supporting information enantioselective recognition of
TRANSCRIPT
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SUPPORTING INFORMATION
Enantioselective Recognition of Amino acids by Chiral Peptido-Calix[4]arenes and Thiacalix[4]arenes
Joackim Bois, Isabelle Bonnamour, Christian Duchamp, Helene Parrot-Lopez, Ulrich Darbost and Caroline Felix*
Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, Chimie Supramoléculaire Appliquée (CSAp), CNRS, UMR 5246, 43 Boulevard du11 Novembre 1918, F-69622, Villeurbanne, France; Université de Lyon, Lyon; Université Lyon 1, Villeurbanne
Contents
NMR spectra (all in CDCl3)
Compound 4 proton (300 MHz)…………………………………………………………………………………………………………….. S3
Compound 4 carbon (75 MHz)…………………………………………………………………………...………………………………… S4
Compound 6 proton (300 MHz)…………………………………………………………………………………………………………….. S5
Compound 6 carbon (75 MHz)…………………………………………………………………………………………..…………………. S6
Compound 8a proton (300 MHz)……………………………………………………………………………………………..…………….. S7
Compound 8a carbon (75 MHz)……………………………………………………………………………………………….…………… S8
Compound 8a COSY ………..…………………………………………..…………………………………………………….…………… S9
Compound 8a NOESY………………………………………………………..……………………………………………….…………… S10
Compound 8b proton (300 MHz)…………………………………………………………………………………………….…………….. S11
Compound 8b carbon (75 MHz)……………………………………………………………………………………………….…………… S12
Compound 8b COSY……………………….………………………………………………………………………………….…………… S13
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S2
Compound 7b COSY ………..…………………………………………..…………………………………………………….…………… S14
Compound 7b NOESY………………………………………………………..……………………………………………….…………… S15
Complexe 7b- (L)-N-Ts-Val COSY………………………………….…….………………………………………………….…………… S16
Complexe 7b- (L)-N-Ts-Val NOESY……………….……………….…….………………………………………………….…………… S17
Complexe 7b- (L)-N-Ts-Val ROESY……………………….……….…….………………………………………………….…………… S18
Mass spectrometry
Complexe 7b – (L)-N-Ts Leu MS………………………………………………………………………………………………………… S19
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S3
Compound 4 proton (300 MHz)
!"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S4
Compound 4 carbon (75 MHz)
!"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S5
Compound 6 proton (300 MHz)
#"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S6
Compound 6 carbon (75 MHz)
#"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S7
Compound 8a proton (300 MHz)
$a"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S8
Compound 8a carbon (75 MHz)
$a"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S9
Compound 8a COSY
$a"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S10
Compound 8a NOESY
$a"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S11
Compound 8b proton (300 MHz)
$&"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S12
Compound 8b carbon (75 MHz)
$&"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S13
Compound 8b COSY
$&"
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S14
Compound 7b COSY
7b
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S15
Compound 7b NOESY
7b
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S16
Complexe 7b- (L)-N-Ts-Val COSY
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S17
Complexe 7b- (L)-N-Ts-Val NOESY
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S18
Complexe 7b- (L)-N-Ts-Val ROESY
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
S1
Mass spectrometry : Complexe 7b – (L)-N-Ts Leu
Supplementary Material (ESI) for New Journal of ChemistryThis journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009