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SAFETY DATA SHEET Page 1 / 10
NEXBASE® 3043 EN
Date 28.11.2013 Previous date: 27.6.2013
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifier1.1.1 Commercial Product Name
NEXBASE® 3043
1.1.2 Product code
(ID 12553) 192508, 822600REACH Registration Number01-2119474889-13-0000 / 01-2119474889-13-0003
Substance name Lubricating oils (petroleum), C20-C50, hydrotreated neutral oilbased
1.2 Relevant identified uses of the substance or mixture and uses advised against1.2.1 Recommended use
Manufacture of substanceUse as an intermediateDistribution of substanceFormulation & (re)packing of substances and mixturesUses in CoatingsUse in Cleaning AgentsUse in Oil and Gas field drilling and production operationsMetal working fluids / rolling oilsUse as binders and release agentsUse in AgrochemicalsRoad and construction applications Rubber production and processingPolymer processing LubricantsUse as a fuel Use in laboratoriesMining chemicalsWater treatment chemicalsExplosives manufacture & useFunctional fluid
See the PROC/SU/ERC codes of the identified uses in Section 16.
1.3 Details of the supplier of the safety data sheet1.3.1 Supplier
Neste Oil N.V.
P.O.Box Industriezone Ravenshout 7304Industrieweg 154
Postcode and post office B-3583 Beringen, BELGIUM
Telephone +32 11 459 511
Telefax +32 11 459 512
Business ID BE451.251.225
Email [email protected]
1.4 Emergency telephone number1.4.1 Telephone number, name and address
+358-9-471 977, +358-9-4711, Poison Information Centre/HUS P.O.B 340 (Tukholmankatu 17) 00029 HUS (Helsinki, Finland)
2. HAZARDS IDENTIFICATION
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2.1 Classification of the substance or mixtureIn accordance with paragraph (d) of 2012 29 CFR §1910.1200 [OSHA GHS].
1272/2008 (CLP)Asp. Tox. 1, H304
67/548/EEC - 1999/45/EC-;
2.2 Label elementsIn accordance with paragraph (f) of 2012 29 CFR §1910.1200 [OSHA GHS].
1272/2008 (CLP)GHS08Signal word DangerHazard StatementsH304 May be fatal if swallowed and enters airways.
Precautionary StatementsP301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.P331 Do NOT induce vomiting.P501 Dispose of the content/package according to the local and national regulations.
2.3 Other hazardsOil mist may irritate the eyes and the respiratory tract. Prolonged or repeated skin contact may irritate the skin and produce dermatitis. Risk of soil and ground water contamination.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances.CAS number Chemical name of the substance Concentration Classification
72623-87-1 /276-38-4(CAS/EC)
Lubricating oils (petroleum), C20-50, hydrotreated neutral oil-based; Baseoil - unspecified
100% CLP: Asp. Tox. 1, H304DSD-DPD: -
3.3 Other informationA petroleum product. DMSO extract < 3 Weight % (IP 346). The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances. (1272/2008/EC ("CLP"), Annex VI, Note L)
Registration number, See chapter 1.1.2.
4. FIRST AID MEASURES
4.1 Description of first aid measures
4.1.2 Inhalation
Inhalation is unlikely because of the low vapour pressure of the substance at ambient temperature. If breathed in, move person into fresh air. Consult a physician.
4.1.3 Skin contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Splashes of hot product cause burns in the eyes and on the skin. Seek medical attention in all cases of serious burns.
4.1.4 Eye contact
Rinse immediately with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist.
4.1.5 Ingestion
DO NOT INDUCE VOMITING. In case of ingestion, always assume that aspiration has occurred. Consult a physician (risk of aspiration into the lungs especially if nausea or irritation occurs).
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NEXBASE® 3043 EN
Date 28.11.2013 Previous date: 27.6.2013
4.2 Most important symptoms and effects, both acute and delayedAspiration into the lungs can cause fatal chemical pneumonitis. Oil mist may irritate the eyes and the respiratory tract.
4.3 Indication of immediate medical attention and special treatment neededAspiration into the lungs can cause fatal chemical pneumonitis.
5. FIREFIGHTING MEASURES
5.1 Extinguishing media5.1.1 Suitable extinguishing media
Dry powder, carbon dioxide. Sand. Heavy foam and water fog for professional fire-fighters.
5.1.2 Extinguishing media which must not be used for safety reasons
Water jet.
5.2 Special hazards arising from the substance or mixtureIncomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates, gases, including carbon monoxide
5.3 Advice for firefightersPrecautions for fire-fighting: Self-contained breathing apparatus and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency proceduresEvacuate unnecessary personnel. Avoid skin contact and inhalation of oil mist. Wear adequate protective equipment at all operations. Spillages make surfaces slippery.
Remove all sources of ignition. Take measures to prevent the build up of electrostatic charge. Large spillages may be cautiously covered with foam, if available, to limit fire risk.
6.2 Environmental precautionsTry to restrict the release and prevent spread of the product into the environment. Collect liquid before it spreads into drains, the ground and waters. In case of spill, immediately contact local authorities. Risk of soil and ground water contamination.
6.3 Methods and materials for containment and cleaning upImmediately start clean-up of the liquid and contaminated soil. Large spills should be collected mechanically (remove by pumping) for disposal. Small amounts can be collected using absorbent material.
If possible, large spillages in open waters should be contained with floating barriers or other mechanical means. If this not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities
6.4 Reference to other sectionsFor personal protection see section 8. Product waste should be disposed in accordance with section 13.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
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NEXBASE® 3043 EN
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Provide sufficient ventilation when handling the product. Avoid skin contact and inhalation of oil mist. Wear protective equipment when needed. Do not ingest. When using, do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Spillages make surfaces slippery. Wear safety shoes while handling containers.
Keep away from fire, sparks and heated surfaces. Take measures to prevent the build up of electrostatic charge. Avoid splash filling of bulk volumes when handling hot liquid product For personal protection see section 8.
7.2 Conditions for safe storage, including any incompatibilitiesKeep tightly closed in a dry, cool and well-ventilated place. Protect against light. Take precautionary measures to prevent product spills into drains, the ground or waters. Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations. Store in accordance with local regulations..
Keep in properly labelled containers. Recommended materials for containers, or container linings use mild steel, stainless steel. Some synthetic materials may be unsuitable for containers or container linings depending on the material specification and intended use.
7.3 Specific end use(s)None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
8.1.1 Threshold limits
5 mg/m3 (8 h)HTP 2011/ FIN
Oil mist
8.1.2 Other information on limit values
The occupational exposure monitoring method: Oil mist: NIOSH Method 5026, SFS-EN 689.
8.1.3 Limit values in other countries
5 mg/m³, TWA PEL (OSHA)5 mg/m³, TLV-TWA (ACGIH)10 mg/m³, TLV-STEL (ACGIH)
8.1.4 DNELs
No information available.
8.1.5 PNECs
No information available.
8.2 Exposure controls8.2.1 Appropriate engineering controls
Ensure adequate ventilation. Use personal protective equipment and/or local ventilation when needed.
8.2.2 Individual protection measures8.2.2.1 Respiratory protection
Oil mist: respirator (combined particle and organic vapour filter, type A2/P2). Filter device could be used maximum 2 hours at a time. Filter devices must not be used in conditions where the oxygen level is low (< 17 vol.-%). At high concentrations a breathing apparatus must be used (self-contained or fresh air hose breathing apparatus). Filter must be changed often enough. Respirators according to standards EN 140 and EN 141.
8.2.2.2 Hand protection
Protective gloves: PVC, nitrile rubber. Change protective gloves regularly. Protective gloves according to standards EN 420 and EN 374.
8.2.2.3 Eye/face protection
Tightly fitting safety goggles.
8.2.2.4 Skin protection
Protective clothing (antistatic), splash-proof chemical protective clothing when needed.
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8.2.3 Environmental exposure controls
Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties9.1.1 Appearance
colourless, clear liquid.
9.1.2 Odour almost odourless
9.1.3 Odour threshold -
9.1.4 pH -
9.1.5 Melting point/freezing point Pour point / Melting point (Melting/pour point) ≤ -12 °C (ASTM D-97).
9.1.6 Initial boiling point and boiling range 350-600 °C
9.1.7 Flash point > 220°C (ASTM D-92).
9.1.8 Evaporation rate -
9.1.9 Flammability (solid, gas) -
9.1.10 Explosive properties9.1.10.1 Lower explosion limit -
9.1.10.2 Upper explosion limit -
9.1.11 Vapour pressure < 0,1 hPa (20 °C)
9.1.12 Vapour density -
9.1.13 Relative density 0,82-0,84 (15°C) (ASTM D-4052).
9.1.14 Solubility(ies)9.1.14.1 Water solubility insoluble
9.1.14.2 Fat solubility (solvent /oil to be specified) -
9.1.15 Partition coefficient: n-octanol/water Base oil hydrocarbons log Kow > 6
9.1.16 Auto-ignition temperature -
9.1.17 Decomposition temperature -
9.1.18 Viscosity Kinematic viscosity, typical value: 20 mm²/s (40°C) (ASTM D-445)
9.1.19 Explosive properties None.
9.1.20 Oxidising properties None.
9.2 Other informationMelting/pour point ≤ -12 °C (ASTM D-97)Viscosity, dynamic 39,4 mPa.s (+20°C)Viscosity, dynamic approx. 50 mPa.s (+16°C)
10. STABILITY AND REACTIVITY
10.1 ReactivityNo dangerous reaction known under conditions of normal use.
10.2 Chemical stabilityStable under recommended storage conditions.
10.3 Possibility of hazardous reactionsNone known.
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10.4 Conditions to avoidKeep away from fire, sparks and heated surfaces.
10.5 Incompatible materialsIncompatible with strong acids and oxidizing agents.
10.6 Hazardous decomposition productsNo hazardous decomposition products are known.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
11.1.1 Acute toxicity
Very low toxicity:LD50/oral/rat > 5000 mg/kg (OECD 401).LD50/dermal/rabbit > 2000 mg/kg (OECD 402).LC50/inhalation/4h/rat = > 5,53 mg/L (OECD 403).
11.1.2 Irritation and corrosion
Not classified. (OECD 404, 405). Oil mist may irritate the eyes and the respiratory tract. Prolonged or repeated skin contact may irritate the skin and produce dermatitis.
11.1.3 Sensitisation
Not a skin sensitizer. (OECD 406)
11.1.4 Subacute, subchronic and prolonged toxicity
Not classifiable as a human carcinogen. (OECD 451, 453).No toxicity to reproduction (OECD 421).Damage to fetus not classifiable (OECD 414).Genotoxicity tests (in vitro and in vivo) have been negative. (OECD 471, 473, 474, 476)
11.1.5 STOT-single exposure
No known effect.
11.1.6 STOT-repeated exposure
No known effect. (OECD 408, 410, 411, 412, 453)
11.1.7 Aspiration hazard
Aspiration into the lungs can cause fatal chemical pneumonitis.
11.1.8 Other information on acute toxicity
Toxicological data are based on tests with corresponding products or componentsUsed oils may contain accumulated contaminants dangerous to health and the environment.
NTP: Not listed. IARC: Not listed.
12. ECOLOGICAL INFORMATION
12.1 Toxicity12.1.1 Aquatic toxicity
Very low toxicity:
Acute aquatic toxicityfish: LL50/96h > 100 mg/L; NOEL/96h >= 100 mg/L (OECD 203)crustacean: EL50/24-48h; NOEL/48-96h; LL50/24-96h > 10 000 mg/L (OECD 202)alga: NOEL/72h >= 100 mg/L (OECD 201)
Chronic aquatic toxicity:crustacean: NOEL/21d = 10 mg/L (OECD 211)
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12.1.2 Toxicity to other organisms
Very low toxicity. Toxicity to microorganisms: NOEL/10min > 1,93 mg/L (DIN 38412, DIN38409)
12.2 Persistence and degradability12.2.1 Biodegradation
Not readily degradable (OECD301B).
12.2.2 Chemical degradation
Not readily degradable.
12.3 Bioaccumulative potentialBase oil hydrocarbons are possibly accumulative (log Kow > 6).
12.4 Mobility in soilThe product is insoluble in water and mainly not volatile. Product can penetrate soil until reaching the surface of ground water. Degradation occurs extremely slowly under anaerobic conditions. Base oil hydrocarbons can be adsorbed onto organic material in soil or sediment (log Kow > 6).
12.5 Results of PBT and vPvB assessmentThis substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB). (anthracene < 0,1 %)
12.6 Other adverse effectsInformation given is based on data on the components and the ecotoxicology of similar products.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methodsProduct waste is hazardous waste. It should be treated according to national regulations and local authorities' advice.
13.2 Waste from residues / unused productsUsed oils may contain accumulated contaminants dangerous to health and the environment. Empty containers may contain combustible product residues Empty containers should be taken for local recycling or waste disposal.
14. TRANSPORT INFORMATION
14.1 UN number Not classified as dangerous in the meaning of transport regulations.
14.2 UN proper shipping name -
14.3 Transport hazard class(es) -
14.4 Packing group -
14.5 Environmental hazards-
14.6 Special precautions for users-
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeBulk : (MARPOL 73/78, Annex II): Noxious liquid, NF, (5) n.o.s. ( NEXBASE 3043, contains Cycloalkanes C 12+), ST 2, Cat. Y. According to MARPOL: "Non-solidifying substance".
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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WGK = 1 (Wassergefährdungsklasse, Germany)
To the best of our knowledge, the product components are not listed on any US national/regional regulatory lists except the TSCA inventory.
The product has been listed in the following chemical inventories: TSCA (USA), DSL (Canada), AICS (Australia), ECL (South Korea), PICCS (Philippines), NZIoC (New Zealand), IECS (China), ENCS (Japan); inventories of Taiwan and Switzerland.
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Updated according to regulation (EU) N:o 453/2010 amending regulation (EC) N:o 1907/2006 (REACH).
15.2 Chemical safety assessmentA Chemical Safety Assessment has been carried out for this substance.
16. OTHER INFORMATION
16.1 Additions, Deletions, Revisions9.1.18 Viscosity 9.2 Further information 16.8 Date of last revision
16.2 Key or legend to abbreviations and acronymsCLP= Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006DSD= Council Directive (67/548/EEC) on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances DPD= Directive 1999/45/EC of the European Parliament and of the Council concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations
DNEL = Derived No-Effect LevelPNEC = Predicted No-Effect ConcentrationPROC = Process CategoryPC = Product CategorySU = Sector of UseERC = Environmental Release Category
PEL = Permissible Exposure LimitSTEL = Short-Term Exposure LimitTLV = Threshold Limit ValueTWA = Time-Weighted Average
OSHA = Occupational Safety and Health AdministrationACGIH = American Conference of Governmental Industrial Hygienists
IARC = International Agency for Research on CancerNTP = National Toxicology Program
16.3 Key literature references and sources for dataConcawe Report no. 11/2010; Hazard Classification and labelling of petroleum substances in the EEA - 2010 (Concawe, 2010).Chemical Safety Report; Other Lubricant Base Oils (Concawe, 2012).
16.5 List of relevant R phrases, hazard statements, safety phrases and/or precautionarystatements
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H304 May be fatal if swallowed and enters airways.
16.7 Recommended restrictionsIdentified uses:
Manufacture of substance (PROC 1, 2, 3, 4, 8a/b, 15; SU 3, 8, 9; ERC 4)Use as an intermediate (PROC 1, 2, 3, 4, 8a/b, 15; SU 3, 8, 9; ERC 6a)Distribution of substance (PROC 1, 2, 3, 4, 8a/b, 9, 15; SU 3; ERC 4, 5, 6a/b/c/d, 7)Formulation & (re)packing of substances and mixtures (PROC 1, 2, 3, 4, 5, 8a/b, 9, 14, 15; SU 10; ERC 2)Uses in Coatings:Industrial use (PROC 1, 2, 3, 4, 5, 7, 8a/b, 10, 13, 15; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 5, 8a/b, 10, 11, 13, 15, 19; SU 22; ERC 8a/d);Consumers (PC 1, 4, 8, 9a/b/c, 18, 23, 24, 31, 34; SU 21; ERC 8a/d)Use in Cleaning Agents:Industrial use (PROC 1, 2, 3, 4, 7, 8a/b, 10, 13, SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 5, 8a/b, 10, 11, 13, 15, 19; SU 22; ERC 8a/d);Consumers (PC 1, 4, 5, 8, 9, 10, 18, 23, 24, 31; SU 21; ERC 8a/d)Use in Oil and Gas field drilling and production operations:Industrial use (PROC 1, 2, 3, 4, 8a/b; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 8a/b; SU 22; ERC 9b)Metal working fluids / rolling oils:Industrial use (PROC 1, 2, 3, 4, 5, 7, 8a/b, 9, 10, 13, 17; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 5, 8a/b, 10, 11, 13, 17; SU 22; ERC 8a/d)Use as binders and release agents:Industrial use (PROC 1, 2, 3, 4, 6, 7, 8b, 10, 13, 14; SU 3; ERC 4);Professional use (PROC 1, 2, 3, 4, 6, 8a/b, 10, 11, 14; SU 22; ERC 8a/d)Use in Agrochemicals:Professional use (PROC 1, 2, 4, 8a/b, 11, 13; SU 22; ERC 8a/d);Consumers (PC 12, 27; SU 21; ERC 8a/d)Road and construction applications: Professional use (PROC 8a/b, 9, 10, 11, 13; SU 22; ERC 8d/f)Rubber production and processing: Industrial use (PROC 1, 2, 3, 4, 5, 6, 7, 8a/b, 10, 13, 14, 15, 21; SU 3, 10, 11; ERC 4, 6d)Polymer processing:Industrial use (PROC 1, 2, 3, 4, 5, 6, 8a/b, 9, 13, 14, 21; SU 10; ERC 4, 6d);Professional use (PROC 1, 2, 6, 8a/b, 14, 21; SU 22; ERC 8a/d)Use as a fuel:Industrial use (PROC 1, 2, 3, 8a/b, 16; SU 3; ERC 7)Professional use (PROC 1, 2, 3, 8a/b, 16; SU 22; ERC 9a/b)Consumers (PC 13; SU 21; ERC 9a/b)Lubricants: Industrial use (PROC 1, 2, 3, 4, 7, 8a/b, 9, 10, 13, 17, 18; SU 3; ERC 4, 7);Professional use (PROC 1, 2, 3, 4, 8a/b, 9, 13, 17, 20; SU 22; ERC (low release) 9a/b; ERC (high release) 8a/d);Consumers (PC 1, 24, 31; SU 21; ERC (low release) 9a/b; ERC (high release) 8a/d)Use in laboratories:Industrial use (PROC 10, 15, SU 3; ERC 4);Professional use (PROC 10, 15, SU 22; ERC 8a)Mining chemicals: Industrial use (PROC 1, 2, 3, 4, 5, 8a/b, 9; SU 10; ERC 4)Water treatment chemicals:Industrial use (PROC 1, 2, 3, 4, 8a/b, 13; SU 10; ERC 4);Professional use (PROC 1, 2, 3, 4, 8a/b, 13; SU 22; ERC 8a/d/f)Explosives manufacture & use: Professional use (PROC 1, 3, 5, 8a/b; SU 22; ERC 8e)Functional fluid:Industrial use (PROC 1, 2, 3, 4, 8a/b, 9; SU 3; ERC 7);Professional use (PROC 1, 2, 3, 8a, 9, 20; SU 22; ERC 9a/b);Consumers (PC 16, 17; SU 21; ERC 9a/b)
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16.8 Further informationDate of last revision: 28 November 2013
ADDITIONAL INFORMATION AVAILABLE FROM: Neste Oil Corporation, Base Oils, Finland, tel. +358 10 45811, fax +358 10 45 85244 , e-mail: [email protected] Neste Oil N.V., Beringen, Belgium tel. +32 11 459 511, fax. +32 11 459 512, e-mail: [email protected]
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NEXBASE 3043 [ENG] Date: 19.6.2013 Previous date: - ID 12553
SECTION 1 EXPOSURE SCENARIO TITLE Title 1. Manufacture of Substance - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
SU 8: Manufacture of bulk, large scale chemicals (including petroleum products)
SU 9: Manufacture of fine chemicals
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 1.1.v1
Processes, Tasks and Activities Covered
Manufacture of the substance or use as an intermediate or a process chemical or extraction agent. Includes recycling/recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container).
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138]
Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated
differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]
Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Process sampling [CS2] No other specific measures identified. [EI20]
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Laboratory activities [CS36]
No other specific measures identified. [EI20]
Bulk transfers [CS14] (open systems) [CS108]
No other specific measures identified. [EI20]
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Bulk product storage [CS67]
Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 8.5E+5
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 6.0E+5
Maximum daily site tonnage (kg/day): 2.0E+6
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 1.0E-4
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-5
Release fraction to soil from process (initial release prior to RMM): 0.0001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b].
Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 90%.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 84.8 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
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Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on following total wastewater treatment removal 5.7E+6 kg per day.
Assumed domestic sewage treatment plant flow 10 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
During manufacturing no waste of the substance is generated [ETW4].
Conditions and measures related to external recovery of waste
During manufacturing no waste of the substance is generated [ERW2].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. G22.
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. G23.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data do not support the need for a DNEL to be established for other health effects. G36. Risk Management Measures are based on qualitative risk characterisation. G37.
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4]. Scaled assessments for EU refineries have been performed using site-specific data and are attached in PETRORISK file – “Site-Specific Production” worksheet [DSU6].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 2. Use as Substance as Intermediate - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
SU 8: Manufacture of bulk, large scale chemicals (including petroleum products)
SU 9: Manufacture of fine chemicals
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 6a: Industrial use resulting in manufacture of another substance (use of intermediates)
Specific Environmental Release Category
ESVOC 6.1a.v1
Processes, Tasks and Activities Covered
Manufacture of the substance or use as an intermediate or process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container).
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138]
Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
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Process sampling [CS2] No other specific measures identified. [EI20]
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Bulk transfers [CS14] (open systems) [CS108]
No other specific measures identified. [EI20]
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Bulk product storage [CS67]
Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.5E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.5E+3
Maximum daily site tonnage (kg/day): 1.5E+4
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 100
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM: 1.0E-5
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-5
Release fraction to soil from process (initial release prior to RMM): 0.001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1a].
Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 80%.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 66.2 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
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Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 9.8E+4 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
This substance is consumed during use and no waste of the substance is generated. [ETW5]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated. [ERW3]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. G22.
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. G23.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data do not support the need for a DNEL to be established for other health effects. G36. Risk Management Measures are based on qualitative risk characterisation. G37.
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 3. Distribution of Substance – Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
ERC 5: Industrial use resulting in inclusion into or onto a matrix
ERC 6a: Industrial use resulting in manufacture of another substance (use of intermediates)
ERC 6b: Industrial use of reactive processing aids
ERC6c: Industrial use of monomers for manufacture of thermoplastics
ERC 6d: Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers
ERC 7: Industrial use of substances in closed systems
Specific Environmental Release Category
ESVOC 1.1b.v1
Processes, Tasks and Activities Covered
Bulk loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, maintenance and associated laboratory activities. Excludes emissions during transport.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Specific Risk Management Measures and Operational Conditions
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Scenarios (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Process sampling [CS2] No other specific measures identified. [EI20]
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Bulk transfers [CS14] (open systems) [CS108]
No other specific measures identified. [EI20]
Drum and small package filling [CS6]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance. [E65]
Storage [CS67] Store substance within a closed system. [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 8.5E+5
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.7E+3
Maximum daily site tonnage (kg/day): 1.7E+4
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 100
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 1.0E-4
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-7
Release fraction to soil from process (initial release prior to RMM): 0.00001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 90%.
Treat onsite wastewater (prior to receiving water discharge) to provide
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the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.1E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 4. Formulation & (re)packing of substances and mixtures
Use Descriptor Sector(s) of Use SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 5: Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 2: Formulation of preparations
Specific Environmental Release Category
ESVOC 2.2.v1
Processes, Tasks and Activities Covered
Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tabletting, compression, pelletization, extrusion, large and small scale packing, maintenance, sampling and associated laboratory activities
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
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General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Batch processes at elevated temperatures [CS136]
No other specific measures identified. [EI20]
Use in contained batch processes [CS37]
Process sampling [CS2] No other specific measures identified. [EI20]
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Mixing operations (open systems) [CS30]
No other specific measures identified. [EI20]
Transfer from/pouring from containers [CS34] Manual [CS22] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Production or preparation or articles by tabletting, compression, extrusion or pelletisation [CS100]
No other specific measures identified. [EI20]
Drum and small package filling [CS6]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance. [E65]
Storage [CS67] Store substance within a closed system. [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 8.5E+5
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 3.0E+4
Maximum daily site tonnage (kg/day): 1.0E+5
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (after typical onsite RMMs, consistent with EU Solvent Emissions Directive requirements): 1.5E-3
Release fraction to wastewater from process (initial release prior to
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RMM): 5.0E-6
Release fraction to soil from process (initial release prior to RMM): 0.0001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]
Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 0%.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 69.5 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 5.7E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
ECETOC TRA has been used to estimate workplace exposures unless otherwise indicated [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should
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ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 5. Uses in Coatings – Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 5: Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact)
PROC 7: Industrial spraying
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC 13: Treatment of articles by dipping and pouring
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 4.3a.v1
Processes, Tasks and Activities Covered
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated diffetently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15] with sample collection [CS56]
No other specific measures identified [EI20]
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Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified [EI20]
Film formation – force drying, stoving and other technologies [CS99] Use in contained systems [CS38] Elevated temperature [CS111]
No other specific measures identified [EI20]
Film formation - air drying [CS95] [CS108] (Open systems)
No other specific measures identified. [EI20]
Preparation of material for application [CS96] Mixing operations (closed systems) [CS29]
No other specific measures identified. [EI20]
Preparation of material for application [CS96] Mixing operations (open systems) [CS30]
No other specific measures identified. [EI20]
Spraying (automatic/robotic) [CS97]
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]
Spraying/fogging by manual application [CS24]
Wear a respirator conforming to EN140 with Type A filter or better. [PPE22]
Material transfers [CS3] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
Material transfers [CS3] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Roller, spreader, flow application [CS98]
No other specific measures identified. [EI20]
Dipping, immersion and pouring [CS4]
No other specific measures identified. [EI20]
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Material transfers [CS3] Drum/batch transfers [CS8] Transfer from/pouring from containers [CS22]
No other specific measures identified. [EI20]
Production or preparation or articles by tabletting, compression, extrusion or pelletisation [CS100]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
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Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.0E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.0E+4
Maximum daily site tonnage (kg/day): 3.5E+4
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.98
Release fraction to wastewater from process (initial release prior to RMM): 2.0E-5
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). [TCR1k]
Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 90 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 71.2 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following totalwastewater treatment removal 1.0E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external
External recovery and recycling of waste should comply with applicable
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recovery of waste local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22]
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 6. Uses in Coatings – Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses:
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 5: Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC11: Non industrial spraying
PROC 13: Treatment of articles by dipping and pouring
PROC 15: Use as laboratory reagent
PROC 19: Hand-mixing with intimate contact and only PPE available
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
Specific Environmental Release Category
ESVOC 8.3b.v1
Processes, Tasks and Activities Covered
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, brush, spreader by hand or similar methods, and film formation), and equipment cleaning, maintenance and associated laboratory activities.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation. [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Specific Risk Management Measures and Operational Conditions
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Scenarios (only required controls to demonstrate safe use listed)
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Preparation of material for application [CS96] Mixing operations (closed systems) [CS29]
No other specific measures identified. [EI20]
Film formation - air drying (indoor/outdoor) [CS95]
No other specific measures identified. [EI20]
Preparation of material for application [CS96] Mixing operations (open systems) [CS30] Pouring from small Containers [CS9] (indoor / outdoor)
No other specific measures identified. [EI20]
Material transfers [CS3] Drum/batch transfers [CS8] Non-dedicated facility [CS82]
Use drum pumps. [E53]
Roller, spreader, flow application [CS98] (indoor/outdoor)
No other specific measures identified. [EI20]
Spraying/fogging by manual application [CS24] Indoor [OC8]
Carry out in a vented booth or extracted enclosure. [E57]
Spraying/fogging by manual application [CS24] Outdoor [OC8]
Wear a half mask respirator conforming to EN140, 149 or equivalent [PPE22]
Dipping, immersion and pouring [CS4] (indoor/outdoor)
No other specific measures identified. [EI20]
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Hand application – finger paints, pastels, adhesives [CS72] (indoor/outdoor)
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance. [E65]
Storage [CS67] Store substance within a closed system. [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
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Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 3.9E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 2.0E+0
Maximum daily site tonnage (kg/day): 5.4E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.98
Release fraction to wastewater from process (initial release prior to RMM): 0.01
Release fraction to soil from process (initial release prior to RMM): 0.01
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 65.0 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 93.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 3.5E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
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The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 7. Uses in Coatings - Consumer
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Products Categories PC 1: Adhesives, sealants
PC 4: Anti-Freeze and de-icing products
PC 8: Biocidal products (e.g. Disinfectants, pest control)
PC 9a: Coatings and paints, thinners, paint removers
PC 9b: Fillers, putties, plasters, modelling clay
PC 9c: Finger paints
PC 18: Ink and toners
PC 23: Leather tanning, dye, finishing, impregnation and care products
PC 24: Lubricants, greases, release products
PC 31: Polishes and wax blends
PC 34: Textile dyes, finishing and impregnating products; including bleaches and other processing aids.
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems.
ERC 8d: Wide dispersive outdoor use of processing aids in open systems.
Specific Environmental Release Category
ESVOC 8.3c.v1
Processes, Tasks and Activities Covered
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138]
Vapour Pressure (kPa) Liquid, vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use/exposure
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Product Category
Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.
Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
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[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.0E+3
Fraction of regional tonnage used locally: 0.0005
Annual site tonnage (tonnes/year): .1.0E+0
Maximum daily site tonnage (kg/day): 2.8E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.985
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.005
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) 1.9E+3.
Assumed domestic sewage treatment plant flow (m3/day): 2000
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
[G21]
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
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Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 8. Use in Cleaning Agents – Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 7: Industrial spraying
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC 13: Treatment of articles by dipping and pouring
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 4.4a.v1
Processes, Tasks and Activities Covered
Covers the use as a component of cleaning products including transfer from storage, pouring/unloading from drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning and maintenance.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently). [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Automated process with (semi) closed systems. [CS93] Use in contained
No other specific measures identified. [EI20]
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systems[CS38]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Automated process with (semi) closed systems.[CS93] Use in contained batch processes [CS37] Elevated temperature [CS111]
No other specific measures identified. [EI20]
Dipping, immersion and pouring [CS4]
No other specific measures identified. [EI20]
Cleaning with low-pressure washers [CS42]
No other specific measures identified. [EI20]
Cleaning with high-pressure washers [CS44]
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings[E60]
Manual [CS34] Cleaning [CS47] Surfaces [CS48] no spraying [CS60]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.0E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.0E+2
Maximum daily site tonnage (kg/day): 5.0E+3
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 1.0
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-7
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] Prevent discharge of undissolved substance to or recover from onsite
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discharges, air emissions and releases to soil
wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 70%.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %. Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 3.3E+4 kg per day. Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Environment Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet
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(http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 9. Use in Cleaning Agents – Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses:
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC11: Non industrial spraying
PROC 13: Treatment of articles by dipping and pouring
PROC 15: Use as laboratory reagent
PROC 19: Hand-mixing with intimate contact and only PPE available
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
Specific Environmental Release Category
ESVOC 8.4b.v1
Processes, Tasks and Activities Covered
Covers the use as a component of cleaning products including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand).
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
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Filling / preparation of equipment from drums or containers. [CS45]
Avoid carrying out activities involving exposure for more than 1 hours [OC27]
Automated process with (semi) closed systems. [CS93] Use in contained systems [CS38]
No other specific measures identified. [EI20]
Semi Automated process. (e.g.: Semiautomatic application of floor care and maintenance products) [CS76]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82] Outdoor [OC9]
Use drum pumps [E53]
Manual [CS34] Surfaces [CS48] Cleaning [CS47] Dipping, immersion and pouring [CS4]
No other specific measures identified. [EI20]
Cleaning with low-pressure washers [CS42] Rolling, Brushing [CS51]
No other specific measures identified. [EI20]
Cleaning with high pressure washers [CS44] Spraying [CS10] (Indoor / outdoor)
No other specific measures identified. [EI20]
Treatment by dipping and pouring [CS34] Surfaces [CS48] Cleaning [CS47] Wiping [CS50] Rolling, Brushing [CS51]
No other specific measures identified. [EI20]
Degreasing small objects in cleaning station [CS41]
No other specific measures identified. [EI20]
Ad hoc manual application via trigger sprays, dipping, etc. [CS27]
No other specific measures identified. [EI20]
Hand-mixing with intimate contact and only PPE available Indoor
No other specific measures identified. [EI20]
Cleaning of medical devices [CS74]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
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[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 3.9E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 2.0E+0
Maximum daily site tonnage (kg/day): 5.3E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.02
Release fraction to wastewater wide dispersive use [OOC8]: 0.000001
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 3.6E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]
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related to external recovery of waste
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22.]
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 10. Use in Cleaning Agents – Consumer
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Products Categories PC 3: Air care products
PC 4: Anti-Freeze and de-icing products
PC 8: Biocidal products (e.g. Disinfectants, pest control)
PC 9a: Coatings and paints, thinners, paint removers
PC 24: Lubricants, greases, release products
PC 35: Washing and cleaning products (including solvent based products)
PC 38: Welding and soldering products (with flux coatings or flux cores.), flux products
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems.
ERC 8d: Wide dispersive outdoor use of processing aids in open systems.
Specific Environmental Release Category
ESVOC 8.4c.v1
Processes, Tasks and Activities Covered
Covers general exposures to consumers arising from the use of household products sold as washing and cleaning products, aerosols, coatings, lubricants and air care products.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use/exposure
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Product Category
Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.
Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.0E+3
Fraction of regional tonnage used locally: 0.0005
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Annual site tonnage (tonnes/year): 1.0E+0
Maximum daily site tonnage (kg/day): 2.7E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.95
Release fraction to wastewater wide dispersive use [OOC8]: 0.025
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.025
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) 1.8 E+1.
Assumed domestic sewage treatment plant flow (m3/day): 2000
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
[G21]
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 11. Use in Oil and Gas Field Drilling and Production Operations – Industrial CES5.1
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
Not Applicable
Processes, Tasks and Activities Covered
Offshore and onshore oil field well drilling (including drilling muds use and well cleaning) and hydraulic fracturing operations; including material transfers, on-site formulation of drilling/fracturing fluid, well head/well bore operations, shaker room activities and related maintenance.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Amount used No limit.
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Assumes use at not > 20oC above ambient [G15].
Assumes a good basic standard of occupational hygiene has been implemented [G1]
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Drilling mud (re-) formulation [CS115] Use in contained batch processes [CS37]
No other specific measures identified. [EI20]
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Drill floor operations [CS116]
No other specific measures identified. [EI20]
Operation of solids filtering equipment [CS117] Elevated temperature [CS111]
Provide the operation with a properly sited receiving hood [E71]
Cleaning of solids filtering equipment [CS120] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
Treatment and disposal of filtered solids [CS121] Use in contained batch processes [CS37]
No other specific measures identified. [EI20]
Process sampling [CS2] No other specific measures identified. [EI20]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Pouring from small containers [CS9] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
General exposures (closed systems) [CS39]
No other specific measures identified. [EI20]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region [A1]: 1
Regional use tonnage (tonnes/year) [A2]: 10
Fraction of regional tonnage used locally [A3]: N/A
Annual site tonnage (tonnes/year) [A5]: N/A
Maximum daily site tonnage (kg/day) [A4]: N/A
Frequency and duration of use
Emission days (days/year) [FD4]: N/A
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1]: N/A
Local marine water dilution factor [EF2]: N/A
Other given operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): N/A
Release fraction to wastewater from process (initial release prior to RMM): N/A
Technical conditions and measures at process level (source) to prevent release
Discharge to aquatic environment is restricted (see Section 4.2) [TCS2].
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Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency N/A.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of N/A.
Organizational measures to prevent / limit release from site
Prevent environmental discharge consistent with regulatory requirements [OMS4].
Conditions and measures related to municipal sewage treatment plant
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%) N/A
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) N/A
Assumed domestic sewage treatment plant flow (m3/d) N/A
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]. Cuttings and process water are disposed according to local and/or national regulations.
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1]. Cuttings and process water are re-injected according to local and/or national regulations.
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. [G8]
Section 3.2 Environment
Quantitative exposure and risk assessment not possible due to lack of emissions to aquatic environment [EE7]. Qualitative approach used to conclude safe use [EE8].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Section 4.2 Environment
Offshore drilling Discharge to aquatic environment is restricted by law and industry prohibits release1 [DSU9]. 1OSPAR Commission 2009. Discharges, Spills and Emissions from Offshore Oil and Gas Installations in 2007, including the assessment of data reported in 2006 and 2007. Onshore drilling Environmental releases are minimized during onshore drilling operations2; waste recycling and disposal is managed according to national and/or local regulations3. 2 International Finance Corporation 2007. Environmental, Health, and Safety Guidelines: onshore oil and gas development. 3Mining Waste Directive (2006/21/EC), European Waste Directive (2008/98/EC) and national transpositions, e.g. Novelle des Kreislaufwirtschaftsgesetzes (KrWG) in Germany Hydraulic fracturing Releases to surface water and soil are minimized during hydraulic fracturing operations. Releases to groundwater are controlled by existing local and EU4 regulations. 4 European Groundwater Directive (2006/118/EC), complementary to the Water Framework Directive.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 12. Use in Oil and Gas Field Drilling and Production Operations – Professional
CES5.2
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
Environmental Release Categories
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Specific Environmental Release Category
Not Applicable
Processes, Tasks and Activities Covered
Oil field well drilling operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related maintenance.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Amount used No limit.
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Assumes use at not > 20oC above ambient [G15].
Assumes a good basic standard of occupational hygiene has been implemented [G1]
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Drilling mud (re-) formulation [CS115] Use in contained batch processes [CS37]
No other specific measures identified. [EI20]
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Drill floor operations [CS116]
No other specific measures identified. [EI20]
Operation of solids filtering equipment –aerosol exposures [CS118] Elevated temperature [CS111]
Provide the operation with a properly sited receiving hood [E71]
Cleaning of solids filtering equipment [CS120] Non-dedivated facility [CS82]
Provide extract ventilation to points where emissions occur [E54]
Treatment and disposal of filtered solids [CS121] Use in contained batch processes [CS37]
No other specific measures identified. [EI20]
Process sampling [CS2] No other specific measures identified. [EI20]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Pouring from small containers [CS9] Non-dedicated facility [CS82]
Carefully pour from containers [E62]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region [A1]: 1
Regional use tonnage (tonnes/year) [A2]: 10
Fraction of regional tonnage used locally [A3]: N/A
Annual site tonnage (tonnes/year) [A5]: N/A
Maximum daily site tonnage (kg/day) [A4]: N/A
Frequency and duration of use
Emission days (days/year) [FD4]: N/A
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1]: N/A
Local marine water dilution factor [EF2]: N/A
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: N/A Release fraction to wastewater wide dispersive use [OOC8]: N/A
Technical conditions and measures at process level
Discharge to aquatic environment is restricted (see Section 4.2) [TCS2].
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(source) to prevent release
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency N/A.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of N/A.
Organizational measures to prevent / limit release from site
Prevent environmental discharge consistent with regulatory requirements [OMS4].
Conditions and measures related to municipal sewage treatment plant
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%) N/A
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) N/A
Assumed domestic sewage treatment plant flow (m3/d) N/A
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]. Cuttings and process water are disposed according to local and/or national regulations.
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1]. uttings and process water are re-injected according to local and/or national regulations.
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. [G8]
Section 3.2 Environment
Quantitative exposure and risk assessment not possible due to lack of emissions to aquatic environment [EE7]. Qualitative approach used to conclude safe use [EE8].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Section 4.2 Environment
Offshore drilling Discharge to aquatic environment is restricted by law and industry prohibits release1 [DSU9]. 1OSPAR Commission 2009. Discharges, Spills and Emissions from Offshore Oil and Gas Installations in 2007, including the assessment of data reported in 2006 and 2007. Onshore drilling Environmental releases are minimized during onshore drilling operations2; waste recycling and disposal is managed according to national and/or local regulations3. 2 International Finance Corporation 2007. Environmental, Health, and Safety Guidelines: onshore oil and gas development. 3Mining Waste Directive (2006/21/EC), European Waste Directive (2008/98/EC) and national transpositions, e.g. Novelle des Kreislaufwirtschaftsgesetzes (KrWG) in Germany Hydraulic fracturing Releases to surface water and soil are minimized during hydraulic fracturing operations. Releases to groundwater are controlled by existing local and EU4 regulations. 4 European Groundwater Directive (2006/118/EC), complementary to the Water Framework
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Directive.
SECTION 1 EXPOSURE SCENARIO TITLE Title 13. Use in Metal Working Fluids/Rolling Oils - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 5: Mixing or blending in batch processes for formulation of preparations* and ar-ticles (multistage and/or significant con-tact)
PROC 7: Industrial spraying
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 10: Roller application or brushing
PROC 13: Treatment of articles by dipping and pouring
PROC 17: Lubrication at high energy conditions and in partly open process
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 4.7a.v1
Processes, Tasks and Activities Covered
Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). OC7. Assumes a good basic standard of occupational hygiene is implemented. G1.
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
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General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Process sampling [CS2] No other specific measures identified. [EI20]
Metal machining operations [CS79]
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]
Treatment by dipping and pouring [CS35]
No other specific measures identified. [EI20]
Spraying [CS10] Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings E60
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Automated metal rolling/forming [CS80] Use in contained systems [CS38] Elevated temperature [CS111]
No other specific measures identified. [EI20]
Semi-automated metal rolling/forming [CS83] Elevated temperature [CS111]
Provide extract ventilation to points where emissions occur [E54]
Equipment cleaning and maintenance [CS39] Dedicated facility [CS81]
Drain down system prior to equipment break-in or maintenance [E65]
Equipment cleaning and maintenance [CS39] Non- dedicated facility [CS81]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 4.2E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.0E+2
Maximum daily site tonnage (kg/day): 5.0E+3
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 20
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Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.02
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-6
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10]. Treat air emission to provide a typical removal efficiency of 70%.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.5 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 3.3E+4 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
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SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 14. Use in Metal working fluids / rolling oils – Professional: high environmental
release
Use Descriptor Sector(s) of Use SU 22: Professional uses:
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 5: Mixing or blending in batch processes for formulation of preparations* and ar-ticles (multistage and/or significant con-tact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC11: Non industrial spraying
PROC 13: Treatment of articles by dipping and pouring
PROC 17: Lubrication at high energy conditions and in partly open process
Environmental Release Categories
ERC 8a:
ERC 8d:
Specific Environmental Release Category
ESVOC 8.7c.v1
Processes, Tasks and Activities Covered
Covers the use in formulated MWFs including transfer operations, open and contained cutting/machining activities, automated and manual application of corrosion protections, draining and working on contaminated/ reject articles, and disposal of waste oils.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation. [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently). [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
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Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82]
Avoid carrying out activities involving exposure for more than 1 hour [OC27]
Process sampling [CS2] No other specific measures identified. [EI20]
Metal machining operations [CS79]
Provide a good standard of controlled ventilation (10 to 15 air changes per hour) [E40] Avoid carrying out activities involving exposure for more than 4 hours [OC28] Limit the substance content in the product to 25 % [OC18]
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Spraying [CS10] Avoid carrying out activities involving exposure for more than 1 hour [OC27] Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11] , or: [G9] Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]
Treatment by dipping and pouring [CS35]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance. [E65]
Storage [CS67] Store substance within a closed system. [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 9.0E+2
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 4.5E-1
Maximum daily site tonnage (kg/day): 1.2E+10
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 5.0E-3
Release fraction to wastewater wide dispersive use [OOC8]: 0.05 Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
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Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 65.1 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 8.1E+0 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures
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[DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 15. Use as Release Agents or Binders - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 6: Calendering operations
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC 13: Treatment of articles by dipping and pouring
PROC 14:
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 4.10a.v1
Processes, Tasks and Activities Covered
Covers the use as binders and release agents including material transfers, mixing, application (including spraying and brushing), mould forming and casting, and handling of waste.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation. [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently). [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Material transfers [CS3] (closed systems) [CS107]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facilities [CS81]
No other specific measures identified. [EI20]
Mixing operations (closed systems) [CS29]
No other specific measures identified. [EI20]
Mixing operations (open No other specific measures identified. [EI20]
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systems) [CS30]
Dipping, immersion and pouring [CS4]
No other specific measures identified. [EI20]
Mold forming [CS31] No other specific measures identified. [EI20]
Casting operations [CS32] (open systems) [CS108] Elevated temperature [CS111]
Apply extract ventilation to emissions [E60]
Spraying [CS10] Carry out in a vented booth or extracted enclosure [E57] , or: [G9] Wear a full face respirator conforming to EN140 with Type A filter or better. [PPE24]
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Treatment by dipping and pouring [CS35]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 3.7E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 2.5E+3
Maximum daily site tonnage (kg/day): 2.5E+4
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 100
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 1.0
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-7
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 80%
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
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If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.4E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 16. Use as Release Agents or Binders – Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 6: Calendering operations
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC 11: Non industrial spraying
PROC 14: Production of preparations or articles by tableting, compression, extrusion, pelletisation
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
Specific Environmental Release Category
ESVOC 8.10b.v1
Processes, Tasks and Activities Covered
Covers the use as binders and release agents including material transfers, mixing, application by spraying, brushing, and handling of waste.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138]
Vapour Pressure (kPa) Liquid, vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently). [G13]
Frequency and duration of use/exposure
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1.]
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Material transfers [CS3] (closed systems) [CS107]
No other specific measures identified. [EI20]
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Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Non-dedicated facility [CS81]
Avoid carrying out activities involving exposure for more than 1 hour [OC27]
Mixing operations (closed systems) [CS29]
No other specific measures identified. [EI20]
Mixing operations (open systems) [CS30]
No other specific measures identified. [EI20]
Mold forming [CS31] No other specific measures identified. [EI20]
Casting operations [CS32] (open systems) [CS108] Elevated temperature [CS111]
Apply extract ventilation to emissions [E60]
Spraying [CS10] Machine [CS33]
Carry out in a vented booth or extracted enclosure E57 Avoid carrying out activities involving exposure for more than 4 hours [OC28]
Spraying [CS10] Manual [CS34]
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11] Avoid carrying out activities involving exposure for more than 1 hour [OC27] , or: [G9] Wear a respirator conforming to EN140 with Type A filter or better [PPE22]
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.7E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.3E+0
Maximum daily site tonnage (kg/day): 3.7E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.95
Release fraction to wastewater wide dispersive use [OOC8]: 0.025 Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.025
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Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 65.5 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 2.4E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
[G21]
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
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Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 17. Use in Agrochemicals - Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Products Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 11: Non industrial spraying
PROC 13: Treatment of articles by dipping and pouring
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems.
ERC 8d: Wide dispersive outdoor use of processing aids in open systems.
Specific Environmental Release Category
8.11a.v1
Processes, Tasks and Activities Covered
Use as an agrochemical excipient for application by manual or machine spraying, smokes and fogging; including equipment clean-downs and disposal.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138]
Vapour Pressure (kPa) Liquid, vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use/exposure
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Transfer from/pouring from containers [CS22] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Mixing operations (open No other specific measures identified. [EI20]
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systems) [CS30]
Spraying/fogging by manual application [CS24]
Wear a respirator conforming to EN140 with Type A filter or better. [PPE22]
Spraying/fogging by machine application [CS25]
Apply within a vented cab supplied with filtered air under positive pressure and with a protection factor of >20 [E70]
Ad hoc manual application via trigger sprays, dipping, etc. [CS27]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 7.5E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.5E+1
Maximum daily site tonnage (kg/day): 4.1E+1
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.9
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.09
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency 68.7%
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of 0.0%
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage
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sewage treatment plant
treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) 2.4E+2.
Assumed domestic sewage treatment plant flow (m3/day): 2000
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
[G21]
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 18. Use in Agrochemicals - Consumer
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Process Categories PC 12: Fertilizers
PC 27: Plant protection products
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems.
ERC 8d: Wide dispersive outdoor use of processing aids in open systems.
Specific Environmental Release Category
ESVOC 8.11b.v1
Processes, Tasks and Activities Covered
Covers the consumer use in agrochemicals in liquid and solid forms.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.0E+3
Fraction of regional tonnage used locally: 0.0005
Annual site tonnage (tonnes/year): 4.1E+0
Maximum daily site tonnage (kg/day): 1.1E+1
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
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Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.9
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.09
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 7.2E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 19. Use in Road and Construction Applications – Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 10: Roller application or brushing
PROC11: Non industrial spraying
PROC 13: Treatment of articles by dipping and pouring
Environmental Release Categories
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix
Specific Environmental Release Category
ESVOC 8.15.v1
Processes, Tasks and Activities Covered
Application of surface coatings and binders in road and construction activities, including paving uses, manual mastic and in the application of roofing and water-proofing membranes
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Drum/batch transfers [CS8] Non-dedicated facility [CS82]
Use drum pumps [E53]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Small scale weighing [CS90]
No other specific measures identified. [EI20]
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Rolling, brushing [CS51] No other specific measures identified. [EI20]
Spraying/ fogging by machine application [CS25]
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60] Operation to be undertaken outdoors [E69] , or: [G9] Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]
Dipping, immersion and pouring [CS4]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.8E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.4E+0
Maximum daily site tonnage (kg/day): 3.8E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.95
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.04
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.9 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
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Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 2.5E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 20. Rubber Production and Processing - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
SU 11: Manufacture of rubber products
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 5: Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact)
PROC 6: Calendering operations
PROC 7: Industrial spraying
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 10: Roller application or brushing
PROC 13: Treatment of articles by dipping andpouring
PROC 14: Production of preparations* or articles by tabletting, compression, extrusion, pelletisation
PROC 15: Use as laboratory reagent
PROC 21: Low energy manipulation of substances bound in materials and/or articles
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
ERC 6d: Industrial use of process regulators for polymerisa-tion processes in produc-tion of resins, rubbers, polymers
Specific Environmental Release Category
ESVOC 4.19a.v1
Processes, Tasks and Activities Covered
Manufacture of tyres and general rubber articles, including processing of raw (uncured) rubber, handling and mixing of rubber additives, calendaring, vulcanising, cooling and finishing as well as maintenance
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Up to 100% (unless stated).
Frequency and duration of Covers daily exposures up to 8 hours (unless stated differently). [G2].
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use
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Bulk weighing [CS91] (closed systems) [CS107]
No other specific measures identified. [EI20]
Small scale weighing [CS90] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Additive premixing [CS92] (open systems) [CS108]
No other specific measures identified. [EI20]
Material transfers [CS3] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Calendering (including Banburys) [CS64] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]
No other specific measures identified. [EI20]
Pressing uncured rubberblanks [CS73]
No other specific measures identified. [EI20]
Tyre build up [CS112] Spraying [CS10]
Minimise exposure by extracted full enclosure for the operation or equipment [E61]
Vulcanisation [CS70] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]
Provide extract ventilation to material transfer points and other openings [E82]
Cooling cured articles [CS71] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]
Provide extract ventilation to points where emissions occur [E54]
Production of articles by dipping and pouring [CS113]
No other specific measures identified. [EI20]
Finishing operations [CS102]
No other specific measures identified. [EI20]
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
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Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 4.4E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 3.0E+4
Maximum daily site tonnage (kg/day): 1.0E+5
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM: 0.01
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-5
Release fraction to soil from process (initial release prior to RMM): 0.0001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]
Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 0%.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 73.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 5.0E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
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Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 21. Use in Polymer Processing - Industrial
Use Descriptor Sector(s) of Use SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact)
PROC 6: Calendering operations
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 13: Treatment of articles by dipping andpouring
PROC 14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation
PROC 21: Low energy manipulation of substances bound in materials and/or articles
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
ERC 6d: Industrial use of process regulators for polymerisa-tion processes in produc-tion of resins, rubbers, polymers
Specific Environmental Release Category
ESVOC 4.21a.v1
Processes, Tasks and Activities Covered
Processing of formulated polymers including material transfers, additives handling (e.g. pigments, stabilisers, fillers, plasticisers, etc.), moulding, curing and forming activities, material re-works, storage and associated maintenance
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138]. Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated differently). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
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Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Bulk weighing [CS91] (closed systems) [CS107]
No other specific measures identified. [EI20]
Small scale weighing [CS90]
No other specific measures identified. [EI20]
Additive premixing [CS92]
No other specific measures identified. [EI20]
Calendering (including Banburys) [CS64] Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7]
Provide extract ventilation to material transfer points and other openings. [E82]
Production of articles by dipping and pouring [CS113]
No other specific measures identified. [EI20]
Extrusion and masterbatching [CS88]
No other specific measures identified. [EI20]
Injection moulding of articles [CS89]
No other specific measures identified. [EI20]
Finishing operations [CS102]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.3E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.3E+4
Maximum daily site tonnage (kg/day): 4.3E+4
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM: 1.0E-1
Release fraction to wastewater from process (initial release prior to RMM): 0
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Release fraction to soil from process (initial release prior to RMM): 0.00001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 80 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 2.9E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects.
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[G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 22. Use in Polymer Processing - Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Products Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 6: Calenderin operations
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at dedicated facili-ties
PROC 14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation
PROC 21: Low energy manipulation of substances bound in materials and/or articles
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
Specific Environmental Release Category
8.21b.v1
Processes, Tasks and Activities Covered
Processing of formulated polymers including material transfers, moulding and forming activities, material re-works and associated maintenance.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use/exposure
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.3E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.3E+4
Maximum daily site tonnage (kg/day): 4.3E+4
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Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM: 1.0E-1
Release fraction to wastewater from process (initial release prior to RMM): 0
Release fraction to soil from process (initial release prior to RMM): 0.00001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 80 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 2.9E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Material transfers [CS3] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Injection moulding of articles [CS89]
No other specific measures identified. [EI20]
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Rework of articles [CS86]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 3.0E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.5E+0
Maximum daily site tonnage (kg/day): 4.1E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution fraction: 10
Local marine dilution fraction: 100
Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.98
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.01
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.9 %.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %.
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %. Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release (kg/d) 2.7E+1.
Assumed domestic sewage treatment plant flow (m3/day): 2000
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Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations. [ERW1]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
[G21]
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 23. Use as a Fuel – Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 16: Using material as fuel sources, limited exposure to unburned product to be expected
Environmental Release Categories
ERC 7: Industrial use of sub-stances in closed systems
Specific Environmental Release Category
ESVOC 7.12a.v1
Processes, Tasks and Activities Covered
Covers the use as a fuel (or fuel additives and additive components) and includes activities associated with its transfer, use, equipment maintenance and handling of waste.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) G13
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Covers the use as a fuel (or fuel additive) and includes activities associated with its transfer, use, equipment
No other specific measures identified. [EI20]
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maintenance and handling of waste. [GES12] (closed systems) [CS107]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 4.6E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 4.6E+4
Maximum daily site tonnage (kg/day): 1.5E+5
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM: 5.0E-3
Release fraction to wastewater from process (initial release prior to RMM): 0.00001
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 95 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 76.5 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based release following total wastewater treatment removal 6.7E+5 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
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Conditions and measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls [ETW1]. Combustion emissions considered in regional exposure assessment [ETW2]. External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated. [ERW3]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk ManagementMeasures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 24. Use as a Fuel – Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 16: Using material as fuel sources, limited exposure to unburned product to be expected
Environmental Release Categories
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Specific Environmental Release Category
ESVOC 9.12b.v1
Processes, Tasks and Activities Covered
Covers the use as a fuel (or fuel additives and additive components) and includes activities associated with its transfer, use, equipment maintenance and handling of waste.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Refuelling vehicles, light aircraft or marine [CS507]
No other specific measures identified. [EI20]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Covers the use as a fuel (or fuel additive) and
Limit the substance content in the product to 5 % [OC17]
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includes activities associated with its transfer, use, equipment maintenance and handling of waste. [GES12] (closed systems) [CS107]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.0E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.0E+1
Maximum daily site tonnage (kg/day): 2.7E+1
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 1.0E-4
Release fraction to wastewater wide dispersive use [OOC8]: 0.00001
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.00001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite
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(domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 1.8E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls [ETW1]. Combustion emissions considered in regional exposure assessment [ETW2]. External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated. [ERW3]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 25. Use as a Fuel – Consumer
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Products Categories PC 13: Fuels
Environmental Release Categories
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Specific Environmental Release Category
9.12c.v1
Processes, Tasks and Activities Covered
Covers consumer uses in fuels
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of consumer exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP. [OC3]
Vapour Pressure (Pa) 231
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently). [G13]
Frequency and duration of use/exposure
Covers daily exposures up to 8 hours (unless stated differently) [G2]
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Product Category
Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.
Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.0E+4
Fraction of regional tonnage used locally: 0.0005
Annual site tonnage (tonnes/year): 5.0E+0
Maximum daily site tonnage (kg/day): 1.4E+1
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other given operational Release fraction to air from wide dispersive use (regional use only)
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conditions affecting environmental exposure
[OOC7]: 1.0E-4
Release fraction to wastewater wide dispersive use [OOC8]: 0.00001
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.00001
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal (kg/d) 9.1E+1.
Assumed domestic sewage treatment plant flow (m3/day): 2000
Conditions and measures related to external treatment of waste for disposal
Combustion emissions limited by required exhaust emission controls [ETW1]. Combustion emissions considered in regional exposure assessment [ETW2]. External treatment and disposal of waste should comply with applicable local and/or national regulations.[ETW3]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated. [ERW3]
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
[G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 26. Lubricants - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (syn-thesis) where opportunity for exposure arises
PROC 7: Industrial spraying
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 10: Roller application or brushing
PROC 13: Treatment of articles by dipping and pouring
PROC 17: Lubrication at high energy conditions and in partly open process
PROC 18: Greasing at high energy conditions
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
ERC 7: Industrial use of sub-stances in closed systems
Specific Environmental Release Category
ESVOC 4.6a.v1
Processes, Tasks and Activities Covered
Covers the use of formulated lubricants in closed and open systems including material transfers operations, operation of machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures No other specific measures identified. [EI20]
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(closed systems) [CS15]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Bulk ransfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
Initial factory fill of equipment [CS75]
No other specific measures identified. [EI20]
Operation and lubrication of high energy open equipment [CS17]
Provide extract ventilation to points where emissions occur [E54]
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Treatment by dipping and pouring [CS35]
No other specific measures identified. [EI20]
Spraying [CS10] Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60]
Maintenance (of larger plant items) and machine set up [CS77] Dedicated facility [CS81] Elevated temperature [CS111]
No other specific measures identified. [EI20]
Maintenance of small items [CS18] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
Remanufacture of reject articles [CS19]
No other specific measures identified. [EI20]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 3.1E+5
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.0E+2
Maximum daily site tonnage (kg/day): 5.0E+3
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting
Release fraction to air from process (initial release prior to RMM): 5.0E-4
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environmental exposure Release fraction to wastewater from process (initial release prior to RMM): 1.0E-6
Release fraction to soil from process (initial release prior to RMM): 0.001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b]. Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 70 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.5 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on domestic sewage treatment release 3.3E+4 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
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Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 27. Lubricants – Professional: Low Environmental Release
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (syn-thesis) where opportunity for exposure arises
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at dedicated facili-ties
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 13: Treatment of articles by dipping andpouring
PROC 17: Lubrication at high energy conditions and in partly open process
PROC 20: Heat and pressure transfer fluids in dispersive, professional use but closed systems
Environmental Release Categories
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Environmental Release Category
ESVOC 9.6b.v1
Processes, Tasks and Activities Covered
Covers the use of formulated lubricants in closed or contained systems including material transfers operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
Operation of equipment containing engine oils and
No other specific measures identified. [EI20]
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similar [CS26] (Closed systems) [CS107]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82]
Avoid carrying out activities involving exposure for more than 1 hour [OC27]
Operation and lubrication of high energy open equipment [CS17] Indoor [OC8]
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]
Operation and lubrication of high energy open equipment [CS17] Outdoor [OC9]
Ensure operation is undertaken outdoors [E69] Avoid carrying out operation for more than 4 hours [OC12] Limit the substance content in the product to 25 % [OC18]
Maintenance (of larger plant items) and machine set up [CS77] Dedicated facility [CS81] Elevated temperature [CS111]
Drain down system prior to equipment break-in or maintenance [E65] Provide extract ventilation to emission points when contact with warm (>50oC) lubricant is likely) [E67]
Maintenance of small items [CS18] Non-dedicated facility [CS82] Elevated temperature [CS11]
Drain or remove substance from equipment prior to break-in or maintenance [E81] Provide a good standard of general ventilation (3 to 5 air changes per hour) [E11]
Engine lubricant service [CS78]
No other specific measures identified. [EI20]
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Spraying [CS10] Carry out in a vented booth or extracted enclosure [E57], or: [G9] Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60] Avoid carrying out activities involving exposure for more than 1 hr [OC27] , or: [G9] Wear a respirator conforming to EN140 with Type A filter or better [PPE22]
Treatment by dipping and pouring [CS35]
No other specific measures identified. [EI20]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.1E+5
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Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 5.3E+1
Maximum daily site tonnage (kg/day): 365
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.01
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.01
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 76.1 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based release following total wastewater treatment removal 6.5E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
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Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 28. Lubricants – Professional: High Environmental Release
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (syn-thesis) where opportunity for exposure arises
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at dedicated facili-ties
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 13: Treatment of articles by dipping andpouring
PROC 17: Lubrication at high energy conditions and in partly open process
PROC 20: Heat and pressure transfer fluids in dispersive, professional use but closed systems
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
Specific Environmental Release Category
ESVOC 8.6c.v1
Processes, Tasks and Activities Covered
Covers the use of formulated lubricants in open systems including material transfers operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
General exposures No other specific measures identified. [EI20]
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(closed systems) [CS15]
Operation of equipment containing engine oils and similar [CS26] (Closed systems) [CS107]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Bulk transfers [CS14] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82]
Avoid carrying out activities involving exposure for more than 1 hour [OC27]
Operation and lubrication of high energy open equipment [CS17] Indoor [OC8]
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]
Operation and lubrication of high energy open equipment [CS17] Outdoor [OC9]
Ensure operation is undertaken outdoors [E69] Avoid carrying out operation for more than 4 hours [OC12] Limit the substance content in the product to 25 % [OC18]
Maintenance (of larger plant items) and machine set up [CS77] Dedicated facility [CS81] Elevated temperature [CS111]
Drain down system prior to equipment break-in or maintenance [E65] Provide extract ventilation to emission points when contact with warm (>50oC) lubricant is likely) [E67]
Maintenance of small items [CS18] Non-dedicated facility [CS82] Elevated temperature [CS111]
Drain or remove substance from equipment prior to break-in or maintenance [E81] Provide a good standard of general ventilation (3 to 5 air changes per hour) [E11]
Engine lubricant service [CS78]
No other specific measures identified. [EI20]
Manual [CS34] Roller, brushing [CS51]
No other specific measures identified. [EI20]
Spraying [CS10] Carry out in a vented booth or extracted enclosure [E57], or: [G9] Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60] Avoid carrying out activities involving exposure for more than 1 hr [OC27] , or: [G9] Wear a respirator conforming to EN140 with Type A filter or better [PPE22]
Treatment by dipping and pouring [CS35]
No other specific measures identified. [EI20]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic.
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[PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 8.1E+4
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 4.0E+1
Maximum daily site tonnage (kg/day): 1.1E+2
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 5.0E-3
Release fraction to wastewater wide dispersive use [OOC8]: 0.05
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 87.6 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on following total wastewater treatment removal 2.6E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION
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Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 29. Lubricants – Consumer: Low Environmental Release
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Process Categories PC 1: Adhesives, sealants
PC 24: Lubricants, greases, release products
PC 31: Polishes and wax blends
Environmental Release Categories
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Specific Environmental Release Category
ESVOC 9.6d.v1
Processes, Tasks and Activities Covered
Covers the consumer use of formulated lubricants in closed or contained systems including transfer operations, application, operation of engines and similar articles, equipment maintenance and disposal of waste oil.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Product Category
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.1E+5
Fraction of regional tonnage used locally: 0.0005
Annual site tonnage (tonnes/year): 5.6E+1
Maximum daily site tonnage (kg/day): 1.6E+2
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
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Other given operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.01
Release fraction to wastewater wide dispersive use [OOC8]: 0.01
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.01
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 6.9E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 30. Lubricants – Consumer: high environmental release
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Process Categories PC 1: Adhesives, sealants
PC 24: Lubricants, greases, release products
PC 31: Polishes and wax blends
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
Specific Environmental Release Category
ESVOC 8.6e.v1
Processes, Tasks and Activities Covered
Covers the consumer use of formulated lubricants in open systems including transfer operations, application, operation of engines and similar articles, equipment maintenance and disposal of waste oil.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Products Category
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure.
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 2.9E+4
Fraction of regional tonnage used locally: 0.0005
Annual site tonnage (tonnes/year): 1.4E+1
Maximum daily site tonnage (kg/day): 3.9E+1
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk
Local freshwater dilution factor: 10
Local marine dilution factor: 100
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management
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 5.0E-3
Release fraction to wastewater wide dispersive use [OOC8]: 0.05
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0.05
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.6E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.
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SECTION 1 EXPOSURE SCENARIO TITLE Title 31. Use in Laboratories - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 10: Roller application or brushing
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
Not Applicable
Processes, Tasks and Activities Covered
Use of the substance within laboratory settings, including material transfers and equipment cleaning
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.2E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 2.0E+0
Maximum daily site tonnage (kg/day): 1.0E+2
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting
Release fraction to air from process (initial release prior to RMM): 0.025
Release fraction to wastewater from process (initial release prior to
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environmental exposure RMM): 0.02
Release fraction to soil from process (initial release prior to RMM): 0.0001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 0 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 78.7 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 4.0E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32].
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Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 32. Use in Laboratories - Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 10: Roller application or brushing
PROC 15: Use as laboratory reagent
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
Specific Environmental Release Category
ESVOC 8.17a.v1
Processes, Tasks and Activities Covered
Use of the substance within laboratory settings, including material transfers and equipment cleaning
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Laboratory activities [CS36]
No other specific measures identified. [EI20]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.2E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 6.0E-1
Maximum daily site tonnage (kg/day): 1.6E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.5
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Release fraction to wastewater wide dispersive use [OOC8]: 0.5
Release fraction to soil from wide dispersive use (regional use only) [OOC9]: 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 0 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 72.1 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 8.6E+0 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32].
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Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 33. Use in Mining Operations – Industrial
Use Descriptor Sector(s) of Use SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 5: Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 4.23.v1
Processes, Tasks and Activities Covered
Covers the use of the substance in extraction processes at mining operations, including material transfers, winning and separation activities, and substance recovery and disposal.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Pouring from small No other specific measures identified. [EI20]
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containers [CS9]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Phase separation [CS106] No other specific measures identified. [EI20]
Ion exchange processes [CS105] (closed systems) [CS107]
No other specific measures identified. [EI20]
Process sampling [CS2] No other specific measures identified. [EI20]
Mixing operations (closed systems) [CS29]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.0E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 2.0E+2
Maximum daily site tonnage (kg/day): 1.0E+4
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.25
Release fraction to wastewater from process (initial release prior to RMM): 0.50
Release fraction to soil from process (initial release prior to RMM): 0.05
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, additional onsite wastewater treatment required [TCR14].
Treat air emission to provide a typical removal efficiency of 80 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 99.0 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 82.0 %
Organizational measures to prevent / limit release
Do not apply industrial sludge to natural soils [OMS2].
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from site Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.0E+4 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 34. Use in Water Treatment Chemicals - Industrial
Use Descriptor Sector(s) of Use SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC 13: Treatment of articles by dipping andpouring
Environmental Release Categories
ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles
Specific Environmental Release Category
ESVOC 4.23.v1
Processes, Tasks and Activities Covered
Covers the use of the substance for the treatment of water at industrial facilities in open and closed systems
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Use in contained systems [CS38]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Geneal Exposures (Closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open No other specific measures identified. [EI20]
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systems) [CS16]
Pouring from small containers [CS9]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 3.3E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 3.0E+1
Maximum daily site tonnage (kg/day): 1.0E+2
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 300
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.05
Release fraction to wastewater from process (initial release prior to RMM): 0.95
Release fraction to soil from process (initial release prior to RMM): 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, additional onsite wastewater treatment required [TCR14].
Treat air emission to provide a typical removal efficiency of 0 %.
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 98.9 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 79.1 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 98.9 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.0E+2 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
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Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 35. Use in Water Treatment Chemicals - Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC 13: Treatment of articles by dipping andpouring
Environmental Release Categories
ERC 8a: Wide dispersive indoor use of processing aids in open systems
ERC 8d: Wide dispersive outdoor use of processing aids in open systems
ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix
Specific Environmental Release Category
ESVOC 8.22b.v1
Processes, Tasks and Activities Covered
Covers the use of the substance for the treatment of water in open and closed systems
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Geneal Exposures (Closed systems) [CS15]
No other specific measures identified. [EI20]
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General exposures (open systems) [CS16]
No other specific measures identified. [EI20]
Pouring from small containers [CS9]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.7E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.5E+0
Maximum daily site tonnage (kg/day): 4.0E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.01
Release fraction to wastewater wide dispersive use [OOC8]: 0.99
Release fraction to soil from wide dispersive use (regional use only) n [OOC9]: 0
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A..
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 84.8 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following
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total wastewater treatment removal 1.1E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 36. Explosives Manufacture and Use - Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
Environmental Release Categories
ERC 8e: Wide dispersive outdoor use of reactive substances in open systems
Specific Environmental Release Category
Not Applicable
Processes, Tasks and Activities Covered
Covers exposures arising from the manufacture and use of slurry explosives (including materials transfer, mixing and charging) and equipment cleaning
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] Use in contained batch process [CS37]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Non-dedicated facility [CS82]
Use drum pumps [E53]
Mixing operations (closed systems) [CS29]
No other specific measures identified. [EI20]
Mixing operations (open systems) [CS30]
No other specific measures identified. [EI20]
Material transfers [CS3] Non-dedicated facility [CS82]
Ensure operation is undertaken outdoors [E69]. Avoid carrying out activities involving exposure for more than 4 hours [OC28]
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Transfer from/pouring from containers [CS22] Non-dedicated facility [CS82]
Ensure operation is undertaken outdoors [E69]. Avoid carrying out activities involving exposure for more than 4 hours [OC28]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.7E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 8.4E-1
Maximum daily site tonnage (kg/day): 2.3E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.001
Release fraction to wastewater wide dispersive use [OOC8]: 0.02
Release fraction to soil from wide dispersive use (regional use only) n [OOC9]: 0.01
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A..
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 65.0 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.5E+1 kg per day.
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Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 37. Use as Functional Fluids - Industrial
Use Descriptor Sector(s) of Use SU 3: Industrial uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
Environmental Release Categories
ERC 7: Industrial use of substances in closed systems
Specific Environmental Release Category
ESVOC 7.13a.v1
Processes, Tasks and Activities Covered
Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants, hydraulic fluids in industrial equipment including maintenance and related material transfers
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling of articles/equipment [CS84] (closed systems) [CS107]
No other specific measures identified. [EI20]
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Filling / preparation of equipment from drums or containers. [CS45] Non-dedicated facility [CS82]
No other specific measures identified. [EI20]
General exposures (closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16] Elevated temperature [CS111]
Restrict area of openings and provide extract ventilation to emission points when substance handled at elevated temperatures [E75]
Remanufacture of reject articles [CS19]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.2E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 1.0E+1
Maximum daily site tonnage (kg/day): 5.0E+2
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 20
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 5.0E-4 Release fraction to wastewater from process (initial release prior to RMM): 1.0E-6 Release fraction to soil from process (initial release prior to RMM): 0.001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] Prevent discharge of undissolved substance to or recover from onsite wastewater [TCR14]. If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of 0 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.4 %
If discharging to domestic sewage treatment plant, provide the required
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onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 3.3E+3 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23].
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 38. Use as Functional Fluids – Professional
Use Descriptor Sector(s) of Use SU 22: Professional uses
Process Categories PROC 1: Use in closed process, no likelihood of exposure
PROC 2: Use in closed, continuous process with occasional controlled exposure
PROC 3: Use in closed batch process (synthesis or formulation)
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC 20: Heat and pressure transfer fluids in dispersive, professional use but closed systems
Environmental Release Categories
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Specific Environmental Release Category
ESVOC 9.13b.v1
Processes, Tasks and Activities Covered
Use as functional fluids e.g. cable oils, transfer oils, insulators, refrigerants, hydraulic fluids in professional equipment including maintenance and related material transfers.
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
Bulk transfers [CS14] (closed systems) [CS107]
No other specific measures identified. [EI20]
Drum/batch transfers [CS8] Dedicated facility [CS81]
No other specific measures identified. [EI20]
Filling of articles/equipment [CS84] (closed systems) [CS107]
No other specific measures identified. [EI20]
Filling / preparation of equipment from drums or
No other specific measures identified. [EI20]
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containers. [CS45] Non-dedicated facilities [CS82]
Geneal Exposures (Closed systems) [CS15]
No other specific measures identified. [EI20]
General exposures (open systems) [CS16] Elevated temperature [CS111]
Restrict area of openings and provide extract ventilation to emission points when substance handled at elevated temperatures [E75]
Remanufacture of reject articles [CS19]
No other specific measures identified. [EI20]
Equipment cleaning and maintenance [CS39]
Drain down system prior to equipment break-in or maintenance [E65]
Storage [CS67] Store substance within a closed system [E84]
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.2E+3
Fraction of regional tonnage used locally: 1
Annual site tonnage (tonnes/year): 6.0E-1
Maximum daily site tonnage (kg/day): 1.6E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting environmental exposure
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.05
Release fraction to wastewater wide dispersive use [OOC8]: 0.025
Release fraction to soil from wide dispersive use (regional use only) n [OOC9]: 0.025
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Risk from environmental exposure is driven by Freshwater Sediment [TCR1b] If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR10].
Treat air emission to provide a typical removal efficiency of N/A..
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency ≥ 64.9 %
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of ≥ 0.0 %
Organizational measures to prevent / limit release from site
Do not apply industrial sludge to natural soils [OMS2].
Sludge should be incinerated, contained or reclaimed [OMS3].
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Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.1E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
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SECTION 1 EXPOSURE SCENARIO TITLE Title 39. Use as Functional Fluids - Consumer
Use Descriptor Sector(s) of Use SU 21: Consumer uses
Process Categories PC 16: Heat transfer fluids
PC 17: Hydraulic fluids
Environmental Release Categories
ERC 9a: Wide dispersive indoor use of substances in closed systems
ERC 9b: Wide dispersive outdoor use of substances in closed systems
Specific Environmental Release Category
ESVOC 9.13c.v1
Processes, Tasks and Activities Covered
Use of sealed items containing functional fluids e.g. transfer oils, hydraulic fluids, refrigerants
SECTION 2 OPERATIONAL CONDITIONS AND RISK MANAGEMENT MEASURES Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, with potential for aerosol generation [CS138] Vapour pressure < 0.5 kPa at STP [OC3].
Concentration of substance in product
Covers percentage substance in the product up to 100% (unless stated differently) [G13]
Frequency and duration of use
Covers daily exposures up to 8 hours (unless stated). [G2].
Other operational conditions affecting worker exposure
Operation is carried out at elevated temperature (> 20°C above ambient temperature). [OC7]. Assumes a good basic standard of occupational hygiene is implemented. [G1].
Contributing Scenarios
Specific Risk Management Measures and Operational Conditions (only required controls to demonstrate safe use listed)
No exposure scenario presented for human health. Re fer to Appendix 2 for the qualitative assessment of consumer aerosol exposure
Section 2.2 Control of environmental exposure
Product characteristics Substance is complex UVCB. [PrC3]. Predominantly hydrophobic. [PrC4a].
Amounts used Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tonnes/year): 1.2E+3
Fraction of regional tonnage used locally: 0.0005
Annual site tonnage (tonnes/year): 6.0E-1
Maximum daily site tonnage (kg/day): 1.6E+0
Frequency and duration of use
Continuous release. [FD2].
Emission days (days/year): 365
Environmental factors not influenced by risk management
Local freshwater dilution factor: 10
Local marine dilution factor: 100
Other operational conditions affecting
Release fraction to air from wide dispersive use (regional use only) [OOC7]: 0.05
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environmental exposure Release fraction to wastewater wide dispersive use [OOC8]: 0.025
Release fraction to soil from wide dispersive use (regional use only) n [OOC9]: 0.025
Conditions and measures related to municipal sewage treatment plant
Not applicable as there is no release to wastewater [STP1].
Estimated substance removal from wastewater via domestic sewage treatment 94.7 %.
Maximum allowable site tonnage (MSafe) based on release following total wastewater treatment removal 1.1E+1 kg per day.
Assumed domestic sewage treatment plant flow 2 000 m3 per day.
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3].
Conditions and measures related to external recovery of waste
External recovery and recycling of waste should comply with applicable local and/or national regulations [ERW1].
SECTION 3 EXPOSURE ESTIMATION Section 3.1 Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. [G21].
Section 3.2 Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model. [EE2].
SECTION 4 GUIDANCE TO CHECK COMPLIANCE WITH THE EXPOSURE SCENARIO Section 4.1 Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented. [G22].
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. [G23]. Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]. Available hazard data do not support the need for a DNEL to be established for other health effects. [G36]. Risk Management Measures are based on qualitative risk characterisation. [G37].
Section 4.2 Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures.