saoz no x and lightning j. p. pommereau and f. goutail ground-based saoz in bauru since 1995 short...
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SAOZ NOx and LightningJ. P. Pommereau and F. Goutail
Ground-based SAOZ in Bauru since 1995
Short duration small balloon flights
MIR long duration flights
Modelling
Further work
SAOZ Spectrometer at IPMet in Bauru since 1995Network for Detection of Stratospheric Change (NDSC)
complementary station
O3 and NO2 columns at Bauru since 1995
350
300
250
200
Vertical Column (DU)
O3
Morning Evening
95 96 97 98 99 00 01 02 03
8
6
4
2
0
Vertical Column (1E15 mol/cm2)
95 96 97 98 99 00 01 02
NO 2
03
O3
NO2
Parameters Slope of correlation
Amplitude (1e15)
Amplitude (%)
Seasonal cycle 0.956 ± 0.02 1.38 38 ENSO shifted by 4 m. 0.10 ± 0.0 2 0.40 11 QBO 10hPa sh 2 mo -0.0007 ± 1e-4 0.45 12 Magnetic activity Kp 0.001 ± 0.003 0.05 1.3 10.7cm Flux sh 2 m. 5e-5 ± 4e-5 0.09 2.5
Most important parameters Season Small influence ENSO and QBO (10 hPa) No influence of Solar flux and Kp Average Residual <0.001%, max 4%
NO2 evening columns above BAURU
NO2 evening columns above BAURU
95 96 97 98 99 00 01 02 03
5
4
3
2
1
NO2 Evening
-0.8
-0.4
0.0
0.4
0.8
-0.8
-0.4
0.0
0.4
0.8
96 97 98 99 00 01 02 03
Residual NO2 Evening
40
35
30
25
20
15
10
53.02.52.01.51.00.50.0
NO2 (x109 mol/cm3)
Morning Evening
40
35
30
25
20
15
10
53.02.52.01.51.00.50.0
Concentration (x109 mol/cm3)
NO2
MorningEvening
ZL 18 Feb Morning
ZL 23 Feb Evening
2001 2003
MIR-SAOZ 2004
Lightning ?
(larger NO2 in the morning ?)
NOy mid-lat ?Local prod by blue-jets ?
350 300 250 200 150 100 50 0
25
20
15
10
5
0
2000
1500
1000
500
0
60
20
20
20 0
0 0
-20
-20
-30
-30
-50
NO2 DEVIATION (%)
∆Z 360-340 KLIS Flashes
NO2 MIR-SAOZ 2001 20°S
% deviation from zonal mean
Maximum in UT over continental convection
Minimum over Maritime areas
Correlated with O3 STE ?
?
MOZART Modelled lightning and NOx production at the Equator JFM (NOx production over continental convection only)
Continental and Maritime convection of different nature
Lightning Imaging Sensor onboard TRMM (DJF)
350 300 250 200 150 100 50 0
25
20
15
10
5
0
15 0
NO2 MIR-SAOZ 2003 20°S
% deviation from zonal mean
Correlated with O3 STE ?
?
High lightning activity at launch
MIR-SAOZ 2003
MIR-SAOZ 2004
Lightning ?
(larger NO2 in the morning ?)
NOy mid-lat ?Local prod by blue-jets ?
2004
2004
As 2001 and 2003
UT / TTLLow over maritime convection (as 2001)
High over Africa (as 2001)Limited over South America (less than 2001)
? 20 km maxbut at diff loc
12-14 March
MIR over Africa
High Lightning activity
20-23 March
MIR over Amazonia
Low Lightning activity
Summary NO2 Sources (I)
Local production vs transportRemoval of H transport by PV correlation
Production by lightning in UT and TTLMaximum column onn strong lightning daysMaximum up to 200 ppt at 15 km , 100 ppt at 12 km highly correlated to lightning activity over continental convective areas Minimum 10-20 ppt over maritime convective areas
Further workMIR Correlation with LIS flashes during 5 days prior to MIR overpass How much NOx produced by lightning: comparison to model simulations, ajustment of parametrisation. LMDz / TOMCAT modelling in progress over Bauru as well as at MIR location
Summary NO2 Sources (2)
Max NO2 0.2-0.3 ppb at 20-22 km at longitude depending on year
STE ? Local production in LS by blue-jets followed by QBO dependent transport ?
Further work
Characterisation: Source in Reprobus and Mimosa Chem ?
Mechanism: MIPLASMO box trajectory ?