safety data sheet · e-mail : [email protected] web : 1.4. emergency phone number emergency first...

SAFETY DATA SHEET

Regulation on 'Safety Information Forms for Harmful Substances and Mixtures (13.12.2014 Date and 29204 No. The Official Gazette) and (EU) are prepared in accordance with No 1272/2008.'

Edits :001 Form No. : OVN-008 Date of Preparation : 25.04.2020 Revision date :

/ 15

MA1. IDENTITY OF ARTICLE/MIX AND COMPANY /DISTRIBUTOR

1.1. Item/The identity of the mixture

Name of the mixture : CLEANSE WISE Hand Sanitizer GEL CAS No : Not implemented EİNECS No : Not applicable

1.2. Designated Uses and Unrecommended Uses of Substance or Mixture Use of Substance/Mixture : Used as antibacterial hand cleaning gel. Unrecommended Uses : Not used in disinfection of foodstuffs.

1.3. Information from the safety data sheet supplier Company Name : Agari International Limited Address : 2nd Floor Congress House Lyon Road / London / england Phone : +44 788 918 2103 E-mail : [email protected]

Web : www.agariltd.com

1.4. Emergency Phone Number

Emergency First Aid Center : 112 Poison Advisory Centre (UZEM) : 114 (National Poison Center) Refik Saydam Hıfzıhha Merk. Bask., ANKARA Fire Department : 110

2. HAZARDS IDENTIFICATION

2.1. Classification of Matter and Mixture 'Published in the Official Gazette dated December 11, 2013 and numbered 28848 (Repeated)

''Classification, Labeling and Packaging of Substances and Mixtures Classification in accordance with regulation'' (SEA)

mailto:[email protected]

http://www.agariltd.com/

SAFETY DATA SHEET



/ 15

Highly flammable liquid and vapour, Category 2 H225

Eye irritation, Category 2 H319

Full text of H expressions: Part 16

2.2. Label Elements 'Published in the Official Gazette dated December 11, 2013 and numbered 28848 (Repeated) Classification, Labelling and Packaging of Substances and Mixtures About Classification in accordance with the Regulation'' (SEA)

DAMAGE MARK (SEA)

GHS 02 GHS 07

WARNING WORD (SEA) : Danger

DANGEROUS MATERIAL : Ethanol

EXPRESSIONS OF DAMAGE (SEA): H225 – Highly flammable liquid and vapour

H319 – Causes Severe Eye Irritation

PRECAUTIONARY STATEMENTS (SEA) :

P210 – Keep away from heat/spark/flame/hot surfaces. – Don’t

Smoking.

P233 – Keep the container tightly closed.

P242 – Use only non-sparking tools.

P305 + P351 + P338 – If in eyes: Rinse cautiously with water for several

minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P337 + P313 – If eye irritation is permanent: Seek medical assistance/care.

P501 - Dispose of content/container according to appropriate disposal

regulations.

2.3. Other Damages Other hazards that do not fall into the classification No additional information.

SAFETY DATA SHEET



/ 15

3.COMPOSITION / INFORMATION ABOON INGREDIENT

ARTICLE OR INFORMATION

EINECS NO.

Cas №

Content

Classification

SEA

Class, H expressions*

Deionized Water - - 24,7% --

Ethyl Alcohol

200-578-6 64-17-5 75%

H225, H319

Glycerin 200-289-5 56-81-5 0.1% --

Acyrilic Resin

618-347-7 9003-01-4 0,2%

H315,H319,H335

*The opening of H and R Expressions is given in Chapter 15.

4.FIRST AID MEASURES

General Recommendation In all suspicious cases or when symptoms persist, consult a doctor.

Contact with the eye

Wash the exposed eye with plenty of water for 15 minutes and rinse carefully. If it's plugged in and easy to do, remove the contact lenses. Seek medical attention if irritation has occurred.

Contact with leather

SAFETY DATA SHEET



/ 15

No adverse effects are expected. However, redness, burning, or itching in the skin wash with plenty of water. If irritation continues, consult your doctor and do not use the product.

Incase of Inhalation

Fresh air should be taken and a doctor should be consulted for weakness.

If Swallowed

Shake the mouth and then drink one or two cups of water (or milk). Don't make the patient throw up. Seek medical attention in the face of long-running symptoms. Show the product container or label to the doctor.

5.Fire Fighting Measures

5.1 Fire extinguishers : Use dry chemical, carbon dioxide, water vapor oracolheile resistant foam for large fires. Suitable extinguishing agents: Carbon dioxide (CO2), Foam and dry chemicals,, Water spray Inappropriate extinguisher agents : High-powered water spray jet. 5.2 Special damages caused by substance or mixture: Explosive gases and liquid may be exposed as a result of burning. It can trigger ignited sources by accumulated vapours indoors or near the ground. Mixing into the sewers can cause a fire or an explosion. As a result of burning, carbon oxide (CO), carbon dioxide (CO2), NITROGEN OXESTS (NO, NO2...), sulfur oxides (SO, SO2...) may be exposed.

SAFETY DATA SHEET



/ 15

5.3 Advice for fire fighting crews: In case of fire: Use a respiratory protection device independent of environmental air. Additional Information Do not inhale the emitted gases in case of explosion and/or burning. Use jet spraying in the danger zone for protection of people and cooling containers. Interfere with the vapors with the water sprayer. Collect contaminated extinguisher water separately. Don't let it reach the sewers or water.

6.Accidental Release Measures

6.1. Personal measures, protective equipment and emergency procedures Remove all ignition sources. Ventilate the affectedarea. Do not inhale gas/smoke/steam/aerosols. Prevent skin, eyes and clothing contact. Use personal protective equipment. 6.2. Environmental measures Don't let it leak into the sewers or the water. Hold the contaminated water back and drain. 6.3. Methods and materials for preservation and cleaning Absorbed with liquid binding material (sand, kiselgur, acid binding, university binding) Getit. Collect in suitable closed containers and take them to treatment/disposal. Ventilate Affected area. 6.4 References to other sections Safe use: see part 7 Personal protective equipment: see section 8 Breakthrough: see part 13

7.Handling and Storage

7.1. Precautions for safe handling Recommendation for safe handling Avoid: Aerosol production/-formation. Use only in well ventilated places. Precautions against fire and explosion protection

SAFETY DATA SHEET



/ 15

Keep away from flammable sources - don't smoke. Take precautions against static electricitydischarge. Vapours can create explosive mixtures with air. The product's vapoursare heavy from the air and can accumulate at high concentrations on theground, pits, canals and basements. 7.2. Conditions for secure storage, including disputes Requirements for warehouses and containers Keep it in a tightly sealed container. Keep the container cool and well ventilated. Keep away from heat/spark/flame/hot surfaces. – No smoking. Recommendations for compatible storage Should not be stored together: Oxidant matter. Details on storage conditions storage temperature: < 30 °C 7.3. Specific enduses Washing and cleaning agents (including solvent-based products)

8.Exposure Controls / Personal Protection

8.1. Control parameters

Exposure Limits

8.2. Exposure controls

Appropriate engineering controls

In open exposure, the device should be used that provides local absorption. Do not inhale

gas/smoke/steam/aerosols.

Protective and hygiene measures

Beware of eye contact. Work in well-ventilated areas or respiratory filter. Hands must be washed

CAS No. Chemical Name Ppm mg/m³ f/ml Category Origin

64-17-5

Ethyl alcohol (Ethanol)

1000

1900

SAFETY DATA SHEET



/ 15

before they take a break and at the end of the job. Use oily skin care agents after cleaning.

Eye/Face protection

Proper eye protection: protective glasses.

Protection of hands

When working with chemicals, protective gloves against CE-labeled chemicals with only a 4-digit control

number are allowed to wear. The design selection of gloves protective against chemicals should be made

specific to the workplace depending on the concentration and quantity of hazardous substances. It is

recommended to consult the glove manufacturer to determine the resistance of the protective gloves

mentioned above against chemicals.

Suitable material: NBR (Nitril rubber), PVA (polyvinyl alcohol), Twisted rubber, FKM

(fluorocarbon rubber). Inappropriate material: CR (polychloropen, chloroprene rubber), NR

(Natural rubber, Natural latex), PVC (Polyvinilchloride).

Protection of skin

Body protection: not necessary.

Protection of the respiratory system

If there's insufficient ventilation, wear a respiratory protector. Full/half/quarter mask (DIN EN 136/140)

9.Physical And Chemical Properties

Definition Value Unit Physical State Fluid Fluid --

Smell Characteristic alcohol smell --

Ph 6 ± 1 -- Specific Weight 0,80 - 0.90 g/cm³ @20 °C

Viscosity >2000 cp. 25°C Soluble Water Soluble

Melting /Freezing Point -48 - -37 ℃ Boiling Point 85-90 ℃

Flash Point 21-22 ℃

Explosion Limits Down 2.8 vol.. Up 18.2 vol..

%

Steam Pressure (20°C) 59 Hpa

10.Stability/Reactivity

10.1. Reaction It can be easily ignited.

SAFETY DATA SHEET



/ 15

10.2. Chemical stability The product is suitable for storage at normal ambient temperatures. 10.3. Possibility of harmful reaction There is a risk of explosion/exothermal reaction with: hydrogen peroxid, perchlorate, perchloric acid, Nitric acid, mercury(II) nitrate,

permanganic acid, nitriller, peroxide compounds, strong oxidizing agents, nitrosil compounds, Peroxides, sodium, potassium, halogen oxides, calcium hypochlorite, nitrogen dioxide, metallic oxides, uranium hexafluoride, iodine, chlorine, alkaline metals, alkaline soil metals, alkaline oxides, Ethylene oxide silver, with nitric acid silver compounds, with ammonia potassium permanganate, with, cons. sulfuric acid ... risk of exploding or creating flammable gas or vapours: halogen-halogen compounds, chromium (VI) oxide, chromium chloride, fluoride,

hydrides, Phosphorus oxides, platinum Nitric acid, with potassium permanganate 10.4. Avoided situations Keep away from heat sources (e.g. hot surfaces), sparks and open flames. Vapours can create explosive mixtures with air. 10.5. Items to avoid Oxidant, strong. Alkaline metals. 10.6. Harmful decay products There are no known decomposition products.

11.Toxicological Information

11.1 Information about toxic effects Acute oral toxicity LD50 Rat: 10,470 mg/kg OECD Test Instruction 401

SAFETY DATA SHEET



/ 15

Symptoms: Nausea, Vomiting Toxicity of acute respiratory (inhalation) LC50 Rat: 124.7 mg/l; 4 h; Steam OECD Test Instruction 403 Symptoms: mild mucosal irritation Acute dermal toxicity This information is not available. Skin irritation Rabbit Conclusion: No skin irritation observed OECD Test Instruction 404 It irritates the skin and burns if exposed at regular intervals due to its reduces the fat content in the skin. Eye irritation Rabbit Conclusion: Eye irritation OECD Test Instruction 405 It causes severe eye irritation. Sensitivity Local lymph node assay (LLNA) Mouse Result: negative Method: OECD Test Kilavuzu 429 Ethety cell mutagenite In vitro genotoxicity Ames test Salmonella typhimurium Result: negative Method: OECD Test Instruction 471 In vitro mammal cell gene mutation test Mouse lymphoma test

SAFETY DATA SHEET



/ 15

Result: negative Method: OECD Test Direction 476 Carcinogenicity This information is not available. Reproductive system toxicity Application Method: Oral Mouse Method: OECD Test Instruction 416 Teratogenicity (may cause developmental injuries) This information is not available. Specific Target Organ Toxicity – Single exposure This information is not available. Specific Target Organ Toxicity – Recurrent exposure This information is not available. Aspiration toxicity This information is not available. 11.2Additional information Systemic effects: feeling extremely fit (euphoria) After absorption: Dizziness, drunkenness, anesthetic, respiratory paralysis Other dangerous features cannot be ignored. Carry it in accordance with industrial hygiene and safety rules.

12.Ecological Information

12.1Toxicity

SAFETY DATA SHEET



/ 15

Toxicity on fish flow-through test EC50 Pimephales promelas (Carp cub): 15,300 mg/l; 96 sa Analytical observation: yes US-EPA Toxicity on Daphnia and other aquatic invertebrates EC50 Daphnia magna (Laurel): 9,268 - 14,221 mg/l; 48 h (IUCLID) Toxicity on algae (algae) IC5 Scenedesmus quadricauda (green algae): 5,000 mg/l; 7 g (Source) Toxicity on bacteria EC5 Pseudomonas putida: 6,500 mg/l; 16 h (IUCLID) Toxicity on Daphnia and other aquatic invertebrates (Chronic toxicity) semi-static test NOEC Daphnia magna (Laurel): 9.6 mg/l; 9 g (ECHA) 12.2Persistence and impairability Biological decay 94 % OECD Test Guide 301E It can be easily dissolved in nature by itself. Biochemical Oxygen Need (BOD) 930 - 1,670 mg/g (5 g) (Source) Theoretical oxygen requirement (ThOD) 2,100 mg/g (Source)

SAFETY DATA SHEET



/ 15

Ratio COD/ThBOD 90 % (Source) 12.3Bio accumulation potential Distribution coefficient (n-octane/water) log Pow: -0.31 (experimental) (Source) Bioaccumulation cannot be expected. 12.4Mobility in the soil No information is available. Results of 12.5PBT and vPvB evaluation Article 1907/2006 Regulation (AT) XIII. It does not meet pbt or vPvb criteria in accordance with the attachment. 12.6Other negative effects Additional information about ecology When used correctly, dysfunction is not expected in the wastewater processing plant. It should be prevented from being thrown into the environment.

13.Disposal Information

Waste processing methods Waste materials must be disposed of in accordance with national and local regulations. Leave the chemicals in their original containers. Don't be involved with any other waste. Process uncleaned containers like the product itself. Waste materials must be disposed of in accordance with Directive 2008/98/AT and other national and local regulations (Regulation on General Principles of Waste

SAFETY DATA SHEET



/ 15

Management, 02.04.2015, R.G 29314). Leave the chemicals in their original containers. Don't mix it with any other waste. Process uncleaned containers like the product itself.

14.Transportation Information

Land transportation (ADR/RID) 14.1 UN NumberUN 1170 14.2 Appropriate UN Transportation NameETHANOL 14.3 Transportation Pest Classes3 14.4 Packaging group 14.5 Environmental Damages-- 14.6 Special measures for the user yes Tunnel restriction codeD/E Transportation in inland waters (ADN) Not Related Air transport (IATA) 14.1 UN Number UN 1170 14.2 Appropriate UN Transportation NameETHANOL 14.3 Transportation Pest Classes3 14.4 Packaging group 14.5 Environmental Damages-- 14.6 Special measures for the user no Sea transportation (IMDG) 14.1 UN Number UN 1170 14.2 Appropriate UN Transportation NameETHANOL 14.3 Transportation Pest Classes3 14.4 Packaging group 14.5 Environmental Damages-- 14.6 Special measures for the user yes EmS F-E/S-DS-D

SAFETY DATA SHEET



/ 15

14.7 MARPOL 73/78 Bulk transport according to additional II and IBC code Not Related

15.Regulatory Information

15.1. National security, health and environmental legislation specific to substance or mixture Regulations

Regulation on Classification, Packaging and Labelling of Hazardous

Substances and Forestry, dated December 26, 2008, dated December 26, 2008

Regulation on Classification, Packaging and Labelling Of Hazardous Substances and Forestry, dated December 13, 2014, of the Ministry of Environment and Forestry

Regulation dated December 11, 2013, No. 28848, on the Classification, Labeling and Packaging of Substances and Mixtures.

Regulation on Health and Safety Measures in Chemical Studies.

Regulation on the Use of Personal Protective Equipment in Workplaces.

Occupational Health and Safety Act 6331.

Regulation on The Control of Hazardous Waste

This product does not contain a substance that is subject to control or prohibited use

in accordance with the Regulation on the Reduction of Ozone layer, dated 12/11/2008 and published in the Official Gazette no. 27052. .

16. OTHER INFORMATION Data Sources : Published in the repeated Official Gazette dated December 11, 2013 and numbered 28848 'Classification, Labelling and Packaging of Substances and Mixtures About Classification in accordance with sea' sea. Data Sources : BIG. Training Advice : Make sure operators understand the danger of flammability. Other Informationler : LIABILITY REJECTED The information in this Safety Data Sheet is that it is trusted, it is sourced from the sources we believe in. However, open or above their accuracy

SAFETY DATA SHEET



/ 15

provided without a closed warranty. Handling, storage of the product, conditions or methods of use or disposal are beyond our control and may not be within our knowledge. For these and similar reasons, the handling of the product, anyloss arising from storage, use or disposal. we deny responsibility for the damage. This Safety Data Sheet is only prepared for use. If the product is used as a component in another product, this Information in the Security Information Form may be invalid.

H-Notifications based on sections 2 and 3 is all text.

H315 – Causes skin irritation. H225 – Highly flammable liquid and vapour H319 – Causes Severe Eye Irritation H335 – May cause respiratory irritation. THE PERSON WHO PREPARED THE SAFETY DATA SHEET; Name ; Burak DURUKAN Certificate Number TÜV/01.220.01 Certificate Validity Date 03.03.2023 Contact information [email protected]

safety data sheet · e-mail : [email protected] web : 1.4. emergency phone number emergency first...

Documents