specification for lithium battery model: cr2032 · power glory battery tech (hk) co., ltd - 3 - (3)...

14
. POWER GLORY BATTERY TECH (HK) CO., LTD - 1 - SPECIFICATION FOR LITHIUM BATTERY Model: CR2032 Approved By Department Name Title Signature/Date (Remarks: The above table shall be filled by customer) POWER GLORY BATTERY TECH (HK) CO., LTD. ROOM E2B, 14 FLOOR, HOI BUN INDUSTRIAL BUILDING, 6 WING YIP STREET. KWUN TONG. KOWLOON. HONG KONG TEL: (852) 3427 5537 FAX : (852) 3427 5526 http://www.omnergy.com.hk

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.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

- 1 -

S P E C I F I C A T I O N

F O R L I T H I U M B A T T E R Y

M o d e l : C R 2 0 3 2

Approved By

Department

Name

Title

Signature/Date

(Remarks: The above table shall be filled by customer)

POWER GLORY BATTERY TECH (HK) CO., LTD.

ROOM E2B, 14 FLOOR, HOI BUN INDUSTRIAL BUILDING, 6 WING YIP STREET. KWUN TONG. KOWLOON. HONG KONG

TEL: (852) 3427 5537 FAX : (852) 3427 5526 http://www.omnergy.com.hk

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

- 2 -

PRODUCT SPECIFICATIONPRODUCT SPECIFICATIONPRODUCT SPECIFICATIONPRODUCT SPECIFICATION !!!!!!!!!!!! 1.Applicability: This specification is applicable to the following product:

Coin type manganese lithium battery !"!"!"!"####$%#$%#$%#$%#&&&&

2.Battery type and ratings:

2.1. Battery type:!!!!!!!!!!!! CR2032 2.2. Nominal voltage: 3.0V

2.3. Nominal capacity: 210mAh (on continuous discharge at 20! under 15kΩ load to

2.0V end-voltage) 2.4 Outer dimensions: Outer dimensions shall be as shown in Fig. 1, Battery Dimensions. 2.5 Standard weight: 3.2 g 2.6 Country of Origin: China 2.7 Terminals: Materials of Positive electrode: SUS430+Ni-plated

Negative electrode: SUS430+Ni-plated

3.Quality requirements:

3.1 Dimensions: Dimensions of batteries when tested in accordance with Subparagraph 4.4.1 shall be as shown in Fig. 1. Battery dimensions.

3.2 Appearance: Battery shall have no deformation, dent, stain, leakage and camber or burr on their sealing members, which may adversely affect their appearance, performance and commercial value. There shall be no coatings or other foreign objects on the surface of terminals which may adversely affect actual use or performance of batteries.

3.3 Characteristics:

(1) Open-circuit voltage: Open-circuit voltage of batteries when tested in accordance with Subparagraph 4.4.3shall meet the requirement set forth in Table 1.

(2) Closed-circuit voltage: Closed-circuit voltage of batteries when test in accordance with Subparagraph 4.4.4 shall meet the requirements set forth in Table 1.

'()*+,&-.'()*+,&-.'()*+,&-.'()*+,&-.&&&&

Ω

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

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(3) Service life: Service life of batteries when tested in accordance with

Subparagraph 4.4.5 shall meet the requirements set forth in Table 2.

'&()*+,&#&.'&()*+,&#&.'&()*+,&#&.'&()*+,&#&.&&&&

(,/(&0(,1(,/(&0(,1(,/(&0(,1(,/(&0(,1&&&& (,12,")(3",(,12,")(3",(,12,")(3",(,12,")(3",&&&& 040(0)+040(0)+040(0)+040(0)+&&&& )5(,"&-#&164(7/)5(,"&-#&164(7/)5(,"&-#&164(7/)5(,"&-#&164(7/&&&& ",1)"8/",1)"8/",1)"8/",1)"8/&&&&

20 2 940 Hrs. or Longer 910 Hrs. or Longer

Service Life 0 2 850Hrs. or Longer 820Hrs. or Longer

Continuous Discharge

Under 15 kΩ Load to 2.0V End-Voltage

(4) Service life after storage at high temperature: Service life of batteries when

tested in accordance with Subparagraph 4.4.6 shall meet the requirements

set forth in Table 3

'&()*+,&'&()*+,&'&()*+,&'&()*+,&%%%%&.&.&.&.&&&&

(,/(&0(,1(,/(&0(,1(,/(&0(,1(,/(&0(,1&&&& /(6")9,&(,12:/(6")9,&(,12:/(6")9,&(,12:/(6")9,&(,12:&&&& /(6")9,&2,"06;/(6")9,&2,"06;/(6")9,&2,"06;/(6")9,&2,"06;&&&& ",<30",1,4(",<30",1,4(",<30",1,4(",<30",1,4(&&&& ",1)"8/",1)"8/",1)"8/",1)"8/&&&&

Service Life After Storage At High

Temperature

60 2

20 Days

910Hrs

Minimum

Continuous Discharge At 20

2 Under 15kΩ Load To

2.0V End-Voltage After Storage.

(5) Leakage characteristics: Batteries when tested in accordance with Subparagraph

4.5.1shall have no leakage.

'&()*'&()*'&()*'&()*+,&=&.+,&=&.+,&=&.+,&=&.&&&&

(,/(&0(,1(,/(&0(,1(,/(&0(,1(,/(&0(,1&&&& ",<30",1,4(",<30",1,4(",<30",1,4(",<30",1,4(&&&& (,/(&!64;0(064/(,/(&!64;0(064/(,/(&!64;0(064/(,/(&!64;0(064/&&&&

Leakage Characteristics

No Leakage

Temperature: 45 2 , Relative Humidity: 75%

Storage: 30 Days Shall Be Inspected By Visual Means

(6) Self-discharge: Self-discharge of batteries when tested in accordance with

Subparagraph 4.5.2 shall be as set forth in Table 5.

'&()*+,&>&.'&()*+,&>&.'&()*+,&>&.'&()*+,&>&.&&&&

(,/(&0(,1(,/(&0(,1(,/(&0(,1(,/(&0(,1&&&& ",<30",1,4(",<30",1,4(",<30",1,4(",<30",1,4(&&&& (,/(&!64;0(064/(,/(&!64;0(064/(,/(&!64;0(064/(,/(&!64;0(064/&&&&

Self-discharge

2% or Below

Continuous Discharge Under 15kΩ Load To 2.0V End-voltage After 12 Months Storage At 20 . ( To Obtain From The Mean Value Of The Same Lot )

4.Testing: 4.1 Test conditions:

4.1.1 Initial test :Initial test must be done within 1 months from delivery 4.1.2Temperature and humidity: Unless otherwise specified elsewhere, tests shall be

conducted at ordinary temperature (20 2 ) and ordinary humidity (65 5%RH).

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

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4.2 Storage of test specimen batteries:

".2.1 Specimen batteries to be tested shall be kept at the ambient temperature of 25! or below

and at the relative humidity of 75% or below. 4.2.2 Storage at less than -20! can deform the plastic parts and may cause a leakage.

4.2.3 To prevent self-discharge caused by corrosion or decrease of insulation, humidity during storage shall be less than75%RH without dewing on battery.

4.3 Measuring instruments and devices: 4.3.1 Dimensions: Outer micrometers specified inJJG26-95, dial gauges specified in JIS B 7503, and vernier callipers specified in JJG30-92 or those having equal or better accuracy shall be used.

4.3.# DC voltmeters: The tolerance shall be "0.01V and the input resistance rating shall

be 10M! or more.

4.$.$ Load resistance: Load resistance shall include resistance throughout external

circuits, and its tolerance shall be "0.5%.

4.4 Test methods: 4.4.1Dimensions: Dimension shall be measured with instruments specified in Subparagraph 4.3.1 above, provided that either one or both sides of such instruments shall be insulated in measuring the overall height of the batteries. 4.4.2Appearance: Appearance of batteries shall be inspected by visual means. 4.4.3Open-circuit voltage: Test specimen batteries shall be kept for 8 hours or longer at the ambient temperature specified in Table 1, and then the voltage between both terminals shall be measured at the same ambient temperature with a voltmeter as specified in Subparagraph 4.3.2. 4.4.4Closed-circuit voltage: Test specimen batteries shall be kept for 8 hours or longer at the ambient temperature specified in Table 1. and then the voltage between both terminals shall be measured with a voltmeter as specified in Subparagraph 4.3.2 while the specified load is connected between both terminals at the same ambient temperature as specified above; provided that the measured value shall be based on meter reading taken 8 seconds after the circuit is closed. 4.4.5 Service life: Test specimen batteries shall be kept for 8 hours or longer at the ambient temperature specified in Table 2. and shall then be continuously discharged at the same ambient temperature and through the specified load resistance. The discharge shall be continued until the terminal voltage of the test specimens falls below the discharge end-point voltage of 2.0V, and the time during which the terminal voltage has been maintained equal to and above the discharge end-point voltage shall be taken as the service life.

4.4.6 Service life after high-temperature storage: Test specimen batteries, after having been stored at the temperature and period specified in Table 3, shall be kept for 12 hours or longer at ordinary temperature (20"2!) and at ordinary humidity

(65"20%RH) and shall then be continuously discharged through the load resistance

15K at ambient temperature of 20"2!. The discharge shall be continued until the

voltage falls below the discharge end-point voltage of 2.0V, and the time during which the voltage has been maintained equal to and above the discharge end-point

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

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voltage shall be taken as the service life. 4.5 Other tests: Tests specified below shall be conducted as required. Except as specified in this paragraph. Test methods be in accordance with the provisions of Paragraph 4.4. 4.5.1 Electrolyte leakage test: Test specimen batteries shall be examined for electrolyte leakage while they are kept at ordinary temperature and at ordinary humidity after having been stored at the temperature, humidity and period specified in Table 4. 4.5.2 Self-discharge: Test specimen batteries which have been stored for 12 month at the ambient temperature of 20 2 and at the relative humidity of 65 20% shall be tested for service life in accordance with the method specified in Subparagraph 4.4.5

Self-discharge shall be determined in the following manner: X1 - X2 Self-discharge rate (%) = ------------- x 100% X1 X1: Average initial discharge life of batteries of the same lot X2: Average discharge life after storage

5.Markings: 5.1 Markings on batteries:

5.1.1 Battery type: CR2%$#

5.1.2 Brand of battery: Omnergy 5.1.3 Polarity: + [(-) shall not be indicated] 5.1.4 Manufacturing marks: The year and month of production shall be marked on the negative (-) terminal side

o o

Month of production (1 letter) Year of production (The last number of Christian era)

[Example] 11..... Manufactured in January 2011

1X Manufactured in October 2011

1Y Manufactured in November 2011

1Z Manufactured in December 2011

Month of production.

- January to September -- 1- 9

- Oct, Nov, Dec, -------X, Y, Z

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

- 6 -

RATINGS OF MANGANESE DIOXIDE LITHIUM BATTERY

(TYPE: CR2032)

CLASSIFICATION MANGANESE DIOXIDE LITHIUM PRIMARY BATTERY

BATTERY SYSTEM COIN TYPE MANGANESE DIOXIDE LITHIUM BATTERY

BATTERY TYPE CR2032

NOMINAL VOLTAGE 3.0V

NOMINAL CAPACITY

210mAh

(ON CONTINUOUS DISCHARGE UNDER 15K! load to

2.0V end-point)

STANDARD DISCHARGE CURRENT

0.2mA

STANDARD WEIGHT 3.2g

TERMINALS CAP TERMINAL

CASE TERMINAL

SUS430+Ni-plated

SUS430+Ni-plated

OUTER DIMENSIONS

DIAMETER OVERALL HEIGHT

!20.0(+0/-0.3)mm

3.2(+0/-0.3)mm

USABLE TEMPERATURE RANGE"

-20#$+70#

STORAGE TEMPERATURE RANGE

0#~30#

STORAGE HUMIDITY RANGE 40%~75%

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

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Marking

Dimensional Diagram

16. 5+0. 3-0. 3

17. 5+0. 3-0. 3

18. 0+0. 3-0. 3

20+0. 0-0. 3

3.2+0.0

-0.3

MIN

2.4

6

(+)

(- )

Fig.1

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

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Cap

acit

y (

mA

h)

Storage at 60 for 30 days equivalent to storage at room temperature for 18 months

Initial

1000

Discharge depth 40%, Pulse load for 15 sec

010

Pulse Load ( )

100 1000

Vo

ltag

e (V

)

1.0

0.5

1.5

2.5

2.0

3.0

s

3.0

1.020010000 0 600

Discharge time (h)

400 800

Vo

ltag

e (V

)

2.0

1.5

2.5

3.5

3.0

After storage

Pulse discharge characteristics

Load (K )

Vo

ltag

e (V

)

1.81

2.2

2.6

3.0

10

Storage characteristics

Load (K )

1

140

10060

100

180

220

10

1200

100

!

1000

EPV 2.0V

Vo

ltag

e (V

)

Vo

ltag

e (V

)

Load vs. Operating voltage

3.4Discharge depth 40%

1.5

0 2001.0

2.5

2.0

3.0

Discharge time (h)

600400 1000800

Load vs. Capacity

260

200

1.5

1200 01.0

2.5

2.0

3.0

600

Discharge time (h)

400 800

Discharge characteristics

3.5

Operating temperature

Continuous standard load

Weight

Temperature characteristics

3.5

"

!"

#

$ %&'()*+,&-

1200

CR2032Lithium manganese dioxide battery

Nominal Capacity

Nominal Voltage

Specifications

Dimensions (mm)

! ./&0

" %1&1

2&%

.!!!! POWER GLORY BATTERY TECH (HK) CO., LTD

- 9 -

7.2 Supplied voltage to load.

Because a diode and a resistance generate the voltage drop on

operating, please take into consideration these voltage drops for

supplied voltage to load.

7.3 Using diodes to prevent charging

Please choose diodes with leak current as small as possible. Please

keep the charged capacity due to leak current to within 1% of

nominal capacity.

7.4 Using and setting protective resistance

Protective resistance is used to prevent the battery from being

charged by large surges of current during diode failure. Please set the

resistance so that the maximum current shown in the right table is

not exceeded. For example, say a CR2032 battery is used in sample

circuit (A) in combination with a main power source 5 volt. Since

the permitted charge current is 10mA and this battery's voltage is 3V,

let resistance be R≥ (5V-3V)/10mA=0.2k ohm, meaning that at least

0.2k ohm is required.

Type Maximum

current

CR2032 10mA

CR3032 15 mA

CR2450 15mA

CR2354 12mA

CR2330 10mA

CR2025 10mA

CR2016 10mA

Warnings 7.1 Precautions in Circuit Design for back-up Use

This is a primary battery and cannot be charged. If used in memory or RTC back-up

applications, be sure to use diodes to prevent charging from the main power source or other

batteries, and protective resistance to regulate the current as shown in the figure below. Note

that the points described below should be taken into careful consideration when selecting

diodes and protective resistance.

!!

Load

Diode

5VLoad

Diode

ProtectiveResistance

Battery

Example(B)

Diode

5V

Diode

ResistanceProtective

Battery

Example(A)

Material Safety Data Sheet Button Type CR Lithium cellDate : 10/2/2009

Document Number: NL MSDS - CR 2032 Revision:002 Page 1 of 4IDENTITY (As Used on Label and List)Note : Blank spaces are not permitted if any item is not applicable or no information is available,the space must be marked to indicate that.Section 1Supplier's NameABOOM INDUSTRIAL CO., LTD.Section II - Hazardous Ingredients / Identity InformationIMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredientscontained within or their combustion products could be harmful.MATERIAL OR

INGREDIENT

1 ,2-Dimethoxyethane1,3-DioxolaneGraphite

Lithium or Lithium AlloyLithium PerchlorateLithiumTrifluorome thane sulf onateLithiumTrifluoromethanesulfonirnideManganese DioxidePropylene Carbonate

PEL (OSHA)

3.5 mg/mj TWANone establishedNone established1 5 mg/m-3 TWA (total dust)

5 mg/m3 TWA (respirablefraction)None establishedNone establishedNone established

None established

5 mg/m'3 Ceiling (as Mn)None established

TLV (ACGIH)

3.5 mg/m-3 TWANone establishedNone established2 mg/mj TWA (respirablefraction)

None establishedNone establishedNone established

None established

0.2 mg/mj TWA (as Mn)None established

%/wt.

0-10-60-80-3

1-60-30-3

0-3

12-420-8

Section III - Physical / Chemical CharacteristicsBoiling Point N.A.Specific Gravity (H2O1) N.A.Vapor Pressure (mm Hg) N.A.Melting Point N.A.Vapor Density (AIR=1) N.A.Evaporation Rate (Butyl Acetate) N.A.Solubility in Water N.A.Appearance and Odor Cylindrical Shape, odorless

Material Safety Data Sheet Button Type CR Lithium cellDocument Number: NL MSDS - CR2032 Revision:002 Page 2 of 4

Section IV - Fire and Explosion Hazard DataFlash Point (Method Used) N.A.Flammable Limits N.A.LEL N.A.UEL N.A.Extinguishing Media N.A.Special Fire Fighting Procedures N.A.Unusual Fire and Explosion HazardsDo not dispose of battery in fire - may explode.Do not short-circuit battery - may cause burns.

Section V - Reactivity DataStability UnstableConditions to Avoid StableIncompatibility (Materials to Avoid)Hazardous Decomposition or ByproductsHazardousPolymerization May Occur Conditions to AvoidWill Not OccurSection VI - Health Hazard DataRoute(s) of EntryInhalation N.A.Skin N.A.Ingestion N.A.Health Hazard (Acute and Chronic) / Toxicological informationIn case of electrolyte leakage, skin will be itchy when contaminated with electrolyte.In contact with electrolyte can cause severe irritation and chemical burns.Inhalation of electrolyte vapors may cause irritation of the upper respiratory tract and lungs.Section VII - First Aid MeasuresFirst Aid ProceduresIf electrolyte leakage occurs and makes contact with skin, wash with plenty of water immediately.If electrolyte comes into contact with eyes, wash with copious amounts of water for fifteen (15)minutes, and contact a physician.If electrolyte vapors are inhaled, provide fresh air and seek medical attention if respiratoryirritation develops. Ventilate the contaminated area.

Material Safety Data Sheet Button Type CR Lithium cellDocument Number: NL MSDS - CR2032 Revision:002 Page 3 of 4

Section VIII - Fire and Explosion Hazard DataFlash Point (Method Used) N.A.Ignition Temp. N.A.Flammable Limits N.A.LEL N.A.UEL N.A.Extinguishing Media Carbon Dioxide, Dry Chemical or Foam extinguishersSpecial Fire Fighting Procedures N.A.Unusual Fire and Explosion Hazards Do not dispose of battery in fire - may explode.Do not short-circuit battery - may cause burns.Section IX - Accidental Release or SpillageSteps to Be Taken in Case Material is Released or SpilledBatteries that are leakage should be handled with rubber gloves.Avoid direct contact with electrolyte.Wear protective clothing and a positive pressure Self-Contained Breathing Apparatus (SCBA).Section X - Handling and StorageSafe handling and storage adviceBatteries should be handled and stored carefully to avoid short circuits.Do not store in disorderly fashion, or allow metal objects to be mixed with stored batteries.Never disassemble a battery.Do not breathe cell vapors or touch internal material with bare hands.Keep batteries between -30°C and 35°C for prolong storage.Section XI - Exposure Controls / Person ProtectionOccupational Exposure Limits: LTEPN.A.STEPN.A.Respiratory Protection (Specify Type)N.A.Ventilation Local ExhaustsN.A.SpecialN.A.Mechanical (General)N.A.OtherN.A.Protective GlovesN.A.

Material Safety Data Sheet Button Type CR Lithium cellDocument Number: NL MSDS - CR 2032 Revision:002 Page 4 of 4

Eye ProtectionN.A.Other Protective Clothing or EquipmentN.A.Work / Hygienic PracticesN.A.Section XII - Ecological InformationN.A.Section XIII - Disposal MethodDispose of batteries according to government regulations.Section XIV - Transportation Information

Shipping name: Lithium batteriesUN Number: UN3090 (UN3091 for lithium batteries in equipment)Hazard Classification: Class 9 (Miscellaneous)

Organizations governing the transport of lithium batteriesAreaInternational

InternationalU.S.A.

MethodAir

MarineAir, Rail, Road,Marine

OrganizationIATA, ICAO

IMODOT

Special provisionPacking instruction968-970SP18849 CFR Section173.185

Their regulations are based on the UN Recommendations. Each special provisionspecificaions on exceptions and packaging for lithium batteries shipping. All CR batteries ofAboom meet all special provisions.

Ref Summary of Packing Instruction (IATA Dangerous Goods Regulations 50th Edition)The minimum requirements necessary to non-restricted goods are as follows:

l)For a lithium metal or lithium alloy cell, the lithium content is not more than Ig, and for alithium-ion cell, the equivalent lithium content is not more than 2.0g;

2)Each cell or battery is of the type proved to meet the requirements of each test in the UNManual of Tests and Criteria, Part III, sub-section 38.3;

3)Each package must be displayed a battery handling label. (Telephone No. must be printedfor emergency call on the handling label);

4)Each Consignment must be accompanied with a declaration of non-dangerous goodsdocument (Telephone No. must be printed for emergency call on the document)

5)Each package must be capable of withstanding al.2m drop test.Aboom will offer the certificate of (1) and (2). If our package is used for transport, weoffer the certificate of (5).

(i) Transportation of batteries installed in equipment as non-restricted goodsIf each package contains no more than 4 cells or 2 batteries, the requirement isthe same as current. But for other cases of cell or battery quantity, therequirements are 1), 2), 3) and 4).

(ii) Transport of batteries packed with equipment as non-restricted godosRegardless of the battery quantity, the requirements (1) and (5) shall be

satisfied. Also the battery quantity within one package is restricted in airtransport to the minimum quantity to operate the application and 2 batteries asspares.

(iii) Transportation of batteries only as non-restricted goods. Regardless of thebattery quantity, the requirements (1) to (5) shall be satisfied.

Section XV - Regulatory InformationN/A

Section XVI - Other InformationIf you want further information, PLS contact Aboom representative

Section XVII - Measures for fire extinctionIn case of fire, it is permissible to use any class of extinguishing medium on these batteries or theirpacking material. Cool exterior of batteries ifexposed to fire to prevent rupture.Fire fighters should wear self-contained breathing apparatus.