s333 stage linked to s333 tp regime shifts - uf/ifas...
TRANSCRIPT
Abstract
Background Field Collection
Materials and Methods
Preliminary Conclusions
As stages in the Water Conservation Area 3A (WCA-3A; Fig 1,2) decline the L67A
canal rather than the marshes conveys the majority of the flow into the
Everglades National Park (ENP). Canal water is typically of poorer quality than
marsh water because canal water has not benefitted from the marsh filtering
removal quality of nutrients. Low stages are associated with high TP levels at
S333. Canal flows, especially at low stage, have the potential of re-suspending
and remobilizing nutrient-rich sediments that accumulate at the bottom of canals.
These phosphorus-rich sediments can be rapidly transported downstream while
contributing part of their P load to canal waters to finally reach the park (Fig 3).
Another potential contributing factor to high phosphorus levels is varying
environmental conditions such as wet and dry seasons, peat oxidation, weather
events, and wildfires.
Research Question
What are the mechanisms responsible for increases in
TP concentration in Everglades canal waters when
water level declines?
The Objectives of this work are:
1- Determine the sources of the elevated TP at S333
2- Establish the most relevant mechanisms driving TP dynamics at S333
Objectives
Cumulative Sum charts
for TP, plotted along the
DO, Turbidity, pH and
sampling time gradients
highlight the thresholds
(red arrow) where TP
changes from below to
above average
concentration.
Similar relationships
TP:WL occurring region
wide suggest
commonalities among
sites in WCA-3A and
perhaps EAA
- There are clear relationships of TP with WL, DO, Turbidity, pH and sampling time (diel
cycle) with thresholds separating hi from low TP waters.
- Although some increase in TP may be due to changing proportions of contribution from
marsh vs upstream canal, a local source from deposited sediments and floc seems an
interesting alternative.
- Changes in the hydraulic geometry of the canal due to declining WL may stir and erode TP-
rich bottom sediments and floc, increasing TP concentration in the water column.
- We are testing this initial hypothesis by collecting and analyzing waters, sediments and floc
during different WL conditions, and especially during critical stages, when approaching and
when reaching the WL threshold
Acknowledgements
This study is part of the NPS funded project “Mechanisms and Conditions Responsible for Elevated TP Levels in Surface
Water Discharges to Shark River Slough within Everglades National Park”, and the NSF funded “Florida Coastal
Everglades Long=Term Ecological Research Project”
ReferencesJaya Das, Samira H. Daroub, Jehangir H. Bhadha, Timothy A. Lang and Manohardeep Josan. 2012. Phosphorus Release and Equilibrium
Dynamics of Canal Sediments within the Everglades Agricultural Area, Florida. Water Air Soil Pollution 223:2865–2879
Katsaounos, Ch., D. L. Giokas, I. D. Leonardos, M.I. Karayannis. 2007. Speciation of phosphorus fractionation in river sediments by
explanatory data analysis. Water Research, 41:406-418
Pisani, O., L.J. Scinto, J.W. Munyon, R. Jaffe. 2015. The respiration of flocculent detrital organic matter (floc) is driven by phosphorus
limitation and substrate quality in a subtropical wetland. Geoderma (241-242) 272-278
Reddy, K. R. , Newman, S. , Osborne, T. Z. , White, J. R. and Fitz, H. C.(2011) 'Phosphorous Cycling in the Greater Everglades Ecosystem:
Legacy Phosphorous Implications for Management and Restoration', Critical Reviews in Environmental Science and Technology, 41:
6, 149 — 186
• Profile measurements (YSI cast): Temp, DO, depth, Cond, Sal, pH, Turbidity
• Surface and bottom waters sampling
• Bottom sediment and floc sampling
• Canal water flow profiles
• Water samples are analyzed for ammonium (NH4+), nitrate+nitrite (N+N), nitrite (NO2-),
total nitrogen (TN), soluble reactive phosphorus (SRP), total phosphorus (TP), total
organic carbon (TOC), silicate (SiO2), chlorophyll a (CHLA), and turbidity using standard
laboratory methods.
• Floc and bottom Sediments collected by pumping and dredging respectively are
subjected to fractionation in i) 30ml deionized water (plant available and water
extractable P; TP-H2O), (ii) 0.5M NaHCO3 (pH ¼ 8.2) (weakly sorbed-bioavailable
organic and inorganic P; TP-HCO3), (iii) 0.1M NaOH (strongly bound chemisorbed P-
potentially bioavailable; TP-NaOH) and (iv) 1M HCl (apatite or Ca-bound P non
bioavailable;TP-HCl)
Total Phosphorous Levels in Surface Water Discharges to Shark River Slough,
Everglades National Park
Joffre Castro1 Henry Briceño2, Piero Gardinali21 National Park Service, Everglades National Park
2Southeast Environmental Research Center
Florida International University, Miami, FL
Monitoring and current studies have identified a strong correlation between
Total Phosphorous (TP) at structure S333 (inflow structure to ENP) and canal
stage. Waters from upstream S333 (along the L67A and L29 canal) are mostly
the results of managed deliveries by the SFWMD and the exchange with
freshwater marshes and groundwater. The conditions and mechanisms that
cause elevated TP are unknown. Some may result from changes in natural
conditions but others may be the direct result of anthropogenic actions. Water
levels in Everglades marshes and canals are closely tied to management and
climate variability. The purpose of this study is to identify the sources of the
elevated TP at S333 and, if possible, characterize them as to be from either
local effects and conditions at S333 or upstream of S333 within the L67A
Canal, L29 Canal or the WCA-3A marsh.
SOURCE:
c= canal
m= marsh
u= upstream
g= ground
s=sediment
CONCEPTUAL MODEL
L29
S152
S333
WC3A
ENP
S12D
Study Area
COMPONENT:
W= water
S= Sediment
Preliminary Results
• Exploration of existing datasets (SFWMD, EDEN, USGS) confirms significant
correlations between TP concentrations and WL, pH, Turbidity, Dissolved oxygen and
even sampling time of the day (Fig 4 to XX)
0
0.005
0.01
0.015
0.02
0.025
0.03
6 6.5 7 7.5 8 8.5 9 9.5
mg
/L T
P
S333 H stage (ft)
S333 Stage linked to S333 TP Regime shifts S333 TP Weighed mean TP
Regime Shift Analysis
• We confirmed the inverse WL:TP relationship for stations connected to WCA3-A
(S151, S152, S12D, S344 and even S150 located in the Everglades Agricultural Area
(EAA) . In all of them there is a significant WL threshold (system shift) separating
above from below average TP (Fig 5, 6). Main thresholds are between 7 and 8 ft WL.
-5
0
5
10
15
20
25
30
35
5 6 7 8 9 10
TP
Cu
sum
S333 WL (ft)
S333 TP cusum
Below average TPAbove average TP
-2
0
2
4
6
8
10
12
6 7 8 9 10 11 12
TP c
usu
m
Water Level S150 T
TP cusum
Above average TP
Below average TP
-2
0
2
4
6
8
10
12
14
16
6.5 7.5 8.5 9.5 10.5
Cu
sum
WL (ft)
S152 (DPM) TP cusum
Above average TP Below average TP
-100
-90
-80
-70
-60
-50
-40
-30
-20
-10
0
0 5 10 15 20
TP C
usum
Turbidity
TP S333
1.5 ft
-20
-15
-10
-5
0
5
0 5 10 15 20 25
TP C
usu
m
Turbidity (NTU)
TP S333
3.1 NTU
-14.0
-12.0
-10.0
-8.0
-6.0
-4.0
-2.0
0.0
2.0
4.0
6.00 6.50 7.00 7.50 8.00 8.50
TP C
usu
m
pH
TP S333
7.58
-10
0
10
20
30
40
50
60
70
0 4 8 12 16
TP C
usu
m
Dissolved Oxygen (mg/l)
TP S3333.4 mg/l
S150
S151
S333S12D
S344
S152
0
1
2
3
4
5
6
7
8
9
10
6 6.5 7 7.5 8 8.5 9 9.5 10 10.5
TP c
usu
m (
SD)
WL S151 H (ft)
TP cusum
Above average TP Below average TP
-4
-202468
10121416
7 7.5 8 8.5 9 9.5 10
Cu
sum
WL S12D
TP S12DA cusum
-50
-40
-30
-20
-10
0
10
7:12 9:36 12:00 14:24 16:48
TP c
usu
m
Day time
TP S333
11:25
Wc
Wm
Ws
WgWc
WcWc Wm
Wc
Wg
Wu
Sm
ScSc Sm
Sc
Su
Sb