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    Research on Modeling and Simulation of Activated Sludge Process

    Wei Yao, Wu Li, Qiao Junfei

    Beijing University of Technology, Beijing, 100124, China

    [email protected]

    AbstractDue to the complexity of wastewater treatment

    process, it is difficult to apply the existing mathematical models

    in practice. A new model is presented for the wastewater

    treatment process in this paper. This model is based on

    Benchmark Simulation Model no.1 (BSM1) modeling method,

    and then simplifies Activated Sludge Model No. 1 (ASM1)

    which was set up to connect the secondary settler model

    dynamically. Meanwhile, the parameters of the model are

    adjusted by the experiment data. Finally, the practical data

    was used to predict the COD values of the water quality. The

    results demonstrate that this proposed model is useful.

    Keywords-Dynamic model; Benchmark Simulation Model no.1(BSM1); Simulation; Activated Sludge Process

    I. INTRODUCTIONGenerally speaking, wastewater treatment process is a

    biological process. However, due to the instability of the

    influent quantity and quality, the complexity of biochemicalreactions, as well as various factors such as regional

    differences, it is difficult to choose an appropriate modeling

    method for the whole wastewater treatment. Therefore, how

    to simulate the wastewater treatment process accurately is

    still an open problem. Activated sludge wastewater

    treatment process, which is the major approach of treatingindustrial organic wastewater and urban sewage in the

    current, has been widely used as the object of mathematical

    modeling for a long time. With a view to guide the practical

    wastewater treatment plant operation and design process, a

    well-known wastewater treatment process model, named

    Activated Sludge Model No. 1 (ASM1) [1] was issued by

    the International Water Association. In ASM1, Matrix form

    was used to describe the various biochemical reaction

    processes. In order to facilitate the computer simulation, the

    factors in the matrix can precisely and intuitively reflects the

    changes of each component in wastewater treatment

    process. However, this model is difficult for practical

    application due to various parameters and reaction

    processes.

    Based on ASM1, many domestic and foreign scholars haveproposed some methods to establish simple and effective

    models. Eveline et al [2] proposed a parallel ASM1 model,

    which performance better when the parameters and

    microbial biomass is not fully given in ASM1. However, a

    large quantity of calculation is still necessary in this model.

    And the forward the assumption did not distinguish solubleCOD and particulate COD. In order to save the

    computational time, Jeppsson [3] carried out ROM model

    based on ASM1; Llse Y. Smets et al [4] selected typical

    input and output data for reasonable linear approximation,

    which greatly simplifies the ASM1 parameters identification

    and model calibration process. Ji et al [5] implemented

    ASM-CN, a simplified ASM1 model of carbon oxidation

    which is suitable for common plug-flow reactor, and Yu etal [6] introduced a corrected and simplified model ASP-CR

    for carbon removal. However, the above models only

    consider the effect of aeration reactor without conducting a

    comprehensive simulation of the overall wastewatertreatment process.

    In order to obtain a universally applicable model of the

    wastewater treatment process for countries around the world,

    the Europe Scientific and Technological Co-operation

    launched the Benchmark Simulation Model no.1 (BSM1)

    [7]. It provides a set of rigorous criteria to improve theapplication of control strategy, including simulation models,

    engineering indicators, controllers, and performance

    indicators and testing processes. Yuan et al [8] combined

    Matlab and C++ to simulate the overall processes of BSM1,

    and verified the stability and consistency of software

    calculating process. In recent years, the intelligent modeling

    methods [9-10] are also used a certain degree ofdevelopment and become a research hotspot. Compared

    with the classical method of mathematical modeling, the

    most serious problem of intelligent modeling is that a

    universal model of the wastewater treatment process can not

    be given. Therefore, how to obtain an exact mathematical

    model is still an open problem for the wastewater treatment

    process simulation.

    In this paper, a new model of the whole wastewatertreatment process is proposed based on the modeling idea ofBSM1. This new simplified model not only reduces theparameters and computation, but it also shows the validitythrough simulation results. The rest paper is organized asfollows: In the next section, the whole architecture of the

    new model is described. This modeling shows the wholewastewater treatment process. In Section , the proposed

    model is used to predict the key parameters in the wastewatertreatment. The simulation results show that the new modelhas a high accuracy with compact structure. Finally, the

    paper is concluded in Section .

    II. WASTEWATERTREATMENT PROCESS MODELINGThe main process of BSM1 is shown in Fig. 1. Using

    A/O process, the benchmark plant is composed of a five

    2010 International Conference on Intelligent Computation Technology and Automation

    978-0-7695-4077-1/10 $26.00 2010 IEEE

    DOI 10.1109/ICICTA.2010.482

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    compartment activated sludge reactor consisting of two

    anoxic tanks followed by three aerobic tanks. ASM1 model

    is used to express the reaction mechanism in aeration reactor,and then the water flow into the secondary settler after

    reaction, the secondary settler was expressed by solid flux

    theory and Takcs double-exponential settling equation

    [11].

    Figure 1. The flowchart of BSM1

    A. Aeration Reactor ModelingASM1 Consists of three major processes: carbon

    oxidation process, nitrification process and denitrification

    process. Then, the treatments are promoted the presentation

    of eight biochemical reaction processes via a matrix format

    of wastewater in aerobic and anoxic conditions, including

    hydrolysis, microbial growth, decay, etc. The model

    includes thirteen components, five stoichiometric

    parameters and 14 kinetic parameters. Due to the

    complexity of ASM1 itself, a certain degree of

    simplification can be simulated according to different

    treatment target. The model in this article only considers the

    carbon oxidation process, without regard to nitrification

    process and denitrification process, so the biochemical

    reactions part of BSM1 model can be reduced to aerobic

    reactor, only consider the removal of carbon; and ASM1

    biochemical reaction processes has been simplified for threereactions. The total influent COD of aerobic reactor consists

    of the following five components, while XBA , XP are

    negligible due to the low concentration in the influent

    wastewater.

    TO S S I I BH COD S X X S X = + + + +

    where SS is the readily biodegradable substrate, XS is slowly

    biodegradable substrate, both of them flow into the

    secondary settler along with effluent water after beingdegraded in the aerobic reactor. XI is the particulate non-

    biodegradable material which is settled in the secondary

    settler without precipitating biochemical reactions in aerobic

    reactor. XBH is the heterotrophic biomass which is in the

    secondary settler for settlement as well after reacted in the

    aerobic reactor. SI is the soluble non-biodegradable material

    and can not be degraded or settled in the whole process.

    Accordingly, the observed conversion rate of each

    component in the activated sludge process can be

    established as follows:

    ( )

    1

    ,

    ,

    S S OH BH

    S S O H O

    S BH O

    h BH

    X S BH O H O

    dS S S r X

    dt K S K S

    X X Sk X

    K X X K S

    = = + + +

    + +

    ( )

    2

    ,

    (1 )S p H BH

    S BH O

    h BH

    X S BH O H O

    dXr f b X

    dt

    X X Sk X

    K X X K S

    = =

    + +

    3

    ,

    S OBHH BH

    S S O H O

    H BH

    S SdXr X

    dt K S K S

    b X

    = = + +

    The mass balance in aerobic reactor can be described as

    follows:

    0 0

    1( )k r r k f f

    dZQ Z Q Z r V Q Z

    dt V= + +

    where V is the volume of the aerobic reactor, rk is the

    reaction rate of the kth component Zk, Qr is the quantity of

    reflux in secondary settler, Q0 is the influent flow rate, Qf is

    the effluent flow rate from the aerobic reactor, Zf is the

    effluent component concentration from the aerobic reactor,

    Zr represents the reflux concentration of the secondary

    settler.

    Based on the above analysis, the modeling conditions

    and basis are:

    This model primarily for inspection of, nitrogen andphosphorus removal is not considered;

    This model only considered carbon oxidationprocess of heterotrophic bacteria under aerobic

    conditions and particulate organic material in the

    hydrolysis process; the corresponding parameters of

    other processes take zero value;

    According to the Benchmark data provided by IWA,the components which account for small proportion

    of effluent COD indicators are negligible;

    The dissolved oxygen concentration in the aerobicreactor is assumed to be constant, based on

    experience set SO = 2mg/l;Assuming heterotrophic microbial species is unitary and

    stability.B. Secondary Settler Modeling

    As an important part of a wastewater treatment system,secondary settler can be divided into two regions accordingto different functions: clarification zone and thickening zone.In secondary settler, soluble components can be considereduniformly distributed, namely, the concentration of solublecomponents do not change through sedimentation. And for

    Q0, Z0

    Qa, Za

    Qe, Ze

    Qf, Zf

    Qw, ZwQu, Zu

    Qr, Zr

    Biological ReactorClarifier

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    particulate components, the sedimentation process can bedescribed by the following differential equation:

    ( ) xX X

    D rt z z z

    = +

    whereX is the total sludge concentration at any height, is the solids flux at corresponding height, D is the

    diffusion coefficient, rx is the biochemical reaction rate.That is, the changing rate with time of the mass

    concentration of solid particles is tantamount to the changealong the height of solid flux concentration which caused bythe transfer and diffusion effect and the conversion rate ofactivated sludge components.

    Equation (4) can be transformed and simplified as thefollowing format:

    The secondary settler only consider the physicalsedimentation while ignore biochemical reactions, rx

    = 0;

    Without regard to the impact of diffusion, let thediffusion coefficientD = 0;

    According to solid flux theory, the solid flux insecondary settler consists of gravitationalsedimentation of solid particles and the flux

    generated by the flow of sludge water.

    Then equation (4) was transformed into:

    ( )( ) ups V XV XX

    t z z

    = +

    ( ) ( )s dnV X V X X

    t z z

    = +

    Equation (5) and (6) are respectively the expressions of

    Thickening zone and Clarification zone. Where /up e

    V Q A=

    and /dn uV Q A= are cross-sectional velocity respectivelygenerated by effluent water and effluent sludge, gravity

    sedimentation rate Vs is represented by Takcs double-

    exponential settling equation. X is the total sludge

    concentration, and the standard values in the original model

    are used as the value of other parameters.In this model, the secondary settler is divided into five

    layers from the bottom to top, the bottom is the 1st layer

    while the top is the 5th layer, and feed layer is the 3rd layer.

    Sludge concentrations in each layer are written as:

    For the bottom layer:

    2 1 ,2 ,11( ) min( , )dn s sV X XdX

    dt h

    +=

    For the layers below the feed layer:

    12

    ,3 ,2 ,2 ,1

    ( )

    min( , ) min( , )

    dn m m

    s s s s

    V X XdX

    dt h

    h

    +

    = +

    For the feed layer:

    33

    ,4 ,3 ,2

    ( )

    min( , )

    f f e u

    clar s s

    Q X Q Q X dX

    dt V

    h

    = +

    For the clarification layers above the feed layer:

    3 4 ,5 ,44( )up clar clar V X XdX

    dt h h

    = +

    For the top layer:

    4 5 ,55( )up clar V X XdX

    dt h

    =

    while, , 1 1 1

    ,

    , 1

    min( , )s j j s j j j tclar j

    s j j j t

    V X V X X X

    V X X X

    >=

    where Vis the volume of the secondary settler, h is theheight of each layer,Xi is the sludge concentration of eachlayer, s,i is sedimentation flux in each layer. The threshold

    concentrationXt is equal to 3000g/m3.

    C. Dynamic CouplingThe coupling of aeration reactor and secondary settler

    lies in the unit conversion of the particulate components. Thesludge concentrationXf which flow into the secondary settlercan be expressed as:

    , , , ,( )f S f I f BH f BA fX k X X X X= + + + where k=0.75. In order to simplify the wastewater treatmentmodel, the secondary settler is considered as the idealcondition. This process main refers to the sedimentation. Therecycle parameters are given as:

    , ,S f S u

    f u

    X X

    X X=

    whereXu is the underflow concentration.

    In the same way, the parameters XP,uXI,uXBH,u

    XBA,u can be calculated by (12).

    D. Some Common MistakesIn order to obtain satisfying simulation results, the

    parameters of simplified model must be calibrated. ASM1includes more than a dozen parameters, most of which arenot constant. These parameters may change its valueaccording to the change of environmental conditions.However, if each one was calibrated under specific practicalwastewater quality conditions and process characteristics, it

    would result in model application difficulties.The first step of parameter calibration is to analyze each

    parameters impact on effluent indicators. Synthesizingliterature [12, 13] about parameter sensitivity analysis, theheterotrophic yield coefficient YH has the greatestsensitivity, followed by the heterotrophic maximum specificgrowth rate H , half-saturation coefficient for heterotrophyKs and maximum specific hydrolysis rate constant Kh. Thecalibration ofYHcan be expressed by following formula:

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    XO TO SOCOD COD COD= +

    XOH

    SO

    CODY

    COD

    =

    where CODSO and CODXO respectively represents the CODconcentration of soluble and particulate components. Due to

    the small impact of other parameters, their values can be

    directly using the recommended ones at 20 for calculating.

    III. SIMULATION AND RESULTS ANALYSISThe processing model was built according to the

    treatment process of some small-scale wastewater treatment

    plant, the treating capacity of which is 60,000 tons/day. The

    plant is designed for meeting the target in accordance with

    national second level effluent standards. Since the model is

    mainly considered for COD removal of the plant, in whichthe effluent COD concentration should be less than 100

    mg/l.

    Simulation steps are given as: First of all, obtain steady-state effluent data of both aeration reactor and secondarysettler through steady-state simulation, then implement theentire wastewater treatment process through dynamicsimulation, which used to observe the fitting results bycomparing actual data and experimental data.

    A. Steady-state SimulationIn the actual operation of wastewater treatment plants,

    the system's steady-state is only relative, the water quantityand quality constantly keep changing every day even everymoment, it just stay relatively stable in the absence ofexceptional circumstances (for example, heavy rainfall andtemperature impact). Thus, the average running data of thewastewater treatment plant was selected as steady-stateoperation data. In this case, flow rate is 50, 000m3/d, and

    influent COD concentration is 338.5mg/l.Based on the experience, the analysis was carried out to

    measure the flow components. Therefore, the influent CODcan be decomposed by he ratio of 54%, 12.8%, 16.8%,11.5%, 4.9%, corresponding to the components respectivelywhich required in the model: XS, XI , SS , SI , XBH. Thus,through calculation, the concentrations of the abovecomponents are listed in order: 182.9mgCOD/l,43.23mgCOD/l, 56.53mgCOD/l, 39.25mgCOD/l and16.625mgCOD/l.

    Finally, the concentration of effluent component will besuperimposed to be the effluent COD concentration bymodeling principles. The results of the steady-statesimulation are shown in Figure 2 and Figure 3 below.

    0 0.1 0.2 0.3 0.4 0.50

    10

    20

    30

    40

    50

    60

    70

    80

    90

    t(day)

    Concen

    tration(mgCOD/l)

    Xs

    Ss

    Figure 2. Steady-state simulation in aeration reactor

    In Fig. 2: Under steady-state condition, aeration reactoreffluent XS , SS concentrations are 38.93mgCOD/l,2.08mgCOD/l respectively, which shows that aerationreactor model can effectively degrade the organic material ofwastewater.

    In Fig. 3: When the secondary settler reaches steadystate, the concentration of the 1st layer to the 5th layer isrespectively: 6765.6mgCOD/l, 182.91mgCOD/l, 182.91mgCOD/l, 25.91mgCOD/l and 8.36mgCOD/l, which showsa good settlement performance as well.

    0 0.1 0.2 0.3 0.4 0.50

    2000

    4000

    6000

    8000

    10000

    t(day)

    Co

    ncentration

    gSS/m3

    The 1st Layer

    (a) Sludge concentration of the 1st layer

    0 0.1 0.2 0.3 0.4 0.50

    500

    1000

    1500

    2000

    2500

    t(day)

    Concen

    tration

    gSS/m3

    The 2nd layer

    The 3rd layer

    (b) Sludge concentration of the 2nd and the 3rd layer

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    0 0.1 0.2 0.3 0.4 0.50

    10

    20

    30

    40

    50

    60

    t(day)

    Concent

    ration

    mgSS/l

    The 4th layer

    The 5th layer

    (c) Sludge concentration of the 4th and the 5th layer

    Figure 3. Steady-state simulation in secondary settlerUnder the steady-state conditions, the effluent COD

    concentration was degraded to 52.6mg/l after calculation,which is close to the first emission standards at the nationallevel, so the model is valid.

    B. Dynamic SimulationTo verify the performance of model capability of

    simulating practical operation, using the 18-day data ofwastewater treatment plant from April 1st to April 18th fordynamic simulation. According to the literature, the influentof a specific wastewater treatment plant is constant and notsubject to flow rate fluctuations for relative content of eachcomponent for urban wastewater, in dynamic simulation,components determination still follows the experience valuein steady-state, and then obtains effluent data through modelcalculation. The simulation results are shown in Fig. 4:

    0 2 4 6 8 10 12 14 16 1830

    40

    50

    60

    70

    80

    90

    100

    t(day)

    COD(mg/l)

    Measured Effluent CODSimulating Effluent COD

    Figure 4. Comparison of effluent CODFrom Figure 4, we can see a similar trend in the two

    curves and the average value from April 1st to April 18th

    of simulated effluent COD can be calculated from the result,of which is 54.78mg/l, while the average value of measuredeffluent COD is 56.93mg/l, the error is 3.78%. Therefore, themodel has capability of predictability on the actual operationof wastewater treatment plants.

    The daily simulated and measured values are shown inTable 1, in which CODIN represents the concentration ofCOD in influent wastewater, and CODM and CODPrespectively represents the measured and the simulated CODconcentration in effluent water.

    As the results shown in Table 1, the model is relativelyweak in anti-interference ability, when the influent

    concentration changed greatly compared to the last day, thedifference between effluent COD of the simulated andmeasured values is comparatively large, therefore, the modelshould be further improved robustness . For example, onApril 9th and April 11th, the errors were 15.4% and 12.48%respectively. At other time, the simulated values can be fittedwell with the measured values.

    TABLE I. SIMULATION RESULTS OF THE EFFLUENT CODDATE

    CODIN

    (mg/l)

    CODM(mg/l)

    CODP

    (mg/l)

    ERROR

    (%)

    4.1 323 51.3 46.6 9.16

    4.2 312 53 47.4 10.57

    4.3 339 53 53.6 1.13

    4.4 335 58.6 57.7 1.54

    4.5 306 56.4 53.6 4.96

    4.6 323 62 61.4 0.97

    4.7 277 56.3 56 0.53

    4.8 242 56 49.4 11.79

    4.9 326 57 65.8 15.44

    4.10 224 52 49.4 5

    4.11 310 62.5 54.7 12.48

    4.12 320 62 65.5 5.65

    4.13 275 55.5 52.5 5.41

    4.14 350 61 56.2 7.87

    4.15 331 55.1 53.3 3.27

    4.16 372 56 57.1 1.96

    4.17 354 60 53.6 10.67

    4.18 347 57 51.4 9.82

    IV. CONCLUSIONThis paper proposed a mathematical model for

    wastewater treatment plants which was established throughreasonable simplification on the aeration reactor and thesecondary settler. Not only the model's components, processand the number of model parameters are greatly reduced, butalso achieved the dynamic connection of aeration reactor andthe secondary settler. At the same time, by simulating thepractical wastewater treatment plants of COD removal, theability of prediction on urban wastewater treatment processis improved. Through the effluent COD simulation of actual

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    process using this model, the obtained simulation results canfollow the trend in measured values, and the error is within acertain range, which indicates the validity of the model andcalculation process.

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