soil vapor extraction (sve) pilot study test results · soil vapor extraction pilot study test...

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T E C H N I C A L M E M O R A N D U M CH2MHILL

Soil Vapor Extraction Pilot Study Test ResultsPREPARED FOR:

PREPARED BY:

COPIES:

DATE:

DCN:

Kathleen Aisling/EPA

CH2M HILL Fruit Avenue RD Project Team

Tom Palaia/CH2M HILL/DENLinda Colella/CH2M HILL/DENBill Lefevre/CH2M HILL/ABQPeter van Noort/CH2M HILL/DFWAmy Halloran/CH2M HILL/ABQ

June 25,2002

02-4226

This technical memorandum (TM) presents the results of the soil vapor extraction (SVE)pilot test that was performed at the Fruit Avenue Plume (FAP) Superfund Site on May 9-11,2002.

Goals and ObjectivesThe primary goal of the SVE pilot study was to obtain sufficient information to permitdesign of a full-scale SVE system that can be used, if necessary, to remediate volatile organiccompound (VOC) contamination present in the vadose zone at the FAP site. In support ofthis goal, the following specific objectives were established for the SVE pilot test:

1. Monitor VOC concentrations in existing monitoring well headspace and in the SVEsystem offgas, and collect SVE system offgas samples to be analyzed in the laboratory toestimate the mass removal rate of an SVE well.

2. Obtain vacuum and airflow rate data at a pilot test well, and gather vacuum, oxygen,and VOC data at several existing surrounding monitoring points to determine site-specific air permeability information, which can be used to determine the radius ofinfluence for full-scale SVE wells.

3. Obtain design data needed to size the SVE blower and efficiently design and configureSVE wells for the full-scale system.

4. Measure SVE system offgas VOC concentrations for full-scale design air permittingpurposes.

Each of these objectives was accomplished and is discussed below.

SVE Pilot Test ProceduresTwo SVE pilot tests were conducted at two existing monitoring wells using a 15-horsepowerregenerative blower (Rotron Model EN12). During the tests, the inlet to the blower wasconnected to the well being tested (either DM-1 or SFMW-2) at ground surface to pull soil

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SOIL VAPOR EXTRACTION PILOT STUDY TEST RESULTS

gas from the screen interval that was exposed in the vadose zone. The soil gas that wasrecovered was processed through the blower and treated from the blower discharge usingtwo vapor-phase granular activated carbon (GAC) drums in series. An airflow meter andpressure gauge were fitted to the SVE blower inlet. A general schematic of the pilot SVEsystem is presented in Figure 1. A site plan is presented as Figure 2; this site plan shows thelocations of the monitoring wells that were used for the tests.

Monitoring Well DataThe day before pilot testing began, baseline monitoring was performed on existingmonitoring well SFMW-2 to obtain information on the natural diurnal fluctuation of soil gaspressure over time. The soil gas pressure in the headspace of the monitoring well wasmeasured by attaching an airtight fitting with a Magnehelic pressure gauge to the top of thewell casing. From approximately 9:00 a.m. to 8:00 p.m., the pressure in the subsurface atmonitoring well SFMW-2 ranged from 0 to +0.09 inches of water. In addition, the naturaldiurnal fluctuation of soil gas pressure was monitored during the SVE pilot tests at a remotewell, SFMW-15. The soil gas pressure was observed to range between -0.03 to +0.08 inchesof water. By conducting baseline monitoring, a range of naturally occurring subsurfacepressure fluctuation was established, thereby ensuring that the effects of the SVE blowercould be isolated and appropriately and accurately assessed.

The purpose of the first test was to obtain design data including contaminant informationfrom DM-1. This test was conducted using existing monitoring well DM-1 as the SVE testwell and existing monitoring wells DM-4, DM-5, SFMW-1, SFMW-2, and SFMW-5 asperimeter vapor monitoring points. The length of screen exposed in the vadose zone in DM-1 was 4.6 feet and ranged from 6.1 to 9.4 feet in the perimeter monitoring wells. This testwas conducted for 24 hours. The test began with baseline monitoring of pressure/vacuum,VOCs, and oxygen at each monitoring well in the test area (time zero measurements). Thepressure/vacuum was measured by attaching an airtight fitting with a Magnehelic pressuregauge to the top of the well casing. The VOC and oxygen content were measured bypumping air through the same airtight fitting. Three well casing volumes of air were purgedand then a Tedlar bag sample was collected. The VOC concentration in parts per million byvolume (ppmv) in the Tedlar bag was measured using a flame ionization detector (FID) andphotoionization detector (PID). The oxygen content was measured using a GasTech GTmeter. The SVE blower was then started at an airflow extraction rate of approximately 86standard cubic feet per minute (scfm) and a vacuum of 67 inches of water. However, after ashort period of time, water was observed to be surging into the SVE blower influent line,indicating that the permeability of the soils across the portion of the well screen above thewater table is low. Consequently, the influent air dilution valve was then slightly opened toreduce the vacuum and alleviate the water extraction. The airflow rate was adjusted toapproximately 55 scfm and the vacuum to 50 inches of water for the remainder of the test.

The original purpose of the second test was to extract soil gas from existing monitoring wellDM-5. However, upon startup of the SVE blower, no airflow could be obtained at themaximum operating capacity of the blower (90 inches of water). As a result, existingmonitoring well SFMW-2 was used for the second SVE test well. Existing monitoring wellsDM-1, DM-4, DM-5, SFMW-1, and SFMW-5 were used as vapor monitoring points. Thelength of screen exposed in the vadose zone in SFMW-2 was 7.3 feet and ranged from 4.6 to9.4 feet in the perimeter monitoring wells. This test was performed for approximately 14.5

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hours, the amount of time needed for parameter stabilization. The test began with baselinemonitoring of pressure/vacuum, VOCs, and oxygen at each monitoring well in the test area(time zero measurements). The measurements were taken using the same methodsdescribed above for the DM-1 SVE test. The SVE blower was then started at an airflowextraction rate of approximately 33 scfm and a vacuum of 60 inches of water. As wasobserved during the test at DM-1, water began to surge into the SVE blower influent line.The influent air dilution valve was then slightly opened to reduce the vacuum and alleviatethe water extraction. The airflow rate was adjusted to approximately 30 scfm and thevacuum to 50 inches of water for the remainder of the test.

The conditions of the SVE blower, the SVE blower offgas, and the effects of the SVE bloweron the subsurface were monitored during the tests. A copy of the field notes is included inAttachment A.

The airflow rate and vacuum of the SVE blower influent were recorded at intervals ofapproximately 0,1,2,4,8,16, and 24 hours. SVE blower offgas samples were collected inTedlar bags for laboratory analysis of VOCs using an FID and FID at intervals ofapproximately 0,1,2,4,8,16, and 24 hours. In addition, SVE blower offgas samples werecollected in Tedlar bags for laboratory analysis of VOCs and petroleum hydrocarbons in theG> to CM range at intervals of approximately 1,4, and 24 hours.

Perimeter Monitoring Well DataPerimeter monitoring well data were collected at intervals of approximately 0,1,2,4,8,16,and 24 hours. It should be noted that the last sampling event for SFMW-2 test was atapproximately 14 hours due to the shortened duration. Magnehelic gauges were firstconnected directly to the wellhead to measure the vacuum response at each perimetermonitoring well. Next, an air-sampling pump was used to purge the stagnant vapor fromthe perimeter monitoring wells and collect a representative gas sample in a Tedlar bag. Thegas samples were analyzed for VOCs using a FID and for oxygen using a portable oxygensensor. A PID was also used to analyze the samples for VOCs to confirm the readingsmeasured with the FID and obtain alternate readings on those samples that had low oxygenlevels. The PID proved a more reliable instrument due to the frequency of FID flame-out asa result of depleted oxygen in the soil gas samples.

SVE Pilot Test ResultsTable 1 summarizes the operating parameters measured during the SVE pilot testsperformed at DM-1 and SFMW-2. Detailed summary tables of the data are included asAttachment B.

As indicated in Table 1, the SVE pilot tests at DM-1 and SFMW-2 produced similar resultswith respect to blower vacuum requirements, time to reach steady-state, and estimatedradius of influence. However, despite a shorter length of screen exposed in the vadosezone, higher airflow rates and concentrations of VOCs were produced during the test atDM-1 which indicate the presence of higher permeability soil conditions in the area aroundthis well.

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TABLE 1

Summary of SVE Pilot Test ResultsFruit Avenue Plume Superfund Site, Albuquerque, NM

Parameter

Name of Vent Well

Exposed Screen Length in Vent Well (feet)

Duration of the Test (hours:minutes)

Extraction Airflow Rate (scfm) 1

Vent Well Vacuum (inches of water) '

Time for Steady-State (hours) 2

Final Offgas VOC Concentration (ppmv) 3

Estimated VOC Removal Rate (Ibs/day) 4

Estimated Radius of Influence (feet) 5

DM-1 SVE Test

DM-1

4.6

24:00

54-86 [55]

50-67 [52]

Approx. 0.5

115-314 [115]

1.4

100+

SFMW-2 SVE Test

SFMW-2

7.3

14:24

30-33 [33]

50-60 [50]

Approx. 0.5

6.7-28 [28]

0.3

100+

NOTES:

1 Number in brackets represents the quasi-steady-state, final conditions after some adjustment to minimize theextraction of water.

2 As indicated by the stabilization of vacuum in the perimeter monitoring wells.3 As measured by a flame ionization detector (FID). Number in brackets represents the value at the end of the

test.

4 Mass Removal Rates are estimated based on a total of detected VOCs and TPH (C9-C11) in the samplecollected at the end of the test.

5 As indicated by vacuum and oxygen measurements.

Figures 3 through 10 illustrate the response of pressure, oxygen concentration, and VOC (asmeasured by PID) concentrations in the perimeter monitoring wells and in the SVE bloweroffgas for each SVE test. The distances from each perimeter monitoring well to the SVE testwell are indicated in the legend on each figure. It should be noted that data from monitoringwell DM-5 were eliminated from consideration due to the potential for a clogged well screenand erroneous results.

Figures 3 and 4 show a rapid decrease in soil gas pressure in the monitoring wells located 30feet from the SVE test well. Vacuum response in the majority of the more distant monitoringpoints was not discernable over ambient diurnal fluctuation. To be conservative, it wasassumed that the soil gas pressure could vary by ± 0.1 inches of water due to naturalfluctuation alone. Therefore, the only additional monitoring point to show a vacuum lessthan -0.1 inches of water was SFMW-5, which was located more than 130 feet from the SVEtest wells. This response was observed consistently in both tests; potentially, it indicates aradius of influence more than 100 feet from the SVE test well.

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The oxygen concentration data shown in Figures 5 and 6 show that the monitoring wellslocated more than 100 feet from the SVE test wells are located in areas of little/nocontamination and that the tests were not performed long enough to flush the monitoringpoints with fresh air. The baseline levels collected for the first test on DM-1 were generallyelevated in all monitoring wells except SFMW-2. These results indicate that all wells exceptSFMW-2 are located in areas with low oxygen demand and potentially little contaminationthat may drive reactions that would deplete the oxygen. Oxygen concentrations changed inall monitoring points during the test and indicate that some influence was exerted from theSVE blower. Figure 5 shows a consistent decrease in oxygen content in all monitoring pointsimmediately after startup of the SVE blower and a slowly increasing concentration as timepassed. The oxygen concentration did not return to baseline conditions after 24 hours oftesting. Figure 6 shows that the oxygen levels did not return to their pre-existing levelsbefore the test on DM-1. The oxygen levels fluctuated slightly immediately after startup ofthe second test, but then either stabilized or slightly declined.

Despite an initial spike in SFMW-5 and DM-4, VOC concentrations in all perimeter-monitoring points during the DM-1 test were very low, as Figure 7 illustrates. Assumingthat some limited airflow was achieved in these wells during the test, these low VOCconcentrations potentially indicate that these monitoring points were located beyond theareas of vadose zone contamination. Figure 8 shows that the only well that consistentlyrecorded elevated VOC concentrations was DM-1 during the SVE test at SFMW-2,indicating that monitoring well DM-1 may be the only well that was monitored that islocated within an area of vadose zone contamination.

Figures 9 and 10 show the SVE blower off gas VOC concentrations (as measured with a PID)during the pilot tests at DM-1 and SFMW-2 respectively. Figure 9 shows a decreasing VOCconcentration with time and indicates that the soil gas was becoming more dilute as the testran. This points to the possibility that the extent of vadose zone contamination may belocalized to the DM-1 area. Figure 10 shows an increasing VOC concentration at SFMW-2with time that did not reach a maximum during the 14-hour test. This indicates that the SVEblower was beginning to extract from the source of VOCs, but that it did not fully reach itspotential. This suggests that the source of the VOC contamination was located some relativedistance from SFMW-2 and potentially close to DM-1 (approximately 33 feet away).

Table 2, which appears at the end of this technical memorandum, summarizes theconcentrations of the chemicals detected in the samples that were analyzed by thelaboratory for VOC and TPH. Attachment C contains the analytical data from the laboratory.Table 2 also shows that more than 99 percent (by weight) of the VOCs removed by the SVEblower were petroleum-based compounds occurring in the Q to Cn range. The VOCconstituents detected at the highest concentrations were 1,2,4 trimethylbenzene and 1,3,5trimthylbenzene, followed by significantly lower concentrations of chlorinated and otherpetroleum-based hydrocarbons. Both 1,2,4 trimethylbenzene and 1,3,5 trimthylbenzene arepresent in most petroluem fuels or solvents such as Stoddard solvent. PCE was consistentlydetected at levels higher than the other chlorinated chemicals. TCE and cis-DCE were alsodetected, but at concentrations generally an order of magnitude below the PCEconcentrations.

The vapor-phase GAC was successful in removing more than 97 percent of the TPH (byweight) from the offgas prior to discharge to the atmosphere.

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Pilot Test ConclusionsThe SVE pilot study at the FAP Superfund Site yields the following general conclusions,which were reached based on the measured field parameters and laboratory data analysis:

• The soil at the site is amenable to removal of contaminants through the use of SVE.

• There is limited contaminant mass present at the water table in the vicinity of DM-1.VOC concentrations in the headspace (i.e., 5 to 10 feet above the water table surface) ofthe other shallow monitoring wells was very low (generally less than 10 ppmv). Existingmonitoring well SFMW-2 is on the fringe of the source of contamination as indicated bymuch lower SVE blower offgas VOC concentrations and increasing VOC concentrationswith time. The offgas concentrations in DM-1 were decreasing with time, potentiallyindicating that the source is not extensive.

• The radius of influence observed using vacuum and oxygen response alone (100 ft+) wassignificant considering the abnormally short length of vent well screen that was used forextraction. This could indicate that the SVE test wells were screened within highlypermeable soil zones where air could preferentially travel significant lateral distances.

• The mass removal rate of 1.4 Ibs/day of total VOCs at the DM-1 site was relativelysignificant. However, the chlorinated fraction of the total mass removed representedless than 1 percent of the total mass suggesting that chlorinated hydrocarboncontamination in the area is very small as compared with the volume of petroleumhydrocarbon contamination.

• The chemicals detected in the offgas from the two SVE wells were consistent. Thisindicates that the vapors are likely from the same source located adjacent to existingmonitoring well DM-1.

• The offgas values are not high enough to indicate a high saturation of non-aqueousphase liquid (NAPL), but rather a low NAPL saturation that is consistent with theobserved low groundwater concentration. Some benzene, toluene, ethylbenzene, xylene(BTEX) is present, potentially indicating that the NAPL is not well weathered.

• The pore exchange rate observed during the test was less than 0.5 pore exchanges perday. This rate is significantly lower than typical design rates of 5 to 10 pore exchangesper day. In a full-scale SVE system, longer SVE well screens and higher airflow rateswould be used, which may result in higher mass removal rates than were observed inthese pilot tests.

• The soil remediation timeframe using full-scale SVE can be estimated by dividing thetotal mass of contamination in the vadose zone by the predicted full-scale mass removalrate. The total estimated mass of PCE within the vadose, or unsaturated soils, is 4.5 IbsPE&S, 2001). The actual mass removal rate of PCE during the pilot test wasapproximately 0.01 Ibs/day, based on the laboratory analysis of the samples taken at theconclusion of each test. Based on these estimates, the remediation time frame would beapproximately 450 days. A shorter time frame is likely if a full-scale remediation systemwere operated. However, the preliminary data show that the mass of contamination (toinclude petroleum hydrocarbons) within the vadose zone may be higher than previously

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estimated. (The original estimate was based on chlorinated solvent soil contaminationgenerally occurring in the top 2iO feet of fiie soil horllori;; The contamination [includingboth chlorinated solvents and petroleum hydrocafbonsppmoved during the pilot testwas recovered from deeper intervals in the vadose zone;[35-40'].) Therefore, theestimated remediation timeframe is uncertain.

In summary, the SVE pilot test at the FAP Superfund Site ffidfcated that SVE is a viableoption for removing contamination that has been determined to be present at or near thewater table surface. However, more than 99 percent of the contamination recovered waspetroleum-based. For the purposes of remediation under Superfund, the detectedpetroleum contamination is not considered a contaminant of concern. It is unclear whetherSVE would be effective at addressing the source of chlorinated hydrocarbon contaminationencountered in intermediate zone ground water, particularly in light of the low detections(at or below the current preliminary remedial goal) of chlorinated hydrocarbons observed inshallow ground water.

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TABLE 2

Summary of SVE Blower Offgas Analytical Results (Detected Analytes Only)Fruit Avenue PlumeSuperfund Site, Albuquerque, NM

Concentration during the DM-1 SVE Test (mg/m3)

Chemical

Chlorinated Hydrocarbons

Perchloroethylene

Trichloroethene

cis-Dichloroethene

trans-Dichloroethene

1 ,2,4 Trichlorobenzene

Petroleum Hydrocarbons

TPH(C9-C11)

Benzene

Toluene

Ethylbenzene

Xylenes, Total

1 ,2,4 Trimethylbenzene

1 ,3,5 Trimethylbenzene

Time = 1 hr,Pre-Carbon

0.44

0.11

0.28

0.04

ND

277

ND

0.05

0.03

0.11

1.20

0.54


1.35

0.20

0.28

0.05

0.04

353

ND

0.10

0.06

0.26

2.40

1.11


1.93

0.17

0.09

0.02

ND

282

ND

0.03

ND

0.06

1.97

0.81

Time = 24 hr,Post-Carbon

ND

ND

ND

ND

ND

1.43

ND

0.13

0.01

0.01

0.01

0.003

Concentration during the SFMW-2 SVE Test (mg/m3)


0.29

0.05

ND

ND

ND

38.9

ND

0.01

ND

0.01

0.05

0.02


0.45

0.06

0.01

ND

ND-

107

ND

0.01

0.01

0.02

0.41

0.18

Time = 14 hr,Post-Carbon

ND

ND

ND

ND

ND

2.67

0.002

ND

ND

ND

0.03

0.01

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ReferencesDuke Engineering & Services (DE&S), 2001. "Feasibility Study Report, Fruit Avenue Plume

Superfund Site, Albuquerque, New Mexico." Prepared for the New MexicoEnvironment Department, Superfund Oversight Section, and the U.S. EnvironmentalI Protection Agency, Region 6, Dallas, TX. June 8, 2001.

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Taken from the Fruit Avenue Plume Superfund Site Feasibility Study, June 2001

• SFMW-1

Location ofFormer

UndergroundStoraoe Tank

(300 gal.)

Wells FargoBank Building

SFMW-6SFMW-5

Parking Lot

C13'-15

18-2ff

S8-6PCETCEctsPCECIS

0.440020.030.030.04

Parking Lot

kSB-1DSB-7 -3 7^ /----

DM-1

ilankPN

1?-13'16'22'

PCETCEPCEPCi

3.00.51.20.78

W W B-V-Location of

FormerUndergroundSlorarm Tank

(1,500 gal.),»DSB-2

OM-2'SF-MW-2

DSB-8

Parking Lot

Legend

Approximate Scale

DE«S. 2000Source: Adapted fromDames & Moore

Summary of Soil Sample Resultsat the Source Area

Fruit Avenue Plume SiteAlbuquerque. NM

(•) Soil Boring£ Shallow Completion Well• Intermediate Completion WellA Deep Completion Well

f~ ~] Tank ExcavationPCE TetracWoroelhylerte (mg/kg)TCE Trichloroelhylene (mg/kg)cis 1,2-Dichloroelhvlene (mg/kg)

mg/Kg = mBIkjram per kilogramMote Tank pit sample location Is approximate andbasod on information provided In the Screenig SiteInspection (NMED, 1990).

002266

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Figure 2

SOU VAPOR EXTRACTION SYSTEMSPortable Pilot Test

6 5\ \

8 4

i_A

10 11

Specifications:Max. overall dimensions (LxWxH; inches) 52x16x26Weight (pounds) 120Required incoming power 230V, l(f)Maximum total amperage (amps) 20Recommended minimum

generator performance (kW)1 14Air Inlet 2" Quick connectAir discharge 2" Quick connect

Notes:1 - Generator sizing is estimated. Please contact generator supplier for generator selection.2 - Some rentals do not have airflow meters, or XP motors. If these items are required, please notify Carbonair.

Performance:Airflow(SCFM)@5"HgAirflow(SCFM)@3"HgAir flow (SCFM)@l"Hg

Typical features2:NEMA7motor starter with power cordExplosion proofblower motorAir flow kit

60140180

CARBONAIRENVIRONMENTAL SYSTEMS

MINNESOTA: (corn hdartrs)Carbonair2731 Nevada Ave. N.New Hope, MN 55427PH:800-526-4999763-544-2154FAX:763-544-2151Homepage: www.carbonair.com

FLORIDA:Carbonair2603 NW 74th PlaceGainesville, FL 32653PH:800-241-7833352-376-9528FAX:352-373-4971

VIRGINIA:Carbonair761 Union StreetSalem, VA 24153PH:800-204-0324540-387-0540FAX: 540-389-6860

TEXAS:Carbonair4105 Hunter Rd. #10San Marcos, TX 78666PH:800-893-5937512-392-0085FAX:512-392-0066

002267

rrrrrrrrr

rrr

rrrrr

Figure 2

SOU VAPOR EXTRACTION SYSTEMSPortable Pilot Test

6 5\ \

8 4

i_A

10 11

Specifications:Max. overall dimensions (LxWxH; inches) 52x16x26Weight (pounds) 120Required incoming power 230V, l(f)Maximum total amperage (amps) 20Recommended minimum

generator performance (kW)1 14Air Inlet 2" Quick connectAir discharge 2" Quick connect

Notes:1 - Generator sizing is estimated. Please contact generator supplier for generator selection.2 - Some rentals do not have airflow meters, or XP motors. If these items are required, please notify Carbonair.

Performance:Airflow(SCFM)@5"HgAirflow(SCFM)@3"HgAir flow (SCFM)@l"Hg

Typical features2:NEMA7motor starter with power cordExplosion proofblower motorAir flow kit

60140180

CARBONAIRENVIRONMENTAL SYSTEMS

MINNESOTA: (corn hdartrs)Carbonair2731 Nevada Ave. N.New Hope, MN 55427PH:800-526-4999763-544-2154FAX:763-544-2151Homepage: www.carbonair.com

FLORIDA:Carbonair2603 NW 74th PlaceGainesville, FL 32653PH:800-241-7833352-376-9528FAX:352-373-4971

VIRGINIA:Carbonair761 Union StreetSalem, VA 24153PH:800-204-0324540-387-0540FAX: 540-389-6860

TEXAS:Carbonair4105 Hunter Rd. #10San Marcos, TX 78666PH:800-893-5937512-392-0085FAX:512-392-0066

002268

rSOIL VATOR EXTRACTION PILOT STUDY TEST RESULTS

f FIGURE 5Oxygen Response during SVE Test at DM-1

-*. Fruit Avenue Plume Superfund Site, Albuquerque, NM

r

r[rr

F

rrrrr[rirr

15g

3 10 <1

5

00:0(

k y

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_____^—————— ^

£=*„....->-— "'*^ —————————————— ....7K —— "

^ ______ • ——————————————— •

— •— SFMW-1 (1611)

— A— SFMW-5(158')

— X— DM-4(1ir)

— *— SFMW-2 (30')

):00 4:48:00 9:36:00 14:24:00 19:12:00 24:00:00 28:48:00

Elasped Time (hr)

I6URE6)xygen Response during SVE Test at SFMW-2ruit Avenue Plume Superfund Site, Albuquerque, NM

201

~

-, , "

-

0•>

o

in

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(o/0) uaBAxo

T\ *~ — — ——————— A

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— *— DM-1 (30')

0:00 2:24:00 4:48:00 7:12:00 9:36:00 12:00:00 14:24:00 16:48:00

Elapsed Time (hr)

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Attachments

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- •' rtfaijp i',,V ';' i V' ""'"•"-, t'*-fi'^1 'V*f & tjfS^ii. ~j£ll5cuij-i._i..__

-t^!

H.&4M-

KJKKBSi

! i

i • -d ~ rg'^./i'Afa JT>!-

. L-'l-

"TI 1

LiU.-.' i I

^

<^tf W

002280

IIIIIIiIIIIIIII1III

Attachment B

Data Summary Tables

002281

FniB Av«ou» Plum« SIMy dHrcRaction ^^^

Data Collected By:TestBlcnnr Turrxd On:

B«««Hii» Otptti to WBaf M

BM Ljl»vr», Unda CotellaSVE Tint Al DM-1

Approx. TimeActual Start Date/Thne: (T*xx hours)

EJtpeed Time from StartWall

SFMW-1SFMW-2Sr-MW-53M-1

DM-4

DM-5

DTW(ft btoc)_B***llne

5/8/20029:0403030

37.1239.2739.4438.5837.0439.41

Too ot Scram

313230342933

Expoeed Screentn>

6.127.279.444.568.046.41

Natural Diurnal RuguallomVacuum Measured in Monitoring Well»

Vecuum (Inch** ot H2O)

TimeWell

SFMW-2

£2030

0.03

10:30:00

0

1£OttOQ

0.05

13S03Q-

o.os

1630:00

0.09

5/U20(& 17:00

173030

0.05

S/8/2G02 1 9:00183030

0.03

5/8/2002 19:4519:4530

0.03

5/8/200£ 20:3020:30

0.08

Natural Dliimul RuduaUonaracuum f Inohea of H2O>

Date/ToneTime

WeilSFMW-15

5/9/Z002 11:1211:12:00

0.04

5/9/2002 16:2510:25:00

0.05

5/10/20020:320:32:00

0.01

5/10/20027:337:33XO

0

F*cuum (tnche* erf H2O>Approx, Tbne

Actual Start Date/Time: fT«» hour*)

WellSFMW-1

Baeelm*5/9/20026:45

•0.03

T«05/9/20028:08

•0.05

5/9/2002 8:21

•0.07

5/10/20028:109:10150

•0.02

5/9/20028:47

-0.06

Vacuum flnchee ol H2O>Approx. Thne

Actual Start Date/Time: (T«xx houre)Elapeed Tlm« from Start

WellSFMW-2

Approx. TbneActual Start Date/Time: n*xx houre)

Elapeed Tim* from StartWell

SFMW-2

Approx. Tton*Actual Start Date/Time: fT*xx hour*}

Bapeed Tbna from StanWell

SFMW-2Vacuum (Inchea of H2O)

Approx. TimeActual Start Date/Time: fT«xx houre]

Elapeed Tbne from Star!Well

SFMW-5

Baaelme5/9/20028:45

(T00:00

-0.09

5/9/20029:261:28:00

-0.61

Recovery5/10/20028:31

24:31 MM

-0.67

B«*eitn*5/9/20026:45

0:00:00

-0.06

5/9/20028:020£2£0

-0.39

5/9/20029:501:50:00

-0.63

5/10/2002 8:3224:32:00

-0.4

T«O5/9/20028:10

0:10:00

•0.085

5/9/20028:04ft04«0

-0.5

5/9/200210:002:00:00

•0.63

5/10/2002 8:3424:34:00

•0.26

5/9/20028:18ft 18:00

•0.15

Vacuum ftnohea of K2OtApprox. Time

Actual Start Date/Time: (T««x houre]Dapeed Time from Start

WellDM-4

5/9/20028:11ftllM)

•0.62

5/9/200210:062AOAO

-0.69

5/10/2002 8:3524:35:00

-0.21

5/9/20028:460:46:00

-0.11

5/9/20029:06

-0.06

5/9/20028:140:14m

•0.65

5/9/2002 12:014:01 BO

-0.59

5/10/2002 8:3624:38:00

-0.18

5/9/20028:041:04 tlO

-0.095

5/10/2O02 16:5816:50:00

0.05

5/9/20029:281 22

-0.04

5/9/20028:170:17:00

-0.66

5^200216:29B:2£00

•0.57

5/10«002 8:3724:37X10

-0.16

5/9/20029:291:29:00

-0.07

5/10/2002 17:2617:26

0.01

5/9/20029:52

•0.05

5/9/20028:250:25:00

•0.66

5/10/20020:4218:42:00

•0.61

5/10/20028:3824:38^0

-0.14

5/9/20029:551:65:00

-0.07

5/10/2002 17:4117:41

0.08

5/10/2002 18:2218:22

0

5/9/2002 12:10

-0.02

5/9/20028:300:30:00

-0.66

5/10/2002 7:2523:2S.-00

-C.53

5/10/20028:4024:40:00

-0.13

5/9/2002 12:104:10:00

-O.OS

' 5/9/2002 16:20, 2^22

•o.oi

5/9/20028:39ft3ftOO

•O.66

5/10/20028:1224:12:00

-0.65

5/10120028:4224:42:00

-0.1

5/9/2002 16:24

6:24:00

•0,04

5/10/2002 19:2519:25

0.02

5/10/20020:19i I2J222

•0.07

5/9/20028:440:44:00

•O.65

5/10/2002 8:4724:4730

-O.OS

5/10/2002 0:2418^430

•O.OS

5/1 1/2002 8:068:06

0.03

5/10/2002 7:29

— SS22 —-O.07

5/9/20028:500:5030

•O.64

5/10/2002 8:5224:52:00

-O.OS

5/10/2002 7:32

23:3230

-0.11

5/10/2002 8:03

•0.07

5/9/20029:001:00:00

-0.65

5/10/20029:1125:1 1*0

-0.03

5/10/20028:06243830

-0.12

B«eattm5/9/20026:45

0:00:00

-o.oe

T«05/9/20028:07

0:07:00

•0.065

5/9/20028:230- 3flO

-0.1

5/9/20028:480:48:00

-0.08

Vacuum (Inchea of H2O1Approx. Time

Actual Start Date/Time: (T*m houre]EJapaed Thne from Start

WellDM-5

aV920029:101:10X»

-0.08

5/9/20029:271:27:00

-0.06

5/9/20029:531:53:00

-O.OS

Baeellne5/9/20026:45

Oft*OO

-O.OS

T-O5/9/20028:04

0:04:00

-0.21

5/9/20028:190:19:00

-0.32

5/9/20028:240:24:00

-0.32

5/9/20028:340:34:00

•0.34

5/9/20028:400:*C«X)

-0.3^

5/9/20028:450:45:00

-0.32

5/9/2002 12:104:10:00

•0.07

5/9/2002 16:156:1 S^X)

•0.02

5/10/20020:1218:12^0

•O.OS

5/10/2002 7:272327:00

-0.11

5/10/2002 8:04• 24:04:00

-0.11

5/10/2002 9:19 5/10/2002 932 5/10/2002 9:5925:1930 25:3230 25:5930

-0.01 -0.01 -0.01

Vacuum (Inchea of K2O)Approx Time

Actual Start Data/Time: (T»xx houre)Elapeed Time from Start

DM-5

Approx. Time

Elapeed Time from Start

5EE

5/9/20028:490:49:00

-0.31§Wr6tiFtacovery

24:3130

-0.32

5/9/20029:011:0130

-0.31

24:3230

535

5/9/20029:301:30:00

-0,3

24:3830

—}

5/9/20029:511:5130

•0,31

24:68:00

o

»»aooa>»1:5930

•0.31

25:1300

^001

5/9/2002 1 1 '043:04:00

-0.32

23:2030

&"02

5/9/2002 12:10

-0.24

20:0030

004

5/9/2002 16:22

-0.24

20:18:00

5/10/20020:22

•0.31

26:38:00

009

5/10720027:30

•0.33

28:55:00

•0.34

002282

oatppmwocOxyg*iWOC Measured In Monitoring Wells

Blower Parameter*

Blower Parameter*Actual Date/TimeElapsed Tlm« (hr)

SVE Vacuum Cm. H2O)SVE Flowrale (adm)

Conversion to adm:T(dogF)=1SO

P (pel) o (3adm v

5/9/20026:040:00:00

6385

5/9/20028:270:27:00

6086

5/0/20028:530:53:00

5965

5/9/20028:540:54:00

6486

5/9/20029:301:30:00

6465

5/9/20029:551:85:00

6484

6/9/200211:373:37:00

5763

5/9/200211:383:30:00

6464

5/9/200212:354:35:00

6784

5/9/2002 13:175:17.00

5057

5/9/2002 16:048:O4:OO

5054

& 10/2002 0:0218:02:00

5255

5/10/2002 6:0024«M»

5255

52.921 53.541 52.92 53.54 52.92 52.29 51.67 S2.29| 52.29 35.461 33.62] 34.24) 34.240654: dilution valve dosed to increase vac.1138: dilution valve dosed to Increase vac.1315: Water surging up 4-inch Ilex hose. Opened dilution valve 100%, vac -20', water still in line. Turn blower oil. empty - 2 gal from M.S.1317: Turn blower on to SO*

OFF-GAS VOC (measured with OVA)

VOC (DOT)Actual Date/TimeElapeed Time (hr)

pro-VOAC • FIDsre-VQAC - P1DPost-VGAC - % O2Posl-VGAC - RDPost-VGAC - PtDBounds Removed (based on FID)Cumulative Pounds RemovedPounds Removed (based on FID)Cumulative Pounds Removed

5/9/20028:250:25:00295.00209.00

2S.911.140.1

. 0,1,0.1 : -0.1

5/9/20029:301:30:00305.00208.0014.9%22.800.630.3, , •0.4 '0.2 ;0.3

5/9/200210:15£15:00314.00203.0014.9%23.0013.30.20.70.10.4

5/9/200212:054:05:00294.00229,0014.7%13.900.34as1.20.30.7

5/9700216:408:40:00

171248

0.666.30.82.00.51.2

5/10/20020:1010:10:00

235159

5.7 10.060.9290.61.8

5/10/2002 8:3024:30:00

115182

2.20.960.93.80.62.4

Laboratory ResultsActual Data/TimeElapeed Time (hr)

pre-VGAC 'Poat-VSAC '

Pounds Removed *Cumulative Pounds Removed '

5/920029:00T=1

877.67JjijjLMyaUBEaaBgBjajE

1.31.3

5/9/2002 12:00T=4

354.93m[i!tyVKSS$i&rf&$@

•6.0. 6.3

5/10/2002 8:00Y^4

2U.201.61

ao.3 ••-26.7..:.- .;."..

1. Values represent total contambatton removed, mg/m3 (I.e.. TPH value plus delected concentrations of chlorinated hydrocarbons)Z. Pounds removed and cumulative pounds removed are based on pn>VQAC samples, and adm values from above table.

002283

SVE Pilot Study Data CollectionFruit Avenue Plume SiteAlbuquerque, New Mexico

Data Collected By:

Test:

Blower Turned On:

Natural Diurnal Fluctuations

BiM Lefevre, Linda Colella

SVE Test At SFMW-2

5/10/2002 17:13

Vacuum Measured In Monitoring Wells

Vacuum (Inches of H2O)Approx. Time

Time/DateWell

SFMW-15

5/10/2002 16:50

0.05

5/10/200217:26

0.01

5/10/2002 17:41

0.08

5/10/2002 18:22

0

5/10/200219:25

0.02

5/1/2002 8:08

-0.03


Actual Start Date/Time: (T=xx hours)Elapsed Time from Start

WellSFMW-1

Baseline5/10/2002 16:59

0:00:00

0.06

T=05/10/2002 17:17

0:04:00

-0.04

5/10/2002 17:230:10:00

-0.04

5/10/2002 17:380:23:00

-0.03

5/10/2002 18:191:06:00

-0.04

5/10/2002 19:202:07:00

0

5/11/20028:0314:50:00

-0.06



WellDM-1

Blower Off: RecoveryApprox. Time


WellDM-1

Blower Off: RecoveryApprox. Time


WellDM-1

Baseline5/10/2002 16:52

0:00:00

0.11

5/10/2002 19:162:03:00

-0.41

5/11/200295916:16:00

-0.13

5/10/200217:140:01:00

-0.19

5/11/20027:5914:46:00

-0.41

5/1 1/2002 9:3016:17:00

-0.11

5/10/2002 17:150:02:00

-0.28

5/11/20029:2416:11:00

-0.38

5/11/20029:3116:18:00

-0.1

5/10/2002 17:300:17:00

-0.39

5/11/20029:2516:12:00

-0.29

5/11/20029:3316:20:00

-0.08

5/10/2002 18:020:49:00

-0.4

5/11/20029:2616:13:00

-0.22

5/11/20029:4016:27:00

-0.06

5/10/200218:151:02:00

-0.36

5/11/20029:2716:14:00

-0.18

5/11/20029:4516:32:00

-0.05

5/10/2002 18:261:13:00

-0.4

5/11/20029:2816:15:00

•0.15

5/11/20029:5016:37:00

-0.04



WellSFMW-5

Baseline5/10/2002 16:56

0:00:00

0.09

T=05/10/200217:19

0:06:00

-0.03

5/10/2002 17:250:12:00

-0.12

5/10/2002 17:380:25:00

-0.04

5/10/2002 18201:07:00

-0.12

5/10/2002 19:232:10:00

-0.08

5/11/20028:0614:53:00

-0.12

SVE at SFMW-2

002284

Vacuum Measured In Monitoring WellsVacuum (Inches of H2O)

Approx. TimeActual Start Date/Time: (T=xx hours)

Elapsed Time from StartWellDM-4

Baseline5/10/2002 17:01

0:00:00

0.06

T=05/10/2002 17:16

0:03:00

•0.04

5/10/2002 17:230:10:00

-0.04

5/10/2002 17:340:21:00

-0.02

5/10/2002 18:171:04:00

-0.06

5/10/2002 19:192:06:00

-0.04

5/11/20028:0114:48:00

-0.06

Vacuum (Inches of H20)Approx. Time


WellDM-5

Baseline5/10/2002 16:51

0:00:00

0.08

T=05/10/2002 17:15

0:02:00

-0.07

5/10/2002 17:210:08:00

-0.16

5/10/2002 17:330:20:00

-0.16

5/10/2002 17:430:30:00

-0.2

5/10/2002 18:040:51:00

-0.18

5/10/2002 18:161:03:00

-0.17

5/10/2002 18:241:11:00

-0.15

5/10/200219:182:05:00

-0.18

5/11/20028:0514:52:00

-0.21

Oxygen/VOC Measured In Monitoring Wells

Actual Start Date/Time: (T=xx hours)

=not measured/flame out

Blower ParametersBlower Parameters

Actual Date/TimeElapsed Time (hr)

SVE Vacuum (in. H2O)SVE Rowrate (scfm)

5/10/2002 17:130:00:00

6030

5/10/2002 17:310:18:00

5930

5/10/2002 18:060:53:00

5730

5/10/2002 18:070:54:00

SO30

5/10/200218:120:59:00

5030

5/10/2002 18:261:13:00

5030

5/10/2002 19:402:27:00

5031

5/11/20027:3714:24:00

5033

T(deg F)=150P(psi)=13

acfm = 18.681 18.68 18.68| 18.681 18.68| 18.68| 19.30) 20.54

1806: Water surging up SVE line. Dilution valve opened to 50 inches of water

SVE at SFMW-2

002285

OFF-GAS VOC (measured with OVA)VOC (pom)

Actual Date/TimeElapsed Time (hr)

pre-VGAC • FIDpre-VGAC - PIDPost-VGAC - % O2Post-VGAC - FIDPost-VGAC - PIDPounds Removed (based on FID)Cumulative Pounds RemovedPounds Removed (based on FID)Cumulative Pounds Removed

5/10/2002 17:400:27:006.707.80

0.000.8

•fr.=- — 0;OOl5S====

0.001 . "_ . „? .- 0.001'P ~ :-•:K-~ ..-rOi001S--5J S=

S/1 0/2002 18:201:07:0015.3212.70

0.001.57

, ::-: 0.002^---_0.003

0:002:r--Tf.O-002r-. '-•

5/10/2002 19:202:07:0019.7723.4418.9%0.000.330;008 •.'.- '•0.0100.0040.008

L 5/11/20028:2515:12:0027.7545.82

0.450

0.110.12^0.070.08

based on scfm

based on acfm

OFF-GAS LAB

LaboratorActual Date/Time

Elapsed Time (hr)

pre-VGAC 'Post-VGAC '

Pounds Removed z

Cumulative Pounds Removed *

i Results

T=1

39.24

0.1o.r - ._- ._ ._ .

T=14"

107.532.67

2.5„ ..,.2.6:...;..

1. Values represent total contamination removed, mg/m3 (i.e., TPH value plus detected concentrations of chlorinated hydrocarbons)2. Pounds removed and cumulative pounds removed are based on pre-VGAC samples, and acfm values from above table.3. Sample was collected at the end of the test, which was 14.4 elasped hours. Note that lab misread ID and caned it T17.

SVE at SFMW-2

002286

IIIIIIIIIIIIIIIIIII

Attachment Ci i

Analytical Data

002287

IIIIIIIIIII1IIII1I

CH2MHIU

Applied Science* Group

2300 NW Walnut Blvd

Cotvdlls, OR

97330-3538

P.O. Box 428

Ccxvdlls. OR

97339-O428

Tel 641.752.4271

Fax 541.752.0276

CH2MHILLApplied Sciences Group

May 31,2002

Fruit Avenue Plume Superfund

168667.DA.FI.04

RE: Laboratory Report for Fruit Avenue Plume SuperfundApplied Sciences Group Reference No. 7424

Rick Dobbins/GNV:

On May 14, 2002, CH2M HDLL Applied Sciences Group received four samples with arequest for analysis of selected parameters. All analyses were performed by CH2M HELLunless otherwise indicated below.

The analytical results and associated quality control data are enclosed. Any unusualdifficulties encountered during the analysis of your samples are discussed in the casenarrative.

CH2M HELL Applied Sciences Group appreciates your business and looks forward toserving your analytical needs again. If you should have any questions concerning the data, orif you need additional information, please call Ms. Kathy McKinley at (541) 758-0235,extension 3 120.

Sincerely,.

Ginger Collins jLaboratory Representative

i

Enclosures

cc:John Ynfante/HOU

OR100022

PAGE 1

002288

7AVOLATILE CONTINUING CALIBRATION CHECK

I%j.-•)

I.• 'I

Lab Name:

Lab Code:

CH2MHILLASL

CVO Case No.: 7424

Instrument ID: GC/MS - G

Lab File ID: CV3_0523.D

Heated Purge: (Y/N)

GC Column: DB-VRX

N

ID: 0.25 (mm)

Contract: 168667.DA.F1.04

SASNo.: 052102 SDG No.: 7424

Calibration Date:

Init. Calib. Date(s):

Init. Calib. Times:

05/23/02 Time: 09:51

05/21/02

09:19

COMPOUND

trans-1 ,2-DichloroetheneToluene-d8Bromofluoro benzene

RRF0.9440.8620.163

RRF4

1.0040.8670.170

%D

" -6.3-0.6-4.5

MAX%D

303030

05/21/02

12:51

II FORM VIIVOA- 5 4 -

Rev. 10/99

002289

8AVOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

Lab Name: CH2M HILL ASL

Lab Code:


CVO Case No.: 7424 SASNo.: 052102 SDG No.: 7424

Lab Rle ID (Standard): CV3_0523.D


GC Column: DB-VRX ID: 0.25 (mm)

Date Analyzed: 05/23/02

Time Analyzed: 09:51

Heated Purge: (Y/N) N

01

02

03

04

05

06

07

24 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLE

NO.

BS2A0523

B1.0523

DM1T24POST

DM1T1PRE

DM1T4PRE

DM1T24RRE

DM1T24RREDUP

IS1

AREA #

41450

58030

24870

41507

41397

43355

43634

47448

46172

46806

RT #

13.54

14.04

13.04

13.54

13.53

13.55

13.5513.53

13.54

13.54

IS2

AREA #

190900

267260

114540

189573

188145

199620

194919218250

209480

212689

RT #

15.98

16.48

15.48

15.99

15.98

15.99

16.00

15.98

15.99

15.99

IS3

AREA #

54234

75928

32540

53499

53605

56263

4152049063

50918

52875

RT *

20.46

20.96

19.96

20.46

20.46

20.46

20.4620.46

20.47

20.46

151 = Bromochloromethane .,152 = 1,4-Difluorobenzene153 = Chlorobenzene-d5AREA UPPER LIMIT = +40% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIMIT = +0.50 minutes of internal standard RTRT LOWER LIMIT = -0.50 minutes of internal standard RT# Column to be used to flag values outside QC limit with an asterisk.* Values outside of contract required QC limits

FORM VIIIVOA- 5 5 -

Rev. 10/99

002290

CH2MHILL Applied Sciences LabCHAIN OF CUSTODY RECORDANDAQREEMENTTO PERFORM SERVICES

CVO 2300 NW Walnut BoulevardConmins. OR 973304538(541)752-4271 FAX (541) 752-0278

coc#.Project* Purchase Order #

jsetNams

*o HIT

Company Name

Report to: Phone No:

Requested Completion Data:

Sampling

Typ«

M

Matrix

W

Sample Disposal:

R«tumD

CUENT SAMPLE ID(8 CHARACTERS)

LABQC

Requested Analytical Method #

Preservative

THIS AREA FOR LAB USE ONLY

Lab* Page of

EPA Tier QC Level

1 (Screening) 2 3

Special Instructions:

Instructions and Agreement Provisions on Reverse Side DISTRIBUTION: Original • LAB, Yellow • LAB, Pink • ClientRev 2/01 Lab form 340

002291

CH2IV3H1LLServices

Sample Receipt Record

Batch Number I Date received:. lo//

Client/Project.

VERIFICATION OF SAMPLE CONDITIONS (verify afl items) * HD = Cfent Hand delivered Samples

Observation .Were custody seals Intact and on the outside of the cooler? .

Was the Chain of Custody Inside the cooler?

•Was the Chain of Custody properly filled out? . .

Were the sample containers bi good condftfon? • A inWas there Ice In the cooler? Enter temp, blank or fcewater? C •'f\J/'T •

YESX.PSX*A

NO

^\- yj

*HD

If the answer to any of the questions above is NO, a Sample Receipt Exceptions Report Must be written.

VERIFICATION OF SAMPLE PRESERVATION (verty afl preserved samples except HAAs, HANs and CH)

SampleNo123456 .78

-9" 10

111213141516

: 17

. 1819

; . 20

21222324 ,25 .262728

-...'29. 3 0

NutrientspH<2

"'

\

Metals pH<2

••

• • =•'

. . . . . .

.- • • '•

VolatilespH<2

•

- " • - ' - . . - . ' - •

s

•..;.-.-••.. : • • - .

" • / . . • " • v>

CyanidespH>12

• • • -. ; '.

." v -

.- - .-.- :•-.?•' • • • ' ' . •••'. '

,. :• -. -. •

• • . . • . ' • • • • • •

.. • . ••- • '

. - . , . - • , . . .

,...,.........•:.

•'•..V'-"-. \-:: : ;

TOC pH- :• '<SL:'

• • • • • . ' • • • :-.

- f c * . - • . ; '

..:... ;-.- .V

• • ' /

- " • -,•*.. ' •

' -'.'V: ;; • ':•••:;.'••../. • • •. '•; ..i

TOXpH;-:'<2 • ' -

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Other dpectty)

.. .

;

. . . . . . . ; .

• . . ' •

• •'.• N/A :-;;tUMonpna}

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\/

• , '

I " ' ' - ' ' •

. '• :

•:. •-. -

.". -•'..: :'..:

. . . . . ...;.- .•:-

LOGIN AND pH VERIFICATIONS PERFORMED BY- • • • • r .JT- / • _ . . . • • - .1 •*- . - ' • .. .. - • * . ••: . . -..•, . .•- . . - • •

AppBed Sciences Laboratory2300NWVtfalnjtj3lvd^

. P:O:Sox42&dR:9733O3538

97339-0425

, Oataffime-

Tel541J52.427TFax54M5Z0276

002292

CH2M HILL Applied Sciences Laboratory

Client InformationProject Name: Fruit Avenue Plume Superfund

Project Manager Rick Dobbins/GNVSampled By: W.LeFEVRE

Sampling Date: 05/21/99Sampling Time: See Cross-reference

Type: IntegratedMatn'x: Air

Lab InformationDate Rec'd: 05/14/2002

* Batch ID: 7424Method: TO-14

Report Revision No.: 0Reported By: CMCReviewed By(T§iE£'

Units: ug/L

Client ID Lab ID

Unresolved Complex MatrixSample DateResult Qualifier Analyzed

DMITIPREDMIT4PREDMIT24RREDMIT24POST

742401742402742403742404

2773532821.43

JJJJ

5/23/20025/23/20025/23/20025/23/2002

U=Not detected at specified reporting limits

CH2MHIU.Applied Sctences Group

-5 -

230? NW Walnjt BM. CavaXt OR W33W538P.O. BOX428. CorvaHs. OR W33WM23

W54I.7S24Z7I RaS4l.7S2j0276

002293

1AVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: GH2MHILLASL Contract: 168667.DA.F1.04

EPA SAMPLE NO.

DM1T1PRE

Lab Code: CVO Case No.: 7424

Matrix: (air/soil/water) Air

Level: (low/med) LOW


SAS No.: 051702 SDG No.: 7424

Lab Sample ID: 742401

Lab File ID: 742401 R.D

Date Received: 05/14/02


Dilution Factor 8

CAS NO. COMPOUND

CONCENTRATION UNITS:

UG/L

TTltti

Q

75-01 -4

75-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

vmyi cnionae1 ,1 -Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem,p-Xyleneso-Xylene T~~ <Z1 ,3,5-Trimethylbenzene CT- 51 ,2,4-Trimethylbenzene 3~- 51,3-Dichlorobenzene t/T— S51 ,4-Dichlorobenzene (AT1* S51,2-Dichlorobenzene U3"- s;1 ,2,4-Trichlorobenzene Ur- Sf

•WT9V

Gmifi ..

9 00 A ..zUU

-0^3*9 —-O0247 —

-0r*08 —^JCX0524 —-0r469 —00970 .......VCTO

, .0060 —S A^O.0168S / 0.540;s/ 1.20

0.04650.0465

i [ 0.0465j \ 0.0574

TT*W

_

— IT-tt-

ij •~

J-——•y-•w-4J-TT"

FORM IVOA-7 -

Rev. 10/99

002294

III

1

1

1

1

1

1

1

1

I

1

1

1

1

1B


EPA SAMPLE NO.

Lab Name:

Lab Code:

CH2MHILLASL Contract: 168667.DA.F1.04DM1T1PRER

CVO Case No.: 7424 SAS No.: 051702 SDGNo.: 7424




Lab Sample ID: 742401R

Lab File ID: 742401 R2.D


CAS NO.

FORM I VGA


Dilution Factor: 3

COMPOUNDCONCENTRATION UNITS:

UG/L

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1•f on_fl9-i •

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem,p-Xyleneso-Xvlene1 ,3,5-Trimethvlbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene *1 O X_Trinhlrtrrthan<yanQ

0.00790.01250.310

0.01250.00990.110

0.05430.436

0.03170.117

two

-0 *86 —

- n npoo —

UU

UU

II

u

R-R&

ft-1•K-RC"

Rev. 10/99

002295

1AVOLATILE ORGANICS ANALYSIS DATA SHE

Lab Name: CH2MHILLASL Contract: 168667.DA.F1.04

EPA SAMPLE NO. , 1TT /

/DM1T4PRE V m

•Lab Code: CVO Case No.: 7424 SAS No.: 051702 SDG No.: 7424

Matrix: (air/soil/water) Air Lab Sample ID: 742402 •

Level: (low/med) LOW Lab File ID: 742402.D "

GC Column: DB-VRX ID: 0.25 (mm) Date Received: 05/14/02


Dilution Factor 9

CAS NO.

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-410CM1-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1


COMPOUND UG/L

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem.p-Xvleneso-Xylene 3"- *S^>1 ,3,5-Trimethvlbenzene 31- $><>1 ,2,4-Trimethvlbenzene "3- SS1 ,3-Dichlorobenzene U~T- S51 ,4-Dichlorobenzene U -j"- ^~S1 ,2-Dichlorobenzene U J- ^S1 ,2,4-Trichlorobenzene 3- S S

0.0385 —o-e?e -

• 0.0065 —

6-ono.-..

9 -\r\Ar-tvK*

1 1,35~0'0636•O-216 —

X6.0454/ 1.11

/ 2.39/ 0.0572

0.0572I 0.0572\ 0.0431

Q

_u

— •&--t-t-U"

^r-v

—

—-y--y--u--* /

NV-~— ^^yr

1

1

I

1

\ 1

>

1 1

FORM I VGA Rev. 10/99

002296

I;V..I

i


Lab Name: CH2M HILL ASL Contract: 168667.DA.F1.04

EPA SAMPLE NO.

DM1T4PRER





SAS No.: 051702 SDG No.: 7424


Lab File ID: 742402R2.D



Dilution Factor: 4

. . .

I

CAS NO. COMPOUND


UG/L Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1I9n-fi9.i

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem,p-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 9 A-Trirhlnrnhonrona

0.0111

0.01750.298

0.01750.00760.1920.1021.28

0.05560.220

-&0334 —0 771

-4^3 —0.0260 —

- -0.0260 —

-Cifiaoi

UU

UJ

b —U —

M

- £

- £

- <

-M— f

iFORM I VOA

-10-Rev. 10/99

002297



EPA SAMPLE NO.

DM1T24RRE





SASNo.: 051702 SDG No.: 7424


Lab File ID: 742403. D



Dilution Factor: 9

m

-.:-:.

I

CAS NO. COMPOUND


UG/L Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem,p-Xyleneso-Xvlene i a"- SS1 ,3,5-Trimethylbenzene JT- SS1 ,2,4-Trimethylbenzene "3"- S>S1 ,3-Dichlorobenzene UCT- S :1 ,4-Dichlorobenzene ( ) .T* *=»S1 ,2-Dichlorobenzene U.T-'SS1 ,2,4-Trichlorobenzene U~- *S>S

0.02240.03540.08770.03540.02790.167

0.03071.93

0.03800.0562.

/015380/ 0.806/ 1.96

; 0.05260.05260.0526

V 0.0649

-y-v-—u--w-• —-<f, ,

&- +

43^^—— --y--y--uJU-

IS

FORM I VGA-11-

Rev. 10/99

002298

1I Lab

Lab

• Matr

• Lev«

• GC

1

1

1

1

1

1

1

1

1

1

I

1

1

1m FOR

VOl

Name: CH2M HILL

Code: CVO

1A EPA SAMPLE NO.

DM1T24RRER.ASL Contract: 168667.DA.F1.04

Case No.: 7424 SASNo.: 051702 SDG No.: 7424

ix: (air/soil/water) Air Lab Sample ID: 742403R

»l: (low/med) LOW Lab File ID: 742403R2.D

Column: DB-VRX

CAS NO.

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

MIVOA

ID: 0.25 (mm) Date Received: 05/14/02


Dilution Factor: 4


COMPOUND. UG/L Q

Vinyl chloride 0.0102 U1,1-Dichloroethane 0.0161 Ucis-1 ,2-Dichloroethene 0.091 01.2-Dichloroethane 0.0161 UBenzene 0.0127 UTrichloroethene 0.161Toluene 0.0276Tetrachloroethene 1 .79Ethylbenzene 0.0161 Jm,p-Xylenes 0.0575 „

,0,0- 1 nrnetnyiuenzsne u.bor • • fs fso, t,4- 1 nrnsinyiusnzens -i.ut> K KC>,o*uicnioroD6nZ6n6 —wdjeoy - u K* r\t>

1.4-Dichlorobenzene 0.0230 U £- KBi . -uicnioroDcnzene •wvcoy— ™" u /%— rst^,2,4- 1 ncniorooenzene — wKJryt? u - ••- ^_fe'6

Rev. 10/99-12-

002299



EPA SAMPLE NO.

DM1T24POST





SASNo.: 051702 SDG No.: 7424





Dilution Factor: 1

CAS NO. COMPOUNDCONCENTRATION UNITS:

UG/L Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.p-Xvleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00230.00360.00350.00360.00290.00480.130

0.00610.01330.01030.00350.00290.01340.00540.00540.00540.0066

UUUUUU

U

JJ

UUUU

FORMIVOA-14 -

Rev. 10/99

002300

I

I

I

I

I

I

I

I

I

I

I

I

I

I

I

• 1A EPA SAMPLE NO. /VOLATILE ORGANICS ANALYSIS DATA SHEET i i J

m DM1T1PRE• Lab Name: CH2MHILLASL Contract: 168667.DA.F1.04

Lab Code: CVO Case No.: 7424 SASNo.: 052102 SDGNo.: 7424

Matn'x: (air/soil/water) Air Lab Sample ID: 742401

Level: (low/med) LOW Lab File ID: 742401 R2.D

I GC Column: DB-VRX ID: 0.25 (mm) Date Received: 05/14/02


Dilution Factor: 3


CAS NO. COMPOUND. UG/L

156-60-5 I trans-1.2-Dichloroethene I 0.0378

FORMIVOA Rev. 10/99-39 -

002301



EPA SAMPLE NO.

DM1T4PRE




GC Column: DB-VR){ ID: 0.25 (mm)

SASNo.: 052102 SDG No.: 7424





Dilution Factor: 4

s*

CAS NO. COMPOUND


UG/L Q

156-60-5 trans-1,2-Dichloroethene 0.0530

FORM I VGA Rev. 10/99- 4 0 -

002302

I

i


EPA SAMPLE NO.

DM1T24RRELab Name: CH2MHILLASL Contract: 168667.DA.F1.04

Lab Code: CVO Case No.: 7424 SAS No.: 052102 SDG No.: 7424








Dilution Factor: 4

I-•i.:i"• ^

I

• -i

I

I


UG/L

156-60-5 trans-1.2-Dichloroethene 0.0180

I•••iw

1FORM I VGA

-41-Rev. 10/99

002303

asl5»



EPA SAMPLE NO.

DM1T24POST

Lab Code: CVO Case No.: 7424 SASNo.: 052102 SDG No.: 7424








Dilution Factor 1

CAS NO. COMPOUND


UG/L Q

I 156-60-5 trans-1,2-Dichloroethene 0.0041 U

FORM I VOA Rev. 10/99- 4 3 -

002304

TO-14A

-2-

002305

11•

1

111MB

I•

1

1

1

1

1

CASE NARRATIVEVOLATILE ORGANIC ANALYSIS

CLIENT/PROJECT: Fruit Avenue Plume Superfund

LABORATORY: CH2M HILL Applied Sciences Lab

LAB CODE: CVO

I. RECEIPT

A. Date: May 14, 2002

B. Sample Information

ANALYTICAL METHOD: TO-14A

PROJECT NO.: 168667.DAJ1.04

LAB BATCH NO.: 7424

_

LAB CLIENT CANISTER SAMPLE DATE TIME RECEIVEDSAMPLE ID SAMPLE ID ID MATRI

742401 DM1T1PRE 578 Air742402 DM1T4PRE 652 Air742403 DM1T24RRE 425 Air742404 DM1T24POST 647 Air

n. Holding Times: /All holding times were met

ffl. Analysis:

A. Calibration: /'All acceptance criteria were met '

B. Blanks: /All acceptance criteria were met

C. Duplicate Samplefs): /All acceptance criteria were met

D. Instrument Performance Check: JAll acceptance criteria were met

E. Surrogate Recoveries:

X SAMPLED SAMPLED PRESS.

05/09/2002 9:00 70605/09/2002 12:00 65605/10/2002 8:00 70505/10/2002 8:00 690

ftorr}

Bromofluorobenzene recoveries were outside of acceptance limits in samples 742401, 742402,742403, 742401R, 742402R, 742403R and 742403D due to matrix interference. Samples were 'analyzed at different dilutions and both sets of results

F. Internal Standards: /All acceptance criteria were met *

G. Laboratory Control Sample (LCS) /• ' ' " * • • - • i i . . f i •* im -I ii* <J

All acceptance criteria were met

H. Matrix Spike{MSYMatrix Spike DuplicatefMSD")Not applicable.

-3-

have been reported.

002306

I. Analytical Exception:None.

J. Other:The unresolved complex matrix results (UCM) were calculated by summing the area under theUCM and using a response factor of 1. This ppbv value was converted to ug/L using an estimatedaverage molecular weight of 135.

IV. Sampling Equipment Exceptions:None.

V. Documentation Exceptions:None -

VI. I certify that mis data package is in compliance with the terms and conditions agreed to by the client and CH2MHELL, both technically and for completeness, except for the conditions detailed above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designee, as verifiedby the following signature.

SIGNED: ' ^t-*~y-^ U0 6<X- 6<3 DATE:Ginger CollinsAnalytical Chemist

- 4 -

002307

-I

SAMPLE DATASUMMARY

-6 -

002308

1I Lab

Lab

• Matr

Leve

• GC

1

1

1

1

1

1

1

1

1

1

1

1

1

1_ FOR

VOL

Name: CH2M HILL

Code: CVO

1A EPA SAMPLE NO.

DM1T24RREDUPASL Contract: 168667.DA.F1.04

Case No.: 7424 SASNo.: 051702 SDGNo.: 7424

ix: (air/soil/water) Air Lab Sample ID: 742403D

»l: (low/med) LOW Lab File ID: 742403D.D

Column: DB-VRX

CAS NO.

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

MIVOA

ID: 0.25 (mm) Date Received: 05/14/02


Dilution Factor: 4


COMPOUND. UG/L Q

Vinyl chloride 0.0102 U1,1-Dichloroethane 0.0161 Ucis-1 ,2-Dichloroethene 0.09371.2-Dichloroethane 0.0161 UBenzene 0.0127 UTrichloroethene 0.161Toluene 0.0288Tetrachloroethene 1.80 /Ethylbenzene 0.0157 J /m.p-Xylenes 0.0554o-Xylene 0.0130 J1 ,3,5-Trimethylbenzene 0.6561 ,2,4-Trimethvlbenzene 1 .011 ,3-Dichlorobenzene 0.0239 U1 ,4-Dichlorobenzene 0.0239 U1 ,2-Dichlorobenzene 0.0239 U1 ,2,4-Trichlorobenzene 0.0295 U

Rev. 10/99-13- .

002309

I



Lab Code: CVO

EPA SAMPLE

B4_0517

Case No.: 7424 SAS No.: 051702 SDG No.: 7424

NO. |

I•

Matrix: (air/soil/water) Air Lab Sample ID: B4_0517 |

Level: (low/med) LOW Lab File ID:

GC Column: DB-VRX

B4 051 7.D

ID: 0.25 (mm) Date Received: NA


Dilution Factor: 1

CAS NO.

75-01-475-34-3


COMPOUND UG/L Q

Vinyl chloride1,1-Dichloroethane

0.0026 U0.0041 U

•

1

1

1

175-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem.p-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethvlbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00260.00410.00400.00410.00320.00550.00380.00690.00440.00880.00440.00500.00500.00610.00610.00610.0075

UUUUUUUUUUUUUUUUU

I

•«*)

ST!

FORM I VGA-15 -

Rev. 10/99

002310

!



EPA SAMPLE NO.

B1JJ521





Lab Sample ID: B1_0521

Lab File ID: B1_0521.D

Date Received: NA


Dilution Factor 1

•!

I•£;H

1


UG/L Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6£41-73-1106-46-795-50-1120-82-1

Vinvl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.p-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00260.00410.00400.00410.00320.00550.00380.00690.00440.00880.00440.00500.00500.00610.00610.00610.0075

UUUUUUUUUUUUUUUUU

FORM I VOA-18-

Rev. 10/99

002311

Lab Name:

Lab Code:


CH2M HILL ASL Contract: 168667.DA.F1.04

EPA SAMPLE NO.

B1_0523

CVO Case No.: 7424




SAS No.: 051702 SDG No.: 7424



Date Received: NA


Dilution Factor: 1

CAS NO. COMPOUND


UG/L

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.p-Xvleneso-Xvlene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00260.00410.00400.00410.00320.00550.00380.00690.00440.00880.00440.00500.00500.00610.00610.00610.0075

UUUUUUUUUUUUUUUUU

J

FORM I VOA-17-

Rev. 10/99

002312

QC SUMMARY

002313

II

^

Lab Name:

Lab Code:

2AVOLATILE SYSTEM MONITORING COMPOUND RECOVERY

CH2MHILLASL Contract: 168667.DA.F1.04


I

01020304050607080910111213

EPA

SAMPLE NO.B4_0517

B1_0521

BS1A0521DM1T4PRE

DM1T24RRE

DM1T1PRE

BS1A0523

B1_0523DM1T24POST

DM1T1PRERDM1T4PRERDM1T24RRER

DM1T24RREDUP

SMC1

#

98999898

10097

1011009999

100101"102

SMC2

#

9295

100f67)^67)(64)10197

102(60>(59)(64)CB3i

TOT

OUT

0001110001111

I SMC1SMC2

Toluene-d8Bromofluorobenzene

QC LIMITS(70-130)(70-130)

I; i

II

# Column to be used to flag recovery values* Values outside of contract required QC limitsD System Monitoring Compound diluted out

FORM II VOA-1 Rev. 10/99

-19-

002314

DUPLICATESVOLATILE ORGANIC ANALYSIS

Lab Name: Applied Sciences LaboratoryLab Code: CVOLab File ID: C:\HPCHEM\1\DATA\052302G1\742403R2.D

Lab File ID: C:\HPCHEM\1\DATA\052302G1\742403DJ>

Instrument ID: GOD7TT.T,A

GC Column: DB-VRX 0.25mm x 60 meters

Project No.: 168667.DAJ1.04

Lab Batch No.: 7424



Concentration Units: ppbv

ANALYTE

Vinyl chloride1 , 1 -Dichloroethenecis- 1 -Dichloroethene1,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem,p-Xyleneso-Xylene1,3,5-Trimetb.ylbenzene1,2,4-Trimethylbenzene1 3-Dichlorobenzene1,4-Dichlorobenzene1 ,2-Dichlorobenzene1,2,4-Trichlorobenzene

CONTROLLIMIT

±30±30±30±30±30±30±30±30±30±30±30±30±30±30±30±30±30

SAMPLE

3.9 U3.9 U

22.63.9 U3.9 U

29.57.22603.6 J

13.03.1 J1332073.9 U3.9 U3.9 U3.9 U

DUPLICATE

3.9 U3.9 U

23.23.9 U3.9 U

29.57.52613.6 J

12.62.9 J1312033.9 U3.9 U3.9 U3.9 U

RPD(%)

—2.6

——

0.04.10.40.03.16.71.52.0

—-

—-

J

- 2 0 -

002315

I 4AVOLATILE METHOD BLANK SUMMARY


EPA SAMPLE NO.

B4JJ517

Lab Code: CVO





GC Column: DB-VRX ID: 0.25


(mm) Heated Purge: (Y/N) N

Instrument ID: GC/MS-G

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

010203040506

EPASAMPLE NO.

1 PPBV STD5 PPBV STD10 PPBV STD20 PPBV STD50 PPBV STD100 PPBV STD

LABSAMPLE ID

LEVEL1LEVEL2LEVELSLEVEL4LEVELSLEVELS

LAB -

FILE ID

LEVEL1.DLEVEL2.DLEVEL3.DLEVEL4.DLEVEL5.DLEVEL6.D

TIMEANALYZED

12:2513:0815:1416:3617:2318:05

\&"'•»I

IICOMMENTS:

FORM IV VOA-21-

Rev. 10/99

002316

4AVOLATILE METHOD BLANK SUMMARY


EPA SAMPLE NO.

B1JJ521

Lab Code: CVO










0102030405

EPA

SAMPLE NO.

CV1_0521

BS1A0521

DM1T4PRE

DM1T24RRE

DM1T1PRE

LAB

SAMPLE ID

CV1 0521BS1A0521742402742403742401

LAB

FILE ID

CV1 0521 .DBS1A0521.D742402.D742403.D742401 R.D

TIME

ANALYZED

13:3314:1515:3716:2217:01

COMMENTS:

FORM IVVOA- 2 2 -

. Rev. 10/99

002317



EPA SAMPLE NO.

B1JJ523

Lab Code: CVO

Lab File ID: B10523.D









01020304050607

EPA

SAMPLE NO.

CV1_0523

BS1A0523

DM1T24POST

DM1T1PRER

DM1T4PRER

DM1T24RRER

DM1T24RREDUP

LAB

SAMPLE ID

CV1 0523BS1A0523742404742401 R742402R742403R742403D

LAB "

FILE ID

CV1 0523.DBS1A0523.D742404R2.D742401 R2.D742402R2.D742403R2.D742403D.D

TIME

ANALYZED

08:3010:3414:4516:0916:4818:1118:54

i2*3i

i

COMMENTS:

FORMIVVOA-23 -

Rev. 10/99

002318

5AVOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK

BROMOFLUOROBENZENE (BFB)


Lab Code: CVO

Lab File ID: T1_0517.D



BFB Injection Date: 05/17/02



BFB Injection Time: 12:25


m/e

50

75

95

96

173

174

175

176177

ION ABUNDANCE CRITERIA

15.0 -40.0% of mass 95 "

30.0 - 60.0% of mass 95

Base peak, 100% relative abundance

5.0 - 9.0% of mass 95

Less than 2.0% of mass 174

50.0 -100.0% of mass 955.0 - 9.0% of mass 174 :

95.0 -101.0% of mass 1745.0 - 9.0% of mass 176

% RELATIVE

ABUNDANCE

17.9

44.3

100.0

6.5

0.0

75.1

8.0

100.06.5

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

01020304050607

EPA

SAMPLE NO.1 PPBV STD

5 PPBV STD

10 PPBV STD

20 PPBV STD

50 PPBV STD

100 PPBV STD

B4_0517

LAB

SAMPLE ID

LEVEL1LEVEL2LEVELSLEVEL4LEVELSLEVEL6B4 0517

LAB

FILE ID

LEVEL1 .DLEVEL2.DLEVEL3.DLEVEL4.DLEVEL5.DLEVEL6.DB4 0517.D

DATEANALYZED

05/17/0205/17/0205/17/0205/17/0205/17/0205/17/0205/17/02

TIMEANALYZED

12:2513:0815:1416:3617:2318:0519:29

V

FORMVVOA Rev. 10/99

- 24 -

002319

IIIIIIIIIIIiiiiiiii




Lab Code: CVO

Lab File ID;


T1 0521 .D






m/e

50

75

95

96

173

174

175

176

177


15.0 -40.0% of mass 95

30.0 - 60.0% of mass 95


5.0 - 9.0% of mass 95


50.0 - 1 00.0% of mass 95

5.0 - 9.0% of mass 1 74

95.0 - 101.0% of mass 174

5.0 - 9.0% of mass 176

% RELATIVE

ABUNDANCE

18.2

43.5

100.0

7.0

0.0

74.7

8.3

97.8

5.9


010203040506

EPA

SAMPLE NO.B1_0521I

CV1_0521

BS1A0521

DM1T4PRE

DM1T24RRE .

DM1T1PRE

LAB

SAMPLE IDB1 0521CV1 0521BS1A0521742402742403742401

LAB

FILE ID

B1 0521 .DCV1 0521 .DBS1A0521.D742402. D742403.D742401 R.D

DATE

ANALYZED05/21/0205/21/0205/21/0205/21/0205/21/0205/21/02

TIME

ANALYZED08:3713:3314:1515:3716:2217:01

'\

FORM V VOA Rev. 10/99

- 2 5 -

002320

v-ti

5AVOLATILE ORGANIC INSTRUMENT.PERFORMANCE CHECK



Lab Code: CVO

Lab Rle ID: T1_0523.D








m/e

50

75

95

96

173

174

175

176177


15.0 -40.0% of mass 95

30.0 - 60.0% of mass 95


5.0 - 9.0% of mass 95


50.0 -100.0% of mass 955.0 - 9.0% of mass 174

95.0 -101.0% of mass 1745.0 -9.0% of mass 176

% RELATIVE

ABUNDANCE

16.6

46.5

100.0

6.3

0.0

69.8

6.4

99.7

7.5


0102030405060708

EPA

SAMPLE NO.CV1_0523

BS1A0523

B1_0523

DM1T24POST

DM1T1PRER

DM1T4PREH

DM1T24RRER

DM1T24RREDUP

LAB

SAMPLE ID

CV1 0523BS1A0523B1 0523742404742401 R742402R742403R742403D

LAB

FILE IDCV1 0523. DBS1A0523.DB1 0523.D742404R2.D742401 R2.D742402R2.D742403R2.D742403D.D

DATEANALYZED

05/23/0205/23/0205/23/0205/23/0205/23/0205/23/0205/23/0205/23/02

TIME

ANALYZED

08:3010:3411:5614:4516:0916:4818:1118:54

FORM V VOA Rev. 10/99

- 2 6 -

002321

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA

II.t.

Lab Name: CH2MHILLASL

Lab Code:


CVO



Heated Purge (Y/N):

GC Column: DB-VRX

N

ID: 0.25

Calibration Date(s):

Calibration Times:

(mm)

05/17/02 05/17/02

12:25 18:05

LAB RLE ID: RRF1 = LEVEL1.D RRF2 = LEVEL2.D RRF3 = LEVEL3.DRRF4 = LEVEL4.D RRF5 = LEVEL5.D RRF6 = LEVEL6.D

COMPOUND

Vinvl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DiehloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.D-Xvleneso-Xvlene1 ,3.5-Trimethylbenzene1 ,2.4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneToluene-d8Bromofluorobenzene

RRF1

0.7421.1520.8860.8292.2580.2440.6460.1100.8910.7310.7600.9130.9220.6330.7140.6340.4800.8680.170

RRF2

0.8801.4261.0971.1002.7750.3020.8110.1271.1840.9350.9661.1241.1220.7700.7960.7240.4950.8830.171

RRF30.8781.4761.1141.1212.7570.3050.8180.1241.2040.9370.9521.1591.1490.7770.7930.7370.4570.8800.174

RRF4-

0.9651.6271.2121.2183.0070.3290.8570.1291.2380.9450.9621.1081.0910.7350.7460.6790.3820.8920.175

RRF50.8521.5491.1521.1752.8440.3070.8060.1171.1910.8820.8811.1631.1620.8220.8320.8030.6220.8870.181

RRF60.8131.4781.1091.1132.5950.2890.7750.1081.1010.7790.7671.0371.0330.7040.7040.6670.5170.9000.184

RRF

0.8551.4511.0951.0932.7060.2960.7850.1191.1350.8680.8811.0841.0800.7400.7640.7070.4920.8850.176

%RSD

8.711.210.112.59.59.79.37.2

11.310.610.98.88.48.96.68.5

16.01.23.2

II

FORM VI VGA- 27 -

Rev. 10/99

002322

AFCEEORGANICS ANALYSES DATA SHEET 7

LABORATORY CONTROL SAMPLE

Analytical Method: TO-14A


Lab Sample ID: BS1A0521


SDGNo.: 7424


Initial Calibration ID: 051702G1

Analyte

Vinvl chloride1.1-Dtehloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.D-Xyleneso-Xvlene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2.4-Trichlorobenzene

Expected

2020202020202020204020202020202020

Found

21.621.721.321.821.421.421.520.722.144.021.921.320.819.819.519.015.0

%R

108' 109

10710910710710810411111010910610499979575

Limits70 - 13070-13070-13070-13070-13070-13070-13070-13070 - 13070 - 13070 - 13070- 13070 - 13070- 13070-13070-13070-130

Qualifier

SurrogateToluene-d8Bromofluorobenzene

%REC98%100%

Control Limits75-12575-125

Qualifier

AFCEE FORM O-7 - 2 8 - Rev. 10/99

002323

i

•h.*>T.lj *

I







SDGNo.: 7424

Contract: 168667. DA. F1.04


AinalyteVinyl chloride1,1 -Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.p-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

Expected2020202020202020204020202020202020

Found22.222.9 '22.622.122.920.521.419.521.342.721.120.320.218.718.118.215.1

%R

1111141131111151021079810610710610210194909175

Limits70-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-130

Qualifier

SurroqateToluene-d8Bromofluorobenzene

%REC101%101%


Qualifier

•*:i!

I

:• "-4

AFCEE FORM O-7 - 2 9 - Rev. 10/99

002324


Lab Code:


Contract: 168667. DA. F 1.04




Heated Purge: (Y/N)

GC Column: DB-VRX

N

Calibration Date: 05/21/02

Init. Calib. Date(s): 05/17/02

Init. Calib. Times: 12:25

Time: 13:33

ID: 0.25 (mm)

COMPOUND

Vinyl chloride1 ,1 -Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem.p-Xyleneso-Xylene1 ,3,5-Trimethvlbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneToluene-d8Bromofluorobenzene

RRF

0.8551.4511.0951.0932.7060.2960.7850.1191.1350.8680.8811.0841.0800.7400.7640.7070.4920.8850.176

RRF4

0.8971.5471.1561.1692.9180.3180.8420.1261.2240.9310.9471.1261.1090.7450.7640.6780.3560.8850.175

%D

= -4.9-6.6-5.6-7.0-7.8-7.4-7.2-5.6-7.9-7.2-7.5-3.9-2.8-0.70.04.2

27.80.00.8

MAX%D

30303030303030303030303030303030303030

05/17/02

18:05

FORM VIIVOA- 3 0 -

Rev. 10/99

002325

I

•J__

=nI



Lab Code:


CVO







Init. Calib. Date(s): 05/17/02


Time: 08:30

(mm)

COMPOUND

Vinyl chloride1,1-Dtehloroethanecis-1 ,2-Dichloroethene1 ,2-Dichloroethane :

BenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.D-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneToluene-d8Bromofluorobenzene

RRF

0.8551.4511.0951.0932.7060.2960.7850.1191.1350.8680.8811.0841.0800.7400.7640.7070.4920.8850.176

RRF4

0.9061.7401.3091.2633.3020.3190.8660.1231.3141.0091.0301.1991.1820.7720.7770.7130.4390.8900.175

%D

- -5.9-19.9-19.6-15.6-22.0-7.7

-10.3-3.0

-15.8-16.2-16.8-10.6-9.5-4.3-1.7-0.810.8-0.60.5

MAX%D

30303030303030303030303030303030303030

05/17/02

18:05

FORM VIIVOA-31-

Rev. 10/99

002326



Lab Code:



Lab File ID (Standard): LEVEL4.D






01

02

24 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLE

NO.

B4_0517

B1JJ521

IS1

AREA #

40612

56857

24367

42262

37422

RT #

13.55

14.05

13.05

13.54

13.56

IS2

AREA #

179874

251824

107924

188594

169380

RT #

15.99

16.49

15.49

15.99

16.00

IS3

AREA #

52299

73219

31379

54291

48490

RT #

20.46

20.96

19.96

20.47

20.47

-I-!

151 = Bromochloromethane152 = 1,4-DifIuorobenzene153 = Chlorobenzene-d5

AREA UPPER LIMIT = +40% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIMIT = +0.50 minutes of internal standard RTRT LOWER LIMIT = -0.50 minutes of internal standard RT

# Column to be used to flag values outside QC limit with an asterisk.* Values outside of contract required QC limits

FORM VIIIVOA-32-

Rev. 10/99

002327


IIIIIIIIiIIII


Lab Code:

Contract: 168667JDA.F1.04


Lab File ID (Standard): CV1_0521.D






01

02

03

04

24 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLE

NO.

BS1A0521

DM1T4PRE

DM1T24RRE

DM1T1PRE

IS1

AREA #

39487

55282

23692

40446

40967

47400

49555

RT #

13.54

14.04

13.04

13.54

13.53

13.53

13.54

IS2

AREA #

171550

240170

102930

178017

177510

209250

223285

RT #

15.99

16.49

15.49

15.99

15.98

15.99

15.99

IS3

AREA #

50675

70945

30405

50446

43458

55950

53737

RT #

20.46

20.96

19.96

20.46

20.46

20.46

20.47

151 = Bromochloromethane .-152 = 1,4-Difluorobenzene153 - Chlorobenzene-d5

AREA UPPER LIMIT = 440% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIMIT = +0.50 minutes of internal standard RTRT LOWER LIMIT = -0.50 minutes of internal standard RT


FORM VIII VGA-33-

Rev. 10/99

002328

8AVOLATILE INTERNAL STANDARD. AREA AND RT SUMMARY


Lab Code:

Contract: 168667. DA.F1.04








0102030405

0607

24 HOUR STDUPPER LIMITLOWER LIMIT

EPA SAMPLENO.

BS1A0523

B1.0523

DM1T24POST

DM1T1PRER

DM1T4PRER

DM1T24RRER

DM1T24RREDUP

IS1

AREA #

407895710524473

41307

415634352843610472734624646396

RT *

13.5614.0613.06

13.5513.5313.5513.5513.5313.5413.54

IS2AREA #

191968268755115181

195547187165201207197056218271209127213280

RT #

16.01

16.5115.51

15.9915.9815.9916.0015.9815.9915.99

IS3AREA #

532997461931979

56061536055626341520490635091852875

RT #

20.4720.9719.97

20.4620.4620.4620.4620.4620.4720.46

151 = Bromochloromethane152 = 1,4-Difluorobenzene153 = Chlorobenzene-d5

AREA UPPER LIMIT = +40% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIMIT = +0.50 minutes of internal standard RTRT LOWER LIMIT = -0.50 minutes of internal standard RT


FORM VIII VOA-34-

Rev. 10/99

002329

Trans-l,2-Dichloroethene by TO-14A

- 3 5 -

002330

IIIIIIIIIIiIII1IIII

CASE NARRATIVETrans-l^-Dichloroethene

CLIENT/PROJECT: Fruit Avenue Plume Superfund

LABORATORY: CH2M HILL Applied Sciences Lab

LAB CODE: CVO

ANALYTICAL METHOD: TO-14A

PROJECT NO.: 168667J5AJ1.04

LAB BATCH NO.: 7424

I.

n.

ra.

RECEIPTA. Date: May 14,2002


LAB

742401742402742403742404

CLIENTRLE:

DM1T1PREDM1T4PRE

DM1T24RREDM1T24POST

CANISTER

578652425647

SAMPLEMATRIX

AirAirAirAir

DATE TIME RECEIVEDSAMPLED SAMPLED PRESS, (torr)

05/09/200205/09/200205/10/200205/10/2002

9:0012:008:008:00

706656705690

Holding Times:All holding times were met

A. Calibration:All acceptance criteria were met

B. Blanks:All acceptance criteria were met

C.

D.

E.

F.

G.

H.

Duplicate Sample(s):All acceptance criteria were met /

Instrument Performance Check:All acceptance criteria were met

Surrogate Recoveries:Bromofluorobenzene recoveries were outside of acceptance limits in samples 742401,742402 and742403 due to matrix interference.

Internal Standards:All acceptance criteria were met. '

Laboratory Control Sample (LCS)All acceptance criteria were met /

Matrix Spike(MSVMatrix Spike DuplicateCMSD')Not applicable.

-36-

002331


J. Other:None


V. Documentation Exceptions:None

VI. I certify that this data package is in compliance with the terms and conditions-agreed to by the client and CH2MHILL, both technically and for completeness, except for the conditions detailed above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designee, as verifiedby the following signature.

SIGNED:Collins

Analytical Chemist

- 37 -

002332

IIiIiiiii

I

I

I

I

iiii

SAMPLE DATASUMMARY

- 3 8 -

002333

002334

i

i



EPA SAMPLE NO.

DM1T24RREDUP





SASNo.: 052102 SDG No.: 7424

Lab Sample ID: 742403D

Lab File ID: 742403D.D



Dilution Factor: 4

iCAS NO. COMPOUND


UG/L Q

M56-60-5 I trans-1,2-Dichloroethene I 0.0178

I-.:«

r-H

i

FORM I VOA Rev. 10/99- 4 2 -

002335

'y'iV>3

:i:~.

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

B1_0521Lab Name: CH2MHILLASL Contract: 168667.DA.F1.04


Matrix: (air/soil/water) Air Lab Sample ID: B1_0521

Level: (low/med) LOW Lab File ID: B1_0521.D

GC Column: DB-VRX ID: 0.25 (mm) Date Received: NA


Dilution Factor: 1

^ CONCENTRATION UNITS:

1 CAS NO. COMPOUND UG/L

156-60J5 I trans-1,2-Dichloroethene | 0.0047 ~u~~~r

^ FORMIVOA Rev. 10/99:-:J - 4 4 -

002336

I



EPA SAMPLE NO.

B1JJ523





SASNo.: 052102 SDG No.: 7424



Date Received: NA


Dilution Factor: 1

CAS NO. COMPOUND

CONCENTRATION UNITS:UG/L

156-60-5 trans-1,2-Dichloroethene 0.0047

I

IFORM IVOA Rev. 10/99

-45 -

002337

IIIIII1III QC SUMMARY

I

I

I

II

I

I

002338

IIIIIIIIIIIIIIIIIII




0102030405060708

EPA

SAMPLE NO.B1.0521BS2A0523

B1_0523DM1T24POST

DM1T1PREDM1T4PREDM1T24RREDM1T24RREDUP

SMC1

#

99101102102103103103105

SMC2

#

95105105110r pp*&>)<S6):

(&')

TOTOUT

00001111

SMC1SMC2


QC LIMITS(70-130)(70-130)

# Column to be used to flag recovery values

* Values outside of contract required QC limits

D System Monitoring Compound diluted out


- 4 7 -

002339

DUPLICATESVOLATILE ORGANIC ANALYSIS

Lab Name: Applied Sciences Laboratory

Lab Code: CVO

Lab File E): C:\HPCHEM\1\DATA\052302G1\742403R2 J>

Lab File ID: C:\HPCHEM\1\DATA\OS2302G1\742403DD

Instrument ID: GODZILLA

GC Column: DB-VRX 0.25mm x 60 meters

Project No.: 168667DA.F1.04

Lab Batch No.: 7424




ANALYTE

trans-l^-Dichloroethene

CONTROLLIMIT

±30

SAMPLE

4.5 J

DUPLICATE

4.4 J

RPD(%)

2.2

- 4 8 -

002340

I

IIII11IIII



EPA SAMPLE NO.

B1 0523

Lab Code: CVO



Lab Sample ID: B1 0523







010203040506

EPA

SAMPLE NO.

BS2A0523

DM1T24POST

DM1T1PRE

DM1T4PRE

OM1T24RRE

DM1T24RREDUP

LAB

SAMPLE ID

BS2A0523742404742401742402742403742403D

LAB

FILE ID

BS2A0523.D742404R2.D742401 R2.D742402R2.D742403R2.D742403D.D

: TIME

ANALYZED

11:1614:4516:0916:4818:1118:54

. COMMENTS:

FORM IV VGA Rev. 10/99

002341

a




Lab Code: CVO

Lab File ID:


T1_0521.D






m/e

50759596

173174

175176177


15.0 -40.0% of mass 9530.0 - 60.0% of mass 95

Base peak, 100% relative abundance5.0 - 9.0% of mass 95Less than 2.0% of. mass 17450.0 - 1 00.0% of mass 955.0 -9.0% of mass 17495.0 -101.0% of mass 1745.0 -9.0% of mass 176

% RELATIVEABUNDANCE

18.2

43.5100.0

7.00.0

74.78.3

97.85.9


010203040506

EPA

SAMPLE NO.1.2 PPBV STD

5.8 PPBV STD

11 PPBV STD

23 PPBV STD

58 PPBV STD

116 PPBV STD

LAB

SAMPLE IDLEVEL1LEVEL2LEVELSLEVEL4LEVELSLEVEL6

LABFILE ID


DATEANALYZED

05/21/0205/21/0205/21/0205/21/0205/21/0205/21/02

TIMEANALYZED

09:1910:0110:4411:2712:0912:51

FORM V VGA

- 5 0 -

Rev. 10/99

002342

IIIIIIIIIIIIIIIIIII




Lab Code: CVO

Lab File ID:


T1JD523.D






m/e

507595

96173174

175176177


15.0 -40.0% of mass 9530.0 - 60.0% of mass 95Base peak, 100% relative abundance

5.0 - 9.0% of mass 95Less than 2.0% of mass 1 7450.0 - 100.0% of mass 955.0 -9.0% of mass 17495.0 -101.0% of mass 174

5.0 - 9.0% of mass 1 76

% RELATIVEABUNDANCE

16.646.5

100.0

6.30.0

69.86.4

99.7

7.5


0102030405060708

EPASAMPLE NO.

CV3_OS23

BS2AOS23

B1_0523

DM1T24POST

DM1T1PRE

DM1T4PRE

DM1T24RRE

DM1T24RREDUP

LABSAMPLE ID

CVS 0523BS2A0523B1 0523742404742401742402742403742403D

LABFILE ID

CV3 0523.DBS2A0523.DB1 0523.D742404R2.D742401 R2.D742402R2.D742403R2.D742403D.D

DATEANALYZED

05/23/0205/23/0205/23/0205/23/0205/23/0205/23/0205/23/0205/23/02

TIMEANALYZED

09:5111:1611:5614:4516:0916:4818:1118:54

FORM VVOA Rev. 10/99

-51-

002343

1


Lab Name:

Lab Code:




Heated Purge (Y/N):

GC Column: DB-VRX

N

ID: 0.25


Calibration Times:

(mm)

05/21/02 05/21/02

09:19 12:51

LAB FILE ID: RRF1 = LEVEL! .D RRF2 = LEVEL2.D RRF3 = LEVEL3.D

RRF4 = LEVEL4.D RRF5 = LEVEL5.D RRF6 = LEVEL6.D

COMPOUND

trans-1 ,2-DichloroetheneToluene-d8Bromofluorobenzene

RRF1

0.6650.8720.164

RRF2

0.8720.8740.165

RRF3

0.8880.8540.164

RRF4 "

1.0500.8680.164

RRF5

1.1310.8550.161

RRF6

1.0560.8510.159

RRF

0.9440.8620.163

%RSD

18.01.21.4

FORM VI VGA- 5 2 -

Rev. 10/99

002344

IIIIIIIIIIIIIiIiii

AFCEEORQANICS ANALYSES DATA SHEET 7






SDGNo.: 7424



Analytetrans- 1 ,2-Dichloroethene

SurroqateToluene-d8Bromofluorobenzene

Expected23.3

Found

24.5

%REC101%105%

%R

_ 105

i Control Limits75-12575-125

Limits70-130

Qualifier

Qualifier

/i/

AFCEE FORM O-7 - 5 3 - Rev. 10/99002345

IIIIIIIIIIIIIIIIIII

CH2M HILL

Applied Science* Group

2300 NW Walnut Blvd

CorvaHliOR

97330-3538

P.O. Box 428

Ccxvallls. OR

9733WJ428

Tel 641.762.4271

Fax 541.752.0276

CH2MHILLApplied Sciences Group

May 31,2002

Fruit Avenue Plume Superfund

168667.DA.FL04

RE: Laboratory Report for Fruit Avenue Plume SuperfundApplied Sciences Group Reference No. 7425

RickDobbins/GNV:

On May 14, 2002, CH2M HILL Applied Sciences Group received three samples with arequest for analysis of selected parameters. All analyses were performed by CH2M HELLunless otherwise indicated below.

The analytical results and associated quality control data are enclosed. Any unusualdifficulties encountered during the analysis of your samples are discussed in the casenarrative.

CH2M HELL Applied Sciences Group appreciates your business and looks forward toserving your analytical needs again. If you should have any questions concerning the data, orif you need additional information, please call Ms. Kathy McKinley at (541) 758-0235,extension 3120.

Sincerely,.

Ginger CollinsLaboratory Representative

Enclosures

cc:John Ynfante/HOU

OR100022

PAGE1 of*/4

002346

1111111111111111111

CH2M HILL Applied Sciences Laboratory

Client Information Lab InformationProject Name: Fruit Avenue Plume Superfund Date Rec'd:

Project Manager Rick Dobbins/GNV Batch ID:Sampled By: W. LeFEURE Method:

Sampling Date: 05/21/99 Report Revision No.:Sampling Time: See Cross-reference Reported By:

Type: Integrated Reviewed By:Matrix: Air Units:

Unresolved ComplexSample

Client ID Lab ID Result

SF2T-1Pre 742501 38.9SF2T-17Pre 742502 107SF2T-17Post 742503 2.67

U=Not detected at specified reporting limits

CH2MHILLApptedSdoncoaGmup .

05/14/20027425TO-140GMC

<&rug/L

MatrixDate

Qualifier Analyzed

J 5/23/2002J 5/23/2002J 5/23/2002

$*h2300NWWOnut8l«l. CorvofcOR 97330-353.

P.O. Box 428. Covcfc OR 97339442:TelS41.7S2.4Sff! KK541.7SZ027

002347



EPA SAMPLE NO.

SF2T-1Pre





SASNo.: 051702 SDG No.: 7425


Lab File ID: 742501 R.D



Dilution Factor 2

CAS NO. COMPOUND


UG/L Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem.p-Xyleneso-Xylene \\~-^:1 ,3,5-Trimethylbenzene ^T- S» "5>1 ,2,4-Trimethylbenzene 3"- S*51 ,3-Dichlorobenzene UT- 6>S1 ,4-Dichlorobenzene U~T- ^1 ,2-Dichlorobenzene V3~- s» ?1 ,2,4-Trichlorobenzene UJ -S

•&9048 —-0^976 —

Q.0076 —

A n - ..

"VA/U/ /

• 0.290 —-4fc6081-0^08€ —

* /"OTOOBT/ 0.0180

0.05020.0112

» 0.0112> 0.0112S V 0.0138

- — tr~— y-

u

— tr—l— i

-u-

—-y--y--u~«-

8-

FORM I VOA-7 -

Rev. 10/99

002348

I

•

1

1

1

1

1

1

1

1

1

1

1

1

1

1•



EPA SAMPLE NO.

SF2T-1PreR






Lab File ID: 742501 R2.D


CAS NO.

FORM IVOA


Dilution Factor: 1

COMPOUND


UG/L

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.p-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00240.00380.00260.00380.00300.04450.00790.274

0.00250.0089

•0,0155 —00366 —

• 0.0056 —

&GG56 —n 0060

UUJUU

J

— y —

— u —u

A-SET

Rev. 10/99

002349



EPA SAMPLE NO.

SF2T-17Pre






Lab File ID: 742502R.D



Dilution Factor 3

CAS NO. COMPOUND


UG/L

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1 ,1 -Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem.p-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene-1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00670.01060.01330.01060.00840.06270.01400.450

0.00650.02430.01140.1820.408

0.01570.01570.01570.0194

UU

UU

J

U

UUUU

FORM I VOA-9-

Rev. 10/99

002350

III•

I!I

I

I

I

I

I

I

I

I

I

I

I

I

I

I



EPA SAMPLE NO.

SF2T-17Post








CAS NO.

FORMIVOA


Dilution Factor: 1

COMPOUNDCONCENTRATION UNITS:

UG/L

-10-

Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzene .TrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.p-Xyleneso-Xvlene1 ,3,5-Trimethvlbenzene1 ,2,4-Trimethvlbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00250.00400.00390.00400.00160.00520.00370.00660.00420.00850.00420.00600.02960.00590.00590.00590.0072

UUUUJUUUUUU

UUUU

Rev. 10/99

002351


SF2T-1PreLab Name: CH2MHILLASL Contract: 168667.DA.F1.04


Matrix: (air/soil/water) Air Lab Sample ID: 742501

Level: (low/med) LOW Lab File ID: 742501 R2.D

GC Column: DB-VRX ID: 0.25 (mm) Date Received: 05/14/02


Dilution Factor: 1


CAS NO. COMPOUND UG/L

156-60-5 I trans-1.2-Dichloroethene I 0.0043 I U

FORMIVOA Rev. 10/99- 28 -

002352

I 1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

I

I

|SF2T-17Prs



• Matrix: (air/soil/water) Air Lab Sample ID: 742502

Level: (low/med) LOW Lab File ID: 742502R.D

• GC Column: DB-VRX ID: 0.25 (mm) Date Received: 05/14/02


Dilution Factor 3

• CONCENTRATION UNITS:

" CAS NO. COMPOUND. UG/L

I 156-60-5 I trans-1.2-Dichloroethene I 0.0120 I U

I FORMIVOA Rev. 10/99-29-

002353

1AVOLATILE ORGANICS ANALYSIS.DATA SHEET


EPA SAMPLE NO.

SF2T-17Post





SAS No.: 052102 SDG No.: 7425





Dilution Factor: 1

CAS NO. COMPOUND


UG/L

156-60-5 I trans-1,2-Dichloroethene 0.0045 U

FORM I VOA- 3 0 -

Rev. 10/99

002354

TO-14A

I

I

I

I -3 -

002355

11I•

11111•

1111I

1

1•

•

1

1

CASE NARRATIVEVOLATILE ORGANIC ANALYSIS

CLIENT/PROJECT: Fruit Avenue Plume Superfund ANALYTICAL METHOD: TO-14A

LABORATORY: CH2M HILL Applied Sciences Lab PROJECT NO.: 168667.DAJF1.04

LAB CODE: CVO LAB BATCH NO.: 7425

I. RECEIPT

A. Date: May 14, 2002


LAB CLIENT CANISTER SAMPLE DATE TIME RECEIVEDSAMPLE ID SAMPT.KTD TO MATRIX SAMPLED SAMPLED PRESS.

742501 SF2T-lPre 649 Air 05/10/2002 18:39 661742502 SF2T-17Pre 639 Air 05/11/2002 10:00 700742503 SF2T-17Post 616 Air 05/11/2002 10:00 630

n. Holding Times:All holding times were met

ffl. Analysis:

A. Calibration:All acceptance criteria were met /

B. Blanks:All acceptance criteria were met t

C. ' Duplicate SampleCs): . . .Duplicate was analyzed on another clients sample in the analytical sequence. All acceptancecriteria were met

D. Instrument Performance Check:All acceptance criteria were met

E. Surrogate Recoveries:

(torr)

Bromofluorobenzene recovery was outside of acceptance limits in sample 742501 due to matrixinterference. The sample was analyzed at a different dilution and both sets of results have beenreported.

F; Internal Standards: /All acceptance criteria were met

G. Laboratory Control Sample (LCS) ./ •All acceptance criteria were met

H. Matrix SpikefMSVMatrix Spike DuplicatefMSD)Not applicable.

. -4-

002356

Analytical Exception:None.

IIIJ. Other:

The unresolved complex matrix results (UCM) were calculated by summing the area under theUCM and using a response factor of 1. This ppbv value was converted to ug/L using an estimatedaverage molecular weight of 135. M


V. Documentation Exceptions: •None -

VI. I certify that this data package is in compliance with the terms and conditions agreed to by the client and CH2M •HELL, both technically and for completeness, except for the conditions detailed above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designee, as verifiedby the following signature. •

SIGNED: '""X^^V-T l^ //s^t^ DATE:Gingejl CollinsAnalytical Chemist

I

I

I

I

-5 -

002357

SAMPLE DATASUMMARY

-6-

002358

IIIIIIIIIIIIIIIIIII



EPA SAMPLE NO.

B4_0517







Date Received: NA

CAS NO.

FORM IVOA


Dilution Factor: 1

COMPOUND.


UG/L

-11-

Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108.67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem.p-Xvleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00260.00410.00400.00410.00320.00550.00380.00690.00440.00880.00440.00500.00500.00610.00610.00610.0075

UUUUUUUUUUUUUUUUU

Rev. 10/99

002359

1A EPA SAMPLE NO.

Lab Name:

Lab Code:

VULAllLCUI-HaANIUS ANALYSIS U/MAsDtlttl

CH2MHILLASL Contract: 168667.DA.F1.04B1JJ523







Date Received: NA


Dilution Factor 1

CAS NO. COMPOUND


UG/L Q

75-01-475-34-3156-59-2107-06-271-43-279-01-6108-88-3127-18-4100-41-41330-20-795-47-6108-67-895-63-6541-73-1106-46-795-50-1120-82-1

Vinyl chloride1,1-Dichloroethanecis-1 ,2-Dichloroethene1,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem,p-Xvleneso-Xyiene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

0.00260.00410.00400.00410.00320.00550.00380.00690.00440.00880.00440.00500.00500.00610.00610.00610.0075

UUUUUUUUUUUUUUUUU

FORM I VOA-12-

Rev. 10/99

002360

IIiIiIi

QC SUMMARY

-13-

002361

I

i

Lab Name:

Lab Code:




01020304050607

EPASAMPLE NO.

B4_0517

BS1A0523

B1.0S23

SF2T-1PRE

SF2T-17POST

SF2T-1PRER

SF2T-17PRE

SMC1

#

981011009998

102102

SMC2#

9210197

V dQ 1^J3w x

100 *70 /72

TOT

OUT0001000

1 SMC1SMC2


QC LIMITS(70-130)(70-130)

I # Column to be used to flag recovery values* Values outside of contract required QC limitsD System Monitoring Compound diluted out


-14-

002362



EPA SAMPLE NO.

B4 0517

Lab Code: CVO

Lab File ID: B4 0517.D








THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES/MS AND MSD:

010203040506

EPA

SAMPLE NO.

1 PPBV STD5 PPBV STD10 PPBV STD20 PPBV STD50 PPBV STD100 PPBV STD

LAB

SAMPLE ID

LEVEL1LEVEL2LEVEL3LEVEL4LEVELSLEVELS

LAB -

FILE ID


TIME

ANALYZED

12:2513:0815:1416:3617:2318:05

'-•-J

COMMENTS:

FORM IV VGA- 1 5 -

Rev. 10/99

002363

IIII

I

IIIIIIIIII

4AVOLATILE METHOD

EPA SAMPLE NO.


Lab Code: CVO

Lab File ID: B10523.D

Contract: 168667.DA.F1.04B1_0523

Case No.: 7425 SASNo.: 051702 SDGNo.: 7425

Lab Sample ID: B1 0523







010203040506

EPA

SAMPLE NO.

CV1_0523BS1A0523SF2T-1PRESF2T-17POST

J3F2T-1PRERSF2T-17PRE

LAB

SAMPLE ID

CV1 0523BS1A0523742501742503742501 R742502

LAB

FILE ID

CV1 0523.DBS1A0523.D742501 R.D742503R2.D742501 R2.D742502R.D

- TIME

ANALYZED

08:3010:3414:0215:2719:3620:19

COMMENTS:

FORMIVVOA Rev. 10/99

002364

ii'

.-"*-':




Lab Code: CVO

Lab File ID:


T1_0517.D






m/e

50

75

95

96

173

174

175

176177


15.0 -40.0% of mass 95 '

30.0 - 60.0% of mass 95


5.0 - 9.0% of mass 95


50.0 -100.0% of mass 95

5.0 - 9.0% of mass 174

95.0 - 101 .0% of mass 174

5.0 - 9.0% of mass 176

% RELATIVE

ABUNDANCE

17.9

44.3

100.0

6.5

0.0

75.1

8.0

100.0

6.5


01020304050607

EPA

SAMPLE NO.1 PPBV STD

5 PPBV STD

10 PPBV STD

20 PPBV STD

50 PPBV .STD

100 PPBV STD

B4_0517

LAB

SAMPLE ID

LEVEL1LEVEL2LEVELSLEVEL4LEVELSLEVEL6B4 0517

LAB

FILE ID

LEVEL! .DLEVEL2.DLEVEL3.DLEVEL4.DLEVEL5.DLEVEL6.DB4 051 7.D

DATE

ANALYZED

05/17/0205/17/0205/17/0205/17/0205/17/0205/17/0205/17/02

TIME

ANALYZED

12:2513:0815:1416:3617:2318:0519:29

1m

!FORM V VGA

-17-

Rev. 10/99

002365

i 5AVOLATILE ORGANIC INSTRUMENT.PERFORMANCE CHECK



Lab Code: CVO

Lai) File ID: T1_0523.D





BFB Injection Date: .05/23/02



m/e

50759596

173174175176177


15.0 -40.0% of mass 95 "30.0 - 60.0% of mass 95Base peak, 100% relative abundance5.0 - 9.0% of mass 95Less than 2.0% of mass 1 7450.0 - 1 00.0% of mass 955.0 - 9.0% of mass 17495.0 - 101.0% of mass 1745.0 - 9.0% of mass 176

% RELATIVE

ABUNDANCE

16.646.5

100.06.30.0

69.86.4

99.77.5


01020304050607

EPASAMPLE NO.

CV1_OS23

BS1A0523

B1_0523

SFZT-1PRE

SF2T-17POST

SF2T-1PRER

SF2T-17PRE

LABSAMPLE ID

CV1_0523BS1A052361^0523742501742503742501 R742502

LABFILE ID

CV1 0523.DBS1A0523.DB1 0523.D742501 R.D742503R2.D742501 R2.D742502R.D

DATEANALYZED

05/23/0205/23/0205/23/0205/23/0205/23/0205/23/0205/23/02

TIMEANALYZED

08:3010:3411:5614:0215:2719:3620:19

I

FORM V VOA

-18-

Rev. 10/99

002366

'••1



Lab Code:


CVO



Heated Purge (Y/N): N


Calibration Times:

05/17/02 05/17/02

12:25 18:05


LAB FILE ID:

COMPOUND



Vinyl chloride1.1-Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem,p-Xyleneso-Xylene1 .3,5-Trimethylbenzene1 ,2.4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneToluene-d8Bromofluorobenzene

RRF1

0.7421.1520.8860.8292.2580.2440.6460.1100.8910.7310.7600.9130.9220.6330.7140.6340.4800.8680.170

RRF2

0.8801.4261.0971.1002.7750.3020.8110.1271.1840.9350.9661.1241.1220.7700.7960.7240.4950.8830.171

RRF3

0.8781.4761.1141.1212.7570.3050.8180.1241.2040.9370.9521.1591.1490.7770.7930.7370.4570.8800.174

RRF4-

0.9651.6271.2121.2183.0070.3290.8570.1291.2380.9450.9621.1081.0910.7350.7460.6790.3820.8920.175

RRF5

0.8521.5491.1521.1752.8440.3070.8060.1171.1910.8820.8811.1631.1620.8220.8320.8030.6220.8870.181

RRF6

0.8131.4781.1091.1132.5950.2890.7750.1081.1010.7790.7671.0371.0330.7040.7040.6670.5170.9000.184

RRF

0.8551.4511.0951.0932.7060.2960.7850.1191.1350.8680.8811.0841.0800.7400.7640.7070.4920.8850.176

RSD

8.711.210.112.59.59.79.37.2

11.310.610.98.88.48.96.68.5

16.01.23.2

FORM VI VGA- 1 9 -

Rev. 10/99

002367

I

i

AFCEE

ORGANICS ANALYSES DATA SHEET 7LABORATORY CONTROL SAMPLE





SDGNo.: 7425



Analyte

Vinyl chloride1 ,1 -Dichloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthvlbenzenem.D-Xyleneso-Xylene1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dtehlorobenzene1 ,2-Dichlorobenzene1 ,2,4-Trichlorobenzene

Expected

2020202020202020204020202020202020

Found

22.2^22.922.622.122.920.521.419.521.342.721.120.320.218.718.118.215.1

%R1111141131111151021079810610710610210194909175

Limits

70-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-13070-130

Qualifier

SurrogateToluene-d8Bromofluoro benzene

%REC101%101%


Qualifier

I

iAFCEE FORM O-7 -20- Rev. 10/99

002368

Lab Name: CH2M HILLASL

Lab Code:



CVO



Lab File ID: CV1 0523.D

Heated Purge: (Y/N)

GC Column: DB-VRX

N


hit. Calib. Date(s): 05/17/02


Time: 08:30

ID: 0.25 (mm)

'•K\

.-y

COMPOUND

Vinvl chloride1.1-Dtehloroethanecis-1 ,2-Dichloroethene1 ,2-DichloroethaneBenzeneTrichloroetheneTolueneTetrachloroetheneEthylbenzenem,D-Xvleneso-Xvlene1 ,3,5-Trimethylbenzene1 .2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneToluene-d8Bromofluorobenzene

RRF

0.8551.4511.0951.0932.7060.2960.7850.1191.1350.8680.8811.0841.0800.7400.7640.7070.4920.8850.176

RRF4

0.9061.7401.3091.2633.3020.3190.8660.1231.3141.0091.0301.1991.1820.7720.7770.7130.4390.8900.175

%D

- -5.9-19.9-19.6-15.6-22.0-7.7

-10.3-3.0

-15.8-16.2-16.8-10.6-9.5-4.3-1.7-0.810.8-0.60.5

MAX%D

30303030303030303030303030303030303030

05/17/02

18:05

1

FORM VII VOA-21-

Rev. 10/99

002369

I

i



Lab Code:



Lab File ID (Standard): LEVEL4.D






01

24 HOUR STDUPPER LIMITLOWER LIMIT

EPA SAMPLENO.

B4J5517

IS1AREA #

406125685724367

42262

RT #

13.55

14.0513.05

13.54

IS2AREA #

179874251824107924

188594

RT #

15.99

16.4915.49

15.99

IS3AREA #

52299

7321931379

54291

RT #

20.4620.9619.96

20.47

I•*:'.'.-i1


: AREA UPPER LIMIT = +40% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIMIT = +0.50 minutes of internal standard RTRT LOWER LIMIT = -0.50 minutes of internal standard RT


FORM VIIIVOA- 2 2 -

Rev. 10/99

002370

i

I'



Lab Code:









01

02

03

04

05

06

24 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLE

NO.

BS1A0523

B1.0523

SF2T-1PRE

SF2T-17POST

SF2T-1PRER

SF2T-17PRE

IS1

AREA #

40789

57105

24473

41307

41563

39917

42025

46330

46579

RT #

13.56

14.06

13.06

13.55

13.53

13.53

13.5313.54

13.54

IS2

AREA #

191968

268755

115181

195547

187165

185105

197771212807

212752

RT #

16.01

16.51

15.51

15.99

15.98

15.99

15.98

15.99

15.99

IS3

AREA #

53299

74619

31979

56061

53605

50646

5528656214

57632

RT #

20.47

20.97

19.97

20.46

20.46

20.46

20.4620.47

20.46

1

i.


AREA UPPER LIMIT = 440% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIMIT = +0.50 minutes of internal standard RTRT LOWER LIMIT = -0.50 minutes of internal standard RT


FORM VIIIVOA- 2 3 -

Rev. 10/99 -

002371

I

I

Trans-l^-Dichloroethene by TO-14A

- 2 4 -

002372

1I•

1CASE NARRATIVE

Trans-l,2-Dichloraethene

CLIENT/PROJECT: Fruit Avenue Plume Superfund ANALYTICAL METHOD: TO-14A

1

1

LABORATORY: CH2M HELL Applied Sciences Lab PROJECT NO.: 168667.DAJF1 .04

LAB CODE: CVO LAB BATCH NO.: 7425

I. RECEIPT

1 A.

B.

Date: May 14, 2002 .

Sample Information

LAB CLIENT CANISTER SAMPLE DATE TIME RECEIVEDSAMPLE ID SAMPLE ID ID MATRIX SAMPLED SAMPLED PRESS, (torr)

I 742501 SF2T-lPre 649 Air 05/10/2002 18:39 661742502 SF2T-17Pre 639 Air 05/11/2002 10:00 700

1'

1

1'

1

1"

1

I

1

1

1

742503 SF2T-17Post 616 Air 05/11/2002 10:00 630

n. Holding Times:All holding times were met / '

El. Analysis:

A.

B.

C.

D.

E.

F.

G.

H.

Calibration:All acceptance criteria were met ''

Blanks:All acceptance criteria were met '•/

Duplicate Samplefs):Duplicate was analyzed on another clients sample in the analytical sequence. All acceptancecriteria were met

Instrument Performance Check: /All acceptance criteria were met

Surrogate Recoveries:Bromofluorobenzene recovery was outside of acceptance limits in sample 742501 due to matrix _interference.

Internal Standards: '%/ •All acceptance criteria were met

Laboratory Control Sample (LCS) ^All acceptance criteria were met

Matrix SpikeflMSVMatrix Spike DuplicatefMSD)Not applicable.

-25-

002373


J. Other:None


V. Documentation Exceptions:None

VI. I certify that this data package is in compliance with the terms and conditions^agreed to by the client and CH2MHILL, both technically and for completeness, except for the conditions detailed above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designee, as verifiedby the following signature.

SIGNED: '\iWVff< (J» t/L(si4£ DATE:Ging^CollinsAnalytical Chemist

-26 -

002374

•at

I'•&

I

SAMPLE DATASUMMARY

I

II

Ii

I-27 -

002375

I 1AVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

B1 0521Lab Name: CH2M HILL ASL Contract: 168667.DA.F1.04







Date Received: NA


Dilution Factor: 1

I'.;:>'3

i

•m

I:,-. !

i

CAS NO. COMPOUND


UG/L Q

J156-60-5 I trans-1,2-Dichloroethene 0.0047 _y I

FORM IVOA-31 -

Rev. 10/99

002376


B1_0523Lab Name: CH2MHILLASL Contract: 168667.DA.F1.04


Matrix: (air/soil/water) Air Lab Sample ID: B1_0523

Level: (low/med) LOW Lab File ID: B1_0523.D

GC Column: DB-VRX ID: 0.25 (mm) Date Received: NA


Dilution Factor:

II CONCENTRATION UNITS:

"-!j CAS NO. COMPOUND UG/L Q

- ' I 156-60-5 I trans-1.2-Dichloroethene I 0.0047 I U I J

FORM I VGA Rev. 10/99-32-

002377

IIIIIIIIII QC SUMMARY

I

I

I

iii ,-. : •iii •"-.

002378

IIIIIIIIIIIIIIIIIII

Lab Name:

Lab Code:




010203040506

EPA

SAMPLE NO.B1_0521

BS2A0523

B1.0523

SF2T-17POST

SF2T-1PRE

SF2T-17PRE

SMC1

#

101101102100105105

SMC2

#

1031051051087778

TOT

OUT

000000

SMC1SMC2

Toluene-d8Bromofluoro benzene

QC LIMITS(70-130)(70-130)

f Column to be used to flag recovery values* Values outside of contract required QC limitsD System Monitoring Compound diluted out

FORMIIVOA-1 Rev. 10/99

- 3 4 -

002379



EPA SAMPLE NO.

B1 0521

Lab Code: CVO










010203040506

EPASAMPLE NO.

1.2 PPBV STD

5.8 PPBV STD

11 PPBV STD

23 PPBV STD

58 PPBV STD

116 PPBV STD

LABSAMPLE ID

LEVEL1LEVEL2LEVELSLEVEL4LEVELSLEVELS

LAB "

FILE ID


TIMEANALYZED

09:1910:0110:4411:2712:0912:51

COMMENTS:

FORMIVVOA- 3 5 -

Rev. 10/99

002380

IIIIII

IIIIIIIIIIII



EPA SAMPLE NO.

B1_0523

Lab Code: CVO










0102030405

EPA

SAMPLE NO.

CV3_0523

BS2A0523SF2T-17POST

SF2T-1PRE

SF2T-17PRE

LAB

SAMPLE ID

CV3 0523BS2A0523742503742501742502

LAB

FILE ID

CV3J5523.DBS2A0523.D742503R2.D742501 R2.D742502R.D

: TIME

ANALYZED

09:5111:1615:2719:3620:19

COMMENTS:

FORMIVVOA- 3 6 -

Rev. 10/99

002381

J,'-]

'A

'4




Lab Code: CVO

Lab File ID:


T1 0521 .D






m/e

50

75

95

96

173

174

175

176177


15.0 -40.0% of mass 9530.0 - 60.0% of mass 95

Base peak, 1 00% relative abundance

5.0 - 9.0% of mass 95

Less than 2.0% of mass 1 74

50.0 - 100.0% of mass 95

5.0 - 9.0% of mass 174

95.0 - 1 01 .0% of mass 1 745.0 - 9.0% of mass 1 76

% RELATIVE

ABUNDANCE

18.2

43.5

100.0

7.0

0.0

74.7

8.3

97.8

5.9

J


01020304050607

EPA

SAMPLE NO.B1_0521

1.2 PPBV STD

5.8 PPBV STD

11 PPBV STD

23 PPBV STD

58 PPBV STD

116 PPBV STD

LAB

SAMPLE ID

B1 0521LEVEL1LEVEL2LEVELSLEVEL4LEVEL5LEVEL6

LAB

FILE ID

B1 0521 .DLEVEL1.DLEVEL2.DLEVEL3.DLEVEL4.DLEVEL5.DLEVEL6.D

DATEANALYZED

05/21/0205/21/0205/21/0205/21/0205/21/0205/21/0205/21/02

TIME

ANALYZED08:3709:1910:0110:4411:2712:0912:51

FORM V VOA

-37 -

Rev. 10/99

002382

I

1




Lai) Code: CVO

Lab File ID: T1_0523.D








m/e

50

75

95

96

173

174

175

176

177


15.0 -40.0% of mass 95

30.0 - 60.0% of mass 95


5.0 - 9.0% of mass 95


50.0 - 100.0% of mass 95

5.0 - 9.0% of mass 174

95.0 -101.0% of mass 174

5.0 -9.0% of mass 176

% RELATIVE

ABUNDANCE

16.6

46.5

100.0

6.3

0.0

69.8

6.4

99.7

7.5


010203040506

EPA

SAMPLE NO.CV3_0523

BS2A0523

B1_0523

SF2T-17POST

8F2T-1PRE

SF2T-17PRE

LAB

SAMPLE ID

CVS 0523BS2A0523B1 0523742503742501742502

LAB

FILE ID

CV3 0523.DBS2A0523.DB1 0523.D742503R2.D742501 R2.D742502R.D

DATE

ANALYZED

05/23/0205/23/0205/23/0205/23/0205/23/0205/23/02

TIME

ANALYZED

09:5111:1611:5615:2719:3620:19

I

fI

FORM V VOA

- 3 8 -

Rev. 10/99

002383


Lab Name:

Lab Code:




Heated Purge (Y/N):

GC Column: DB-VRX

N

ID: 0.25


Calibration Times:

(mm)

05/21/02 05/21/02

09:19 12:51

LAB FILE ID:

COMPOUND

RRF1 = LEVEL1.D RRF2 = LEVEL2.D RRF3 = LEVELS. D


trans-1 ,2-DichloroetheneToluene-d8Bromofluorobenzene

RRF1

0.6650.8720.164

RRF2

0.8720.8740.165

RRF3

0.8880.8540.164

RRF4-

1.0500.8680.164

RRF5

1.1310.8550.161

RRF6

1.056. 0.851

0.159

RRF

0.9440.8620.163

%RSD

18.01.21.4

FORM VIVOA-39-

Rev. 10/99

002384

IIIIIIIII1IIIIIIIII







AFCEE FORM 0-7

SDGNo.: 7425

Contract: 168667. DA.F1.04


Analyte

trans-1 ,2-Dichloroethene

SurrogateToluene-d8Bromofluorobenzene

Expected23.3

Found24.5

%REC101%105%

%R105


Limits70-130

Qualifier

Qualifier

/• /

- 4 0 - Rev. 10/99

002385

.'-M


Lab Name:

Lab Code:


CVO Case No.: 7425 SAS No.: 052102 SDG No.: 7425


Lab Re ID: CV3_0523.D

Heated Purge: (Y/N)

GC Column: DB-VRX

N

Calibration Date:

Init. Calib. Date(s):

Init. Calib. Times:

05/23/02 Time: 09:51

05/21/02

09:19

ID: 0.25 (mm)

COMPOUND

trans- 1 j2-D ichloroetheneToluene-d8Bromofluorobenzene

RRF

0.9440.8620.163

RRF4

1.0040.8670.170

%D

- -6.3-0.6-4.5

MAX%D

303030

05/21/02

12:51

FORM VII VGA-41-

Rev. 10/99

002386

1| Labi

LabC

• LabF

Insta

I GCC

1


Jame: CH2MHILLASL Contract: 168667.DA.F1.04

)ode: CVO Case No.: 7425 SAS No.: 052102 SDG No.: 7425:ile ID (Standard): CV3_0523.D

mentID: GC/MS-G



-olumn: DB-VRX ID: 0.25 (mm) Heated Purge: (Y/N) N

94 HOI IR STn

IS1

AREA # F

4i4«;n 1?

IS2

IT # AREA #

t tiA lonann

RT #

15QB

IS3

AREA # F

(ram •>

I

II1II

iiiiii

01020304

05

24 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLE

NO.

BS2A0523

B1_0523

SF2T-17POST

SF2T-1PRE

SF2T-17PRE

IS1

AREA #

41450

58030

24870

41507

41397

42235

46507

46302

RT #

13.54

14.04

13.04

13.54

13.53

13.53

13.54

13.54

IS2

AREA #

190900

267260

114540

189573

188145

197591

212592

213212

RT #

15.98

16.48

15.48

15.99

15.98

15.98

15.99

15.99

IS3

AREA #

54234

75928

32540

53499

53605

55286

56214

57632

RT #

20.46

20.96

19.96

20.46

20.46

20.46

20.47

20.46

y

151 = Bromochloromethane152 = 1,4-Difluorobenzene153 = Chlorobenzene-d5AREA UPPER LIMIT = +40% of internal standard areaAREA LOWER LIMIT = - 40% of internal standard areaRT UPPER LIM IT = +0.50 minutes of internal standard RTRT LOWER LIMIT =-0.50 minutes of internal standard RT# Column to be used to flag values outside QC limit with an asterisk.* Values outside of contract required QC limits

FORM VIII VGA- 4 2 -

Rev. 10/99

002387

t CH2MHILL Applied Sciences LabCHAIN OF CUSTODY RECORDAND AGREEMENT TO PERFORM SERVICES

CVO 2300 NW Walnut BoulevardCorvallls. OR 97330-3538(641) 752-4271 FAX (541) 752-0276

coc#.Project # Purchase Order #

Company Name

Report to: Phone No:

Requested Completion Date:

Sampling

Date Time

Typ.

M

Matrix

W

Sample Disposal:

OlipoM Rttum

CLIENT SAMPLE ID(8 CHARACTERS)

LABQC

Requested Analytical Method 0

Preservative

THIS AREA FOR LAB USE ONLY

Lab # Page of

EPA Tier QC Level

1 (Screening) 2 3

Alternate Description Lab ID

RD"

IWD E ?.*«

Special Instnicttbns:

Instructions and Agreement Provisions on Reverse Side DISTRIBUTION: Original- LAB, Yellow- LAB, Pink - Client2/01

002388

IIIIIiIIIIIIIII'Ii»

I

CH2IVIHILLServices

Sample Receipt Record

Batch Number | _-].';.;-:Date receiy&J:. J

CluMt/ProjectVERIFICATION OF SAMPLE CONDITIONS (verfly afl Bems) * HP = Otent Hand delivered Samples

Observation ..Were custody seals Intact and on the outside of the cooler?Was the Chain of Custody Inside the cooler? .: Was the Chain of Custody properly filled out? . :

Were the sample containers hi good condition? ••• - •.Was there tee fin the cooler? Enter temp, blank or teewater? C /i//T~

YESb?vox-3

. : -

NO

^U

*HD

If the answer to any of the questions above is .NO, a Sample Receipt Exceptions ReportMust be written.

VERIFICATION OF SAMPLE PRESERVATIONtverffy afl preserved sarnples except HMs,HANsantfCH)

SampleNo12345678

-9" 10

111213141516

. 171SIO19

• .2021222324 .25262728

...: 2930

NutrientspH <2

-• . *

-

\

Metals pH<2

VolatilespH<2

•

^

. ••;. •

•'" • '':-.-

CyanidespH>12

•'• • • '.-

• -

:• • • : •:.-

. • • • • • - . • • • • • •

: • • •• ' • •

'• • •; •• '-

'- - ••' •' :'. ' .

' ..• .-.- -. •'

• • : : - • • • • • ' •-.'.-

• ' • • • ":-..;'•.'*• • • ' *•

•- - •; v .j. ,,f' -"• ;

' . ;•. . .;':-.• : • ' • •

TOC pH'•/'::- <2r>-;-

• ":• . •'

•• : .-

" . ' • • • ' .

. • • • • . • ' .

• •• - . - • • • :• .'• ~. •: '

' ' ' ' .* '••• " '

•• ""* '" ' . :• • •

•:/ .•-•: :"'•-.

TOXpH' -,':-<2-'

; .

. - • : • - •• .• '•' . • :

omw(sp«cay

.

' . ' " •,. •• -.- • ;..-

•

• . . '•• • •'

' ' - . - • WA-:- •'-'••';•. (soflsAinpres)

IJ '\s

'-• '• •• • •• : '.-.••IV •.;'.-• - •:.

'.'•;• • • ' • ' • • '• '•'

. ' • ! • • • • '•;'•. • .... •>.

.••'•'•• -.. • . .'.

- • • . ' - . • • • . ' •

•. /•• . -• • • : . " •

••''. - '• '•• :"-,>.

LOGIN AND pH VERIFICATIONS PERFORMED BY

AppBed Sciences Laboratory2300 NWWdtnutBlvcL,. COfYOflfc OR 97330-3538

P.O. Box428t COrvd»X>f? 973394428fe/541752.4271

Fax 541752027$

002389

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