safety data sheet section 1: identification of the...

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Safety data sheetaccording to 1907/2006/EC, Article 31

Printing date 15.07.2015 Revision: 15.07.2015Version number 3

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier

· Trade name NEUKADUR hardener 242

· Article number: E1285

· Utilization of the substance of the formulation: Hardener for epoxi resin· 1.2 Relevant identified uses of the substance or mixture and uses advised against

No further relevant information available.· Application for the substance / the preparation hardener for epoxiresin· Uses advised against Not suitable for use in do-it-yourself applications.

· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:

ALTROPOL KUNSTSTOFF GmbHRudolf-Diesel-Str 9 - 13D-23617 StockelsdorfTel. +49 (0)451-49960-0Fax. +49 (0)451-49960-20e-mail: [email protected]

· Further information obtainable from: environment protection department· 1.4 Emergency telephone number:

During normal opening times (7 am - 5 pm )phone : +49 (0)451-49960-0 or +49 (0)176-10232577

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008

d~ GHS08 health hazard

Repr. 2 H361f Suspected of damaging fertility.

d~ GHS05 corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.

Eye Dam. 1 H318 Causes serious eye damage.

d~ GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H312 Harmful in contact with skin.

Skin Sens. 1 H317 May cause an allergic skin reaction.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.

· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008

The product is classified and labelled according to the CLP regulation.· Hazard pictograms

d~GHS05

d~GHS07

d~GHS08

(Contd. on page 2)

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d~ GHS05 corrosion



d~ GHS07







d~GHS05

d~GHS07

d~GHS08

(Contd. on page 2)

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d~ GHS05 corrosion



d~ GHS07







d~GHS05

d~GHS07

d~GHS08

(Contd. on page 2)

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Safety Data Sheet according to Regulation (EC) No. 1907/2006

Hardener GP 472

Date of issue/Date of revision: 15.07.2015 Version 3

1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation: Hardener GP 472 Use of the substance/preparation: hardener for epoxi resin Company/undertaking identification Company name: Gößl + Pfaff GmbH Street: Münchener Str. 13 Place: 85123 Karlskron/Brautlach Telephone: +49 (0) 8450 / 932-0 Fax-No.: +49 (0) 8450 / 932-13 Contact person: Management: Mr. Gößl, Mr. Pfaff e-mail: [email protected] Internet: www.goessl-pfaff.de Responsible Department: Management Emergency telephone: +49 (0) 8450 / 932-0

2. Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Repr. 2 H361f Suspected of damaging fertility

GHS05 corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage.

GHS07 Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H312 Harmful in contact with skin. Skin Sens. 1 H317 May cause an allergic skin reaction. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictograms

Signal word Danger

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d~ GHS05 corrosion



d~ GHS07







d~GHS05

d~GHS07

d~GHS08

(Contd. on page 2)

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Hazard-determining components of labelling: 3-aminomethyl-3,5,5-trimethylcyclohexylamine bisphenol A Polyetheramin m-phenylenebis (methylamine) Hazard statements H302+H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H361f Suspected of damaging fertility. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

3. Composition/information on ingredients 3.2 Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions.

Additional information: For the wording of the listed risk phrases refer to section 16.

4. First aid measures 4.1 Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

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Trade name NEUKADUR hardener 242

(Contd. of page 1)

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· Signal word Danger

· Hazard-determining components of labelling:3-aminomethyl-3,5,5-trimethylcyclohexylaminebisphenol APolyetheraminm-phenylenebis(methylamine)

· Hazard statementsH302+H312 Harmful if swallowed or in contact with skin.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.H361f Suspected of damaging fertility.H412 Harmful to aquatic life with long lasting effects.

· Precautionary statementsP260 Do not breathe dust/fume/gas/mist/vapours/spray.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with

water/shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.P310 Immediately call a POISON CENTER/doctor.P405 Store locked up.P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures· Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous components:

CAS: 2855-13-2EINECS: 220-666-8Reg.nr.: 01-2119514687-32

3-aminomethyl-3,5,5-trimethylcyclohexylamine

d~ Skin Corr. 1B, H314; d~ Acute Tox. 4, H302; Acute Tox. 4,H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412

75 - 100%

CAS: 39423-51-3Reg.nr.: 01-2119556886-20

Polyetheramin

d~ Eye Dam. 1, H318; d~ Aquatic Chronic 2, H411; d~ Acute Tox.4, H302; Acute Tox. 4, H312

5 - 10%

CAS: 80-05-7EINECS: 201-245-8Reg.nr.: 01-211945785623

bisphenol A

d~ Repr. 2, H361f; d~ Eye Dam. 1, H318; d~ Skin Sens. 1, H317;STOT SE 3, H335

2.5-5.0%

CAS: 1477-55-0EINECS: 216-032-5

m-phenylenebis(methylamine)

d~ Acute Tox. 3, H331; d~ Skin Corr. 1A, H314; d~ Acute Tox. 4,H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3,H412

2.5-5.0%

CAS: 25620-58-0EINECS: 247-134-8

trimethylhexane-1,6-diamine

d~ Skin Corr. 1B, H314; d~ Acute Tox. 4, H302; Skin Sens. 1,H317; Aquatic Chronic 3, H412

0.25-2.5%

CAS: 9046-10-0 Poly(oxypropylene)diamine

d~ Skin Corr. 1B, H314; d~ Acute Tox. 4, H302; Acute Tox. 4,H312; STOT SE 3, H335; Aquatic Chronic 3, H412

0.25-2.5%

CAS: 2467-02-9 2,2 Methylendiphenol

d~ Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335

0.25-2.5%

(Contd. on page 3)

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Personal protection for the First Aider. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. Immediate medical treatment necessary. Failure to treat burns can prevent wounds from healing. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. Protect unharmed eye. Seek medical treatment. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. If swallowed or vomiting, danger of entering the lungs. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.

5. Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: Water with full jet 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Corrosive vapors / gases Nitrogen oxides (NOx) toxic fume 5.3 Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Additional information Cool endangered receptacles with water spray. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Use respiratory protective device against the effects of fumes/dust/aerosol. Do not breathe vapor. Avoid contact with eyes and skin 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Prevent from spreading (e.g. by damming-in or oil barriers). Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralising agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

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(Contd. of page 4)

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Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.

· Respiratory protection:Unless the exposure levels below the established exposure limits remain is no respiratory protection isrequired. Where exposures exceed the established exposure limits, respiratory protection to the material andthe degree of exposure is recommended accordingly. A respiratory protection unit offers the same eye and face protection. The cutting, grinding or sanding of parts after curing can result in respirable dust. Wearing appropriate forthis dust respirators may be necessary.Use suitable respiratory protective device when aerosol or mist is formed.Filter P2Filter P3

· Protection of hands:Preventive skin protection (3-point program) required

S̀ Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.Chemical-resistant, impervious gloves complying with an approved standard at all times when handlingchemical products carriedbe, if a risk assessment indicates this is necessary.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.Suitable materials for protective gloves, EN 374-3: Polychloroprene - CR: thickness> = 0.5 mm, breakthrough time> = 480 min. NBR - NBR: thickness> = 0,35 mm, Breakthrough time> = 480 min. Butyl rubber - IIR: thickness> = 0.5 mm, breakthrough time> = 480 min. Fluorine rubber - FKM: thickness> = 0.4 mm; breakthrough time> = 480 min. Recommendation: Dispose of contaminated gloves ..

· Eye protection:

R̀ Tightly sealed goggles

· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties· General Information· Appearance:

Form: LiquidColour: Yellowish

· Odour: Ammonia-like

(Contd. on page 6)

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7. Handling and storage 7.1 Precautions for safe handling provide for best ventilation in the work space Ensure that suitable extractors are available on processing machines Prevent formation of aerosols. Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Segregate from foods and animal feeds. Segregate from acids. Segregate from oxidants. Information about storage in one common storage facility: Do not store together with oxidising and acidic materials as well as heavy-metal compounds. Store away from reducing agents. Store away from foodstuffs. Further information about storage conditions: Keep container tightly sealed. Protect from heat and direct sunlight. Protect from humidity and water. Store in cool, dry conditions in well sealed receptacles. Storage class: 8 A 7.3 Specific end use(s) No further relevant information available.

8. Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters

Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Respiratory protection: Unless the exposure levels below the established exposure limits remain is no respiratory protection is required. Where exposures exceed the established exposure limits, respiratory protection to the material and the degree of exposure is recommended accordingly. A respiratory protection unit offers the same eye and face protection. The cutting, grinding or sanding of parts after curing can result in respirable dust. Wearing appropriate for this dust respirators may be necessary. Use suitable respiratory protective device when aerosol or mist is formed. Filter P2 Filter P3 Protection of hands: Preventive skin protection (3-point program) required Protective gloves

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(Contd. of page 4)

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Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.

· Respiratory protection:Unless the exposure levels below the established exposure limits remain is no respiratory protection isrequired. Where exposures exceed the established exposure limits, respiratory protection to the material andthe degree of exposure is recommended accordingly. A respiratory protection unit offers the same eye and face protection. The cutting, grinding or sanding of parts after curing can result in respirable dust. Wearing appropriate forthis dust respirators may be necessary.Use suitable respiratory protective device when aerosol or mist is formed.Filter P2Filter P3

· Protection of hands:Preventive skin protection (3-point program) required

S̀ Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.Chemical-resistant, impervious gloves complying with an approved standard at all times when handlingchemical products carriedbe, if a risk assessment indicates this is necessary.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.Suitable materials for protective gloves, EN 374-3: Polychloroprene - CR: thickness> = 0.5 mm, breakthrough time> = 480 min. NBR - NBR: thickness> = 0,35 mm, Breakthrough time> = 480 min. Butyl rubber - IIR: thickness> = 0.5 mm, breakthrough time> = 480 min. Fluorine rubber - FKM: thickness> = 0.4 mm; breakthrough time> = 480 min. Recommendation: Dispose of contaminated gloves ..

· Eye protection:

R̀ Tightly sealed goggles

· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties· General Information· Appearance:

Form: LiquidColour: Yellowish

· Odour: Ammonia-like

(Contd. on page 6)

GB

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Chemical-resistant, impervious gloves complying with an approved standard at all times when handling chemical products carried be, if a risk assessment indicates this is necessary. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Suitable materials for protective gloves, EN 374-3: Polychloroprene - CR: thickness> = 0.5 mm, breakthrough time> = 480 min. NBR - NBR: thickness> = 0,35 mm, Breakthrough time> = 480 min. Butyl rubber - IIR: thickness> = 0.5 mm, breakthrough time> = 480 min. Fluorine rubber - FKM: thickness> = 0.4 mm; breakthrough time> = 480 min. Recommendation: Dispose of contaminated gloves .. Eye protection: Tightly sealed goggles Body protection: Protective work clothing

9. Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Liquid Colour: Yellowish Odour: Ammonia-like Odour threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 200 °C Flash point: 101 °C Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. Upper: Not determined. Vapour pressure: Not determined. Density at 20 °C: 1 g/cm3 Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Insoluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic at 20 °C: 80 mPas Kinematic: Not determined. Solvent content: Organic solvents: 0.0 % 9.2 Other information No further relevant information available.

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10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions Reaction with epoxies and isocyanates Strong exothermic reaction with acids. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: acid , chlorinated hydrocarbon , oxidizing agents , copper and copper alloy , nickel , cobalt . 10.6 Hazardous decomposition products: Ammonia Nitrogen oxides

11. Toxicological information 11.1 Information on toxicological effects Acute toxicity

Primary irritant effect: Skin corrosion/irritation Caustic effect on skin and mucous membranes. Serious eye damage/irritation Strong caustic effect. Respiratory or skin sensitisation Sensitisation possible through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Corrosive Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Repr. 2

12. Ecological information 12.1 Toxicity

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12.2 Persistence and degradability No further relevant information available. Other information: Elimination by adsorption onto activated sludge 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Harmful to fish Additional ecological information: General notes: Must not reach sewage water or drainage ditch undiluted or unneutralised. Harmful to aquatic organisms Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. 12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 12.6 Other adverse effects No further relevant information available.

13. Disposal considerations 13.1 Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. Must not be disposed together with household garbage. Do not empty into drains. In an appropriate facility or burn in an approved landfill Dispose. All applicable local and national or regional rules. Waste disposal key: The waste code according to the Waste Catalogue (AVV) depends on the waste producer and can therefore be different for a product. The waste code is to identify them separately from each waste producer. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. Recommended cleansing agents: Water, if necessary together with cleansing agents.

14. Transport information 14.1 UN-Number ADR, IMDG, IATA UN1760 14.2 UN proper shipping name ADR 1760 CORROSIVE LIQUID, N.O.S. (Polyetheramin, ISOPHORONEDIAMINE) IMDG, IATA CORROSIVE LIQUID, N.O.S. (Polyetheramin, ISOPHORONEDIAMINE) 14.3 Transport hazard class(es) ADR

Class 8 (C9) Corrosive substances. Label 8

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(Contd. of page 7)

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· Additional ecological information:· General notes:

Must not reach sewage water or drainage ditch undiluted or unneutralised.Harmful to aquatic organismsWater hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.

· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods· Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.Must be specially treated adhering to official regulations.Must not be disposed together with household garbage. Do not empty into drains.In an appropriate facility or burn in an approved landfillDispose. All applicable local and national or regional rules.

· Waste disposal key:The waste code according to the Waste Catalogue (AVV) depends on the waste producer and can thereforebe different for a product. The waste code is to identify them separately from each waste producer.

· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.· Recommended cleansing agents: Water, if necessary together with cleansing agents.

SECTION 14: Transport information

· 14.1 UN-Number· ADR, IMDG, IATA UN1760

· 14.2 UN proper shipping name· ADR 1760 CORROSIVE LIQUID, N.O.S. (Polyetheramin,

ISOPHORONEDIAMINE)· IMDG, IATA CORROS IVE LI QUID, N.O.S . (Po lye thera min ,

ISOPHORONEDIAMINE)

· 14.3 Transport hazard class(es)

· ADR

daco}· Class 8 (C9) Corrosive substances.· Label 8

· IMDG, IATA

daco}· Class 8 Corrosive substances.· Label 8

(Contd. on page 9)

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IMDG, IATA

Class 8 Corrosive substances. Label 8 14.4 Packing group ADR, IMDG, IATA III 14.5 Environmental hazards: Marine pollutant: No 14.6 Special precautions for user Warning: Corrosive substances. Danger code (Kemler): 80 EMS Number: F-A,S-B 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: ADR Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml Transport category 3 Tunnel restriction code E IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN1760, CORROSIVE LIQUID, N.O.S. (Polyetheramin, ISOPHORONEDIAMINE), 8, III

15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictograms

Signal word Danger Hazard-determining components of labelling: 3-aminomethyl-3,5,5-trimethylcyclohexylamine bisphenol A Polyetheramin m-phenylenebis(methylamine) Hazard statements H302+H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H361f Suspected of damaging fertility. H412 Harmful to aquatic life with long lasting effects Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor.

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(Contd. of page 7)

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· Additional ecological information:· General notes:

Must not reach sewage water or drainage ditch undiluted or unneutralised.Harmful to aquatic organismsWater hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.

· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods· Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.Must be specially treated adhering to official regulations.Must not be disposed together with household garbage. Do not empty into drains.In an appropriate facility or burn in an approved landfillDispose. All applicable local and national or regional rules.

· Waste disposal key:The waste code according to the Waste Catalogue (AVV) depends on the waste producer and can thereforebe different for a product. The waste code is to identify them separately from each waste producer.

· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.· Recommended cleansing agents: Water, if necessary together with cleansing agents.

SECTION 14: Transport information

· 14.1 UN-Number· ADR, IMDG, IATA UN1760

· 14.2 UN proper shipping name· ADR 1760 CORROSIVE LIQUID, N.O.S. (Polyetheramin,

ISOPHORONEDIAMINE)· IMDG, IATA CORROS IVE LI QUID, N.O.S . (Po lye thera min ,

ISOPHORONEDIAMINE)

· 14.3 Transport hazard class(es)

· ADR

daco}· Class 8 (C9) Corrosive substances.· Label 8

· IMDG, IATA

daco}· Class 8 Corrosive substances.· Label 8

(Contd. on page 9)

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(Contd. of page 8)

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· 14.4 Packing group· ADR, IMDG, IATA III

· 14.5 Environmental hazards:· Marine pollutant: No

· 14.6 Special precautions for user Warning: Corrosive substances.· Danger code (Kemler): 80· EMS Number: F-A,S-B

· 14.7 Transport in bulk according to Annex II ofMARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information:

· ADR· Limited quantities (LQ) 5L· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 1000 ml

· Transport category 3 · Tunnel restriction code E

· IMDG· Limited quantities (LQ) 5L· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 1000 ml

· UN "Model Regulation": UN1760, CORROSIVE LIQUID, N.O.S. (Polyetheramin,ISOPHORONEDIAMINE), 8, III

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture· Labelling according to Regulation (EC) No 1272/2008


d~GHS05

d~GHS07

d~GHS08

· Signal word Danger

· Hazard-determining components of labelling:3-aminomethyl-3,5,5-trimethylcyclohexylaminebisphenol APolyetheraminm-phenylenebis(methylamine)

· Hazard statementsH302+H312 Harmful if swallowed or in contact with skin.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.H361f Suspected of damaging fertility.H412 Harmful to aquatic life with long lasting effects.

· Precautionary statementsP260 Do not breathe dust/fume/gas/mist/vapours/spray.

(Contd. on page 10)

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P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed. National regulations: Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water. 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16. Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H335 May cause respiratory irritation. H361f Suspected of damaging fertility. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Acute Tox. 3: Acute toxicity, Hazard Category 3 Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Repr. 2: Reproductive toxicity, Hazard Category 2 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3

safety data sheet section 1: identification of the...

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