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Accession #: Dl96057123

Document #: SD-WM-TRP-243

TitlelDesc: PHYSICAL PROPERTY CHARACTERIZATION OF 183H BASIN SLUDGE

SUPPORTING DOCUMENT

3. N W r

WHC-SD-WM-TRP-243

~~~~ ~ ~

2. T i t l e Basin Physical Property Characterization of 183-HAS1 udge

Bulk Density, Absorbent Density, Absorbance, Free Liquids, Loss-on-ignition, Calcination

I \ 5. Key Uords

4. Rev No.

0

7. Abstract

Signature U

OrganizationKharge code OM570/A4219

This document describes the characterization of 183-H Basin sludge physical properties, e.g. bulk density of sludge and absorbent, and determination o f free liquids. Calcination o f crucible-size samples o f sludge was also done and the resulting 'loss-on-ignition' was compared to the theoretical weight loss based on sludge analysis obtained from Weston Labs.

8. RELEASE STAMP

A-6400-073 (08/94) UEF124

WHC-SD-WH-TRP-243, Rev. 0

3.0 LOSS-ON-1GNITION.TESTS

These loss -on - ign i t i on t e s t s evaluate t h e e f f e c t o f heat ing t h e sludge a t 950'C f o r 16 hours. The d e t a i l e d procedure, which inc ludes t h e c a l c u l a t i o n o f mois ture ton ten t , i s g iven i n Sect ion 7.1 o f B u i l d i n g 377 Procedures (Greenhalgh et a l . 1995).

A t h e o r e t i c a l es t imat ion o f t h e weight l o s s has a iso been made us ing i n fo rma t ion f rom an exhaust ive thermodynamic s imu la t ion o f c a l c i n a t i o n of Hanford tank wastes (Delegard e t a l . 1994). Pre fer red species, formed on c a l c i n a t i o n o f t y p i c a l compounds present i n t h e wastes l i s t e d i n t h a t repo r t , and q u a n t i t a t i v e sludge ana lys i s obta ined from Weston Labs, have been used t o determine t h e t h e o r e t i c a l composi t ion o f c a l c i n a t i o n residues o f 183-H Basin wastes. Data obta ined from t h i s t h e o r e t i c a l development, and actual l a b t e s t s , a re presented i n Table 2 and a comparison made i n Sect ions 3.2 and 3.3.

3.1 Data f rom Lab Test ing, and Eva lua t ion o f Theore t ica l LO1

Seventy sludge samples from Basin 183-H. were ca l c ined i n c r u c i b l e s us ing t h i s method, and t h e decrease i n weight measured. This measured decrease i n weight i s termed ' l oss -on - ign i t i on ' (LOI). Only median values from t e s t r e s u l t s have been repor ted (Table 2, row 3) .

Using data prov ided by Weston, median ana ly te concentrat ions o f t h e 7 waste ca tegor ies have been es tab l i shed (Table 2, rows 10 t h r u 40). These median f i g u r e s have been used t o determine t h e species l i k e l y t o remain i n t h e res idue a f t e r c a l c i n a t i o n . De ta i l ed r e s u l t s o f these c a l c u l a t i o n s and analyses have been presented i n t h e form o f spreadsheet p r i n t o u t s i n Appendix 3. Ca lc ina t i on assumptions and impor tant observat ions on Weston analyses have been noted the re in . A summary o f t h i s t h e o r e t i c a l eva lua t ion i s g iven i n Table 2, row 8.

Rows 6 and 7 (Table 2) g i v e t h e median w t % water present i n t h e sludge samples.

3.2 Discuss ion o f Resul ts

I n t h e data i n Appendix 3, a s i g n i f i c a n t parameter i s t h e t o t a l weight o f anions and ca t i ons repor ted by Weston. The unanalyzed p o r t i o n o f t h e waste (Table 2, row 5) ranges from 9.6% f o r Basin 4 samples t o 98.1% f o r Sand B l a s t G r i t . These f i g u r e s presented i n Table 2, row 5 have been taken from t h e upper r i g h t hand corner o f the spreadsheets i n Appendix 3. The l a r g e unanalyzed p o r t i o n i n some ca tegor ies o f Basin 183-H waste cou ld be due t o incomplete d i s s o l u t i o n o f t h e sample being prepared f o r ana lys is .

The median t h e o r e t i c a l LO1 (Table 2, row 2) has been based on t h e sum o f the weight o f t h e anions and ca t ions repor ted by Weston i n t h e waste samples (see t h e f i g u r e i n 'ppm' a t t h e bottom o f t h e 3 r d column i n t h e spreadsheets i n Appendix 3 ) . I n many cases the l a t t e r f i g u r e i s cons iderably lower than 10E6 ppm i . e . 100 wt%, e.g. f o r Sand B l a s t G r i t t h i s f i g u r e i s on ly 1.9% o f t o t a l sample weight. The gener ic c a l c u l a t i o n method f o r t h e t h e o r e t i c a l LOI, used w i t h on l y

3

WHC-SO-WM-TRP-243, Rev. 0

slight modification for all types of wastes, resulted in negative LOI's (see row 8 ' of Table 2 ) for 3 waste types. This anomaly was probably due to this discrepancy in Weston Lab's figures.

The theoretical LO1 described above, can be compared'with LO1 figures obtained by direct lab measurement. The lab LO1 figures range from 0% for Sand Blast Grit to 59.3% for Precipitated Crystal waste. No samples from the Evaporated Liquids category were calcined in the lab.

Determination of LO1 in the lab has been based on the weight of the waste after drying at 110°C for 4 hours, whereas the theoretical LO1 method has been based on the sum of the weight of the anions and cations reported by Weston.

3.3 Conclusions

In accordance with 183-H Basin Mixed Waste Analysis & Test Plan (McGuffey 1994) a difference of under 10% between the two LO1 figures (compare row 3 and row 8 of Table 2 ) will. enhance the reliability of the composition characterization of Basin 183-H sludge. The waste categories Basin 4, Unknown 3 & 4 Basin solids, and Precipitated Crystals meet this criteria. In the cases where the agreement in LO1 figures is not within lo%, the waste types have an unanalyzed portion of Weston solids greater than 30%.

There is excellent agreement between row 2 and row 8 figures. Reiterating, row 2 figures are median results from Weston's analyses of 70 samples, individually, in the standard calculation method given in Appendix 3 . Row 8 figures are based on median analytical figures provided by Weston; spreadsheets of these calculations are presented in Appendix 3 . This confirms that median analytical data, presented by Weston, is a valid representation of the results of their individual sample analysis. It does not reflect upon the accuracy of their analyses which was sought to be corroborated, as a goal of this study.

Comparison of rows 6 and 7 of Table 2 shows good agreement between the wt% water in the waste types reported by Weston and that measured in the Building 377 1 ab.

4

WHC-SD-WM-TRP-243, Rev. 0

TABLE 2. Summary o f LO1 X Water Calculations

BASIN 3 BASIN 4 UNK 384 SAND B.G. PPT CRYST EVAP LIa SEEP Lla

Median LO1 I E ~ c I 6.2% 33.0% 22.8% -82.2% 52.6% -9.9% Median LOllBldp 3771 24.9% 34.1% 19.6% 0.0% 59.3% 33.9% X of Bldp 377 S?mple. 17 12 6 7 13 16

%We* Unanalyzed 31.6% 9.6% 51.1% 98.1% 10.0% 65.2% 67.9%

Analyzed

%HZOIBldg 3771 16.7% 15.4% 24.0% 4.9% 1.8% 28.6%

%H20 lW..tonl 15.0% 11.9% 23.3% 5.3% 2.1% 22.5% 22.8%

LO1 wing M d i m values 5.3% 29.3% 22.9% -33.3% 51.7% -6.6% -7.5%

MEDIAN ANALYTICAL VALUES Aig 34.4 35.1 9.5 0.4 0.3 0.3 0.3 AL 9270.0 428.0 7990.0 1565.0 375.5 7405.0 7005.0 Ea 177.0 4.4 150.0 19.9 2.0 16.5 15.7 Be 4.3 4.0 0.0 0.1 0.0 0.3 0.3 CS 7580.0 281.5 9900.0 5340.0 1520.0 149000.0 140150.0

CO 4.7 0.9 5.1 1.6 0.2 2.4 2.0 C r 202.0 168.5 110.0 8.9 4.5 37.6 25.1 cu 86500.0 81700.0 31700.0 167.9 156.5 18.4 10.3 Fe 3550.0 1470.0 7570.0 3985.0 275.5 3445.0 3485 .o Hg 2.8 13.6 1.7 0.0 0.0 0.3 0.0 K 440.0 534.5 1155.0 178.5 78.4 1680.0 1685.0

Mg 1060.0 14.7 4590.0 1028.0 349.5 17900.0 17550.0 Hn 670.0 554.0 363.0 74.4 3.8 53.7 54.4 no 5.7 5.1 0.0 1.1 1.5 2.9 2.9 Na 202000.0 222000.0 133000.0 650.5 241000.0 75900.0 73900.0 N i 74.9 75.5 49.9 1.6 1.5 16.0 13.0 Sb 8.2 10.0 0.0 6.9 1.7 1.7 2.9

S i 2680.0 3190.0 2130.0 401.0 384.5 6555.0 1595.0 T i 0.0 0.0 0.0 135.0 0.0 275.0 ’ 274.5 U 1200.0 660.0 510.0 9.8 26.0 320.0 165.0 V 31.6 1.2 32.3 3.5 0.8 5.9 5.8 2n 253.0 226.0 140.0 50.6 3.3 12.7 9.9 2r 22300.0 24500.0 9460.0 159.5 67.6 37.2 18.0 C I 82.0 139.8 584.0 53.2 32.0 802.5 688.5 F 38854.0 39650.0 18000.0 79.1 2740.0 503.5 410.0

Formate 366.0 84.7 40.7 3.3 697.0 216.0 177.0

SO4 171000.0 143000.0 59300.0 348.5 13000.0 10400.0 6750.0 N O 3 122622 358128 192123 395 635246 20031 19168 TOC 3990 4575 1893 2010 1132.5 19560 22185

UP04 676 141 284 338 52 137 227 HC03 8244 22058 8244 1741 2835 33874 25580

X Sol ids 85.0 88.1 76.7 94.7 97.9 77.5 77.4 N 27700.0 80900.0 43400.0 89.2 143500.0 4525.0 4330.0

TOC( rau) 1330.0 1525.0 631 .o 670.0 377.5 6520.0 7395.0 P 218.0 45.5 91.8 109.0 16.7 44.1 673.3

T I C ( rau) 1650.0 4415.0 1650.0 348.5 567.5 6780.0 5120.0

5

WHC-SD-WM-TRP-243, Rev. 0

183H SOIL DENSITY BASIN 3 SOLIDS

183H Soil Free Liquid Identification Confirmed? 183H-1213 (B08ZH7) 183H-1403 183H-467 (B08ZH9) 183H-1213 183H-1627 183H-106 183H-1333 183H-1527 183H-I844 183H-1478 183H-467 183H-617 183H-2157 183H-2527 183H-2585 183H-2942 183H-2978 (B08ZN2) 183H-3134 183H-1922 183H-2893 183H-2978 183H-1844 (B08ZM8) 1831-1-2463 183H-2991

2.1 N 2.1 N 2.0 N 2.0 N 2.0 N 1.9 N 1.9 N 1.9 N 1.9 N 1.6 Y 1.5 Y 1.3 N 2.0 N 2.0 N 2.0 N 2.0 N 2.0 N 2.0 N 1.8 N 1.7 N 1.6 Y 1.5 N 1.4 N 1.4 N

Density units are grams / cubic centimeter

a

WHC-SD-WM-TRP-243, Rev. 0

183H ABSORBENT DENSITY and ABSORPTION CAPACITY BASIN 3 SOLIDS

183H Absorbent Absorbance Identification , Density (% of specimen mass) 183H-1922 (B08ZN3) 183H-2463 (B08ZH5) 183H-2527 (B08ZH6) 183H-2585 (B08ZM7) 183H-106 (B08ZM5) 183H-I 21 3 (B08ZH7) 183H-1333 183H-1403 183H-1478 (BO8ZJ1) 183H-1627 (B08ZH8) 183H-1844 183H-1844 (B08ZM8) 183H-2157 (B08ZM9) 1831-1-2893 (B08ZNO) 183H-2942 (BO8ZJO) 183H-2978 (B08ZN2) 183H-2991 (B08ZN1) 183H-3134 (BO8ZJ4) 183H-467 (B08ZH9)

1 .o 1 .o 1 .o 1 .o 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.5

15 20 15 15 20 15 30 20 20 15 15 15 10 15 20 15 15 15 90

Density units are grams I cubic centimeter

16

WHC-SD-WM-TRP-243, Rev. 0

183H ABSORBENT DENSITY and ABSORPTION CAPACITY BASIN 4 SOLIDS

183H Absorbent Absorbance Identification Density (% of specimen mass) 183-H4-578 183-H4-875 (808287) 183-H4-484 183-H4-578 (B08ZG8) 183-H4-736 183-H4-736 (B08ZH2) 183-H4-965 (B08ZH1) 183-H4-1278 183-H4-472 (608ZG7) 183-H4-480 (B08ZG9) 183-H4-556 #1 183-H4-484 (808293) 183-H4-667 (B08ZHO) 183-H4-1126 (B08Z91) 183-H4-556 #2 183-H4-580 (B08Z88) 183-H4-1055 (B08Z86) 183-H4-51

1.2 1 .o 0.9 0.9 0.9 0.9 0.9 0.9 0.8 0.7 0.7 0.6 0.5 0.5 0.4 0.4 0.3 0.1

0.0 20 20 20 15 20 20 20 30 40 20 40 50 45 80 129 89

601

Density units are grams / cubic centimeter Specimen 183-H4-578 was saturated

17

WHC-SO-WM-TRP-243, Rev. 0

183H ABSORBENT DENSITY and ABSORPTION CAPACITY UNKNOWN SOLIDS

183H Absorbent Density Absorbance Identification (% of specimen mass) 90-DD-6503 1 . I 25 90-DD-6439 90-DD-6442 90-DD-6469 90-DD-6474 90-DD-6515 90-DD-6454

0.9 0.9 0.9 0.9 0.9 0.8

35 40 30 30 25 40

SANDBLAST GRIT

183H Absorbent Density Absorbance Identification (% of specimen mass) 89-DD-66 0.9 30 89-DD-06 0.8 25

P REC I P ITATE D C RY STALS

183H Absorbent Density Absorbance Identification (% of specimen mass) 90-DD-1905 0.8 35 90-DD-1813 0.5 84

Density units are grams I cubic centimeter

18

WHC-SD-WM-TRP-243, Rev. 0

183H ABSORBENT DENSITY and ABSORPTION CAPACITY S 0 LID I FI ED SEE PAG E Ll Q U I D S

183H Absorbent Density Absorbance Identification (% of specimen mass) 90-DD-4967 0.7 94 90-DD-5102 0.7 80 90-DD-4916 90-DD-2969 90-DD-3373 90-DD-4031 90-DD-3013 90-DD-3018 90-DD-3039 90-DD-3073 90-DD-3259 90-DD-3268 90-DD-3469 90-DD-3686 90-DD-3987 90-DD-4048

0.6 0.5 0.5 0.5 0.4 0.4 0.4 0.4 0.4 . 0.4 0.4 0.4 0.4 0.4

100 134 139 165 149 160 154 155 159 180 170 155 150 160

Density units are grams / cubic centimeter

20

Cmlslnd Compound M.lahi Belance Mob./ Mob Famub WdgM W d ~ W

kg 101.n. Fmcllon Compomd WdgN [ p ) Franion Mob Wdn 3.52E-03 423E-MC.3(P04)2 310.1828 1 . W - 0 3 131E-01 128E-03 1.55E-04 8.0 1535384 3.ME-M 237E-02 ~ ~ B E - O Z J Z ~ E - O ~ MOO 403044 2.71E-03 2.11E-01 3.lSE-04 3mE-05AgO 1238874 8 . M - 0 5 4.7.E-03 3876-03 4.85E-04 2nO 813684 495E-04 318E-02 3.88E-03 4EE-04 N.2004 1819732 0.7oE-04 7.5Y-02 1.13E-02 135E-03 KOH E5.1oB4 . 8.74E-04 758E-02 1.74E-01 2.08E-02 -0 58.0784 1.5OE-02 1.17EIW 3.44E-01 4.12E-02 NaNO2 81.8701 4.34E-02 338E1W 8aeE-w 7 ~ 3 ~ 4 N.F.OP ll0835a l . M - 0 2 8 , s - 0 1 851E-02 1.lK-02 N.4904 184MZE 2.7lE-02 2 . l l E t W 2.44E-01 2.W-02 ZrO2 1232188 4 .84 -02 382EtW 2.48E-01 28SE-02 N.2C03 1 0 5 M 8 4.02E-02 3.13EtW 1 .%E+ W 1.83E-01 CuO 78.5454 1.87E-01 13G++O1 1.22E-02 1.48E-03 Uno2 88.8378 l.83E-03 127E-01 1.78E+W 2.14E-01 Na2SO4 1420412 3.8OE-01 304Et01 P.OSE+W ZAJE-01 NaF 419882 1.32E-01 1.03Et01 l 9 8 E t W 227E-01 NaOH 389872 1.17E-01 8.OBEtW 2.3lE-03 2.78E-04 N a a 58.4428 2.08E-04 1.82E-02 O.WE+W O.WE+W N ~ T I O J 1419778 O.WE+OO O.WE+W 5.O.E-03 8.ME-04 U03 288.0282 2.22E-03 1.73E-01

8.33 77.88

M.1.hlc.Uon. It. m. Id Ail 107.W N 8. 8. c. Cd CO C, C" Fe HO K Mg M" MO Na NI Sh S* SI

U V 2"

n

28982 137.33 8.0122 u).oB

11241 58.833 51 ,888 83.5.8 55.847 200.58 38.W8 24.305 54.838 8594 2298

58.7 121.75 7898

ZB.OQ8 47.90 238.03 50.942

8122 8538

Won. F~mwl.(o) U 35.453 F 18.888 Frm.ls 43.018

827Et03 1.77E+02 425E+W 7.38Et03 2 .7E+W 4.70EtW 2.02E+02 8.85Et04 3.55Et03 2.90EtW 4.4OE+OZ 1.mEt03 8.70Et02 5.70EtW 2.02EtOS 7.4SEtOl 8 2 E + W 5 .W-01 2.88E+03 O.WE+W 1.20Et03 3.18Et01 2.53Et02 2.23Et01

337852

3.44E-01 2.58E-03 1.28E-03 9.43E-04 4.72E-04 3.88E-01 1.84E-01 4.8OE-05 2.4OE-05

7.88E-05 3.88E-03 1.38E+W 8.38E-02

2.78E-05 1.u)E-05 1.13E-02 1.13E-02 8.72E-02 4.38E-02

122E-02 5.84E-05

8.7SE+W 8.7SEtW 128E-03 8.74E-05 8.33E-08 8.W-02 O m E t W 5.04E-03 Sum 8rnE-04

3.87E-03 3.87E-03 2.44E-01

8.281

An. Equk. IEq&P) 2.3lE-03 2.31E-03 2.05EtW P.ME+W 8.13E-03 8.13E-03

28.018 l.WE+W 8.15E-05 8.15E-05 88.058 1.7lEIDJ 3.%E+M 1.78E+W 82.005 123EIO5 1.88E+W 1.88EtW

CN S M NO3 TOC 38.033 3.88Et03 1,llE-01 1.11E-01 H P M 85980 8.78Et02 1.41E-02 7.04E-03 C03 81.017 824Et03 2.70E-01 1.35E-01

Syll 345838 7.888

Sum Y.W.IWonr en2587 1272 Wlton % Sdds 85.0

NO3:m.Uloi N*((14.0087+ 3*15988*/14.OOBil TOG msUI lor T0C.l; lo repmunt unspehl.d suboxy8s add adon.

C03 r .~u~l~lol . l lwgardc urhon'((12.011+3'15.8884)l12.011)

R B i ~ ~ i 6 a ) s h g ~ u d l B A S l N ~ 8 - J ~ y - l M 5

PH 11.8

H P O ~ resun for ~*( i~) .s7i+~. i5 .8884+ i .w78)m.e7~)

lW-%Wadonadyz.d 31.8% SmPb II.PPm luulyle 0ASN3 mid- Ao 34.4 C&(p04)2 N 8270 8.0 8.

c. Cd ca cr C" FB HO K MO U"

e.

MO N. NI Sh 5. SI

U V 2" 2,

F Famue CN S M NO3 TOC HPO4 w3 PH %SoUds

n

a

2.7 HWRO4 4.7 KOH

202 a0 88500 NaN02 3550 N e e m

2 8 N.4904

p(L8 MI" 1.1 0 2 1.8 O D

0.8 0.8 9.7

282 7.0

17.8 30.1 28.1

,083

oa

5.7 MOM 1.1 202WO NWSO4 252.8

749 NaF 85.8 82NeOH 75.8 05 NaU 0 ,

5.7 MOM 1.1 202WO NWSO4 252.8

749 NaF 85.8 82NeOH 75.8 05 NaU O ~ l ~.

2880 N . 2 W 3 0.0 0 U03 1.1

12w Sum 8472 31.8.

22300 253 L a i w 5.3%

82 38854

2aa 1 .e

171WO 122822

3990 878

8244 11.8

85

s

3

n I v) 0 I

I I P W I N W a "

P (0 < 0

S m p k

A9 Me1alrlC.Uonr

U 0. 0. c. cd c4 cr C" F. H9 K MP M" Llo N. NI Sb 5. si

u V 2" ZI sun

n

N P

UNK3h4 Weslon Labr&mlyY*

M.W.(DI (I,ppm IEqlLDI ImoVLDI 0 1 . Equiu. MoleCons.

107.888 9SOEtW 8.81E-05 8.9lE-05 28382 738Et03 2.98E-01 137.33 1.5UEtOZ 2.18E-03 1.09E-03 8.0122 O.mE+w OmE+W O W E t W 40.08 8BOEt03 4.84E-01 2.47E-01

112.41 3.80EtW 8.4lE-05 32OE-05

51.898 I.IOEt02 2.12E-03 83.548 3.17EtM a.98E-01 55.847 7.57E103 l.%E-Ol 2W.58 1.70E+W 1.88E-05 8.47E-08 3 9 . W l.lBEt03 2.85E-02 2.95E-02 24.305 458Et03 3.78E-01 1.88E-01 54.93a 3.83Et02 8.81E-03 85.94 O.WE+W O.WE+W 22.89 1.33Et05 5.79EtW 5.79EtW JB.7 4.90EtOl # .ME-M

121.75 O.WE+W O.WE+W 78.98 l.lOE+W 1 3 E - M

28088 2.13Et03 7.JBE-02 47.80 O M E t W O.WE+W

238.03 5.10Et02 2.l4E-03 Sum 50.942 323EIOl 8.34E-04 65.38 1.40E102 2.14E-03 2.14E-03 81.22 B.UEt03 1 .ME -01

58.933 5.1OE100 8.8s&m

ZOllfl7lZ B.89l

A n EoW. Anions FarmW.ld I I.PPm

a 35.453 5.84€+02 F 18.988 l . M E + O I Fwn.C 45.018 4.07Et01 CN 28418 1.4oEtW SO4 98.058 5.83Et04 NO3 62,005 132Et05 TOC 38.033 1.88EtO3 WO4 85.9W 2.84Et02 HC03 81.017 824EIO3 SWl 2BOI70 PH 8.9 Sum MehIrlAnlonr 489341 1.199 Weslon % Solids 78.7

IEqn9l l.85E-02 1.85E-02 8.47E-01 9.47E-01 9.ME-04 @.ME-M 5.38E-05 %%E-05 1.23EtW 8.17E-01 3.lOE+W 3.lOEtW 52--02 5 2 5 - 0 2 5.82E-03 2.98E-03 1.35E-01 1.35E-01

5.492

ka soln. Fzadbn c4npound l.4BE-03 2.54E-04 WIP0412 1.09E-03 1.87E-048a0 1.88E-01 324E-02 M@ 8.81E-05 ldlE-05ApO 2.tU-03 367E-042nO 2.12E-03 3S3E-04 N.2004 Z J K - 0 2 5.07E-03 KOH 2.43E-01 4. t€€-0200 2.98E-01 5.M-02 NaIK)Z (.%E-01 2.33E-02 NaFeOe 7.58E-02 1.30-02 N.45104 I.ME-01 1.7UE-022102 IS( IE-Ol 322E-02 N e w 3 4.99E-01 8.58E-02 CuO 8.8lE-03 1.13E-03 Mn02 8.17E-01 (ME-01 N.2904 9.47.E-01 163E-OI N.F 2.47EtW 424&0l NaOH 1.65E--02 2 -43 N K i O M E t W 0,OOEtW N U W 3 2.14E-03 3.68E-MU03

5.83

F o r m a Welpht Id

310.1828 1533384 4 0 M u

123-74 81,2894

181.9732 58.1W 68.0794 81.9701

1106358 194.0428 1232188 lM.0889 79-54 88.8378

142.0412 413082 3S.Se72 58.448

141.8778 288.0282

Wcl9N mlpW Fmdion Mob 0!dm 12 IE-M 767E-02 4.43E-M 237E-02 ZJlE-02 l.31EtW 269E-05 1S7E-03 46lE-04 2.9SE-02 %=E-04 5.98E-02 4.30E-03 2.84E-01 3.80E-02 233EtW 8.42E-02 4.17EIW 337E-02 2JE+w 3.8eE-02 I . a E + M 338E-02 2 . leEtm 52BE-02 3.41E+W I.ME-01 8S lE+W 1.52E-03 8.86E-02 2.32E-01 lSOE+Ol 1.05E-01 863EtW 2.81E-01 1.7DEtOl 2.55E-03 IS5E-01 O.WE+W O M E t W 1.82E-03 1.05E-01

84.88

H9 K Mu M" MO N. NI Sb 5. 81

U V 2"

n

21

F a

FOrrn.1. CN ' SO4 NO3 TOC HPO4 HC03

%SoUd% PH

1.7 N.45104 1155Zr02 4590 NUC03 383 c u o

0 Uno2 133000 N.2904

493 NaF

1.1 NaU

0 U03

0 NaOH

2130 NU~OI

510 Sum 32.3

8480 58.

lSM0 a . 7

1.4

192123 1893 284

8244 83

76.7

IM La(w

5 9 3 ~

8/L0 soin 0.5 02 7 3 0.0 0 2

1.7 oa

13.0 24.3 15.0 144 124 I O J 39.7 0.8

87.1 30.8 98.8

0.0 0.6

377.5

in

22.8%

c z x z 0 z W

a a

P

3 a

c) I u) 0 I

I

-0 I N P w " W m < 0

F. H9 K Mil M" MO N. NI Sb Se SI

U V

n

28.982 7.41EtO3 137.33 1.85Et01 2.WE-04 8.0122 3.ME-01 8BBE-05 40.08 1.48EtO5 7.44EtW

112.41 3WE-01 5.34E-OB 58.833 ZAOEIW 61.888 318Et01 83.548 184EtOl 55.847 3.45Et03 2W.58 3.WE-01 2-E-08 38088 l.ME+03 4.m-CQ 24.305 1.79EtO4 1 1 7 E + M 54.838 5.37EIOl 85.84 2.80EtW

58.7 IBOEtOl 121.75 1.70Et00 78.88 8.WE-OI

28.088 838EtO3 47.00 2.75Et02

238.03 32OE+02 m.842 5 9 0 E t W 65.38 127Et01 l.84E-04 81.22 3.72Et01

282887.1 12253

n.98 7.58Et04 3.30EtOO

MolaConc. (momill 2.78E-OB 2.74E-01 1.20E-M 3.33E-M 3.72EtW 2.87E-OB 4.07E--05 7.23E-M 2.BOE-04 8.17E-02 1.50E-08 4.30E-02 7.35E-01 8.77E-04 3.02E-05 3.30EtW 2.73E-04 ,.WE-05 1.14E-05 2.33E-01 5.74E-03 1.34E-03 1.18E-M 1 .84E-O4 4.MIE-04

U

Anions FamW.ig) 1 I.ppm U 35.453 8.03EtM F 18.888 5.04Et02 Famala 45.018 2.18Et02 cn 28.018 3 . W - 0 1 so4 M.058 I.04EtO4 NO3 82.W5 Z.WE+M TOC 38.033 l S 6 E t M PO4 84.972 1.37Et02 w3 8O.WB 3.3SEtO4 Sun 85524 PH 132 Sum Melalrlhlons 34821 1 Maon % SoYds 77.5

An. Equiu. (Eqn i l l 22BE-02 2.28E-02 2.65E-02 2.85E-02 4.WE-W 4.BOE-03 l.lSE-05 l.15E-05 2.17E-01 1.00E-01 323E-01 3.23E-01 5.4s-01 5.UE-01 4.33E-W l.44E-03 1.13EIW 5.8IE-01

2270

8,983

Calslwd Compound hlerhl Balance Mob# Mob

kg r d n . Fnctlon Compound 7.21E-04 127E-04 Ca3IPOB2 1.20E-04 2.12E-M 0.0 7.38E-01 1.3OE-01 Up0 2.78E-08 4 . W - 0 7 Ago 1.84E-04 3.43E-052nO 7.23E-M 8.38E-05 a 0 3 4.30E-02 7.586-03 KOH 2.50EtW 4.4lE-01 C.0 2.74E-01 484E-CQ NuU02 8.17E-02 5.4.E-03 Fe203 2.33E-OI 4.12E-02 Si02 ..ME-M 7.lSE-05 2102 1.1 l E + W l.85E-01 N U W 3 2.80E-04 5.11E-MCuO 8.77E-04 1.72E-MMn02 1.08E-Ol l J I E - 0 2 N U S U 4 2.65E-02 4.87E-W NaF 5.47E-01 8.8IE-02 NaOH 2.28E-02 3.98E-03 NaU

1.34E-03 2.37E-04UOJ 5 . n - 0 3 i . o i ~ - o 3 no2

5.87

F o m a W . W (a)

310.1828

40.3044 1236871 81.3584

1518802 58.1084

81.8701 158.8922 80.owa

l 2121W 1058W 78.5454 ea8378

(42.0412 41.8882 38.9872 58.4428

m a 3 8 4

=a784

W*CM wpw R a d o n Mob C.161- 8 O l E - M 3.85E-02 4.85E-05 32JE-03 7.WE-02 523E+W 8-E-07 8.08E-05 425E-OS 2.786-03 IABE-O~ S.BSE-OJ 8.48E-03 425E-01 3.77E-01 2.47Et01 @.ME-02 3 8 7 E t W 1 . W - 0 2 0.88E-01 3.77E-02 2.47E+W 135E-04 8B8E-M 3.lJE-01 2.07EtOl 8.18E-05 4.OBE-03 2.28E-04 1.5OE-02 4.l3E-02 2.71EIW 2.8OE-03 1.88E-01 5.88E-02 3.MEtW 3.58E-03 2.33E-01

78.8888 1.23E-03 %WE-02 288.0282 1.03E-03 8.78E-02

85.82

I W - X Weaon .Wzed *P* II,PPm ANlW EVWLIO Wdn A0 N 7105 8.0 0. 18.5 MOO 0. c. Cd co cr CY F. Hg K Mil M" Ma N. NI Sb 1.7 NaOH 5. 0.8 NaU

n 275 U03 U 320 Sum V 5.8 2n zr 37.2 U 802.5 F €43.5 F a n a b 218 CN SO4 NO3 TOC PO4 C03

852%

0.3 C.3(POIj2

61 8555 no2

12.7 L a ( q j

PH %SoUds

0.3 M-0 14Sa-3 2nO

2.4 KOH 37.8 C.0 18.4 N-2

3445 Fe203

1880 a02

53.7 cuo

oa 0203

oa SIM

17800 NUC03

~~

0.3 l o a n 2M31 18580

137 33874 .

132 77.5

mil .Ob

0 2 0.0

29.7 0.0 0.0 0.1 2.4

I102 22.5 9.8

0.1 117.4

0.0 0.1

i i a

0.4 378.2

-8.0%

W 2 0

N 03

SUnPb

M U 8. ae ca Cd co a CY FC Hg K Mg M" MO N. NI Sb

Metelr/CstiOnr

EVAP Lio Westton Lab. Amlyds

4. WL. I@ 11. P P ~ IEqAgI -1. Equiv.

107.888 3.WE-01 2.78E-08 28.882 7.4 lEt03 137.33 1.65EtOl 2.40E-04 8.0122 3.00E-01 8.88E-05 40.08 1.48E105 7.44E+W

112.41 3 .W-01 5.34E-08

51.888 3.78EtOl 58.833 2.40EtW

m . 5 a 184EEtOi 55.847 3.45Et03 2W.58 %WE-01 2.98E-06 38.088 1.88Et03 4.30E-02 24.305 1,78E+O* 117E+00 54.838 5.37EtOi 95.84 2.80EtW

58.7 1.8OE+Ol 121.75 1.7OEtW 7a.M 8.OOE-01

47.80 215Et02

50.842 5 . W E t W 85.38 1.27EtOl 1 -9s-04 81.22 3.72Et01

262807.1 12.253

22.88 7.58Et04 3JOE+W

28.088 8.58EtO3

238.03 3 2 0 ~ t a z

MobConc. (mom@ 2.78E-08 2.74E-01 1.20E-04 3.33E-05 3.72EtW 2.87E-08 4.07E-05 7.23E-04 2.80E-04 8.17E-02 1.50E-W 4.30E-02 7.38E-01 8.77E-04 3.02E-05 3.3oE+w 2.73E-04 1.40E-05 1.14E-05 2.33E-01 5.7s-03 1.34E-03 1.18E-M 1.S4E-04 4.WE-04

An. EqulY Anion$ Form WLId 11. PPm I E q i W

a 35.453 8.03E+02 2.28E-02 2.28E-02 F 18.888 5.04EtOZ 2.85E-02 2.85E-02 Formete 45,018 2.l8EtOZ 4.8OE-03 4.80E-03 CN 26.018 3.00E-01 1.15E-05 1.15E-05 SO4 w.058 1.04EI04 2.17E-01 1.08E-01 NO3 82.W5 2,WEtM 3.23E-01 3.23E-01 TOC 38.033 1.88E+O4 513E-01 5.UE-01 PO4 84,872 1.37Et02 4.33s-03 1.44-03 C03 Bo.008 3.39Et04 l . l J E t 0 0 5.6*-01 svm 85524 2.270

s u m UcWUAMone Weston % Solids

pn 13.2 Ma211 8.983

77.5

N03: resun for N*((l4.W87+ 3'15.SSSlll4.mS7) TOG resun lor TOC.3; lo reprexnl unrpeclaled carboxylic acid aMans P04: ~ I Y X tar P'((30.874+4*15.88841~0.874~ C03: m s u I lor lolai Inorganic wbon*(( lZ.Oli +3'15.8994)112.011)

s u m

W c i w d Compound Matmirl0e!ance MoCU Mob kg s0I.n. Fradon Gempound 7.21E-04 128E-04 W(PO4)P 1.20E-04 2.13E-05 8.0 7.38E-01 1.31E-01 MgO 2.78E-08 483E-07 Ago 1.84E-04 3 . M - 0 5 ZnO 3.82E-04 3 2 1 E - 0 5 W 0 3 4.30E-02 7.82E-03 UOH Z.ME+M 4.43-01 CaO 2.7s-01 487E-02 N d O 2 3.WE-02 2.73E-03 Fe203 2.33E-01 4.14E-02 8102 4.08E-04 723E-05 Zl02 1 . l t E + W 1.88E-01 NaZC03 2.90E-04 5.13E-05 CUO 8.77E-04 1.73E-M Mn02 *.WE-01 1.82E-02 NUS04 2.85E-02 4.70E-03 NaF 5.47E-01 8.SSE-02 NaOH 2.28E-02 4.01E-03 N a a

1.34E-03 2.39E-04U03 5.74E-03 I.OZE-O~ no2

5.84

F P m h Welpht lsl

310,1828 153.3394 40.3044

123.8874 81.3504

1518802 58.1084 58.0784 81.8701

158.8822 80,0848

1232188 105.8888 78.ys4 88.8378

142.0412 41 .SUB2 38.8872 58.4428 7 8 m M

286.0282

WaIgM WdghV Fm&n MobWdm 8.05E-04 3.87E-02 4.88E-05 3.27E-03 8.WE-02 5.28EtW 8.32E-07 8.11E-05 428E-06 2.WE-03 7.43E-05 4.87E-03 8.52E-03 428E-01 3.78E-01 2.4SEtOl 8.08E-02 3.88EtW @.WE-03 4.37E-01 3.78E-02 2.48E+W 1.38E-M 88lE-03 3.18E-01 2.08EtOl 8.23E-05 4.08E-03 2.30E-04 1.51E-02 4.18E-02 2.73EtW 3.01E-03 1.87E-01 5.82E-02 3.88EtW 3.58E-03 2.35E-01 1 2 s - 0 3 8.13E-02 1.04E-03 8.82E-02

85.54

CALCINATION ASWMPTIONS: 1.M.N.preeenlar mate. 2. W nbals calcined Io glve hydroxide and reacts furthe, l a make N-02. 3. No spec*suolatillzed except HZO and N2102

4.41 01g.M~ carbon converted 10 &anale

5. Phosphate reads prefemntWiy with Ca IMg. h f m m oxlde%%xce*2 Ca as -01. 8 . 0 , Fa. and SI m . k e oxldar. U makas N.402 hm NaN03 UISIIIC. 7. Fluoil&, chlorlde. sulflita, &onate l a m rodlum d*:

(ham &conpodtion olnitrau).

IC02 hom TOC oxidallan captured by NaOH.

.exsesl Fodium accounted as hydrorlde.

COMMENTS ON WESTON (AOUEOUS) ANALYSES: 1, Analyt. material b a h c e @OW 34821 1 ppm)

2. Cauonlanion balanu 001 good (h cations as anions: probably dus l o ca hydroiyslsl. 3. Anion -lactian (CO3.PO4) sonsistent

4. Msbisthalue CationlcaIpH '-13.2Ue

DOES NOT compare wfih 77.5 W Iollds reported.

wfihpn 132 obuwed.

Ag. 0% 0% Ca. Cd. Hg. I(, Mp, Ne.. and Zn

olhars(e.p.. l i a n ~ o n m e W % a n d e x c e s ~ Ca) me hydrolyr-d 10 maka hydrous oddas 1e.g.. Z102xH20 and -01.

5 . Appusnliy, Incomplete dlsnalution occurred In analyzing

and react with PO4lSO4lCO3lCl arlorm nXR(Ie -%:

1W - X Weslon a ru lpd 852% svnple ~ I .PP~ Anrrlyia E V W U O WdN As oa w ( ~ 0 1 1 2 4 7- 0.0 0. 18.5 Me0 0e 0.3 Ago ca 1 m Z n O Cd 0.3 u 2 0 3 CO 2.4 KOH a C" F.

37.8 cao 18A NaN02 Jus F U 0 3

0.3 SI02 1880 no2

178w NaZCO3 53.7 C"9 2.8 MnM

Na 758W NUS04 Ni 18 NaF Sb 1 .7 NaOH SC 0.8 N a a Si 8555 no2 n U V 2" 28 CI F Formate CN SO4 NO3 TOC PO4 C03 PH %Solids

275 U03 320 Sum 5.8

12.7 L U ( d d 3 7 2

802.5 503.5

218 0.3

10400 2M31 18580

137 33874

1 3 2 77.5

SmP =In 0.2 0.0

29.7 0 0 0 0 0.1 2.4

140.2 22.5 4.8

14.0 0.1

117.4 0.0 0.1

15.4 1.1

21.8 1.3 0.5 0.4

371 2

-8.8%

P

3 A F

c) I v) 0 I

I N P w "

P ID < 0

R0iyanlbCDelegud/EVAPLlO~8 -July- 1885

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