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Dow.com State of CMP Materials Marty W. DeGroot July 12, 2017

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Page 1: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Dow.com

State of CMP MaterialsMarty W. DeGrootJuly 12, 2017

Page 2: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

More CMP Advanced device structures leading to increase in the need for CMP

Wafer-scale control in FEOL for FinFET devices Narrow window of operation: tighter lot-to-lot and with-in lot variation Stringent thickness control requirements Edge profile control and consistency is critical

Reduced topography and defect tolerance Challenging selectivity requirements Low dishing, high PE is increasingly important

Incoming topography < typical CMP capability More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth

3D stack designs High removal rate for microns thick oxide films High planarization and low dishing across mm features

The Changing Landscape of CMP:Trends and Challenges for Advanced Devices

Page 3: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

2D NAND

Average 9 CMP Steps

3D NAND

Average 19 CMP Steps

Planar LOGIC

Average 1-3 FEOL CMP Steps2-3 MOL CMP Steps

7-9 Metal BEOL CMP Steps

3D LOGIC

Average 9-11 FEOL CMP Steps5-7 MOL CMP Steps

10-13 Metal BEOL CMP Steps

Conventional Packaging

No CMP Steps

Adv. Packaging, 3D DRAM

Adv. Packaging, 3D DRAM:2-4 CMP Steps/Layer

Changes in CMP Scope:Advanced Devices Drive More CMP

Page 4: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Shift in CMP Scope: Layer Augmentation in Advanced Devices

Advanced logic Advanced FDSOI

Memory

Page 5: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

CMP Physics Across All Length Scales

Pad Stack Components, Properties and Mechanics

Macro-ScaleCMP ToolOperation

Micro/Nano-ScaleReaction and

Abrasion Events

Thermal and Frictional Effects at Wafer, Groove and Texture Scale

Slurry Flow Dynamics at Wafer, Groove and Texture Scale

Pad Texture Formation, Characteristics and Influence

Mechanisms of CMP Material Removal, Defect Formation and Pad Wear

Full Optimization of Top Pad Material, Texture, Groove Design and Pad Stack

Page 6: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Improving Uniformity via Texture & Disk Characterization

Disk 1

Disk 2

Advanced characterization enables precise quantification of:• Pad texture morphology, uniformity and consistency through lifetime• Conditioning disk diamond uniformity and wear characteristics

Parameters to improve texture variation

Understanding disk variation

Page 7: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Typical CMP process removes 2000 – 8000 Å/min thickness across full surface of wafer

Implies combination of− O(109) nano-abrasions

by slurry particles− O(107) micro-abrasions

by full asperity tips

Typical CMP defect counts are O(10) – O(100) defects

Malfunctions of abrasion that incur defect happen only once in100,000 to 100,000,000 events

CMP Material Removal Events and Defect Events

Approaches to defect reduction involve combinations of physical and chemical approaches to minimize the probability of formation or impact of defect forming particles

Page 8: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Defect Improvement by Polymer Engineering

IK = IKONIC™, a trademark of the Dow Chemical Company

Modified polymer

Order of magnitude defect improvement possible by polymer design while enabling high PE / RR

Mat

eria

l par

amet

er

Page 9: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Challenges in Planarization: Breaking Conventional Trade-offs in PE and Defectivity

VP = VisionPad™

dlocal bending:

Lpad

∆L=ddlocal

bending:Lpad

∆L=d

Materials that minimize low area contact while enabling low defectivity

Page 10: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Challenges in Planarization: Breaking Conventional Trade-offs in PE and Defectivity

Low abrasive silica-based slurries and soft pad synergy enabling improved PE, low defects

Fumed Silica

EXP Slurry B

Acidic ILD Slurry

EXP Slurry A

Nor

mal

ized

Def

ects

1.0

0.2

0.4

0.8

0.6

Acidic ILD slurry / IC1000™

EXP ILD slurry / IC1000™

Acidic ILD slurry / VP6000

Page 11: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Pad stackRegions of higher contact stress

Thick oxide removal for multilayer 3D stacks

Die scale thickness variation

Challenges in Planarization: Long Length PE

CMP

High RR, high PE materials

Page 12: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Pad stackRegions of higher contact stress

Thick oxide removal for multilayer 3D stacks

Die scale thickness variation

Challenges in Planarization: Long Length PE

CMP

Selective, low dishing silica-based slurry

SiN loss on active area

Rem

aini

ng o

xide

on

field

EXP Slurry

Ceria Slurry

Page 13: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

Change in CMP Complexity: Top Challenges for Advanced Devices

Wafer-scale control in FEOL for FinFET devices Narrow window of operation: tighter lot-to-lot and

with-in lot variation Stringent thickness control requirements: Edge profile control and consistency is critical

Reduced topography and defect tolerance Challenging selectivity requirements Low dishing, high PE is increasingly important

Incoming topography < typical CMP capability More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and

depth

3D stack designs High removal rate for microns thick oxide films High planarization and low dishing across mm

features

• Materials that break PE/defect trade-offs

• Low abrasive slurry

• Products that extend planarization length

• High RR materials• Selective, low

dishing silica slurry

• Contact pressure regulation on wafer

Page 14: State of CMP Materials - NCCAVS Usergroups · More CMP near the transistor – dishing and defects! Emphasis on reduction of micro-scratch count and depth 3D stack designs High removal

ThankYou

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