study of bound water in the surface layer of mars workshop hend-2002 “the first year of hend...

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Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002 Institute for Space Research Moscow, Russia Vernadsky Institute of Geochemistry and Analytical Chemistry Russian Acedemy of Science Moscow 119991 Russia [email protected] Alexander T. Basilevsky

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Page 1: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Study of bound water in the surface layer of Mars

Workshop HEND-2002“The First year of HEND operations on the NASA Odyssey Mars Orbiter”

May 20-22, 2002Institute for Space Research

Moscow, Russia

Vernadsky Institute of Geochemistry and Analytical Chemistry

Russian Acedemy of ScienceMoscow 119991 Russia

[email protected]

Alexander T. Basilevsky

Page 2: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Bound water - water incorporated into minerals and rocks which can not be removed without changing structure or composition of these materials.

Minerals H2O contentGypsum - CaSO4 2H2O 21%Goethite - FeO (OH) 10%Nontronite

- Na0.33Fe23+(Al0.33Si3.67)O10 (OH)2 nH2O 5-15%

Chlorite - (Mg,Fe2+,Fe3+)6AlSi3O10(OH)8 5-14%Serpentine - (MgFe)3Si2O5(OH)4 10-13%Hornblende - (Ca,Na)2-3 (Mg,Fe2+,Fe3+,Al)5 (Al,Si)8 (OH)2 2-3%

RocksBasalt - volcanic rock with 44-50% SiO2 0.1 to 2%Andesite - volcanic rock with 53-63% SiO2 1-4%Rhyolite - volcanic rock with >68% SiO2 3-7%-----------------------------

Clays of platforms of Earth 4-6%----------------------------

Martian soil (Viking GS-MS estimate) up to 1%

Page 3: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Bound water in tholeitic basalts of intra-plate hot spots, Earth

Page 4: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Water on Mars: Noachian Period -Warm and wet or cold and dry?

If it was water, it should be chemically incorporated into weatheringproducts and sediments and its hydrogen may potentially be seen

in HEND data

Viking image of cratered terrain with valley network

Page 5: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Water on Mars: Hesperian Period- Outflow channels - water or liquid CO2

If it was water, their deposits may contain H2O-OH-bearing mineralsand their hydrogen may potentially be seen in HEND data

Viking image of Mars Pathfinder site at the mouth of Ares Vallis

Page 6: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Water on Mars: Hesperian Period- Did aqueous ocean exist on Mars?

If yes, its sediments should contain H2O-OH-bearing mineralsand their hydrogen may potentially be seen in HEND data

Mola topography map of Mars. Courtesy of Mola Team

Page 7: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Water on Mars: Amazonian PeriodWas liquid water on and near the surface?

If yes, surface deposits may contain H2O-OH-bearing mineralsand their hydrogen may potentially be seen in HEND data

MOC image of gullies on the walls of crater Kaiser (46.5S, 341.4W).

Page 8: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Impact-induced and magmatic hydrothermal activityAmount of impact-induced and magmatic hydrothermal

mineralization decreases with depth (Masaitis & Naumov, 1993). Should be most prominent on the surface. Possible (magmatic)

analog: Hydrothermal deposits of Yellowstone National Park

Bedrock: Rhyolite (Bauer, 1948; Browny, 1978) Hydrothermal deposits: Travertine CaCO3, Geiserite SiO2

High-silica zeolites, Clays…

Courtesy of Elizabeth Tritthart, West Yellowstone Web Works

Mammoth Terrace Norris Geiser

Page 9: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

How to search for bound water? - To study areas where seasonal/perrenial ices/frosts are not expected: Equatorial zone for all seasons and mid-latitudes at summer

Mola shaded relief map of Mars. Courtesy of MOLA Team

Page 10: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

General approach: - To correlate HEND data with a) bedrock geology

b) topography and c) surface roughness

Geologic map of Mars. Tanaka et al., 1978

a)

Page 11: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

General approach: - To correlate HEND data with a) bedrock geology

b) topography and c) surface roughness

Mola topography map of Mars. Courtesy of MOLA Team

b)

Page 12: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Map of kilometer roughness of Mars. Kreslavsky and Head, 2000

General approach: - To correlate HEND data with a) bedrock geology

b) topography and c) surface roughness

c)

Page 13: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

HEND data: (0.4 eV-100 keV)

Page 14: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

HEND v.s. bedrock geology

Page 15: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

HEND v.s. MOLA topography

Page 16: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

HEND v.s. MOLA km-scale roughness

Page 17: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Discussion and conclusions

Some correlation of HEND measured neutron fluxwith geologic structures of Mars is seen:• Syrtis Major Planitia (more H, hyps. higher)

v.s Isidis Planitia (less H, hyps. lower) • Hellas basin floor (more H, hyps. lower)

v.s. Argyre basin floor (less H, hyps higher)• Noachian-Hesperian cratered terrain within 0-40W, 30N-15S

has highest contents of H among all equatorial zone,being usual in hypsometry and surface roughness

• Medusa Fossae: increase in H content comparing to surrounding areas

• Elysium Fossae: increase in H content comparing to Elysium Mons and its other surroundings

• Olympus, Arsia, Pavonis, Ascreus volcanic constructs showlow H contents, same as materials of close vicinities

More analysis needed to reach meaningful conclusions

Page 18: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

HEND data: (0.4 eV-100 keV)

HEND data: (1-7 MeV)

Page 19: Study of bound water in the surface layer of Mars Workshop HEND-2002 “The First year of HEND operations on the NASA Odyssey Mars Orbiter” May 20-22, 2002

Needs for future studies

• To understand meaning of neutron flux of different energies in the geological context (likbez)

• To have HEND results maps in cylindical projection

• To work on different gradations of the flux intensity categories on the maps

• To play with degree of smoothening on the maps

• Calibration of the results in percent of H2O

• Possibility of improvement of spatial resolution due to multiple overlapping of the measuring orbits?