cleanup efforts.
C h a p t e r 4
69
exchange and joint action concerning the development and demonstration ofinnovative technologies for hazardous waste remediation. Additional informationis available at http://www.frtr.gov.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
70
TABL
E 4.
1 R
eleva
nt R
esea
rch in
Fede
ral A
genc
ies
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
U.S
.DEP
AR
TMEN
T O
F A
GR
ICU
LTU
RE
Ag
ricul
tura
l N
atio
nal P
rog
ram
on
Wat
er Q
ualit
y an
d
All
soil
and
wat
er w
ithin
ARS
:In
tra
http
://w
ww
.np
s.ar
s.us
da.
gov
/Re
sear
ch S
ervi
ceN
atur
al R
esou
rces
and
W
ater
Man
agem
ent
FY 9
9:$8
6M F
Y 98
:$86
M
pro
gra
ms/
201b
.htm
Sust
aina
ble
Ag
ricul
ture
The
prim
ary
mis
sion
of t
his
natio
nal p
rog
ram
is t
wof
old
:to
dev
elop
inno
vativ
e co
ncep
ts fo
r det
erm
inin
g t
he m
ovem
ent
of w
ater
and
its
asso
ciat
ed c
onst
ituen
ts in
ag
ricul
tura
lla
ndsc
apes
and
wat
ersh
eds,
and
to
dev
elop
new
and
imp
rove
d p
ract
ices
,tec
hnol
ogie
s,an
d s
trat
egie
s fo
r man
agin
g t
he n
atio
n’s
agric
ultu
ral w
ater
reso
urce
s.Th
ese
adva
nces
will
pro
vid
e fo
od a
nd fi
ber
pro
duc
ers,
loca
l com
mun
ities
,and
reso
urce
man
agem
ent
agen
cies
with
too
ls t
o im
pro
ve w
ater
con
serv
atio
n an
d w
ater
use
effi
cien
cy in
irrig
ated
and
dry
land
ag
ricul
ture
,enh
ance
wat
er q
ualit
y,p
rote
ct ru
ral c
omm
uniti
es fr
om t
he ra
vag
es o
f flo
ods
and
dro
ught
s,an
d p
reve
nt t
he d
egra
dat
ion
of la
ndsc
apes
,aq
uatic
eco
syst
ems,
and
str
eam
cor
ridor
s.
Ag
ricul
tura
l So
il,W
ater
,and
Air
Coo
per
ativ
e $2
MBo
th
http
://hy
dro
lab.
arsu
sda.
gov
/Re
sear
ch S
ervi
ceQ
ualit
y/ E
nviro
nmen
tal
Rese
arch
:met
als
in
ecl/
CRI
S%20
Rep
orts
/met
alsi
n1.h
tmC
hem
istr
y La
bor
ator
yso
il;m
etal
s/p
lant
up
take
This
pro
gra
m t
arg
ets
toxi
c tr
ace
elem
ents
,org
anic
ag
roch
emic
als,
and
rad
ionu
clid
es.T
he m
ain
app
roac
hes
incl
ude:
a) u
se o
f sp
ecia
lly d
esig
ned
bio
solid
com
pos
t to
red
uce
the
bio
avai
lab
ility
of t
oxic
tra
ce e
lem
ents
,b) p
hyto
rem
edia
tion
usin
g h
yper
accu
mul
ator
pla
nts
or p
lant
s th
at c
onve
rt t
oxic
ele
men
ts t
o no
ntox
ic fo
rms,
and
c) a
ccel
erat
ed m
icro
bia
ld
egra
dat
ion
of o
rgan
ic c
omp
ound
s.Fu
ndin
g fo
r thi
s p
rog
ram
is a
pp
roxi
mat
ely
$1.5
M o
f ag
ency
fund
ing
and
ap
pro
xim
atel
y $0
.5M
in g
rant
fund
ing
per
yea
r.
U.S
.DEP
AR
TMEN
T O
F C
OM
MER
CE
Nat
iona
l Ins
titut
e C
hem
ical
Sci
ence
and
D
ivis
ions
FY
98:
Intr
aht
tp://
ww
w.n
ist.g
ov/
of S
tand
ard
s an
d
Tech
nolo
gy
Lab
orat
ory
(ap
pro
xim
ate
Ap
pro
xim
atel
y $5
8Mp
ublic
_affa
irs/g
uid
e/cs
tpag
e.ht
mTe
chno
log
y fu
ndin
g le
vels
b
ased
on
FY98
p
roje
ctio
ns):
Biot
echn
olog
y (~
$10.
3M)
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
C h a p t e r 4
71
Proc
ess
Mea
sure
men
ts
(~$1
0.6M
)
Surf
ace
and
M
icro
anal
ysis
Sc
ienc
e (~
$8.4
M)
Phys
ical
and
C
hem
ical
Pro
per
ties
(~$1
3.3M
)
Ana
lytic
al C
hem
istr
y (~
$13.
9M)
The
Che
mic
al S
cien
ce a
nd T
echn
olog
y La
bor
ator
y p
erfo
rms
cutt
ing
-ed
ge
rese
arch
in m
easu
rem
ent
scie
nce;
dev
elop
s an
d m
aint
ains
mea
sure
men
t m
etho
ds,
stan
dar
ds,
and
ref-
eren
ce d
ata;
and
dev
elop
s m
odel
s fo
r che
mic
al,b
ioch
emic
al,a
nd p
hysi
cal p
rop
ertie
s an
d p
roce
sses
.The
lab
pro
vid
es t
hese
cap
abili
ties
to e
nhan
ce U
.S.i
ndus
try'
s p
rod
uctiv
ityan
d c
omp
etiti
vene
ss;e
nsur
e eq
uity
in t
rad
e;an
d im
pro
ve p
ublic
hea
lth,s
afet
y,an
d e
nviro
nmen
tal q
ualit
y.
Nat
iona
l Ins
titut
e M
ater
ials
Sci
ence
and
D
ivis
ions
FY
98:
Both
http
://w
ww
.mse
l.nis
t.gov
/of
Sta
ndar
ds
and
En
gin
eerin
g L
abor
ator
y (a
pp
roxi
mat
e A
pp
roxi
mat
ely
$50M
Tech
nolo
gy
fund
ing
leve
ls
bas
ed o
n FY
98
pro
ject
ions
):
Mat
eria
ls (~
$5.7
M)
Met
allu
rgy
(~$1
0.9M
)
Poly
mer
s (~
$8.9
M)
Cer
amic
s (~
$11.
9M)
NIS
T C
ente
r for
N
eutr
on R
esea
rch
(~$1
4.9M
)
The
Mat
eria
ls S
cien
ce a
nd E
ngin
eerin
g L
abor
ator
y p
rovi
des
tec
hnic
al le
ader
ship
and
par
ticip
ates
in d
evel
opin
g t
he m
easu
rem
ent
and
sta
ndar
ds
infr
astr
uctu
re re
late
d t
o m
ater
i-al
s cr
itica
l to
U.S
.ind
ustr
y,ac
adem
ia,g
over
nmen
t,an
d t
he p
ublic
.Mat
eria
ls s
cien
ce a
nd e
ngin
eerin
g p
rog
ram
s co
ver a
full
rang
e of
mat
eria
ls is
sues
from
des
ign
to p
roce
ssin
g t
op
erfo
rman
ce.A
uni
fyin
g a
im is
to
acq
uire
the
kno
wle
dg
e an
d t
ools
nee
ded
for i
ntel
ligen
t m
anuf
actu
ring
met
hod
s w
ith re
al-t
ime
auto
mat
ed p
roce
ss c
ontr
ols.
Sep
arat
e re
sear
chin
itiat
ives
ad
dre
ss c
eram
ics,
met
als,
pol
ymer
s,co
mp
osite
s,an
d s
uper
cond
ucto
rs.T
his
rese
arch
sup
por
ts e
ffort
s of
U.S
.ind
ustr
y to
dev
elop
relia
ble
,low
-cos
t m
anuf
actu
ring
met
h-od
s fo
r tai
lor-
mad
e m
ater
ials
and
pro
duc
ts w
ith s
uper
ior p
rop
ertie
s.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Nat
iona
l Ins
titut
ePh
ysic
s La
bor
ator
yD
ivis
ions
FY
98:
Both
http
://p
hysi
cs.n
ist.g
ov/
of S
tand
ard
s an
d
(fund
ing
leve
ls a
re
Ap
pro
xim
atel
y $4
8.3M
Tech
nolo
gy
app
roxi
mat
e b
ased
on
pro
ject
ions
fo
r FY9
8:
Elec
tron
& O
ptic
al
Phys
ics
(~$5
.8M
)
Ato
mic
Phy
sics
(~
$8.1
M)
Op
tical
Tec
hnol
ogy
(~$1
1.1M
)
Ioni
zing
Rad
iatio
n (~
$6.8
M)
Tim
e an
d F
req
uenc
y (~
$8.4
M)
Qua
ntum
Phy
sics
(~
$5.8
)
The
Phys
ics
Lab
orat
ory
is o
ne o
f the
maj
or o
per
atin
g u
nits
of t
he N
atio
nal I
nstit
ute
of S
tand
ard
s an
d T
echn
olog
y.It
s m
issi
on is
to
sup
por
t U
.S.i
ndus
try
by
pro
vid
ing
mea
sure
-m
ent
serv
ices
and
rese
arch
for e
lect
roni
c,op
tical
,and
rad
iatio
n te
chno
log
ies.
The
lab
orat
ory
pur
sues
dire
cted
rese
arch
in t
he p
hysi
cal s
cien
ces;
dev
elop
s ne
w p
hysi
cal s
tand
ard
s,m
easu
rem
ent
met
hod
s,an
d d
ata;
cond
ucts
an
agg
ress
ive
dis
sem
inat
ion
pro
gra
m;a
nd c
olla
bor
ates
with
ind
ustr
y to
com
mer
cial
ize
inve
ntio
ns a
nd d
isco
verie
s.Pr
ogra
ms
span
the
full
rang
e fr
om t
ests
of f
und
amen
tal p
ostu
late
s of
phy
sics
thr
oug
h g
ener
ic t
echn
olog
y to
the
mor
e im
med
iate
nee
ds
of in
dus
try
and
com
mer
ce.I
ts c
onst
ituen
cy is
bro
adly
dis
trib
uted
thr
oug
hout
aca
dem
ia,g
over
nmen
t,an
d in
dus
try.
S U B S U R F A C E S C I E N C E
72
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
U.S
.DEP
AR
TMEN
T O
F D
EFEN
SE
Air
Forc
eA
ir Fo
rce
Mat
erie
l C
hem
istr
y an
d L
ife
Ap
pro
xim
atel
y $5
M
Both
http
://w
eb.fi
e.co
m/
Com
man
d/A
ir Fo
rce
Scie
nces
:Bio
-an
nual
ly ($
2M in
tra/
ht
doc
/fed
/afr
/afo
/any
/tex
t/O
ffice
of S
cien
tific
en
viro
nmen
tal
$3M
ext
ra)
any/
rib99
-1.h
tm#6
Rese
arch
/Air
Forc
e Sc
ienc
eRe
sear
ch L
abor
ator
y
The
Bioe
nviro
nmen
tal S
cien
ce P
rog
ram
sup
por
ts t
oxic
olog
y-re
late
d re
sear
ch t
hat
inve
stig
ates
the
inte
ract
ions
of b
iolo
gic
al s
yste
ms
with
non
-ioni
zing
rad
iatio
n an
d c
hem
ical
s of
inte
rest
to
the
Air
Forc
e.A
ir Fo
rce
oper
atio
ns u
se p
hysi
cal a
nd c
hem
ical
ag
ents
suc
h as
non
-ioni
zing
rad
iant
ene
rgie
s (r
adio
freq
uenc
y ra
dia
tion,
mic
row
aves
,and
lase
r lig
ht),
heav
y m
etal
s (c
hrom
ium
and
cad
miu
m),
and
var
ious
che
mic
als
that
con
stitu
te fu
els,
pro
pel
lant
s,an
d lu
bric
ants
of i
nter
est
to t
he A
ir Fo
rce
that
can
be
pot
entia
lly h
arm
ful t
o m
ili-
tary
and
civ
ilian
per
sonn
el,t
o th
e su
rrou
ndin
g p
opul
ace,
or t
o th
e en
viro
nmen
t.Ex
pos
ure
to t
hese
ag
ents
may
be
a d
irect
resu
lt of
the
ir us
e d
urin
g A
ir Fo
rce
oper
atio
ns a
ndm
aint
enan
ce a
nd,i
n th
e ca
se o
f che
mic
als,
may
als
o oc
cur i
ndire
ctly
as
a re
sult
of le
aky
stor
age
cont
aine
rs t
hat
cont
amin
ate
was
te s
trea
ms,
gro
und
wat
er,a
nd s
oil.T
he A
ir Fo
rce
sup
por
ts b
asic
rese
arch
to
und
erst
and
the
bio
log
ical
effe
cts
of t
hese
ag
ents
,the
ir m
echa
nism
s of
tox
icity
,and
the
use
of e
xper
imen
tal a
nd c
omp
utat
iona
l mod
elin
g in
ass
essi
ngth
eir p
oten
tial h
ealth
ris
ks.
Air
Forc
eA
ir Fo
rce
Mat
erie
l M
ater
ials
and
A
pp
roxi
mat
ely
Intr
aht
tp://
ww
w.m
l.afr
l.af.m
il/C
omm
and
/Air
Forc
e M
anuf
actu
ring
$3
00,0
00 a
nnua
llyd
ivis
ions
/mlq
/wud
_bt.h
tml
Offi
ce o
f Sci
entif
ic
Dire
ctor
ate/
Rese
arch
/Air
Forc
e Bi
otec
hnol
ogy
Rese
arch
Lab
orat
ory
The
Biot
echn
olog
y D
ivis
ion
cond
ucts
in-h
ouse
rese
arch
in b
iod
egra
dat
ion,
spec
ifica
lly s
trat
egie
s to
pre
dic
t,en
hanc
e,or
pre
vent
mic
rob
ial a
ttac
k on
mat
eria
ls a
nd in
bio
cata
lysi
sto
dis
cove
r and
enh
ance
nov
el m
etab
olic
pro
cess
es fo
r use
in s
ynth
esis
of m
ater
ials
.Thi
s p
rog
ram
focu
ses
on m
itig
atin
g t
he A
ir Fo
rce'
s in
dus
tria
l haz
ard
ous
was
te s
trea
ms,
and
red
ucin
g o
r pre
vent
ing
env
ironm
enta
l con
tam
inat
ion
at A
ir Fo
rce
and
oth
er D
epar
tmen
t of
Def
ense
site
s.Th
is w
ill m
inim
ize
the
hig
h co
sts
and
tox
ic b
ypro
duc
ts o
f con
vent
ion-
al c
hem
istr
y fo
r mat
eria
ls p
rod
uctio
n.
Arm
yA
rmy
Mat
erie
l M
echa
nica
l and
$4
.6M
aEx
tra
http
://w
ww
.aro
.arm
y.m
il/C
omm
and
/Arm
y En
viro
nmen
tal
rese
arch
/baa
99-1
/baa
99.h
tm#e
sRe
sear
ch L
abor
ator
y/Sc
ienc
es D
ivis
ion:
Arm
y Re
sear
ch O
ffice
Terr
estr
ial S
cien
ces
Prog
ram
The
Terr
estr
ial S
cien
ces
Prog
ram
is c
once
rned
with
the
imp
act
of E
arth
's s
urfic
ial e
nviro
nmen
t on
Arm
y ac
tiviti
es.P
rog
ram
inte
rest
s co
ver a
bro
ad s
pec
trum
,ran
gin
g fr
om t
erra
inch
arac
teriz
atio
n an
d a
naly
sis,
to m
ilita
ry e
ngin
eerin
g a
nd m
obili
ty c
onsi
der
atio
ns u
nder
com
bat
con
diti
ons,
to e
nviro
nmen
tal m
anag
emen
t an
d s
tew
ard
ship
.Prim
ary
emp
hasi
sis
dire
cted
tow
ard
und
erst
and
ing
the
beh
avio
r of t
he la
nd s
urfa
ce a
nd t
he n
ear-
surf
ace
envi
ronm
ents
,und
erst
and
ing
the
nat
ural
pro
cess
es o
per
atin
g o
n an
d in
the
se d
omai
ns,
and
mod
elin
g t
hese
env
ironm
ents
for p
red
ictiv
e an
d s
imul
atio
n p
urp
oses
.Sp
ecia
l em
pha
sis
is g
iven
to
the
need
to
bet
ter u
nder
stan
d,m
odel
,and
pre
dic
t th
ose
cond
ition
s th
atar
e m
ost
extr
eme,
dyn
amic
,or r
estr
ictiv
e to
sys
tem
s p
erfo
rman
ce o
r mili
tary
op
erat
ions
.The
thr
ee a
reas
of c
urre
nt in
tere
st t
o th
e p
rog
ram
are
ter
rain
pro
per
ties
and
cha
ract
eri-
zatio
n,te
rres
tria
l pro
cess
es a
nd la
ndsc
ape
dyn
amic
s,an
d t
erre
stria
l sys
tem
mod
elin
g a
nd m
odel
inte
gra
tion.
In a
ll ca
ses,
the
emp
hasi
s is
on
bas
ic re
sear
ch.
C h a p t e r 4
73Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Arm
y M
ater
iel
Mec
hani
cal a
nd
Spec
ial P
rog
ram
s:A
pp
roxi
mat
ely
Extr
abht
tp://
ww
w.a
ro.a
rmy.
mil/
Com
man
d/
Envi
ronm
enta
l C
ente
r for
Mul
tipha
se
$1M
ann
ually
aror
ev/e
nviro
ma.
htm
Arm
y Re
sear
ch
Scie
nces
Div
isio
n:Fl
uid
Flo
w a
nd
Lab
orat
ory/
Arm
y Te
rres
tria
l Sc
ienc
es
Con
tam
inan
t ht
tp://
cmr.s
ph.
unc.
edu/
CM
R/Re
sear
ch O
ffice
Prog
ram
Tran
spor
tht
tp://
cmr.s
ph.
unc.
edu/
CM
R/
The
rese
arch
tea
m is
eng
aged
in a
var
iety
of e
xper
imen
tal,
theo
retic
al,a
nd n
umer
ical
stu
die
s d
irect
ed t
owar
d u
nder
stan
din
g t
he fu
ndam
enta
ls o
f flu
id fl
ow a
nd c
onta
min
ant
tran
spor
t p
roce
sses
in h
eter
ogen
eous
,mul
tipha
se p
orou
s m
edia
sys
tem
s.Th
e ob
ject
ives
are
:(1)
to
obse
rve
fluid
flow
and
con
tam
inan
t tr
ansp
ort
thro
ugh
cont
rolle
d la
bor
ator
yex
per
imen
ts a
t a
varie
ty o
f sca
les;
(2) t
o d
evel
op a
nd a
pp
ly n
umer
ical
mod
els
to s
imul
ate
flow
and
tra
nsp
ort;
and
(3) t
o th
eore
tical
ly e
valu
ate
the
pra
ctic
al c
onse
que
nces
and
effe
cts
of fl
ow a
nd t
rans
por
t p
heno
men
a in
the
con
text
of t
he d
ual g
oals
of i
mp
rove
d m
odel
ing
cap
abili
ties
and
pra
ctic
al p
roce
dure
s fo
r and
effi
cien
cy in
env
ironm
enta
lre
stor
atio
n.Th
e ce
nter
is a
t th
e U
nive
rsity
of N
orth
Car
olin
a an
d s
upp
orte
d b
y m
ultip
le o
rgan
izat
ions
(Cra
y Re
sear
ch,I
nc.;G
erm
an A
cad
emic
Exc
hang
e Se
rvic
e;Su
per
fund
Bas
icRe
sear
ch P
rog
ram
;Nor
th C
arol
ina
Sup
erco
mp
utin
g C
ente
r;U
.S.A
rmy
Rese
arch
Offi
ce;U
.S.A
rmy
Wat
erw
ays
Exp
erim
ent
Stat
ion;
and
U.S
.Dep
artm
ent
of E
nerg
y).
Rese
arch
und
er-
take
n b
y th
e U
nive
rsity
of N
orth
Car
olin
a,C
hap
el H
ill t
eam
has
bee
n co
ord
inat
ed a
nd s
hare
d w
ith A
rmy
rese
arch
ers
at t
he U
.S.A
rmy
Cor
ps
of E
ngin
eers
Wat
erw
ays
Exp
erim
ent
Stat
ion.
Thes
e ef
fort
s ha
ve re
sulte
d in
ap
pro
ache
s an
d c
omp
uter
cod
es t
hat
are
read
ily a
pp
licab
le t
o fie
ld a
pp
licat
ions
,and
hav
e b
een
mad
e av
aila
ble
to
the
Dep
artm
ent
ofD
efen
se G
roun
d w
ater
Mod
el S
yste
m P
rog
ram
.
Arm
yU
.S.A
rmy
Cor
ps
of
Envi
ronm
enta
l A
pp
roxi
mat
ely
Intr
acht
tp://
ww
w.w
es.a
rmy.
mil/
Eng
inee
rs/W
ater
way
s La
bor
ator
y/Fa
te a
nd
$4M
ann
ually
el
/env
rest
.htm
lEx
per
imen
t St
atio
nEf
fect
s Re
sear
ch
Vick
sbur
g,M
issi
ssip
pi
Fate
and
effe
cts
rese
arch
beg
an in
the
ear
ly 1
970s
to
sup
por
t th
e C
orp
s d
red
gin
g p
rog
ram
s,w
hich
incl
uded
dev
elop
men
t of
tes
ting
man
uals
for s
edim
ent
cont
amin
ants
.Thi
sw
as q
uick
ly e
xpan
ded
to
was
te c
hara
cter
izat
ion,
envi
ronm
enta
l mon
itorin
g,nu
mer
ical
mod
elin
g,an
d p
hysi
cal a
nd b
iolo
gic
al p
roce
sses
.Res
ults
of t
his
rese
arch
wer
e us
ed t
oas
sist
with
was
te d
isp
osal
pra
ctic
es a
nd g
roun
d w
ater
mon
itorin
g a
t su
ch fa
cilit
ies
as A
ber
dee
n Pr
ovin
g G
roun
ds,
Rock
y M
ount
ain
Ars
enal
,and
Pin
e Bl
uff A
rsen
al.E
nviro
nmen
tal
fate
and
effe
cts
rese
arch
at
the
stat
ion
enco
mp
asse
s a
varie
ty o
f pro
gra
ms
in s
upp
ort
of D
epar
tmen
t of
Def
ense
ag
enci
es,o
ther
fed
eral
ag
enci
es,a
nd v
ario
us s
tate
ag
enci
es.T
his
envi
ronm
enta
l R&
D w
as d
evel
oped
from
Cor
ps
civi
l wor
ks p
rog
ram
s w
ith m
ajor
reim
bur
sab
le w
ork
from
mili
tary
and
civ
ilian
sp
onso
rs.R
&D
has
freq
uent
ly b
een
imp
lem
ente
d in
a co
oper
ativ
e en
viro
nmen
t w
ith o
ther
fed
eral
ag
enci
es (s
uch
as t
he U
.S.E
PA) t
o p
rovi
de
unifo
rm g
uid
ance
to
spon
sors
.
S U B S U R F A C E S C I E N C E
74
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Arm
yU
.S.A
rmy
Cor
ps
of
Envi
ronm
enta
l N
ot A
vaila
ble
Intr
aht
tp://
ww
w.w
es.a
rmy.
mil/
Eng
inee
rs /
Wat
erw
ays
Lab
orat
ory/
Dre
dg
ing
el
/dot
s/d
oer/
cs.h
tml
Exp
erim
ent
Stat
ion
Op
erat
ions
and
En
viro
nmen
tal
Rese
arch
/Con
tam
i-na
nt S
edim
ents
Foc
us
This
pro
gra
m e
xam
ines
the
mos
t co
mm
only
con
sid
ered
alte
rnat
ives
for c
onta
min
ated
sed
imen
ts,w
hich
are
pla
cem
ent
in c
onfin
ed d
ispo
sal f
acili
ties
(CD
Fs) a
nd c
app
ing,
anop
tion
for c
onta
inm
ent
in s
ubaq
ueou
s si
tes.
CD
Fs a
re lo
cate
d o
n la
nd o
r in
area
s of
rela
tivel
y sh
elte
red
wat
er.M
any
CD
Fs a
re n
ear c
losu
re,a
nd fu
ture
loca
tions
may
incl
ude
non-
trad
ition
al a
reas
suc
h as
offs
hore
.Tre
atm
ent
to re
clai
m C
DF
cap
acity
may
be
pro
mis
ing
for c
erta
in s
ites.
Cap
pin
g h
as s
igni
fican
t pot
entia
l as
a d
isp
osal
alte
rnat
ive,
but
issu
esre
late
d t
o its
long
-ter
m e
ffect
iven
ess
and
pot
entia
l ap
plic
atio
n to
dee
per
wat
ers
or h
igh-
ener
gy
envi
ronm
ents
req
uire
ad
diti
onal
env
ironm
enta
l inv
estig
atio
n.Th
is p
rog
ram
will
add
ress
hig
h p
riorit
y re
sear
ch n
eed
s ai
med
at
red
ucin
g c
osts
ass
ocia
ted
with
scr
eeni
ng a
nd a
sses
sing
pot
entia
l im
pac
ts o
f con
tam
inan
ts a
nd in
crea
sing
the
relia
bili
ty a
ndac
cep
tab
ility
of C
DF
and
cap
pin
g o
ptio
ns fo
r man
agem
ent
of c
onta
min
ated
sed
imen
ts.
Def
ense
Ad
vanc
ed
Def
ense
Sci
ence
s C
hem
ical
Plu
me
Ap
pro
xim
atel
y Ex
tra
http
://w
ww
.dar
pa.
mil/
Rese
arch
Pro
ject
s O
ffice
Trac
ing
$15M
DSO
/sol
icita
tions
/RA
98-0
9/A
gen
cy (D
ARP
A)
(Joi
nt p
rog
ram
S/
add
ition
al.h
tml
with
the
Offi
ce
of N
aval
Res
earc
h)ht
tp://
ww
w.d
arp
a.m
il/D
SO/s
olic
itatio
ns/R
A98
-09/
S/cb
d.ht
ml
Man
y an
imal
s (e
.g.,l
obst
ers,
mot
hs,a
nd d
ogs)
are
cap
able
of t
rack
ing
che
mic
al p
lum
es t
o th
eir s
ourc
e.It
is b
elie
ved
tha
t a
care
ful u
nder
stan
din
g o
f how
ani
mal
s ac
com
plis
h th
ista
sk w
ill le
ad t
o th
e d
evel
opm
ent
of a
rtifi
cial
plu
me
trac
ing
sys
tem
s th
at c
an b
e em
plo
yed
to
loca
te t
he s
ourc
e of
che
mic
al p
lum
es fo
r a v
arie
ty o
f ap
plic
atio
ns,i
nclu
din
g t
helo
catio
n of
land
min
es (u
sing
plu
mes
in a
ir) a
nd u
nder
wat
er u
nexp
lod
ed o
rdna
nce
(usi
ng p
lum
es in
wat
er).
Def
ense
Ad
vanc
ed
Def
ense
Sci
ence
s C
ontr
olle
d
Not
ava
ilab
leEx
tra
http
://w
ww
.dar
pa.
mil/
Rese
arch
Pro
ject
s O
ffice
Biol
ogic
al S
yste
ms
DSO
/sol
icita
tions
/A
gen
cy (D
ARP
A)
BAA
98-0
7/S/
cbd.
htm
The
prin
cip
al o
bje
ctiv
e of
thi
s p
rog
ram
is t
o co
ntro
l,in
fluen
ce,a
nd m
onito
r dis
trib
uted
bio
log
ical
sys
tem
s.A
pp
licat
ions
of i
nter
est
incl
ude
cont
rolli
ng t
he d
istr
ibut
ion
of b
iolo
gi-
cal s
yste
ms
for r
eal-t
ime
mon
itorin
g o
f ind
ivid
uals
or p
opul
atio
ns o
f org
anis
ms
(e.g
.,sw
arm
s,hi
ves,
den
s,sc
hool
s) t
o se
ek o
ut a
nd c
olle
ct in
form
atio
n in
the
env
ironm
ent
(air,
land
,or w
ater
) ab
out
agen
ts o
f har
m,i
nclu
din
g c
hem
ical
or b
iolo
gic
al w
eap
ons
and
une
xplo
ded
ord
nanc
e.Th
e p
rog
ram
will
exp
lore
the
con
trol
of b
iolo
gic
al s
yste
ms
as fi
rst
war
ning
sys
tem
s fo
r pre
dic
ting
hum
an h
ealth
ris
k.A
pp
licat
ion
of c
ontr
olle
d b
iolo
gic
al s
yste
ms
coul
d in
clud
e m
app
ing
ag
ent
conc
entr
atio
n an
d d
istr
ibut
ion
in p
oten
tially
con
ta-
min
ated
air,
land
,and
wat
er,a
nd c
ount
erm
easu
re d
eliv
ery
or in
telli
gen
ce in
form
atio
n g
athe
ring
in h
ostil
e or
inac
cess
ible
env
ironm
ents
.All
pro
gra
m a
spec
ts a
re fo
r def
ensi
vep
urp
oses
onl
y.O
ther
ap
plic
atio
ns c
ould
invo
lve
cont
rolli
ng t
he d
istr
ibut
ion
of p
est
org
anis
ms
to im
pro
ve o
per
atio
nal e
nviro
nmen
ts fo
r tro
ops.
To a
ccom
plis
h th
is o
bje
ctiv
e th
ep
rog
ram
will
see
k to
mon
itor a
nd u
se t
he s
enso
ry s
igna
ls (e
.g.,c
hem
ical
,vis
ual,
ther
mal
,aco
ustic
,oth
er) e
mp
loye
d b
y b
iolo
gic
al o
rgan
ism
s to
fora
ge
and
rep
rod
uce
in t
heir
envi
-ro
nmen
t.Re
sear
cher
s al
so s
eek
to d
evel
op re
volu
tiona
ry m
etho
ds
to in
terf
ace
with
ind
ivid
uals
or p
opul
atio
ns o
f bio
log
ical
sys
tem
s as
the
y d
istr
ibut
e in
the
env
ironm
ent.
The
Con
trol
led
Bio
log
ical
Sys
tem
s Pr
ogra
m s
eeks
maj
or t
echn
olog
y in
nova
tion
in n
ew c
once
pts
for "
plu
gg
ing
into
" th
e si
gna
ls u
sed
by
bio
log
ical
org
anis
ms
and
usi
ng t
hem
to
dire
ct d
istr
ibut
ion
of b
iolo
gic
al s
yste
ms
and
to
colle
ct e
nviro
nmen
tal i
nfor
mat
ion.
C h a p t e r 4
75Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Nav
yO
ffice
of N
aval
M
ater
ials
Sci
ence
N
ot a
vaila
ble
dBo
thht
tp://
cbm
sew
s1.n
rl.na
vy.m
il/Re
sear
ch/
and
Com
pon
ent
Tech
nolo
gy
http
://he
ron.
nrl.n
avy.
mil/
Nav
al R
esea
rch
Dire
ctor
ate/
cont
ract
s/99
baa
/951
.htm
Lab
orat
ory
Cen
ter f
or B
io-
http
://he
ron.
nrl.n
avy.
mil/
Mol
ecul
ar S
cien
ce
cont
ract
s/99
baa
/924
.htm
and
Eng
inee
ring
The
Cen
ter f
or B
io-M
olec
ular
Sci
ence
and
Eng
inee
ring
con
duc
ts m
ultid
isci
plin
ary
rese
arch
in b
iote
chno
log
y,us
ing
the
tec
hniq
ues
of m
oder
n m
olec
ular
bio
log
y,b
iop
hysi
cs,
chem
istr
y,m
icro
elec
tron
ics,
and
eng
inee
ring
to
fab
ricat
e b
iose
nsor
s,b
iom
ater
ials
,and
ad
vanc
ed s
yste
ms.
Cur
rent
rese
arch
are
as in
clud
e (1
) bio
phy
sica
l che
mis
try
of m
emb
rane
s;(2
) res
earc
h in
to b
iose
nsor
s,in
clud
ing
con
stru
ctio
n of
nov
el d
evic
es,a
cces
sorie
s fo
r aut
omat
ed re
agen
t d
eliv
ery,
pro
duc
tion
of b
iom
olec
ular
reco
gni
tion
elem
ents
,or c
onfig
ura-
tion
of b
ioas
says
for i
nteg
ratio
n in
to t
he s
enso
r (ta
rget
s of
det
ectio
n in
clud
e ex
plo
sive
s,p
ollu
tant
s,p
atho
gen
s,to
xic
agen
ts,a
nd h
azar
dou
s ch
emic
als)
;(3)
gen
etic
eng
inee
ring
of
bio
mat
eria
ls;(
4) s
elf-
asse
mb
led
film
s an
d p
atte
rns
for a
dva
nced
mat
eria
l dev
elop
men
t;(5
) lip
osom
al d
eliv
ery
of v
acci
nes
and
pha
rmac
eutic
als;
and
(6) p
hysi
cal c
hara
cter
izat
ion
of t
hin
film
s an
d s
urfa
ces.
Nav
yO
ffice
of N
aval
C
hem
istr
y D
ivis
ion
Ap
pro
xim
atel
y In
tra
http
://ch
emd
iv-w
ww
.nrl.
navy
.mil/
Rese
arch
/En
viro
nmen
t an
d
$100
M a
nnua
llyin
dex
.htm
lBi
otec
hnol
ogy
Nav
al R
esea
rch
Bran
ch
Lab
orat
ory
This
Env
ironm
ent
and
Bio
tech
nolo
gy
Bran
ch h
as b
road
man
agem
ent
resp
onsi
bili
ty fo
r bio
tech
nolo
gy
pro
gra
ms
with
in t
he N
RL a
nd t
he D
OD
.The
pro
gra
m m
anag
er s
erve
s as
exp
ert
cons
ulta
nt a
nd a
dvi
sor i
n b
iote
chno
log
y to
the
Cen
ter f
or B
iom
olec
ular
Sci
ence
and
Eng
inee
ring,
the
div
isio
n su
per
inte
nden
t,to
the
ass
ocia
te d
irect
or o
f res
earc
h fo
rm
ater
ials
sci
ence
and
com
pon
ent
tech
nolo
gy,
and
to
the
dire
ctor
of d
efen
se re
sear
ch a
nd e
ngin
eerin
g in
the
Offi
ce o
f the
Und
er S
ecre
tary
of D
efen
se.A
dd
ition
ally
,the
pro
gra
mm
anag
er s
erve
s as
a N
avy/
DO
D re
pre
sent
ativ
e or
liai
son
to n
umer
ous
inte
rag
ency
com
mitt
ees.
The
pro
gra
m is
div
ided
into
med
ical
and
non
med
ical
(or m
ater
ials
) bio
tech
nolo
-g
y.Th
is t
echn
olog
y ha
s th
e p
oten
tial t
o p
rod
uce
new
vac
cine
s an
d t
hera
pie
s,ne
w s
truc
tura
l mat
eria
ls,a
nd p
ract
ical
sol
utio
ns t
o w
aste
site
rem
edia
tion.
Thru
st a
reas
are
bio
sen-
sors
,bio
pro
cess
ing,
mat
eria
ls,b
iom
icro
elec
tron
ics,
and
bio
rem
edia
tion.
This
pro
gra
m is
a D
OD
crit
ical
tec
hnol
ogy
and
is c
onsi
der
ed a
gro
wth
are
a.
S U B S U R F A C E S C I E N C E
76
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Nav
yO
ffice
of N
aval
C
hem
istr
y D
ivis
ion
Not
ava
ilab
leIn
tra
http
://p
ony.
nrl.n
avy.
mil/
eqsh
ome.
htm
lRe
sear
ch/
http
://ch
emd
iv-w
ww
.nrl.
navy
.mil/
Nav
al R
esea
rch
Che
mic
al D
ynam
ics
ind
ex.h
tml
Lab
orat
ory
and
Dia
gno
stic
s Br
anch
Envi
ronm
enta
l Q
ualit
y Sc
ienc
e Se
ctio
n
The
Envi
ronm
enta
l Qua
lity
Scie
nces
Sec
tion
cond
ucts
bas
ic a
nd a
pp
lied
rese
arch
in (1
) the
dev
elop
men
t an
d im
ple
men
tatio
n of
in s
itu re
med
iatio
n tr
eatm
ent
stra
teg
ies
for
cont
amin
ated
soi
l,se
dim
ent,
and
gro
und
wat
er,u
sing
a c
omb
inat
ion
of la
bor
ator
y,m
esoc
osm
,and
fiel
d-s
cale
stu
die
s;(2
) the
use
of m
icro
bia
l pro
cess
es,s
uch
as b
iod
egra
dat
ion,
bio
emul
sific
atio
n,an
d m
iner
al c
yclin
g t
o re
duc
e co
ntam
inan
ts in
was
te s
trea
ms
and
env
ironm
enta
l con
tam
inat
ion
of s
ite m
ater
ials
;(3)
the
cha
ract
eriz
atio
n an
d m
onito
ring
of
ecol
ogic
al p
aram
eter
s in
volv
ing
nut
rient
cyc
ling,
food
web
dyn
amic
s,ec
osys
tem
cha
ract
eriz
atio
n,an
d re
sour
ce m
anag
emen
t to
enh
ance
pol
lutio
n co
ntro
l and
op
timiz
e en
vi-
ronm
enta
l rec
over
y an
d re
stor
atio
n;(4
) bio
log
ical
-bas
ed s
enso
rs fo
r che
mic
al,b
iolo
gic
al,a
nd e
nviro
nmen
tal q
ualit
y m
onito
ring
;(5)
the
use
of m
ass
spec
trom
etry
and
rela
ted
tech
niq
ues
to d
evel
op in
stru
men
tatio
n fo
r rea
l-tim
e en
viro
nmen
tal a
naly
sis,
and
to
det
ect,
iden
tify,
and
str
uctu
rally
cha
ract
eriz
e b
iom
olec
ules
,met
al-b
iom
olec
ule
com
ple
xes,
and
oth
er m
ater
ials
;and
(6) s
tud
y th
e fu
ndam
enta
l pro
cess
es d
esor
ptio
n,io
niza
tion,
frag
men
tatio
n,an
d g
as-p
hase
reac
tions
of l
arge
ions
.
Offi
ce o
f the
St
rate
gic
Env
ironm
enta
l St
rate
gic
FY
99:
$59.
4MEx
tra
http
://w
ww
.ser
dp.
gov
Secr
etar
y of
Re
sear
ch a
nd
Envi
ronm
enta
l (3
1% fo
r cle
anup
D
efen
seD
evel
opm
ent
Prog
ram
Re
sear
ch a
nd
rese
arch
)ht
tp://
ww
w.s
erd
p.g
ov/
Dev
elop
men
t fu
ndin
g/F
und
ing
_Pro
cess
.htm
Prog
ram
The
Stra
teg
ic E
nviro
nmen
tal R
esea
rch
and
Dev
elop
men
t Pr
ogra
m is
the
Dep
artm
ent
of D
efen
se’s
corp
orat
e en
viro
nmen
tal r
esea
rch
and
dev
elop
men
t p
rog
ram
,pla
nned
and
exec
uted
in fu
ll p
artn
ersh
ip w
ith t
he D
epar
tmen
t of
Ene
rgy
and
the
Env
ironm
enta
l Pro
tect
ion
Ag
ency
,with
par
ticip
atio
n b
y nu
mer
ous
othe
r fed
eral
and
non
-fed
eral
org
aniz
a-tio
ns.
With
in it
s b
road
are
as o
f int
eres
t,th
e p
rog
ram
focu
ses
on c
lean
up,c
omp
lianc
e,co
nser
vatio
n,an
d p
ollu
tion
pre
vent
ion
tech
nolo
gie
s.
U.S
.DEP
AR
TMEN
T O
F EN
ERG
Y
Offi
ce o
f En
viro
nmen
tal
$47M
Extr
aht
tp://
ww
w.e
m.d
oe.g
ov/s
cien
ce/
Envi
ronm
enta
l M
anag
emen
t M
anag
emen
t &
Sc
ienc
e Pr
ogra
m
Offi
ce o
f Sci
ence
The
Envi
ronm
enta
l Man
agem
ent
Scie
nce
Prog
ram
is a
col
lab
orat
ive
pro
gra
m o
f the
DO
E's
Offi
ce o
f Env
ironm
enta
l Man
agem
ent
and
Offi
ce o
f Sci
ence
(for
mer
ly t
he O
ffice
of
Ener
gy
Rese
arch
) tha
t id
entif
ies
long
-ter
m b
asic
sci
ence
rese
arch
nee
ds
and
tar
get
s th
e re
sear
ch a
nd d
evel
opm
ent
to E
M's
pro
ble
ms
as a
key
to
dev
elop
ing
inno
vativ
e an
dco
st-e
ffect
ive
clea
nup
met
hod
s.Th
e Su
bsu
rfac
e C
onta
min
ants
Foc
us A
rea
relie
s on
the
Offi
ce o
f Sci
ence
and
the
Env
ironm
enta
l Man
agem
ent
Scie
nce
Prog
ram
to
answ
er b
asic
scie
nce
que
stio
ns re
gar
din
g c
onta
min
ant
tran
spor
t,so
il in
tera
ctio
n,an
d s
orp
tion
to u
nder
gro
und
sub
stra
tes.
C h a p t e r 4
77Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f O
ffice
of S
cien
ce
Tech
nolo
gy
FY 9
9:$1
87.2
MEx
tra
http
://os
t.em
.doe
.gov
/En
viro
nmen
tal
and
Tec
hnol
ogy
dev
elop
men
t ifd
/ost
/pro
gra
ms.
htm
Man
agem
ent
and
dep
loym
ent
http
://w
ww
.cfo
.doe
.gov
/b
udg
et/0
0bud
get
/hig
hlite
/hig
hlite
.pd
f
The
Offi
ce o
f Sci
ence
and
Tec
hnol
ogy
sup
por
ts a
full
rang
e of
tec
hnol
ogy
rese
arch
,dev
elop
men
t,an
d d
eplo
ymen
t ac
tiviti
es fo
cuse
d on
DO
E cl
eanu
p.Th
e p
rog
ram
s ar
e st
ruc-
ture
d a
roun
d p
rob
lem
"fo
cus
area
s" (d
eact
ivat
ion
and
dec
omm
issi
onin
g;m
ixed
was
tes;
sub
surf
ace
cont
amin
ants
;and
tan
ks) a
nd c
ross
cutt
ing
issu
es (c
hara
cter
izat
ion,
mon
itor-
ing
and
sen
sor t
echn
olog
y;ef
ficie
nt s
epar
atio
ns;i
ndus
try
pro
gra
ms;
rob
otic
s;an
d in
teg
rate
d p
roce
ss a
naly
sis)
.
Offi
ce o
f Sci
ence
Basi
c En
erg
y Sc
ienc
esC
hem
ical
Sci
ence
sFY
98:
$196
M
Extr
aht
tp://
ww
w.e
r.doe
.gov
/p
rod
uctio
n/b
es/
Div
isio
n.ht
m#c
hem
ical
The
Div
isio
n of
Che
mic
al S
cien
ces
sup
por
ts b
asic
rese
arch
at
univ
ersi
ties,
DO
E na
tiona
l lab
orat
orie
s,an
d o
ther
ap
pro
pria
te o
rgan
izat
ions
for t
he p
urp
ose
of p
rovi
din
g t
he k
now
l-ed
ge
req
uire
d t
o d
evel
op e
nerg
y te
chno
log
ies
to m
eet
natio
nal g
oals
of e
nerg
y ef
ficie
ncy,
pub
lic h
ealth
and
saf
ety,
envi
ronm
enta
l pro
tect
ion
and
rest
orat
ion,
and
con
serv
atio
nof
nat
ural
reso
urce
s.Pr
ojec
ts s
upp
orte
d a
re s
elec
ted
for r
elev
ance
to
thes
e g
oals
and
for s
cien
tific
exc
elle
nce
as ju
dg
ed b
y p
eer r
evie
w.
Offi
ce o
f Sci
ence
Basi
c En
erg
y Sc
ienc
esEn
gin
eerin
g &
FY
98:
$40M
Bo
thht
tp://
ww
w.e
r.doe
.gov
/G
eosc
ienc
esFY
99:
$42M
ep
rod
uctio
n/b
es/D
ivis
ion.
htm
#Eng
Geo
The
Div
isio
n of
Eng
inee
ring
and
Geo
scie
nces
con
duc
ts re
sear
ch in
tw
o d
isci
plin
ary
area
s:en
gin
eerin
g a
nd g
eosc
ienc
es.I
n en
gin
eerin
g re
sear
ch,t
he g
oals
are
to
exte
nd t
heb
ody
of k
now
led
ge
und
erly
ing
cur
rent
eng
inee
ring
pra
ctic
e to
cre
ate
new
op
tions
for i
mp
rovi
ng e
nerg
y ef
ficie
ncy
and
to
bro
aden
the
tech
nica
l and
con
cep
tual
kno
wle
dg
eb
ase
for s
olvi
ng t
he e
ngin
eerin
g p
rob
lem
s of
ene
rgy
tech
nolo
gie
s.In
geo
scie
nces
rese
arch
,the
em
pha
sis
is o
n fu
ndam
enta
l kno
wle
dge
of t
he p
roce
sses
tha
t tr
ansp
ort,
conc
en-
trat
e,em
pla
ce,a
nd m
odify
the
ene
rgy
and
min
eral
reso
urce
s an
d t
he b
ypro
duc
ts o
f ene
rgy
pro
duc
tion.
The
rese
arch
sup
por
ts e
xist
ing
ene
rgy
tech
nolo
gie
s an
d s
tren
gth
ens
the
foun
dat
ion
for t
he d
evel
opm
ent
of fu
ture
ene
rgy
tech
nolo
gie
s.U
ltim
atel
y th
e re
sear
ch im
pac
ts c
ontr
ol o
f ind
ustr
ial p
roce
sses
to
imp
rove
effi
cien
cy a
nd re
duc
e p
ollu
tion,
toin
crea
se e
nerg
y su
pp
lies,
and
to
low
er c
ost
and
incr
ease
the
effe
ctiv
enes
s of
env
ironm
enta
l rem
edia
tion
of p
ollu
ted
site
s.
S U B S U R F A C E S C I E N C E
78
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Sci
ence
Basi
c En
erg
y Sc
ienc
esEn
erg
y Bi
osci
ence
sFY
98:
$26.
7M
Both
ht
tp://
ww
w.e
r.doe
.gov
/FY
99:
$29.
8M
pro
duc
tion/
bes
/D
ivis
ion.
htm
#bio
scie
nces
The
Div
isio
n of
Ene
rgy
Bios
cien
ces
sup
por
ts re
sear
ch t
o p
rovi
de
a b
asic
und
erst
and
ing
of t
he b
iolo
gic
al p
heno
men
a as
soci
ated
with
the
cap
ture
,tra
nsfo
rmat
ion,
stor
age,
and
use
of e
nerg
y.Re
sear
ch o
n p
lant
s an
d n
onm
edic
al m
icro
org
anis
ms
focu
ses
on a
rang
e of
bio
log
ical
pro
cess
es,i
nclu
din
g p
hoto
synt
hesi
s,b
ioen
erg
etic
s,p
rimar
y an
d s
econ
dar
ym
etab
olis
m,t
he s
ynth
esis
and
deg
rad
atio
n of
bio
pol
ymer
s su
ch a
s lig
nin
and
cel
lulo
se,a
naer
obic
ferm
enta
tions
,gen
etic
reg
ulat
ion
of g
row
th a
nd d
evel
opm
ent,
ther
mop
hily
(e.g
.,bac
teria
l gro
wth
und
er h
igh
tem
per
atur
e),a
nd o
ther
phe
nom
ena
with
the
pot
entia
l to
imp
act
bio
log
ical
ene
rgy
pro
duc
tion
and
con
vers
ion.
The
rese
arch
is fu
ndam
enta
lan
d is
sel
ecte
d t
o b
road
ly s
upp
ort
DO
E g
oals
and
ob
ject
ives
in e
nerg
y p
rod
uctio
n,en
viro
nmen
tal m
anag
emen
t,an
d e
nerg
y co
nser
vatio
n.
Offi
ce o
f Sci
ence
Basi
c En
erg
y Sc
ienc
esM
ater
ials
Sci
ence
sFY
98:
$381
M
Both
http
://w
ww
.er.d
oe.g
ov/
FY 9
9:$4
14M
fp
rod
uctio
n/b
es/
Div
isio
n.ht
m#m
ater
ials
The
Div
isio
n of
Mat
eria
ls S
cien
ces
sup
por
ts b
asic
rese
arch
in c
ond
ense
d m
atte
r phy
sics
,met
als
and
cer
amic
s sc
ienc
es,a
nd m
ater
ials
che
mis
try.
This
rese
arch
see
ks t
o un
der
stan
dth
e at
omis
tic b
asis
of m
ater
ials
pro
per
ties
and
beh
avio
r and
how
to
mak
e m
ater
ials
per
form
bet
ter a
t ac
cep
tab
le c
ost
thro
ugh
new
met
hod
s of
syn
thes
is a
nd p
roce
ssin
g.Re
sear
ch is
sup
por
ted
in c
orro
sion
,met
als,
cera
mic
s,al
loys
,sem
icon
duc
tors
,sup
erco
nduc
tors
,pol
ymer
s,m
etal
lic g
lass
es,c
eram
ic m
atrix
com
pos
ites,
non-
des
truc
tive
eval
uatio
n,m
agne
tic m
ater
ials
,sur
face
sci
ence
,neu
tron
and
X-r
ay s
catt
erin
g,ch
emic
al a
nd p
hysi
cal p
rop
ertie
s,an
d n
ew in
stru
men
tatio
n.U
ltim
atel
y th
e re
sear
ch le
ads
to t
he d
evel
opm
ent
of m
ater
ials
tha
t im
pro
ve t
he e
ffici
ency
,eco
nom
y,en
viro
nmen
tal a
ccep
tab
ility
,and
saf
ety
in e
nerg
y g
ener
atio
n,co
nver
sion
,tra
nsm
issi
on,a
nd u
se.T
hese
mat
eria
l stu
die
s af
fect
dev
elop
men
ts in
num
erou
s ar
eas
such
as
sola
r ene
rgy
conv
ersi
on,t
rans
por
tatio
n,el
ectr
ic p
ower
pro
duc
tion,
and
pet
role
um re
finin
g.
Offi
ce o
f Sci
ence
Basi
c En
erg
y Sc
ienc
esN
atio
nal U
ser
Both
http
://w
ww
.er.d
oe.g
ov/p
rod
uctio
n/b
es/B
ESfa
cilit
ies.
htm
Faci
litie
sht
tp://
ww
w.e
r.doe
.gov
/pro
duc
tion/
ober
/fac
ilitie
s.ht
ml
The
Offi
ce o
f Bas
ic E
nerg
y Sc
ienc
es p
lans
,con
stru
cts,
and
op
erat
es 1
8 m
ajor
sci
entif
ic u
ser f
acili
ties
to s
erve
rese
arch
ers
at u
nive
rsiti
es,n
atio
nal l
abor
ator
ies,
and
ind
ustr
y.Th
ese
faci
litie
s en
able
the
acq
uisi
tion
of n
ew k
now
led
ge
that
oft
en c
anno
t ot
herw
ise
be
obta
ined
.Ea
ch y
ear,
thou
sand
s of
sci
entis
ts c
ond
uct
exp
erim
ents
at
the
user
faci
litie
s.O
ther
rese
arch
ers
colla
bor
ate
with
the
se u
sers
and
ana
lyze
the
dat
a fr
om t
he e
xper
imen
ts t
o p
ublis
h ne
w s
cien
tific
find
ing
s in
pee
r-re
view
ed jo
urna
ls.S
ee T
able
4.2
for a
list
of t
hese
faci
litie
s.
C h a p t e r 4
79Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Sci
ence
Biol
ogic
al a
nd
Envi
ronm
enta
lFY
98:
$54M
Bo
thht
tp://
ww
w.e
r.doe
.gov
/En
viro
nmen
tal
Scie
nces
/FY
99:
$56M
pro
duc
tion/
ober
/ESD
_top
.htm
lRe
sear
chEn
viro
nmen
tal
Rem
edia
tion
http
://w
ww
.er.d
oe.g
ov/
Rese
arch
/p
rod
uctio
n/ob
er/E
PR/n
abir.
htm
l N
ABI
R &
EM
SLg
http
://w
ww
.lbl.g
ov/N
ABI
R/
http
://w
ww
.em
sl.p
nl.g
ov:2
080/
http
://w
ww
.er.d
oe.g
ov/
pro
duc
tion/
ober
/fac
ilitie
s.ht
ml
The
envi
ronm
enta
l rem
edia
tion
rese
arch
por
tfol
io is
focu
sed
on
dev
elop
ing
an
und
erst
and
ing
of t
he fu
ndam
enta
l phy
sica
l,ch
emic
al,g
eolo
gic
al,a
nd b
iolo
gic
al p
roce
sses
tha
tm
ust
be
mar
shal
ed fo
r the
dev
elop
men
t an
d a
dva
ncem
ent
of n
ew,e
ffect
ive,
and
effi
cien
t p
roce
sses
for t
he re
med
iatio
n an
d re
stor
atio
n of
the
nat
ion’
s nu
clea
r wea
pon
sp
rod
uctio
n si
tes.
A p
rimar
y ef
fort
is t
he N
atur
al a
nd A
ccel
erat
ed B
iore
med
iatio
n Re
sear
ch (N
ABI
R) p
rog
ram
,whi
ch is
a b
asic
rese
arch
pro
gra
m t
hat
seek
s to
pro
vid
e th
e sc
ient
ific
und
erst
and
ing
nee
ded
to
mak
e us
e of
nat
ural
pro
cess
es a
nd t
o d
evel
op m
etho
ds
to a
ccel
erat
e th
ese
pro
cess
es fo
r bio
rem
edia
tion
of c
onta
min
ated
sub
surf
ace
sed
imen
ts a
ndg
roun
d w
ater
at
DO
E fa
cilit
ies.
Fund
ing
for t
he o
per
atio
n of
the
Env
ironm
enta
l Mol
ecul
ar S
cien
ces
Lab
orat
ory
(EM
SL),
the
only
nat
iona
l sci
entif
ic u
ser f
acili
ty fo
cuse
d o
n D
OE'
sen
viro
nmen
tal m
issi
ons,
is a
key
par
t of
the
com
mitm
ent
to e
nviro
nmen
tal r
emed
iatio
n.
Offi
ce o
f Sci
ence
Offi
ce o
f Bio
log
ical
and
Li
fe S
cien
ces/
Bo
thht
tp://
ww
w.e
r.doe
.gov
/En
viro
nmen
tal R
esea
rch
Mic
rob
ial G
enom
e p
rod
uctio
n/ob
er/m
icro
bia
l.htm
lPr
ogra
m
The
focu
s of
the
Mic
rob
ial G
enom
e Pr
ogra
m is
to
dev
elop
the
ab
ility
to
seq
uenc
e th
e g
enet
ic m
ater
ial o
f mic
rob
ial o
rgan
ism
s.Th
is w
ill p
rovi
de
det
aile
d g
enet
ic in
form
atio
n on
mic
roor
gan
ism
s w
ith im
por
tanc
e to
the
env
ironm
ent,
ener
gy
pro
duc
tion,
and
oth
er im
por
tant
ap
plic
atio
ns.T
he p
rog
ram
,sp
un-o
ff fr
om th
e H
uman
Gen
ome
Prog
ram
in 1
994,
isal
read
y p
rovi
din
g c
omp
lete
seq
uenc
e in
form
atio
n on
key
mic
roor
gan
ism
s.Th
is e
ffort
will
ena
ble
the
sci
entif
ic c
omm
unity
to
mak
e un
ique
sid
e-b
y-si
de
com
par
ison
s of
com
-p
lete
gen
etic
info
rmat
ion
from
mic
roor
gan
ism
s w
ith s
imila
r att
ribut
es.
S U B S U R F A C E S C I E N C E
80
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
U.S
.DEP
AR
TMEN
T O
F TH
E IN
TER
IOR
U.S
.Geo
log
ical
W
ater
Res
ourc
esN
atio
nal R
esea
rch
Intr
aht
tp://
wat
er.u
sgs.
gov
/Su
rvey
Prog
ram
(sev
eral
nr
p/i
ndex
-are
as.h
tml
rela
ted
cur
rent
re
sear
ch t
opic
s)
The
Nat
iona
l Res
earc
h Pr
ogra
m c
ond
ucts
bas
ic a
nd p
rob
lem
-orie
nted
hyd
rolo
gic
rese
arch
in s
upp
ort
of t
he m
issi
on o
f the
U.S
.Geo
log
ical
Sur
vey.
Rele
vant
hyd
rolo
gic
info
rma-
tion
is a
vaila
ble
tod
ay t
o as
sist
the
nat
ion
in s
olvi
ng it
s w
ater
pro
ble
ms
bec
ause
of a
con
scio
us d
ecis
ion
mad
e in
yea
rs p
ast
to in
vest
in re
sear
ch.T
he p
rog
ram
has
bee
n d
esig
ned
to e
ncou
rag
e p
ursu
it of
a d
iver
se a
gen
da
of re
sear
ch t
opic
s ai
med
at
pro
vid
ing
new
kno
wle
dg
e an
d in
sig
hts
into
var
ied
and
com
ple
x hy
dro
log
ic p
roce
sses
tha
t ar
e no
t w
ell
und
erst
ood.
The
rese
arch
em
pha
sis
chan
ges
thr
oug
h tim
e,re
flect
ing
the
em
erg
ence
of p
rom
isin
g n
ew a
reas
of i
nqui
ry a
nd t
he d
eman
d fo
r new
too
ls a
nd t
echn
ique
s w
ithw
hich
to
add
ress
wat
er re
sour
ces
issu
es.
U.S
.Geo
log
ical
Sur
vey
Wat
er R
esou
rces
Toxi
c Su
bst
ance
s $1
0MIn
tra
http
://to
xics
.usg
s.g
ov/t
oxic
s/H
ydro
log
y (T
oxic
s)
Prog
ram
This
pro
gra
m's
goa
l is
to p
rovi
de
scie
ntifi
c in
form
atio
n on
tox
ic s
ubst
ance
s in
sub
surf
ace
and
gro
und
wat
ers
for u
se in
avo
idin
g h
uman
exp
osur
e,d
evel
opin
g e
ffect
ive
rem
edia
lst
rate
gie
s,an
d p
reve
ntin
g fu
rthe
r con
tam
inat
ion.
Fund
ed re
sear
ch c
ateg
orie
s ar
e p
oint
-sou
rce
gro
und
wat
er c
onta
min
atio
n;no
npoi
nt s
ourc
e co
ntam
inat
ion;
and
har
dro
ck m
in-
ing
con
tam
inat
ion
U.S
.Geo
log
ical
Bi
olog
ical
Res
ourc
es
Nat
iona
l Pro
gra
ms:
$2.1
MIn
tra
http
://w
ww
.bes
t.usg
s.g
ov/
Surv
eyD
ivis
ion
Biom
onito
ring
of
Envi
ronm
enta
l Sta
tus
and
Tre
nds
(BES
T)
The
Biom
onito
ring
of E
nviro
nmen
tal S
tatu
s an
d T
rend
s Pr
ogra
m h
as b
een
des
igne
d t
o id
entif
y an
d u
nder
stan
d t
he e
ffect
s of
env
ironm
enta
l con
tam
inan
ts o
n b
iolo
gic
alre
sour
ces,
par
ticul
arly
tho
se re
sour
ces
und
er t
he s
tew
ard
ship
of t
he D
epar
tmen
t of
the
Inte
rior.T
he p
rog
ram
pro
vid
es s
ound
sci
entif
ic in
form
atio
n to
be
used
pro
activ
ely
to p
re-
vent
or l
imit
cont
amin
ant-
rela
ted
effe
cts
on b
iolo
gic
al re
sour
ces.
Prim
ary
goa
ls o
f the
pro
gra
m a
re t
o (1
) det
erm
ine
the
stat
us a
nd t
rend
s of
env
ironm
enta
l con
tam
inan
ts a
ndth
eir e
ffect
s on
bio
log
ical
reso
urce
s;(2
) id
entif
y,as
sess
,and
pre
dic
t th
e ef
fect
s of
con
tam
inan
ts o
n ec
osys
tem
s an
d b
iolo
gic
al p
opul
atio
ns;a
nd (3
) pro
vid
e su
mm
ary
info
rmat
ion
ina
timel
y m
anne
r to
man
ager
s an
d t
he p
ublic
for g
uid
ing
con
serv
atio
n ef
fort
s.Th
e p
rog
ram
use
s d
iffer
ent
app
roac
hes
to g
oal a
chie
vem
ent,
incl
udin
g a
com
bin
atio
n of
fiel
d b
io-
mon
itorin
g m
etho
ds
and
info
rmat
ion
asse
ssm
ent
tool
s to
exa
min
e co
ntam
inan
t is
sues
at
natio
nal,
reg
iona
l,an
d lo
cal l
evel
s.Bi
olog
ical
rese
arch
is e
ssen
tial f
or s
upp
ort
of t
hese
pro
gra
m c
omp
onen
ts,i
nclu
din
g d
evel
opm
ent
of b
iom
onito
ring
too
ls a
nd e
stab
lishm
ent
of li
nks
bet
wee
n b
iolo
gic
al re
spon
ses
and
exp
osur
e to
con
tam
inan
ts.R
esea
rch
cond
uct-
ed a
t th
e En
viro
nmen
tal a
nd C
onta
min
ants
Res
earc
h C
ente
r and
Pat
uxen
t Wild
life
Rese
arch
Cen
ter h
as c
ontr
ibut
ed e
ssen
tial t
ools
to t
he p
rog
ram
.In a
dd
ition
,dat
a m
anag
emen
t,g
eog
rap
hica
l inf
orm
atio
n sy
stem
s,an
d In
tern
et c
apab
ilitie
s d
evel
oped
at
the
Mid
cont
inen
t Ec
olog
ical
Sci
ence
Cen
ter h
ave
bee
n cr
itica
l to
pro
gra
m im
ple
men
tatio
n.
C h a p t e r 4
81Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
U.S
.EN
VIR
ON
MEN
TAL
PR
OTE
CTI
ON
AG
ENC
Y
Offi
ce o
f Res
earc
h N
atio
nal E
xpos
ure
Surf
ace/
$3.8
MIn
tra
http
://w
ww
.ep
a.g
ov/c
rdlv
web
/an
d D
evel
opm
ent
Rese
arch
Lab
orat
ory
Sub
surf
ace
(Res
earc
h Tr
iang
le
Cha
ract
eriz
atio
n Pa
rk,N
.C.)
and
Sam
plin
g
Inad
equa
te s
ite c
hara
cter
izat
ions
and
a la
ck o
f kno
wle
dg
e of
sur
face
and
sub
surf
ace
cont
amin
ant
dis
trib
utio
ns (p
artic
ular
ly v
olat
ile o
rgan
ic c
omp
ound
s an
d N
APL
s) h
ind
er o
urab
ility
to
mak
e g
ood
dec
isio
ns o
n re
med
iatio
n op
tions
and
con
duc
t ad
equa
te c
lean
up e
ffort
s.N
onin
vasi
ve g
eop
hysi
cal t
echn
ique
s ca
n p
rovi
de
met
hod
s fo
r sub
surf
ace
site
char
acte
rizat
ion.
Futu
re e
ffort
is b
eing
dire
cted
tow
ard
exp
erim
ents
at
the
uniq
ue fi
eld
tes
t fa
cilit
y fo
r eva
luat
ing
the
se g
eop
hysi
cal t
echn
olog
ies
und
er c
ontr
olle
d D
NA
PL s
pill
cond
ition
s.Th
is la
b w
ill a
lso
be
used
to
eval
uate
oth
er g
roun
d w
ater
sam
plin
g m
etho
ds
and
des
igns
.Res
earc
h is
bei
ng c
ond
ucte
d to
dev
elop
and
imp
lem
ent
stat
e-of
-the
-sci
-en
ce a
pp
roac
hes
to im
pro
ved
soi
l sam
plin
g t
echn
ique
s,m
easu
rem
ent
des
ign
and
geo
stat
istic
s,an
d d
ata
anal
ysis
thr
oug
h ch
emom
etric
and
rob
ust
stat
istic
al t
echn
ique
s.Im
pro
vem
ents
in a
ll as
pec
ts o
f soi
l sam
plin
g a
re b
eing
inve
stig
ated
to
qua
ntify
and
red
uce
or e
limin
ate
pos
sib
le e
rror
s th
at c
omm
only
occ
ur d
urin
g s
amp
le c
olle
ctio
n,ha
ndlin
g,p
rese
rvat
ion,
and
sto
rag
e.C
urre
nt re
sear
ch fo
cuse
s on
imp
rovi
ng t
he c
olle
ctio
n of
soi
ls c
onta
min
ated
with
vol
atile
org
anic
com
pou
nds
incl
udin
g a
n ex
amin
atio
n of
the
influ
-en
ce o
f sam
ple
siz
e on
"re
pre
sent
ativ
enes
s" o
f VO
C re
sults
,VO
C re
leas
es d
ue t
o sa
mp
le d
istu
rban
ce,a
nd t
he p
enet
rab
ility
of c
alic
he t
o N
APL
s.
Offi
ce o
f Res
earc
h N
atio
nal E
xpos
ure
Ana
lytic
al M
etho
ds
$1.7
MIn
tra
http
://w
ww
.ep
a.g
ov/c
rdlv
web
/an
d D
evel
opm
ent
Rese
arch
Lab
orat
ory
for G
roun
d W
ater
(R
esea
rch
Tria
ngle
an
d S
oils
Park
,N.C
.)
Rese
arch
in t
he a
pp
licat
ion
of a
dva
nced
inst
rum
enta
tion
to s
oils
and
gro
und
wat
er c
hara
cter
izat
ion
focu
ses
on m
etho
ds
that
will
pro
vid
e hi
gh-
qua
lity
dat
a ra
pid
ly w
ith s
imp
lean
d ru
gg
ed p
roto
cols
.Em
pha
sis
is o
n te
chno
log
ies
that
can
be
used
to
per
form
ana
lysi
s in
the
fiel
d,th
ose
that
can
det
erm
ine
pol
luta
nts
that
are
intr
acta
ble
by
conv
entio
nal
met
hod
s,an
d t
hose
tha
t im
pro
ve r
isk
asse
ssm
ents
by
pro
vid
ing
sp
ecifi
c in
form
atio
n on
the
mos
t ha
zard
ous
form
s of
pol
luta
nts.
Cur
rent
ly,p
ollu
tant
s of
prim
ary
inte
rest
are
pol
y-cy
clic
aro
mat
ic h
ydro
carb
ons,
chlo
rinat
ed o
rgan
ics,
pet
role
um-r
elat
ed c
omp
ound
s,an
d t
oxic
met
als.
Futu
re e
mp
hasi
s w
ill b
e on
inno
vativ
e m
etho
ds
and
tec
hnol
ogie
s to
eva
lu-
ate
and
cha
ract
eriz
e th
e na
tura
l att
enua
tion
of c
onta
min
ants
in g
roun
dw
ater
and
soi
ls.
S U B S U R F A C E S C I E N C E
82
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Res
earc
h N
atio
nal C
ente
r for
Su
per
fund
Hea
lth
$2.1
MIn
tra
http
://w
ww
.ep
a.g
ov/n
cea/
and
Dev
elop
men
tEn
viro
nmen
tal
Risk
Ass
essm
ent
Ass
essm
ent
(Was
hing
ton,
D.C
.;Re
sear
ch T
riang
le
Park
,N.C
.;and
C
inci
nnat
i,O
h.)
This
rese
arch
dev
elop
s m
etho
dol
ogie
s,m
odel
s,an
d fa
ctor
s th
at w
ill e
nab
le r
isk
asse
ssor
s to
der
ive
an a
ccur
ate
estim
ate
of t
he a
mou
nt o
f a c
onta
min
ant
foun
d in
the
soi
l tha
t is
bio
log
ical
ly "
avai
lab
le"
to h
uman
s.Fu
ture
em
pha
sis
will
incl
ude
dev
elop
ing
sta
tistic
al d
istr
ibut
ions
for e
xpos
ure
fact
ors
to fa
cilit
ate
pro
bab
ilist
ic a
naly
sis;
furt
her r
efin
ing
and
val
i-d
atin
g t
he b
ioki
netic
mod
el fo
r lea
d;d
evel
opin
g b
ette
r mod
els
and
met
hod
s fo
r the
der
mal
rout
e of
exp
osur
e;an
d e
valu
atin
g t
he b
ioav
aila
bili
ty o
f soi
l-bor
ne c
onta
min
ants
.In
add
ition
,res
earc
h is
con
duc
ted
to
dev
elop
mod
els
and
fact
ors
to p
red
ict
the
rela
tive
toxi
city
of c
omp
lex
mix
ture
s of
gro
und
wat
er c
onta
min
ants
com
par
ed t
o th
eir i
ndiv
idua
lto
xici
ties.
This
rese
arch
att
emp
ts t
o an
swer
the
que
stio
n of
whe
ther
mix
ture
s of
gro
und
wat
er c
onta
min
ants
pro
duc
e a
mor
e to
xic
resp
onse
,a le
ss t
oxic
resp
onse
,or n
o ne
tch
ang
e in
hum
an re
spon
se.
Offi
ce o
f Res
earc
h N
atio
nal C
ente
r for
Su
per
fund
Eco
log
ical
$1
.0M
Intr
aht
tp://
ww
w.e
pa.
gov
/nce
a/an
d D
evel
opm
ent
Envi
ronm
enta
l Ri
sk A
sses
smen
tA
sses
smen
t(W
ashi
ngto
n,D
.C.;
Rese
arch
Tria
ngle
Pa
rk,N
.C.;a
nd
Cin
cinn
ati,
Oh.
)
This
rese
arch
dev
elop
s m
etho
dol
ogie
s an
d fa
ctor
s th
at w
ill e
nab
le e
colo
gic
al r
isk
asse
ssor
s to
est
imat
e th
e am
ount
of s
oil-b
orne
con
tam
inat
ion
that
is b
iolo
gic
ally
"av
aila
ble
" to
wild
life.
The
maj
or a
rea
of e
mp
hasi
s w
ill b
e to
dev
elop
eco
log
ical
soi
l scr
eeni
ng v
alue
s fo
r com
mon
soi
l con
tam
inan
ts.
Offi
ce o
f Res
earc
h N
atio
nal R
isk
Gro
und
Wat
er
$4.2
MIn
tra
Htt
p://
ww
w.e
pa.
gov
/an
d D
evel
opm
ent
Man
agem
ent
Rem
edia
tion
ada/
kerr
cent
er.h
tml
Rese
arch
Lab
orat
ory
(Cin
cinn
ati,
Oh.
)
This
rese
arch
ad
dre
sses
prio
rity
rem
edia
tion
pro
ble
ms
for g
roun
d w
ater
and
maj
or s
ubsu
rfac
e so
urce
s of
gro
und
wat
er c
onta
min
atio
n,su
ch a
s N
APL
s.Re
sear
ch in
clud
es t
reat
-m
ent,
cont
ainm
ent
and
rela
ted
sou
rce
char
acte
rizat
ion,
and
gro
und
wat
er fa
te (i
nclu
din
g n
atur
al a
tten
uatio
n) a
nd t
rans
por
t m
odel
ing.
DN
APL
s ar
e a
maj
or s
ourc
e of
gro
und
wat
er c
onta
min
ate
for w
hich
the
re a
re fe
w e
ffect
ive
com
mer
cial
ized
rem
edia
tion
optio
ns.R
esea
rch
on d
isso
lved
org
anic
con
tam
inan
ts w
ill c
ontin
ue a
nd w
ill in
clud
e st
udie
s of
the
app
licat
ion
and
long
-ter
m p
erfo
rman
ce o
f per
mea
ble
reac
tive
bar
riers
(PRB
s) t
o ch
lorin
ated
org
anic
s.Re
sear
ch o
n im
pro
ved
ind
icat
ors
for m
onito
red
nat
ural
att
enua
tion
(MN
A) o
f org
anic
s w
ill b
e co
ntin
ued.
Rese
arch
will
be
exp
and
ed o
n th
e re
med
iatio
n of
dis
solv
ed in
org
anic
plu
mes
and
rela
ted
sou
rce
area
s.Re
sear
ch o
n M
NA
of d
isso
lved
met
-al
s w
ill s
hift
from
lab
orat
ory
to fi
eld
stu
die
s,as
will
stu
die
s of
the
ap
plic
atio
n of
PRB
s to
ars
enic
.Res
earc
h on
bio
trea
tmen
t of m
etal
con
tam
inan
ts w
ill c
ontin
ue.W
ork
will
be
initi
-at
ed o
n th
e ap
plic
atio
n of
PRB
con
cep
ts t
o m
etal
con
tam
inan
ts in
sou
rce
area
s.
C h a p t e r 4
83Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Res
earc
h N
atio
nal R
isk
Soil
Rem
edia
tion
$5.6
MIn
tra
http
://w
ww
.ep
a.g
ov/
and
Dev
elop
men
tM
anag
emen
tO
RD/N
RMRL
/lrp
cd/
Rese
arch
Lab
orat
ory
(Cin
cinn
ati,
Oh.
)
This
rese
arch
eva
luat
es a
nd d
evel
ops
mor
e co
st-e
ffect
ive
tech
niq
ues
for c
lean
up o
f prio
rity
cont
amin
atio
n p
rob
lem
s in
soi
ls,t
he v
ados
e zo
ne,a
nd s
edim
ents
.The
pro
gra
m w
illex
pan
d re
sear
ch o
n se
dim
ents
con
tam
inat
ed w
ith p
ersi
sten
t or
gan
ics
and
met
als.
Benc
h- a
nd fi
eld
-sca
le s
tud
ies
will
be
cond
ucte
d t
o d
evel
op a
nd re
fine
met
hod
s to
ass
ess
MN
A e
ffect
iven
ess.
Emer
gin
g re
med
iatio
n te
chni
que
s fo
r in
situ
sed
imen
ts w
ill b
e ev
alua
ted,
alon
g w
ith im
pro
ved
met
hod
s fo
r ass
essi
ng t
heir
per
form
ance
.Stu
die
s w
ill b
e co
n-d
ucte
d o
f the
effe
ctiv
enes
s of
the
bio
trea
tmen
t of
dre
dg
ed s
edim
ents
to
allo
w t
heir
ben
efic
ial u
se.R
esea
rch
on t
he im
mob
iliza
tion
of m
etal
s in
soi
ls w
ill c
ontin
ue,f
ocus
ing
on
com
ple
ting
lead
stu
die
s an
d c
ontin
uing
cad
miu
m s
tud
ies.
Con
curr
ent
test
ing
will
be
don
e on
cha
nges
in m
etal
bio
avai
lab
ility
as
a re
sult
of im
mob
iliza
tion.
Offi
ce o
f Res
earc
h N
atio
nal R
isk
Con
tain
men
t$1
.9M
Intr
aht
tp://
ww
w.e
pa.
gov
/an
d D
evel
opm
ent
Man
agem
ent
ORD
/NRM
RL/l
rpcd
/Re
sear
ch L
abor
ator
y (C
inci
nnat
i,O
h.)
This
rese
arch
ad
dre
sses
the
effe
ctiv
enes
s of
cur
rent
con
tain
men
t sy
stem
s an
d d
evel
opin
g n
ew s
yste
ms
usin
g in
nova
tive
mat
eria
ls a
nd m
etho
ds.
The
stud
y in
clud
es c
aps,
cove
rs,
and
ver
tical
bar
riers
for t
he v
ados
e zo
ne,a
s w
ell a
s fix
ed b
arrie
rs a
nd p
ump
ing
met
hod
s fo
r con
tain
ing
con
tam
inat
ed p
lum
es.R
esea
rch
on b
arrie
rs w
ill a
dd
ress
the
long
-ter
mm
aint
enan
ce,e
ffect
iven
ess,
and
mat
eria
ls t
hat
coul
d m
ake
them
mor
e ef
fect
ive.
Offi
ce o
f Res
earc
h N
atio
nal C
ente
r for
H
azar
dou
s Su
bst
ance
$8
.9M
Both
http
://es
.ep
a.g
ov/n
cerq
a/hs
rc.h
tml
and
Dev
elop
men
tEn
viro
nmen
tal
Rese
arch
Cen
ters
/Re
sear
ch a
nd
Min
ority
Cen
ters
http
://es
.ep
a.g
ov/n
cerq
a/m
ibc.
htm
lQ
ualit
y A
ssur
ance
(N
CER
QA
) (W
ashi
ngto
n,D
.C.)
The
mis
sion
of t
he H
azar
dou
s Su
bst
ance
Res
earc
h C
ente
rs P
rog
ram
is t
o co
nduc
t re
sear
ch t
o d
evel
op a
nd d
emon
stra
te n
ew m
etho
ds
that
ass
ess
and
rem
edia
te s
ites
cont
ami-
nate
d w
ith h
azar
dou
s su
bst
ance
s;im
pro
ve e
xist
ing
tre
atm
ent
tech
nolo
gie
s;d
ecre
ase
the
pro
duc
tion
and
use
of h
azar
dou
s su
bst
ance
s;an
d e
duc
ate
haza
rdou
s su
bst
ance
man
-ag
emen
t p
rofe
ssio
nals
and
imp
rove
com
mun
ity p
ublic
aw
aren
ess.
Five
mul
ti-un
iver
sity
cen
ters
,eac
h lo
cate
d in
a p
air o
f EPA
reg
ions
,foc
us o
n d
iffer
ent
asp
ects
of h
azar
dou
ssu
bst
ance
man
agem
ent,
brin
gin
g t
oget
her r
esea
rche
rs fr
om a
var
iety
of d
isci
plin
es t
o co
llab
orat
e on
inte
gra
ted
rese
arch
pro
ject
s.A
dd
ition
ally
,tw
o ta
rget
ed c
ente
rs s
erve
the
par
ticul
ar re
sear
ch n
eed
s of
min
ority
and
dis
adva
ntag
ed c
omm
uniti
es.T
hese
cen
ters
ad
dre
ss s
uch
issu
es a
s en
viro
nmen
tal j
ustic
e,ris
k co
mm
unic
atio
n an
d p
erce
ptio
n of
ris
k,co
rrel
atio
n w
ith s
ocio
econ
omic
sta
tus,
and
exp
osur
e to
env
ironm
enta
l con
tam
inan
ts.h
S U B S U R F A C E S C I E N C E
84
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Res
earc
hN
CER
QA
Jo
int
Prog
ram
on
$1.0
MEx
tra
http
://w
ww
.ep
a.g
ov/
and
Dev
elop
men
t(W
ashi
ngto
n,D
.C.)
Bior
emed
iatio
n d
ocs/
ord
ntrn
t/(E
PA is
lead
ag
ency
;O
ER-W
eb/g
rant
s96/
join
t/in
dex
.htm
lD
OE,
EPA
,NSF
,and
O
NR
are
also
invo
lved
)ht
tp://
es.e
pa.
gov
/nce
rqa/
rfa/
bio
.htm
ll
This
pro
gra
m fo
cuse
s on
rese
arch
tha
t ai
ms
to fu
rthe
r fun
dam
enta
l und
erst
and
ing
of t
he c
hem
ical
,phy
sica
l,an
d b
iolo
gic
al p
roce
sses
influ
enci
ng t
he b
ioav
aila
bili
ty a
nd re
leas
eof
che
mic
als
in s
oil,
sed
imen
ts,a
nd g
roun
d w
ater
und
er n
atur
al c
ond
ition
s an
d a
lso
the
role
of c
hem
ical
con
tam
inan
ts t
hat,
whe
n re
leas
ed fr
om t
he m
ediu
m a
nd a
ssim
ilate
d b
yliv
ing
org
anis
ms,
resu
lt in
ad
vers
e ef
fect
s.Th
e re
sear
ch o
bje
ctiv
e sh
ould
be
to u
nder
stan
d t
he c
omm
onal
ity o
f pro
cess
es a
nd/o
r env
ironm
enta
l effe
cts
invo
lved
in c
onta
min
ant
rele
ase,
mov
emen
t,an
d a
ssim
ilatio
n in
ord
er t
o d
eter
min
e b
road
ly a
pp
licab
le t
echn
ique
s fo
r mea
surin
g t
he p
oten
tial i
mp
acts
in c
omp
lex
mat
rices
.Mec
hani
stic
and
kin
etic
stu
d-
ies
are
enco
urag
ed.T
hese
dat
a ca
n th
en b
e us
ed t
o co
nstr
uct
mod
els
that
incr
ease
our
und
erst
and
ing
of b
ioav
aila
bili
ty (
Not
e:Th
ere
are
no n
ew e
ffort
s b
eing
fund
ed u
nder
thi
sg
rant
,but
not
all
activ
ities
and
rep
orts
und
er t
he g
rant
hav
e b
een
com
ple
ted.
)
Offi
ce o
f Res
earc
h N
CER
QA
C
omp
lex
Mix
ture
s$2
.7M
Extr
aht
tp://
es.e
pa.
gov
/an
d D
evel
opm
ent
(Joi
nt P
rog
ram
nc
erq
a/rf
a/ch
em.h
tml
with
NIE
HS)
The
goa
ls a
nd s
cop
e of
thi
s p
rog
ram
are
to
enco
urag
e an
d s
upp
ort
rese
arch
on
chem
ical
mix
ture
s th
at w
ill t
ake
adva
ntag
e of
the
late
st a
dva
nces
in c
omp
utat
iona
l and
info
r-m
atio
n te
chno
log
ies
and
mol
ecul
ar b
iolo
gy
tech
niq
ues.
The
focu
s is
on
the
mec
hani
stic
bas
is fo
r che
mic
al in
tera
ctio
ns in
bio
log
ical
sys
tem
s an
d re
late
d h
ealth
effe
cts
and
dev
elop
men
t of
bet
ter m
athe
mat
ical
too
ls fo
r ris
k as
sess
men
t.Si
nce
ther
e is
a g
ener
al la
ck o
f kno
wle
dg
e co
ncer
ning
the
cha
ract
eriz
atio
n of
real
-life
mix
ture
s b
ased
on
hum
anex
pos
ure
and
bod
y b
urd
en,r
esea
rch
will
be
sup
por
ted
tha
t fo
cuse
s on
exp
osur
e as
sess
men
t,in
clud
ing
env
ironm
enta
l tra
nsp
ort
and
fate
.
Offi
ce o
f Res
earc
h N
CER
QA
Scie
nce
to A
chie
ve
Ap
pro
xim
atel
y Ex
tra
http
://es
.ep
a.g
ov/n
cerq
a/g
rant
s/an
d D
evel
opm
ent
Resu
lts (S
TAR)
$1
00M
ann
ually
ht
tp://
es.e
pa.
gov
/nce
rqa/
rfa/
Prog
ram
/(fu
ndin
g le
vels
var
y)
Envi
ronm
enta
l Re
sear
ch G
rant
s
EPA
's re
sear
ch p
rog
ram
s se
ek t
o re
duc
e ris
ks t
o p
ublic
hea
lth a
nd e
cosy
stem
s an
d t
he u
ncer
tain
ty a
ssoc
iate
d o
f env
ironm
enta
l hea
lth r
isk
asse
ssm
ent
and
man
agem
ent,
acco
rd-
ing
the
hig
hest
prio
rity
to t
hose
are
as w
here
unc
erta
inty
is h
igh
and
tha
t ar
e in
crit
ical
nee
d o
f new
con
cep
ts,m
etho
ds,
and
dat
a.EP
A a
lso
fost
ers
the
dev
elop
men
t an
d e
valu
a-tio
n of
new
ris
k re
duc
tion
tech
nolo
gie
s,in
clud
ing
pol
lutio
n p
reve
ntio
n,en
d-o
f-p
ipe
cont
rols
,rem
edia
tion,
and
mon
itorin
g.EP
A's
ext
ram
ural
rese
arch
gra
nt p
rog
ram
s ar
e ad
min
-is
tere
d b
y th
e N
atio
nal C
ente
r for
Env
ironm
enta
l Res
earc
h an
d Q
ualit
y A
ssur
ance
thr
oug
h th
e Sc
ienc
e to
Ach
ieve
Res
ults
Pro
gra
m,w
hich
has
four
form
al s
olic
itatio
n p
erio
ds
dur
-in
g t
he y
ear—
Janu
ary,
Ap
ril,A
ugus
t,an
d O
ctob
er.R
eque
sts
for A
pp
licat
ions
invi
te re
sear
ch p
rop
osal
s fr
om a
cad
emic
and
non
-pro
fit in
stitu
tions
loca
ted
in t
he U
.S.,a
nd s
tate
and
loca
l gov
ernm
ents
.Re
sear
ch t
opic
s va
ry.T
he 1
999
solic
itatio
ns c
an b
e fo
und
on
http
://es
.ep
a.g
ov/n
cerq
a/g
rant
s/99
gra
nts.
htm
l.
C h a p t e r 4
85Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
U.S
.DEP
AR
TMEN
T O
F H
EALT
H A
ND
HU
MA
N S
ERV
ICES
Nat
iona
l Ins
titut
es
Nat
iona
l Ins
titut
e of
Su
per
fund
A
pp
roxi
mat
ely
$37M
Ex
tra
http
://w
ww
.nie
hs.n
ih.g
ov/
of H
ealth
Envi
ronm
enta
l Hea
lth
Haz
ard
ous
in F
Y 20
00 t
o fu
nd
sbrp
/new
web
/sb
rpre
s.ht
mSc
ienc
esSu
bst
ance
s Ba
sic
15 t
o 20
new
gra
nts
Rese
arch
Pro
gra
m
or c
omp
etiti
ve
(thi
s is
a jo
int
cont
inua
tion
gra
nts
pro
gra
m b
etw
een
NIE
HS
and
EPA
)
Rese
arch
effo
rts
are
bei
ng p
ursu
ed t
hat
are
focu
sed
on
(1) u
nder
stan
din
g t
he r
isks
haz
ard
ous
was
te e
xpos
ures
pos
e to
hum
ans,
and
(2) d
evel
opin
g n
ew t
echn
olog
y th
at w
illhe
lp re
med
iate
con
tam
inat
ed s
ites.
This
pro
gra
m w
as e
stab
lishe
d b
y th
e Su
per
fund
Am
end
men
ts a
nd R
eaut
horiz
atio
n A
ct o
f 198
6.It
rece
ives
its
fund
ing
thr
oug
h an
inte
ra-
gen
cy a
gre
emen
t w
ith t
he E
PA u
sing
Sup
erfu
nd T
rust
mon
ies
and
is a
dm
inis
tere
d b
y th
e N
atio
nal I
nstit
ue o
f Env
ironm
enta
l Hea
lth S
cien
ces.
NA
TIO
NA
L SC
IEN
CE
FOU
ND
ATI
ON
Biol
ogic
al
Envi
ronm
enta
l (In
clud
ing
Lon
g
FY 9
8:$7
9.3M
Extr
aht
tp://
ww
w.n
sf.g
ov/
Scie
nces
Biol
ogy
Div
isio
nTe
rm E
colo
gic
al
FY 9
9:$8
5.9M
bfa
/bud
/fy1
999/
star
t.htm
Rese
arch
Site
s Pr
ogra
m)
http
://w
ww
.nsf
.gov
/bfa
/bud
/fy2
000/
http
://lte
rnet
.ed
u/in
dex
.htm
l
The
Div
isio
n of
Env
ironm
enta
l Bio
log
y su
pp
orts
fund
amen
tal r
esea
rch
on t
he o
rigin
s,fu
nctio
ns,r
elat
ions
hip
s,in
tera
ctio
ns,a
nd e
volu
tiona
ry h
isto
ry o
f pop
ulat
ions
,sp
ecie
s,co
m-
mun
ities
,and
eco
syst
ems.
Scie
ntifi
c em
pha
ses
incl
ude
bio
div
ersi
ty,m
olec
ular
evo
lutio
n,m
esos
cale
eco
log
y,co
mp
utat
iona
l bio
log
y (in
clud
ing
mod
elin
g),
cons
erva
tion
bio
log
y,g
lob
al c
hang
e,an
d re
stor
atio
n ec
olog
y.Th
e d
ivis
ion
also
sup
por
ts a
net
wor
k of
long
-ter
m e
colo
gic
al re
sear
ch s
ites;i
doc
tora
l dis
sert
atio
n re
sear
ch;r
esea
rch
conf
eren
ces
and
wor
ksho
ps;
und
erg
rad
uate
men
torin
g in
env
ironm
enta
l bio
log
y;an
d a
var
iety
of f
ound
atio
n-w
ide
activ
ities
.
S U B S U R F A C E S C I E N C E
86
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Biol
ogic
al
Plan
t G
enom
e FY
98:
$40M
Extr
aht
tp://
ww
w.n
sf.g
ov/
Scie
nces
Rese
arch
FY 9
9 $5
0Mb
fa/b
ud/f
y199
9/st
art.h
tm
The
pla
nt g
enom
e re
sear
ch s
ubac
tivity
,beg
un in
FY
1998
,sup
por
ts re
sear
ch t
o ad
vanc
e un
der
stan
din
g o
f the
str
uctu
re,o
rgan
izat
ion,
and
func
tion
of p
lant
gen
omes
.Thi
s ef
fort
is b
uilt
on a
n ex
istin
g b
ase
of g
enom
e re
sear
ch s
upp
orte
d t
hrou
gho
ut t
he b
iolo
gic
al s
cien
ces
div
isio
n.En
hanc
ed s
upp
ort
for f
unda
men
tal r
esea
rch
will
acc
eler
ate
the
use
ofne
w k
now
led
ge
and
inno
vativ
e te
chno
log
ies
tow
ard
a m
ore
com
ple
te u
nder
stan
din
g o
f bas
ic b
iolo
gic
al p
roce
sses
in p
lant
s,w
ith e
mph
asis
on
such
eco
nom
ical
ly s
igni
fican
tsp
ecie
s as
cor
n.
Eng
inee
ring
Bioe
ngin
eerin
g a
nd
Envi
ronm
enta
l FY
98:
$28.
8M
Extr
aht
tp://
ww
w.e
ng.n
sf.g
ov/
Envi
ronm
enta
l Sys
tem
sEn
gin
eerin
g
FY 9
9 $3
2.42
M
bes
/Pro
gra
ms/
Envi
ronm
enta
l_Pr
ogra
m(t
his
is fo
r all
of
Eng
inee
ring
_Bas
i/en
viro
nmen
tal_
Bioe
ngin
eerin
g
eng
inee
ring
_bas
i.htm
and
Env
ironm
enta
l Sy
stem
s)
The
Envi
ronm
enta
l Eng
inee
ring
Pro
gra
m s
upp
orts
sus
tain
able
dev
elop
men
t re
sear
ch w
ith t
he g
oal o
f ap
ply
ing
eng
inee
ring
prin
cip
les
to re
duc
e ad
vers
e ef
fect
s of
sol
id,l
iqui
d,an
d g
aseo
us d
isch
arg
es in
to la
nd,f
resh
and
oce
an w
ater
s,an
d a
ir th
at re
sult
from
hum
an a
ctiv
ity a
nd im
pai
r the
val
ue o
f tho
se re
sour
ces.
This
pro
gra
m a
lso
sup
por
ts re
sear
chon
inno
vativ
e b
iolo
gic
al,c
hem
ical
,and
phy
sica
l pro
cess
es u
sed
alo
ne o
r as
com
pon
ents
of e
ngin
eere
d s
yste
ms
to re
stor
e th
e us
eful
ness
of p
ollu
ted
land
,wat
er,a
nd a
irre
sour
ces.
Eng
inee
ring
prin
cip
les
und
erly
ing
pol
lutio
n av
oid
ance
,as
wel
l as
pol
lutio
n tr
eatm
ent
and
rep
arat
ion
are
emp
hasi
zed.
Imp
rove
d s
enso
rs,i
nnov
ativ
e p
rod
uctio
np
roce
sses
,was
te re
duc
tion
and
recy
clin
g,an
d in
dus
tria
l eco
log
y ar
e im
por
tant
to
this
pro
gra
m.R
esea
rch
may
be
dire
cted
tow
ard
imp
rovi
ng t
he c
ost
effe
ctiv
enes
s of
pol
lutio
nav
oid
ance
,as
wel
l as
dev
elop
ing
fres
h p
rinci
ple
s fo
r pol
lutio
n av
oid
ance
tec
hnol
ogie
s.
Eng
inee
ring
Che
mic
al a
nd
Flui
d a
nd P
artic
le
FY 9
8:$3
9.67
M
Extr
aht
tp://
ww
w.e
ng.n
sf.g
ov/
Tran
spor
t Sy
stem
s (C
TS)
Proc
esse
s Pr
ogra
mFY
99:
$42.
14M
ct
s/ht
ml/
fluid
.htm
(for a
ll of
Che
mic
al
and
Tra
nsp
ort
Syst
ems)
This
pro
gra
m s
upp
orts
fund
amen
tal a
nd a
pp
lied
rese
arch
on
mec
hani
sms
and
phe
nom
ena
gov
erni
ng s
ing
le a
nd m
ultip
hase
flui
d fl
ow,p
artic
le fo
rmat
ion
and
tra
nsp
ort,
vario
usm
ultip
hase
pro
cess
es,n
anos
truc
ture
s,an
d fl
uid
-sol
id s
yste
m in
tera
ctio
n.Re
sear
ch is
sou
ght
tha
t co
ntrib
utes
to
imp
rovi
ng b
asic
und
erst
and
ing
and
des
ign,
pre
dic
tab
ility
,effi
cien
-cy
,and
con
trol
of e
xist
ing
sys
tem
s th
at in
volv
e d
ynam
ics
of fl
uid
s an
d p
artic
ulat
es;a
nd t
he in
nova
tive
uses
of f
luid
s an
d p
artic
ulat
es in
mat
eria
ls d
evel
opm
ent,
man
ufac
turin
g,b
iote
chno
log
y,an
d t
he e
nviro
nmen
t.
Eng
inee
ring
Che
mic
al a
nd
Inte
rfac
ial,T
rans
por
t,(s
ee a
bov
e)Ex
tra
http
://w
ww
.eng
.nsf
.gov
/Tr
ansp
ort
Syst
ems
(CTS
)an
d S
epar
atio
n Pr
oces
sct
s/ht
ml/
inte
rfac
ial.h
tm
This
pro
gra
m s
upp
orts
rese
arch
in a
reas
rela
ted
to
inte
rfac
ial p
heno
men
a,m
ass
tran
spor
t p
heno
men
a,se
par
atio
n sc
ienc
e,an
d p
hase
eq
uilib
rium
the
rmod
ynam
ics.
Rese
arch
inth
ese
area
s su
pp
orts
var
ious
asp
ects
of e
ngin
eerin
g t
echn
olog
y w
ith m
ajor
imp
act
on c
hem
ical
and
mat
eria
l pro
cess
ing,
as w
ell a
s b
iop
roce
ss e
ngin
eerin
g.Re
sear
ch in
thi
s p
ro-
gra
m a
lso
cont
ribut
es t
o th
e d
ivis
ion
emp
hasi
s on
bas
ic k
now
led
ge
imp
actin
g o
n p
hysi
coch
emic
al h
azar
dou
s w
aste
tre
atm
ent
and
avo
idan
ce.T
he p
rog
ram
pro
vid
es s
upp
ort
for n
ew t
heor
ies
and
ap
pro
ache
s d
eter
min
ing
the
the
rmod
ynam
ic p
rop
ertie
s of
flui
ds
and
flui
d m
ixtu
res
in b
iolo
gic
al a
nd o
ther
flui
ds
with
com
ple
x m
olec
ules
.Sep
arat
ions
rese
arch
is d
irect
ed a
t m
any
area
s w
ith s
pec
ial e
mp
hasi
s on
bio
pro
cess
ing
and
all
form
s of
chr
omat
ogra
phi
c,m
emb
rane
,and
sp
ecia
l affi
nity
sep
arat
ions
.
C h a p t e r 4
87Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Eng
inee
ring
Civ
il an
d M
echa
nica
l C
onst
ruct
ion/
FY 9
8:$4
4.71
M;
Extr
aht
tp://
ww
w.e
ng.n
sf.g
ov/
Syst
ems
Geo
tech
nolo
gy/
FY 9
9 (r
eque
sted
):$5
9.5M
cms/
CG
S/cg
s.ht
mSt
ruct
ures
(for a
ll of
Civ
il an
d
Mec
hani
cal S
yste
ms)
Rese
arch
is s
upp
orte
d t
hat
incr
ease
s g
eote
chni
cal k
now
led
ge
of fo
und
atio
ns,s
lop
es,e
xcav
atio
ns,a
nd o
ther
geo
stru
ctur
es,i
nclu
din
g so
il an
d ro
ck im
pro
vem
ent
tech
nolo
gie
san
d re
info
rcem
ent
syst
ems;
cons
titut
ive
mod
elin
g a
nd v
erifi
catio
n in
geo
mec
hani
cs;r
emed
iatio
n an
d c
onta
inm
ent
of g
eoen
viro
nmen
tal c
onta
min
atio
n;tr
ansf
erab
ility
of
lab
orat
ory
resu
lts t
o fie
ld s
cale
;and
non
des
truc
tive
and
in s
itu e
valu
atio
n.Re
sear
ch is
als
o su
pp
orte
d t
hat
will
ad
vanc
e th
e kn
owle
dg
e b
ase
on a
dva
nced
pol
ymer
mat
eria
ls;h
igh
per
form
ance
ste
el a
nd c
oncr
ete
mat
eria
ls;d
urab
ility
of c
onst
ruct
ion
mat
eria
ls;s
afet
y an
d re
liab
ility
of b
ridg
es,i
nclu
din
g c
ond
ition
ass
essm
ent;
and
ind
oor e
nviro
nmen
tal
cond
ition
s,su
ch a
s ai
r qua
lity
and
per
sonn
el c
omfo
rt in
bui
ldin
gs.
Als
o of
inte
rest
are
act
iviti
es t
hat
will
incr
ease
the
pre
sent
und
erst
and
ing
of t
he s
cien
ce a
nd t
echn
olog
y us
edto
des
ign,
anal
yze,
dia
gno
se,r
epai
r,re
med
iate
,ret
rofit
,and
enh
ance
the
per
form
ance
of c
onst
ruct
ed fa
cilit
ies
and
inte
ract
ions
bet
wee
n na
tura
l and
con
stru
cted
env
ironm
ents
,an
d t
o us
e kn
owle
dg
e g
aine
d t
o im
pro
ve t
he m
anag
emen
t an
d p
erfo
rman
ce o
f new
and
exi
stin
g in
fras
truc
ture
sys
tem
s an
d fa
cilit
ies.
Mat
hem
atic
al a
nd
Che
mis
try
Inor
gan
ic,
FY 9
8:$1
13M
Ex
tra
http
://w
ww
.nsf
.gov
/Ph
ysic
al S
cien
ces
Bioi
norg
anic
,and
FY
99
req
uest
:$12
5.3M
m
ps/
chem
/prg
min
fo/p
rog
ram
s.ht
mO
rgan
omet
allic
(for a
ll C
hem
istr
y)
This
pro
gra
m s
upp
orts
rese
arch
on
synt
hesi
s,st
ruct
ure,
and
reac
tion
mec
hani
sms
of m
olec
ules
con
tain
ing
met
als,
met
allo
ids,
and
non
met
als
enco
mp
assi
ng t
he e
ntire
per
iod
icta
ble
of t
he e
lem
ents
.Inc
lud
ed a
re s
tud
ies
of s
toic
hiom
etric
and
hom
ogen
eous
cat
alyt
ic c
hem
ical
reac
tion;
bio
inor
gan
ic a
nd o
rgan
omet
allic
reag
ents
and
reac
tion;
and
the
syn
-th
esis
of n
ew in
org
anic
sub
stan
ces
with
pre
dic
tab
le c
hem
ical
,phy
sica
l,an
d b
iolo
gic
al p
rop
ertie
s.Su
ch re
sear
ch p
rovi
des
the
bas
is fo
r und
erst
and
ing
the
func
tion
of m
etal
ions
in b
iolo
gic
al s
yste
ms,
for u
nder
stan
din
g t
he s
ynth
esis
of n
ew in
org
anic
mat
eria
ls a
nd n
ew in
dus
tria
l cat
alys
ts,a
nd fo
r sys
tem
atic
und
erst
and
ing
of c
hem
istr
y of
mos
t of
the
ele
-m
ents
in t
he e
nviro
nmen
t.
Mat
hem
atic
al a
nd
Che
mis
try
Org
anic
Che
mic
al
(see
ab
ove)
Extr
aht
tp://
ww
w.n
sf.g
ov/
Phys
ical
Sci
ence
sD
ynam
ics
mp
s/ch
em/p
rgm
info
/pro
gra
ms.
htm
This
pro
gra
m s
upp
orts
rese
arch
on
the
stru
ctur
es a
nd re
actio
n d
ynam
ics
of c
arb
on-b
ased
mol
ecul
es,m
etal
lo-o
rgan
ic s
yste
ms,
and
org
aniz
ed m
olec
ular
ass
emb
lies.
Rese
arch
incl
udes
stu
die
s of
reac
tivity
,rea
ctio
n m
echa
nism
s,re
activ
e in
term
edia
tes,
and
cha
ract
eriz
atio
n an
d in
vest
igat
ion
of n
ew o
rgan
ic m
ater
ials
.Suc
h re
sear
ch p
rovi
des
the
bas
is fo
run
der
stan
din
g a
nd m
odel
ing
bio
log
ical
pro
cess
es a
nd fo
r dev
elop
ing
new
or i
mp
rove
d t
heor
ies
rela
ting
che
mic
al s
truc
ture
s an
d p
rop
ertie
s.
S U B S U R F A C E S C I E N C E
88
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Geo
scie
nces
Eart
h Sc
ienc
es
Hyd
rolo
gic
Sci
ence
sFY
98:
$58.
6M
Extr
aht
tp://
ww
w.g
eo.n
sf.g
ov/
FY 9
9 re
que
st:$
65.7
M
ear/
earc
ore.
htm
(for a
ll of
Ear
th S
cien
ces)
The
Hyd
rolo
gic
Sci
ence
s Pr
ogra
m s
upp
orts
bas
ic re
sear
ch d
ealin
g w
ith t
he e
arth
's h
ydro
log
ic c
ycle
and
the
role
of w
ater
on
and
nea
r the
con
tinen
tal s
urfa
ces.
The
Prog
ram
view
s hy
dro
log
ic s
cien
ces
as a
geo
scie
nce
inte
ract
ive
on a
wid
e ra
nge
of s
pac
e an
d t
ime
scal
es w
ith t
he o
cean
,atm
osp
heric
,and
sol
id e
arth
sci
ence
s as
wel
l as
pla
nt a
nd a
nim
alsc
ienc
es.
Sup
por
ted
pro
ject
s m
ay in
volv
e w
ater
in t
he fo
rm o
f pre
cip
itatio
n,la
kes,
stre
ams,
and
gro
und
wat
er,a
nd in
tera
ctio
ns w
ith la
ndfo
rms,
soils
,the
atm
osp
here
,the
bio
s-p
here
,and
the
Ear
th's
cru
st.T
he p
rog
ram
enc
oura
ges
inte
gra
ted
stu
die
s of
wat
er b
alan
ce a
nd fl
uxes
am
ong
the
var
ious
rese
rvoi
rs.
Geo
scie
nces
Eart
h Sc
ienc
esG
eop
hysi
cs(s
ee a
bov
e)Ex
tra
http
://w
ww
.geo
.nsf
.gov
/ea
r/ea
rcor
e.ht
m
The
Geo
phy
sics
Pro
gra
m s
upp
orts
lab
orat
ory,
field
,the
oret
ical
,and
com
put
atio
nal s
tud
ies
rela
ted
to
com
pos
ition
,str
uctu
re,a
nd p
roce
sses
of t
he E
arth
's in
terio
r.To
pic
s in
clud
est
udie
s in
sei
smic
ity a
nd s
eism
ic w
ave
pro
pag
atio
n;th
e na
ture
and
occ
urre
nce
of e
arth
qua
kes;
mag
netic
,gra
vity
,and
ele
ctric
al fi
eld
s;an
d in
tern
al t
emp
erat
ure
dis
trib
utio
n.Su
pp
orte
d re
sear
ch a
lso
incl
udes
geo
phy
sica
l stu
die
s of
act
ive
def
orm
atio
n,in
clud
ing
GPS
-bas
ed g
eod
esy,
and
fund
amen
tal l
abor
ator
y st
udie
s of
pro
per
ties
and
beh
avio
r of
Eart
h m
ater
ials
in s
upp
ort
of g
eop
hysi
cal o
bse
rvat
ion
and
the
ory.
Geo
scie
nces
Eart
h Sc
ienc
esG
eolo
gy
and
(s
ee a
bov
e)Ex
tra
http
://w
ww
.geo
.nsf
.gov
/Pa
leon
tolo
gy
ear/
earc
ore.
htm
The
Geo
log
y an
d P
aleo
ntol
ogy
Prog
ram
sup
por
ts s
tud
ies
of p
hysi
cal,c
hem
ical
,geo
log
ical
,and
bio
log
ical
pro
cess
es a
t or
nea
r Ear
th's
sur
face
and
the
land
form
s,se
dim
ents
,fos
sils
,lo
w-t
emp
erat
ure
fluid
s,an
d s
edim
enta
ry ro
cks
that
the
y p
rod
uce.
Top
ics
rep
rese
nted
in t
he p
rog
ram
incl
ude
pal
eont
olog
y,p
aleo
ecol
ogy,
stra
tigra
phy
,pal
eocl
imat
olog
y,g
eom
or-
pho
log
y,g
laci
al g
eolo
gy,
sed
imen
tolo
gy,
soil
gen
esis
,sed
imen
tary
pet
rolo
gy,
dia
gen
esis
,and
org
anic
geo
chem
istr
y.
Geo
scie
nces
Cro
sscu
ttin
g P
rog
ram
sEn
viro
nmen
tal
Ap
pro
xim
atel
y $4
.8M
Extr
aht
tp://
ww
w.n
sf.g
ov/
Geo
chem
istr
y an
d
hom
e/cr
ssp
rgm
/eg
b/s
tart
.htm
lBi
ogeo
chem
istr
y
The
goa
l of t
he E
nviro
nmen
tal G
eoch
emis
try
and
Bio
geo
chem
istr
y ac
tivity
is t
o en
hanc
e fu
ndam
enta
l int
erd
isci
plin
ary
rese
arch
on
chem
ical
pro
cess
es t
hat
det
erm
ine
the
beh
avio
r and
dis
trib
utio
n of
inor
gan
ic a
nd o
rgan
ic m
ater
ials
in e
nviro
nmen
ts n
ear E
arth
's s
urfa
ce.O
f par
ticul
ar im
por
tanc
e ar
e p
roje
cts
that
cha
ract
eriz
e ch
emic
al p
aram
eter
s in
bot
h p
ertu
rbed
and
unp
ertu
rbed
nat
ural
sys
tem
s,cl
arify
the
che
mic
al a
nd b
iolo
gic
al p
roce
sses
or b
ehav
ior o
bse
rved
,or c
omb
ine
obse
rvat
ions
and
inte
rpre
tatio
ns in
to p
red
ic-
tive
mod
els.
No
new
aw
ard
s ar
e p
lann
ed a
fter
the
end
of F
Y99.
C h a p t e r 4
89Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
NU
CLE
AR
REG
ULA
TOR
Y C
OM
MIS
SIO
N
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,(F
und
ing
leve
ls a
re
Both
Web
pag
e d
escr
ibin
g a
ll on
-goi
ng
Reg
ulat
ory
Rese
arch
Envi
ronm
enta
l Ris
k,lis
ted
for i
ndiv
idua
l O
ffice
of R
esea
rch
pro
ject
s is
und
er
and
Was
te M
anag
emen
t p
roje
cts
bel
ow a
nd
dev
elop
men
tBr
anch
are
for p
lann
ing
p
urp
oses
onl
y.)
The
rese
arch
con
duc
ted
in t
his
bra
nch
is d
esig
ned
to
mai
ntai
n or
imp
rove
too
ls u
sed
to
eval
uate
the
con
seq
uenc
es o
f dec
isio
ns re
gar
din
g t
he d
isp
ositi
on o
f site
s an
d/o
r fac
ili-
ties
cont
amin
ated
with
rad
ioac
tive
mat
eria
l.Th
is w
ork
is a
com
bin
atio
n of
ap
plie
d a
nd b
asic
rese
arch
.The
bas
ic re
sear
ch is
dire
cted
at
bet
ter u
nder
stan
din
g a
nd m
odel
ing
pro
cess
es,s
yste
ms,
and
eve
nts
that
may
effe
ct s
imul
atio
ns o
f the
evo
lutio
n of
con
tam
inat
ed s
yste
ms
over
tim
e an
d t
he a
ccom
pan
ying
pot
entia
l exp
osur
es o
f the
pub
lic t
o lo
wle
vels
of r
adia
tion.
The
app
lied
rese
arch
is d
irect
ed t
owar
d in
corp
orat
ing
the
se p
roce
ss,s
yste
m,a
nd e
vent
mod
els
into
use
r-fr
iend
ly c
omp
utat
iona
l too
ls.
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,En
gin
eere
d B
arrie
r $1
00K
Both
Reg
ulat
ory
Rese
arch
Envi
ronm
enta
l Ris
k,Pe
rfor
man
cean
d W
aste
Man
agem
ent
Bran
ch
This
pro
gra
m is
dev
elop
ing
mod
els
to a
sses
s th
e lo
ng-t
erm
per
form
ance
of e
ngin
eere
d b
arrie
rs.
A c
oncr
ete
mod
el h
as b
een
dev
elop
ed a
nd is
bei
ng v
alid
ated
thr
oug
h th
e co
l-le
ctio
n an
d s
tud
y of
arc
heol
ogic
al s
amp
les.
Futu
re w
ork
is p
lann
ed t
o lo
ok a
t lo
ng-t
erm
deg
rad
atio
n of
non
-con
cret
e en
gin
eere
d b
arrie
r mat
eria
ls.T
he w
ork
is c
ond
ucte
d in
coop
erat
ion
with
the
Nat
iona
l Ins
titut
e of
Sci
ence
and
Tec
hnol
ogy.
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,So
urce
Ter
m
$100
KIn
tra
Reg
ulat
ory
Rese
arch
Envi
ronm
enta
l Ris
k,C
hara
cter
izat
ion
and
Was
te M
anag
emen
t Br
anch
This
wor
k is
bei
ng c
ond
ucte
d t
o es
tab
lish
the
mec
hani
sms
of d
egra
dat
ion
and
rele
ase
rate
s fo
r rad
ioac
tive
mat
eria
ls fr
om m
iner
al p
hase
s fo
und
in s
lag
s fr
om o
re p
roce
ssin
g.M
any
of t
he s
ame
rad
ionu
clid
e-b
earin
g m
iner
al p
hase
s w
ill b
e fo
und
in a
rtifi
cial
was
te fo
rms
such
as
bor
osili
cate
gla
ss.
Con
tem
por
ary
and
arc
heol
ogic
al s
lag
s ar
e b
eing
exa
m-
ined
with
sop
hist
icat
ed a
naly
tical
eq
uip
men
t at
The
Joh
ns H
opki
ns U
nive
rsity
to
iden
tify
rad
ionu
clid
e b
earin
g m
iner
al p
hase
s an
d t
hen
esta
blis
h d
egra
dat
ion
rate
s fo
r per
iod
s of
up t
o a
thou
sand
yea
rs.T
his
wor
k w
ill e
nd in
Mar
ch 2
000.
S U B S U R F A C E S C I E N C E
90
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,So
rptio
n M
echa
nism
s$5
50K
(in t
wo
Extr
aRe
gul
ator
y Re
sear
chEn
viro
nmen
tal R
isk,
sep
arat
e p
roje
cts)
and
Was
te M
anag
emen
t Br
anch
Sorp
tion
pro
cess
es t
hat
cont
rol t
he re
tard
atio
n of
rad
ioac
tive
mat
eria
ls m
ovin
g in
gro
und
wat
er a
re b
eing
stu
die
d t
o p
rovi
de
bet
ter m
odel
s fo
r thi
s co
mp
lex
pro
cess
.Thi
s w
ork
is b
eing
con
duc
ted
by
Sand
ia N
atio
nal L
abor
ator
ies
(low
to
mid
ato
mic
num
ber
rad
ionu
clid
es) a
nd t
he U
.S.G
eolo
gic
al S
urve
y (u
rani
um a
nd it
s d
ecay
dau
ght
ers)
.
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,C
once
ptu
al M
odel
$4
00K
Extr
aRe
gul
ator
y Re
sear
chEn
viro
nmen
tal R
isk,
Unc
erta
inty
and
Was
te M
anag
emen
t Br
anch
Trad
ition
al e
stim
ates
of u
ncer
tain
ty a
nd v
aria
bili
ty fo
cus
on t
he h
eter
ogen
eity
of n
atur
al s
yste
ms
and
the
par
amet
ers
that
des
crib
e th
ose
syst
ems
as w
ell a
s th
e ac
cura
cy o
f mea
-su
rem
ent
tech
niq
ues.
Dat
a us
ed t
o su
pp
ort
mod
els
are
ofte
n su
bje
ct t
o m
ultip
le in
terp
reta
tions
but
the
unc
erta
inty
ass
ocia
ted
with
sel
ectin
g o
ne in
terp
reta
tion
for m
odel
ing
pur
pos
es is
sel
dom
ad
dre
ssed
or q
uant
ified
.Thi
s p
roje
ct is
sys
tem
atic
ally
look
ing
at
the
pro
cess
of d
ata
colle
ctio
n an
d m
odel
sel
ectio
n fo
r hyd
rog
eolo
gic
sys
tem
s an
d w
ill p
ro-
vid
e a
met
hod
olog
y fo
r ad
dre
ssin
g t
he u
ncer
tain
ty a
ssoc
iate
d w
ith a
ltern
ativ
e co
ncep
tual
mod
els.
This
wor
k is
bei
ng c
ond
ucte
d a
t th
e U
nive
rsity
of A
rizon
a an
d w
ill e
xten
din
to F
Y 20
02.
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,D
eter
min
istic
Effe
cts
$300
KEx
tra
Reg
ulat
ory
Rese
arch
Envi
ronm
enta
l Ris
k,of
Occ
upat
iona
l an
d W
aste
Man
agem
ent
Dos
esBr
anch
Rad
iatio
n ex
pos
ure
dat
a an
d m
edic
al h
isto
ries
for w
orke
rs a
t th
e M
ayak
Pro
duc
tion
Ass
ocia
tion
in R
ussi
a ar
e b
eing
ana
lyze
d u
nder
a jo
int
pro
ject
with
Rus
sian
sci
entis
ts t
oes
tab
lish
a b
asis
for e
stim
atin
g t
he e
ffect
s of
suc
h ex
pos
ures
on
hum
ans.
The
wor
k is
bei
ng c
ond
ucte
d a
t th
e U
nive
rsity
of P
ittsb
urg
h an
d w
ill e
xten
d t
hrou
gh
FY 2
002.
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,Ra
dio
nucl
ide
$150
KEx
tra
Reg
ulat
ory
Rese
arch
Envi
ronm
enta
l Ris
k,So
lub
ilitie
san
d W
aste
Man
agem
ent
Bran
ch
Wor
k b
eing
con
duc
ted
to
exte
nd t
he d
ata
bas
e on
the
sol
ubili
ties
of ra
dio
activ
e sp
ecie
s un
der
diff
eren
t en
viro
nmen
tal c
ond
ition
s su
ch a
s p
H,E
h,an
d io
nic
stre
ngth
.W
ork
isb
eing
con
duc
ted
at
Paci
fic N
orth
wes
t N
atio
nal L
abor
ator
y an
d is
pla
nned
to
cont
inue
thr
oug
h FY
200
0.
C h a p t e r 4
91Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,Pa
ram
eter
$6
00K
Extr
aRe
gul
ator
y Re
sear
chEn
viro
nmen
tal R
isk,
Unc
erta
inty
and
Was
te M
anag
emen
t Br
anch
Thre
e p
roje
cts
are
look
ing
at
def
ault
par
amet
er v
alue
s an
d a
ssum
ptio
ns fo
r per
form
ance
ass
essm
ent
mod
els.
Both
hyd
rog
eolo
gic
par
amet
ers
and
hea
lth e
ffect
s p
aram
eter
s ar
eb
eing
exa
min
ed t
o id
entif
y an
d d
ocum
ent
the
bas
is fo
r cur
rent
par
amet
ers
or re
com
men
d n
ew p
aram
eter
s an
d a
n as
soci
ated
tec
hnic
al b
asis
.Thi
s w
ork
is b
eing
car
ried
out
at
Paci
fic N
orth
wes
t N
atio
nal L
abor
ator
y,A
rgon
ne N
atio
nal L
abor
ator
y,an
d S
and
ia N
atio
nal L
abor
ator
ies
and
will
con
tinue
thr
oug
h FY
200
0.
Offi
ce o
f Nuc
lear
Ra
dia
tion
Prot
ectio
n,Pe
rfor
man
ce$4
50K
Extr
a Re
gul
ator
y Re
sear
chEn
viro
nmen
tal R
isk,
Ass
essm
ent
Cod
e an
d W
aste
Man
agem
ent
Dev
elop
men
t an
d
Bran
chM
aint
enan
ce
A fl
exib
le,i
nteg
rate
d m
odel
cap
able
of a
sses
sing
the
per
form
ance
of a
com
ple
x co
ntam
inat
ed s
ite o
r dis
pos
al fa
cilit
y is
bei
ng d
evel
oped
.The
mod
el is
bei
ng d
evel
oped
with
am
odul
ar s
truc
ture
to
allo
w v
ario
us p
roce
ss m
odel
s to
be
incl
uded
and
with
in a
fully
pro
bab
ilist
ic fr
amew
ork.
This
wor
k is
bei
ng c
ond
ucte
d b
y Sa
ndia
Nat
iona
l Lab
orat
orie
s an
dth
e cu
rren
t p
hase
will
con
tinue
thr
oug
h FY
200
2.
a Ab
out
a q
uart
er o
f thi
s is
dire
cted
tow
ard
site
cha
ract
eriz
atio
n an
d fa
te a
nd t
rans
por
t re
sear
ch.
b Coo
per
ativ
e su
pp
ort—
rese
arch
don
e b
y C
ente
r for
Mul
tipha
se R
esea
rch,
Dep
artm
ent
of E
nviro
nmen
tal S
cien
ces
and
Eng
inee
ring,
Uni
vers
ity o
f Nor
th C
arol
ina.
c WES
Fat
e an
d E
ffect
s p
rog
ram
is b
oth
dire
ct-
and
reim
bur
sab
ly-f
und
ed.
Hea
dq
uart
ers,
U.S
.Arm
y C
orp
s of
Eng
inee
rs,p
rovi
des
the
dire
ct fu
nds
and
Arm
y in
stal
latio
ns m
ay o
r may
not
pro
vid
e th
e
reim
bur
sab
le fu
nds.
d This
lab
orat
ory
oper
ates
as
a N
avy
Wor
king
Cap
ital F
und
act
ivity
.As
such
,all
cost
s,in
clud
ing
ove
rhea
d,m
ust
be
reco
vere
d fr
om v
ario
us s
pon
sors
.Fun
din
g c
omes
from
the
Chi
ef o
f Nav
al R
esea
rch,
the
Nav
al S
yste
ms
Com
man
ds,
and
oth
er g
over
nmen
t ag
enci
es,s
uch
as t
he U
.S.A
ir Fo
rce,
the
Ad
vanc
ed R
esea
rch
Proj
ects
Ag
ency
,the
Dep
artm
ent
of E
nerg
y,an
d t
he N
atio
nal A
eron
autic
s an
d S
pac
e
Ad
min
istr
atio
n,as
wel
l as
seve
ral n
ong
over
nmen
t en
titie
s.e In
clud
es fa
cilit
y op
erat
ions
.FY
99 n
umb
ers
are
for r
esea
rch
only
:En
gin
eerin
g:$
17.4
71M
,Geo
scie
nces
:$24
.189
M.
f Thes
e ar
e to
tal p
rog
ram
cos
ts in
clud
ing
faci
lity
oper
atio
ns.
FY98
"sc
ient
ific
rese
arch
" $1
87M
.g Th
e N
atio
nal U
ser F
acili
ties
are
mai
ntai
ned
by
bot
h of
the
se e
ntiti
es.T
hese
use
r fac
ilitie
s ar
e lis
ted
in T
able
4.2
h Th
e H
azar
dou
s Su
bst
ance
s Re
sear
ch C
ente
rs a
re li
sted
in t
he t
ext.
i The
NSF
pro
vid
es p
artia
l sup
por
t fo
r 21
Long
Ter
m E
colo
gic
al R
esea
rch
Site
s.Th
e D
ivis
ion
on B
iolo
gy
pro
vid
es s
upp
ort
for 1
9 of
thes
e 21
.In
FY
99 $
12.7
M o
f bio
log
y fu
ndin
g w
as a
lloca
ted
for t
his
pro
gra
m.
S U B S U R F A C E S C I E N C E
92
TABL
E 4.
1 Co
ntin
ued
(Not
e:Fu
ndin
g in
form
atio
n is
for f
isca
l yea
r 199
9 un
less
oth
erw
ise
note
d.Th
e fu
ndin
g le
vels
are
for c
omp
aris
on p
urp
oses
onl
y an
d a
re a
pp
roxi
mat
e fig
ures
bas
ed o
n th
e b
est
avai
lab
le d
ata.
In s
ome
case
s re
liab
le d
ata
coul
d n
ot b
e ac
qui
red.
This
list
is n
ot c
omp
rehe
nsiv
e.)
Sect
ion,
Prog
ram
Sub
-pro
gra
mFu
ndin
g L
evel
Intr
a- o
r W
eb S
ite fo
r D
epar
tmen
t,Ex
tram
ural
Sour
ce a
nd
or D
ivis
ion
Mor
e In
form
atio
n
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
5
Knowledge Gaps and Research Needs
The statement of task for this study directed the committee to identifysignificant knowledge gaps relevant to subsurface contamination prob-lems at DOE sites and to provide recommendations for a long-termbasic research program to fill those gaps (see Sidebar 1.1). In thischapter, the committee identifies what it judges to be the significantknowledge gaps that emerged from its review of DOE’s subsurfacecontamination problems in Chapter 2 and, for each identified gap, thecommittee provides a short discussion of basic research needs. Thisinformation will be used to formulate recommendations for a long-termresearch program in Chapter 6.
For purposes of this discussion, the committee defines “knowledgegap” as a deficiency in scientific or engineering understanding that isnow, or likely will be in the future, a significant impediment to DOE’sefforts to complete its mission to clean up, stabilize, or contain subsur-face contamination. Perhaps the most direct manifestation of a DOEknowledge gap is a technology gap, that is, a deficiency in technicalcapabilities to identify and deal with contamination problems. Thecommittee has not focused on technology gaps in this report; that is thetopic of another recent NRC report (NRC, 1999). Rather, the committeehas focused on the identification of the knowledge gaps that underpinthose technology gaps.
The committee has been selective in the identification of subsurfacecontamination knowledge gaps and research needs for the EM ScienceProgram. The identification of knowledge gaps involves an appreciableelement of judgment on the part of the committee, especially in inter-preting the significance of the subsurface contamination problems (seeChapter 2) and the scope and objective of other federal research pro-grams. The committee believes that the gaps it has identified are highly
C h a p t e r 5
93Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
significant and that they must be addressed through basic research ifthe DOE cleanup program is to succeed. Further, the committeebelieves that a focus on these knowledge gaps is likely to yield thegreatest payoffs for DOE in terms of enhanced cleanup capabilities atreduced costs and risks at major DOE sites.1 This is especially truegiven the small size of the EM Science Program relative to the scope ofthe DOE cleanup mission. The annual budget for the EM ScienceProgram budget is on the order of $30 million to $50 million and isused to support basic research related to all aspects of the cleanup mis-sion. This is less than 0.1 percent of the total EM annual budget of $5.8billion. Without a significant increase in its budget, the EM Science pro-gram is unlikely to have a significant impact on DOE cleanup effective-ness and costs.
Organiz ing Scheme Used in ThisAnalys is
The committee identified significant knowledge gaps and researchneeds through discussions and analyses of the “snapshot” of DOE’s sub-surface contamination problems presented in Chapter 2. To organizethis analysis and ensure its completeness, the committee developed theorganizing scheme shown in Figure 5.1. This organizing scheme isbased partly on the approach used by the Subsurface ContaminantsFocus Area to organize its technology development programs (seeFigure 3.2), but it also includes the data collection and analysis stepsthat provide the supporting information needed to make appropriatecorrective action decisions.2 The committee’s organizing scheme, here-after referred to as the framework for site remediation, is describedbriefly in the following paragraphs.
S U B S U R F A C E S C I E N C E
94
1As discussed in Chapter 2, the major sites represent DOE’s largest future mort-gages and longest-term commitments.
2The committee uses the term "corrective action" in the following discussion torefer to actions taken by DOE to address its subsurface contamination problems. Acorrective action can range from no action in cases where the subsurface contami-nation is thought to pose minimal hazards to humans or the environment, orwhere remediation is infeasible, to aggressive actions to treat, remove, or containcontamination that poses significant hazards. As noted in Chapter 1, the term issometimes used interchangeably with terms like "cleanup" and "remedial action,"but it really encompasses a broader range of possible options for dealing with con-tamination, because it includes the no action (i.e., no cleanup or no remedialaction) option.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
The boxes in Figure 5.1 represent each of the major steps in theremediation process, and the arrows represent decision and assessmentpoints. Boxes 1 through 5 represent the process that could be followedto develop information to make an appropriate corrective action deci-sion. The initial step is focused on locating and characterizing the conta-minants of concern (Box 1). This step involves determining the spatialdistributions, types, amounts, and physical and chemical states of sub-surface contaminants, as well as the subsurface properties that affectcontaminant fate and transport behavior. Locating and characterizing con-tamination in the subsurface may be done using direct (e.g., drilling andsampling) and indirect (e.g., surface and borehole geophysical) tech-niques.
The location and characterization data obtained in the first step arethen used to develop a conceptual model of the site (Box 2), that is, adescription of the subsurface as estimated from knowledge of theknown site geology and hydrology and the physical, chemical, and bio-logical processes that govern contaminant behavior. The conceptualmodel provides a descriptive framework for assessing how the subsur-face system will behave with passing time and in response to potentialcorrective actions. As noted later in this discussion, the conceptualmodel is improved over time as more information on subsurface condi-tions and processes becomes available.
The conceptual model provides a basis for constructing more quan-
95
C h a p t e r 5
Locate &characterize
Developconceptual
model
Predictsystem
behavior Monitor
Assessrisk
Monitor
1.
1.
2.
2. 3. 4. 5. 7.
Validate models
Validate performance of remedial action
6. Corrective
Action
A. Take noremedial action
B. Contain &stabilize
C. In situ treator transform
D. Removehotspots
E. Removecontamination
FIGURE 5.1 Framework for site
remediation.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
titative dynamic models that can be used to predict behavior (Box 3) ofthe subsurface system over a specified time period. These predictivemodels are developed from mathematical representations of the con-ceptual model. In current practice, most predictive models are discreterepresentations of the physically continuous subsurface system and aretypically solved with such numerical techniques as finite elements andfinite difference.3 The parameters in these models represent the physi-cal, chemical, and biological characteristics at each point in the subsur-face. Parameters of interest in predictive models quantify the relation-ship between the driving forces (e.g., hydraulic gradient and chemicalconcentration gradient) and the resulting behavior (e.g., flow and trans-port). In the case of discrete models, the parameter values are meant torepresent volume-averaged properties around each modeled point.
The predicted system behavior is then compared to the observedbehavior as measured in the field through monitoring activities (Box 4).A feedback loop (Arrow 1) updates the conceptual and predictive mod-els when the behaviors do not match according to some specified mea-sure(s) of comparison. The process of testing the predictive model todetermine whether it appropriately represents the system behavior ofinterest is usually referred to as model validation.4 Because of uncer-tainties in the model and data any match between predicted andobserved behaviors is only possible in a statistical sense. Consequently,validation is best thought of as a process of confidence buildingthrough increased understanding of fundamental mechanisms in theunderlying system rather than as a process to confirm or prove the cor-rectness of a model.
The predictive model can be used to understand the present behav-ior of the subsurface system and to estimate future contaminant migra-tion to assess risk to human and environmental health (Box 5). A cor-rective action decision (Box 6A-E) that will reduce risk to acceptablelevels is then made using the information developed in the risk assess-ment. The corrective action can range from no action (Box 6A) toremove contamination (Box 6E).
During and following the corrective action, monitoring activities(Box 7) are again employed to assess the efficacy of that action. Long-term monitoring is usually required to confirm the effectiveness of, or togain regulatory approval for, approaches that involve no action or con-
S U B S U R F A C E S C I E N C E
96
3Continuous representations are sometimes used in analytical models forscreening-level assessments.
4In model development protocol, a step referred to as model verificationinvolves evaluating whether the numerical model solves the mathematical equa-tions of the conceptual model with acceptable accuracy. In this discussion, modelverification is included as a step in the validation process.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
tainment and stabilization. Inconsistencies between the measured andpredicted performance of the corrective action may indicate that theconceptual model of the system is deficient or that the parameters ofthe model are not sufficiently resolved, and it may be extremely diffi-cult to know which is the case. In these cases, there is a feedback loop(Arrow 2) to the conceptual model (Box 2) through the predictivemodel, which must be updated so that the corrective action decisionprocess can be revisited.
Although the framework for site remediation shown in Figure 5.1 ispresented as a linear process, it is in reality an observational procedurethat follows both parallel and iterative paths. The framework may betraversed many times as new information is acquired and incorporatedinto the conceptual and predictive models and as corrective action per-formance is assessed.
There is some correspondence between the organizing scheme out-lined in Figure 5.1 and the technology development organizing schemeshown in Figure 3.2. For example, the identify function in Figure 3.2 isroughly equivalent to the locate and characterize function in Figure5.1. Similarly, the validate function in Figure 3.2 is roughly equivalentto the validate performance of remedial action function (Arrow 2) inFigure 5.1. The remaining functions in Figure 3.2 have no directlyequivalent functions in Figure 5.1, and there are many functions inFigure 5.1 that are not represented at all in Figure 3.2 (e.g., the developconceptual model and predict system behavior functions). The organiz-ing scheme shown in Figure 5.1 is more complete than that given inFigure 3.2.
Knowledge G apsThe committee identified significant knowledge gaps in the follow-
ing process steps in the framework for site remediation shown in Figure5.1:
• location and characterization of subsurface contaminants andcharacterization of the subsurface (Box 1);
• conceptual modeling (Box 2);• containment and stabilization (Box 6B); and• monitoring and validation (Boxes 4 and 7 and Arrows 1 and 2).
These knowledge gaps do not include those associated with activeremediation of subsurface contamination (Boxes 6C-6E), with theexception of remediation monitoring. This may come as a surprise to
C h a p t e r 5
97Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
some readers, given that the current EM Science Program portfolio isheavily focused on this area (see the closing section of Chapter 3). Thecommittee did not highlight knowledge gaps on these process steps,because subsurface contamination is highly distributed at many DOEsites, making cost-effective remediation infeasible, and because EMScience Program resources are limited and there is much work on thesetopics in other federal research programs (see Chapter 4).
Location and Characterization of SubsurfaceContaminants and Characterization of the Subsurface An important conclusion that emerges from the committee’s analysis
of subsurface contamination problems in Chapter 2 is that the capabili-ties to locate and characterize subsurface contaminants at many DOEsites are incomplete. This conclusion is perhaps best supported by thefollowing three examples from Chapter 2:
• subsurface radionuclide contamination in the 200 Area atHanford;
• mixed contaminant plumes at Test Area North at the Idaho Site;and
• contaminant plumes and hot spots in waste burial grounds at theSavannah River Site.
Locating contamination in the subsurface at DOE sites has focusedon three interrelated approaches: (1) information derived from historicaloperations and records; (2) direct observations of contamination on thesurface, in surface water, and in boreholes; and (3) indirect geochemi-cal and geophysical measurements from the surface and in boreholes.These three sources of information have been used at some sites todevelop predictive models of contaminant movement in the subsurface,and the predictive models have been tested by further direct observa-tions and measurements. Frequently, these models have not capturedthe essential behavior of the contaminant, either in direction or speedof movement.
The challenges of locating subsurface contamination are magnifiedby the wide range of contaminant types (e.g., mixtures of organic sol-vents, metals, and radionuclides) in the subsurface at many DOE sites(see Chapter 2); the wide variety of geological and hydrological condi-tions across the DOE complex (see Table 2.2); and the wide range ofspatial resolutions at which this contamination must be located andcharacterized, ranging from widely dispersed contamination in ground-water plumes to small isolated hot spots in waste burial grounds.Moreover, because contaminant migration involves dynamic transport
S U B S U R F A C E S C I E N C E
98Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
processes, continuous temporal information on contaminant locationsis required. In effect, location, characterization, and continuing moni-toring efforts must be integrated to assure an adequate database forplanning and implementing appropriate corrective actions.
Fundamental advances in capabilities to locate and characterizesubsurface contamination and important subsurface properties will helpDOE better assess the potential hazards of its contamination problemsand to design and implement appropriate corrective action strategies(e.g., see Sidebar 5.1). Moreover, research on subsurface heterogeneityin geology, geochemistry, hydrology, and microbiology will provide aframework for assessing the fate and transport of contaminants.Examples of significant knowledge gaps include the following:
• Locating contaminants in the subsurface. At many sites, thepoints of entry of contaminants into the subsurface (e.g., througha leaking waste burial ground or injection well) are at leastapproximately known. However, the determination of the spatialdistributions of contaminants (that may or may not change withtime) once they enter the subsurface remains a major knowledgegap. Currently available indirect measurement methods (e.g.,geophysical methods) are inadequate for locating most types ofcontaminants in the subsurface, and direct methods such asdrilling are both expensive and limited in effectiveness, becausethey only provide samples from specific points in the subsurfacealong the borehole. Moreover, boreholes provide potential con-taminant transport pathways through the subsurface.
• Characterizing contaminants in the subsurface. Once contami-nants enter the subsurface, they can act as long-term sources ofpollution to ground or surface water. Understanding how tocharacterize the concentrations, speciations, and release rates ofcontaminants in the subsurface is a significant knowledge gapacross the DOE complex. In general, there are poor records ofcontaminant discharges to the subsurface, so contaminant quan-tities are highly uncertain. Moreover, once contaminants enterthe subsurface they can move long distances, either diffusingthrough the fluid medium or migrating as a distinct plume, lead-ing to contaminant distributions that are variable in size, shape,
C h a p t e r 5
99
5Direct observing technologies allow in situ measurements or samples to beobtained (e.g., by drilling). Indirect observing technologies allow measurements to be made remotely (e.g., through geophysical measurements of the subsurface).The terms "invasive" and "noninvasive" are sometimes used synonymously, but thisusage is not strictly correct. Indirect measurements can be obtained through inva-
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
and concentration. Currently available direct and indirectobserving technologies5 have limited effectiveness for character-izing site conditions and defining the extent and concentrationsof contaminant bodies.
• Characterizing physical, chemical, and biological properties ofthe subsurface, including improved approaches to understandingthe properties of the geologic system and relating them to conta-minant fate and transport. The subsurface characteristics at a siteplace fundamental controls on contaminant fate and transportbehavior. Subsurface characteristics also govern the selection ofconceptual and predictive models as well as the application andeffectiveness of appropriate corrective actions. The knowledgegaps include understanding which characteristics control fateand transport behavior in the subsurface and also understandinghow those characteristics can be measured at the appropriatescales over large subsurface volumes, using both indirect anddirect techniques. The integration of direct measurements of sub-surface geologic properties with indirect measurements (e.g.,from geophysical methods) has been used very successfully inthe petroleum industry to develop conceptual and quantitativemodels of subsurface transport. Such methods are potentiallyapplicable to DOE sites.
• Characterizing highly heterogeneous systems. This knowledgegap is a special case of the previous knowledge gap and is a sig-nificant problem at many DOE sites, which are very large in spa-tial extent and exhibit intra- and inter-site variations in geologicand hydrologic conditions (see Chapter 2). Heterogeneity arisesfrom the spatial variability in geological, chemical, and biologi-cal properties of the subsurface. A fundamental understanding ofthese properties, and especially the geological framework, is anecessary prerequisite to understanding the fate and transport ofcontaminants. Heterogeneity may occur at several spatial scalesin complex subsurface systems, but they may control contami-nant fate and transport processes only at one or a few scales.The primary knowledge gaps are in understanding the hetero-geneity scales that govern these processes, how to characterizethis heterogeneity without having to perform an exhaustive char-acterization of the subsurface, and how to represent this hetero-geneity in mathematical formulations.
Research Needs
S U B S U R F A C E S C I E N C E
100
sive means, as when borehole geophysical methods are employed to obtain sub-surface measurements.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
In the committee’s judgment, basic research can support the devel-opment of new and improved capabilities to locate and characterizecontamination in the subsurface, and also to characterize subsurfaceproperties at the scales that control contaminant fate and transportbehavior. Development of the following capabilities is especially needed:
1. Improved capabilities for characterizing the physical, chemical,and biological properties of the subsurface. These approachesshould provide information on the following system propertiesand behaviors at the spatial and temporal scales that controlcontaminant fate and transport behavior:
• contaminant locations and characteristics;• transport pathways;• subsurface properties and boundary conditions that control
contaminant fate and transport behavior; and• physical, chemical, and biological interactions between con-
C h a p t e r 5
101
SIDEBAR 5.1 NEW APPROACHES FOR DIRECT OBSERVING
The major limitations on direct observations by conventional drilling and sampling have been high
costs and concerns that direct approaches may unwittingly exacerbate the spread of contaminants in
the subsurface. The use of reduced diameter drillholes (using 4- to 6-inch diameter drills) as a cost-sav-
ing method has been explored widely in the petroleum industry, but cost reductions have not been
encouraging. However, recent developments in miniaturized drilling and sampling technologies (e.g.,
Albright and Dreesen, 2000) hold promise for significantly reducing drilling costs and reducing the
potential for contaminant spread when these technologies are used at DOE sites.
A new technology, microdrilling, represents the kinds of advanced capabilities made possible by basic
scientific and engineering research. This technology uses coiled tubing, steerable miniature-diameter
(1 3/8 inches to 2 inches [3.5 centimeters to 5.1 centimeters]) down-hole motors, and down-hole micro-
instrumentation to obtain in situ measurements and samples of contaminated subsurface environ-
ments. Additionally, smaller diameter holes reduce contaminant migration potential and promote
more effective sealing.
The depth capabilities thus far demonstrated are adequate for almost all of the major DOE sites (down
to about 300 meters, or about 1,000 feet). Many aspects of this microborehole technology still require
extensive research and development, including work on sampling techniques, down-hole instrumenta-
tion for diverse measurements, and effective plugging; however, enough feasibility demonstrations
have been completed to indicate great promise for use at DOE and other contaminated sites.
Albright and Dreesen (2000) suggest that this technology may cut drilling costs by at least 70 percent
compared to conventional technologies. They also suggest that much greater cost savings are possible
as these techniques are refined.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
taminants and earth materials.
Research on indirect observations could involve the develop-ment of new approaches for measuring contaminant and subsur-face properties (e.g., approaches utilizing “unconventional” geo-physical wave attributes such as polarized and nonlinear waveresponses) or new ways of interpreting “conventional” observa-tional data to obtain information on the system properties ofinterest. For direct observations, the research must also addresshow the observing process changes the system being measured.Approaches for making direct and indirect observations in theunsaturated zone are especially needed.
2. Improved capabilities for characterizing physical, chemical, andbiological heterogeneity, especially at the scales that controlcontaminant fate and transport behavior. Approaches that allowmeasurements or estimates of heterogeneity features to beobtained directly (i.e., without having to perform a detailed char-acterization of the subsurface) are especially needed.
3. Improved capabilities for measuring contaminant migration andthe system properties that control contaminant movement.
4. Methods to integrate data collected at different spatial and tem-poral scales to better estimate contaminant and subsurface prop-erties and processes, and also methods to integrate such datainto conceptual models.
Conceptual ModelingAs shown by several examples in Chapter 2, DOE is finding subsur-
face contamination in unexpected places:
• Technetium was discovered in groundwater beneath the SX TankFarm in the 200 Area at the Hanford Site.
• Plutonium was discovered in colloids in groundwater near theBenham Test at the Nevada Test Site.
• Plutonium was discovered in groundwater beneath theRadioactive Waste Management Complex at the Idaho Site.
These discoveries were “unexpected” because models of the subsur-face at these sites did not predict them (e.g., see Sidebar 2.6). Concep-tual and predictive models have been developed for subsurface conta-minant fate and transport for many DOE sites, but in many cases thesemodels have proven ineffective for understanding and predicting conta-minant movement, especially at sites that have thick unsaturated zonesor complex subsurface characteristics.
S U B S U R F A C E S C I E N C E
102Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
The conceptual model “problem” has many possible causes. Themodels themselves may be deficient because they were developedusing insufficient data on subsurface characteristics, contaminant distri-butions, or transport processes, or the models may simply have aninappropriate theoretical basis. Good conceptual models must begrounded in sound theory and underpinned with sound and sufficientdata. In the committee’s judgment, at least part of the problem is thatconceptual model development is not viewed as an explicit part ofremediation practice. Consequently, there are few standardized tools oraccepted methodologies for developing such models, which has led toad hoc and inconsistent approaches across DOE sites.
Accurate conceptualizations are essential for understanding thelong-term fate of contaminants in the subsurface and the selection andapplication of appropriate corrective actions. The significant knowledgegaps include the following:
• Contaminant fate and transport. Understanding the factors con-trolling the long-term fate of contaminants in the subsurface isimportant for assessing the potential for human and ecologicalexposure and for selecting appropriate corrective actions.Understanding the dominant contaminant transport processesand pathways through the subsurface remains a significantknowledge gap for building accurate and useful conceptual andpredictive models. The simplest formulation of contaminanttransport uses porous media flow of a dissolved phase, but suchtransport may be the exception at many DOE sites, where trans-port can occur in several distinct manners (e.g., colloidal trans-port) through both porous media and fractures and may involvea variety of chemical and biological reactions. The myriadchemical, biological, and physical processes operating in thesubsurface operate at different time scales and are poorly under-stood, especially for metals and radionuclides.
• Coupling physical, chemical, and biological processes. The phys-ical, chemical, and biological properties and processes that gov-ern contaminant fate and transport do not act independently.Rather, they interact (i.e., they are coupled) in complex and oftenpoorly understood ways. Many coupled processes operate oververy small spatial scales that are defined by a distribution of prop-erties, making it difficult to incorporate representations of theseprocesses into conceptual and mathematical models. For exam-ple, redox potential and pH (chemical properties related to bulkmineralogy, biological activity, and fluid composition) can affecteither or both physisorption and chemisorption of contaminants
C h a p t e r 5
103Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
onto solid phases. The heterogeneous distribution of permeability(a physical property related to the geological characteristics of thesubsurface) can result in highly variable rates of fluid flow (aphysical process). These processes combine to effect transport (acoupled process) of certain metals and radionuclides over smallspatial scales. Similarly, the coupling of biomass availability (aproperty with biological, physical, and chemical components)and substrate availability (controlled by processes such as sorp-tion, dissolution, and transport) with the distribution of electronacceptors (also possessing biological, physical, and chemicalcontrols) can result in spatially variable rates of in situ contami-nant biodegradation (a coupled process). The coupling ofprocesses and their control by subsurface properties are onlybeginning to be understood. Moreover, little progress has beenmade on how to represent coupled processes in predictive mod-els.
• Model parameter development. Model parameters are wellunderstood and definable for very simple homogeneous subsur-face systems. However, in highly complex subsurface systems,parameter definition may require unobtainable amounts ofdetailed characterization data. In these cases, it is important tounderstand which processes are actually dominating the behav-ior of the system and to define parameters appropriate to thoseprocesses. Determining how to make the appropriate simplifica-tions and approximations is the main thrust of conceptual mod-eling research that leads to the identification of appropriatemodel parameters.
The definition and estimation of model parameters requires a goodunderstanding of the subsurface system and transport processes beingmodeled, which is not often the case at DOE sites. For example, thetraditional approach for modeling porous media is to choose perme-ability as a model parameter. If the porous medium is highly heteroge-neous (e.g., if it contains a few large and interconnected fractures) thenthe generalized concept of permeability is not well defined, and perme-ability may not be an appropriate characterization of the physical sys-tem. Flow and transport may be dominated by the fracture system, andthe model parameters should represent the properties of these perme-able and connected pathways. Similarly, for fate and transport models,the traditional approach is to assume equilibrium sorption and use theequilibrium partition coefficient as a model parameter. If the sorptionreactions are not at equilibrium, however, then the equilibrium parti-tion coefficient by itself is not an appropriate parameter, and additional
S U B S U R F A C E S C I E N C E
104Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
parameters describing mass transfer kinetics must also be included. Thechallenge is to define the right conceptualization of the physical, chem-ical, or biological processes that dominate system behavior, which inturn defines the appropriate model parameters to be used.
The field observations used to develop parameter estimates aremade at many different scales and times and provide information aboutdifferent properties of the subsurface system. Samples from drillholecore, for example, can provide detailed information on the physical,chemical, and biological properties of the subsurface at small (centime-ter) spatial scales. Borehole testing data (e.g., hydraulic pumping testsand tracer tests) and indirect observations (e.g., seismic surveys) provideindirect measurements of subsurface properties averaged over muchlarger (meters to tens of meters) spatial scales. Observations of a givensubsurface region using different measurement techniques can yieldvery different results, and measurements from a single technique canshow significant variations over small spatial scales. One of the primaryknowledge gaps for model conceptualizations is understanding how tointegrate these field observations into the models and parameter esti-mates. The knowledge gaps include understanding the scale effects anddeveloping methods for data integration that take these effects intoaccount.
Research NeedsConceptual model development has not been an explicit topic for
basic research in its own right. Indeed, conceptual model developmentis viewed as an inherently empirical and site-specific process usingobservational approaches that are not easily generalized or tested. Thecommittee believes, however, that basic research that addresses thefundamental approaches and assumptions underlying conceptual modeldevelopment could produce a tool box of methodologies that areapplicable to contaminated sites both inside and outside the DOE com-plex. This research should focus on the following topics:
1. New observational and experimental approaches and tools fordeveloping conceptual models that apply to complex subsurfaceenvironments, including such phenomena as colloidal transportand biologic activity.
2. New approaches for incorporating geological, hydrological,chemical, and biological subsurface heterogeneity into concep-tual model formulations at scales that dominate flow and trans-port behavior.
3. Development of coupled-process models through experimentalstudies at variable scales and complexities that account for the
C h a p t e r 5
105Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
interacting physical, chemical, and biological processes thatgovern contaminant fate and transport behavior.
4. Methods to integrate process knowledge from small-scale testsand observations into model formulations, including methods forincorporating qualitative geological information from surface andnear-surface observations into conceptual model formulations.
5. Methods to measure and predict the scale dependency of para-meter values.
6. Approaches for establishing bounds on the accuracy of parame-ters and conceptual model estimates from field and experimentaldata.
The research needs outlined above call for more hypothesis-drivenexperimental approaches that address the fundamental methods andassumptions underlying the development of conceptual models. Thisresearch will require expertise from a wide range of disciplines andmust be conducted at scales ranging from the laboratory bench top tocontaminated field sites.
Moreover, to have long-term relevance to the DOE cleanup mission,this research must be focused on the kinds of subsurface environmentsand contamination problems commonly encountered at major DOEsites. One way to ensure this focus is to give researchers the opportuni-ty to conduct research at contaminated DOE sites. The committee pro-vides additional comments on this issue in the next chapter.6
Containment and StabilizationAs noted by DOE in Paths to Closure (DOE, 1998a) and as shown in
Chapter 2 of this report, a great deal of subsurface contamination islikely to remain at DOE sites even after DOE’s cleanup program is com-pleted. It will include contaminant plumes in groundwater, contaminat-ed soil, and waste burial grounds—both the historical burial groundsdiscussed in Chapter 2 and new burial grounds developed by DOE todispose of waste from its current and future cleanup operations. DOE isresponsible for the long-term management of this contamination andmust develop methods to contain and stabilize it until it no longerposes a hazard to humans or the environment—or until new methodsto remediate this contamination are developed. DOE’s managementcommitment potentially extends for many thousands of years. DOE’scontainment and stabilization systems are likely to include surfacecaps, subsurface barriers, and other in situ stabilization systems. Once
S U B S U R F A C E S C I E N C E
106
6See the section titled "Field Sites" in Chapter 6.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
installed, these systems will have to be monitored to assure that theyperform as expected, and if these systems fail, additional correctiveactions may have to be taken to repair the barriers and remediate resid-ual contamination. There has been an increasing emphasis and accep-tance of waste containment and stabilization in recent years, both inDOE and by regulatory agencies. Decreasing cleanup budgets, evalua-tions that show that containment is a low-risk choice for some prob-lems, and recognition that some contamination cannot be remediatedeither with current technologies or conceivable new technologies areresponsible for this change in philosophy. This shift in emphasis is per-haps first fully acknowledged by DOE in Paths to Closure (DOE,1998a), which lays out DOE’s cleanup objectives, and appears to be adeveloping trend across the DOE complex.7 A more recent DOE report(DOE, 1999) discusses the long-term stewardship challenges.
At some sites, containment and stabilization may be an interimmeasure and has its own set of associated technical problems. Theseinclude particularly the availability of appropriate technologies to bothcontain and stabilize the residual contamination and to monitor andvalidate the long-term performance of containment and stabilizationsystems themselves. There is little understanding of the long-term per-formance of containment and stabilization systems, and there is a gen-eral absence of effective methods to validate that such systems areproperly installed or that they can provide effective long-term perfor-mance. To address this knowledge gap, advances in basic knowledge tosupport the development of new and improved waste containment andstabilization systems will be needed, as noted below.
The development of improved and novel containment and stabiliza-tion approaches will likely have the highest potential for cost savingsand lowered risk of the four knowledge gaps identified by the commit-tee. The committee believes that the significant knowledge gapsinclude the following:
• Development of robust physical, chemical, and biological con-tainment and stabilization systems. Traditional containment sys-
C h a p t e r 5
107
7Another recent example of the shift in emphasis to containment strategies canbe found in a recent report on disposal of DOE low-level waste (DOE, 1998e).This report shows that DOE’s estimates of the volume of its low-level waste requir-ing disposal between 1998 and 2070 has decreased from about 32 million cubicmeters to about 8 million cubic meters, largely because DOE has decided to con-tain much of this low-level waste in place at its sites, rather than removing it fortreatment or disposal elsewhere in the complex. Most of this waste exists in wasteburial grounds at the major DOE sites (see Chapter 2).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
tems comprised of surface caps, in situ walls, and bottom barri-ers employ low-permeability materials to reduce water infiltra-tion and provide a barrier to contaminant migration. Whendesigned properly, these systems may provide effective contain-ment for periods of up to a few decades,8 but current designs donot meet DOE’s needs for containment of its long-lived radioac-tive and hazardous waste—both for wastes contained in placeand new waste sites developed from current and future cleanupoperations. Natural low-permeability materials for minimizinginfiltration (e.g., clays) work well in humid environments, butthey may not be effective in arid regions, where dessication canlead to the development of preferred pathways.
To the committee’s knowledge, there has been little or noresearch or development work on longer-term systems for con-tainment of subsurface contamination of the sort encountered atDOE sites, either by DOE or by other organizations.9 Theknowledge gaps include understanding how to design moreeffective and permanent barrier systems for long-term contain-ment, especially in arid environments characteristic of the west-ern DOE sites, including the development and application ofmore durable materials for barrier systems—materials that arecompatible with the surrounding environment and with thewaste that is being contained.
• New containment approaches. Conventional barrier systemsseek to minimize water infiltration into the contained waste andto minimize the spread of waste from containment zones intothe environment. Surface barrier systems (caps) have proven veryeffective for retarding water infiltration into containment zones,but they require ongoing maintenance to ensure their continuedintegrity, and they have short lives relative to the hazard of thecontained waste. Moreover, subsurface infiltration barriers (e.g.,impermeable walls installed around or beneath waste burialgrounds) are extremely difficult to install and maintain, especial-ly barriers emplaced beneath waste containment zones, andtheir performance is also extremely difficult to monitor.
New approaches are needed to address DOE’s needs forlong-term in situ containment and treatment of subsurface conta-
S U B S U R F A C E S C I E N C E
108
8To the committee’s knowledge, this supposition has never been tested at aDOE site, so the actual longevity of such barrier systems is uncertain at best.
9There has been a great deal of research and development work in the UnitedStates and other countries on long-term containment systems for spent fuel andvitrified high-level waste, but this work does not appear to be directly applicableto the contamination problems at DOE sites.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
mination. The recent development of reactive barriers (i.e., barri-ers that degrade or immobilize contaminants through geochemi-cally and biochemically mediated reactions, such as ionexchange or redox processes) is an example of the kind of newapproach that holds promise. The continued development ofreactive barriers and the development of other hybrid systems(e.g., barrier systems that incorporate biological materials toreduce maintenance requirements and enhance long-term per-formance, or systems that use controlled water infiltration toenhance waste decomposition or transformation) could improvethe technology for containment and in-situ stabilization of sub-surface contaminants across the DOE complex.
Research NeedsThe construction of stabilization and containment systems is proper-
ly within the province of applied technology development and will bethe responsibility of other DOE programs (e.g., the Subsurface Contami-nants Focus Area). However, basic research focused on the followingtopics will be needed to support this technology development effort:
1. The mechanisms and kinetics of chemically and biologicallymediated reactions that can be applied to new stabilization andcontainment approaches (e.g., reactions that can extend the useof reactive barriers to a greater range of contaminant types foundat DOE sites) or that can be used to understand the long-termreversibility of chemical and biological stabilization methods.
2. The physical, chemical, and biological reactions that occur amongcontaminants (metals, radionuclides, and organics), soils, and barri-er components so that more compatible and durable materials forcontainment and stabilization systems can be developed.
3. The fluid transport behavior in conventional barrier systems, forexample, understanding water infiltration into layered systems,including infiltration under partially saturated conditions andunder the influences of capillary, chemical, electrical, and ther-mal gradients that can be used to support the design of moreeffective infiltration barrier systems.
4. The development of methods for assessing the long-term durabil-ity of containment and stabilization systems.
Monitoring and ValidationThe ability to monitor and validate is essential to the successful
application of any corrective action to a subsurface contaminationproblem, as is regulatory acceptance of that action. However, the
C h a p t e r 5
109Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
knowledge and technology bases to support these activities are not fullydeveloped and are receiving little attention in EM’s science and tech-nology programs. The monitor process step does not appear on theSubsurface Contaminants Focus Area’s remedial action flow chart (seeFigure 3.2), and its validate process step applies only to the confirma-tion of the performance of a remedial action. As noted in Chapter 3,very little research relevant to these activities is being supported cur-rently by the EM Science Program.
As illustrated by Figure 5.1, monitoring and validation are importantat both the front and back ends of the site remediation process. At thefront end, monitoring and validation are used to support the develop-ment of conceptual and predictive models of subsurface and contami-nant behavior (Box 4 and Arrow 1). At the back end, monitoring andvalidation are used to gain regulatory acceptance for corrective actionsand to demonstrate the effectiveness of efforts to remove, treat, or espe-cially to contain contamination (Box 7 and Arrow 2). Such monitoringand validation efforts can also improve the understanding of the conta-minant fate and transport processes and can be used to recalibrate andrevise conceptual and predictive models—important elements of themodel building process.
Improvements in capabilities to monitor and validate could greatlyimprove the technical success of DOE’s efforts to contain and stabilizecontamination at its sites. The development of new containment andstabilization approaches could lower the cost, accelerate regulatoryapprovals for, and increase public confidence in efforts to address DOEcontamination problems. In the committee’s judgment, the significantknowledge gaps include the following:
• Design of efficient and effective monitoring systems. There is lit-tle experience with monitoring over the long (decadal to centen-nial) time scales that are required at DOE sites. Consequently, agreat deal of basic knowledge is required to design efficient andeffective monitoring systems. The knowledge gaps includeunderstanding what parameters need to be measured to assesssystem performance (e.g., the performance of a subsurface barri-er); where, when, and how to obtain these measurements; andhow to relate these measurements to system behavior.
• Unsaturated zone monitoring. Monitoring of the unsaturatedzone is a special case of the previous knowledge gap and is aspecial need for DOE, because most of its containment and sta-bilization systems are being constructed above the water table,especially at the western U.S. sites. Unsaturated zone monitoringis an especially difficult problem; the physics and chemistry of
S U B S U R F A C E S C I E N C E
110Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
unsaturated zone processes are more complicated than for thesaturated zone, and these processes have received far less atten-tion from researchers. Contaminants may be present in bothliquid and gas phases in unsaturated zone environments andunder both aerobic and anaerobic conditions. The exchange,degree of equilibration of these phases, and the transport ofthese phases may occur by different processes with very differentrates. There is a great disparity between what can currently bemeasured and what needs to be measured to predict the behav-ior of contaminants in many unsaturated settings.
• Model validation. A conceptual model is an estimate of the real-world behavior and must be tested to ensure that it appropriatelyrepresents the behaviors of interest. This testing is usually carriedout by comparing predictions made with the model against fieldand experimental observations. This testing also allows themodel to be improved as new information on the subsurface sys-tem is collected. The science of model testing, or validation, hasreceived relatively little attention until recently and is an areawhere significant work is needed. The knowledge gaps includeunderstanding what measurements need to be collected to vali-date a model (it is frequently the case that what can be calculat-ed in a model cannot be measured in the field, and vice versa);how to evaluate the relationships between measured and pre-dicted behaviors; and understanding what diagnostic informationthese differences provide for assessing and improving the accura-cy of the models (e.g., see Sidebar 5.2).
• Performance validation. Performance validation is a necessarystep to document the success, or lack thereof, with every stepshown in Figure 5.1. The issues here are similar to those formodel validation, that is, how to assess whether the process isperforming as designed. The knowledge gaps include under-standing what to measure, how to measure it, how to assess dis-crepancies between designed and measured behavior, and deter-mining what diagnostic information these differences provide forassessing and improving performance.
For example, with regard to locating and characterizing con-taminants, one must determine when enough information for riskcharacterization and remedy selection has been gathered. Thisrequires tools to validate the assessments of contaminantamounts, distributions, and mass release rates. Similar considera-tions arise for validation of predictive models in the face of vari-ability and uncertainty. The difficulty increases when probabilitymodels are introduced to try to deal with uncertainty. With
C h a p t e r 5
111Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
regard to corrective action performance, validation is an essen-tial step that is lacking for many innovative technologies, andhas prevented their selection for site remediation because of reg-ulatory and stakeholder concerns. Knowledge gaps in perfor-mance validation include understanding how to develop moni-toring systems and sampling strategies, understanding the criticalsystem variables that need to be used, strategies for data collec-tion in highly heterogeneous systems, and the development ofstatistical methods to be used in performance evaluation.
Research NeedsMany of the research needs for monitoring and validation have
been covered in previous sections; for example, research on locatingcontaminants and characterizing contaminant and subsurface propertiesand research on data integration will provide new knowledge andcapabilities for monitoring and validation. In addition, the committeebelieves that basic research is needed on the following topics:
• Development of methods for designing monitoring systems todetect both the current conditions and changes in system behav-iors. These methods may involve the application of conceptual,mathematical, and statistical models to determine the types andlocations of observation systems and also will involve predictingthe spatial and temporal resolutions at which observations needto be made. For example, such methods may help to determinewhat types of measurements (e.g., core samples from a boreholeversus seismic images of the subsurface) can be used to validatethe model and also suggest where such measurements should bemade in both time and space.
• Development of validation processes. The research questionsinclude (1) understanding what a representation of systembehavior means and how to judge when a model provides anaccurate representation of a system behavior—the model maygive the right answers for the wrong reasons and thus may notbe a good predictive tool; and (2) how to validate the future per-formance of the model or system behavior based on present-daymeasurements. These questions might be addressed throughresearch projects that focus on the development of validationmethodologies using real-world examples at DOE sites.
• Data for model validation. Determining the key measurementsthat are required to validate models and system behaviors, thespatial and temporal resolutions at which such measurementsmust be obtained, and the extent to which surrogate data (e.g.,
S U B S U R F A C E S C I E N C E
112Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
data from lab-scale testing facilities) can be used in validationefforts.
• Research to support the development of methods to monitor fluidand gaseous fluxes through the unsaturated zone, and for differ-entiating diurnal and seasonal changes from longer-term secularchanges. These methods may involve both direct (e.g., in situsensors) and indirect (e.g., using plants and animals) measure-ments over long time periods, particularly for harsh chemicalenvironments characteristic of some DOE sites. This researchshould support the development of both the physical instrumen-
C h a p t e r 5
113
SIDEBAR 5.2 MANAGING UNCERTAINTY
Management of uncertainty in model and performance validation is a theme that cuts across many of
the knowledge gaps identified in this chapter. Uncertainties arise in multiple ways. In field data they
can emerge in quality features: random measurement error, systematic errors from imperfectly cali-
brated instruments, and recording and other transmission errors. In mathematical models, uncertain-
ties stem from incorrect specifications and through propagation of errors in the data that are input to
the computational models. In the integration (or combination) of models and data, uncertainties are
affected by the need to link data and models that are on mismatched scales; some data may have to be
aggregated, other data may need to be disaggregated.
Quantifying the uncertainties in, for example, a site characterization problem can involve all the paths
described above. There may be several data sets of varying quality; missing data (measurements on
some contaminants may be found at some monitoring wells but missing at others); auxiliary data sets
(e.g., river flow data) on time scales very different from the frequency of sampled monitoring data; his-
torical records of differing content and quality; and transport models requiring uncertain input para-
meters. How best to combine the variety of information and assess the accuracy of results and predic-
tions is a great challenge.
Similar issues are found in validation and performance assessment. These may be compounded by the
need to perform detailed computer experiments to determine the impacts of uncertainties in data
quality and input specifications. For perfomance assessment and validation, attention has to be given
to design of future data collection: Where and when should collection be done to assure a desired level
of accuracy?
The daunting technical problem is how to respond to complex, though simple sounding, queries (e.g.,
Where is the contaminant plume now? Where will it be next year?) that demand intricate combinations
of computer and statistical models fed by several data sources. Powerful methods such as Bayesian
hierarchical modeling are emerging to break such complicated problems into components and,
through intensive computation, capture the uncertainties; but implementation is limited by the com-
plexity and scale of the problems typically encountered in subsurface contamination.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
tation and measurement techniques. The latter includes measure-ment strategies and data analysis (including statistical) approach-es.
Discuss ionAs noted in the introduction to this chapter, the committee has been
selective in the identification of subsurface contamination knowledgegaps and research needs for the EM Science Program. Indeed, the list ofknowledge gaps presented in this chapter is not exhaustive and is per-haps notable for what it does not include, namely, the knowledge gapsassociated with assessment of risk (Box 5 in Figure 5.1)10 and many ofthe corrective actions associated with EM’s cleanup program (Boxes 6Cthrough 6E in Figure 5.1). The committee has been selective because (1) it believes that much of the subsurface at DOE sites cannot be reme-diated cost effectively; (2) the contamination is highly distributed invery large volumes of the subsurface; and (3) the EM Science Programdoes not have the management or financial capital to support a com-prehensive research program to address all of EM’s cleanup problems.Further, the committee recognizes that there is much good research onthese excluded topics being supported by other programs (see Chapter 4).
The committee has selected the four research areas highlighted inthis chapter because, as illustrated by the examples in Chapter 2, thesethemes cut across all DOE cleanup efforts, and the committee believesthat they are key to the long-term success of the DOE’s cleanup pro-gram. Further, the committee believes that a focused, sustained, andadequately funded research program directed at the knowledge gapscould result both in significant improvements to DOE cleanup capabili-ties and the effectiveness of its cleanup actions.
The committee discussed whether it should prioritize these fourresearch areas, but decided against doing so. The selection of thesefour research foci from among a much broader range of potentialresearch areas is in itself a significant prioritization. Further, the com-mittee believes that all four research foci are equally important forDOE’s cleanup mission and will need to be pursued aggressively ifDOE is to improve its capabilities to address its subsurface contamina-tion problems. The new location, characterization, modeling, and mon-itoring capabilities that can result from this research, when applied
S U B S U R F A C E S C I E N C E
114
10Of course, the committee recognizes that the basic research needs outlinedin this chapter will produce new knowledge on contaminant locations and behaviorand thereby affect critical steps in the risk assessment.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
6
Recommendations for a Long-Term Research Program
This chapter provides recommendations for a long-term basicresearch program to address subsurface contamination problems atDOE sites, as directed by the statement of task (see Sidebar 1.1). Therecommendations address the following three issues:
1. program vision,2. research agenda, and3. implementation of the research agenda.
These recommendations are based on analyses of the informationprovided in Chapters 2 through 5 of this report and the committee’sinterim report (NRC, 1998), as well as the reports of the previousNational Research Council Committee on the Environmental Manage-ment (EM) Science Program (NRC, 1997b).
Program Vis ionThe EM Science Program has been in existence for almost four
years, but there does not appear to be a clear and agreed-upon pro-gram vision in DOE, and especially in upper management in the Officeof Environmental Management (EM). This conclusion is based on twoobservations made by the committee during the course of this study.First, the EM Science Program does not appear to be an important partof EM’s plan for technology research and development. EM released itsEnvironmental Management Research and Development Plan in 1998(DOE, 1998f). This plan describes the investments to be made in sci-ence and technology to support the DOE cleanup mission. The main
C h a p t e r 6
115Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
text of this plan is 36 pages in length, but only one section comprisingtwo paragraphs is devoted to a discussion of the EM Science Program.The discussion in this plan focuses primarily on the management of theprogram rather than the program’s objectives and content.
Second, the program also does not appear to be a high priority,judging by EM’s budget requests to Congress. When the program wascreated in fiscal year 1996, Congress appropriated $50 million to itfrom EM’s technology development programs.1 In fiscal year 1997, EMrequested $38 million for the program; however, Congress appropriated$50 million, an increase of $12 million over EM’s request. In fiscal year1998, $32 million was requested; Congress again increased its appro-priation to $47 million. For fiscal year 1999, $32 million was requestedand appropriated.2 Congress and EM appear to have different views ofthe importance of this program. In the committee’s view, $50 million isinadequate for a research program that has the scope of the EM ScienceProgram. This is especially true since the program was designed toaddress a wide spectrum of problems, ranging from groundwater conta-mination to high-level waste. Additional discussions of program fundingare provided later in this chapter.
The committee believes that if the program is to remain viable overthe long term and have a significant impact on the DOE cleanup mis-sion, program managers must articulate a vision for the program that issupported both programmatically and financially by upper managementin EM and DOE. In the committee’s view, this vision should include thefollowing four elements:
1. The objective of the EM Science Program should be to generatenew knowledge to support DOE’s mission to clean up its conta-minated sites. This objective is consistent with the intent of thecongressional language that established this program in 1996(see Chapter 1), with the conclusions in this committee’s interimreport (NRC, 1998), and with the conclusions of the previousNRC committee on the EM Science Program (NRC, 1997b). Thisobjective also has been articulated in EM’s strategic plan for itsscience and technology programs (DOE, 1998f). The commit-tee’s analysis of subsurface contamination problems in Chapter 2shows that the environmental remediation and management mis-sion is unlikely to succeed without new knowledge to supportthe development of new and improved technologies to treat,
S U B S U R F A C E S C I E N C E
116
1Specifically, from the Office of Science and Technology.2About $10 million of the appropriation was for research on low-dose ionizing
radiation.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
remove, or contain and stabilize subsurface contamination atDOE sites.
2. The EM Science Program should be well connected to DOE’sdifficult cleanup problems. In the past, the program was operat-ed somewhat like a first generation research and developmentprogram, which has been characterized (perhaps with tongue incheek) as “put a few bright people in a dark room, pour inmoney, and hope” (Hamel and Prahalad, 1989; see also Rousseland others, 1991). Clearly, this model is inappropriate for theprogram, which will succeed only if it is well connected, both inperception and fact, to EM’s significant cleanup problems. Theefforts by the program managers to develop science plans repre-sents a positive move in this direction. The committee hopes therecommendations for basic research foci presented in this reportwill aid this effort.
3. A major focus of the EM Science Program should continue to beon research to resolve DOE’s subsurface contamination prob-lems. Based on its review of subsurface contamination problemsin Chapter 2, the committee concluded that DOE faces signifi-cant difficulties in remediating radionuclide-, metal-, and sol-vent-contaminated soil and groundwater at all of its major sites.DOE’s own analyses and publications (see Chapter 2) also sup-port the conclusion that subsurface contamination is a significantlong-term problem. Moreover, previous National ResearchCouncil reports have shown that DOE lacks the technologiesneeded to effectively remediate much of the subsurface contami-nation at its sites (e.g., NRC, 1997a,c, 1999). The committeebelieves, therefore, that new knowledge (and technologies) willbe required to address DOE’s subsurface contamination prob-lems, and the committee recommends that subsurface contami-nation should continue to be a major focus of the EM ScienceProgram.
4. The EM Science Program should have a long-term, multidiscipli-nary, basic-research3 focus. As discussed in Chapter 2, the activephase of DOE’s cleanup efforts is planned to last until at least2050 (see Table 2.3), and DOE faces additional long-term moni-toring commitments beyond 2070. Consequently, DOE has suffi-cient time to undertake and to benefit from long-term basicresearch under the auspices of the EM Science Program.
117
C h a p t e r 6
3As noted in Sidebar 1.1, basic research creates new generic knowledge and isfocused on long-term, rather than short-term, problems.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A long-term basic research focus will allow the EM Science Programto sponsor fundamental research on subsurface contamination that canlead to significant knowledge and technology breakthroughs.4 It alsowill insulate the program from the ongoing shifts in emphasis in theDOE cleanup effort. Indeed, a long-term focus will enable the programto provide sustained funding, including renewals in funding for success-ful projects, so that investigators can pursue and build on significantresearch results.
The committee defines “long term” as long enough to set ambitiousgoals for addressing the knowledge gaps identified in Chapter 5 and tohave reasonable expectations that those goals can be attained. In thecommittee’s judgment, a time horizon on the order of a decade will berequired to make cumulative progress on the knowledge gaps, althoughshorter-term results of use to DOE almost certainly will be obtainedover the lifetimes of individual research projects (i.e., over a three-yeartime frame). A decadal time horizon would produce a critical mass ofresearchers and research projects focused on the knowledge gaps; itwould provide for several proposal cycles so that investigators couldpursue important research ideas and develop significant researchresults. With the proper encouragement from program managers, itwould also encourage researchers to develop collaborations that couldlead to novel approaches to addressing the knowledge gaps, many ofwhich are highly interdisciplinary.5
The decadal time horizon would allow investigators to apply forcompetitive renewals to pursue significant research findings. Suchrenewals could accelerate progress in addressing the knowledge gaps,keep good researchers focused on problems of importance to DOE,and, in the case of university-funded projects, provide a strategic invest-ment in future generations of researchers knowledgeable of DOE’s prob-lems through support for graduate students and postdoctoral scientists.
Research AgendaThe committee has identified four critical knowledge gaps that it
believes are significant impediments to the successful completion ofDOE’s cleanup mission and that are addressable through a focused,sustained, and adequately funded research program. Although these
S U B S U R F A C E S C I E N C E
118
4A good discussion of the value of long-term research is provided in a previousNRC report (NRC, 1997b), especially in Chapter 2.
5The value of multidiscipinary research is discussed in some detail in a previousNRC report (NRC, 1997b).
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
may not be the only critical knowledge gaps in DOE’s evolving subsur-face cleanup program, the committee is certain that these four chal-lenges must be addressed for DOE’s cleanup program to be completedsafely and cost effectively.
The committee recommends that the subsurface component of theEM Science Program should emphasize research on the four knowledgegaps that were identified in Chapter 5 and discussed below. The specif-ic research topics suggested in this section are for illustrative purposesand are not meant to be prescriptive. The committee expects that theresearch supported by this program will be truly basic, imaginative, andinnovative. The committee’s recommendation of four research foci doesnot imply that the subsurface research supported in the current EMScience Program portfolio is inappropriate or misdirected. Rather, thesefour foci represent areas where more research clearly is needed.
Location and Characterization of SubsurfaceContaminants and Characterization of the SubsurfaceThe challenges of locating subsurface contamination are magnified
by the wide range of contaminant types (e.g., mixtures of organic sol-vents, metals, and radionuclides) in the subsurface at many DOE sites;the wide variety of geological and hydrological conditions across theDOE complex; and the wide range of spatial resolutions at which thiscontamination must be located and characterized, from widely dis-persed contamination in groundwater plumes to small isolated hotspots in waste burial grounds.
As discussed in Chapter 5, the committee believes that basicresearch is needed to support the development of the following capa-bilities to locate and characterize contamination in the subsurface andto characterize subsurface properties at the scales that control contami-nant fate and transport behavior:
• Improved capabilities for characterizing the physical, chemical,and biological properties of the subsurface.
• Improved capabilities for characterizing physical, chemical, andbiological heterogeneity, especially at the scales that controlcontaminant fate and transport behavior. Approaches that allowthe identification and measurement of the heterogeneity featuresthat control contaminant fate and transport to be obtained direct-ly (i.e., without having to perform a detailed characterization ofthe subsurface) are especially needed.
• Improved capabilities for measuring contaminant migration andsystem properties that control contaminant movement.
• Methods to integrate data collected at different spatial and tem-
C h a p t e r 6
119Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
poral scales to better estimate contaminant and subsurface prop-erties and processes.
• Methods to integrate such data into conceptual models.
Conceptual ModelingExisting conceptual and predictive models have often proven inef-
fective for understanding and predicting contaminant movement, espe-cially at sites that have thick unsaturated zones or complex subsurfacecharacteristics. Accurate conceptualizations are essential for under-standing the long-term fate of contaminants in the subsurface and theselection and application of appropriate corrective actions. The com-mittee believes that basic research explicitly focused on fundamentalapproaches and assumptions underlying conceptual model develop-ment could produce a tool box of methodologies that are applicable tocontaminated sites both inside and outside the DOE complex. Thisresearch should focus on the following topics:
• New observational and experimental approaches and tools fordeveloping conceptual models that apply to complex subsurfaceenvironments, including such phenomena as colloidal transportand biologic activity.
• New approaches for incorporating geological, hydrological,chemical, and biological subsurface heterogeneity into concep-tual model formulations at scales that dominate flow and trans-port behavior.
• Development of coupled-process models through experimentalstudies at variable scales and complexities that account for theinteracting physical, chemical, and biological processes thatgovern contaminant fate and transport behavior.
• Methods to integrate process knowledge from small-scale testsand observations into model formulations, including methods forincorporating qualitative geological information from surface andnear-surface observations into conceptual model formulations.
• Methods to measure and predict the scale dependency of para-meter values.
• Approaches for establishing bounds on the accuracy of parame-ters and conceptual model estimates from field and experimentaldata.
The research needs outlined above call for more hypothesis-drivenexperimental approaches that address how to integrate the understand-ing of system behavior. This research will require expertise from a widerange of disciplines and must be conducted at scales ranging from thelaboratory bench top to contaminated field sites. Moreover, to have
S U B S U R F A C E S C I E N C E
120Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
long-term relevance to the DOE cleanup mission, this research must befocused on the kinds of subsurface environments and contaminationproblems commonly encountered at major DOE sites.
Containment and StabilizationThere has been an increasing emphasis on and acceptance of waste
containment and stabilization in recent years, both in DOE and by reg-ulatory agencies. Decreasing cleanup budgets, evaluations that showcontainment is a low-risk choice for some problems, and recognitionthat some contamination cannot be remediated either with currenttechnologies or conceivable new technologies are responsible for thischange in philosophy. However, at some sites, containment and stabi-lization may be an interim measure and has its own set of associatedtechnical problems. There is little understanding of the long-term per-formance of containment and stabilization systems, and there is a gen-eral absence of robust and cost-effective methods to validate that suchsystems are installed properly or that they can provide effective long-term protection.
The construction of stabilization and containment systems is proper-ly within the province of applied technology development. However,basic research focused on the following topics will be needed to sup-port this technology development effort:
• The mechanisms and kinetics of chemically and biologicallymediated reactions that can be applied to new stabilization andcontainment approaches (e.g., reactions that can extend the useof reactive barriers to a greater range of contaminant types foundat DOE sites) or that can be used to understand the long-termreversibility of chemical and biological stabilization methods.
• The physical, chemical, and biological reactions that occuramong contaminants (metals, radionuclides, and organics), soils,and barrier components so that more compatible and durablematerials for containment and stabilization systems can bedeveloped.
• The fluid transport behavior in conventional barrier systems, forexample, understanding water infiltration into layered systems,including infiltration under partially saturated conditions andunder the influences of capillary, chemical, electrical, and ther-mal gradients can be used to support the design of more effec-tive infiltration barrier systems.
• The development of methods for assessing the long-term durabil-ity of containment and stabilization systems.
C h a p t e r 6
121Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Monitoring and ValidationMonitoring and validation are necessary at both the front and the
back ends of the site remediation process. At the front end, monitoringand validation are used to support the development of conceptual andpredictive models of subsurface and contaminant behavior. At the backend, monitoring and validation are used to demonstrate the effective-ness of efforts to remove, treat, or especially to contain contaminationand to gain regulatory acceptance for such corrective actions.Moreover, such monitoring and validation efforts can also improve theunderstanding of the contaminant fate and transport processes and canbe used to recalibrate and revise conceptual and predictive models—important elements of the model building process.
The ability to monitor and validate is essential to the successfulapplication of any corrective action to a subsurface contaminationproblem and regulatory acceptance of that action. However, the knowl-edge and technology bases to support these activities are not fullydeveloped and are receiving little attention in EM’s science and tech-nology programs.
Many of the research opportunities for monitoring and validationhave been covered in the research emphases discussed above. In addi-tion, the committee believes that basic research is needed on the fol-lowing topics:
• Development of methods for designing monitoring systems todetect both current conditions and changes in system behaviors.These methods may involve the application of conceptual,mathematical, and statistical models to determine the types andlocations of observation systems and prediction of the spatialand temporal resolutions at which observations need to bemade.
• Development of validation processes. The research questionsinclude (1) understanding what a representation of systembehavior means and how to judge when a model provides anaccurate representation of a system behavior—the model maygive the right answers for the wrong reasons and thus may notbe a good predictive tool; and (2) how to validate the future per-formance of the model or system behavior based on present-daymeasurements.
• Data for model validation. Determining the key measurementsthat are required to validate models and system behaviors, thespatial and temporal resolutions at which such measurementsmust be obtained, and the extent to which surrogate data (e.g.,
S U B S U R F A C E S C I E N C E
122Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
data from lab-scale testing facilities) can be used in validationefforts.
• Research to support the development of methods to monitorfluid and gaseous fluxes through the unsaturated zone, and fordifferentiating diurnal and seasonal changes from longer-termsecular changes. These methods may involve both direct (e.g., in situ sensors) and indirect (e.g., using plants and animals) measurements over long time periods, particularly for harshchemical environments characteristic of some DOE sites. Thisresearch should support the development of both the physicalinstrumentation and measurement techniques. The latterincludes measurement strategies and data analysis (including sta-tistical) approaches.
Other Recommendations on the Research AgendaWithin the four research emphases described above, the committee
recommends that the EM Science Program encourage research on met-als and radionuclides. Many of the metal and radionuclide contamina-tion problems are almost wholly “owned” by DOE, especiallytransuranic contaminants. The committee recognizes that DOE also hasmany dense non-aqueous phase liquid contamination problems at itssites, but as discussed in Chapter 4, there are many research programsin other parts of DOE and in other federal agencies that provide fund-ing for research on this contaminant. The committee judges that this isless true for research on metals and radionuclides.
The committee also recommends that there be sufficient flexibilityin future calls for subsurface proposals so that support can be providedfor high-risk but potentially high-payoff research ideas that intersectwith the four research emphases. Such projects could produce majorknowledge breakthroughs leading to significant improvements in DOE’scleanup capabilities and costs.
Implementat ion of the Research AgendaThe EM Science Program is a basic research program focused on
very real DOE problems. The program’s success will be measured bothby its impact on advancing the science and its impact on DOE sitecleanup. To be successful, the program must not only be focused on theright problems but it must also encourage researchers to do the rightwork; and it must find a way to hand off the results of this work to tech-nology developers and problem holders at DOE sites. In this section the
C h a p t e r 6
123Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
committee offers strategic recommendations for achieving the first twoobjectives;6 these recommendations address the following:
• integration, • field sites, and • program funding.
IntegrationThe committee believes that EM Science Program managers must
encourage and support integration activities across the program if it isto advance subsurface science and have a significant impact on DOEcleanup. To this end, the program’s implementation strategy shouldhave the following three integrative elements:
1. The program should continue to reach beyond the usual groupof DOE researchers to pull in new and novel ideas to addressDOE-specific problems. Much of the expertise needed to addressthe knowledge gaps identified in Chapter 5 can be found outsidethe traditional DOE research community. Indeed, the previousNRC committee on the EM Science Program encouraged pro-gram managers to broaden the community of investigatorsinvolved in the program and to expand the core or committedcadre of investigators who are knowledgeable of EM’s problems(NRC, 1997b, p. 4). Judging from the committee’s review of thecurrent program portfolio in Chapter 3, the program appears tobe making progress in meeting this objective. The committeeencourages program managers to continue their efforts to broad-en the community of researchers from government agencies withresearch capabilities, national laboratories, universities, andindustry.
2. The program should continue to encourage multidisciplinaryresearch and university-national laboratory-industry collabora-tions that will promote new insights into the very complex sub-surface problems at DOE sites. Many of the challenges identifiedin Chapter 5 are technically difficult and inherently interdiscipli-nary. The committee believes that to make significant progress inaddressing them, the program must encourage and support mul-tidisciplinary research teams. There is a good representation ofmultiple-investigator projects in the current program portfolio(see Table 3.1), especially collaborations among university and
S U B S U R F A C E S C I E N C E
124
6The third objective on moving science into application, although extremelyimportant, is beyond the statement of task for the present study.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
national laboratory scientists. The committee recommends thatprogram managers continue to encourage such collaborations byproviding support for workshops and seminars to bring scientiststogether with site problem holders to discuss DOE contamina-tion problems and possible research approaches; this was rec-ommended by the previous NRC committee on the EM ScienceProgram (NRC, 1997b). The committee offers an additional rec-ommendation to encourage collaborations in the next section ofthis chapter.
3. The program should integrate existing data and ideas—both fromDOE sites and basic research programs outside DOE—to pro-mote advancements in subsurface science and improvements incapabilities to address DOE’s subsurface contamination prob-lems. The program can also play a lead role in integrating theconsiderable amount of relevant subsurface science research thatis being supported by DOE and other federal agencies. As dis-cussed in Chapter 4, there is a great deal of potentially relevantsubsurface research that is being supported outside the EMScience Program, but the committee found that there is little orno effort being made to coordinate these research investments orto transfer results into the DOE cleanup program.
The program has the potential to provide leadership in theadvancement of subsurface science, primarily because it canprovide access to scientifically interesting and intellectually chal-lenging problems at DOE sites—problems that do not exist any-where else in the United States and few places in the world—and because many DOE sites possess rich caches of data thatcan be used in research projects to address the knowledge gapsidentified earlier in this chapter. Groundwater monitoring datafrom sites like Hanford, for example, could be used to developforensic methods to estimate contaminant release rates or todevelop and test conceptual models (see Chapter 2). However,to be useful in this regard, researchers must have access to DOEdata, sites, and site-knowledgeable personnel.
Field SitesThe committee recommends that program managers examine the
feasibility of developing field research sites where investigators withprogram awards could work on the knowledge gaps described earlier inthis chapter. These field sites could include contaminated or uncontam-inated areas at the major DOE sites; analog uncontaminated sites thathave subsurface characteristics similar to contaminated DOE sites; andeven virtual sites comprised of data on historical and contemporary
C h a p t e r 6
125Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
contamination problems. These sites could be established by the pro-gram itself or in cooperation with other research programs.7
Access to field research sites could allow investigators to make sig-nificant progress in addressing the four knowledge gaps identified pre-viously in this chapter. For example, research on location and charac-terization will require access to field sites where measurements on realsubsurface and contaminant properties can be made and where mea-surement methodologies can be compared. Research on conceptualmodel development and testing and on validation and monitoring areinherently field based. Researchers must have hands-on familiarity thatcomes from working in the field to develop and test new methodolo-gies and approaches. Research on containment and stabilization willrequire access to field sites to test ideas developed in the laboratory ormodeling studies, for example, to measure in situ rates of chemicalreactions that could be used to develop new and improved contain-ment and treatment approaches.
The establishment of field research sites could have several tangiblebenefits to the program. First, program managers could encourageresearch on specific knowledge gaps by establishing field sites in cer-tain kinds of contaminated environments. For example, program man-agers could encourage research on unsaturated zone contamination byestablishing an unsaturated zone field site at one of the major DOEinstallations in the western United States. Second, such sites couldattract new researchers to the program, especially if the field sites couldprovide research opportunities unavailable through other programs.Third, field sites could encourage both formal and informal multidisci-plinary collaborations among the researchers working at these sites,thereby providing benefits that are greater than the sum of individualprojects. Such collaborations could be enhanced if the program identi-fied a site manager who could coordinate the research activities at thesite and encourage researchers with common interests to work together.Finally, the establishment of field research sites could facilitate thetransfer of research results into application because of site proximity tothe problem holders and the problems themselves.
The establishment of field research sites is potentially expensive,especially if the field sites are located in contaminated areas wheredrilling, sample collection, and sample handling would be costly andwhere investigators would be required to follow DOE environmental
S U B S U R F A C E S C I E N C E
126
7For example, the Natural and Accelerated Bioremediation Research program(see Chapter 4) plans to establish a field research site at a major DOE site in fiscalyear 2000 and may be an appropriate test bed for research sponsored by the EMScience Program.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
health and safety procedures.8 Moreover, the program may have to payfor the services of a site manager and may have to develop proceduresand provide funding to ensure that site data are properly archived anddisseminated to researchers and cleanup personnel. Consequently, theestablishment of such sites would require additional budget supportbeyond that required to fund individual research projects, and wellbeyond the amount of funding available to the program for new startsin fiscal year 1999. Indeed, support for field research sites could con-sume a significant fraction of the program budget for new starts. How-ever, field research is just one component in a well-balanced researchprogram and should not be supported at the expense of projects thatinvolve laboratory and modeling approaches. Consequently, additionalfunding would have to be made available to the program to support thedevelopment of field sites, or funding for the sites would have to comefrom other parts of EM (e.g., the Office of Site Closure or the Office ofProject Completion, which have the primary responsibility for cleanupof contaminated soil and groundwater). The use of such sites wouldhave to be evaluated periodically to determine whether they are addingvalue to the research effort, particularly given the cost of such sites rela-tive to the total size of the program budget.
Program FundingThe issue of funding for the EM Science Program has received a
great deal of attention from a previous NRC committee (NRC, 1997b),which concluded that the “program must be large enough to support asignificant number of ‘new starts’ (i.e., new projects or competitiverenewals) each year if it is to be successful in attracting innovative pro-posals from outstanding researchers ….” The program needs to have asignificant number of new starts each year to keep potential investiga-tors engaged and willing to invest the time and intellectual energy tobecome knowledgeable of DOE problems and develop research ideasto address them.
New starts will help establish a cadre of knowledgeable and com-mitted investigators—undergraduates, graduates, postdocs, and profes-sionals—who can be called on by DOE in the years ahead for helpwith its most difficult contamination problems. New starts are alsoneeded to maintain continuity in the research effort; the advancementof scientific knowledge is a cumulative effort involving many scientists
C h a p t e r 6
127
8Field research at a contaminated site would need to be carefully reviewed bymanagers familiar with the research activity and the nature of hazards at the site toensure that health and safety requirements are met and that the research activitydoes not exacerbate the spread of contamination.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
over long periods of time. This effort is set back significantly each timeprogram funding is interrupted. Researchers may become frustrated andmove on to other projects, and graduate students and postdocs mayseek training in other fields. Even a single year’s interruption in programsupport can have negative effects that last for several years.
Small program budgets can also lead to significant investigator frus-tration, especially when proposal success rates fall below acceptednorms and highly rated proposals are declined. When proposal successrates fall to low levels, talented investigators may view the proposalpreparation and submission process as a bad investment of their timeand may stop submitting proposals. This will have an immediate nega-tive impact on the quality of the research being sponsored and long-term negative impact on the DOE technology development efforts.
It is the committee’s strong impression that the current level of pro-gram funding is not sufficient to support the research emphases out-lined in this report, especially when subsurface research is just one ofmany research areas supported by the program. However, the commit-tee has no basis on which to recommend a specific funding level, andsuch a recommendation would be well beyond the committee’s state-ment of task. The committee believes that it is the responsibility of EMScience Program managers to estimate the amount of funding requiredto provide adequate support for a research program focused onaddressing the knowledge gaps presented in Chapter 5. One approachfor estimating the annual research budget is to estimate the number ofprojects needed to attain a critical mass of research on each technicalchallenge area, and then to multiply that number by the average annualgrant size.
The committee believes that such estimates could be used to justifyfuture, and possibly larger, budget requests to upper DOE managementand Congress, especially if the estimates were reviewed and validatedby DOE’s internal advisory committees like the EnvironmentalManagement Advisory Board or other external advisory committees.Future and larger budget requests are likely to be seen in an increasing-ly more favorable light as the EM Science Program becomes more firm-ly connected to EM’s cleanup problems.
Concluding Obser vat ionsThe basic research supported by the EM Science Program and other
relevant research programs in the federal government will have little ifany impact on DOE cleanup unless research results are transferred intotechnology development programs in EM and to problem holders at
S U B S U R F A C E S C I E N C E
128Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
DOE sites. EM Science Program managers have a responsibility toensure that specific procedures are in place to foster the handoff fromresearch to development, both for research results developed in its pro-grams and from other relevant programs in the federal government.
The committee believes that there must be strong scientific, techni-cal, and management leadership at all levels of EM, from the EMScience Program up to and including the assistant secretary for environ-mental management, if significant progress on closing the knowledgegaps and applying results effectively to the cleanup effort is to be madein the next decade. The development of such leadership remains a con-tinuing challenge—and a significant opportunity—for the EM ScienceProgram and DOE.
C h a p t e r 6
129Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
130Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
References
Agnew, S.F., J. Boyer, R.A. Corbin, T.B. Duran, J.R. Fitzpatrick, K.A.Jurgensen, T.P. Ortiz, and B.L. Young. 1997. Hanford Tank Chemicaland Radionuclide Inventories: HDW Model, Rev. 4. Report LA-UR-96-3860. Los Alamos National Laboratory, New Mexico.
Albright, J.N., and D.S. Dreesen. 2000. Microhole technology lowersreservoir exploration, characterization costs. Oil and Gas Journal(January 10):39-41.
DOE (Department of Energy). 1995. Closing the Circle on the Splittingof the Atom: The Environmental Legacy of Nuclear WeaponsProduction in the United States and What the Department of EnergyIs Doing About It. DOE/EM-0266. Washington, D.C.: Office ofEnvironmental Management.
DOE. 1996. The 1996 Baseline Environmental Management Report (2volumes). DOE/EM-0290. Washington, D.C.: Office ofEnvironmental Management.
DOE. 1997a. Linking Legacies: Connecting the Cold War NuclearWeapons Production Processes to Their EnvironmentalConsequences. DOE/EM-0319. Washington, D.C.: Office ofEnvironmental Management.
DOE. 1997b. Subsurface Contaminants Focus Area 1997 AnnualReport. DOE/EM-0361. Washington, D.C.: Office of EnvironmentalManagement.
DOE. 1998a. Accelerating Cleanup: Paths to Closure. DOE/EM-0362.Washington, D.C.: Office of Environmental Management.
DOE. 1998b. Groundwater/Vadose Zone Integration ProjectSpecification. DOE/RL-98-48. Draft C. December 17. Richland,Washington: Department of Energy.
DOE. 1998c. Environmental Management Science Program Workshop.CONF-980736. Washington, D.C.: Office of EnvironmentalManagement.
R e f e r e n c e s
131Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
DOE. 1998d. Subsurface Contaminants Focus Area 1998 AnnualReport. Washington, D.C.: Office of Environmental Management.
DOE. 1998e. The Current and Planned Low-Level Waste DisposalCapacity Report, Revision 1. Washington, D.C.: Office ofEnvironmental Management.
DOE. 1998f. Environmental Management Research and DevelopmentPlan: Solution-Based Investments in Science and Technology.Washington, D.C.: Office of Environmental Management.
DOE. 1998g. Report to Congress on the U.S. Department of Energy’sEnvironmental Management Science Program: Research Funded andIts Linkages to Environmental Cleanup Problems (3 volumes).DOE/EM-0357. Washington, D.C.: Office of EnvironmentalManagement.
DOE. 1999. From Cleanup to Stewardship. DOE/EM-0466.Washington, D.C.: Office of Environmental Management.
EPA (Environmental Protection Agency). 1977. Cleaning Up theNation’s Waste Sites: Markets and Technology Trends. EPA 542-R-96-005. Washington, D.C.: Office of Solid Waste and EmergencyResponse.
Gephart, R.E., and R.E. Lundgren. 1998. Hanford Tank Clean Up: AGuide to Understanding the Technical Issues. Richland,Washington: Battelle Press.
Hamel, G., and C.K. Prahalad. 1989. Strategy and Intent. HarvardBusiness Review (May-June): 63.
Hunt, J.R., N. Sitar, and K.S. Udell. 1986a. Nonaqueous phase liquidtransport and cleanup: I. analysis of mechanisms. Water ResourcesResearch 24(8): 1247-1258.
Hunt, J.R., N. Sitar, and K.S. Udell. 1986b. Nonaqueous phase liquidtransport and cleanup: II. experimental studies. Water ResourcesResearch 24(8): 1259-1269.
Illangasekare, T.H., J.L. Ramsey, K.S. Jensen, and M.B. Butts. 1995.Experimental study of movement and distribution of dense organiccontaminants in heterogenous aquifers. Journal of ContaminantHydrology 20: 1-25.
INEEL (Idaho National Engineering and Environmental Laboratory).1997. Decision Analysis for Remediation Technologies (DART) DataBase and User’s Manual. INEEL/EXT-97-01052, Idaho Falls, Idaho:INEEL.
Karsting, A. B., D.W. Efurd, D.L. Finnegan, D.J. Rokop, D.K. Smith, andJ.L. Thompson. 1999. Migration of plutonium in ground water at theNevada Test Site. Nature 397: 56-59.
Kueper, B.H., and E.O. Frind. 1991. Two-phase flow in heterogeneousporous media 1. model development. Water Resources Research27(6): 1049-1057.
S U B S U R F A C E S C I E N C E
132Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
NRC (National Research Council). 1966. Committee on GeologicalAspects of Radioactive Waste Disposal: Report to the U.S. AtomicEnergy Commission. Washington, D.C.: National Academy Press.
NRC. 1994. Alternatives for Ground Water Cleanup. Washington, D.C.:National Academy Press.
NRC. 1995. Allocating Federal Funds for Science and Technology.Washington, D.C.: National Academy Press.
NRC. 1996a. Building an Effective Environmental Management ScienceProgram: Initial Assessment. Washington, D.C.: National AcademyPress.
NRC. 1996b. Letter Report on the Environmental Management ScienceProgram Dated October 6. Washington, D.C.: Board on RadioactiveWaste Management, National Research Council.
NRC. 1997a. Innovations in Ground Water and Soil Cleanup: FromConcept to Commercialization. Washington, D.C.: NationalAcademy Press.
NRC. 1997b. Building an Effective Environmental Management ScienceProgram: Final Assessment. Washington, D.C.: National AcademyPress.
NRC. 1997c. Improving the Environment: An Evaluation of DOE’sEnvironmental Management Program. Washington, D.C.: NationalAcademy Press.
NRC. 1998. Letter Report on the Environmental Management ScienceProgram Dated December 10. Washington, D.C.: Board onRadioactive Waste Management, National Research Council.
NRC. 1999. Ground Water and Soil Cleanup: Improving Managementof Persistent Contaminants. Washington, D.C.: National AcademyPress.
Olsen, C.R., I.L. Larsen, P.D. Lowry, C.R. Moriones, C.J. Ford, K.C.Dearstone, R.R. Turner, B.L. Kimmel, and C.C. Brandt. 1992.Transport and accumulation of cesium-137 and mercury in theClinch River and Watts Bar Reservoir System. ORNL/ER-7. OakRidge, Tennessee: Oak Ridge National Laboratory.
Pfannkuch, H.O. 1984. Determination of the contaminant sourcestrength from mass exchange processes at the petroleum ground-water interface in shallow aquifer systems. In Proceedings of theNWWA Conference on Petroleum Hydrocarbons and OrganicChemicals in Groundwater, pp. 111-129. Dublin, Ohio: NationalWell Water Association.
Pielke, R.A., and R. Byerly. 1998. Beyond basic and applied. PhysicsToday (February): 42-46.
Reidel, S.P., K.A. Lindsey, and K.R. Fecht. 1992. Field Trip Guide to theHanford Site. WHC-MR-0391. Richland, Washington: WestinghouseHanford Co.
R e f e r e n c e s
133Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Riley R.G., and J.M. Zachara. 1992. Chemical Contaminants on DOELands and Selection of Contaminated Mixtures for SubsurfaceScience Research. DOE/ER-0547T. Washington, D.C.: Office ofEnergy Research.
Roussel, P.A., K.N. Saad, and T.J. Erickson. 1991. Third GenerationR&D: Managing the Link to Corporate Strategy. Boston,Massachusetts: Harvard Business School Press.
Sandia National Laboratories. 1996. Performance Evaluation of theTechnical Capabilities of DOE Sites for Disposal of Mixed Low-LevelWaste. Albuquerque, New Mexico: Sandia National Laboratories.
Schwille, F. 1988. Dense Chlorinated Solvents in Porous and FracturedMedia. (Translated by J. F. Pankow). Chelsea, Michigan: LewisPublishers.
Thorpe, R.K., W.F. Isherwood, M.D. Dresen, and C.P. Webster-Sholten(eds.). 1990. CERCLA Remedial Investigations Report for the LLNLLivermore Site. UCAR-10299. Livermore, California: LawrenceLivermore National Laboratory.
Tompson, A.F.B., R.D. Falgout, S.G. Smith, W.J. Bosl, and S.F. Ashby,1998. Analysis of subsurface contaminant migration and remedia-tion using high performance computing. Advances in WaterResources 23(3): 203-221. (This paper can be viewed in electronicform at http://www.elsevier.nl/locate/advwatres, where a number ofanimated sequences are available to more clearly visualize theeffects of heterogeneity.)
Walker, J.B., and P.J. Liebendorfer. 1998. Long-term stewardship at theNevada Test Site. Paper prepared for the State Tribal GovernmentWorking Group Subcommittee on Stewardship.(http://207.12.87.1/nucwaste/nts/steward.htm#contamination)
Westinghouse Savannah River Company. 1995. A/M Area GroundwaterCleanup. Fact Sheet. Aiken, South Carolina: Savannah RiverOperations Office.
Westinghouse Savannah River Company. 1998. Savannah River SiteBurial Ground Complex. Fact Sheet. Aiken, South Carolina:Savannah River Operations Office.
S U B S U R F A C E S C I E N C E
134Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Appendixes
135
13359 Subsurface Appendixes 2/15/02 2:16 PM Page 135
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
13359 Subsurface Appendixes 2/15/02 2:16 PM Page 136
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A
Description of the Environmental Management Science Program
The Environmental Management (EM) Science Program was initiatedby the 104th Congress to stimulate basic research and technology devel-opment for cleanup of the DOE complex. The program was created inthe conference report that accompanied the Energy and WaterDevelopment Appropriations Bill (Public Law 104-46, 1995):
The conferees agree with the concern expressed by the Senate thatthe Department [of Energy] is not providing sufficient attentionand resources to longer term basic science research which needsto be done to ultimately reduce cleanup costs. The current tech-nology development program continues to favor near-termapplied research efforts while failing to utilize the existing basicresearch infrastructure within the Department and the Office ofEnergy Research. As a result of this, the conferees direct that atleast $50,000,000 of the technology development funding provid-ed to the environmental management program in fiscal year 1996be managed by the Office of Energy Research and used to devel-op a program that takes advantage of laboratory and universityexpertise. This funding is to be used to stimulate the required basicresearch, development and demonstration efforts to seek new andinnovative cleanup methods to replace current conventionalapproaches which are often costly and ineffective.
The EM Science Program is managed jointly by DOE’s Office ofEnvironmental Management and Office of Science.1 Staff from thesetwo offices work together to develop proposal calls, review proposals,
A p p e n d i x A
137
1Formerly the Office of Energy Research. The office was renamed by Congressin 1998.
13359 Subsurface Appendixes 2/15/02 2:16 PM Page 137
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
and make award recommendations. Staff of these two offices have dif-ferent but complementary roles in the proposal solicitation and reviewprocess, as explained below.
The program is run on an annual cycle that begins each fall with thepublication of a program announcement in the Federal Register invitinginvestigators in academia, national laboratories, and industry to submitproposals to the program. The proposal submission process has twosteps. Initially, investigators are invited to submit short descriptions oftheir research ideas, or pre-proposals, for consideration.2 These pre-pro-posals undergo an in-house screening to determine whether they meetthe criteria laid out in the program announcement, namely, whether theproposed project constitutes basic research (as opposed to technologydevelopment, for example) and addresses one or more of the identifiedpriority areas. Investigators whose pre-proposals are judged to meetthese criteria are then encouraged to submit full proposals.
The review of full proposals is carried out in a two-stage process,the first to assess scientific merit and the second to assess programrelevance. This review process is managed jointly by Office of Scienceand Office of Environmental Management staff. Merit review isobtained through peer review panels, composed of scientists fromindustry, national laboratories, and universities, organized along disci-plinary lines consistent with normal Office of Science practices. Thoseproposals that are highly rated in the merit review are then put forwardfor relevance review, which is performed by a panel of program man-agers from DOE head-quarters and field offices who are knowledgeableof EM’s cleanup needs and priorities.
Following these reviews, Office of Science and Office of Environ-mental Management program staff provide an overall rating for each ofthe proposals and make award recommendations to their management.Final award decisions are made by the director of the Office of Scienceand the deputy assistant secretary for science and technology, Office ofEnvironmental Management. Successful proposals are funded for up tothree years, typically at $100,000 to $300,000 per year.
S U B S U R F A C E S C I E N C E
138
2The preapplication process is voluntary.
13359 Subsurface Appendixes 2/15/02 2:16 PM Page 138
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
B
List of Presentations
September 9, 1998Opening Remarks by DOE, Gerald Boyd, DOE-Office of Environmental
Management (EM); Roland Hirsch, DOE-Office of Energy Research(ER)
Overview of the EM Science Program, Mark Gilbertson, DOE-EM;Roland Hirsch, DOE-ER
Overview of the DOE Complex and Subsurface ContaminationProblems, Tom Hicks, Savannah River Site
Overview of the EM Science Program Portfolio Directed at SubsurfaceContamination Problems, Tom Williams, Idaho Engineering andEnvironmental Laboratory
Other R&D Work in EM Focused on Subsurface ContaminationProblems, Tom Hicks, Savannah River Site
November 10, 1998Update on EM Science Program Budget, Mark Gilbertson, DOE-EMSubsurface Contamination Problems at the Savannah River Site, Tom
Temples, DOE-Savannah RiverSubsurface Contamination Problems at the Oak Ridge Site, Gary
Hartman and Paula Kirk, Oak Ridge Site
December 15, 1998Subsurface Contamination Problems at the Nevada Test Site, Robert
Bangerter, DOE-Nevada Operations OfficeSubsurface Contamination Problems at the Idaho Site, Tom Williams,
Tom Wood, Tom Stoops, Bob Smith, Annette Schafer, IdahoEngineering and Environmental Laboratory
Subsurface Contamination Problems at the Hanford Site, Roy Gephart,John Zachara, Pacific Northwest National Laboratory
A p p e n d i x B
139
13359 Subsurface Appendixes 2/15/02 2:17 PM Page 139
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
January 28, 1999Update on EM Science Program, Gerald Boyd, DOE-EM; Mark
Gilbertson, DOE-EM; Roland Hirsch, DOE-Office of Science (SC)EM Science Program Opportunities and Challenges in Subsurface
Research: A View from Environmental Management Advisory Board(EMAB), Frank Parker, Vanderbilt University, EMAB ScienceCommittee Chair
Research Programs in the U.S. Geological Survey (USGS), Mary JoBaedecker, USGS
Research Programs in the U.S. Environmental Protection Agency (EPA),Lee Mulkey, EPA
Research Programs in the U.S. Department of Energy, SkipChamberlain, DOE-EM and John Houghton, DOE-SC
Research Programs in the U.S. Department of Defense, Bradley Smith,Strategic Environmental Research and Development Program
May 6, 1999Update on the EM Science Program and Desired Outcomes of the
Committee’s Work, Mark Gilbertson, DOE-EM
S U B S U R F A C E S C I E N C E
140
13359 Subsurface Appendixes 2/15/02 2:17 PM Page 140
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A p p e n d i x C
141
C
Biographical Sketches of Committee Members
JANE C.S. LONG (Chair) is dean of the Mackay School of Mines atthe University of Nevada, Reno. She is an expert in fracture hydrologyand has worked on several U.S. and international underground nuclearrepository research projects. She serves on the National Research Coun-cil’s Board on Radioactive Waste Management and has served as chairof the Board on Earth Science’s Rock Mechanics Committee. Dr. Longreceived an Sc.B. in engineering from Brown University, an M.S. ingeotechnical engineering and a Ph.D. in materials science and mineralengineering from the University of California, Berkeley.
JAMES K. MITCHELL (Vice-Chair) is university distinguished profes-sor emeritus at Virginia Polytechnic Institute and State University. Hehas served on several NRC committees including the Committee onSeeing Into the Earth and as chair of the Geotechnical Board. Dr.Mitchell’s expertise lies in the areas of soil behavior related to geotech-nical problems, soil improvement and ground reinforcement, and insitu measurement of soil properties. He received his B.S. in civil engi-neering from Rensselaer Polytechnic Institute, and his M.S. and Sc.D. in civil engineering from Massachusetts Institute of Technology. He is a member of the National Academy of Sciences and the NationalAcademy of Engineering.
RANDALL J. CHARBENEAU is professor of civil engineering andassociate dean for research in the College of Engineering at the Univer-sity of Texas at Austin. His expertise is in groundwater pollution, fateand transport, and modeling. Dr. Charbeneau is a member of the NRCCommittee on Technologies for Cleanup of Subsurface Contaminants inthe DOE Weapons Complex. He holds civil engineering degrees from
13359 Subsurface Appendixes 2/15/02 2:18 PM Page 141
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
the University of Michigan (B.S.), Oregon State University (M.S.), andStanford University (Ph.D.).
JEFFREY J. DANIELS is an associate professor in the Department ofGeological Sciences at Ohio State University. His expertise is in shal-low geophysics for subsurface characterization, and he focuses hisresearch on the use of ground penetrating radar and shallow seismictechniques for remote characterization of the subsurface. Dr. Daniels isa member of the American Geophysical Union, the Society of Explora-tion Geophysicists, and several other professional societies. He holds aB.S. and an M.S. in geology from Michigan State University and a Ph.D.in geophysical engineering from the Colorado School of Mines.
JOHN N. FISCHER is an environmental consultant. His expertise isin groundwater hydrology. His career includes 22 years with the U.S.Geological Survey (USGS) during which time he served as acting asso-ciate director, associate chief of the Water Resources Division and theNational Mapping Division, and as assistant chief hydrologist for pro-gram coordination. In the latter capacity, he was responsible for USGSprograms at civilian and DOE radioactive waste disposal sites and atthe DOE site at Yucca Mountain. He holds degrees from the U.S. NavalAcademy, Michigan State University, and the University of Arizona.
TISSA H. ILLANGASEKARE is the AMAX distinguished chair of envi-ronmental sciences and engineering and a professor of civil engineeringat the Colorado School of Mines. Until August 1998, he served as aprofessor of civil and environmental engineering in the Department ofCivil Environmental and Architectural Engineering at the University ofColorado, Boulder. His expertise is in numerical modeling of flow andtransport in porous and fractured media, multiphase flow modeling,aquifer remediation, and physical modeling of flow and transport inlaboratory test tanks. He holds a Ph.D. in civil engineering fromColorado State University. He is also a registered professional engineerand a professional hydrologist.
AARON L. MILLS is a professor of environmental science at theUniversity of Virginia. He has expertise in microbial transformations oforganic and inorganic pollutants and bacteria in the subsurface envi-ronment. He is a member of the American Geophysical Union, theAmerican Society for Microbiology, and the National Ground WaterAssociation. Dr. Mills holds a B.A. in biology from Ithaca College, andan M.S. in soil science with a minor in microbiology and a Ph.D. insoil science and ecology from Cornell University.
S U B S U R F A C E S C I E N C E
142
13359 Subsurface Appendixes 2/15/02 2:18 PM Page 142
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A p p e n d i x C
143
DONALD T. REED is group leader of the Actinide Speciation andChemistry Group in the Chemical Technology Division at ArgonneNational Laboratory. He is an expert in radionuclide speciation andmigration in subsurface media. He has undertaken a number of basicand applied projects in the fields of actinide speciation, solubility, andsubsurface interactions. His most recent research is focused on micro-biological-actinide interactions in the subsurface and the application ofsynchrotron-based methods to the analysis of actinide species in envi-ronmental samples. He is a member of the Nuclear Chemistry Divisionof the American Chemical Society, American Geophysical Union, andthe Material Research Society. He holds a Ph.D. in physical chemistryfrom Ohio State University.
JEROME SACKS is director of the National Institute of StatisticalSciences in Research Triangle Park, North Carolina and a professor atthe Institute of Statistics and Decision Sciences at Duke University. Hisinterests include the use of statistical techniques for characterization ofsubsurface properties. He has served on several National ResearchCouncil committees and boards including membership on the NRCCommittee on Building an Environmental Management Science Pro-gram, which helped the Department of Energy establish its Environ-mental Management Science Program, the topic of the current study.He has held professorships at the California Institute of Technology,Columbia University, Cornell University, Northwestern University,Rutgers University, University of Illinois, and Duke University. Dr. Sackshas served as program director for statistics and probability at theNational Science Foundation. He holds a B.A. and Ph.D. in mathemat-ics from Cornell University.
BRIDGET R. SCANLON is a research scientist in the Bureau ofEconomic Geology and also teaches courses in the geology and civilengineering departments at the University of Texas at Austin. Herexpertise lies in unsaturated zone hydrology, soil physics, environmen-tal tracers, and numerical simulations to quantify subsurface flow inarid regions. She served on the National Research Council Committeeon Ward Valley. She has served as a consultant to the Nuclear WasteTechnical Review Board. Dr. Scanlon received her Ph.D. in geology atthe University of Kentucky.
LEON T. SILVER is a W.M. Keck Foundation professor for resourcegeology, emeritus, Division of Geological and Planetary Sciences, at theCalifornia Institute of Technology. He has expertise in geology, petrolo-gy, and geochemistry, with special emphasis on uranium and thorium.
13359 Subsurface Appendixes 2/15/02 2:18 PM Page 143
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Dr. Silver was a public works officer in the U.S. Naval Civil EngineerCorps from 1945 to 1946, and held several positions at the U.S. Geo-logical Survey before he joined Caltech. He has served on numerousNRC committees, panels and boards, including his past membership onthe committee on Building an Environmental Management ScienceProgram. He earned a B.S. in civil engineering from the University ofColorado, an M.S. in geology from the University of New Mexico, anda Ph.D. in geology and geochemistry from the California Institute ofTechnology. He is a member of the National Academy of Sciences anda past president of the Geological Society of America.
CLAIRE WELTY is associate professor of civil and environmentalengineering and associate director and graduate advisor at the Schoolof Environmental Science, Engineering and Policy at Drexel University.She has expertise in groundwater hydrology and contaminant transport.Her current research projects include evaluation of the effects of theinteraction between porous medium heterogeneity and fluid density onfield-scale dispersion, stochastic analysis of virus transport in aquifers,and tracer tests in fractured sedementary rock. She teaches graduatecourses in groundwater hydrology, subsurface contaminant transport,water resources systems analysis, and stochastic subsurface hydrology.Dr. Welty holds a Ph.D. from Massachusetts Institute of Technology.
S U B S U R F A C E S C I E N C E
144
13359 Subsurface Appendixes 2/15/02 2:18 PM Page 144
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
D
Additional Resources
The following publications provide additional information on theDOE complex and subsurface contamination research and develop-ment. The DOE and EM web sites (www.doe.gov; www.em.doe.gov)provide additional information and resources.
1. Closing the Circle on the Splitting of the Atom: The Environmen-tal Legacy of Nuclear Weapons Production in the United Statesand What the Department of Energy Is Doing About It. Washing-ton, D.C.: U.S. Department of Energy, Office of EnvironmentalManagement. 1995.
The report describes the environmental legacy from the pro-duction of nuclear weapons and the cleanup underway by DOE.The report gives a detailed explanation of the nuclear productionprocess and includes information on the extent and types of con-taminants produced by each of the steps in the process. Thereport also describes the types of waste, cleanup actions, andprogress made at some DOE sites. The report contains manyphotographs of the sites and past waste management practices. Italso contains a short section on the production of nuclearweapons in other countries, and on environmental contamina-tion in the former Soviet Union.
2. Bioremediation of Metals and Radionuclides: What It Is andHow It Works. LBNL-42595. J. McCullough, T.C. Hazen, S.M.Benson, F.B. Metting, and A.C. Palmisano. Lawrence BerkeleyNational Laboratory. 1995.
This report explores the possibilities of using bioremediationtechnology to clean up hazardous metal and radionuclide conta-minants found in the DOE complex. Included in the report is anoverview of contamination problems at DOE facilities, a summa-ry of some of the most commonly used bioremediation technolo-
A p p e n d i x D
145
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
gies, a discussion of the chemical and physical properties ofmetals and radionuclides found in contaminant mixtures at DOEsites, an overview of the basic microbial processes that occur inbioremediation, specific in situ bioremediation processes thatcan be used on these contaminant mixtures, and a hypotheticalcase study of a composite DOE site with contaminated ground-water.
3. The 1996 Baseline Environmental Management Report.DOE/EM-0290. Washington, D.C.: U.S. Department of Energy,Office of Environmental Management. 1996.
The report provides an estimate of life-cycle costs and sched-ules for DOE’s environmental cleanup mission. Although the costand schedule estimates in this report have been superseded bythe 1998 Paths to Closure Report, the descriptions of waste andcontamination problems at DOE sites are still among the mostcomprehensive published to date.
4. Linking Legacies: Connecting the Cold War Nuclear WeaponsProduction Processes to Their Environmental Consequences.DOE/EM-0319. Washington, D.C.: U.S. Department of Energy,Office of Environmental Management. 1997.
The report provides a detailed analysis of the sources ofwaste and the contamination generated by the production ofnuclear weapons, giving specific environmental impacts of par-ticular production activities, in effect “linking” two of DOE’slegacies—nuclear weapons manufacturing and environmentalmanagement. The report quantifies the current environmentalresults of past weapons production activities and also containsinformation on the mission and functions of nuclear weaponsfacilities, the inventories of waste and materials remaining atthese facilities, and the extent and characteristics of contamina-tion in and around these facilities.
5. Accelerating Cleanup: Paths to Closure. DOE/EM-0362.Washington, D.C.: U.S. Department of Energy, Office ofEnvironmental Management. 1998.
The report outlines DOE’s cleanup plans based on site-devel-oped, project-by-project forecasts of the scope, schedule, andcosts to complete the more than 300 projects in its cleanup pro-gram. The forecasts provide information on technical activities,budgets, worker health and safety, and risk. The report also pro-vides a discussion of the Environmental Management program’sdecision-making process and the relationship of the “Paths toClosure” plan to that process. Included in the report are sum-maries of environmental management activities at specific sites,which provide information on the type and extent of the contam-
S U B S U R F A C E S C I E N C E
146
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
ination problem, end states, cost and completion dates, remedialactions, and critical closure paths.
6. Groundwater/Vadose Zone Integration Project Specification.DOE/RL-98-48. Draft C. Washington, D.C.: U.S. Department ofEnergy, Office of Environmental Management. 1998.
The report describes the Hanford Site’s Groundwater/VadoseZone Integration Project, a science-based strategy established in1997 to integrate all aspects of the remediation work at Hanfordwith the ultimate goal of protecting the Columbia River, river-dependent life, and users of the river’s resources. Included in thereport is a detailed description of the environmental setting ofthe Hanford Site, its climate and meteorology, geology, hydrolo-gy, water quality, and ecology. Also included is a long-range planfor remediation and closure for each of Hanford’s main areas(100, 200, and 300 areas). The report appendixes includedescriptions of technical elements, the operational history ofwaste disposal at Hanford, federal and state laws and regula-tions, current state of technical knowledge, and an applied sci-ence and technology plan.
7. Environmental Management Research and DevelopmentProgram Plan: Solution-Based Investments in Science andTechnology. Washington, D.C.: U.S. Department of Energy,Office of Environmental Management. 1998.
This program plan describes the investments that theEnvironmental Management (EM) program will make in scienceand technology to support the DOE cleanup mission. It alsodescribes EM’s approach to planning and managing these invest-ments. The plan incorporates what DOE terms “roadmapping” toidentify the science and technology areas that promise the great-est return on investment by reducing cleanup project cost,schedule, technical risk, and risk to workers, the public, and theenvironment. The program plan describes EM’s major problemareas, including contaminated environmental soil and ground-water, high-level radioactive waste, spent nuclear fuel, andnuclear materials.
8. Hanford Tank Clean Up: A Guide to Understanding the TechnicalIssues. R.E. Gephart and R.E. Lundgren. Battelle Press. 1998.
The report provides a good summary of the basic issues relat-ed to high-level radioactive waste that is being stored in 177underground tanks at the Hanford Site. It provides backgroundinformation on the history of the site, the production of high-level radioactive waste, the construction of the undergroundtanks and related facilities, and efforts to manage the waste andassociated environmental contamination. The report also details
A p p e n d i x D
147
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
the critical technical issues that need to be addressed forcleanup of the tanks.
9. National Research Council (NRC). Ground Water and SoilCleanup: Improving Management of Persistent Contaminants.Washington, D.C.: National Academy Press. 1999.
This report advises DOE on technologies and strategies forcleaning up three types of soil and ground water contaminants:metals, radionuclides, and dense nonaqueous phase liquids. Thereport describes DOE’s program in groundwater and soil remedi-ation, the changing regulatory environment, and technologiesbeing used to remediate each of the contaminant types notedabove. Specific advice to DOE suggests ways to set priorities intechnology development, to improve the overall technologydevelopment program, to overcome barriers to technologydeployment, and to address budget limitations.
10. From Cleanup to Stewardship. DOE/EM-0466. Washington, D.C.:U.S. Department of Energy, Office of EnvironmentalManagement. 1999.
This is a companion report to Accelerating Cleanup: Paths toClosure and provides background information on current andplanned long-term stewardship activities at DOE sites. The reportsummarizes what is currently known about end states at DOEsites, and it also provides information on the number and loca-tions of sites that will require continuing management after DOEcleanup is completed. Additionally, the report identifies severalissues that will need to be addressed to ensure a successful tran-sition from cleanup to stewardship.
S U B S U R F A C E S C I E N C E
148
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
E
Interim Report
Use original copy. (8 pages; shoot & strip in)
A p p e n d i x E
149
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A p p e n d i x E
151
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
152
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A p p e n d i x E
153
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
154
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A p p e n d i x E
155
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
156
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
A p p e n d i x E
157
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
158
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
F
Acronym List
DNAPL Dense non-aqueous phase liquidDOD U.S. Department of DefenseDOE U.S. Department of Energy
EM Environmental ManagementEPA U.S. Environmental Protection Agency
NAPL Non-aqueous phase liquidNRC National Research CouncilNSF National Science Foundation
USGS U.S. Geological Survey
A p p e n d i x F
159
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
Color Plates
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
LEGEND
Facility Boundary
Stream
Estimated extentof aquifer zoneIIB2 saturation
100 pCi/ml tritium
500 pCi/ml tritium
5,000 pCi/ml tritium
10,000 pCi/ml tritium
50,000 pCi/ml tritium
100,000 pCi/ml tritium
1 mile
1.6 kilometers
0
0
Solid W
aste O
perations
MW and LLWManagement Facilities
Old Radioactive Waste
Burial Ground
N
LEGEND
Facility Boundary
Stream
Estimated extentof aquifer zoneIIB2 saturation
5 ug /l trichloroethylene
50 ug /l trichloroethylene
100 ug /l trichloroethylene
200 ug /l trichloroethylene
300 ug /l trichloroethylene
1 mile
1.6 kilometers
0
0
Solid W
aste
Operations
MW and LLWManagement Facilities
Old Radioactive Waste
Burial Ground
N
PLATE 1A
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
C o l o r P l a t e s
PLATE 1A Plan view of the
Waste Burial Ground Com-
plex at the Savannah River
Site and associated tritium
(top) and trichloroethylene
(bottom) groundwater
plumes.
PLATE1B Schematic cross-
section of the surface barri-
er, or geosynthetic cap, and
photo of a cap that is being
constructed over the old
waste burial ground.
SOURCE: Savannah River
Site.
PLATE1B
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
PLATE 2 Plan view of Rocky Flats Environmental Technology Site showing areas of plutonium soil contamination.
SOURCE: Rocky Flats Environmental Technology Site.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
C o l o r P l a t e sCopyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
PLATE 3A
PLATE 3 Plan view of Hanford Site showing locations of features in the 100 and 200 Areas and boundaries of major ground-
water plumes. The 100 Area is located along the Columbia River and contains the site’s production reactors. The 200 Area,
which is located in the central part of the site, contains waste management facilities. A. Radionuclide contaminant plumes.
B. Hazardous chemical and nitrate plumes. (DWS = drinking water standards.) SOURCE: Richland Operations Office.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
C o l o r P l a t e s
PLATE 3B
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html
S U B S U R F A C E S C I E N C E
PLATE 4 Oblique view (looking from below the tanks toward the surface) showing cesium-137 contamination beneath
the SX tank farm in 200 East Area at Hanford. Elevation is shown in feet above mean sea level, and the visible tanks are
numbered with the prefix SX-. SOURCE: Richland Operations Office.
PLATE 5 Photo of mercury
found in soils at the Y-12
Plant at the Oak Ridge Site.
SOURCE: Oak Ridge
National Laboratory.
Copyright © 2003 National Academy of Sciences. All rights reserved.Unless otherwise indicated, all materials in this PDF File provided by the National Academies Press (www.nap.edu) for researchpurposes are copyrighted by the National Academy of Sciences. Distribution, posting, or copying is strictly prohibited withoutwritten permission of the NAP.Generated for [email protected] on Tue Aug 26 04:58:04 2003
http://books.nap.edu/catalog/9793.html