sec 8-1 describing chemical reactions

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  • 8/14/2019 Sec 8-1 Describing Chemical Reactions

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    Describing ChemicalReactions

    8-1

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    What is a chemical reaction

    A chemical reaction is the process bywhich one or more substances arechanged into one or more different

    substances. Original substances = reactants

    Resulting substances =products

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    Chemical Equations

    Are used to represent, with symbols, andformulas, the identities and relativeamounts of reactants and products in a

    chemical reaction.

    (NH4)2Cr2O7(s) N2(g) + Cr2O3(s) + 4H2O(g)

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    Indications of a chemical reaction

    Evolution of heat and light

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    Indications of a chemical reaction

    Production of a gas

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    Indications of a chemical reaction

    Formation of a precipitate (ppt)

    A solid that is produced as a result of achemical reaction in solution and that

    separates from the solution

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    Characteristics of Chemical Equations

    The equation must represent known facts

    All reactant and products must be identified

    The equation must contain the correct

    formulas for the reactants and products Diatomic Elements - When using H,N,O or any

    halogens they are represented by theirmolecular formulas

    H2, N2, O2,F2, Cl2, Br2, I2 2H2(g) + O2(g) 2H2O(l)

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    Characteristics of Chemical Equations

    The law of conservation of mass must besatisfied

    The same number of atoms of each element

    must appear on each side of the equation Coefficients are used, by placing them in front

    of a formula specifies the relative number ofmoles of a substance

    H2 + O2

    H2O 2H2(g) + O2(g) 2H2O(l)

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    Word Equations

    Is an equation in which the reactants andproducts in a chemical reaction arerepresented by words

    Have on qualitative (descriptive) meaning Do not give us quantities

    methane + oxygen carbon dioxide + water

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    Formula Equation

    Represents the reactants and products ofa chemical reaction by using their symbolsor formulas

    CH4(g) + O2(g) CO2(g) + H2O(g)

    CH4(g) + O2(g) CO2(g) + 2H2O(g)

    CH4(g) +2O2(g) CO2(g) + 2H2O(g)

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    Additional Symbols used in chemical

    equations

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    Practice

    Solid sodium oxide is added to water atroom tempertature and forms sodiumhydroxide (dissolved in water).

    Sodium oxide + water sodium hydroxide

    Na2O(s) + H2O(l) NaOH(aq)Na2O(s) + H2O(l) 2NaOH(aq)

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    Practice

    Hydrogen peroxide in an aqueous solutiondecomposes to produce oxygen andwater.

    Hydrogen peroxide oxygen + water

    H2O2(aq) O2(g) + H2O(l)

    2H2O2(aq) O2(g) + 2H2O(l)

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    Practice

    Solid zinc metal reacts with aqueouscopper sulfate to produce solid coppermetal and aqueous zinc sulfate.

    Zinc + copper sulfate copper + zinc sulfate

    Zn(s) + CuSO4(aq) Cu(s) + ZnSO4(aq)

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    Significance of a Chemical Reaction

    The coefficients of a chemical reactionindicate relative, not absolute amounts ofreactants and products.

    H2 + Cl2 2HCl

    1moleH2 : 1mole Cl2: 2moles HCl.5 mol : .5 mol : 1 mol

    10 mol : 10 mol : 20 mol

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    Significance of a Chemical Reaction

    The relative masses of the reactants andproducts of a chemical reaction can bedetermined from the reactions

    coefficients.H2 + Cl2 2HCl

    1mol H2 x 2.02g/mol = 2.02 g H2

    1mol Cl2x 70.90g/mol = 70.90g Cl22mol HCl x 36.46g/mol = 72.92 g HCl

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    Significance of a Chemical Reaction

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    Significance of a Chemical Reaction

    The reverse reaction for a chemicalequation has the same relative amounts ofsubstances as the forward reaction

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    Balancing Chemical Equations

    First and foremost make sure you have thecorrect formula equation.

    Steps

    Balance the different types of atoms one at a

    time First balance the atoms of elements that are

    combined and that appear only once on eachside of the equation

    Balance polyatomic ions that appear on bothsides of the equation as single units

    Balance H and O atoms after atoms of all otherelements have been balanced

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    Practice

    Zinc + hydrochloric acid

    zinc chloride + hydrogen

    Zn + HCl ZnCl2 + H2

    Zn + 2HCl ZnCl2 + H2(1Zn)+(2H+2Cl) (1Zn+2Cl)+(2H)

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    Practice

    Al4C3 + H2O CH4 + Al(OH)3

    Al4C3 + 12H2O

    3CH4 + 4Al(OH)3

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    Practice

    Aluminum Sulfate and Calcium hydroxideare combined they react to producealuminum hydroxide and calcium sulfate.

    Al2(SO4)3 + Ca(OH)2 Al(OH)3 + CaSO4

    Al2(SO4)3 + 3Ca(OH)22Al(OH)3 + 3CaSO4

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    Homework

    Pg 290

    #s 10, 13-16