safety data sheet cement - secil group...safety data sheet cement section 1 details of the mixture...

SAFETY DATA SHEETCEMENT

Section 1Details of the Mixture and the Company

1.1 Product details

Name for notification

Packing capacity

REACH-register

Clinker for Portland cements EINECS:266-043-4 (1) • CAS: 65997-15-1

Bulk40kg and 25kg sacks

Clinker for Portland cements is exempt from the REACH register in accordance with Art. 2.7 (b) and Annex V.10 of this Regulation.

(1) Code assigned to Portland cement but also describes clinker for Portland cements. C&L reference number: 02-2119682167-31-0000

Commercial name (in accordance with NP EN 197-1: 2012)This Safety data sheet applies to cements produced or marketed by the Company, indicated below, notwithstanding its application to other cements that the Company may produce and market.

• Portland Cement CEM I 52,5R and CEM I 42,5R• Portland Limestone Cement CEM II/A-L 42,5R• Portland Limestone Cement CEM II/B-L 42,5R and CEM II/B-L 32,5N• Portland Pozzolana cement CEM IV/A (V) 32,5R - SR and CEM IV/B

(V) 32,5R - SR• Portland White Cement CEM I 52,5R (br)• Portland Limestone White Cement CEM II/A-L 52,5N (br)• Portland Limestone White Cement CEM II/B-L 32,5R (br)

1.2 Identified uses of the mixture and non-recommended uses Cements are used in industrial facilities for the production / formulation of hydraulic binders, for use in building and construction, such as ready-mix concrete, mortars, plasters, grouts, stucco and prefabricated concrete.Common cements and mixtures containing cements (hydraulic binders) are used industrially, by professionals and consumers in the production of construction materials and in construction activities, inside and outside. The uses identified for cements and mixtures containing cement include dry products and wet suspension products (paste).See section 16.2 for more information on the uses of the mixture and hazard categories.Any uses not mentioned above, are not recommended.

1.3 Details of the supplier of the safety data sheet SECIL - Companhia Geral de Cal e Cimento, S.A.Outão - Apartado 712901-864 SetúbalTel.: 212 198 100

1.4 Emergency telephone numberEuropean emergency number: 112Anti-toxins Information Centre (CIAV):24 hour number: (+351) 808250143Language: Portuguese

SECTION 2Identification of Hazards

2.1 Classification of the mixtureIn accordance with Regulation (EC) No. 1272/2008

Hazard warningsH318: Causes serious eye damageH315: Causes skin irritationH317: May cause allergic skin reactionsH335: May cause respiratory irritation

2.2 Label elements In accordance with Regulation (EC) No. 1272/2008


Precautionary statementsP102: Keep out of reach of childrenP280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338+P310: IN THE EVENT OF CONTACT WITH THE EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if possible. Continue rinsing. Immediately call a doctor or the Anti-toxins Centre.

P302+P352+P333+P313: IN THE EVENT OF CONTACT WITH THE SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs seek medical advice/attention.P261+P304+P340+P312: IN THE EVENT OF INHALATION::Avoid breathing dust, fumes, gases, mists, vapours, aerosols. Remove victim to fresh air and keep at rest in a position that is comfortable for breathing. If you feel unwell, contact a doctor or the Anti-toxins Centre.P501: Dispose of contents/container (package) at a waste treatment facility in accordance with national legislation.

2.3 Other hazardsCement does not meet the criteria for PBT or vPvB in accordance with Annex XIII of REACH (Regulation (EC) No 1907/2006).

SECTION 3Composition/information on ingredients

3.1. SubstancesNot applicable (this safety data sheet is for a mixture).

3.2. MixturesCommon cements in accordance with NP EN 197-1:2012.

SECTION 4First aid

4.1 Description of first aid measures

4.1.1 GeneralNo personal protective equipment is needed for first aid responders, but they should avoid contact with wet cement or mixtures containing wet cement.4.1.2 Following contact with eyesDo not rub eyes in order to avoid possible cornea damage due to friction. Remove lenses, if worn. Incline head to the side of the injured eye, open the eyelid(s) wide and rinse eye(s) immediately with plenty of clean water for at least 20 minutes to remove all particles. If possible, use isotonic water (0.9% NaCl). Contact a specialist in occupational medicine or an eye specialist, preferably an

ophthalmologist.4.1.3 Following contact with skinDry cement: Remove the cement and rinse abundantly with water.Wet cement: Wash skin with plenty of water. Remove contaminated clothing, footwear, watch, etc. and clean thoroughly before re-use.

Seek medical treatment in all cases of skin irritation or burns.4.1.4 Following accidental inhalationMove the person to fresh air. Dust in throat and nasal passages should clear spontaneously. Contact a doctor if irritation, cough or other symptoms persist or develop later.4.1.5 Following accidental ingestionDo not induce vomiting. If the person is conscious, wash out mouth with water and give plenty of water to drink. Seek immediate medical attention or contact the Anti-toxins Centre (see 1.4 Emergency Number).

4.2. Most important symptoms and e�ects, acute and delayedEyes: Eye contact with cement (dry or wet) may cause serious and potentially irreversible injuries.Skin: Cement may have an irritating e�ect on moist skin (due to sweat or humidity) or may cause contact dermatitis after prolonged contact. Prolonged skin contact with cement powder or wet concrete may cause serious irritation, dermatitis or serious burns, because they develop without pain being felt.Inhalation: Repeated inhalation of large quantities of cement dust over a long period of time increases the risk of developing lung diseases.Environment: Under normal conditions, there is no expected environmental hazard from common cements.

4.3. Immediate medical attention and special treatment neededWhen contacting a doctor/physician, following the above exposures take this Safety Data sheet with you.

SECTION 5Fire-fighting measures

5.1 Extinguishing meansCements are not flammable.

5.2 Special hazards arising from the mixtureCement is neither flammable nor explosive and will not cause or contribute to the combustion of other materials.

5.3 Advice for fire-fightersCement poses no fire-related hazards. No specific protective equipment is required for fire-fighters.

SECTION 6Measures to be Taken in the Event of Accidental Releases

6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnelWear protective equipment as described under Section 8 and follow the advice for safe handling and use given under Section 7.6.1.2 For emergency respondersEmergency procedures are not required. However, respiratory protection is needed in situations with high dust levels.

6.2. Environmental precautionsDo not wash cement down sewage and drainage systems or into water courses (e.g. streams).

Hazard class

Skin irritation

Serious eye damage/eye irritation

Skin sensitisation

Specific target organ toxicity single exposure respiratory tract irritation

Hazard category

2

1

1B

3

Hazard statements

H315: Causes skin irritation

H318: Causes serious eye damage

H317: May cause an allergic skin reaction

H335: May cause respiratory irritation

6.3. Containment and cleaning methods and materials Clean up the spillage or release in a dry state if possible.Dry cement - Use dry cleaning methods that do not cause airborne dispersion, for example:

- Vacuum system - Industrial portable units, equipped with high e�ciency air filters (HEPA filters) or equivalent technique); - Removal of particles by wiping - mopping or water sprays or hoses (to avoid dust dispersion) with removal of slurry.If not possible, remove slurry with water (see wet cement paste). When wet or vacuum cleaning is not possible and only dry cleaning with brushes is available, ensure that workers wear the appropriate personal protective equipment and dust dispersion.Avoid inhalation of cement and contact with skin. Place spilled materials in a container. Wet pastes must be solidified before disposal as described under Section 13.

Wet Cement – Clean up wet cement and place in a container. Allow material to dry and solidify before disposal as described under Section 13.

6.4. Reference to other sectionsSee sections 8 and 13 for further details.

SECTION 7Handling and Storage

7.1 Safe handling precautions

7.1.1 Protective measuresFollow the recommendations provided in Section 8. To clean up dry cement, see Subsection 6.3.Fire-fighting measures: Not Applicable.

Dust dispersion prevention measures: Do not sweep.Use dry clean-up methods such as vacuuming or vacuum extraction, which do not cause airborne dispersion.The "Good Practice Guides" contain advice on safe handling practices:

http://www.nepsi.eu/agreement-good-practice-guide/good-practice-guide.aspx

These good practices have been adopted as part of the European Social Dialogue Agreement on the protection of workers' health through the correct use and handling of crystalline silica and products containing crystalline silica by Employers' and Workers' Organizations through European industry associations, including CEMBUREAU.Measures to protect the environment No particular measures to be taken

7.1.2 Information on general occupational hygieneDo not handle or store near food and beverages or tobacco.In dusty environments, wear dust mask and protective goggles. Use protective gloves to avoid contact with the skin.

7.2. Conditions for safe storage, including any incompatibilitiesCement should be stored in open areas that are waterproof, dry (i.e. with internal condensation minimised), clean and protected from contamination. Engulfment hazard: To prevent burial or su�ocation, do not enter a confined space, such as a silo, hopper, tank or other storage container or vessel that stores or contains cement without taking the proper safety measures. Cement can build up or adhere to the walls of a confined space. Cement can be released, collapse or fall unexpectedly.Do not use aluminium tanks to transport or store hydraulic binders due to the incompatibility between these materials.

7.3 Specific end usesNo additional information for the specific end uses (see section 1.2).

7.4. Control of soluble Cr (VI)For cements treated with a Cr (VI) reducing agent according to the regulations provided in Section 15, the e�ectiveness of the reducing agent diminishes with time. Therefore, cement bags and/or delivery documents will contain information on the packaging date, the storage conditions and the appropriate storage period to ensure that the reducing agent keeps the content of soluble chromium (VI) below 0.0002 % of the total dry weight of the cement ready for use, in accordance with EN 196-10. They must also indicate the appropriate storage conditions for maintaining the e�ectiveness of the reducing agent.

SECTION 8Exposure Controls/Personal Protection

8.1 Control Parameters:For indicative purposes only, please refer to standard NP 1796:2014 - the weighted average concentration for a working day of 8 hours and a week of 40 hours, which is applicable to practically all workers, day after day, without adverse health e�ects (VLE-MP), is:

8.2 Control of exposureFor each PROC, users can choose option A) or B) in the table below, whichever is best suited to their specific situation. The option that is chosen must also be chosen in the table in section "8.2.2 Personal protective measures, including personal protective equipment" - Specification of respiratory protective equipment. Only combinations A) - A) and B) - B) are possible.

8.2.1 Appropriate engineering controlsMeasures to reduce generation of dust and to avoid dust being dispersed in the environment such as de-dusting, exhaust ventilation and dry clean-up methods which do not cause airborne

dispersion.

8.2.2 Individual protection measures such as personal protection equipment

General: During work avoid kneeling in fresh mortar or concrete wherever possible. If kneeling is absolutely necessary then appropriate waterproof personal protective equipment must be worn. Do not eat, drink or smoke when working with cement to avoid contact with skin or mouth. Before starting to work with cement, apply a barrier cream and reapply it at regular intervals.Immediately after working with cement or cement-containing materials, workers should wash or shower or use skin moisturisers. Remove contaminated clothing, footwear, watch, etc. and clean thoroughly before re-use.

Eye/face protection Wear approved glasses or safety goggles according to EN 166 [Reference (17)] when handling dry or wet cement to prevent contact with eyes.Skin protection Use watertight, wear-and alkali-resistant protective gloves (e.g. nitrile soaked cotton gloves with CE marking) internally lined with cotton; boots; closed long-sleeved protective clothing as well as skin care products (e.g. barrier creams) to protect the skin from prolonged contact with wet cement. Particular care should be taken to ensure that wet cement does not enter the boots. In some circumstances, such as when laying concrete or screed, waterproof trousers or kneepads are necessary.Respiratory protection: When a person is potentially exposed to dust levels above exposure limits, use appropriate respiratory protection. The type of respiratory protection should be adapted to the dust level and conform to the relevant EN standard, (e.g. EN 149 or national standards).Thermal hazards: Not applicable

A summary of the APFs of the di�erent RPEs (in accordance with EN 529:2005) is provided in the MEASE glossary (16).Any RPE, as defined above, must be used if the following principles are implemented simultaneously: The duration of the work (compare with “duration of exposure” above) should reflect the additional physiological stress for the worker due to the breathing resistance and mass of the RPE itself, due to the increased thermal stress by enclosing the head. In addition, it must be considered that the worker’s ability to use tools and communicate are reduced when RPE is worn.Hence, for the reasons given above, the worker must be (i) healthy (especially in view of medical problems that may a�ect the use of RPE), (ii) have suitable facial characteristics reducing leakages between face and mask. The recommended devices above which rely on a tight face seal will not provide the required protection unless they fit the contours of the face properly and securely.The employer and self-employed persons have legal responsibilities for the maintenance and issue of respiratory protective devices and the management of their correct use in the workplace. Therefore, they must define and document a suitable policy for respiratory protective devices, including training for workers.

8.2 Control of environmental exposureAir: Environmental exposure control for the emission of cement particles into the air must be in accordance with the available technology and regulations for the emission of general dust particles.Water: Do not wash cement into sewage systems or into water courses, to avoid high pH. Above pH 9 negative ecotoxicological impacts are possible.Soil: No special emission control measures are necessary.

SECTION 9

9.1. Physical and chemical properties

9.1.1. General information on physical and chemical propertiesThis information applies to the whole mixture.

Issue/revision date: 15/03/2018 Version: 5 p. 1/11

Hazard










2.2 Label elementsIn accordance with Regulation (EC) No. 1272/2008








SECTION 4First aid


4.1.1 GeneralNo personal protective equipment is needed for first aid responders, but they should avoid contact with wet cement or mixtures containing wet cement.

4.1.2 Following contact with eyesDo not rub eyes in order to avoid possible cornea damage due to

friction. Remove lenses, if worn. Incline head to the side of the injured eye, open the eyelid(s) wide and rinse eye(s) immediately with plenty of clean water for at least 20 minutes to remove all particles. If possible, use isotonic water (0.9% NaCl). Contact a specialist in occupational medicine or an eye specialist, preferably an

ophthalmologist.4.1.3 Following contact with skin

Dry cement: Remove the cement and rinse abundantly with water. Wet cement: Wash skin with plenty of water. Remove contaminated

clothing, footwear, watch, etc. and clean thoroughly before re-use.

Seek medical treatment in all cases of skin irritation or burns.4.1.4 Following accidental inhalationMove the person to fresh air. Dust in throat and nasal passages should clear spontaneously. Contact a doctor if irritation, cough or other symptoms persist or develop later.

4.1.5 Following accidental ingestionDo not induce vomiting. If the person is conscious, wash out mouth with water and give plenty of water to drink. Seek immediate medical attention or contact the Anti-toxins Centre (see 1.4 Emergency Number).









6.1.1 For non-emergency personnelWear protective equipment as described under Section 8 and follow the advice for safe handling and use given under Section 7.

6.1.2 For emergency respondersEmergency procedures are not required. However, respiratory protection is needed in situations with high dust levels.


(1) REACH register number: 01-2119491179-27-0012(2) REACH register number: 01-2119486767-17-0048 e 01-2119486767-17-0057



















dispersion.






SECTION 9



Substance

Portland cement clinker

Limestone

Fly ash (1)

(Pulverized Fuel Ash)

"Flue dust"(2)

Concentrationrange (% by wt in cement)

45-100%

0-35%

0-55%

0-5%

EINECSCAS

266-043-465997-15-1

215-279-61317-65-3

931-322-868131-74-8

270-659-968475-76-3

ClassificationHazard Statement

XiR37/38, R41, R43

Not applicable

Not applicable

XiR37/38, R41, R43



















SECTION 4First aid
















- Vacuum system - Industrial portable units, equipped with highe�ciency air filters (HEPA filters) or equivalent technique); - Removal of particles by wiping - mopping or water sprays orhoses (to avoid dust dispersion) with removal of slurry.If not possible, remove slurry with water (see wet cement paste).When wet or vacuum cleaning is not possible and only dry cleaningwith brushes is available, ensure that workers wear the appropriatepersonal protective equipment and dust dispersion.Avoid inhalation of cement and contact with skin. Place spilledmaterials in a container. Wet pastes must be solidified beforedisposal as described under Section 13.





7.1.1 Protective measuresFollow the recommendations provided in Section 8. To clean up dry cement, see Subsection 6.3.

Fire-fighting measures: Not Applicable.Dust dispersion prevention measures: Do not sweep.Use dry clean-up methods such as vacuuming or vacuum extraction, which do not cause airborne dispersion.The "Good Practice Guides" contain advice on safe handling practices:











dispersion.

VLE-MPInhalable dust

Respirable dust

10 mg/m3

1 mg/m3






SECTION 9





















SECTION 4First aid

































dispersion.

Use

Industrial production, formulation of hydraulic agglomerates and construction materials

Industrial uses of dry hydraulic binders and building and construction materials (indoors and outdoors)

Industrial uses of hydraulic binders in wet suspension and materials for building and construction

Professional use of dry hydraulic binders and building and construction materials (indoors and outdoors)

Professional use of hydraulic binders in wet suspension and materials for building and construction

PROC*

2, 3

14, 26

5 - 9

2

14, 22, 26

5, 8b, 9

7

2,5, 8b, 9, 10, 13, 14

2

9, 26

8, 8a, 8b, 14

19

11

2, 5, 8a, 8b, 9, 10, 13, 14, 19

Localized Controls

Not required

A) Not requiredorB) Local general ventilation with extraction

A) General ventilation,orB) Local general ventilation with extraction

Not required


A) General ventilation,orB) Local general ventilation with extraction


Not required

Not required



Local controls are not applicable, process in well ventilated areas or outdoors


Not required

Exposure

Unlimited duration (up to 480 min/shift, 5 shifts/week)


E�ciency

-

-

78%

17%

78%

-

-

78%

17%

78%

-

78%

-

-

-

72%

-

87%

-

-

72%

-

8.2.2 Individual protection measures such as personal protection equipment General: During work avoid kneeling in fresh mortar or concrete

wherever possible. If kneeling is absolutely necessary then appropriate waterproof personal protective equipment must be worn. Do not eat, drink or smoke when working with cement to avoid contact with skin or mouth. Before starting to work with cement, apply a barrier cream and reapply it at regular intervals.Immediately after working with cement or cement-containing materials, workers should wash or shower or use skin moisturisers. Remove contaminated clothing, footwear, watch, etc. and clean thoroughly before re-use.


Use




PROC*

2, 3

14, 26

5, 8b, 9

2

14, 22, 26

5, 8b, 9

7

2, 5, 8b, 9, 10, 13, 14

Specification of RPE - Respiratory Protection Equipment

Not required

A) Respiratory protection P1 (FFP1)B) Not required

A) Respiratory protection P2 (FFP2)B) Respiratory protection P1 (FFP1)

Not required




Not required

Exposure

Unlimited duration (up to 480 min/shift, 5 shifts/week

E�ciency of RPE (APF **)

-

APF=4

-

APF=10

APF=4

-

APF=4

-

APF=10

APF=4

APF=4

-

-

*PROC are the uses identified and defined in section 1.2



SECTION 9





















SECTION 4First aid

































dispersion.




Use



PROC*

2

9, 26

5, 8a, 8b, 14

19

11

2, 5, 8a, 8b, 9, 10, 13, 14, 19


Respiratory protection P1 (FFP1)



Respiratory protection P2 (FFP2)


Not required

Exposure


ABM doelmatigheid (TPF**)

APF=4

APF=10

APF=4

APF=20

APF=4

APF=10

APF=10

APF=4

-

* PROC are the uses identified and defined in section 1.2.** APF is the assigned protection factor.



Characteristic

Dry cement is a finely ground solid inorganic material (grey or white powder). Main particle size: 5-30 µm.

No odour threshold; odourless

Apparent 0.90 g / cm3 to 1.50 g / cm3

Real 2.75g / cm3 to 3.20g / cm3

slight (0.1-1.5g/l)

11.0 - 13.5

Greater than 1 250 °C

Not applicable as is not a liquid.

Not applicable - non-combustible solid which does not cause or contribute to fire through

Not applicable as is not a flammable gas.

Not applicable as melting point > 1250 °C

Not applicable as product is an inorganic substance.

Not applicable (no pyrophoricity – no organo-metallic, organo- metalloid or organo-phosphine bindings of its derivatives. There is no other pyrophoric constituent in its composition.

Not applicable as no organic peroxide present.

Not Applicable. Not explosive or pyrotechnic.

Not applicable as does not cause or contribute to the combustion of other materials

SECTION 9



9.2 Other informationNot Applicable.

SECTION 10.Stability and Reactivity

10.1. ReactivityWhen mixed with water, cements will harden into a stable mass that is not reactive in normal environments.

10.2. Chemical stabilityDry cements are stable as long as they are properly stored (see Section 7) and compatible with most other building materials. They should be kept dry. Contact with incompatible materials should be avoided. Wet cement is alkaline and incompatible with acids, with ammonium salts, with aluminium or other non-noble metals. Cement dissolves in hydrofluoric acid to produce corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates in cement react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride.

10.3 Possibility of hazardous reactionsNot Applicable.

10.4 Conditions to be avoidedHumid conditions during storage may cause lump formation and loss of product quality.

10.5 Incompatible materialsAcids, ammonium salts, aluminium or other non-noble metals. Uncontrolled use of aluminium powder in wet cement should be avoided as hydrogen is produced.

10.6 Hazardous decomposition productsCements will not decompose into any hazardous products.

SECTION 11.Toxicological Information

11.1 Information on toxicological e�ectsProperty

Appearance

Odour: Odour threshold

Density

Solubility in water (T = 20 °C):

pH: (T = 20°C in water, water-solid ratio 1:2):

Melting point:

Initial boiling point and boiling range; Evaporation rate; Flashpoint; Viscosity

Flammability

Upper/lower flammability or explosive limits:

Vapour pressure: Vapour density

Partition coe�cient: n-octanol/water:

Auto-ignition temperature

Decomposition temperature

Explosive properties:

Oxidising properties


9.2 Other informationNot Applicable.

SECTION 10.Stability and Reactivity

10.1. ReactivityWhen mixed with water, cements will harden into a stable mass that is not reactive in normal environments.

10.2. Chemical stabilityDry cements are stable as long as they are properly stored (see Section 7) and compatible with most other building materials. They should be kept dry. Contact with incompatible materials should be avoided. Wet cement is alkaline and incompatible with acids, with ammonium salts, with aluminium or other non-noble metals. Cement dissolves in hydrofluoric acid to produce corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates in cement react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride.

10.3 Possibility of hazardous reactionsNot Applicable.

10.4 Conditions to be avoidedHumid conditions during storage may cause lump formation and loss of product quality.

10.5 Incompatible materialsAcids, ammonium salts, aluminium or other non-noble metals. Uncontrolled use of aluminium powder in wet cement should be avoided as hydrogen is produced.

10.6 Hazardous decomposition productsCements will not decompose into any hazardous products.

SECTION 11.Toxicological Information

11.1 Information on toxicological e�ects

Hazard class

Acute dermal toxicity

Acute toxicity due to inhalation

Acute oral toxicity

Corrosion /irritation

Serious eye damage/eye irritation

Skin sensitisation

Respiratory sensitisation

Cell mutagenicity

Carcinogenicity

Reproductive toxicity

STOT- Specific Target Organ Toxicity- single exposure

STOT- Specific Target Organ Toxicity- repeated exposure

Aspiration hazard

Cat.

-

-

-

2

1

1

-

-

-

-

3

Referentie

(2)

(9)

Literatuuronderzoek

(2)Menselijke ervaringen

(10) e (11)

(3), (4) en (17)

(1)

(12) and (13)

(1) and (14)

No evidence from human experience

(1)

(15)

-

E�ects

Limit test, rabbit, 24 hours contact, 2,000 mg/kg body weight – no lethality. Based on available data, the classification criteria are not met.

No acute toxicity by inhalation observed. Based on available data, the classification criteria are not met.

No indication of oral toxicity from studies with cement kiln dust. These powders contain clinker in various concentrations. Based on available data, the classification criteria are not met.

Cement in contact with wet skin may cause thickening, cracking or fissuring of the skin. Prolonged contact in combination with abrasion may cause severe burns.

Portland cement clinker caused a mixed picture of corneal e�ects and the calculated irritation index was 128. Common cements contain varying quantities of Portland cement clinker, fly ash, blast furnace slag, gypsum, limestone and other substances. Direct contact with cement may cause corneal damage due to mechanical stress, immediate or delayed irritation or inflammation. Direct contact with larger amounts of dry Portland cement or splashes of wet cement may cause e�ects ranging from moderate eye irritation (e.g. conjunctivitis or blepharitis) to chemical burns and blindness

Some individuals may develop eczema upon exposure to wet cement dust, caused either by the high pH which induces irritant contact dermatitis after prolonged contact, or by an immunological reaction to soluble Cr (VI) which causes allergic contact dermatitis. The response may appear in a variety of forms ranging from a mild rash to severe dermatitis or as a combination of these two symptoms.If the cement contains a soluble Cr (VI) reducing agent and as long as the mentioned period of e�ectiveness of the chromate reduction is not exceeded, a sensitising e�ect is not expected (Reference (3))

There is no indication of sensitisation of the respiratory tracts. Based on available data, the classification criteria are not met.

No indication. Based on available data, the classification criteria are not met.

No causal association has been established between Portland cement exposure and cancer. The epidemiological literature does not support the designation of Portland cement as a suspected human carcinogen. Portland cement is not classifiable as a human carcinogen (in accordance with ACGIH A4: agents that cause concern that they could be carcinogenic for humans but which cannot be assessed conclusively because of a lack of data. In vitro or animal studies do not provide indications of carcinogenicity that are su�cient to classify the agent with one of the other notations). Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

Clinker dust for Portland cement may irritate the throat and respiratory tract. Coughing, sneezing, and shortness of breath may occur following exposures in excess of the exposure limits.Overall, the pattern of evidence clearly indicates that occupational exposure to cement dust produces deficits in respiratory function. However, the commonly available evidence is insu�cient to establish the dose-response relationship for these e�ects with any confidence.

There is an indication of COPD. The e�ects are acute and due to high exposures. No chronic e�ects or e�ects at low concentrations have been observed.Based on available data, the classification criteria are not met.

Not applicable - cements are not used as aerosols.

Apart from skin sensitisation, Portland cement clinker and common cements have the same toxicological and eco-toxicological properties.

11.2 Medical conditions aggravated by exposureInhalation of cement dust may aggravate existing respiratory diseases and / or health conditions such as emphysema or asthma and / or skin and / or eye problems.


SECTION 12.Environmental Information

12.1. ToxicityThe product is not hazardous to the environment. Ecotoxicological tests with Portland cement on Daphnia magna [(Reference (5)) and Selenas-trum coli (Reference (6)) have shown little toxicological impact. However, LC50 and EC50 values could not be determined (Reference (7)). There is no indication of sediment phase toxicity [Reference (8)]. The addition of large amounts of cement to water may, however, cause a rise in pH and may, therefore, be toxic to aquatic life under certain circumstances

12.2 Persistence and degradability.Not relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.3 Bioaccumulative potential.Not relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.4 Mobility in soilNot relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.5 Results of PBT and vPvB assessment. Other adverse e�ects.Not relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.6 Other adverse e�ects.Not relevant

SECTION 13.Disposal considerations

13.1 Waste treatment methodsDo not dispose of cement into surface waters or storm drains or sewers.Product - cement that has exceeded its shelf lifeEWC CODE 101399 (other non-specified waste)(and when demonstrated that it contains more than 0.0002% soluble Cr (VI)): not for use/sale other than in controlled closed and totally automated processes or should be recycled or disposed of according to local legislation or treated again with a reducing agent.Product - unused residue or dry spillageEWC CODE 101306 (Other particulates and dust)Dry recovery. Mark the containers. Possibly reuse, depending upon shelf life considerations and the requirement to avoid dust exposure. For disposal, harden with water and process as per “Product – after addition of water, hardening".

Product - Pastes (wet cement):Allow to harden, avoid entry in sewage and drainage systems or into bodies of water (e.g. streams) and dispose of as explained under “Product - after addition of water, hardening”.Product - after addition of water, hardening:Dispose of in accordance with local legislation. Avoid disposal into the waste water system. Dispose of hardened product as for concrete waste. Due to inertisation, concrete waste is not hazardous waste.EWC CODE 101314 (waste from cement manufacture - waste concrete or concrete sludge) or 170101 (construction and demolition wastes - concrete).

Packaging:Completely empty the packaging and process in accordance with local legislationEWC CODE 150101 (waste paper and cardboard packaging) and 150105 (composite packaging waste)

SECTION 14.Transportation Information

Transportation of the product is not covered by the international regulation on the transport of hazardous materials (IMDG, IATA,ADR/RID). Cement is transported in suitable paper pages or, in bulk, in a tanker truck. No special precautions are needed apart from those mentioned under Section 8.

14.1 UN numberNot relevant

14.2 UN proper shipping nameNot relevant

14.3 Transport hazard class(es)Not relevant

14.4 Packing groupNot relevant

14.5 Environmental hazardsNot relevant

14.6 Special precautions for usersNot relevant

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not relevant

SECTION 15.REGULATORY INFORMATION

15.1. Health, safety and environmental regulations/ legislation specific for the substance or mixture

European regulatory informationCement is a mixture covered by REACH and is not subject to registration. Cement clinker is exempt from registration (Art 2.7 (b) and Annex V.10 of REACH).The marketing and use of cement is subject to a restrictions on the content of soluble Cr (VI) (REACH Annex XVII point 47 Chromium VI compounds).National regulatory information(1) Decree-Law No. 72/2005, transposes EC directive 2003/53/EC into domestic law.(2) Decree-Law No. 82/2003, transposes EC directives 1999/45/EC, 2001/58/EC and 2001/60/EC into domestic law.(3) Decree-Law 98/2010, which establishes the system governing the classification, packaging and labelling of substances that are hazardous to human health or for the environment for its marketing, partially transposes Directive 2008/112/EC and directive 2006f/121/EC.(4) Decree 220/2012, which implements the obligations arising from Regulation 1272/2008, concerning the classification, labelling and packaging of substances and mixtures, amending and repealing the Directives 67/548/EC and 1999/45/EC and changes EC regulation 1907/2006.(5) Decree-Law No 293/2009 of 13 October (transposes EC Regulation 1907/2006 of the European Parliament and of the Council of 18 December (REACH) and establishes the creation of the European Chemicals Agency).(5) NP EN 197-1: 2012 - Cement Part 1: Composition, specifications and conformity criteria for common cements.(6) NP 1796: 2014 - Health and Safety at Work Values professional exposure limit for chemicals.(7) NP EN 196-10: 2007 (Ed.1) Cement testing methods-Part 10: Determination of soluble chromium (VI) content in water in cement.

15.2 Safety assessment of chemical risksNo chemical safety assessment has been carried out for this mixture by the supplier

SECTION 16.Other information

16.1 Indication of changesThis safety data sheet replaces the previous Version (04) of June 2007 and was changed to cover, in particular, the provisions set forth in the following regulatory documents: • EU regulation 453/2010 of the Commission, dated 20 May 2010,

amending EC regulation 1907/2006 of the European Parliament and of the Council on the registration, evaluation, authorization and restriction of chemicals (REACH).

• EC Regulation 1272/2008 of the European Parliament and of the Council dated 16 December 2008 CLP Regulation on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548 / EEC and 1999/45 / EC, 1907/2006 of the European Parliament and of the Council of 18 December 2006

REACH).And also the revision of the national and normative legislation contained in Section 15.2 of the Safety Data Sheet (Version: 04) June, 2007.

16.2 Identification of uses, descriptions and categoriesThe table below shows the descriptions of all uses identified for cement or hydraulic mixtures containing cement. All uses are grouped into the classes identified because of the di�erent and specific exposure conditions for human and environmental health. For each specific use, a set of management measures and localized controls have been defined (See Section 8), which need to be implemented by the user of cement or hydraulic mixtures containing cement to reduce exposure to acceptable levels.


SECTION 12.Environmental Information

12.1. ToxicityThe product is not hazardous to the environment. Ecotoxicological tests with Portland cement on Daphnia magna [(Reference (5)) and Selenas-trum coli (Reference (6)) have shown little toxicological impact. However, LC50 and EC50 values could not be determined (Reference (7)). There is no indication of sediment phase toxicity [Reference (8)]. The addition of large amounts of cement to water may, however, cause a rise in pH and may, therefore, be toxic to aquatic life under certain circumstances

12.2 Persistence and degradability.Not relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.3 Bioaccumulative potential.Not relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.4 Mobility in soilNot relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.5 Results of PBT and vPvB assessment. Other adverse e�ects.Not relevant as cement is inorganic. After hardening, cement presents no toxicity risks.

12.6 Other adverse e�ects.Not relevant

SECTION 13.Disposal considerations

13.1 Waste treatment methodsDo not dispose of cement into surface waters or storm drains or sewers.Product - cement that has exceeded its shelf lifeEWC CODE 101399 (other non-specified waste)(and when demonstrated that it contains more than 0.0002% soluble Cr (VI)): not for use/sale other than in controlled closed and totally automated processes or should be recycled or disposed of according to local legislation or treated again with a reducing agent.Product - unused residue or dry spillageEWC CODE 101306 (Other particulates and dust)Dry recovery. Mark the containers. Possibly reuse, depending upon shelf life considerations and the requirement to avoid dust exposure. For disposal, harden with water and process as per “Product – after addition of water, hardening".

Product - Pastes (wet cement):Allow to harden, avoid entry in sewage and drainage systems or into bodies of water (e.g. streams) and dispose of as explained under “Product - after addition of water, hardening”.Product - after addition of water, hardening:Dispose of in accordance with local legislation. Avoid disposal into the waste water system. Dispose of hardened product as for concrete waste. Due to inertisation, concrete waste is not hazardous waste.EWC CODE 101314 (waste from cement manufacture - waste concrete or concrete sludge) or 170101 (construction and demolition wastes - concrete).

Packaging:Completely empty the packaging and process in accordance with local legislationEWC CODE 150101 (waste paper and cardboard packaging) and 150105 (composite packaging waste)

SECTION 14.Transportation Information

Transportation of the product is not covered by the international regulation on the transport of hazardous materials (IMDG, IATA,ADR/RID). Cement is transported in suitable paper pages or, in bulk, in a tanker truck. No special precautions are needed apart from those mentioned under Section 8.

14.1 UN numberNot relevant

14.2 UN proper shipping nameNot relevant

14.3 Transport hazard class(es)Not relevant

14.4 Packing groupNot relevant

14.5 Environmental hazardsNot relevant

14.6 Special precautions for usersNot relevant

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not relevant

SECTION 15.REGULATORY INFORMATION

15.1. Health, safety and environmental regulations/ legislation specific for the substance or mixture

European regulatory informationCement is a mixture covered by REACH and is not subject to registration. Cement clinker is exempt from registration (Art 2.7 (b) and Annex V.10 of REACH).The marketing and use of cement is subject to a restrictions on the content of soluble Cr (VI) (REACH Annex XVII point 47 Chromium VI compounds).National regulatory information(1) Decree-Law No. 72/2005, transposes EC directive 2003/53/EC into domestic law.(2) Decree-Law No. 82/2003, transposes EC directives 1999/45/EC, 2001/58/EC and 2001/60/EC into domestic law.(3) Decree-Law 98/2010, which establishes the system governing the classification, packaging and labelling of substances that are hazardous to human health or for the environment for its marketing, partially transposes Directive 2008/112/EC and directive 2006f/121/EC.(4) Decree 220/2012, which implements the obligations arising from Regulation 1272/2008, concerning the classification, labelling and packaging of substances and mixtures, amending and repealing the Directives 67/548/EC and 1999/45/EC and changes EC regulation 1907/2006.(5) Decree-Law No 293/2009 of 13 October (transposes EC Regulation 1907/2006 of the European Parliament and of the Council of 18 December (REACH) and establishes the creation of the European Chemicals Agency).(5) NP EN 197-1: 2012 - Cement Part 1: Composition, specifications and conformity criteria for common cements.(6) NP 1796: 2014 - Health and Safety at Work Values professional exposure limit for chemicals.(7) NP EN 196-10: 2007 (Ed.1) Cement testing methods-Part 10: Determination of soluble chromium (VI) content in water in cement.

15.2 Safety assessment of chemical risksNo chemical safety assessment has been carried out for this mixture by the supplier

SECTION 16.Other information

16.1 Indication of changesThis safety data sheet replaces the previous Version (04) of June 2007 and was changed to cover, in particular, the provisions set forth in the following regulatory documents:

• EU regulation 453/2010 of the Commission, dated 20 May 2010,amending EC regulation 1907/2006 of the European Parliamentand of the Council on the registration, evaluation, authorization andrestriction of chemicals (REACH).• EC Regulation 1272/2008 of the European Parliament and of theCouncil dated 16 December 2008 CLP Regulation on classification,labelling and packaging of substances and mixtures, amending andrepealing Directives 67/548 / EEC and 1999/45 / EC, 1907/2006 ofthe European Parliament and of the Council of 18 December 2006REACH).

And also the revision of the national and normative legislation contained in Section 15.2 of the Safety Data Sheet (Version: 04) June, 2007.

16.2 Identification of uses, descriptions and categoriesThe table below shows the descriptions of all uses identified for cement or hydraulic mixtures containing cement. All uses are grouped into the classes identified because of the di�erent and specific exposure conditions for human and environmental health. For each specific use, a set of management measures and localized controls have been defined (See Section 8), which need to be implemented by the user of cement or hydraulic mixtures containing cement to reduce exposure to acceptable levels.

Process category (PROC)

2

3

5

7

8a

8b

9

10

11

13

14

19

22

26

Identified usesDescription of use

Use in continuous, close process with occasional controlled exposures (e.g. Industrial production of hydraulic binders).

Use in closed process, through production of batches or dosing (e.g. Industrial production of ready-mixed concrete).

Mixing using dosing processes for formulation of mixtures for formulation of mixtures or articles (e.g. Industrial production of prefabricated concrete)

Industrial projection / spraying.

Transfer of substances or mixtures to and from ships, large tanks in non-specific and appropriate large facilities.

Transfer of substances or mixtures to and from ships, large tanks in non-specific and appropriate large tanks.

Transfer of substances or products to small packages or containers.

Roller and brush applications.

Non-industrial projection / spraying.

Treatment of articles by immersion or coating.

Production of articles or mixtures by cold agglomeration, compression-extrusion and pelletizing (e.g. Production of tiles).

Manual mixing with direct contact, whenever personal protective equipment (PPE) is available.

Potentially closed processing operations of minerals / metals at high temperatures in industrial situations.

Handling of solid inorganic substances at ambient temperatures.

Manufacture or formulation of

X

X

X

-

-

-

X

-

-

-

X

X

-

X

Industrial or professional use of

X

X

X

X

X

X

X

X

X

X

X

X

X

X

building and construction materials


16.3 Abbreviations and acronymsACGIH American Conference of Industrial HygienistsADR/RID European Agreements on the transport of Dangerous goods

by Road/Railway CAS Chemical Abstracts ServiceCLP Classification, labelling and packaging (Regulation (EC) No

1272/2008)CPOD Chronic Obstructive Pulmonary DiseaseDNEL Derived no-e�ect level CE50 A verage e�ective concentration: a statistically measured

concentration estimated to cause a non-lethal e�ect defined as 50% of a given population of organisms under defined conditions

ECHA European Chemicals AgencyCr(VI) Chromium (VI)EINECS European Inventory of Existing Commercial chemical

SubstancesEWC European Waste CatalogueHEPA Type of high e�ciency air filterIATA International Air Transport AssociationIMDG International agreement on the Maritime transport of

Dangerous GoodsCL50 Lethal concentration for which 50% of animals undergoing

tests diesMEASE Metals estimation and assessment of substance exposure,

EBRCConsulting GmbH for Eurometaux,

http://www.ebrc.de/ebrc/ebrc-mease.phpUN United NationsPBT Persistent, bio-accumulative and toxicPROC Process category REACH Registration, Evaluation and Authorization of ChemicalsPPE Personal Protection EquipmentSCOEL Scientific Committee on Occupational Exposure Limit ValuesSDS Safety Data sheetSTOT Specific Target Organ ToxicityTRGS Technische Regeln für Gefahrsto�eVLE-MP Exposure limit value-weighted averagevPvB Very persistent, very bio-accumulative

16.4 References and data sources

(1) Portland Cement Dust- Hazard assessment documentEH75/7, UK Health and Safety Executive, 2006. Available from:http://www.hse.gov.uk/pubns/web/portlandcement.pdf.

(2) Observations on the e�ects of skin irritation caused bycement, Kietzman et al, Dermatosen, 47,5,184-189(1999).

(3) European Commission's Scientific Committee on Toxicology,Ecotoxicology and the Environment (SCTEE) opinion of therisks to health from Cr (VI) in cement (European Commission,2002). http://ec.europa.eu/health/archive/ph_risk/commit tees/sct/document s/out158_en.pdf.

(4) Epidemiological assessment of the occurrence of allergicdermatitis in workers in the construction industry related tothe content of Cr (VI) in cement, NIOH, Page 11, 2003.

(5) U.S. EPA, Short-term Methods for Estimating the ChronicToxicity of E�uents and Receiving Waters to FreshwaterOrganisms, 3rd ed. EPA/600/7-91/002, EnvironmentalMonitoring and Support Laboratory, U.S. EPA, Cincinnati, OH(1994a) and 4th ed. EPA-821-R-02-013, US EPA, o�ce ofwater, Washington D.C. (2002)

(6) U.S. EPA, Methods for Measuring the Acute Toxicity ofE�uents and Receiving Waters to Freshwater and MarineOrganisms, 4th ed. EPA/600/4-90/027F, EnvironmentalMonitoring and Support Laboratory, U.S. EPA, Cincinnati, OH(1993) and 5th ed. EPA-821-R-02-012, US EPA, o�ce ofwater, Washington D.C. (2002)

(7) Environmental Impact of Construction and Repair Materialson Surface and Ground Waters. Summary of Methodology,Laboratory Results, and Model Development. NCHRP report448, National Academy Press, Washington, D.C., 2001.

(8) Final report Sediment Phase Toxicity Test Results withCorophium volutator for Portland clinker prepared forNorcem A.S. by AnalyCen EcotoxAS, 2007.

(9) TNO report V8801/02, An acute (4-hour) inhalation toxicitystudy with Portland Cement Clinker CLP/GHS 03-2010-finein rats, August 2010.

(10) TNO report V8815/09, Evaluation of eye irritation potential ofcement clinker G in vitro using the isolated chicken eye test,April2010.

(11) TNO report V8815/10, Evaluation of eye irritation potential ofcement clinker W in vitro using the isolated chicken eye test,April 2010.

(12) Investigation of the cytotoxic and proinflammatory e�ects ofcement dusts in rat alveolar macrophages, Van Berlo et al,Chem. Res. Toxicol., 2009 Sept; 22(9):1548-58.

(13) Cytotoxicity and genotoxicity of cement dusts in A549 humanepithelial lung cells in vitro; Gminski et al, Abstract DGPTconference Mainz, 2008.

(14) Comments on a recommendation from the AmericanConference of governmental industrial Hygienists to changethe threshold limit value for Portland cement, Patrick A.Hessel and John F. Gamble, EpiLung Consulting, June 2008.

(15) Prospective monitoring of exposure and lung function amongcement workers, Interim report of the study after the datacollection of Phase I-II 2006-2010, Hilde Not0, Helge Kjuus,Marit Skogstad and Karl-Christian Nordby, National Instituteof Occupational Health, Oslo, Norway, March 2010.

(16) MEASE, Metals estimation and assessment of substanceexposure, EBRC Consulting GmbH for Eurometaux,http://www.ebrc.de/ebrc/ebrc-mease.php.

(17) Occurrence of allergic contact dermatitis caused bychromium in cement.A review of epidemiological investiga tions, Káre Lenvik, Helge Kjuus, NIOH, Oslo, December 2011.

16.5 Relevant R-phrases and/or H-StatementsR37/38 Irritating to respiratory system and skinR41 Risk of serious damage to eyesR43 May cause sensitisation by skin contact

16.6 Training adviceIn addition to health, safety and environmental training programmes for their workers, companies must ensure that workers read, understand and apply the requirements of this safety data sheet

16.7 Further informationAs substances subject to registration or considered hazardous by the REACH Regulation are not included, in significant quantities, in the cement mixtures listed in Section 1, no specific annexes are presented with additional exposure scenarios beyond those relating to the mixture itself. Section 11.1 explicitly mentions or refers to the values and test methods used to define the classification of common cements.

16.8 Classification and procedure used to determine the classification of mixtures in accordance with EC Regulation 1272/2008

Classification in accordance with EC Regulation 1272/2008

Skin irritation 2, H315

Serious eye damage/eye irritation 1, H318

Skin sensitisation, 1B, H317

Specific target organ toxicity single exposure respiratory tract irritation 3 H335

Classification procedure

Based on experimental data

Based on experimental data

Human experience

Human experience

16.9 DisclaimerThe information in this data sheet reflects the currently available knowledge and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product, including the use of the product in combination with any other product or any other process, is the responsibility of the user.It is implicit that the user is responsible for determining appropriate safety measures and for applying the legislation covering his/her own activities.


Use






Localized Controls

Not required

A) Not requiredB) Local general ventilation with extraction

Local general ventilation with extraction

Not required


Local general ventilation with extraction


Not required



Local integrated ventilation with extraction



Not required

Exposure


(#)< 240 min

PROC*

2, 3

14, 26

5, 8b,9

2

14, 22, 26

5, 8b,9

7

2, 5, 8b, 9, 10, 13, 14

2

9, 26

5, 8a,8b, 14

19 (#)

11

2, 5, 8a, 8b, 9, 10, 13, 14, 19

E�ciency

-78%

78%

-

-78%

78%

-78%

-

-72%

-72%

72%

50%

-72%

-

8.2.2 Individual protection measures such as personal protection equipment.

Use

Industrial production formulation of hydraulic agglomerates and construction materials






Not required

A) Respiratory protection P2 (FF,FM)B) Respiratory protection P1 (FF,FM)

A) Respiratory protection P2 (FF,FM)

Not required


Respiratory protection P2 (FF,FM)


Not required


A) Respiratory protection P3 (FF,FM)B) Respiratory protection P2 (FF.FM)



A) Respiratory protection P3 (FF,FM)B) Respiratory protection P2 (FF.FM)

Not required

Blootstelling

Duration is limited (up to 480 min. /shift, 5 shifts/week)

(#) < 240 min

PROC*

2, 3

14, 26

5, 8b,9

2

14, 22, 26

5, 8b,9

7

2, 5, 8b, 9, 10, 13, 14

2

9, 26

5,8a,8b, 14

19 (#)

11

2, 5, 8a, 8b, 9, 10, 13, 14, 19

E�ciëntie

-

APF=10APF=4

APF=10

-

APF=10APF=4

APF=10

APF=20APF=10

-

APF=10APF=4

APF=20APF=10

APF=20

APF=20

APF=20APF=10

-

*PROC are the uses identified and defined in section 1.2.**APF is the assigned protection factor.

ANNEXESAdditional tables with technical measurements of section 8.2 control and measures of individual protection for

1. DNEL inhalation of 1mg/m3

8.2.1 Appropriate engineering controls


*PROC are the uses identified and defined in section 1.2.**APF is the assigned protection factor.

Use






Localized Controls

Not required



Not required


B) Local general ventilation with extractionA) General ventilation,


Not required

A) Not requiredA) General ventilation,





Not required

Exposure


PROC*

2, 3

14, 26

5, 8b,9

2

14, 22, 26

5, 8b,9

7

2, 5, 8b, 9, 10, 13, 14

2

9, 26

5, 8a,8b, 14

19

11

2, 5, 8a, 8b, 9, 10, 13, 14, 19

E�ciency

-78%

-82%

-

-78%

-82%

-78%

-

-29%

-77%

-72%

50%

-77%

-

ANNEXEAddition tables with technical measures for section 8.2

2 DNEL inhalation of 5mg/m38.2.1 Doelmatige technische controlemaatregelen

8.2.2 Individual protection measures such as personal protection equipment.

Use







Not required

A) Respiratory protection P1 (FF,FM)B) Not required


Not required


Respiratory protection P2 (FF,FM)B) Not required


Not required






Not required

Exposure

Duration is limited (up to 480 min. /shift, 5 shifts/week)

PROC*

2, 3

14, 26

5, 8b, 9

2

14, 22, 26

5 - 9

7

2, 5, 8b, 9, 10, 13, 14

2

9, 26

5, 8a,8b,

19

11

2, 5, 8a, 8b, 9, 10, 13, 14, 14

E�ciency of RPE (APF **)

-

APF=4-

APF=4-

-

APF=4APF=4

APF=10-

APF=10-

-

APF=4-

APF=10-

APF=20APF=4

APF=10

APF=10-

-


safety data sheet cement - secil group...safety data sheet cement section 1 details of the mixture...

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