response action contract - superfund records collections · response action contract no. 68-w6-0036...

$: RESPONSE ACTION CONTRACT - Superfund Records Collections · Response Action Contract No. 68-W6-0036 ... \151498\SAP\PERRYTONWBLLHSP.DOC 1. ... Heat Cramps Heat Exhaustion Heat Stroke$
RESPONSE ACTION CONTRACT

United States Environmental Protection Agency Region VI

Contract No. 68-W6-0036

W CH2MHILL//i Association With:

Science Applications International CorporationGeomarine, Inc.

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135203

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*135203*

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Health and Safety PlanEngineering Evaluation/Cost Analysis

City of Perryton Well No. 2 SiteMarch, 1999

Work Assignment No. 034-NSEE-06DHDCN 99-1185

Health and Safety PlanEngineering Evaluation/Cost Analysis

City of Perryton Well No. 2 SitePerryton, Ochiltree County, Texas

Response Action Contract No. 68-W6-0036EPA Work Assignment No. 034-NSEE-06DH

CH2M HILL Project No. 151498DCN 99-1185

Prepared for:U.S. Environmental Protection Agency

Prepared by;CH2M HILL, INC

March 1999

Table of Contents

Section Page

1 Project Information and Description ................................................................................ 1

2 Project Organization and Tasks To Be Performed Under This Plan................................ 42.1 Project Organization............................................................................................. 42.2 Description of Tasks ............................................................................................4

2.2.1 Hazwoper-Regulated Tasks........................................................................ 42.2.2 Non-Hazwoper-Regulated Tasks............................................................... 4

3 Hazard Evaluation and Control......................................................................................... 53.1 Heat and Cold Stress............................................................................................ 5

3.1.1 Preventing Heat Stress ............................................................................... 53.1.2 Symptoms and Treatment of Heat Stress................................................... 53.1.3 Heat-Stress Monitoring.............................................................................. 53.1.4 Preventing Cold Stress........................................................—..—...............63.1.5 Symptoms and Treatment of Cold Stress................................................... 6

3.2 Procedures for Locating Buried Utilities............................................................. 63.3 General Physical (Safety) Hazards and Controls................................................. 73.4 Biological Hazards and Controls .................;..................................................... 103.5 Tick Bites........................................................................................................... 113.6 Radiological Hazards and Controls.................................................................... 113.7 Hazards Posed By Chemicals Brought on the Site............................................ 12

3.7.1 Hazard Communication ........................................................................... 123.7.2 Shipping and Transportation of Chemical Products................................ 12

3.8 Contaminants of Concern................................................................................... 133.9 Potential Routes of Exposure............................................................................. 16

4 Personnel............—..................................—..................................................................... 174.1 CH2M HILL Employee Medical Surveillance and Training............................. 174.2 Field Team Chain of Command and Communication Procedures .................... 17

4.2.1 Client........................................................................................................ 174.2.2 CH2M HILL............................................................................................. 184.2.3 Subcontractors.......................................................................................... 184.2.4 Contractors...............................................................—............................. 19

5 Personal Protective Equipment (PPE)............................................................................ 205.1 PPE Specifications.........................................:........:.....:.:.................................. 205.2 Reasons for Upgrading or Downgrading Level of Protection........................... 20

6 Air Monitoring Specifications........................................................................................ 216.1 Calibration Specifications.................................................................................. 226.2 Air Sampling...................................................................................................... 22

Table of Contents (Continued)

Section

7 Decontamination............................................................................................................. 237.1 Decontamination Specifications ........................................................................ 237.2 Diagram ofPersonnel-Decontamination Line................................................... 23

8 Spill-Containment Procedures........................................................................................ 23

9 Confined-Space Entry..................................................................................................... 23

10 Site-Control Plan............................................................................................................. 2510.1 Site-Control Procedures..................................................................................... 2510.2 Hazwoper Compliance Plan............................................................................... 26

11 Emergency Response Plan.............................................................................................. 2711.1 Pre-Emergency Planning.................................................................................... 2711.2 Emergency Equipment and Supplies .................................................................2811.3 Emergency Medical Treatment.......................................................................... 2811.4 Nonemergency Procedures................................................................................. 2811.5 Incident Response .............................................................................................. 2911.6 Evacuation...............................................................................—.........—............2911.7 Evacuation Routes and Assembly Points—...———..——————————. 2911.8 Evacuation Signals.......................................................................———.............29

12 Emergency Response—..——...—.........———..............—.....———.—..——..—..———— .3012.1 Emergency Response Telephone Numbers—..—....................—————.—..— 3012.2 Government Agencies Involved in Project................—...—...........—..————. 30

13 Emergency Contacts ....— —....—...—..—...... —............. —.—————————............32

14 Approval...—.——————....—..——.—..——.———————————— ——...— ——.—3314.1 Original Plan ...................-....-...............-.;....—————————————— 3314.2 Revisions— — — — — — — —..—..—..——.—...——————— ————.——. ..——33

15 Distribution...... ———..—.— —.——— ——...—..........——...————— ——————— .———33

16 Attachments—.—.————...——.—...—......................—...—————————————— 33

Attachment I Employee SignoffAttachment 2 Material Safety Data Sheets

DFWP:\151498\SAP\PERRYTONWELLHSP.DOC

CH2M HILL HEALTH AND SAFETY PLAN(Reference CH2M HILL SOP 19, Health and Safety Plans)

This health and safety plan will be kept on the site during field activities and will be reviewed and updated asnecessary. The plan adopts, by reference, the standards of practice (SOP) in the CH2M HELL Corporate Healthand Safety Program, Program and Training Manual, and CH2M HILL'S Site safety Notebook as appropriate.The site safety coordinator (SSC) is to be familiar with these SOPs and the content of this plan. Site personnelmust sign Attachment 1. In addition, this plan adopts procedures in the work plan for the project.

1 PROJECT INFORMATION AND DESCRIPTION

CLIENT OR OWNER: Vincent Malott PROJECT NO: 151498

CH2M HILL PROJECT MANAGER: Peter Van Noort OFFICE: DFW

SITE NAME: City of Perryton Well #2

SITE ADDRESS: Ochiltree County, Perryton, Texas

DATE HEALTH AND SAFETY PLAN PREPARED: February 16,1999

DATE(S) OF INITIAL VISIT: February 1999

DATE(S) OF SITE WORK: April 1999

SITE ACCESS: restricted

SITE SIZE: 1.7 acres

SITE TOPOGRAPHY: NA

PREVAILING WEATHER: Average annual temperature of 57° Fahrenheit, total annual averageprecipitation 19 inches, prevailing wind direction changes seasonally.

SITE DESCRIPTION AND HISTORY:

The City of Perryton Well No. 2 site is a public drinking water supply well contaminated by carbontetrachloride (CTC) at concentrations ranging from 35.8 ug/1 to 50.3 ug/1. Chloroform was also detected atconcentrations less than 5 ug/1. The well has been out of service since June 1989 when the TexasDepartment of Health originally documented the contamination. CTC has not been detected in the otherwater supply wells.

The source of the CTC contamination is unknown and the area of contamination is undefined. Previousinvestigations have suggested potential sources for the contamination; however, they have identified nosingle definitive source. The Ogallala Aquifer is the principal source of drinking water within OchiltreeCounty. Ground water is the major pathway of concern.

The ESI ground water sampling activities conducted in June 1996 at Well No. 2 included a 200 gpm test thatpumped approximately 6,000 gallons and a second test 5 days later at 179 gpm that pumped approximately19,700 gallons. During the second test, lead was detected at concentrations ranging from 35 Ug/1 to 60.9

DFW\P:\151498\SAP\PERRYTONWBLLHSP.DOC 1

u.g/1. Lead was not detected during the first test. Also detected in the well tests were the herbicidesPropazine (concentrations of 3.3 (lg/1 to 5.0 u,g/l) and Atazine (concentrations less than 1 (lg/1.Soil testing was also conducted as part of the ESI. No CTC was reported in the soil samples. Lowconcentrations ofmethylene chloride and chloroform, possible degradation products of CTC, were reportedin soils from the site, but no direct corelation to the CTC groundwater comtamination was located.

The City ofPerryton is in the extreme northernmost part of the Texas panhandle in Ochiltree County. WellNo. 2 is located within a 1.7 acre maintenance yard used by me City ofPerryton Utility Department. Thewell is located on the southeast comer of the property, near the northwest corner of the intersection of NorthAmherst Street and Santa Fe Ave. The geographical coordinates of the site are approximately 36 degrees 24'05" north latitude and 100 degrees 48' 20" longitude.

Further site characterization is necessary to verify the presence of lead in groundwater at Well #2, as well asto gather further physical characterization information for consideration of future removal or treatmentalternatives. Currently scheduled site activities include groundwater sampling at Well #2. For additionalactivities beyond this sampling, Site Specific Health and Safely Plan Addenda will be prepared tospecifically address the activities to be performed.

DFW\P:\151498\SAP\PERRYTONWELLHSP.DOC 2

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SOURCE: REFERENCE 4

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FIGURE 1SITE PLAN

CITY OF PERRYTON WELL NO. 2PERRYTON, TEXAS

.________ CH2IVIHILL

2 PROJECT ORGANIZATION AND TASKS TO BE PERFORMED UNDER THIS PLAN

2.1 PROJECT ORGANIZATION

CLIENT: Vincent Malott

CH2MHILL:Project Manager: Peter Van Noort/DFWField Team Leader: To be determinedRefer to Section 4 for field staff.

CONTRACTORS and SUBCONTRACTORS: Refer to Section 4.2.

2.2 DESCRIPTION OF TASKS (Reference Section 1, "Field Activity Start-up Form," of Site Safety Notebook

Refer to project documents (i.e., work plan) for detailed task information. A health and safety risk analysis has beenperformed for each task and is incorporated in this plan through task-specific hazard controls and requirements formonitoring and protection. Tasks in addition to those listed below require an approved amendment to this plan beforeadditional work begins. Refer to Section 10.2 for procedures related to tasks that do not involve hazardous wasteoperations and emergency response (Hazwoper).

2.2.1 HAZWOPER-REGULATED TASKS

• Groundwater monitoring • Investigation-derived waste (drum) sampling and disposal

2.2.2 NON-HAZWOPER-REGULATED TASKS

Under specific circumstances, the training and medical monitoring requirements of federal or state Hazwoperregulations are not applicable. It must be demonstrated that the tasks can be performed without the possibility ofexposure in order to use non-Hazwoper-trained personnel. Prior approval from the HSM is required beforethese tasks are conducted on regulated hazardous waste sites.

TASK RESTRICTIVE CONDITIONS

DFW\P:\15l498\SAP\PERRYTONWELLHSP.DOC - — ^

3 HAZARD EVALUATION AND CONTROL

3.1 HEAT AND COLD STRESS (Reference CH2M HILL SOP HS-09, Heat and Cold Stress)

3.1.1 PREVENTING HEAT STRESS

• Drink 16 ounces of water before beginning work, such as in the morning or after lunch. Disposable (e.g.,4-ounce) cups and water maintained at 50° to 60°F should be available. Under severe conditions, drink 1 to2 cups every 20 minutes, for a total of 1 to 2 gallons per day. Take regular breaks in a cool, preferably air-conditioned, area. Do not use alcohol in place of water or other nonalcoholic fluids. Decrease your intake ofcoffee and caffeinated soft drinks during working hours. Monitor for signs of heat stress.

• Acclimate to site work conditions by slowly increasing workloads; e.g., do not begin site work with extremelydemanding activities.

• Use cooling devices, such as cooling vests, to aid natural body ventilation. The devices add weight, so theiruse should be balanced against efficiency.

• Use mobile showers or hose-down facilities to reduce body temperature and cool protective clothing.• During hot weather, conduct field activities in the early morning or evening if possible.• Provide adequate shelter to protect personnel against radiant heat (sun, flames, hot metal), which can decrease

physical efficiency and increase the probability of heat stress.• In hot weather, rotate shifts of workers. ; ,• Maintain good hygiene standards by frequently changing clothing and by showering. Clothing should be

permitted to dry during rest periods. Persons who notice skin problems should consult medical personnel.

3.1.2 SYMPTOMS AND TREATMENT OF HEAT STRESS

Heat Syncope Heat Rash (miliariarubra, "prickly heat")

Heat Cramps Heat Exhaustion Heat Stroke

Signs andSymptoms

Treatment

Sluggishness orfainting whilestanding erect orimmobile in heat.

Remove to coolerarea. Rest lyingdown. Increase fluidintake. Recoveryusually is prompt andcomplete.

Profiise dny raised redblister-like vesicles onaffected areas, alongwith pricklingsensations during heatexposure.

Use mild drying lotionsand powders, and keepskin clean for dryingskin and preventinginfection.

Painful spasms inmuscles usedduring work(arms, legs, orabdomen); onsetduring or afterwork hours.

Remove to coolerarea. Rest lyingdown. Increasefluid intake.

Fatigue, nausea, headache,giddiness; skin clammy andmoist; complexion pale,muddy, or flushed; may fainton standing; rapid threadypulse and low blood pressure;oral temperature normal or low

Remove to cooler area. Restlying down, with head in lowposition. Administer fluids bymouth. Seek medicalattention.

—

Red, hot, dryskin; dizziness;confusion; rapidbreathing andpulse; high oraltemperature.

Cool rapidly bysoaking in cool-but not cold-water. Callambulance, andget medicalattentionimmediately!

3.1.3 HEAT-STRESS MONITORING

For field activities part of ongoing site work activities in hot weather, the following procedures should be used tomonitor the body's physiological response to heat and to estimate the work-cycle/rest-cycle when workers areperforming moderate levels of work. These procedures should be considered when the ambient air temperatureexceeds 70°F, the relative humidity is high(>50%), or when the workers exhibit symptoms of heat stress.

The heart rate should be measured by the radial pulse for 30 seconds, as early as possible in the resting period.The HR at the beginning of the rest period should not exceed 110 beats/minute, or 20 beats/minute above restingpulse. If the HR is higher, the next work period should be shortened by 33 percent, while the length of the restperiod stays the same. If the pulse rate still exceeds 110 beats/minute at the beginning of the next rest period, thefollowing work cycle should be further shortened by 33 percent. The procedure is continued until the rate ismaintained below 110 beats/minute, or 20 beats/minute above resting pulse.

DFW\P:\151498\SAP\PERRYTONWELLHSP.DOC

3.1.4 PREVENTING COLD STRESS

Be aware of the symptoms of cold-related disorders, and wear proper clothing for the anticipatedfieldwork.Consider monitoring the work conditions and adjusting the work schedule, using guidelines developed bythe U.S. Army (wind-chill index) and the National Safety Council (NSC).Wind-Chill Index. This measure relates the dry bulb temperature and the wind velocity. It is used only toestimate the combined effect of wind and low air temperatures on exposed skin. The wind-chill indexsometimes is limited in its usefulness because the index does not take into account the body part that isexposed, the level of activity, or the amount or type of clothing worn. For those reasons, it is used only as aguideline to warn workers when they are in a situation that can cause cold-related illnesses. Used inconjunction with the NSC guidelines, the wind-chill index provides a starting point for adjusting work andwarm-up schedules.NSC Guidelines for Work and Warm-Up Schedules. The cold-exposure limits recommended by the NSCcan be used in conjunction with the wind-chill index to estimate work and warm-up schedules forfieldwork. The guidelines are not absolute; workers should be monitored for symptoms of cold-relatedillness. If symptoms are not observed, the work duration can be increased.The wind-chill index and the NSC guidelines are in the CH2M HILL Corporate Health and SafetyProgram, Program and Training Manual, SOP HS-09.

3.1.5 SYMPTOMS AND TREATMENT OF COLD STRESS

Immersion (Trench) Foot Frostbite Hypothermia

Signs andSymptoms

Treatment

Feet discolored and painful;infection and swellingpresent.

Seek medical treatmentimmediately.

Blanched, white, waxy skin, but tissue resilient;tissue cold and pale.

Remove victim to a warm place. Rewann areaquickly in warm-but not hot-water. Havevictim drink warm fluids, but not coffee oralcohol. Do not break blisters. Elevate theinjured area, and get medical attention.

Shivering, apathy, sleepiness; rapid drop inbody temperature; glassy stare; slow pulse;slow respiration.

Remove victim to a warm place. Havevictim drink warm fluids, but not coffee oralcohol. Get medical attention.

3.2 PROCEDURES FOR LOCATING BURIED UTILITIES

Local Utility Mark-Out ServiceName: NAPhone: NA

Where available, obtain utility diagrams for the facility.Review locations of sanitary and storm sewers, electrical conduits, water supply lines, natural-gaslines, and fuel tanks and lines.Review proposed locations of intrusive work with facility personnel knowledgeable of locationsof utilities. Check locations against information from utility mark-out service.Where necessary, clear locations with a utility-locating instrument (e.g., metal detector).Where necessary (e.g., uncertainty about utility locations), excavation or drilling of the upperdepth interval should be performed manually.Monitor for signs of utilities during advancement of intrusive work (e.g., sudden change inadvancement of auger or split spoon).When the client or other onsite party is responsible for determining the presence and locations ofburied utilities, the SSC should confirm that arrangement. ;

.3.3 GENERAL PHYSICAL (SAFETY) HAZARDS AND CONTROLSEngineering and administrative controls are to be implemented by the party in control of the site or the hazard (i.e., CH2M HILL, subcontractor, or contractor). CH2M HILL employees and subcontractors must, at a minimum, remain aware of hazards affecting them regardless of who is responsible for controlling the hazards.Specialty subcontractors are responsible for the safe operation of their equipment (e.g., drill rig, heavy equipment). CH2M HILL employees are not to operate, or assist in the operation of, any subcontractor or contractor equipment

Tasks

Hazard(Refer to SOP, or HSP Section)

Hying debris/objects (HS-07)Noise > 85 dBAGas cylinders (HS-21)

Electrical

Suspended loadsBuriedTiniities.-dramsT'tanta, etc. -(Section 3.3)Slip, trip, fall hazards (e.g.,wet/muddy surface, inadequaterailing, unstable surface)

Back injury (HS-29)

Confined space entry (Section 9.0)

Trenches/excavations (HS-32)

Protruding objects

Visible lightning

Vehicle traffic(HS-24)Stairways, ladders, and scaffolds(HS-25)

Engineering Controls, Administrative Controls, and Work PracticesProvide shielding and PPE; maintain distance.Noise protection and monitoring required.Instruct employees in the safe use of compressed gases. Make certain gas cylinders areproperly anchored and chained. Keep cylinders away from ignition sources. Capcylinders when not in use.

Make certain third wire is properly grounded. Do not tamperwith electrical wiring unless qualified to do so. Ground asappropriate.Project field sites should have ground fault circuit interrupters(GFCIs) installed for all wiring, including extension cords.Heavy equipment (e.g., drill rig) should remain at Jeast 15 feetfrom overhead power line for power lines of 50 kV or less. Foreach 10 kV > 50, increase distance by Vi foot.Operate and maintain equipment according to manufacturer'sinstructions.Use only extension cords that are three-wire grounded. Cordspassing through work areas must be covered or elevated toprotect from damage.Use only electrical tools and equipment that are eithereffectively grounded or double-insulated UL approved.Properly label switches, fuses, and circuit breakers.Remove cord from an outlet by grasping the plug, not pullingthe cord.Protect all electrical equipment, tools, switches, etc., fromelements.Avoid physical contact with power circuitOnly qualified electricians are to install and work on electricalcircuits and equipment.

Work not permitted under suspended loads.Locate buried utilities, drums, tanks, etc., before digging or drilling and mark location.

Provide slip-resistant surfaces, ropes, and/or other devices to be used. Brace and shoreequipment

Use proper lifting techniques, or provide mechanical lifting aids.

Space must be evaluated by qualified person. Additional controls and monitoring,training, and an approved entry permit are generally required.

Make certain trench meets OSHA standard before entering. All excavations > 4 feetdeep must be sloped or shored, and have a ladder every 25 feet. Personnel andequipment must remain at least 2 feet from edge of trench at all times.

Flag visible objects.

Stop work.Provide temporary traffic controls, including trained flaggers and lookouts. Implementtraffic control program when required.Stairways and ladders are generally required when there is a break in elevation of 19inches or more. Keep access ways clear. Equipment must meet OSHA specifications.Document employee training.

Test Pitand

Excavation

...

NOT

Drilling, GeoproneInstallation, WellInstallation andAbandonment

GroundwaterMonitoring,

Aquifer Testing, andVideo Surveying of

Wells

X-

X

X

X

X

Surface Waterand Sediment

Sampling Usinga Boat

Surface Water andSediment Samplingfrom the Shore or

WaterHand

Angering Surveying

rowDrum Sampling and

Disposal*

X

X

X

XX

Observation ofLoading ofMaterial for

Offsite Disposal

Remediation andConstruction

Oversight

3.3 GENERAL PHYSICAL (SAFETY) HAZARDS AND CONTROLSEngineering and administrative controls are to be implemented by the party in control of the site or the hazard (i.e., CH2M HELL, subcontractor, or contractor). CH2M HILL employees and subcontractors must, at a minimum, remain aware of hazards affecting them regardless of who is responsible for controlling the hazards.Specialty subcontractors are responsible for the safe operation of their equipment (e.g., drill rig, heavy equipment). CH2M HILL employees are not to operate, or assist in the operation of, any subcontractor or contractor equipment.

Tasks


Elevated work area/falls(HS-31)

Fire prevention and control (HS-22)

Inadequate illumination

Entanglement in rotating equipment

Drilling

Heavy equipment

Engineering Controls, Administrative Controls, and Work Practices

Provide guardrail, safety net, floor covers, body harness, and monitoring system, whereapplicable. Document employee training.

No spark sources are allowed within exclusion or decontamination zones.Appropriate firefighting equipment must be available on the site.Extinguishers are to be inspected visually every month and undergo an annualmaintenance check.Post "Exit" signs over exiting doors, and post "Fire Extinguisher" signs overextinguisher locations. Keep areas near exits and extinguishers clear. Open

--flames are prohibited in the vidiuty of flammable materials.Combustible materials stored outside should be at least 10 feet &om thebuilding.Unnecessary combustible materials and flammable or combustible liquidsmust not be allowed to accumulate.Flammable or combustible liquids must be kept in approved containers, andmust be stored in an approved storage cabinet.

Site work will be performed during daylight hours whenever possible. Workconducted during hours of darkness will require enough illumination intensity "to reada newspaper without difficulty."• Prohibit loose clothing and hair• Prohibit wearing jewelry• The drill rig is not to be operated in inclement weather.• The driller is to verify that the rig is properly leveled and stabilized before raising

the mast.• Personnel should be cleared from the sides and rear of the rig before the mast is

raised.• The driller is not to drive the rig with the mast in the raised position.s The driller must check for overhead power lines before raising the mast. A

minimum distance of 15 feet between mast and overhead lines (<50 kV) isrecommended. Increased separation may be required for lines greater than 50 kV.

• Personnel should stand clear before rig startup.• The driller is to verify that the rig is in neutral when the operator is not at the

controls.• Become familiar with the hazards associated with the drilling method used (cable

tool, air rotary, hollow-stem auger, etc.).• Do not wear loose-fitting clothing, watches, etc., that could get caught in moving

parts.• Do not smoke or permit other spark-producing equipment around the drill rig.• • The'drilrrig must be equipped -witha •kin wirew switch; and"personnei-areto be

informed of its location.• Be aware and stand clear of heavy objects that are hoisted overhead.• The driller is to verify that the rig is properly maintained in accordance with the

drilling company's maintenance program.• The driller is to verify that all machine guards are in place while the rig is in

operation.• The driller is responsible for housekeeping (maintaining a clean work area).• The drill rig should be equipped with at least one fire extinguisher.• If the drill rig comes into contact with electrical wires and becomes electrically

energized, do not touch any part of the rig or any person in contact with the rig, andstay as far away as possible. Notify emergency personnel immediately.

• Become familiar with hazards specific to the equipment being used.• Always confirm that the operator is aware of your location, particularly when you

approach or pass by equipment.• Backup alarm is required for heavy equipment Do not count on backup alarms

always functioning. Look around when alarm sounds.• Do not ride equipment not designed for passengers.• Do not climb on operating equipment.• Do not place yourself between fixed and moving parts or objects.• Do not stand adjacent to the equipment.

' Test Pit"and

Excavation

--

Drilling, GeoprobeInstallation, WellInstallation andAbandonment


" Aquifer Testing, andVideo Surveying of

Wells

X

Surface Waterand Sediment "'


•--

Surface Water and'Sediment Samplingfrom the Shore or

Water

-—-

HandAngering

-

•

Surveying


Disposal*

X

X

Observation ofLoading of

Material forOffsite Disposal

•

•


Oversight

DFW\P:\151498\SAP\PERRYTONWELLHSP.DOC

3.3 GENHRAL PHYSICAL (SAFETY) HAZARDS AND CONTROLSEngineering and administrative controls are to be implemented by the party in control of the site or the hazard (i.e., CH2M HILL, subcontractor, or contractor). CH2M HILL employees and subcontractors must, at a minimum, remain aware of hazards affecting them regardless of who is responsible for controlling the hazards.Specialty subcontractors are responsible for the safe operation of their equipment (e.g., drill rig, heavy equipment). CH2M HILL employees are not to operate, or assist in the operation of, any subcontractor or contractor equipment.

Tasks


Working near water

Working on water

IDW Drum sampling

Engineering Controls, Administrative Controls, and Work Practices• Stay clear of equipment on cross slopes and unstable terrain.• Stay clear of pile-driving operations.• Stay outside the turning radius of the equipment• Operators using all-terrain vehicles (ATV) must be trained; other ATV requirements

may apply.• Observer must remain in contact with operator and signal safe backup.• Personnel must remain outside the turning radius.

• U.S. Coast Guard-approved personal flotation devices (PFDs-e.g., life jacket)provided for each employee will be worn.

• PFDs will be inspected before and after each use. Defective equipment will not beused.

• Sampling and other equipment will be used according to the manufacturer'sinstructions.

• A minimum of one life-saving skiff will be provided for emergency rescue.• A minimum of one ring buoy with 90 feet of 3/8-inch solid-braid polypropylene (or

equal) rope will be provided for emergency rescue.• Keep nonessential personnel 3 feet from edge of water• Safe means of boarding or leaving a boat or a platform will be provided to prevent

slipping and falling. Boat/barge must be equipped with adequate railing.instructions/warnings (e.g., protect from pinch points, sharp objects, rope

burns/entanglement).• Work requiring the use of a boat will take place only during daylight hours.• Work requiring the use of a boat will not take place during inclement weather.• The boat/barge must be operated according to U.S. Coast Guard regulations (speed,

lightning, right-of-way, etc.). Shut off engine before refueling; do not smoke whilerefueling.

Personnel are allowed to handle and/or sample drums containing investigation-derivedwaste (IDW) only; handling or sampling other drums requires a plan revision oramendment approved by the CH2M HILL HSM. The following control measures willbe taken when sampling drums containing BDW:

Minimize transportation of drums.Minimize number of people involved in the actual sampling.Sample only labeled drums or drums known to contain IDW.Use caution when sampling bulging or swollen drums. Relieve pressure slowly.If drums contain, or potentially contain, flammable materials, use nonsparking toolsto open.Picks, chisels, and firearms may not be used to open drums.Reseal bung holes or plugs whenever possible.Avoid mixing incompatible drum contents.Sample drums without leaning over the drum opening.If there is evidence of contamination on the lid of the drum, cover the lid withplastic sheeting.Transfer the content of drums using a method that minimizes contact with material.Air monitoring and PPE requirements specified in sections 5 and 6 must addressdrum sampling.

• Spill-containment procedures specified in Section 8 must be appropriate for thematerial to be handled.

- TestPirand

Excavation

Drilling, Geoprobe"Installation, Wen

Installation andAbandonment


Aquifer Testing, and~Video Surveying of

Wells

-

''

Surface Waterand Sediment""


-

Surface Water andSediment Samplingfrom the Shore or

WaterHand

Angering

..

Surveying

-


Disposal*

X

i

Observation ofLoading of

Material forOffsite Disposal


Oversight

3.4 BIOLOGICAL HAZARDS AND CONTROLS

Hazard and Location Control Measures

Snakes typically are found in underbrushand tall grassy areas.

If you encounter a snake, stay calm and look around; there may beother snakes. Turn around and walk away on the same path you usedto approach the area. If a person is bitten by a snake, wash andimmobilize the injured area, keeping it lower than the heart ifpossible. Seek medical attention immediately. DO NOT apply ice,cut the wound, or apply a tourniquet. Carry the victim or havehim/her walk slowly if the victim must be moved. Try to identify thetype of snake: note color, size, patterns, and markings.

Poison ivy, poison oak, and poisonsumac typically are found in brush orwooded areas. They are more commonlyfound in moist areas or along the edges ofwooded areas.

Become familiar with the identity of these plants. Wear protectiveclothing that covers exposed skin and clothes. Avoid contact withplants and the outside of protective clothing. If skin contacts a plant,wash the area with soap and water immediately. If the reaction issevere or worsens, seek medical attention.

Exposure to bloodborne pathogens mayoccur when rendering first aid or CPR, orwhen coming into contact with medical orother potentially infectious material, orwhen coming into contact with landfillwaste or waste streams containing suchinfectious material.

Training is required before a task involving potential exposure isperformed. Exposure controls and personal protective equipment(PPE) are required as specified in CH2M fflLL SOP HS-36,Bloodborne Pathogens. Hepatitis B vaccination must be offeredbefore the person peirticipates in a task where exposure is apossibility.

Bees and other stinging insects may beencountered almost anywhere and maypresent a serious hazard, particularly topeople who are allergic.

Watch for and avoid nests. Keep exposed skin to a minimum. Carrya kit if you have had allergic reactions in the past, and inform the SSCand/or the buddy. If a stinger is present, remove it carefully withtweezers. Wash and disinfect the wound, cover it, and apply ice.Watch for allergic reaction; seek medical attention if a reactiondevelops.

Other Potential Biological Hazards: None anticipated

10

3.5 TICK BITES (Reference CH2M HILL HS-03, Tick Bites)

Ticks typically are in wooded areas, bushes, tall grass, and brush. Ticks are black, black and red, or brownand can be up to one-quarter inch in size.

Prevention against tick bites includes avoiding tick areas; wearing tightly woven light-colored clothing withlong sleeves and wearing pant legs tucked into boots or socks; spraying only outside of clothing with insectrepellent containing permethrin or permanone, and spraying skin with DEET; and checking yourselffrequently for ticks and showering as soon as possible. To prevent chemical repellents from interfering withsample analyses, exercise care while using repellents during the collection and handling of environmentalsamples.

If bitten by a tick, carefully remove the tick with tweezers, grasping the tick as close as possible to the pointof attachment while being careful not to crush the tick. After removing the tick, wash your hands anddisinfect and press the bite area. The removed tick should be saved. Report the bite to human resourcespersonnel.

Look for symptoms of Lyme disease or Rocky Mountain spotted fever (RMSF). Lyme: a rash that lookslike a bullseye with a small welt in the center. RMSF: a rash of red spots under the skin 3 to 10 days afterthe tick bite. In both cases, chills, fever, headache, fatigue, stiff neck, bone pain may develop. If symptomsappear, seek medical attention.

3.6 RADIOLOGICAL HAZARDS AND CONTROLS

Refer to CH2M HILL'S Corporate Health and Safety Program, Program and Training Manual, and CorporateHealth and Safety Program, Radiation Protection Program Manual, for standards of practice for operating incontaminated areas.

Hazards Controls

None Known None Required


3.7 HAZARDS POSED BY CHEMICALS BROUGHT ON THE SITE

3.7.1 HAZARD COMMUNICATION(Reference CH2M HILL Hazard Communication Manual and Section 5 of the Site Safety Notebook)

CH2M HILL'S Hazard Communication Program Manual, which is available from area or regional offices and fromthe Corporate Human Resources Department in Denver. The project manager is to request Material Safety DataSheets (MSDSs) from the client or from the contractors and the subcontractors for chemicals to which CH2M HILLemployees potentially are exposed. The SSC is to do the following:• Give employees required site-specific HAZCOM training.• Confirm that the inventory of chemicals brought on the site by subcontractors is available.• Before or as the chemicals arrive on the site, obtain an MSDS for each hazardous chemical.• Label chemical containers with the identity of the chemical and with hazard warnings, if any.

The chemical products listed below will be used on the site. Refer to Attachment 2 for MSDSs.

Chemical Quantity Location

Methane (calibration gas)

Isobutylene (calibration gas)

Pentane (calibration gas)

Hydrochloric Acid (sample preservative)

Nitric Acid (sample preservative)

Sulfuric Acid (sample preservative)

Sodium Hydroxide (sample preservative)

Methanol (decontamination solvent)

Hexane (decontamination solvent)

Isopropanol (decontamination solvent)

pH Buffers (calibration standard)

MSA Sanitizer (respirator cleaner)

Alconox/Liquinox (detergent)

1 liter, compressed gas



< 500 ml

<500ml

< 500 ml

< 500 ml

< 1 gallon

< 1 gallon

< 1 gallon

< 500 ml

< 1 liter, powder

< 1 liter, powder/liquid

Support Zone

Support Zone

Support Zone

Support/Exclusion Zone




Support/Decontamination Zone



Support Zone



3.7.2 SHIPPING AND TRANSPORTATION OF CHEMICAL PRODUCTS(Reference CH2M HILL'S Procedures for Shipping and Transporting Dangerous Goods)

Nearly all chemicals brought to the site are considered hazardous materials by the U.S. Department ofTransportation (DOT). All staff who ship the materials or transport them by road must receive the CH2M HILLtraining in shipping dangerous goods. All hazardous materials that are shipped (e.g., via Federal Express) or aretransported by road must be properly identified, labeled, packed, and documented by trained staff. Contact the HSMor the Equipment Coordinator for additional information.


3.8 CONTAMINANTS OF CONCERN (REFER TO PROJECT FILES FOR MORE-DETAILED CONTAMINANT INFORMATION)

Contaminant

Arsenic

Benzene

2-Butanone (Methyl Bthyl Ketone, MEK)

Cadmium

Carbon Tetrachloride

Chlordane

Chlorobenzene

Chloroform

Chromium (as Cr(H) & Cr (III))

Chromium (hexavalent)

Location and Highest"Concentration (ppb)

OW: 5.4SB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:49.6SB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:4.9SB:ss:

GW;24SB:SS:

GW:NASB:SS;

ExposureLimit''

0.01 mg/m'

1 ppm

200 ppm

0.005 mg/m'

2 ppm

0.5 mg/m3

10 ppm

2 ppm

0.5 mg/m'

0.05 mg/m'

iDLir5

Ca

500

Ca

3,000

9

Ca

200

Ca

100

Ca

1,000

500

Ca

25

15

Ca

Symptoms and Effects of Exposure

Ulceration of nasal septum, respiratory irritation; dermatitis; gastrointestinaldisturbances; peripheral neuropathy, hyperpigmentation

Eye, nose, skin, and respiratory irritation; headache; nausea; dermatitis;fatigue; giddiness; staggered gait; bone marrow depression

Eye, skin, and nose irritation: headache, dizziness; vomiting, dermatitis

Pulmonary edema, coughing, chest tightness/pain, headache; chills, muscleaches, nausea, vomiting, diarrhea; difficulty breathing; loss of sense of smell;emphysema; mild anemia

Central nervous system (CNS) depression; nausea; vomiting; eye and skinirritation; liver and kidney injury; drowsiness; dizziness

Blurred vision, confusion, ataxia, delirium, coughing, abdominal pain, nausea,vomiting, diarrhea, irrilabiiity, tremors, ariuria

Skin, eye, and nose irritation; drowsiness; uncoordination; CNS depression

Dizziness, mental dullness, nausea, confusion, disorientation, headache,fatigue, eye and skin irritation, anesthesia, enlarged liver

Irritated eyes, sensitization dermatitis, histologic fibrosis of lungs

Irritated respiratory system; nasal septum perforation; liver and kidneydamage; leucytosis; leupen; monocytosis; eosinophilla; eye injury,conjuctivitis; skin ulcer; sensitization dermatitis

PIP4

(eV)

NA

9.24

9.54

NA

11.47

UK

9.07

11.42

NA

NA

000064 13DPW\P:\151498\SAP\PERRYTONWELLHSP.DOC

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Contaminant

Cobalt (Metal, Dusts, and Fumes)

DDT

o-Dichlorobenzene (1,2-Dichlorobenzene)

p-Dichlorobenzene (1,4-Dichlorobenzene)

1,1-Dichloroethane

1,2-Dichloroethane (Ethylene Dichloride)

Endosulfan

Ethyl Benzene

Lead

Mercury


GW:NDSB:SS:

GW:NDSB:SS:

GW:NASB:SS:

GW:NASB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:60.9SB:SS:

GW:NDSB:SS:

ExposureLimit''

0.05 mg/m'

0.5 mg/m'

25 ppm

lOppm

100 ppm

1 ppm

0,1 mg/m'

100 ppm

0.05 mg/m'

0.05 mg/m'

IDLH1

20

500

Ca

200

Ca

150

Ca

3,000

50

Ca

NL

800

100

10


Coughing; difficulty breathing; wheezing; decreased pulmonary function;diffuse nodule fibrosous; dermatitis; respiratory hypersensitivity; asthma

Paresthesia of tongue, lips, hand, and face; tremors; dizziness; confusion;headache; fatigue; convulsions; eye and skin irritation; vomiting

Nose and eye irritation; liver and kidney damage; skin blisters

Headache, eye irritation, nausea, vomiting; swelling periorbital; profuserhinitis; jaundice; cirrhosis

CNS depression, skin irritation; liver, kidney, and lung damage

CNS depression; nausea; vomiting; dermatitis; eye irritation; liver, kidney, andCNS damage; cornea! opacity

Irritated skin, nausea, confusion, agitation, flushing, dry mouth, tremor,convulsion, headache

Eye, skin, and mucous membrane irritation; headache; dermatitis; narcotic;coma

Weakness, lassitude; facial pallor; pal eye; weight loss, malnutrition;abdominal pain, constipation; anemia; gingival lead line; tremors; paralysis ofwrist and ankles; encephalopathy; kidney disease; irritated eyes; hypotension

Skin and eye irritation, cough, chest pain, difficult breathing, bronchitis,pneumontitis, tremors, insomnia, irritability, indecision, headache, fatigue,weakness, GI disturbance

PIP4

(eV)

NA

UK

9.06

8.98

11.06

11.05

UK

8.76

NA

NA

000065 14

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Contaminant

Naphthalene

PCBs

PNAs (Limits as Coal Tar Pitch)

1,1,2,2-Tetrachloroethane(Tetrachloroethane)

Tetrachloroethene

1,1,2-Trichloroethane

Trichloroethylene

Toluene

Xylenes

Vinyl Chloride


OW:NASB:SS:

OW;NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:NDSB:SS:

GW:ND

SB:

SS:

GW:NDSB:SS:

ExposureLimit"

lOppm

0.5 nig/in'

0.2 mg/m'

Ippni

25 ppm

lOppm

25 ppm

50 ppm

100 ppm

Ippm

IDLH°

250

5

Ca

80

Ca

100

Ca

150

Ca

100

Ca

1,000

Ca

500

900

NL

Ca


Eye irritation, headache, confusion, excitement, nausea, vomiting, abdominalpain, bladder irritation, profuse sweating, dermatitis, comeal damage, opticalneuritis

Eye and skin irritation, acne-form dermatitis, liver damage, reproductiveeffects

Dermatitis, bronchitis

Nausea, vomiting, abdominal pain, finger tremors, jaundice, hepatitis, livertenderness, monocytosis, kidney damage, dermatitis

Eye, nose, and throat irritation; nausea; flushed face and neck; vertigo;dizziness; sleepiness; skin redness; headache; liver damage

Eye and nose irritation, CNS depression, liver damage, dermatitis

Headache, vertigo, visual disturbance, eye and skin irritation, fatigue,giddiness, tremors, sleepiness, nausea, vomiting, dermatitis, cardiacarrhythmia, paresthesia, liver injury

Eye and nose irritation, fatigue, weakness, confusion, dizziness, headache,dilated pupils, excessive tearing, nervousness, muscle fatigue, paresthesia,dermatitis, liver and kidney damage

Irritated eyes, skin, nose, throat; dizziness; excitement; drowsiness;incoherence; staggering gait; comeal vacuolization; anorexia; nausea;vomiting; abdominal pain; dermatitis

Weakness, abdominal pain, gastrointestinal bleeding, enlarged liver, pallor orcyanosis of extremities

PIP4

(eV)

8.12

UK

UK

11.10

9.32

11.00

9.45

8.82

8.56

9.99

000066DFW\P:\151498\SAP\PERRYTONWELLHSP.DOC

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15

3.8 CONTAMINANTS OF CONCERN (REFER TO PROJECT FILES FOR MORE-DETAILED CONTAMINANT INFORMATION)3.8 CONTAMINANTS OF CONCERN (REFER TO PROJECT FILES FOR MORE-DETAILED CONTAMINANT INFORMATION)

Contaminant

Vinylidene Chloride(1,1 -dichloroethylene)

Footnotes:

a: Specify sample-designation and media: SB (Soil Boring), A (Air), D (Drums), OW (Oroundwater), L (Lagoon), TK (Tank), SS (Surface Soil), SL (Sludge), SW (Surface Water),b: Appropriate value of PEL, REL, or TLV listedc: IDLH = immediately dangerous to life and health (units are the same as specified "Exposure Limit" units for that contaminant); NL = No limit found in reference materials; CA = Potential

occupational carcinogend: PIP = pholoionization potential; N A = Not applicable; UK = Uknown


GW:NDSB:SS;

ExposureLimit''

Ippm

IDLH°

NL

Ca


Eye, skin, and throat irritation; dizziness; headache; nausea; difficultbreathing; liver and kidney dysfunction; pneumonitis

PIP4

(eV)

UK

3.9 POTENTIAL ROUTES OF EXPOSURE

DERMAL; Contact with contaminated media. This routeof exposure is minimized through proper use of PPE, asspecified in Section 5.

INHALATION: Vapors and contaminated particulates.This route of exposure is minimized through properrespiratory protection and monitoring, as specified insections 5 and 6, respectively.

OTHER; Inadvertent ingestion of contaminated media. This route should notpresent a concern if good hygiene practices are followed (e.g., wash hands and facebefore eating, drinking, or smoking).

DFWP:\151498\SAP\PERRYTONWELLHSP.DOC 16000067

Footnotes:

a: Specify sample-designation and media: SB (Soil Boring), A (Air), D (Drums), OW (Oroundwater), L (Lagoon), TK (Tank), SS (Surface Soil), SL (Sludge), SW (Surface Water),b: Appropriate value of PEL, REL, or TLV listedc: IDLH = immediately dangerous to life and health (units are the same as specified "Exposure Limit" units for that contaminant); NL = No limit found in reference materials; CA = Potential

occupational carcinogend: PIP = pholoionization potential; N A = Not applicable; UK = Uknown

4 PERSONNEL

4.1 CH2M HILL EMPLOYEE MEDICAL SURVEILLANCE AND TRAINING(Reference CH2M HILL SOP HS-01, Medical Surveillance, and HS-02, Health anil Safety Training)

The employees listed below are enrolled in the CH2M HILL Comprehensive Health and Safety Program and meet state and federalhazardous waste operations requirements for 40-hour initial training, 3-day on-the-job experience, and 8-hour annual refreshertraining. Employees designated "SSC" have received 8 hours of supervisor and instrument training and can serve as site safetycoordinator (SSC) for the level of protection indicated. An SSC with a level designation (D, C, B) equal to or greater than the levelof protection being used must be present during all tasks performed in exclusion or decontamination zones that involve thepotential for exposure to health and safety hazards. Employees designated "FA-CPR" are currently certified by the American RedCross, or equivalent, in first aid and CPR. At least one FA-CPR designated employee must be present during all tasks performedin exclusion or decontamination zones that involve the potential for exposure to health and safety hazards. The employees listedbelow are currendy active in a medical surveillance program that meets state and federal regulatory requirements for hazardouswaste operations. Certain tasks (e.g., confined-space entry) and contaminants (e.g., lead) may require additional training andmedical monitoring.

Pregnant employees are to be informed of and are to follow the procedures in CH2M HILL'S SOP HS-04, ReproductionProtection, includingobtaining a physician's statement of the employee's ability to perform hazardous activities, before being assigned fieldwork.

Employee Name Office Responsibility SSC/FA-CPR

Peter Van Noort DFW Project Manager Level D SSC; FA-CPR

Katie Swanson DFW Project Staff Level D SSC; FA-CPR

TomPalaia DEN Project Staff Level C SSC; FA-CPR

4.2 FIELD TEAM CHAIN OF COMMAND AND COMMUNICATION PROCEDURES

4.2.1 CLIENT

Contact Name: Vincent MalottPhone:(214)665-8313Facility Contact Name: David Landis, Perryton City ManagerPhone: (806)435-4014


4.2.2 CH2M HELL

Project Manager: Peter Van NoortHealth and Safety Manager: Angelo LiberatoreField Team Leader: To be determinedSite Safety Coordinator: To be determined

The SSC is responsible for contacting the field team leader and the project manager. In general, the projectmanager either will contact or will identify the client contact. The Health and Safety Manager (HSM)should be contacted as appropriate. The SSC or the project manager must notify the client and the HSMwhen a serious injury or a death occurs or when health and safety inspections by OSHA or other agencies areconducted. Refer to sections 10 through 12 for emergency procedures and phone numbers.

4.2.3 SUBCONTRACTORS(Reference Section 3, Corporate Health and Safety Program Manual)

When specified in the project documents (e.g., contract), this plan may cover CH2M HILL subcontractors.However, this plan does not address hazards associated with tasks and equipment that the subcontractor hasexpertise in (e.g., operation of drill rig). Specialty subcontractors are responsible for health and safetyprocedures and plans specific to their work. Specialty subcontractors are to submit plans to CH2M HILL forreview and approval before the start of fieldwork. Subcontractors must comply with the established healthand safety plan(s). CH2M HILL must monitor and enforce compliance with the established plan(s).

SubcontractorNASubcontractor Contact:Telephone:

General health and safety communication with subcontractors contracted with CH2M HILL and covered bythis plan is to be conducted as follows:

• Request that the subcontractor, if a specialty subcontractor, submit a safety or health plan applicable totheir expertise (e.g., drill-rig safety plan or nuclear density gauge [NDG] health plan); attach thereviewed plan.

• Supply subcontractors with a copy of this plan, and brief them on its provisions.

• Direct health and safety communication to the subcontractor-designated safety representative.

• Notify the subcontractor-designated representative if a violation of the plan(s) is observed. Specialtysubcontractors are responsible for mitigating hazards in which they have expertise.

• If a hazard condition persists, inform the subcontractor. If the hazard is not mitigated, stop affectedwork as a last resort and notify the project manager.

• When an apparent imminent danger exists, promptly remove all affected personnel. Notify the projectmanager.

• Make clear that consistent violations of the health and safety plan by a subcontractor may result intermination of the subcontract.


4.2.4 CONTRACTORS(Reference Section 3, Corporate Health and Safety Program Mama!)

This plan does not cover contractors that are contracted directly to the client or the owner. CH2M HILL is notresponsible for directing contractor personnel and is not to assume responsibility through their actions. When thecontractor is in control of the site, ask the contractor to conduct a briefing of their health and safety practices and todescribe how they apply to CH2M HILL'S activities. Request a copy of the contractor's health and safety plan.

ContractorNAContact Name:Telephone:

General health and safety communication with contractors not contracted with CH2M HILL is listed below.These procedures can also be applied to other third party communications (e.g., client personnel).

• Ask the contractor to brief CH2M HILL on the contractor's health and safety plan for how the planaffects CH2M HILL employees on the site.

• If acceptable to the client, communicate about health and safety directly with the contractor PM orother onsite contractor-designated representative. CH2M HILL employees are not to direct thedetails of the contractor's work or to advise on health and safety (e.g., how the contractor correctsunsafe conditions).

• If an observed hazard poses a risk to CH2M HELL personnel, notify the party controlling the workactivity as soon as possible. Notify the project manager; the project manager will notify the client.Document oral notification in project records (i.e., the field logbook).

• If a hazardous condition endangering a CH2M HILL employee persists, inform the contractor andthe project manager (the project manager will contact the client) that CH2M HILL cannot executethe assigned work until the hazard is mitigated.

• When an apparent imminent danger exists, orally warn the person(s) in danger and orally notify thecontractor promptly. When an imminent danger involves a CH2M HILL employee, remove theemployee and suspend CH2M HILL work immediately until the hazard has been mitigated. Informthe project manager and the contractor promptly.

• The SSC or the project manager must notify the client and CH2M HILL health and safety staff when(1) the contractor fails to remedy an unsafe condition affecting CH2M HILL personnel, (2) thecontractor does not remedy the hazardous condition within a reasonable period of time, or (3) thecontractor repeatedly creates the hazardous condition.


5 PERSONAL PROTECTIVE EQUIPMENT (PPE) (Reference CH2M HILL SOP HS-07, Personal ProtectiveEquipment, HS-08, Respiratory Protection, Section 2 of the Site Safety Notebook)

5.1 PPE SPECIFICATIONS'

Task

General work uniform when nochemical exposure is anticipated

Groundwater Sampling; EDWsampling and disposal

Level

D

Modified D

Body

Work clothes; steel-toe, steel-shank leatherwork boots; work gloves

COVERALLS: Uncoated Tyvek®BOOTS: Steel-toe, steel-shank chemical-resistant boots OR steel-toe, steel-shankleather work boots with outer rubber bootcoversGLOVES: Inner surgical-style nitrile glove.

Head

Hardhat'Safety glassesEar protection'1

Hardhat'Splash shield'Safety glassesEar protection'1

Respirator

None required

None required

b

Groundwater Sampling; IDW sampling and disposal' Modifications are as indicated. CH2M HILL will provide PPE to only CH2M HILLemployees." No facial hair that would interfere with respirator fit is permitted.° Hardhat and splash-shield areas are to determined by she SSC.' Ear protection should be worn while working around drill rigs or other noise-producing equipment or when conversations cannot be held atdistances of 3 feet or less without shouting. Refer to Section 6 for other requirements.

The GME-H cartridge is the new standard-issue cartridge. Available stock of the previously standard GMC-H cartridges may be used for taskscovered by this plan.

5.2 REASONS FOR UPGRADING OR DOWNGRADING LEVEL OF PROTECTION

Upgrade* Downgrade

Request from individual performing task.Change in work task that will increase contact orpotential contact with hazardous materials.Occurrence or likely occurrence of gas or vaporemission.Known or suspected presence of dermal hazards.Instrument action levels (Section 6) exceeded.

New information indicating thatsituation is less hazardous thanoriginally thought.Change in site conditions that decreasesthe hazard.Change in work task that will reducecontact with hazardous materials.

*Perfbrming a task that requires an upgrade to a higher level of protection (e.g., level D to level C) is permittedonly when the PPE requirements have been specified in Section 5 and an SSC who meets the requirementsspecified in subsection 4.1 is present.

20

6 AIR MONITORING SPECIFICATIONS (Reference CH2M HILL SOP HS-06, Air Monitoring, and Section 2 of the :_Site Safety Notebook) ^ gp

Instrument Tasks Action Levels' Frequency1' Calibration <^)

Note : Well monitoring procedures involve sampling water from a tap and directing water to a closed sewer § i.;,system. Given the low volatility/concentration of carbon tetrachloride at 60 ppb in water and the lowconcentration of chloroform at 2 ppb in water, the potential for personnel exposure is remote. Personnelmonitoring procedures are not required to be performed. .


6.1 CALIBRATION SPECIFICATIONS(Refer to the respective manufacturer's instructions for proper instrument-maintenance procedures)

Instrument

PID: HNU, 10.2 eV probe

HNU.11.7eV probe

Pro: OVM, 10.0 or 10.6eV bulb

OVM, 11.8 eV bulb

Fro: OVA-128

FTO: TVA 1000

6.2 AIR SAMPLINGSampling may be required by other OSHA regulations where there may be exposure to certain contaminants. Airsampling typically is required when site contaminants include lead, cadmium, arsenic, asbestos, and certain volatileorganic compounds. Contact the HSM immediately if these contaminants are encountered.

Gas

100 ppmisobutylene

100 ppmisobutylene

100 ppm methane

100 ppm methane

Span

9.8 ±2.0

5.0 ±2.0

RF=0.55

RF=0.68

3.0 ±1.5

CF=1.00

Reading

55 ppm

68 ppm

55 ppm

68 ppm

100 ppm

100 ppm ± 10

Method

1.51pmregT-tubing

OR0.25 1pm regdirect tubing

1.51pmregT-tubing

1.51pm regT-tubing

1.51pm regT-tubing

Method Description: Not Applicable

Personnel and Areas

Results must be sent immediately to the HSM. Regulations may require reporting to monitored personnel. Resultsreported to:

HSM: Angelo Liberatore/ATLOther:

7 DECONTAMINATION (REFERENCE cn2M HILL SOP ns-ia. DECONTAMINATION

The SSC must monitor the effectiveness of the decontamination procedures. Decontamination procedures found tobe ineffective will be modified by the SSC.

7.1 DECONTAMINATION SPECIFICATIONS

Personnel

• Boot wash/rinse •

• Glove wash/rinse •

• Outer-glove removal •

• Body-suit removal NA

• Inner-glove removal

• Respirator removal

• Hand wash/rinse

• Face wash/rinse

• Shower ASAP

• PPE-disposal method:Municipal waste stream

• Water-disposal method:Sanitary sewer

Sample Equipment

Wash/rinse equipment

Solvent-rinse equipment

Solvent-disposal method:

Heavy Equipment

Power wash

Steam clean

Water-disposal method:

NA

7.2 DIAGRAM OF PERSONNEL-DECONTAMINATION LINE

No eating, drinking, or smoking is permitted in contaminated areas and in exclusion or decontamination zones. TheSSC should establish areas for eating, drinking, and smoking. Contact lenses are not permitted in exclusion ordecontamination zones.

Figure 7-1 illustrates a typical establishment of work zones, including the decontamination line. Work zones areto be modified by the SSC to accommodate task-specific requirements.

8 SPELL-CONTAINMENT PROCEDURES

Sorbent material will be maintained in the support zone. Incidental spills will be contained with sorbent andwill be disposed of properly.

9 CONFINED-SPACE ENTRY(Reference CH2M HILL SOP HS-17, Confined Space Entry)

No confined-space entry will be permitted. Confined-space entry requires additional health and safetyprocedures, training, and a permit. If conditions change such that confined-space entry is necessary, contact theHSM to develop the required entry permit.

When planned activities will not include confined-space entry, permit-required confined spaces accessible toCH2M HILL personnel are to be identified before the task begins. The SSC is to confirm that permit spaces areproperly posted or that employees are informed of their locations and informed of their hazards.


•\

«

•

*«

\•

»Êxclusion .

Zone *.Boundary \

•

i

Equipment drop m,onto clean ||

surface |

Samplepreparation —>

San

1 ——••

1•

1 PP••

1••

1R•

1

••

1«

•

, 1 . .. .....••

1

nple Tat

i•

PP

Eto

3le

Dispose of PPE asspecified in Sectio

7.1 of the HSP

be re-u

Ssdecent

and

disposed

Return to | exclusion zone | "^—

sed

y

Outer glove, bocand coverall

(e.g., Tyvek®)<, wash

ampleaminationpacking

Notes:„„. , 1. This figure can be used as a guide in esta

n

-^

\

D

/•

cr

Y

^0

^

rectlon or re-used, and can be applied to any level o2. This stations illustrated below may be rem

0applicable (e.g., no respirator station if not w

~~^~- 3. The SSC may modify the decontaminatioron site-specific conditions.

r 'Y r ^\Remove outer | Remove coveralls |

gloves and boots or 1—————————^> (e.g., Tyvek®) |boot covers • 1 and inner gloves •

t \"

Change out respirator | F „ A nr> ârtridges or air tank. lf| lf worn.remove APR or |emoved, replace outer | SCBA- '^P0ôf L

boots and gloves. J cartridges and decon |-<

-L-. ,———i r-ûter glove, bootj Remove outer boots| Remove inner |and coverall B >. gloves, and |- gloves and |

rinse | coveralls | coveralls |

Dispose of PPE as ( ^specified in Section — \^ ^

7.1 of the HSP —— ^^

Figure 7-1Personnel DecontamiCH2M HILL Heath an

blist-eithefproloveearinnsec

J«•

^

•

•

•

•

•

•

•

s

ling aer disposed of,tection.d when notg Level C).quence based

/•""4•

«*••*•

^ \Wash face and |hands. Shower|

as soon as S^ possible. J|

upport zone

nation Lined Safety Plan

DFW\P:\151498\SAP\PERRYTONWELLHSP.DOC 24 000075

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10 SITE-CONTROL PLAN

10.1 SITE-CONTROL PROCEDURES

The site safety coordinator (SSC) will conduct a site safety briefing (see below) before starting fieldactivities or as tasks and site conditions change.

Topics for briefing on site safety: general discussion of health and safety plan, site-specific hazards,locations of work zones, PPE requirements, equipment, special procedures, emergencies. Refer toSection 8 of Site Safety Notebook.

The SSC records attendance at safety briefings in a logbook and documents the topics discussed.

Post the OSHA job-site poster in a central and conspicuous location at sites where project field offices,trailers, or equipment storage boxes are established. Posters can be obtained by calling either 800/548-4776 or 800/999-9111.

Field Trailers: Post "Exit" signs above exit doors, and post "Fire Extinguisher" signs above locations ofextinguishers. Keep areas near exits and extinguishers clear.

Determine wind direction.

Establish work zones: support, decontamination, and exclusion zones. Delineate work zones with flagsor cones as appropriate. Support zone should be upwind of the site.

Establish decontamination procedures, including respirator-decontamination procedures, and test theprocedures.

Use access control at the entry and exit from each work zone.

Store chemicals in appropriate containers.

Make MSDSs available for onsite chemicals to which employees are exposed.

Establish onsite communication consisting of the following:

Line-of-sight and hand signalsAir hornTwo-way radio or cellular telephone if available

Establish offsite communication.

Establish and maintain the "buddy system."

Establish procedures for disposing of material generated on the site.

Initial air monitoring is conducted by the SSC in appropriate level of protection.

The SSC is to conduct periodic inspections of work practices to determine the effectiveness of this plan -refer to CH2M HILL SOP 18, Health and Safety Checklist, or Section 4 of Site Safety Notebook.Deficiencies are to be noted, reported to the HSM, and corrected.


10.2 HAZWOPER COMPLIANCE PLAN (Reference CH2M HILL SOP HS.17.ffro/rA and Safety- Plans)

This section outlines procedures to be followed when certain activities do not require 24- or 40-hour training.Note, prior approval from the HSM is required before these tasks are conducted on regulated hazardous wastesites.

• Certain parts of the site work may be covered by state or federal Hazwoper standards and therefore requiretraining and medical monitoring. Anticipated tasks must be included in subsection 2.2.1.

• Air sampling must confirm that there is no exposure to gases or vapors before non-Hazwoper-trainedpersonnel are allowed on the site. Other data (e.g., soil) also must document that there is no potential forexposure. The HSM must approve the interpretation of these data. Refer to subsections 3.8 and 6.2 forcontaminant data and air sampling requirements, respectively.

• Non-Hazwoper-trained personnel must be informed of the nature of the existing contamination and itslocations, the limits of their access, and the emergency action plan for the site. Non-Hazwoper-trainedpersonnel also must be trained in accordance with all other state and federal OSHA requirements, including29 CFR 1910.1200 (HAZCOM). Refer to subsection 3.7.1 for hazard communication requirements.

• Air monitoring with direct-reading instruments conducted during regulated tasks also should be used toensure that non-Hazwoper-trained personnel (e.g., in an adjacent area) are not exposed to volatilecontaminants. Non-Hazwoper-trained personnel should be monitored whenever the belief is that there maybe a possibility of exposure (e.g., change in site conditions), or at some reasonable frequency to confirm thatthere is no exposure. Refer to Section 6.1 for air monitoring requirements.

• Treatment system start-ups: Once a treatment system begins to pump and treat contaminated media, the siteis, for the purposes of applying the Hazwoper standard, considered a treatment, storage, and disposal facility(TSDF). Therefore, once the system begins operation, only Hazwoper-trained personnel (minimum of24 hours of training) will be permitted to enter the site. All non-Hazwoper-trained personnel must leave thesite.

If Hazwoper-regulated tasks are conducted concurrently with nonregulated tasks, non-Hazwoper-trainedsubcontractors must be removed from areas of exposure. If non-Hazwoper-trained personnel remain on the sitewhile a Hazwoper-regulated task is conducted, the contaminant/exposure area (exclusion zone) must be posted,non-Hazwoper-trained personnel must be reminded of the locations of restricted areas and the limits of theiraccess, and real-time monitoring must be conducted. Non-Hazwoper-trained personnel at risk of exposure mustbe removed from the site until it can be demonstrated that there is no longer a potential for exposure to health andsafety hazards.


11 EMERGENCY RESPONSE PLAN (REFERENCE OUM HILL sop HS-IZ, EMERGENCY KESPOWE)

11.1 PRE-EMERGENCY PLANNING

The SSC performs the applicable pre-emergency planning tasks before starting field activities andcoordinates emergency response with the facility and local emergency-service providers as appropriate.

Review the facility emergency and contingency plans where applicable.

Locate the nearest telephone; determine what onsite communication equipment is available (e.g., two-way radio, air hom).

Identify and communicate chemical, safety, radiological, and biological hazards.

Confirm and post emergency telephone numbers, evacuation routes, assembly areas, and route tohospital; communicate the information to onsite personnel.

Post site map marked with locations of emergency equipment and supplies, and post OSHA job-siteposter. The OSHA job-site poster is required at sites where project field offices, trailers, or equipment-storage boxes are established. Posters can be obtained by calling either 800/548-4776 or 800/999-9111.

Field Trailers: Post "Exit" signs above exit doors, and post "Fire Extinguisher" signs above locations ofextinguishers. Keep areas near exits and extinguishers clear.

Review changed site conditions, onsite operations, and personnel availability in relation to emergencyresponse procedures.

Evaluate capabilities of local response teams where applicable.

Where appropriate and acceptable to the client, inform emergency room and ambulance and emergencyresponse teams of anticipated types of site emergencies.

Designate one vehicle as the emergency vehicle; place hospital directions and map inside; keep keys inignition during field activities.

Inventory and check site emergency equipment, supplies, and potable water.

Communicate emergency procedures for personnel injury, exposures, fires, explosions, chemical andvapor releases.

Review notification procedures for contacting CH2M HILL'S medical consultant and team member'soccupational physician.

Rehearse the emergency response plan once before site activities begin, including driving the route to thehospital.

Brief new workers on the emergency response plan.

The SSC will evaluate emergency response actions and initiate appropriate follow-up actions.


11.2 EMERGENCY EQUIPMENT AND SUPPLIES

The SSC should mark the locations of emergency equipment on die site map and should post the map.

Emergency Equipment and Supplies Location

20 Ib (or two 10-lb) fire extinguisher (A, B, and C classes)

First aid kit

Eye wash

Potable water

Bloodbome-pathogen kit

Additional equipment (specify)

11.3 EMERGENCY MEDICAL TREATMENT

Notify appropriate emergency response authorities listed in sections 12 and 13 (e.g., 911).

During a time of no emergency, contact CH2M HILL'S medical consultant for advice and guidance onmedical treatment.

The SSC will assume charge during a medical emergency until the ambulance arrives or until the injuredperson is admitted to the emergency room.

Prevent further injury.

Initiate first aid and CPR where feasible.

Get medical attention immediately.

Perform decontamination where feasible; lifesaving and first aid or medical treatment take priority.

Notify the field team leader and the project manager of the injury.

Make certain that the injured person is accompanied to me emergency room.

Notify the health and safety manager.

Notify the injured person's human resources department within 24 hours.

Prepare an incident report — refer to CH2M HILL SOP 12, Emergency Response and First Aid, andSection 6 of Site Safety Notebook. Submit the report to the corporate director of health and safety and thecorporate human resources department (COR) within 48 hours.

When contacting the medical consultant, state that you are calling about a CH2M HILL matter, and giveyour name, your telephone number, the name of the injured person, the extent of the injury or exposure,and the name and location of the medical facility where Ihe injured person was taken.

11.4 NONEMERGENCY PROCEDURES

The procedures listed above may be applied to nonemergency incidents. Injuries and illnesses (includingoverexposure to contaminants) must be reported to Human Resources. If there is doubt about whether medicaltreatment is necessary, or if the injured person is reluctant to accept medical treatment, contact the CH2M HILLmedical consultant.

• When contacting the medical consultant, state that the situation is a CH2M HILL matter, and give yourname, your telephone number, the name of the injured pyson, the extent of the injury or exposure, andthe name and location of the medical facility where the injured person was taken.

• Follow these procedures as appropriate.


11.5 INCIDENT RESPONSE

In fires, explosions, or chemical releases, actions to be taken include the following:

• Shut down CH2M HILL operations and evacuate the immediate work area.• Account for personnel at the designated assembly area(s).• Notify appropriate response personnel.• Assess the need for site evacuation, and evacuate the site as warranted.

Instead of implementing a work-area evacuation, note that small fires or spills posing minimal safety or healthhazards may be controlled.

11.6 EVACUATION

Evacuation routes will be designated by the SSC before work begins.

Onsite and offsite assembly points will be designated before work begins.

Personnel will leave the exclusion zone and assemble at the onsite assembly point upon hearing theemergency signal for evacuation.

Personnel will assemble at the offsite point upon hearing the emergency signal for a site evacuation.

The SSC and a "buddy" will remain on the site after the site has been evacuated (if possible) to assistlocal responders and advise them of the nature and location of the incident.

The SSC accounts for all personnel in the onsite assembly zone.

A person designated by the SSC before work begins will account for personnel at the offsite assemblyarea.

The SSC will write up the incident as soon as possible after it occurs and will submit a report to thecorporate director of health and safety.

11.7 EVACUATION ROUTES AND ASSEMBLY POINTS

Refer to the site map in Section 1. Evacuation routes and assembly areas (and alternative routes andassembly areas) are specified on the site map.

11.8 EVACUATION SIGNALS

Signal Meaning

Grasping throat with handThumbs upGrasping buddy's wristContinuous sounding ofhomClient/Facility:

Emergency-help me.OK; understood.Leave area now.Emergency; leave site now.


12 EMERGENCY RESPONSE

12.1 EMERGENCY RESPONSE TELEPHONE NUMBERS

SITE ADDRESS: North Amherst Street, Perryton, Phone: NATexas Cellular Phone:

Police: Perryton Police Department

Fire: Perryton Fire Department

Ambulance: Perryton Fire Department

Water: City of Perryton

Gas: City of Perryton

Electric: SPS

Phome: 911* (verify)

Phonie: 911* (verify)

Phome: 911* (verify)

Phone: 806/435-4014

Phone: 806/435-4014

Phone: 806/378-2121

*When using a cellular phone outside the telephone's normal calling area, exercise caution in relying on the cellularphone to activate 911. When the caller is outside the normal calling area, the cellular service carrier should connectthe caller with emergency services in the area where the call originated, but this may not occur. Telephonenumbers of backup emergency services should be provided if a cellular phone is relied on to activate 911.

Hospital: Ochiltree General Hospital Phone: 806/ 435-3606Address: 3101 Garrett, Perryton, TX 79070

Route to Hospital: (Refer to Figure 12-1) Proceed east on Santa Fe to 83 (Main Street), go south on 83,turn left (east) on 32" Street. Ochiltree General Hospital is on the corner of 32nd and Garrett.

12.2 GOVERNMENT AGENCIES INVOLVED IN PROJECT

Federal Agency and Contact Name: U.S. Environmental Protection Agency, Vincent MalottPhone: (214) 665-8313

State Agency and Contact Name:Phone:

Local Agency and contact Name:Phone:

Contact the project manager. Generally, the project manager will contact relevant government agencies.


13 EMERGENCY CONTACTS

If an injury occurs, notify the injured person's personnel office as soon as possible after obtaining medical attentionfor the injured person. Notification MUST be made within 24 hours of the injury.

CH2M HILL Medical Consultant

Peter P. Greaney, M.D.WorkCare, Inc.

333 S. Anita Drive

Orange, CA 92868(800)455-6155This is a 24-hour coverage number. All after hour

(6a.rn.-6p.rn. Pacific are regular working hours) callswill be answered in 20 minutes

Occupational Physician (Regional or Local)

Concentra1345 Valwood Parkway, Suite 306Carrollton, TX 75006972/484-6435

Dr. Byron Niebruegge, M.D.

Corporate Director Health and Safety

Name: David Waite/SEAPhone: 206/453-5005

Site Safety Coordinator (SSC)

Name: Katie Swanson/DFWPhone: 972/980-2188

Medical and Training Administrator

Name: Cyndi CareVSEAPhone: 206/453-5005

Regional Manager

Name: Cliff Thompson/ATLPhone: 770/604-9182

Health and Safety Manager (HSM)

Name: Angelo Liberatore/ATLPhone: 770/604-9182 EXT. 592

Project Manager

Name: Peter Van Noort/DFWPhone: 972/980-2170

Radiation Health Manager (RHM)

Name: Frank Petelka/OROPhone: 615/483-9032 (H)615/482-8667

Regional Human Resources Department

Name: Mary Jo Jordan/GNVPhone: 352/335-5877

Client

Name: Vincent MalottPhone: 214/665-8313

Corporate Human Resources Department

Name: Julie Zimmerman/CORPhone: 303/771-0900

Federal Express Dangerous Goods ShippingPhone: 800/238-5355

CH2M HILL Emergency Number for ShippingDangerous GoodsPhone: 800/255-3924

Worker's Compensation and Auto Claims

Sterling Administration ServicesPhone: 800/420-8926 After hours 800/497-4566

Report fatalities AND report vehicular accidentsinvolving pedestrians, motorcycles, or more than twocars.

32

14 APPROVAL

This site-specific health and safety plan has been written for use by CH2M HELL only. CH2M HILL claims noresponsibility for its use by others unless that use has been specified and defined in project or contract documents.The plan is written for the specific site conditions, purposes, dates, and personnel specified and must be amended ifthose conditions change.

14.1 ORIGINAL PLAN

WRITTEN BY:Katie Swanson DATE: February, 1999

APPROVED BY: Angelo Liberatore DATE: February, 1999

14.2 REVISIONS

REVISIONS MADE BY: DATE:

REVISIONS TO PLAN:

REVISIONS APPROVED BY: DATE:

15 DISTRIBUTION

Name

Angelo Liberatore/ATL

Peter Van Noort/DFW

Field Team Leader/Field Team

Katie Swanson/DFW

Client

Office

Health and SafetyManager/Approver

NA

Responsibility

Project Manager

Site Safety Coordinator

Client Project manager

Number of Copies

1

1

1

16 ATTACHMENTS

Attachment 1: Employee SignoffAttachment 2: Applicable Material Safety Data Sheets


Attachment 1Employee Signoff


EMPLOYEE SIGNOFF

The employees listed below have been given a copy of this health and safety plan, have read and understoodit, and agree to abide by its provisions.

EMPLOYEE NAME EMPLOYEE SIGNATURE AND DATE

35

Attachment 2Material Safety Data Sheets


DUPONT E I AND - HYDROCHLORIC ACID SOLUTION - HYDROCHLORIC ACID,.. Page 1 of 4

DUPONT E I AND — HYDROCHLORIC ACID SOLUTION -.HYDROCHLORIC ACID, TECHNICALMATERIAL SAFETY DATA SHEET . . . " • • -NSN: 6810004261864Manufacturer's CAGE: 18873Part No. Indicator: APart Number/Trade Name: HYDROCHLORIC ACID SOLUTION

General Information

Item Name: HYDROCHLORIC ACID, TECHNICALCompany's Name: DU FONT E I DE NEMOURS AND CO INCCompany's Street: 1007 MARKET STREETCompany's P. 0. Box: 1635Company's City: WILMINGTONCompany's State: DECompany's Country: USCompany's Zip Code: 19899Company's Emerg Ph #: 800-441-3637/CHEMTREC 800-424-9300Company's Info Ph #: 800-441-7515/9442 OR 302-999-5072Record No. For Safety Entry: 002Tot Safety Entries This Stk#: 005Status: SEDate MSDS Prepared: 01NOV88Safety Data Review Date: 09NOV92Supply Item Manager: CXMSDS Preparer's Name: J . C . WATTSPreparer's Company: DU FONT CO, CHEMICALS AND PIGMENTS DEPT.Preparer's St Or P. 0. Box: CHESTNUT RUN PLAZA, P . O . BOX 80709Preparer's City: WILMINGTONPreparer's State: DEPreparer's Zip Code: 19880-0709MSDS Serial Number: BDYPXHazard Characteristic Code: ClUnit Of Issue: DRUnit Of Issue Container Qty: 15.0 GL

Ingredients/Identity Information

Proprietary: NOIngredient: HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III)Ingredient Sequence Number: 01Percent: 31.5 :NIOSH (RTECS) Number: MW4025000CAS Number: 7647-01-0OSHA PEL: C 5 PPMACGIH TLV: C 5 PPM; 9293Other Recommended Limit: NONE RECOMMENDED

Proprietary: NOIngredient: WATERIngredient Sequence Number: 02Percent: 6 8 . 5NIOSH (RTECS) Number: ZC0110000CAS Number: 7732-18-5OSHA PEL: NOT ESTABLISHEDACGIH TLV: NOT ESTABLISHEDOther Recommended Limit: NONE RECOMMENDED

Physical/Chemical Characteristics

Appearance And Odor: CLEAR LIQUID.Boiling Point: 183F.84CMelting Point: -51F,-46C

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Vapor Pressure (MM Hg/70 F ) : 33 MM HGVapor Density (Air=l): 1.3N/KSpecific Gravity: 1.16Decomposition Temperature: UNKNOWNEvaporation Rate And Ref: >1 (N-BUTYL ACETATE=1)Solubility In Water: 100%pH: <1Corrosion Rate (IPY): UNKNOWN

Fire and Explosion Hazard Data

Flash Point: WILL NOT BURNExtinguishing Media: USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.Special Fire Fighting Proc: WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND AFULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERSWITH WATER SPRAY.Unusual Fire And Expl Hazrds: NEUTRALIZE RUNOFF FORM FIRE CONTROL WITHLIME, SODA ASH, ETC. COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUSDECOMPOSITION PRODUCTS AND VAPORS.=======:=:========== :=;=;=== ========= ====== ======= =====================;=================:= ================

Reactivity Data

Stability: YESCond To Avoid (Stability) : HIGH HEAT, OPEN FLAMES AMD OTHER SOURCES OFIGNITION.Materials To Avoid: REACTS WITH MOST METALS, STRONG OXIDIZING AGENTS,CYANIDES, SULFIDES, AND WITH FORMALDEHYDE.Hazardous Decomp Products: HYDROGEN CHLORIDE (GAS); OR ON CONTACT WITHMETALS, HYDROGEN (EXPLOSION HAZARD).Hazardous Poly Occur: NOConditions To Avoid (Poly): NOT APPLICABLE

Health Hazard Data

LD50-LC50 Mixture: LD50 = 900 MG/KG ,- LC50 = 3124 PPM,1 HRRoute Of Entry - Inhalation: YESRoute Of Entry - Skin: YESRoute Of Entry - Ingestion: YESHealth Haz Acute And Chronic: PRODUCT IS CORROSIVE TO BODY TISSUES.TOXICITY IS BY CORROSIVITY IN ALL THREE ROUTES OF ENTRY. CAUSES BURNS ONCONTACT. CHRONIC CONTACT IN DILUTE FORM MAY CAUSE ULCERATION.Carcinogenicity - NTP: NOCarcinogen!city - IARC: NOCarcinogenicity - OSHA: NOExplanation Carcinogenicity: THIS PRODUCT IS NOT LISTED BY IARC, NTP, OROSHA AS A CARCINOGEN.IRRITATION/BURNS. INHALED: INTENSE RESPIRATORY IRRITATION, COUGHING SUCH THATINHALATION OF TOXIC QUANTITIES IS UNLIKELY UNLESS TRAPPED. CHRONICINHALATION MAY CAUSE ULCERATION. INGESTED:G/I IRRITATION, BURNS.Med Cond Aggravated By Exp: PERSONS WITH A HISTORY OF AILMENTS OR WITH APRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY BE AT INCREASEDRISK FROM EXPOSURE.Emergency/First Aid Proc: EYE: PLUSH WITH WATER 15 MIN. GET MEDICAL CARE.SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP & WATER. LAUNDER CLOTHINGBEFORE REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING. GET IMMEDIATEMEDICAL CARE. INGESTION: DO NOT INDUCE VOMITING. GIVE LIME WATER OR MILK OFMAGNESIA. GET IMMEDIATE MEDICAL CARE.

Precautions for Safe Handling and Use

Steps If Mati Released/Spill: USE APPROPRIATE PROTECTIVE EQUIPMENT &PROCEDURES. CONTAIN SPILL AND RECOVER LIQUID IF POSSIBLE. NEUTRALIZE.ADSORB OR OTHERWISE COLLECT.Neutralizing Agent: SODIUM BICARBONATE OR 50/50 MIX LIME & SODA ASH

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Waste Disposal Method: DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE ANDLOCAL ENVIRONMENTAL REGULATIONS. MFR SUGGESTS NEUTRALIZED SOLUTION MAY BEFLUSHED TO DRAIN.Precautions-Handling/Storing: KEEP CONTAINER TIGHTLY CLOSED. STORE INCORROSION-PROOF AREA. KEEP'CONTAINERS OUT OF SUN AND AWAY FROM HEAT.ISOLATE FROM INCOMPATIBLE MATERIALS.Other Precautions: ALWAYS LOOSEN CAPS SLOWLY AND CAREFULLY. 'EMPTY'CONTAINERS MAY CONTAIN RESIDUE OR VAPOR. TREAT THEM WITH THE RESPECT DUEPULL ONES. DO NOT CUT,WELD,ETC. ON THEM.

Control Measures

Respiratory Protection: RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USENIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR ACID DUST/MIST IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR 1910.134 FOR REGULATIONSPERTAINING TO RESPIRATOR USE.Ventilation: USE MECHANICAL (GENERAL) OR LOCAL EXHAUST VENTILATION TO MEETTLV REQUIREMENTS.Protective Gloves: RUBBER GLOVESEye Protection: SAFETY GOGGLES WITH OPTIONAL FACE SHIELDOther Protective Equipment: EYE WASH STATION AND SAFETY SHOWER. ACID SUITOR APRON WITH RUBBER BOOTS AS DICTATED BY TASK AT HAND.Work Hygienic Practices: OBSERVE GOOD CHEMICAL HYGIENE PRACTICES ANDRECOMMENDED PROCEDURES. AVOID ANY CONTACT IF POSSIBLE.Suppl. Safety & Health Data: NONE

Transportation Data

Trans Data Review Date: 85004DOT PSN Code: HJGDOT Proper Shipping Name: HYDROCHLORIC ACID, SOLUTIONDOT Class: 8DOT ID Number: UN1789DOT Pack Group: IIDOT Label: CORROSIVEIMO PSN Code: IEXIMO Proper Shipping Name: HYDROCHLORIC ACIDIMO Regulations Page Number: 8183 'IMO UN Number: 1789IMO UN Class: 8IMO Subsidiary Risk Label: -IATA PSN Code: NPGIATA UN ID Number: 1789IATA Proper Shipping Name: HYDROCHLORIC ACIDIATA UN Class: 8IATA Label: CORROSIVEAFI PSN Code: NPGAPI Symbols: TAFI Prop. Shipping Name: HYDROCHLORIC ACID, SOLUTIONAFI Class: 8AFI ID Number: UN1789AFI Pack Group: IIAFI Special Prov: A3,A6,N41AFI Basic Pac Ref: 12-5Additional Trans Data: HANDLE WITH CARE.TARGET ORGANS RESP SYS, LUNGS,SKIN-EYES.USE FULL PROTECTIVE CLOTHING.

Disposal Data

Disposal Data Review Date: 89108Rec # For This Disp Entry: 02Tot Disp Entries Per NSN: 005Landfill Ban Item: YESDisposal Supplemental Data: MSDS DATED 8/83 IN CASE OF ACCIDENTAL EXPOSURE

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OR DISCHARGE, CONSULT HEALTH AND SAFETY FILE FOR PRECAUTIONS.1st EPA Haz Wst Code New: D0021st EPA Haz Wst Name New: CORROSIVE1st EPA Haz Wst Char New: CORROSIVITY1st EPA Acute Hazard New: NO

Label Data

Label Required: YESTechnical Review Date: 09NOV92Label Status: FCommon Name: HYDROCHLORIC ACID SOLUTIONSignal Word: DANGER!Acute Health Hazard-Moderate: XContact Hazard-Severe: XFire Hazard-None: XReactivity Hazard-Slight: XSpecial Hazard Precautions: PRODUCT IS CORROSIVE TO BODY TISSUES. TOXICITYIS BY CORROSIVITY IN ALL THREE ROUTES OF ENTRY. CAUSES BURNS ON CONTACT.CHRONIC CONTACT IN DILUTE FORM MAY CAUSE ULCERATION. KEEP CONTAINER TIGHTLYCLOSED. STORE IN CORROSION-PROOF AREA. KEEP CONTAINERS OUT OF SUN AND AWAYFROM HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS. FIRST AID: EYE:FLUSH WITHWATER 15 MIN. GET MEDICAL CARE. SKIN:REMOVE CONTAMINATED CLOTHING. WASHWITH SOAP & WATER. LAUNDER CLOTHING BEFORE REUSE. INHALED:REMOVE TO FRESHAIR. RESTORE BREATHING. GET IMMEDIATE MEDICAL CARE. INGESTION: DO NOTINDUCE VOMITING. GIVE LIME WATER OR MILK OF MAGNESIA. GET IMMEDIATE MEDICALCARE.Protect Eye: YProtect Skin: YProtect Respiratory: YLabel Name: DU FONT E I DE NEMOURS AND CO INCLabel Street: 1007 MARKET STREETLabel P . O . Box: 1635Label City: WILMINGTONLabel State: DELabel Zip Code: 19899 - _ ;Label Country: USLabel Emergency Number: 800-441-3637/CHEMTREC 800-424-9300

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International Chemical Safety Cards (WHO/IPCS/ILO) Page l o f 3

International Chemical Safety Cards

HYDROGEN CHLORIDE ICSC: 0163

HYDROGEN CHLOPJDEAnhydrous hydrogen chlorideHydrochloric acid, anhydrous

(cylinder)HC1

Molecular mass: 36.5CAS# 7647-01-0RTECS#MW4025000ICSC #0163UN # 1050EC # 017-002-00-2

TYPES OFHAZARD/

EXPOSURE

FIRE

EXPLOSION

EXPOSURE

• INHALATION

• SKIN

• EYES

• INGESTION |[

SPILLAGE DISPOSAL

Evacuate danger area! Consult anexpert! Ventilation. Remove gas withfine water spray (extra personalprotection: complete protectiveclothing including self-containedbreathing apparatus).

SEE IMPORTANT INFORMATION ON BACK

ACUTE HAZARDS/SYMPTOMS

Not combustible.

Corrosive. Burning sensation.Cough. Laboured breathing.Shortness of breath. Sore throat.Symptoms may be delayed (seeNotes).Corrosive. Serious skin bums.Pain.

Corrosive. Pain. Blurred vision.Severe deep bums.

STORAGE

Separated from combustible andreducing substances, strong oxidants,strong bases, metals. Keep in a well-ventilated room.

PREVENTION

AVOID ALL CONTACT!

Ventilation, local exhaust, orbreathing protection.

Protective gloves. Protectiveclothing.

Safety goggles, face shield, oreye protection in combinationwith breathing protection.

11

PACKAGING &LABELLING

C symbolR: 35-37S: 7/9-26-44UN Haz Class: 2.3UN Subsidiary Risks: 8

FIRST AID/FIRE FIGHTING

In case of fire in thesurroundings: all extinguishingagents allowed.In case of fire: keep cylindercool by spraying with water butNO direct contact with water.

IN ALL CASES CONSULT ADOCTOR!Fresh air, rest. Half-uprightposition. Artificial respiration ifindicated. Refer for medicalattention.

Remove contaminated clothes.Rinse skin with plenty of wateror shower. Refer for medicalattention.First rinse with plenty of waterfor several minutes (removecontact lenses if easilypossible), then take to a doctor.

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International Chemical Safety Cards (WHO/IPCS/ELO) Page 2 of 3

ICSC: 0163 Prepared in the context of cooperation between the International Programme on Chemical Safety & theCommission of the European Communities 6) IPCS CEC 1993


HYDROGEN CHLORIDE ICSC: 0163

IMP0RTANT

DATA

PHYSICALPROPERTIES

ENVIRONMENTALDATA

NOTES

The applying occupational exposure limit value should not be exceeded during any part of the working exposure. Thesymptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated byphysical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray,by a doctor or a person authorized by him/her, should be considered. Do NOT spray water on leaking cylinder (toprevent corrosion of cylinder). Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.

Transport Emergency Card: TEC (R)-135NFPACode:H3;FO;RO;

ADDITIONAL INFORMATION

ICSC: 0163 HYDROGEN CHLORIDE© IPCS, CEC, 1993

PHYSICAL STATE; APPEARANCE: ROUTES OF EXPOSURE:COLOURLESS COMPRESSED LIQUEFED The substance can be absorbed into the bodyGAS, WITH PUNGENT ODOUR, by inhalation.

PHYSICAL DANGERS: INHALATION RISK:The gas is heavier than air. A harmful concentration of this gas in the air

will be reached very quickly on loss ofCHEMICAL DANGERS: containment.The solution in water is a strong acid, it reactsviolently with bases and is corrosive. Reacts EFFECTS OF SHORT-TERMviolently with oxidants forming toxic gas EXPOSURE:(chlorine) (see ICSC # 0126). On contact with Corrosive. The substance is corrosive to theair it emits corrosive fumes (hydrochloric eyes, the skin and the respiratory tract.acid). Attacks many metals forming Inhalation of high concentrations of the gascombustible gas (HYDROGEN — see ICSC # may cause lung oedema (see Notes). The0001). effects may be delayed.

OCCUPATIONAL EXPOSURE LIMITS EFFECTS OF LONG-TERM OR(OELs): REPEATED EXPOSURE:TLV: 5 ppm; 7.5 mg/m3 (ceiling values) The substance may have effects on the lungs,(ACGIH 1992-1993). resulting in chronic bronchitis. The substance

may have effects on the teeth, resulting inerosion.

Boiling point at 101.3 kPa: -85°C Relative vapour density (air = I): 1.3Melting point: -114°C Octanol/water partition coefficient as log Pow:Solubility in water, g/100 ml at 20°C: 72 0.25


International Chemical Safety Cards (WHO/IPCS/ILO) Page 3 of 3

IMPORTANTLEGAL

NOTICE:

Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS isresponsible for the use which might be made of this information. This card contains the collectiveviews of the IPCS Peer Review Committee and may not reflect in all cases all the detailedrequirements included in national legislation on the subject. The user should verify compliance ofthe cards with the relevant legislation in the country of use.

http ://siri. org/msds/mf/cards/file/O163 .html 3/5/99

ANACHEMIA CHEMICALS - NITRIC ACID SOLUTIONS - NITRIC ACID, REAGENT Page 1 of 3

ANACHEMIA CHEMICALS -- NITRIC ACID SOLUTIONS - NITRIC ACID, REAGENTMATERIAL SAFETY DATA SHEETNSN: 6810001487155Manufacturer's CAGE: 4A444 ' , -Part No. Indicator: APart Number/Trade Name: NITRIC ACID SOLUTIONS

General Information

Item Name: NITRIC ACID, REAGENTCompany's Name: ANACHEMIA CHEMICALS INCCompany's Street: 3 LINCOLN BLVDCompany's City: ROUSES POINTCompany's State: NYCompany's Country: USCompany's Zip Code: 12979-9970Company's Emerg Ph #: 800-424-9300 (CHEMTREC)Company's Info Ph #: 518-297-4444Record No. For Safety Entry: 002Tot Safety Entries This Stk#: 005Status: SMJDate MSDS Prepared: 06SEP90Safety Data Review Date: 27APR92Supply Item Manager: N35MSDS Preparer's Name: A. SEYMOURPreparer's Company: SAMEMSDS Serial Number: BJRLB


Proprie tary: NOIngredient: NITRIC ACID (SARA III). (SEE SUPP DATA)Ingredient Sequence Number: 01Percent: <30 W/WNIOSH (RTECS) Number: QU5775000CAS Number: 7697-37-2OSHA PEL: 2 PPM/4 STELACGIH TLV: 2 PPM/4 STEL; 9192

Proprietary: NOIngredient: WATERIngredient Sequence Number: 02Percent: BALANCENIOSH (RTECS) Number: ZC0110000CAS Number: 7732-18-5OSHA PEL: NOT APPLICABLEACGIH TLV: NOT APPLICABLE


Appearance And Odor: YELLOW TO LIGHT BROWN LIQUID WITH PUNGENT ODORSolubility In Water: COMPLETE _. :Percent Volatiles By Volume: 100pH: ACIDIC


Flash Point: NONELower Explosive Limit: N/AUpper Explosive Limit: N/AExtinguishing Media: WATER SPRAYSpecial Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA WITH FULLFACEPIECE OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE.

http://siri.org/msds/h/q 136/q267.html 3/5/99


USE WATER SPRAY. COOL CNTNRS WITH WATER SPRAY.Unusual Fire And Expl Hazrds: OXIDIZING MATERIAL--CONTRIBUTES TOCOMBUSTION OF OTHER MATERIALS. EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Reactivity Data

Stability: YESCond To Avoid (Stability):Materials To Avoid: STRONGCOMBUSTIBLE MATLS, ORGANICHazardous Decomp Products:Hazardous Poly Occur: NOConditions To Avoid (Poly);

NONE SPECIFIED BY MANUFACTURER.BASES, CARBONATES, SULFIDES, CYANIDES,MATLS, STRONG REDUCING AGENTS, (SEE SUPP DATA)OXIDES OF NITROGEN

NOT RELEVANT

Health Hazard Data

LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.Route Of Entry - Inhalation: YESRoute Of Entry - Skin: NORoute Of Entry - Ingestion: NOHealth Haz Acute And Chronic: (ACUTE) EYES: MAY CAUSE SEVERE BURNS & LOSSOF VISION. SKIN: CAUSES SEVERE BURNS. INHAL: MAY CAUSE RESPIRATORYINFLAMMATION. MAY CAUSE DELAYED LUNG INJURY. INGEST: MAY CAUSE NAUSEA,VOMITING, &-SEVERE BURNS TO MOUTH, THROAT & STOMACH. PERFORATION OP GITRACT MAY RESULT. (CHRONIC) MAY INCLUDE DAMAGE TO LUNGS & TEETH.Carcinogenicifcy - NTP: NO - -Carcinogenicifcy - IARC: NOCarcinogen!city - OSHA: NOExplanation Carcinogenicifcy: NOT RELEVANTSigns/Symptoms Of Overexp: MFR IDENTIFIES SKIN AS PRIMARY ROUTE OF ENTRY.Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.Emergency/First Aid Proc: EYES: WASH W/COPIOUS QTYS'OF WATER FOR AT LEAST15 MIN. CALL MD. SKIN: WASH W/SOAP & WATER. REMOVE CONTAM CLTHG. IF IRRITOCCURS OR PERSISTS, SEEK MD. INHAL: REMOVE TO FRESH AIR. GIVE APPRVD OXYGENSUPPLY IF BRTHG DFCLT. GIVE ARTP RESP OR CPR IF BRTHG CEASED. CALL MD.INGEST: DO NOT INDUCE VOMITING. GIVE LARGE QTY OF WATER TO DILUTE. CALL MD.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.


Steps If Mati Released/Spill: EVACUATE AND VENTILATE THE AREA. ADD LIME.MIX WITH WATER TO FORM A SLURRY. PLACE IN A SUITABLE CONTAINER AND SEND FORDISPOSAL.Neutralizing Agent: LIMEWaste Disposal Method: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERALREGULATIONS.Precautions-Handling/Storing.: KEEP CNTNR TIGHTLY CLOSED. STORE SEPARATELY& AWAY FROM FLAMM & COMBUST MATLS. ISOLATE FROM INCOMPATIBLE MATLS. KEEPPROD OUT OF LIGHT.Other Precautions: NONE SPECIFIED BY MANUFACTURER.

Control Measures

Respiratory Protection: IF VENTILATION IS INADEQUATE TO MAINTAIN VAPOR/DUST BELOW TLV, WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.Ventilation: USE ADEQUATE VENTILATION. USE ONLY IN A CHEMICAL FUME HOOD.Protective Gloves: NEOPRENE OR POLYETHYLENE GLOVESEye Protection: CHEM WORK GOG & FULL LENGTH FACESHIELDOther Protective Equipment: APRON OR CLOTHING TO PROTECT SKIN. EYE BATH &EMERGENCY SHOWER. ;Work Hygienic Practices: AVOID SKIN AND EYE CONTACT. WASH HANDS THOROUGHLYAND FREQUENTLY DURING CONTACT WITH MATERIAL. (FP N)Suppl. Safety & Health Data: MATLS TO AVOID: MOST COMMON METALS, POWDEREDMETALS, CARBIDES, AMMONIUM HYDROXIDE, WATER, ALCOHOLS. INGRED 1: THIS STOCK



NUMBER IS MANAGED BY THE NUCLEAR GROUP OF SPCC. THE PER CENT OF NITRIC ACIDIS NEGOTIATED WITH EACH CONTRACT RESULTING IN VARYING PERCENTAGES OF NITRICACID UNDER THE SAME STOCK NUMBER (FP N ) .

Transportation Data

Trans Data Review Date: 91098 :DOT PSN Code: DWGDOT Proper Shipping Name: CORROSIVE LIQUIDS, N . O . S .DOT Class: 8DOT ID Number: UN1760DOT Pack Group: IIIDOT Label: CORROSIVEIMO PSN Code: ESHIMO Proper Shipping Name: CORROSIVE LIQUID, N . O . S . oIMO Regulations Page Number: 8147 'IMO UN Number: 1760IMO UN Class: 8IMO Subsidiary Risk Label: -IATA PSN Code: HKWIATA UN ID Number: 1760IATA Proper Shipping Name: CORROSIVE LIQUID, N . O . S . *IATA UN Class: 8IATA Label: CORROSIVEAPI PSN Code: HKWAPI Prop. Shipping Name: CORROSIVE LIQUID, N . O . S .AFI Class: 8API ID Number: UN1760 :API Pack Group: IIIAPI Basic Pac Ref: 12-5

Disposal Data

Label Data

Label Required: YESTechnical Review Date: 27FEB91Label Status: FCommon Name: NITRIC ACID SOLUTIONSChronic Hazard: YESSignal Word: DANGER;Acute Health Hazard-Severe: XContact Hazard-Severe: XFire Hazard-None: XReactivity Hazard-None: XSpecial Hazard Precautions: ACUTE: EYES: MAY CAUSE SEVERE BURNS & LOSS OFVISION. SKIN: MAY CAUSE SEVERE BURNS. INHALATION: MAY CAUSE RESPIRATORYINFLAMMATION. MAY CAUSE DELAYED LUNG INJURY. INGESTION: MAY CAUSE NAUSEA,VOMITING & SEVERE BURNS TO MOUTH, THROAT & STOMACH. PERFORATION OF G . I .TRACT MAY RESULT. :Protect Eye: YProtect Skin: Y _ .Protect Respiratory: YLabel Name: ANACHEMIA CHEMICALS INCLabel Street: 3 LINCOLN BLVDLabel City: ROUSES POINTLabel State: NYLabel Zip Code: 12979-9970 :Label Country: USLabel Emergency Number: 800-424-9300 (CHEMTREC)




NITRIC ACID ICSC: 0183

NITRIC ACIDConcentrated Nitric Acid (70%)

HNOgMolecular mass: 63.0

CAS# 7697-37-2RTECS#QU5775000ICSC #0183UN #2031EC #007-004-00-1

TYPES OFHAZARD/

EXPOSURE

ACUTE HAZARDS/SYMPTOMS PREVENTION


FIRE

Not combustible but enhancescombustion of other substances.Gives off irritating or toxicfumes (or gases) in a Fire.

NO contact with flammablesubstances. NO contact withcombustibles or organicchemicals.

In case of fire in thesurroundings: NO FOAM.

EXPLOSIONRisk of fire and explosion oncontact with many commonorganic compounds.

In case of fire: keep drums, etc.,cool by spraying with water.

EXPOSURE AVOID ALL CONTACT!

INHALATION

Burning sensation. Cough.Laboured breathing.Unconsciousness. Symptomsmay be delayed (see Notes).


Fresh air, rest. Half-uprightposition. Artificial respiration ifindicated. Refer for medicalattention.

SKIN

Corrosive. Serious skin burns.Pain. Yellow discolouration.

Protective clothing. Remove contaminated clothes.Rinse skin with plenty of wateror shower. Refer for medicalattention.

EYES

Corrosive. Redness. Pain.Severe deep burns.

Face shield or eye protection incombination with breathingprotection.

First rinse with plenty of waterfor several minutes (removecontact lenses if easilypossible), then take to a doctor.

INGESTIONCorrosive. Abdominal pain.Burning sensation. Shock.

Do not eat, drink, or smokeduring work. Wash hands beforeeating.__ __ __ __

Do NOT induce vomiting. Giveplenty of water to drink. Rest.Refer for medical attention.

SPILLAGE DISPOSAL STORAGE PACKAGING &LABELLING

Evacuate danger area! Consult anexpert! Ventilation. Collect leakingliquid in scalable containers.Cautiously neutralize remainder with

Separated from combustible andreducing substances, bases, food andfeedstuffs, organic chemicals. Cool.Dry. Keep in a well-ventilated room.

Unbreakable packaging; put breakablepackaging into closed unbreakablecontainer. Do not transport with foodand feedstuffs.



sodium carbonate. Then wash awaywith plenty of water. Do NOT absorbin saw-dust or other combustibleabsorbents (extra personal protection:complete protective clothing includingself-contained breathing apparatus).

0 symbolC symbolR: 8-35S: (1/2-)23-26-36-45Note: BUN Hazard Class: 8


ICSC: 0183 Prepared in the context of cooperation between the International Programme on Chemical Safety & theCommission of the European Communities © IPCS CEC 1993


NITRIC ACID ICSC: 0183

iM

p0

R

T

A

N

T

D

A

T

A

PHYSICALPROPERTIES

ENVIRONMENTALDATA

N O T E S

Depending on the degredo not become manifesobservation are therefor

PHYSICAL STATE; APPEARANCE: ROUTES OF EXPOSURE:COLOURLESS TO YELLOW LIQUID , The substance can be absorbed into the bodyWITH PUNGENT ODOUR, by inhalation of its vapour and by ingestion.

INHALATION RISK:A harmful contamination of the air can bereached very quickly on evaporation of this

CHEMICAL DANGERS: substance at 20°C.The substance decomposes on warmingproducing nitrogen oxides. The substance is a EFFECTS OF SHORT-TERMstrong oxidant and reacts violently with EXPOSURE:combustible and reducing materials, e.g., The substance is very corrosive to the eyes,turpentine, charcoal, alcohol. The substance is the skin and the respiratory tract. Corrosive ona strong acid, it reacts violently with bases and ingestion as well. Inhalation of vapour mayis corrosive to metals. Reacts very violently cause lung oedema (see Notes).with organic chemicals (e.g., acetone, aceticacid, acetic anhydride), causing fire and EFFECTS OF LONG-TERM ORexplosion hazard. Attacks some plastics. REPEATED EXPOSURE:

OCCUPATIONAL EXPOSURE LIMITS(OELs):TLV: 2 ppm; S.I mg/m3 (as STEL: 4 ppm; 10mg/m3) (ACGIH 1993-1994).

Boiling point: 121 °C Vapour pressure, kPa at 20°C: 6.4Melting point: -41.6°C Relative vapour density (air = I): 2.2Relative density (water = I): 1.4 Relative density of the vapour/air-mixture atSolubility in water: miscible 20°C (air = I): 1.07

e of exposure, periodic medical examination is indicated. The symptoms of lung oedema oftent until a few hours have passed and they are aggravated by physical effort. Rest and medicale essential. Rinse contaminated clothes (fire hazard) with plenty of water.

Transport Emergency Card: TEC (R)-9BNFPACode:H3;FO;RO;


POLYCHEM DIV OF POLYMER CHEMISTS - BATTERY ACID 35% SULPURIC AC.. Page 1 of 4

POLYCHEM DIV OP POLYMER CHEMISTS -- BATTERY ACID 35% SULFURIC ACID - SULFIRIC ACID,MATERIAL SAFETY DATA SHEETNSN: 6810009049372Manufacturer's CAGE: POLYCPart No. Indicator: APart Number/Trade Name: BATTERY ACID 35% SULPURIC ACID

General Information

Item Name: SULFIRIC ACID,ELECTROLYTE :Company's Name: POLYCHEM, DIV OF POLYMER CHEMISTS, INCCompany's Street: 519 B STREETCompany's City: SAN RAFAELCompany's State: CA ' •Company's Country: USCompany's Zip Code: 94901Company's Emerg Ph #: 800-424-9300(CHEMTREC)Company's Info Ph #: UNKNOWNRecord No. For Safety Entry: 001 :Tot Safety Entries This Stk#: OilStatus: SEDate MSDS Prepared: 23SEP91Safety Data Review Date: 18MAR96Supply Item Manager: CXMSDS Preparer's Name: MICHAEL POLEYMSDS Serial Number: BMSXVSpecification Number: O-S-801Spec Type, Grade, Class: 4 CLASSHazard Characteristic Code: Cl .Unit Of Issue: DRUnit Of Issue Container Qty: 5.000 GALLONSType Of Container: 1H1Net Unit Weight: 54.2 LBS


Proprietary: NOIngredient: SULFURIC ACID (SARA III)Ingredient Sequence Number; 01Percent: 35%NIOSH (RTECS) Number: WS5600000CAS Number: 7664-93-9OSHA PEL: 1 MG/M3ACGIH TLV: 1 MG/M3; 9192Other Recommended Limit: NONE SPECIFIED


Appearance And Odor: CLEAR LIQUID WITH A SLIGHT ACIDIC ODOR.Boiling Point: 235F.113CMelting Point: UNKNOWN :

Vapor Pressure (MM Hg/70 F ) : 1.4 :Vapor Density (Air=l): 2 . 0Specific Gravity: 1.30 :Decomposition Temperature: UNKNOWNEvaporation Rate And Ref: UNKNOWNSolubility In Water: COMPLETEPercent Volatiles By Volume: N/AViscosity: UNKNOWNCorrosion Rate ( I P Y ) : UNKNOWN

Fire and Explosion Hazard Data.

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POLYCHEM DIV OF POLYMER CHEMISTS - BATTERY ACID 35% SULFURIC AC.. Page 2 of 4

Flash Point: NOT APPLICABLEExtinguishing Media: WATER SPRAY, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.Special Fire Fighting Proc: WEAR FULL PROTECTIVE EQUIPMENT INCLUDING SELFCONTAINED BREATHING APPARATUS. LIQUID IS CORROSIVE. DILUTION WITH WATER MAYLIBERATE HEAT WHICH CAN CAUSE BOILING.Unusual Fire And Expl Hazrds: MAY PRODUCE HAZARDOUS DECOMPOSITIONPRODUCTS. READILY ATTACKS SOME METALS (ALUMINUM, MAGNESIUM, ZINC) TOLIBERATE FLAMMABLE/EXPLOSIVE HYDROGEN GAS.

Reactivity Data

Stability: YESCond To Avoid (Stability): HIGH HEAT, MOISTUREMaterials To Avoid: ALKALINE MATERIALS, ORGANICS, MAGNESIUM, ALUMINUM,ZINC, CAUSTICS, ALKALI :Hazardous Decomp Products: OXIDES OF SULFUR, HYDROGEN SULFIDE, HYDROGENGASHazardous Poly Occur: NO

Health Hazard Data

LD50-LC50 Mixture: ORAL LD50 (RAT) IS 2140 MG/KGRoute Of Entry - Inhalation: YESRoute Of Entry - Skin: NORoute Of Entry - Ingestion: NOHealth Haz Acute And Chronic: ACUTE: SEVERE BURNS. CHRONIC: ACID BURNS.Carcinogenicity - NTP: NOCarcinogenicity - IARC: YESCarcinogenicity - OSHA: NOExplanation Carcinogenicity: SULFURIC ACID MISTS ARE CLASSIFIED IARC-2B.Signs/Symptoms Of Overexp: INHALATION: IRRITATION OF THE MUCOUS MEMBRANESTO PNEUMONITIS. EYES AND SKIN: CAUSES BURNS. CAN RESULT IN PERMANENT EYEDAMAGE AND LOSS OF VISION. INGESTION: ACID BURNS TO THE MOUTH, ESOPHAGUS,STOMACH, AND OTHER TISSUE. LARGE AMOUNTS CAN BE FATAL.Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.Emergency/First Aid Proc: EYES: FLUSH WITH WATER FOR 15 MINUTES WHILEHOLDING EYELIDS OPEN. SKIN: FLUSH WITH WATER WHILE REMOVING CONTAMINATEDCLOTHING. INHALED: REMOVE TO FRESH AIR. IP NOT BREATHING PERFORM CPR. IFBREATHING IS HARD, GIVE OXYGEN. SWALLOWED: DO NOT INDUCE VOMITING. IFCONSCIOUS, DRINK LARGE AMOUNTS OF MILK OR WATER. IN ALL CASES TAKE VICTIMIMMEDIATELY TO A PHYSICIAN OR HOSPITAL.


Steps If Mati Released/Spill: DIKE AREA TO CONTAIN SPILL. CAREFULLY ADDLIME OR SODIUM CARBONATE TO' NEUTRALIZE ACID. PICK UP AND CONTAINERIZERESIDUE FOR DISPOSAL. FLUSH SPILL AREA WITH WATER, COLLECT RINSATE FORDISPOSAL OR SEWER, AS APPROPIATE.Neutralizing Agent: LIME OR SODIUM CARBONATE.Waste Disposal Method: DISPOSE OF NEUTRALIZED ACID IN AN APPROVEDLANDFILL. DISPOSE OF ALL WASTE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERALREGULATIONS.Precautions-Handling/Storing: KEEP CONTAINERS CLOSED WHEN MATERIAL IS NOTIN USE.Other Precautions: DO NOT ADD THIS PRODUCT TO HYPOCHLORITE BLEACHES,CHLORINE SANITIZERS, OR CHLORINATED CLEANERS AS THIS LIBERATES TOXIC,CORROSIVE CHLORINE G A S ! i !

Control Measures

Respiratory Protection: NIOSH APPROVED MECHANICAL FILTER FOR EXPOSURE TOMIST. :Ventilation: LOCAL EXHAUST - ADEQUATE VENTILATION.Protective Gloves: RUBBER, OR SYNTHETIC RUBBER FOR ACID



Eye Protection: FACE SHIELD AND GOGGLESOther Protective Equipment: RUBBER APRON OR BOOTS OR EQUIVALENT FOR ACIDSERVICE. EYE WASH, SAFETY SHOWERWork Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.Suppl. Safety & Health Data: NONE

Transportation Data

Trans Data Review Date: 96078DOT PSN Code: BQXDOT Proper Shipping Name: BATTERY FLUID, ACIDDOT Class: 8DOT ID Number: UN2796DOT Pack Group: IIDOT Label: CORROSIVEIMO PSN Code: OFFIMO Proper Shipping Name: SULPHURIC ACIDIMO Regulations Page Number; 8230IMO UN Number: 2796IMO UN Class: 8IMO Subsidiary Risk Label: -IATA PSN Code: DAGIATA UN ID Number: 2796IATA Proper Shipping Name: BATTERY FLUID, ACIDIATA UN Class: 8IATA Label: CORROSIVEAFI PSN Code: DAGAFI Prop. Shipping Name: BATTERY FLUID, ACIDAFI Class: 8AFI ID Number: UN2796AFI Pack Group: IIAFI Special Prov: A3,A7,N6,N34AFI Basic Pac Ref: A12.3.A12.5MMAC Code: NRAdditional Trans Data: NONE

Disposal Data

Label Data

Label Required: YES :Technical Review Date: 19MAR96 :MFR Label Number: UNKNOWNLabel Status: FCommon Name: BATTERY ACID 35% SULFURIC ACIDSignal Word: WARNING!Acute Health Hazard-Moderate: XContact Hazard-Moderate: XFire Hazard-None: XReactivity Hazard-None: XSpecial Hazard Precautions': FIRE-READILY ATTACKS SOME METALS (ALUMINUM,CAREFULLY ADD LIME OR SODIUM CARBONATE TO NEUTRALIZE ACID. PICK UP &CONTAINERIZE RESIDUE FOR DISPOSAL. STORE-KEEP CONTAINERS CLOSED WHEN NOT INUSE. FIRST AID: EYES-FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDSOPEN. SKIN-WFLUSH WITH WATER WHILE REMOVE CONTAMINATED CLOTHING. INHALED-REMOVE TO FRESH AIR. IF NOT BREATHING PERFORM CPR. IF BREATHING IS HARD,GIVE OXYGEN. SWALLOWED-DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGEAMOUNTS OF MILK OR WATER. IN ALL CASES TAKE IMMEDIATELY TO A PHYSICIAN ORHOSPITAL. - -Protect Eye: YProtect Skin: YProtect Respiratory: YLabel Name: POLYCHEM, DIV OF POLYMER CHEMISTS, INC

http.V/siri-org/msds/h/q 198/q239.html 3/5/99


Label Street: 519 B STREETLabel City: SAN RAFAELLabel State: CALabel Zip Code: 94901Label Country: USLabel Emergency Number: 800-424-9300(CHEMTREC)




SULFURIC ACID ICSC: 0362

SULFURIC ACIDSulfuric acid 100%

Oil of vitriolH^S04

Molecular mass: 98.1CAS# 7664-93-9RTECS#WS5600000ICSC # 0362UN #1830EC #016-020-00-8

TYPES OFHAZARD/

EXPOSURE

ACUTE HAZARDS/SYMPTOMS PREVENTION


FIRE

Not combustible. Manyreactions may cause fire orexplosion. Gives off irritating ortoxic fumes (or gases) in a fire.

NO contact with flammablesubstances. NO contact withcombustibles.

NO water. In case of fire in thesurroundings: powder, AFFF,foam, carbon dioxide.

EXPLOSION

Risk of fire and explosion oncontact with base(s),combustible substances,oxidants, reducing agents orwater.

In case of fire: keep drums, etc.,cool by spraying with water butNO direct contact with water.

EXPOSUREPREVENT GENERATION OFMISTS'AVOID ALLCONTACT!

IN ALL CASES CONSULT ADOCTOR!

• INHALATION

Corrosive. Burning sensation.Cough. Laboured breathing.


Fresh air, rest. Half-uprightposition. Artificial respiration ifindicated. Refer for medicalattention.

SKIN

Corrosive. Redness. Seriousskin bums. Pain.


Remove contaminated clothes.Rinse skin with plenty of wateror shower. Refer for medicalattention.

EYES

Corrosive. Redness. Pain.Severe deep bums.



INGESTIONCorrosive. Abdominal pain.Burning sensation. Collapse.

) not eat, drink, or smokering work.

Rinse mouth. Do NOT inducevomiting. Refer for medicalattention.

SPILLAGE DISPOSAL STORAGE PACKAGING &LABELLING

Collect leaking liquid in scalablecontainers. Do NOT absorb in saw-dust or other combustible absorbents

Separated from combustible andreducing substances, strong oxidants,strong bases, other materials, food and

Unbreakable packaging; put breakablepackaging into closed unbreakablecontainer. Do not transport with food

http://siri.uvm.edu/msds/mf/cards/file/0362.html 3/5/99


(extra personal protection: completeprotective clothing including self-contained breathing apparatus).

feedstuffs (see Notes). May be storedin stainless steel containers (seeNotes).

and feedstuffs.C symbolR:35S: 2-26-30UN Hazard Class: 8UN Packing Group: II




SULFURIC ACID ICSC: 0362

iMp0RTANT

PHYSICAL STATE; APPEARANCE:COLOURLESS, OILY HYGROSCOPICLIQUID , WITH NO ODOUR.

PHYSICAL DANGERS:

CHEMICAL DANGERS:The substance is a strong oxidant and reactsviolently with combustible and reducingmaterials. The substance is a strong acid, itreacts violently with bases and is corrosive tomost common metals forming aflammable/explosive gas (hydrogen see ICSC# 0001). Reacts violently with water andorganic materials with evolution of heat (seeNotes). Upon heating, irritating or toxic fumes(or gases) (sulfur oxides) are formed.

OCCUPATIONAL EXPOSURE LIMITS(OELs):TLV: ppm; 1 mg/m3 (as TWA); 3 mg/m3 (asSTEL)(ACGIH 1993-1994).PDK: 1 mg/m3 (USSR 1988).MAK: ppm; 1 mg/m3; respirable fraction ofaerosol (1991).

ROUTES OF EXPOSURE:The substance can be absorbed into the bodyby inhalation of its aerosol and by ingestion.

INHALATION RISK:Evaporation at 20°C is negligible; a harmfulconcentration of airborne particles can,however, be reached quickly on spraying.

EFFECTS OF SHORT-TERMEXPOSURE:Corrosive. The substance is very corrosive tothe eyes the skin and the respiratory tract.Corrosive on ingestion. Inhalation of anaerosol of this substance may cause lungoedema (see Notes).

EFFECTS OF LONG-TERM ORREPEATED EXPOSURE:Lungs may be affected by repeated orprolonged exposure to an aerosol of thissubstance. Risk of tooth erosion upon repeatedor prolonged exposure to an aerosol of thissubstance.

PHYSICALPROPERTIES

Boiling point (decomposes): 340°CMelting point: 10°CRelative density (water = I): 1.8

Solubility in water: miscibleVapour pressure, kPa at 146°C: 0.13Relative vapour density (air = I): 3.4

ENVIRONMENTALDATA

This substance may be hazardous to the environment; special attention should be given towater organisms.

NOTES

The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated byphysical effort. Rest and medical observation are therefore essential. NEVER pour water into this substance; whendissolving or diluting always add it slowly to the water. Store in an area having corrosion resistant concrete floor.

[ Transport Emergency Card: TEC (R)-10BNFPA Code: H 3; F 0; R 2; W


CHEM SERVICE - CARBON TETRACHLORIDE Page 1 of 3

CHEM SERVICE -- CARBON TETRACHLORIDEMATERIAL SAFETY DATA SHEETNSN: 681000N050733Manufacturer's CAGE: 84898Part No. Indicator: APart Number/Trade Name: CARBON TETRACHLORIDE

General Information

Company's Name: CHEM SERVICE INCCompany's P. 0. Box: 3108Company's City: WESTCHESTERCompany's State: PACompany's Country: USCompany's Zip Code: 19381Company's Emerg Ph #: 215-692-3026Record No. For Safety Entry: 001Tot Safety Entries This Stk#: 001Status: SMJDate MSDS Prepared: 02JUL91.- .Safety Data Review Date: 04AUG94MSDS Serial Number: BVDWZHazard Characteristic Code: NK


Proprietary: NOIngredient: CARBON TETRACHLORIDEIngredient Sequence Number: 01NIOSH (RTECS) Number: FG4900000CAS Number: 56-23-5OSHA PEL: 10 PPMACGIH TLV: 5 PPM,C


Appearance And Odor: COLORLESS LIQUID, ETHER LIKE ODORBoiling Point: 170F,77C - •Melting Point: 73.4F,23.0C :Vapor Pressure (MM Hg/70 F ) : 91&20CVapor Density (Air=l): 5 . 1Specific Gravity: 1.589Evaporation Rate And Ref: 0.33(BUTYL ACETATE=1)Solubility In Water: VERY SLIGHTLY SOL


Flash Point: NON-FLAMMABLEExtinguishing Media: CARBON DIOXIDE/DRY CHEMICAL POWDER. DO NOT USE WATER!Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULLPROTECTIVE EQUIPMENT (FP N ) .Unusual Fire And Expl Hazrds: NO EXPLOSION LIMITS ARE AVAILABLE FOR THISCOMPOUND.

Reactivity Data

Stability: YESCond To Avoid (Stability): REACTS WITH AMIDES. SENSITIVE TO HEAT/LIGHT.DARK COLOR DOES NOT AFFECT PURITY. VOLATILE.Materials To Avoid: ACTIVE METALS ( E . G . SODIUM); POWDERED METALS; STRONGOXIDIZING AGENTS.Hazardous Decomp Products: DECOMPOSITION LIBERATES TOXIC FUMES.Hazardous Poly Occur: NO

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Conditions To Avoid (Poly): NOT RELEVANT

Health Hazard Data

LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.Route Of Entry - Inhalation: YESRoute Of Entry - Skin: YESRoute Of Entry - Ingesfcion: YESHealth Haz Acute And Chronic: ALL CHEM SHOULD BE CONSIDERED HAZ-AVOIDDIRECT PHYSICAL CONT. MAY PRDCE CANCER. MAY BE FATAL IF ABSORBED THRU SKIN.MAY BE FATAL IF INHALED. MAY BE FATAL IF SWALLOWED. PRLNGD EXPOS MAY CAUSENAUS/HDCH/DIZZ &/OR EYE DAM. INGEST MAY CAUSE DIARR. EXPOS CAN CAUSE LIVERDAM. EXPOS CAN CAUSE KIDNEY DAM. (EFTS OF OVEREXP)Carcinogenicity - NTP: YESCarcinogenicity - IARC: YESCarcinogenicity - OSHA: NOExplanation Carcinogenicifcy: CARBON TETRACHLORIDE:IARC MONO, SUPP, VOL 7 ,PG 143, 1987: GRP 2B. NTP 6TH ANNUAL REPORT ON CARCINS, 1991: ANTIC(SUPDAT)Signs/Symptoms Of Overexp: HLTH HAZ: RPTD EXPOS TO VAPS &/OR DUST CANCAUSE EYE INJURY. CAM CAUSE SENSIT BY SKIN CONT. CAM CAUSE DELAYED ADVERSEHLTH EFTS. CAN CAUSE GI DISTURB. AVOID CONSUMPTION OF ALCOHOL BEFORE &AFTER HNDLG OF CMPD. MAY BE RAPIDLY ABSORBED THRU SKIN W/POTNTL ADVERSEHLTH EFTS.Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.Emergency/First Aid Proc: EYES: FLUSH CONTINOUSLY W/WATER FOR @ LST 15-20MIN. SKIN: FLUSH W/WATER FOR 15-20 MIN. IF NO BURNS 'HAVE OCCURRED-USE SOAP& WATER TO CLEANSE SKIN. REMOVE & WASH CONTAMD CLTHG. INHAL: REMOVE TOFRESH AIR. ADMINISTER OXYGEN IF HAVING DFLCTY BRTHG. IF PATIENT HAS STOPPEDBRTHG ADMINISTER ARTF RESP. IF PATIENT IS IN CARDIAC ARREST ADMIN CPR.CONTINUE LIFE SUPPORTING MEASURES UNTIL MED ASSIST (SUPDAT)


Steps If Mati Released/Spill: EVAC AREA. WEAR APPROPRIATE NIOSH/MSHAAPPROVED REGULATED EQUIPMENT. ABSORB ON VERMICULITE/SIMILAR MATERIAL. SWEEPUP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMDTO SURF TO REMOVE ANY RESIDUES.Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.Waste Disposal Method: BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH ANAFTERBURNER AND SCRUBBER. DISPOSE OF I/A/W FEDERAL, STATE AND LOCALREGULATIONS (FP N ) .Precautions-HandLing/Storing: AVOID CONT W/SKIN, EYES & CLTHG. KEEPTIGHTLY CLSD IM A COOL DRY PLACE. STORE ONLY W/COMPATIBLE CHEMICALS.Other Precautions: NONE SPECIFIED BY MANUFACTURER.

Control Measures

Respiratory Protection: USE APPROPRIATE NIOSH/MSHA APPROVED SAFETYEQUIPMENT.Ventilation: THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.Protective Gloves: IMPERVIOUS GLOVES (FP N ) .Eye Protection: ANSI APPRVD CHEM WORKS GOGGS (PP N ) .Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.Suppl. Safety & Health Data: EXPLAN OF CARCIN: TO BE CARCIN. HUMAN: LIVER,KIDNEYS, LUNG DMG. FIRST AID PROC: HAS ARRIVED. IF EXHIBITING SIGNS OFSHOCK-KEEP WARM & QUIET. INDUCE VOMIT. DO NOT ADMINISTER LIQ/INDUCE VOMITTO AN UNCON/CONVULS PERSON. CONT POIS CTL CTR IMMED IF NEC. GET MED ATTN IFNEC.

Transportation Data

Disposal Data

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Label Data

Label Required: YESTechnical Review Date: 04AUG94 ;Label Date: 16MAY94Label Status: G -Common Name: CARBON TETRACHLORIDEChronic Hazard: YESSignal Word: WARMING!Acute Health Hazard-Moderate: XContact Hazard-Moderate: XFire Hazard-None: XReactivity Hazard-Slight: XSpecial Hazard Precautions: REACTS W/AMIDES, ACTIVE METALS, PWDR METALS,OXIDIZERS. SENSITIVE TO HEAT/LIGHT. VOLAT. DECOMP FUMES ARE TOX. ACUTE:VAPSCONTRIBUTE TO OCCURRENCE OF IRREGULAR HEARTBEAT ( F P N ) . MAY BE FATAL IFABSORBED THRU SKIN, INHAL, INGEST. PRLNG EXPOS MAY CAUSE NAUS/HDCH/DIZZ &/OR EYE DMG. INGEST MAY CAUSE DIARR. CAN CAUSE LIVER DMG. RPTD EXPOS TO VAPS&/OR- DUST CAN CAUSE EYE INJURY. CAN CAUSE SENSIT BY SKIN CNTCT. CAN CAUSEGI DISTURB. AVOID CONSUMING ALCOHOL BEFORE & AFTER HNDLG. MAY BE RAPIDLYABSORBED THRU SKIN W/POTNTL ADVERSE HLTH EFTS. CHRONIC:CANCER HAZ. CNTNSCARBON TETRACHLORIDE WHICH IS LISTED AS CARCIN ( F P N ) . CAN CAUSE DELAYEDHLTH EFTS.Protect Eye: YProtect Skin: YProtect Respiratory: YLabel Name: CHEM SERVICE INCLabel P . O . Box: 3108 'Label City: WESTCHESTERLabel State: PA : - .Label Zip Code: 19381Label Country: USLabel Emergency Number: 215-692-3026

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CARBON TETRACHLORIDE ICSC: 0024

CARBON TETRACHLORIDETetrachloromethaneTetrachlorocarbon

TetraCCl4

Molecular mass: 153.8CAS # 56-23-5RTECS#FG4900000ICSC #0024UN #1846EC # 602-008-00-5

TYPES OFHAZARD/

EXPOSURE

FIRE

EXPLOSION

EXPOSURE

• INHALATION

• SKIN

• EYES

• INGESTION

SPILLAGE DISPOSAL STORAGE ^^S^NG5^

Evacuate danger area! Consult an Separated from metals (see Chemical Unbreakable packaging; put breakableexpert! Collect leaking and spilled Dangers), fluorine, food and packaging into closed unbreakableliquid in scalable containers as far as feedstuffs. Ventilation along the floor, container. Do not transport with food

ACUTE HAZARDS/SYMPTOMS

Not combustible. Gives offirritating or toxic fumes (orgases) in a fire.

Risk of fire and explosion (seeChemical Dangers).

Dizziness. Drowsiness.Headache. Nausea.

MAY BE ABSORBED!Redness. Pain.

Redness. Pain.

Abdominal pain. Diarrhoea(further see Inhalation).

PREVENTION

•

AVOID ALL CONTACT




Do not eat, drink, or smokeduring work.


In case of fire in thesurroundings: all extinguishingagents allowed.

In case of fire: keep drums, etc.,cool by spraying with water.

Fresh air, rest. Artificialrespiration if indicated. Referfor medical attention.

Remove contaminated clothes.Rinse skin with plenty of wateror shower. Refer for medicalattention.


Rinse mouth. Give plenty ofwater to drink. Refer formedical attention.



possible. Absorb remaining liquid insand or inert absorbent and remove tosafe place. Do NOT let this chemicalenter the environment (extra personalprotection: complete protectiveclothing including self-containedbreathing apparatus).

and feedstuffs.T symbolR: 23/24/25-40-48/23S: 23-36/37/44UN Hazard Class: 6.1UN Packing Group: IIMarine pollutant.



International Chemical Safety CardsICSC: 0024CARBON TETRACHLORIDE

IMp0RTANT

DATA

PHYSICALPROPERTIES

ENVIRONMENTALDATA

NOTES

Use of alcoholic beveraexamination is indicatethe vicinity of a fire or

PHYSICAL STATE; APPEARANCE:COLOURLESS LIQUID, WITHCHARACTERISTIC ODOUR.

PHYSICAL DANGERS:The vapour is heavier than air.

CHEMICAL DANGERS:On contact with hot surfaces or flames thissubstance decomposes forming toxic andirritating fumes (hydrogen chloride, ICSC #0163; chlorine, ICSC # 0126; phosgene, ICSC# 0007). Reacts violently with some metalssuch as aluminium, barium, magnesium,potassium, sodium, with fluorine and othersubstances, causing fire and explosion hazard.Attacks copper, lead and zinc.

OCCUPATIONAL EXPOSURE LIMITS(OELs):TLV (as TWA): 5 ppm; 31 mg/m3 A2 (skin)(ACGIH 1992-1993).MAK: 10 ppm; 65 mg/m3; 11,1, H, D (1992).MAK: class IIIB (1992). .

Boiling point: 76.5°CMelting point: -23°CRelative density (water = I): 1.59Solubility in water, g/100 ml at 20°C: 0.1

This substance may be hazardous to the environwater.

ges enhances the harmful effect. Depending ond. The odour warning when the exposure limit va hot surface, or during welding. Ascordin, Kata

iment; special attention should be given toi

the degree of exposure, periodic medicalalue is exceeded is insufficient. Do NOT use inrin, Tetracol, Chlorasol are trade names.

Transport Emergency Card: TEC (R)-102

ROUTES OF EXPOSURE:The substance can be absorbed into the bodyby inhalation, through the skin and byingestion.

INHALATION RISK:A harmful contamination of the air can bereached very quickly on evaporation of thissubstance at 20°C.

EFFECTS OF SHORT-TERMEXPOSURE:Thesubstance irritates the eyes. The substancemay cause effects on the liver, kidneys and thecentral nervous system, resulting inunconsciousness. Medical observation isindicated.

EFFECTS OF LONG-TERM ORREPEATED EXPOSURE:Repeated or prolonged contact with skin maycause dermatitis. This substance is possiblycarcinogenic to humans.

• 1 !1"

Vapour pressure, kPa at 20°C: 12.2Relative vapour density (air = I): 5.3Relative density of the vapour/air-mixture at20°C (air = I): 1.5Octanol/water partition coefficient as log Pow:2.64


response action contract - superfund records collections · response action contract no. 68-w6-0036...

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