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Page 1: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 2: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 3: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 4: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 5: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 6: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 7: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 8: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 9: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 10: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 11: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 12: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

Hydrophilic (water loving) and Hydrophobic (water hating/oil‐liking) Groupings Allow For Surface 

Interaction With Many Contaminants

Page 13: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

Surfactant Interaction with DNAPL.  Helps dissolve DNAPL into pore space.

Page 14: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

Dichlorobenzene before and after Ivey‐sol addition.

Page 15: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 16: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 17: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 18: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 19: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 20: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 21: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 22: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 23: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 24: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 25: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 26: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 27: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

20

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Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05 Jan‐06 Jul‐06 Jan‐07 Jul‐07 Jan‐08 Jul‐08 Jan‐09 Jul‐09 Jan‐10 Jul‐10

Elevations (feet M

SL)

(μg/L

TPH‐d in MW‐2 1st Pilot

2nd Pilot Elevation in feet MSL

3rd Pilot

Page 28: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

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Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05 Jan‐06 Jul‐06 Jan‐07 Jul‐07 Jan‐08 Jul‐08 Jan‐09 Jul‐09 Jan‐10 Jul‐10

Elevations (feet MSL)

(μg/L)

TPH‐d in MW‐7 1st Pilot 2nd Pilot

Elevation in Feet MSL 3rd Pilot

Page 29: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

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Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05 Jan‐06 Jul‐06 Jan‐07 Jul‐07 Jan‐08 Jul‐08 Jan‐09 Jul‐09 Jan‐10 Jul‐10

Elevations (feet M

SL)

(μg/L)

TPH‐d in MW‐11 1st Pilot2nd Pilot Elevation in Feet MSL3rd Pilot

Page 30: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

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Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05 Jan‐06 Jul‐06 Jan‐07 Jul‐07 Jan‐08 Jul‐08 Jan‐09 Jul‐09 Jan‐10 Jul‐10

Elevations (feet MSL)

(μg/L)

TPH‐d in MW‐15 1st Pilot 2nd Pilot

Elevation in feet MSL 3rd Pilot

Page 31: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

Response in MW‐7 from injections in MW‐15

Page 32: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 33: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05
Page 34: Surfactant Enhanced HVDPE Remediation of Petroleum ... · 20 25 30 35 40 45 50 10 100 1,000 10,000 100,000 1,000,000 Jul‐02 Jan‐03 Jul‐03 Jan‐04 Jul‐04 Jan‐05 Jul‐05

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