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Safety Data Sheet VRLA Rechargeable Battery / Portable Jump Starters Utilizing Same Updated August 24, 2017 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Valve Regulated Lead-Acid Rechargeable Battery, Maintenance Free Battery Company: Clore Automotive Address: 8735 Rosehill Rd., Suite 220, Lenexa, KS 66215 E-mail: [email protected] Phone: 913.310.1050 Emergency: CHEMTEL – 888.255.3924; +1.813.248.0573 Models: JNC300XL/JNC300XLC/JNC4000/JNC660/JNC660C/JNCAIR/JNC770/ JNC950/JNC1224/JNC065/JNC080/JNC100/JNC105/JNC110 Remark: This item (sealed VRLA rechargeable battery) is considered an article as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). The information contained in this SDS is supplied at the customer’s request for information only. Chemical family: This product is a non-spillable, wet lead acid storage battery. May also include gel absorbed electrolyte type lead acid battery types. SECTION 2: HAZARDS IDENTIFICATION GHS Label Elements: Signal Word: Danger

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Page 1: Safety Data Sheet VRLA Rechargeable Battery / Portable ... SDS 20… · Safety Data Sheet VRLA Rechargeable Battery / ... Valve Regulated Lead-Acid Rechargeable Battery, Maintenance

SafetyDataSheetVRLARechargeableBattery/

PortableJumpStartersUtilizingSameUpdatedAugust24,2017

SECTION1:PRODUCTANDCOMPANYIDENTIFICATIONProductName: ValveRegulatedLead-AcidRechargeableBattery,MaintenanceFreeBatteryCompany: CloreAutomotiveAddress: 8735RosehillRd.,Suite220,Lenexa,KS66215E-mail: [email protected]: 913.310.1050Emergency: CHEMTEL–888.255.3924;+1.813.248.0573Models: JNC300XL/JNC300XLC/JNC4000/JNC660/JNC660C/JNCAIR/JNC770/ JNC950/JNC1224/JNC065/JNC080/JNC100/JNC105/JNC110Remark: Thisitem(sealedVRLArechargeablebattery)isconsideredanarticleas definedby29CFR1910.1200(OSHAHazardCommunicationStandard). TheinformationcontainedinthisSDSissuppliedatthecustomer’srequest forinformationonly.Chemicalfamily:Thisproductisanon-spillable,wetleadacidstoragebattery.Mayalsoincludegelabsorbedelectrolytetypeleadacidbatterytypes.SECTION2:HAZARDSIDENTIFICATIONGHSLabelElements:

SignalWord:Danger

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Category GHSCodes DescriptionHealth

STOTRE2AcuteTox.4Repr.1A

SkinCorr.1AFlam.Gas1

AquaticChronic1AquaticAcute1

H302H314H332H360H373H220H410P260P301/330/331P303/361/353

-Harmfulifswallowed.-Causessevereskinburnsandeyedamage.-Harmfulifinhaled.-Maydamagefertilityortheunbornchild.-Maycausedamagetoorgansthroughprolongedorrepeatedexposure.-Extremelyflammablegas(hydrogen).-Verytoxictoaquaticlifewithlonglastingeffects.-Donotbreathedust/fume/gas/mist/vapors/spray.-IFSWALLOWED:rinsemouth.DoNOTinducevomiting.-IFONSKIN(orhair):Remove/Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwater/shower.-IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.ImmediatelycallaPOISONCENTERordoctor/physician.

Handling P210P260P264P280P403P405P391P273P501

-Keepawayfromheat/sparks/openflames/hotsurfaces.Nosmoking.-Donotbreathedust/fume/gas/mist/vapors/spray.-Washthoroughlyafterhandling.-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.-Storeinwell-ventilatedarea-Storelockedup.-Collectspillage.-Avoidreleasetotheenvironment.-Disposeofcontents/containerinaccordancewithlocal/regional/national/internationalregulation.

Note:Thebatteryhaspassedthevibrationtest,pressuredifferentialtestandleakagetestat55°CaccordingtorecommendationsontheTRANSPORTOFDANGEROUSGOODSModelRegulation

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17thSPECIALPROVISION238.ItisnotrestrictedaccordingtoIATADangerousGoodsRegulation(DGR)56thperspecialprovisionA67andisnotrestrictedaccordingtoIMDGCODEperspecialprovision238.

SECTION3:INFORMATIONONINGREDIENTS

Ingredient CASNo. Concentration(%byWt.) HazardousLabelInorganicLead/LeadCompounds

7439-92-1 ~72% T

SulfuricAcid 7664-93-9 ~20% CFiberglassSeparator 65997-17-3 ~2% /

SiliconDioxide(Gelbatteriesonly) 7631-86-9 ~10%ofacidWt. /

ContainerPlastic(ABSorPP)

9003-56-9(ABS) ~5% /9003-07-0(PP) /

Note:Inorganicleadandelectrolyte(waterandsulfuricacidsolution)aretheprimarycomponentsofallCloreAutomotiveportablejumpstarterbatteries.Otheringredientsmaybepresentdependentuponbatterytype.ABSistheprimarycasematerialofourjumpstarterbatteries.SECTION4:FIRST-AIDMEASURESTakeproperprecautionstoensureyourownhealthandsafetybeforeattemptingtorescueavictimandprovidefirstaid.SkinContact:Electrolyte:Flushwithlargeamountsofwaterforatleast15minutes;removecontaminatedclothingcompletely,includingshoes,anddonotwearagainuntilcleaned.Ifacidissplashedonshoes,removeanddiscardiftheycontainleather.Leadcompounds:Washimmediatelywithsoapandwater.Leadcompoundsarenotreadilyabsorbedthroughtheskin.EyeContact:ElectrolyteandLeadcompounds:Flushimmediatelywithlargeamountsofwaterforatleast15minutes;consultphysicianimmediately.InhalationExposure:Electrolyte:Ifsulfuricacidmistorvaporisinhaled,movetoanareawithfreshairandwarmyourselfusingablanket.Seekmedicaladvice/attentionimmediately.Leadcompounds:Removefromexposure,gargle,washnoseandlips;consultphysician.

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OralExposure:Electrolyte:Ifthisliquidisswallowed,washyourmouthwithplentyofwaterimmediately,thendrinkplentyofwater.Obtainmedicaladviceorattention.Donotinducevomitingwhenswallowed.Inaddition,donotperformanyaction,suchasaneutralizationprocess.Leadcompounds:Consultphysicianimmediately.

SECTION5:FIREFIGHTINGMEASURES

FlashPoint:NotApplicableFlammableLimits:LEL=4.1%(hydrogengasinair);UEL=74.1%ExtinguishingMedia:Smallfire–Foamhalogenand/ornon-flammablegasfireextinguisherLargefire:Largequantitiesofsprinkledand/oratomizedwater.(Inthiscase,topreventenvironmentaldamage,flushwatermustbetreatedappropriately.)Particularhazards:Irritant,corrosiveand/ortoxicgasesmayescapefromaburningbattery.Properfirefighting:Ifpossible,disconnectfrompowerfirstifbatteriesareonchargeorremoveignitionsourceandremovebatteriesfromthefiresource.Wherepossible,extinguishthefirefromwellventilatedareaupwindfromfire.Waterusedtoextinguishfiremustbetreatedappropriatelytopreventenvironmentaldamage.Cooldownburntbatteriesusingplentyofwater.FireFightingProcedures:Usepositivepressure,self-containedbreathingapparatus.Bewareofacidsplatterduringwaterapplicationandwearacid-resistantclothing,gloves,faceandeyeprotection.Ifbatteriesareoncharge,shutoffpowertothechargingequipment,but,notethatstringsofseriesconnectedbatteriesmaystillposeriskofelectricshockevenwhenchargingequipmentisshutdown.

SECTION6:ACCIDENTALRELEASEMEASURES

Humanbody:Donottouchthespilledelectrolyteandwalkaroundthespillagesite.Keepoutsidersfromthespillagesite.Environment:Spilledelectrolytemustbetreatedappropriatelytopreventenvironmentaldamage,suchasdirectoutflowingofthespilledelectrolyteintoriver,drain,etc..Neutralization:Neutralizespilledelectrolytewithsodiumbicarbonate,lime,etc.andflushwithlargequantitiesofwater.

SECTION7:HANDLINGANDSTORAGE

Handling:Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.Avoidmechanicalorelectricalabuseandovercharge.Morethanamomentary

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shortcircuitwillgenerallyreducethebatteryservicelife.Avoidreversingbatterypolaritywithinthebatteryassembly.Storage:Storeinacool,well-ventilatedarea.Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.MaterialstoAvoid:Strongoxidant,combustiblematerialsandcorrosives.Charging:Thereisapossibleriskofelectricshockfromchargingequipmentandfromstringsofseriesconnectedbatteries,whetherornottheyarebeingcharged.Shutoffpowertochargerswhenevernotinuseandbeforedetachmentofanycircuitconnections.Batteriesbeingchargedwillgenerateandreleaseflammablehydrogengas.Charginglocationshouldbewellventilated.Keepbatteryventcapsinposition.Prohibitsmokingandavoidcreationofflamesandsparksnearby.Wearfaceandeyeprotectionwhennearbatteries.

SECTION8:EXPOSURECONTROLANDPERSONALPROTECTION NotapplicableforValveRegulatedLeadAcidbattery.

SECTION9:PHYSICAL/CHEMICALPROPERTIESNotapplicableforValveRegulatedLeadAcidbattery.

Reference(component)

Electrolyte(SulfuricAcid) LeadAppearance Clear Silverysolid

SpecificGravity 1.280–1.380(38–48%) 11.3BoilingPoint 112deg.C(38%) 1740deg.CMeltingPoint -40deg.Corbelow 327deg.C

SolidifyingPoint -56.4deg.C(34.6%) -VaporPressure 3.17kPa(30%) 0.1Paorless(25deg.C)

SECTION10:STABILITYANDREACTIVITY

Stability:Stableundernormaltemperaturesandpressures.MaterialstoAvoid:Strongoxidant,corrosives.ConditionstoAvoid:Avoidexposuretoheatandopenflame.Avoidmechanicalorelectricalabuseandovercharge.Preventshortcircuits.Preventmovementwhichcouldleadtoshortcircuits.HazardousPolymerization:Willnotoccur.HazardousDecompositionProducts:Sulfuroxides,Sulfuricacidmist,Metaloxides.

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SECTION11:TOXICOLOGICALINFORMATION

RoutesofEntry:Electrolyte:Harmfulbyallroutesofentry.Undernormalconditionsofuse,sulfuricacidvaporsandmistarenotgenerated.Sulfuricacidvaporsandmistmaybegeneratedwhenproductisoverheated,oxidized,orotherwiseprocessedordamaged.Leadcompounds:Undernormalconditionsofuse,leaddust,vapors,andfumesarenotgenerated.Hazardousexposurecanoccuronlywhenproductisheatedabovethemeltingpoint,oxidizedorotherwiseprocessedordamagedtocreatedust,vapor,orfume.AcuteToxicity:InhalationLD50:Electrolyte:LC50rat:375mg/m3;LC50:guineapig:510mg/m3ElementalLead:AcuteToxicityPointEstimate=4500ppmV(basedonleadbullion)OralLD50:Electrolyte:rat:2140mg/kgElementallead:AcuteToxicityEstimate(ATE)=500mg/kgbodyweight(basedonleadbullion)Correspondtosection3

SECTION12:ECOLOGICALINFORMATION

EnvironmentalFate:Leadisverypersistentinsoilandsediments.Nodataonenvironmentaldegradation.Mobilityofmetallicleadbetweenecologicalcompartmentsisslow.Bioaccumulationofleadoccursinaquaticandterrestrialanimalsandplantsbutlittlebioaccumulationoccursthroughthefoodchain.Moststudiesincludeleadcompoundsandnotelementallead.EnvironmentalToxicity:AquaticToxicity:Sulfuricacid:24-hrLC50,freshwaterfish(Brachydaniorerio):82mg/L96hr-LOEC,freshwaterfish(Cyprinuscarpio):22mg/LLead:48hrLC50(modeledforaquaticinvertebrates):<1mg/L,basedonleadbullion

SECTION13:DISPOSALCONSIDERATIONS

AppropriateMethodofDisposalofSubstance:Lead-acidbatteriesarecompletelyrecyclable.Returnwholescrapbatteriestodistributor,manufacturerorleadsmelterforrecycling.Forneutralizedspills,placeresidueinacid-resistantcontainerswithsorbentmaterial,sandorearthanddisposeofinaccordancewithlocal,stateandfederalregulationsforacidandleadcompounds.Contactlocaland/orstateenvironmentalofficialsregardingdisposalinformation.

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SECTION14:TRANSPORTINFORMATION

WeherebycertifythatalllistedCloreAutomotiveportablejumpstarterbatteriesconformtotheUN2800classificationas“Batteries,Wet,Non-Spillable”asaresultofpassingtheVibrationandPressureDifferentialTestdescribedinD.O.T.,49CFR173.159(f),andIMO/IMDG,andICAO/IATApackinginstruction872andnoteA48,A67,A164andA183.ThebatteriesarenotrestrictedaccordingtoIMO/IMDGcodeperspecialprovision238.CloreAutomotiveportablejumpstarterbatteries,havingmettherelatedconditions,areEXEMPTfromhazardousgoodsregulationsforthepurposeoftransportationbyDOTandIATA/ICAO,andthereforeareunrestrictedfortransportationbyanymeans.Forallmodesoftransportation,eachbatteryouterpackagemustbelabeled"NON-SPILLABLE."ProductsreturnedtoCloreAutomotive,orsubsequentlytransported,thatcontainabatteryorjumpstarter,mustbereturnedintheoriginalpackageorinastrongouterbox,certifiedfortheweightoftheunit,withadequatepackingmaterialtopreventtheunitfrommovementinsidethecarton.Forshipmentsofbatteries,batterypostsmustbeprotectedtopreventanypossibleshortcircuit.Forjumpstarters,thegripsmustbeproperlywrappedaroundtheunitandclampssecuredtopreventashortcircuitintransit.Ifaunitisbeingtransportedwithmetalclamps,gripsmustbeprotectedusingtheoriginallysuppliedgripguards,orthegripswrappedsoastopreventashortcircuit.Inadditionthecartonmustbemarkedwithphrase'Non-spillablebattery'soastocomplywiththerequirementsfortransportingthisasanon-dangerousshipment.

SECTION15:REGULATORYINFORMATION

EURegulation:InaccordancewithEU2006/66/ECBatteryDirective,VRLAbatteriesshouldpresentcrossed-outwheeledbinsymbolofleadtogetherwiththeISOrecyclingsymbol.Doesnotcontainanymercury,Hg,(<0.0005%)orcadmium,Cd,(<0.002%).

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SECTION16:OTHERINFORMATION

ProductssuchasBatteriesarenotinthescopeofregulationwhichrequiresthepublicationofanEUSafetyDataSheet(91/155/EEC).