safety data sheet...safety data sheet version 2.1 sds number 002e revision date 10/22/2018 print...

Safety Data Sheet Version 2.1

SDS Number 002e Revision Date 10/22/2018 Print Date 10/22/2018 SECTION1:Identificationofthesubstance/mixtureandthecompany/undertaking

1.1ProductIdentifier: OneStepNo-RinseCleanser

RefertoSection3forREACHinformation

1.2Relevantidentifiedusesofthesubstanceofmixtureandusesadvisedagainst

1.2.1UseoftheSubstance/Mixture : DetergentCleansingProductWashingProducts:BleachingAgent

1.2.2Usesadvisedagainst : Nousesadvisedagainstknown

1.3Detailsofthesupplierofthesafetydatasheet

AddressofthesupplieroftheSDS : LOGIC,Inc.P.O.Box1586Midlothian,VA23113USA

EmailAddress–TechnicalInformation : [email protected] : 00+1+8446556442

1.4Emergencytelephonenumber

00 + 1 + 800 424 9300 00 + 1 + 800 424 9300 CCN824341

SECTION2:Hazardsidentification 2.2Labelelements

LabellingaccordingtoRegulationECNo.1272/2008

H-statements H319 CausesseriouseyeirritationH315 Causesskinirritation P-Statements P264 WashexposedskinafterhandlingP280 Weareyeprotection,protectivegloves


SDS Number 002e Revision Date 10/22/2018 Print Date 10/22/2018

P302+P352 Ifonskin:WashwithsoapandwaterP305+P351+P338 Ifineyes:Rinsecautiouslywithwaterforseveralminutes.Remove

contactlenses,ifpresentandeasytodo.Continuerinsing.P337+P313 Ifeyeirritationpersists:Getmedicaladvice/attention

2.3Otherhazards

Noadditionalinformationavailable

SECTION3:Composition/informationoningredients3.1Substances : Mono-constituentsubstance

Product/ingredientname Identifier REACHnumber Wt% ClassificationaccordingtoCLP(1) TypeSodiumCarbonatePeroxyhydrate

CAS15630-89-4EC239-707-6

01-2119457268-30 40–60 Ox.Sol.2;H272AcuteTox.4;H302EyeDam.1;H318

[A]

SodiumCarbonate CAS497-19-8EC207-838-8

01-2119485498-19 20–40 EyeIrrit.2A;H319 [A]

SodiumCitrate CAS6132-04-3EC200-675-3

01-2119457027-40 10–20 NotClassified. [C]

SodiumChloride CAS7647-14-5EC231-598-3

Nodataavailable 0–10 NotClassified. [B]

Therearenoadditionalingredientspresentwhich,withintheknowledgeofthesupplier,areclassified andcontributetotheclassificationofthesubstanceandhencerequirereportingwithinthissection.(1) ForH-statementsinfull:seeheading16Type[A]Constituent[B]Impurity[C]Stabilisingadditive

3.2Mixtures

Notapplicable

SECTION4:Firstaidmeasures:4.1Descriptionoffirstaidmeasures:

General:

Checkthevitalfunctions.Unconscious:maintainadequateairwayandrespiration.Respiratoryarrest:artificialrespirationoroxygen.Cardiacarrest:performresuscitation.Victimconsciouswithlabouredbreathing:half-seated.Victiminshock:onhisbackwithlegsslightlyraised.Vomiting:preventasphyxia/aspirationpneumonia.Preventcoolingbycoveringthevictim(nowarmingup).Keepwatchingthe



victim.Givepsychologicalaid.Keepthevictimcalm,avoidphysicalstrain.Dependingonthevictim'scondition:doctor/hospital.

Afterinhalation:

Removethepersontofreshair.Respiratoryproblems:consultadoctor/medicalservice.

Afterskincontact:

Rinsewithwater.Soapmaybeused.Donotapply(chemical)neutralizingagents.Takevictimtoadoctorifirritationpersists.

Aftereyecontact:

Rinseimmediatelywithplentyofwater.Donotapplyneutralizingagents.Takevictimtoanophthalmologistifirritationpersists.Removecontactlensesifpresentandeasytodo.Continuerinsing.Ifeyeirritationpersists:Getmedicaladvice/attention.

Afteringestion:

Rinsemouthwithwater.Immediatelyafteringestion:givelotsofwatertodrink.Donotinducevomiting.Consultadoctor/medicalserviceifyoufeelunwell.

4.2Mostimportantsymptomsandeffects,bothacuteanddelayed:

4.2.1Acutesymptoms:

Afterinhalation:

AFTERINHALATIONOFDUST:Dry/sorethroat.Coughing.Irritationoftherespiratorytract.Irritationofthenasalmucousmembranes.

Afterskincontact:

Notirritating.

Aftereyecontact:

Irritationoftheeyetissue.Irritationtoeyes.

Afteringestion:

AFTERABSORPTIONOFHIGHQUANTITIES:Nausea.Abdominalpain.Irritationofthegastric/intestinalmucosa.

4.2.2Delayedsymptoms

Noeffectsknown.

4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded:

Treatsymptomatically

SECTION5:Firefightingmeasures5.1Extinguishingmedia:

5.1.1Suitableextinguishingmedia:

Adaptextinguishingmediatotheenvironment.Waterspray.Drypowder.Foam.

5.1.2Unsuitableextinguishingmedia:



Nounsuitableextinguishingmediaknown.

5.2Specialhazardsarisingfromthesubstanceormixture:

Uponcombustion:COandCO2areformed.

5.3Adviceforfirefighters:

5.3.1Instructions:

Cooltanks/drumswithwaterspray/removethemtosafety.Donotmovetheloadifexposedtoheat.Aftercooling:persistentriskofphysicalexplosion.

5.3.2Specialprotectiveequipmentforfire-fighters:

Gloves.Safetyglasses.Protectiveclothing.Dustcloudproduction:compressedair/oxygenapparatus.Heat/fireexposure:compressedair/oxygenapparatus.

SECTION6:Accidentalreleasemeasures6.1Personalprecautions,protectiveequipmentandemergencyprocedures:

Preventdustcloudformation,e.g.bywetting.Nonakedflames.

6.1.1Protectiveequipmentfornon-emergencypersonnel

Gloves.Safetyglasses.Protectiveclothing.

6.1.2Protectiveequipmentforemergencyresponders

Gloves.Safetyglasses.Protectiveclothing.Dustcloudproduction:compressedair/oxygenapparatus.

Suitableprotectiveclothing

Seeheading8.2

6.2Environmentalprecautions:

Containreleasedsubstance,pumpintosuitablecontainers.Plugtheleak,cutoffthesupply.Damupthesolidspill.Knockdown/dilutedustcloudwithwaterspray.Preventspreadinginsewers.

6.3Methodsandmaterialforcontainmentandcleaningup:

Preventdustcloudformation.Scoopsolidspillintoclosingcontainers.CleancontaminatedsurfaceswithanExcessofwater.Washclothingandequipmentafterhandling.

6.4Referencetoothersections:

Seeheading13.

SECTION7:HandlingandstorageTheinformationinthissectionisageneraldescription.Ifapplicableandavailable,exposurescenariosareattachedinannex.Alwaysusetherelevantexposurescenariosthatcorrespondtoyouridentifieduse.

7.1Precautionsforsafehandling:



Avoidraisingdust.Keepawayfromnakedflames/heat.Observenormalhygienestandards.Keepcontainertightlyclosed.Removecontaminatedclothing.Cleancontaminatedclothing.Avoidcontactwitheyes.Alwayswashhandsafterhandlingtheproduct.

7.2Conditionsforsafestorage,includinganyincompatibilities:

7.2.1Safestoragerequirements:

Storeinacoolarea.Storeinadryarea.Keepcontainerinawell-ventilatedplace.Keepoutofdirectsunlight.

7.2.2Keepawayfrom:

Heatsources,oxidizingagents,(strong)acids,(strong)bases,metals,water/moisture.

7.2.3Suitablepackagingmaterial:

Stainlesssteel,polyethylene,polypropylene.

7.2.4Nonsuitablepackagingmaterial:

Aluminium,zinc.

7.3Specificenduse(s):

Noadditionalinformationisavailable.

SECTION8:Exposurecontrols/personalprotection8.1Controlparameters:

8.1.1Occupationalexposure

a)Occupationalexposurelimitvalues

Iflimitvaluesareapplicableandavailablethesewillbelistedbelow.

b)Nationalbiologicallimitvalues

Iflimitvaluesareapplicableandavailablethesewillbelistedbelow.

DNEL–Generalpopulation

Product/ingredientname Type Exposure ValueSodiumCarbonatePeroxyhydrate DNEL Long-termlocaleffects,inhalation 5mg/m3

Long-termlocaleffects,dermal 6.4mg/cm2Acutelocaleffectsdermal 6.4mg/cm2

SodiumCarbonate DNEL Acutelocaleffects,inhalation 10mg/m3

PNEC

Product/ingredientname Compartments ValueSodiumCarbonatePeroxyhydrate

FreshWater 0.035mg/LMarineWater 0.035mg/LAqua(intermittentreleases) 0.035mg/LSTP 16.24mg/L



8.2Exposurecontrols:

Theinformationinthissectionisageneraldescription.Ifapplicableandavailable,exposurescenariosareattachedinannex.Alwaysusetherelevantexposurescenariosthatcorrespondtoyouridentifieduse.

8.2.1Appropriateengineeringcontrols

Avoidraisingdust.Keepawayfromnakedflames/heat.Carryoperationsintheopen/underlocalexhaust/ventilationorwithrespiratoryprotection.

8.2.2Individualprotectionmeasures,suchaspersonalprotectiveequipment

Observenormalhygienestandards.Keepcontainertightlyclosed.Donoteat,drinkorsmokeduringwork.

a)Respiratoryprotection:

Dustproduction:dustmaskwithfiltertypeP2.

b)Handprotection:

Gloves.

-materialsforprotectiveclothing(goodresistance)

Butylrubber,PVC.

c)Eyeprotection:

Safetyglasses.Incaseofdustproduction:protectivegoggles.

d)Skinprotection:

Protectiveclothing.

8.2.3Environmentalexposurecontrols:

Seeheadings6.2,6.3and13

SECTION9:Physicalandchemicalproperties9.1Informationonbasicphysicalandchemicalproperties:Physicalstate : Solid(Powder)Appearance : CrystallinepowderOdour : MildlyalkalineOdourthreshold : NodataavailableColour : WhitepH : 10.5at1%;20oCLogKow : NodataavailableRelativedensity : NodataavailableDynamicviscosity : NotapplicableKinematicviscosity : NotapplicableVaporpressure : NotapplicableVapordensity(air=1) : NotapplicableEvaporationrate : NotapplicableBoilingpoint : Notapplicable



Freezing/meltingpoint : NotapplicableFlashpoint : Nodataavailable Method : Flammability : Notapplicable UFL : Explosionlimits : NotapplicableDecompositiontemperature : >75oCAutoignitiontemperature : NotapplicableOxidizingproperties : Mayintensifyfire;oxidizer%volatile : NotapplicableSolubilityinwater : 300g/liter

9.2Otherinformation:

Absolutedensity:1850kg/m³

SECTION10:Stabilityandreactivity10.1Reactivity:

Promotescombustion.Substancehasbasicreaction.

10.2Chemicalstability:

Hygroscopic.

10.3Possibilityofhazardousreactions:

Decomposesslowly:oxidationresultinginincreasedfireorexplosionrisk.Thisreactionisacceleratedonexposuretowater(moisture)andtemperaturerise.

10.4Conditionstoavoid:

Avoidraisingdust.Keepawayfromnakedflames/heat.

10.5Incompatiblematerials:

Oxidizingagents,(strong)acids,(strong)bases,metals,water/moisture,aluminium,zinc.

10.6Hazardousdecompositionproducts:

Reactswithmanycompounds:oxidationresultinginincreasedfireorexplosionrisk.Uponcombustion:COandCO2areformed.

SECTION11:Toxicologicalinformation11.1Informationontoxicologicaleffects:

Notestdataisavailableonthemixture

Substancedata,whererelevantandavailable,arelistedbelow.

Acutetoxicity

AcuteoraltoxicityIngredient(s) Endpoint Value(mg/kg) Species Method Exposuretime(h)

SodiumCarbonate LD50 2800 Rat Methodnotgiven SodiumCarbonatePeroxyhydrate LD50 1034 Rat Methodnotgiven


SDS Number 002e Revision Date 10/22/2018 Print Date 10/22/2018 Acutedermaltoxicity

Ingredient(s) Endpoint Value(mg/kg) Species Method Exposuretime(h)

SodiumCarbonate LD50 >2000 Rabbit Methodnotgiven SodiumCarbonatePeroxyhydrate LD50 >2000 Rabbit OECD402(EUB.3) Acuteinhalativetoxicity

Ingredient(s) Endpoint Value(mg/kg) Species Method Exposuretime(h)

SodiumCarbonate LC50 2.3(dust) Rat OECD402(EUB.2) 2SodiumCarbonatePeroxyhydrate Nodataavailable IrritationandcorrosivitySkinirritationandcorrosivity

Ingredient(s) Result Species Method Exposuretime(h)

SodiumCarbonate Notirritant Rabbit Methodnotgiven SodiumCarbonatePeroxyhydrate Notirritant Rabbit Methodnotgiven

EyeirritationandcorrosivityIngredient(s) Result Species Method Exposuretime

(h)SodiumCarbonate Irritant Rabbit Methodnotgiven SodiumCarbonatePeroxyhydrate SevereDamage Rabbit EPAOPP81-4

RespiratorytractirritationandcorrosivityIngredient(s) Result Species Method Exposuretime

(h)SodiumCarbonate Nodataavailable SodiumCarbonatePeroxyhydrate Irritatingtorespiratorytract Mouse Methodnotgiven

SensitisationSensitisationbyskincontact

Ingredient(s) Result Species Method Exposuretime(h)

SodiumCarbonate Notsensitising Methodnotgiven SodiumCarbonatePeroxyhydrate Notsensitising Guineapig OECD406(EUB.6)/Buehlertest

SensitisationbyinhalationIngredient(s) Result Species Method Exposuretime

(h)


SDS Number 002e Revision Date 10/22/2018 Print Date 10/22/2018 SodiumCarbonate Nodataavailable SodiumCarbonatePeroxyhydrate Nodataavailable

Repeateddosetoxicity

Nodataavailable

CMReffects(carcinogenicity,mutagenicityandtoxicityforreproduction)

Nodataavailable

Potentialadversehealtheffectsandsymptoms

Effectsandsymptomsrelatedtotheproduct,ifany,arelistedinsubsection4.2

SECTION12:Ecologicalinformation12.1Toxicity:

Notestdataisavailableonthemixture

Substancedata,whererelevantandavailable,arelistedbelow.

Aquaticshort-termtoxicity

Aquaticshort-termtoxicity-fishIngredient(s) Endpoint Value(mg/l) Species Method Exposuretime(h)

SodiumCarbonate LC50 300 Lepomismacrochirus Methodnotgiven 96SodiumCarbonatePeroxyhydrate LC50 70.7 Pimephalespromelas Methodnotgiven 96

Aquaticshort-termtoxicity-crustaceaIngredient(s) Endpoint Value(mg/l) Species Method Exposuretime(h)

SodiumCarbonate EC50 265 Daphniamagna Methodnotgiven 96SodiumCarbonatePeroxyhydrate EC50 4.9 Daphniapulex Methodnotgiven 48

Aquaticshort-termtoxicity-algeaIngredient(s) Endpoint Value(mg/l) Species Method Exposuretime(h)

SodiumCarbonate Nodataavailable SodiumCarbonatePeroxyhydrate Nodataavailable

Impactonsewageplants–toxicitytobacteriaIngredient(s) Endpoint Value(mg/l) Inoculum Method Exposuretime(h)

SodiumCarbonate Nodataavailable SodiumCarbonatePeroxyhydrate EC50 466 Activatedsludge OECD209 0.5

Aquaticlong-termtoxicityAquaticlong-termtoxicity-fish



Ingredient(s) Endpoint Value(mg/l) Species Method Exposuretime(h)SodiumCarbonate Nodataavailable SodiumCarbonatePeroxyhydrate NOEC 7.4 Pimephalespromelas Methodnotgiven 96

Aquaticlong-termtoxicity-crustaceaIngredient(s) Endpoint Value(mg/l) Species Method Exposuretime(h)

SodiumCarbonate Nodataavailable SodiumCarbonatePeroxyhydrate NOEC 2 Daphniapulex Methodnotgiven 48

12.2Persistenceanddegradability:

AbioticDegradationIngredient(s) Degradation Half-lifetime Method Evaluation

SodiumCarbonatePeroxyhydrate

Photodegradationinair NA Methodnotgiven Hydrolysisinfreshwater <1day Methodnotgiven Hydrolysible

SodiumCarbonate Hydrolysisinfreshwater Nodataavailable Rapidlyhydrolysible

BiodegradationReadybiodegradability–aerobicconditions

Ingredient(s) Inoculum Analytical DT50 Method EvaluationSodiumCarbonatePeroxyhydrate

Notapplicable(inorganicsubstance)

SodiumCarbonate Notapplicable(inorganicsubstance)

SodiumCitrate Methodnotgiven 97%in28days Methodnotgiven ReadilybiodegradableSodiumChloride Notapplicable(inorganic

substance)

12.3Bioaccumulativepotential:

Notbioaccumulative.

12.4Mobilityinsoil:

Lowpotentialforadsorptioninsoil.

12.5ResultsofPBTandvPvBassessment:

SubstancesthatfulfillthecriteriaforPBT/nPvB,ifany,arelistedinsection3.

12.6Otheradverseaffects:

Nodataavailable.

SECTION13:Disposalconsiderations13.1Wastetreatmentmethods:



Wastetreatmentmethods : Disposeinasafemannerinaccordancewithlocal/nationalregulations.

Wastedisposalrecommendations

: Removewasteinaccordancewithlocaland/ornationalregulations.Hazardouswasteshallnotbemixedtogetherifthismayentailariskofpollutionorcreateproblemsforthefurthermanagementofthewaste.Hazardouswasteshallbemanagedresponsibly.Allentitiesthatstore,transportorhandlehazardouswasteshalltakethenecessarymeasurestopreventrisksofpollutionordamagetopeopleoranimals.Precipitate/makeinsoluble.Removetoanauthorizeddump(ClassI).Treatusingthebestavailabletechniquesbeforedischargeintodrainsortheaquaticenvironment.

Europeanwastecatalogue : 200129*-detergentscontainingdangeroussubstances

SECTION14:Transportinformation14.1UNnumber:

Notregulatedfortransport

14.2Propershippingname:

ADR/RID: NotregulatedIMDG: NotregulatedIATA: Notregulated

14.3Transporthazardclass(es):

ADR/RID: --IMDG: --IATA: --

14.4Packinggroup:

ADR/RID: --IMDG: --IATA: --

14.5Environmentalhazard

MarinePollutant: No

14.6Specialprecautionforuser

Notavailable

14.7TransporttobulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode

Notavailable

SECTION15:Regulatoryinformation15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture:



EURegulation(EC)No.1907/2006(REACH)

AnnexXIV-Listofsubstancessubjecttoauthorization

Substancesofveryhighconcern

Carcinogen : Noneofthecomponentsarelisted.Mutagen : Noneofthecomponentsarelisted.Toxictoreproduction : Noneofthecomponentsarelisted.PBT : Noneofthecomponentsarelisted.vPvB : Noneofthecomponentsarelisted.

AnnexXVII-Restrictionsonthemanufacture,placingonthemarketanduseofcertaindangeroussubstances,mixturesandarticles

Notapplicable.

OtherEUregulations

Europeinventory : Noneofthecomponentsarelisted.Integratedpollutionpreventionandcontrollist(IPPC)-Air–

: Notlisted

Integratedpollutionpreventionandcontrollist(IPPC)-Water–

: Notlisted

IngredientsaccordingtoECDetergentsRegulation648/2004

Oxygen-basedbleachingagents40-60%

15.2Chemicalsafetyassessment

Achemicalsafetyassessmenthasnotbeencarriedoutonthemixture

SECTION16:OtherinformationTheinformationinthisdocumentisbasedonourbestpresentknowledge.However,itdoesnotconstituteaguaranteeforanspecificproductfeaturesanddoesnotestablishalegallybindingcontract.

SDSVersion:2.5e Revision:2016/09/23

Reasonforrevision:

OveralldesignadjustedinaccordancewithRegulation(EC)No1907/2006,AnnexII

FulltextofanyH-statementsreferredtounderheadings2and3:H272–Mayintensifyfire;oxidizer.H302–Harmfulifswallowed.H315–Causesskinirritation.


SDS Number 002e Revision Date 10/22/2018 Print Date 10/22/2018 H318–Causesseriouseyedamage.H319–Causesseriouseyeirritation.

Abbreviationsandacronyms:PBT-substances=persistent,bioaccumulativeandtoxicsubstancesCLP(EU-GHS)–Classification,labellingandpackaging(GloballyHarmonisedSysteminEurope)DNEL–DerivedNoEffectLimitNTP–NationalToxicologyProgramPBT–Persistent,Bioaccumulative,andToxicPNEC–PredictedNoEffectLimitvPvB–veryPersistentandveryBioaccumulative

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