separation of ionic solutes - gbv · program of sections and plenary lectures of sis'97...

897*

UB/TIB Hannover _ _ ^ ^ ^ ^studies in nuclear cnemistry and radioecology 1

SEPARATIONOF IONIC SOLUTES

Vol. VII

Abstracts of the7th INTERNATIONAL CONFERENCE SIS'97

Piest'any Spa, SlovakiaMay 18 - 23,1997

Edited byF. MACASEK AND J. KURUC

Omega Info UB/TIB Hannover 89115 889 99X

Program of Sections and Plenary Lectures of S1S'97

Sunday, May 18 (17.30-19.00)

17.30 Opening Session

Lectures & Oral Communications

Monday, May 19 (9.00-12.00)A. Inductory Session |

[A-l] p.5-7A.R.Ware, K.J. Odell:Analysis of Radioactive Metal Ions in Environmental and Liquid EffluentSamples.

[A-2] p.9-11H.P.van Leeuwen:Metal Speciation. Dynamics.

[A-3] p.12-13V.I.Volk, A.Yu.Vakhrushin, V.S.Vlasov, V.N.Rubisov:Mobile Liquid Membrane in the Process of Extraction and Separation ofSubstances.

[A-4] p. 14G.Werner:Separation of Ionic Surfactants by Capillary Electrophoresis and HPLC.

[A-5] p. 15-16S.V.Chizhevskaya, A.V.Ochkin, N.E.Chernyavkaya, S.V.Stefanovsky:Incorporation of High-Level Waste in Some Mineral Matrices.

[A-6] pi 7-20C.W.Francis, M.E.Timpson, S.Y.Lee, M.P.Elless, J.H.Wilson:The use of Carbonate Lixiviants to Remove Uranium from Uranium-Contaminated Soils.

ROUND TABLE:Can Soil be Efficiently Remediated by Chemical Extraction ofRadioactive and Heavy Metal Ions? (Dr.C.W.Francis)

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Program of Sections and Plenary Lectures of SIS'97

Tuesday, May 20 (9.00-12.00)B. Solvent Extraction, Liquid Membranes, and Micellar Separations

[B-l] p.23-24Z.Kolarik:Recent Development of Macrocyclic and Soft-Donor Extractants and theirRadiochemical Applications.

[B-2] p.25-28V.I.Golovanov:Colloidal Metal Containing Neutral Extraction Agents. The NovelMechanism of Extraction and Solubilisation of Ionic Substances by Non-Polar Solvents.

[B-3] p.29S.A.E1 Reefy, Y.T.Selim, H.F.Aly:Recovery of Uranium from Thorium from Hydrochloric Acid Medium byLiquid Emulsion Membrane Containing Trioctylphosphine Oxide.

[B-4] ^ p.30-32G.Cara, S.Schlosser, M.Munoz, M.Valiente:Pertraction ofNeodymium in a Hollow-Fibre Contactor.

[B-5] p.33M.M.Naim:Desalination by Liquid Membranes.

Tuesday, May 20 (14.00-16.00)BB. Oral Communications

[BB-1] p.35S.Kusakabe:Hydration and Solvation of Metal Perchlorates Extracted withTrioctylphosphine Oxide in Hexane.

[BB-2] p.36-37O.A.Sinegribova, A.V.Ochkin, E.Baquero:Modelling of Extraction of Mineral Acids in Tributylphosphate.

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[BB-3] p.38-39H.Boerrigter, A.C.Veltkamp, W.Verboom, D.N.Reinhoudt:Solvent Extraction with Supported Liquid Membranes (SLM's) Using NewResorcinarene Cavitand CMPO Ligands.

[BB-4] p.40S.N.Kalmykov, A.A.Arhipov, A.A.Abramov, N.A.Ivanova, B.Z.Iofa,O.P.Pronina, Yu.A.Sapozhnikov, A.V.Anisimov, J.A.Broadway:Extraction ofSr, Ag(I) and Pb(II) Some Oxa-Tia- and Tia-Crown Ethers.

[BB-5] p.41H.H.Someda, A.A.El-Zahhar, M.K.Shehata, H.A.El-Naggar:Extraction Studies of Uranyl Ion (UO22+) by Dihexyl-N,N-diethylcarbamoylMethyl Phosphonate (DHDECMP).

[BB-6] p.42J.Hala:Extraction of Europium from Aqueous-Organic Solutions.

[BB-7] p.43M.Yamada, T.Sekine:Rapid Solvent Extraction of Chromium(III) as Intermediate Complexes withAcetylacetone.

[BB-8] p.44-47G.Uchiyama, T.Asakura, M.Watanabe, S.Fujine, M.Maeda:Neptunium and Technetium Recovery in Purex Process.

[BB-9] p.48O.Koreh, K.Torkos, B.M. Mahara, J.Borossay:Extraction and Determination ofFuranic Compounds in Insulating Oil.

Monday, May 19 (16.00-18.00)BP. Posters

[BP-1] p.49F.N.Abudeab, R.Kopunec:Electrical Conductivity of Tetraphenylarsonium, Tetraphenylphosphonium,Triphenyltin and Trioctyltin Chloride and Pertechnetate in NonaqueousSolutions

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[BP-2] p.50R.Kopunec, F.N.Abudeab:Extraction of Pertechnetate by Triphenyltin Chloride and TrioctyltinChloride.

[BP-3] p.51E.Baquero, A.V.Ochkin, O.A.Sinegribova:Description of the Solvent Extraction of Hydrobromic Acid by Tributyl-n-phosphate.

[BP-4] p.52-53P.Bartos, F.Macasek, P. Gerhart:Partition of Lead in Milk-Pectin Aqueous Piphasic System with ComplexationAgents.

[BP-5] p.54M.B.Bogacki, J.Szymanowski:Computational Studies (PM3) of Dipentylpyridine-2,5-dicarboxylateHydration.

[BP-6] p.55M.B.Bogacki, M.Wisniewski, J.Szymanowski:Effect of Extractant on ArsenicfV) Recovery from Sulfuric Acid Solutions.

[BP-7] p.56C.Bouvier, G.Cote, A.Sobczyhska, M.B.Bogacki, J.Szymanowski:Interfacial Behaviour of ACORGA CLX-50 and Surface Kinetics of CopperExtraction.

[BP-8] p.57R.Cierpiszewski, D.Rusinska-Roszak, J.Szymanowski, W.Mickler,E.Uhlemann:Rate of Copper Extraction and Structure of Model fi-Dike tones and 4-Acyl-5-pyrazolones.

[BP-9] p.58-59C.Costache, Sz.Lanyi, R.Stanescu, A.Drost, I.Constantinescu:Theoretical and Experimental Correlations in Equilibrium of Phosphoricacid Extraction with n-Butylic Alcohols.

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[BP-10] p.60-61V.I.Golovanov, S.M.Kuznetsov:The Simulation of Extraction Equilibriums and the Association (Micellation)of Multivalent Metal Dialkylphosphates Based on pH titration data.

[BP-11] p.62-63N.F.Kizim, Yu.P.Davidov, A.P.Larkov:Dynamic Separation of Some d- andf-Elements by Liquid Extraction.

[BP-12] p.64-65M.Kopacz, S.Kopacz, D.Nowak:Extractive and Spectrophotometric Determination ofPr(III), Eu(III), Gd(III),Dy(III), and Er (III) Ions with Quercetin-5'sulfonic Aacid (QSA).

[BP-13] p.66S.Kopacz, B.Papciak, J.Kalemkiewicz, Ya.I.Korenman:Influence of Electrolyte on 2-Chlorobenzoic Acid Partition in Toluene - WaterTwo-Phase Systems.

[BP-14] p.67-68Ya.I.Korenman, T.N.Yermolaeva, A.V.Mishina, S.Kopacz, J.Kalemkiewicz:Extraction of Nitrogen-Containing Phenols by Hydrophilic Solvents as theStage of Sample Preparation for Electrochemical Analysis of Nature Objects.

[BP-15] p.69-70Ya.I.Korenman, R.P.Lisitskaya, V.V.Alyoshina:Separate Determination of Phenol and Aniline in Aqueous Media by theMethods of Extraction and High Efficient Liquid Chromatography.

[BP-16] p.71-72Ya.I.Korenman, N.A.Novikova, S.I.Niftaliev, S.Kopacz, J.Kalembkiewicz:Separate Determination of Aminobenzoic Acids by the Method ofConductometric Titration of Non-Aqueous Extract.

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Tuesday, May 20 (16.00-18.00)I BP. Posters

[BP-17] p.73-74Ya.I.Korenman, A.T.Alymova:Effect of the Surface of Solid Cellular Carrier on the Selectivity of OrganicSolvents-Extragent

[BP-18] p.75-76Ya.I.Korenman, T.N.Yermolayeva, E.A.Podolina:Selective Potentiometric Determination of Phenol and Alkylphenol in Non-Aqueous Extracts.

[BP-19] p.77-78Ya.I.Korenman:homeric Effects While Extracting Aromatic Bases.

[BP-20] p.79-80M.Litvina:Extraction of Am(III) from Nitric Acid Solutions by Nitrogen SubstitutedCarbamoylmetylphosphine oxides.

[BP-21] p.81-82E.Matel, O.Rosskopfova, K.Vlnkova, P.Rajec, D.Keltos:Separation of239'240Pu, and24'Am from water of long term waste pond NPPA-I Jaslovske Bohunice using TRU Resin SPS and comparison withconventional extraction Method.

[BP-22] P-83I.Miesac, J.Szymanowski:Extraction of Penicillin G in Hollow Fiber Membranes.

[BP-23] P-84G.Modolo, R.Odoj:Selective Extraction of Trivalent Aclinides from Lanthanids withDithiophophinic Acid.

[BP-24] P-85M.M.Naim, A.A.Mounir:Application of the Emulsion Liquid Membrane Technique to the Extractionand Concentration of alkalis from Aqueous Solutions. 2. Extraction ofAmmonia by Type 1 Facilitated Transport.

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Program of Sections and Plenary Lectures of SISr97

[BP-25] p.86P.Nekovaf, D.Schrotterova:Liquid-Liquid Extraction ofMo(VI) and V(V) by Primene JMT.

[BP-26] p.87A.M.Rozen, V.I.VoIk, A.Yu.Vakhrushin, Z.I.Nikolotova, N.A.Kartasheva:Extraction of Actinides from Heavy Water Solutions.

[BP-27] v p.88V.Scasnar:Ion-Pair Extraction of [3H]Stobadine from Biological Fluids.

[BP-28] p.89P.Vanura:The Extraction Behaviour of Some Dicarbollylcobaltate Crown ExtractionSystems.

[BP-29] p.90V.I.VoIk, A.Yu.Vakhrushin, V.G.Balakhonov:Use of Micelle Extraction for Extractant Reprocessing.

[BP-30] p.91M.WiSniewski:Removal of Arsenic from Sulphuric Acid Solutions.

[BP-31] p.92M.Wisniewski, A.Jakubiak, J.Szymanowski:Interfacial Phenomena in Solvent Extraxtion of Metals. Extraction ofPalladium(II).

Tuesday, May 20 (9.00-11.00)C. Ion Exchange, Chromatography, Electrophoretic and

Electrochemical Separations

[C-l] p.95-96J.Labuda, M.Buckova, E.Korgova, M.Vanickova:Speciation of Metals Using Chemically Modified Electrodes.

[C-2] p.97A.Harms, J.T. van Elteren:Chromatographic Separation ofTechnetium Species.

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[C-3] p.98-101B.K.Sharma, P.Rajamani, P.K.Mathur:Ion Exchange Chromatographic Separation and MS Analysis of Isotopes ofBoron.

[C-4] p. 102P.Rajec, F.Macasek, P.Misaelides:Comparative Ion Metal Sorption by Zeolites and Bentonites.

[C-5] p. 103-104Z.Szeglowski, L.I.Guseva, T.L.Dinh, V.P.Domanov, B.Kubica,G.S.Tikhomirova, O.Constantinescu, M. Constantinescu, A.B.Yakushev:On Line Ion Exchange Isolation of Short Lived Zr, Hf Mo, Ta and W Isotopesas Homologs ofTransactinide Elements.

[C-6] p. 105-107Hisham F. Aly, I.M. El-Naggar:Tetravalent Metal Antimonates Synthesis, Characteristics and Use inTreatment of Radioactive Waste Solutions.

Wednesday, May 21 (16.00-18.00)| CP. Posters

[CP-1] p. 108B.Bartos, A.Bilewicz, R.Delmas, C.Loos-Neskovic:Synthesis and Ion Exchange Properties of Various Forms of ManganeseDioxide for Cations of I and II Groups.

[CP-2] p. 109-110P.Gerhart, P.Rajec, F.Macasek:Speciation of Fission Products in Raw Cow Milk by High-Performance SizeExclusion Radiochromatography.

[CP-3] p. 111-112P.Gerhart, P.Rajec, I.S.Shaban, P.Bartos:Speciation of 137-Cs in the Humic Acids by HP-SEC Combined withRadiodetector.

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[CP-4] p.113L.Guseva:Elaboration of Ion Exchange Chromatography Methods for Isolation,Separation and Purification of Actinide and Transactinide Elements.

[CP-5] p. 114M.Hutta, R.Halko, S.Megova:Separation of Cationic Mercury and Organomercurials by Micellar High-Performance High-Performance Liquid Chromatography.

[CP-6] p.115-116D.Kaniansky, J.Marak, M.Masar, J.Lastinec, J.V.Reijenga, F.I.Onuska:On-line ITP-CZE: Preconcentration and Clean-up Aspects.

[CP-7] p-117M.Kohlickova, V.Jedinakova-Kfizova:Effect ofpH and Eh on Sorption of Selected Radionuclides.

[CP-8] p.118-119J.Kuruc, P.Moravec, R.Cech, P.Rajec:Determination of Radiation Yields of Mono-n-butylphosphate at Radiolysis ofWater-Di-n-butylphosphate Two-Phase Systems by CapillaryIsotachophoresis.

[CP-9] p. 120-121J. Kuruc, A.Petru, R.M.Batista, R. Cech, P. Rajec:The Mechanism of Formation of Ionogenic Products of Decomposition ofTri-n-butylphosphate and Di-n-butylphosphate at the Radiolysis of Water-Tri-n-butylphosphate and Water-Di-n-butylphosphate Two-Phase Systems

[CP-10] p. 122M.Lochny, R.Odoj:Separation ofActinides by Means ofHPLC.

[CP-11] P-123S.Milonjic, S.D.Cupic:Adsorption of Ferric and Ferro Ions on Silica Gel.

[CP-12] p. 124Ch.Neskovic, R.Delmas, M.Hussonnois, A.Bilewicz, B.Bartos:A Chemical Studies of the 24Ne cluster decay of2i2Th.

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[CP-13] p.125-126A.Paulenova, P.Rajec, P.AdamCik:Preconcentration of Strontium in the Anionic Micellar System.

[CP-14] p.127-128A.Paulenova, P.Rajec, M.Jezikova:Micellar Enhanced Preconcentration of Cadmium.

[CP-15] p.129-130A.Paulenova, P.Rajec, G.Saskoiova:The Study of the Binding of Strontium by Humic Acid.

[CP-16] p.131T.Prochackova, R.Gora, J.Kandrac. M.Hutta:Distribution of Mercury in Soil Organic Matter Fractions Obtained byDissolution / Precipitation Method.

[CP-17] p.132-133P.Rajec, J.Orechovska:Sorption of Cesium on Nickel Hexacyanoferrate Incorporated in Silica-gelMatrix.

[CP-18] p. 134P.Rajec, V.Svec, V.Mikulaj, R.Hanzel:Coprecipitation of Crown-Ethers Complexes of Lead and Strontium withTungstosilicic Acid.

[CP-19] p. 135J.Satyanarayana, A.Bilewicz, G.S.Murthy:Adsorption of Mono, Di and Trivalent Metal Cations on VariousAntimonates.

Wednesday, May 21 (14.00-16.00)D. Fractionation of Radionuclides and Metals in Environmental

Systems (Transfer and Speciation)

[D-l] p.139I.M.Matveenko, O.M.Zhukova, M.G.Germenchuk:State and Projection of Radiation Situation on the Territory of Belarus Afterthe Chernobyl Catastrophe.

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[D-2] p. 140-143C.Testa:The Importance of the Separation Chemistry for the Determination ofRadionuclides in Environmental Samples.

[D-3] p. 144-147B.F.Myasoedov, A.P.Novikov:Main Sources of Radioactive Contamination in Russia and Methods for TheirDetermination and Speciation.

[D-4] p.148-150N.G.Isayeva:Choice of Protective Barriers for Radioactive Wastes Localization.

Thursday, May 22 (14.00-16.00)DP. Oral Communications

[DD-1] p.151V.Jedinakova-Kfizova:Migration of Radionuclides in the Environment.

[DD-2] p. 152O.M.Zhukova, E.D.Shagalova, M.G.Germenchuk, T.S.Zenich,I.l.Matveenko:Analysis of the Results of Many Years Observations of RadionuclidesMigration on the Network of Representative Landscape-Geochemical Areason the Terrirory of the Republic of Belarus.

[DD-3] p.153M.T.Valentini Ganzerli, V.Crespi Caramella, L.Maggi, P.A.Borroni:Use of Inorganic Adsorbers in Radium analysis.

[DD-4] p. 154S.N.Kalmykov, Yu.A.Sapozhnikov, I.P.Efimov, J.A.Broadway,L.D.Sapozhnikova:Extraction of Radionuclides from Natural Waters Using Alginates.

[DD-5] p. 155-157F.Macasek, P.Rajec, E.Matel:Speciation of cesium and treatment of the radiocesium contaminated soils.

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Thursday, May 22(16.00-18.00)DP. Posters

[DP-1] p.158M.G.Germenchuk, O.M.Zhukova, E.D.Shagalova, I.I.Matveenko:Radioecological Mapping of the Territory of Belarus on the Base Informationof Radiation Monitoring.

[DP-2] p. 159P.Jurcek, V.Jedinakova-Kfizova:Sorption and Diffusion Processes with Cs-137 and Sr-85.

[DP-3] p.160-161J.Kalembkiewicz, L.Filar:Investigation of Partition of ChromiumfVI) in the Two-Phase Systems Soil-Soil Extract and Its Analysis by FAAS Method.

[DP-4] p. 162-163V.Koprda, M.Harangozo, L.Bohacik:Permeation ofCs Ions Through a Skin Barrier.

[DP-5] ^ p. 164M.Zemberyova, A.Al-Hakem Zwaik, I.Farkasovska:Squential Procedure for Speciation of Some Heavy Metals in Soils.

Thursday, May 22 (9.00-12.00)E. Cleanup Technologies (Water, Soil, Equipment) ]

[E-l] p. 167-170J.D.Navratil, T.A.Todd, J.A. Van Vliet:Overview of Chemical Separation Activities in Environmental Management atthe Idaho National Engineering and Environmental Laboratory.

[E-2] p.171-172F.Sebesta, J.John, A.Motl:Apllication of PAN-Based Composite Absorbers for Treatment of SalineRadioactive Wastes.

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[E-3] p. 173-176J.Szymanowski:Extractants for Arsenic Recovery from Technological Sulphuric AcidSolutions.

[E-4] p. 177-178A.Meghea, H.H.Rehner, I.Peleanu, R.Mihalache:Test-fitting on Adsorption Isotherms of Organic Pollutants from Wastewaterson Activated Carbon.

[E-5] p. 179-180D.I.Skorovadov, L.I.Rousine, A.V.Lomonosov, G.K.Celishchev:Cleaning of Phosphoric Acid by Liquid Extraction in Fertilizers Production(in Russian).

[E-6] p.181-184J.Vachtova, J.Prochazka, A.Heyberger, M.Mrnka:Processing of Spent Ni-Wo Catalysts from Petrochemistry.

Thursday, May 22(14.00-16.00)EP. Posters

[EP-l] p. 185F.Aurelian, G.Jinescu:The Influence of the Poisoning Ions on the Uranium Residualy WatersTreatment.

[EP-2] p. 186-187M.F61desov£, P.Lukac, P.Dillinger, E.Klosova, Z.Malek, E.Vecernikova,V.Balek:Characterisation of Morphological and Structural Changes of ChemiclyModified Clinoptilolite.

[EP-3] p. 188-189O.Gyliene, M.Salkauskas:Metal Ions Precipitation by Organic Acids as a Mean for Metal Recovery andDecontamination of Solution.

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[EP-4] p. 190D.Kauspediene, J.Snukigkis, A.Gefeniene:Simultaneous Purification of Sewage from Cd(II) and Nonionic Surfactantwith Cation Exchanger.

[EP-5] p.191-192A.Mihalache, I.Peleanu, I. Meghea, A.Tudorache:Competitive Adsorption Models of Organic Pollutants from Bi- and Tri-Solute Systems on Activated Carbon.

[EP-6] p. 193-194L.Stoica, D.Filip, G.Filip, A.Razvan, F.Bunus:Removal of^^Ra(II)from Uranium Mining and Processing Liquid Effluents.

[EP-6] p. 195L.Stoica, D.Filip, G.Filip, A.Razvan, F.Bunus:Recovery of Y(III) from Uranium Mining and Processing Liquid Byproducts.

[EP-7] p. 196-197I.S.Shaban, F.Maca§ek:Influence of Humic Substances on Sorption of Cesium and Strontium onMontmorillonite.

[EP-8] p. 198-199F.Macasek, I.S.Shaban:Cesium Speciation in Solid Matrix and its Specific Ion Adsorption by Soils.

Friday, May 23, (9.00-12.00)ROUND TABLES:1. Issues for Optimization of Analytical and Preparative Separation

Techniques (Prof.Ya.I.Korenman).2. Trends in the Recent Hybrid "Instrumental" Analytical Techniques

for Non-Volatile Compounds (Prof.E.Plsko).

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separation of ionic solutes - gbv · program of sections and plenary lectures of sis'97...

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