Fastness as self shade

Dyeingdepth

(1/6 SD)

LightOxidative

bleach damageWashing Water

ISO 105-B02AATCC 16E

20AFUM&S C10A

ISO 105-C06 C2S

AATCC61-2A

ISO 105-E01

Ch Ch Ch Ch/CO Ch/CO Ch/CO

Exhaust dyeing

Yellow K-HL 0.67% 5 4-5 4-5 4-5/ 5 4-5 / 5 4-5 / 4-5

Red K-HL 1.00% 4 4 4-5 4-5 / 4 4-5 / 4-5 4-5 / 4-5

Blue K-HL 0.58% 4-5 4-5 4-5 4-5 / 4-5 4-5 / 4-5 4-5 / 4-5

Violet K-HL 0.67% 4 4 4 4-5/5 4-5/5 4-5/4-5

Grey K-HL 1.00% 4-5 4-5 3-4 4-5/4-5 4-5/4-5 4-5/4-5

Continuous dyeing

Yellow K-HL 6.67g/ 5 5 4-5 4-5/5 4-5/5 4-5/5

Red K-HL 6.67g/ 4 4-5 4-5 4-5/5 4-5/5 4-5/5

Blue K-HL 6.67g/ 5 4-5 4-5 4-5/5 4-5/5 4-5/5

Violet K-HL 7.50g/ 5 4-5 4-5 4-5/5 4-5/5 4-5/5

Grey K-HL 10.00g/ 5 4-5 4 4/5 4-5/5 4/5

HEAD OFFICE 112-31 Yeomchang-Dong Kangseo-Gu, Seoul, 157-040, Korea Tel: 82-2-3665-4001 Fax: 82-2-3660-8635E-mail: kiscotech@kyungin.co.krURL: http://www.kyungin.co.kr

Edition 2012Copyrightⓒ2012 Kyung-In Synthetic Corporation. All rights reserved.

Kyung-In Synthetic Corporation

Synozol K-HL dyesReactive dyes

Kyung-In Synthetic Corporation

For Exhaust & Continuous dyeing

Synozol K-HL dyes*Material : Exhaust dyeing - Unmercerized cotton

Continuous dyeing - Mercerized cotton

NEW TO THE INDUSTRY

One trichromatic combination for multiple processes

Pale / Light shades with high light fastness

Extremely cost efficient

Unique range of dyes - market exclusive

Tailing / Listing in Pad Application eliminated

Perfect leveling in difficult shade area’s

Homogeneous Violet and Grey as supplementary products

Synozol K-HL dyes

Superior technical advantages with low cost

Can be used as an alternative to Vat dyes for pale shades

Proven dyestuff chemistry using just 3 core elements

Excellent Compatibility

Unique alternative for pale shades with good light fastness

In Exhaust and Continuous dyeing

Excellent

Compatibility

Excellent Reproducibilty !!Right First Time !!

LEVELING & REPRODUCIBILITY!

Easy to formulate

Earth shades

Low Sensitivity

to various dyeing

parameters

Synozol K-HL dyes

+++ : suitable++ : suitable with limits

+ : unsuitable

Exhaust +++

Padding Cold Pad Batch +++

Continuous PDPS +++

PDT ++

E-control ++

Cotton +++

Viscose rayon +++

PES/CO +++

PA/CO ++

Suitability

BrownYellow K-HL 0.33%Red K-HL 0.33%Blue K-HL 0.33%

YEL K-HLRED K-HLBLU K-HL

80.0%

100.0%

60.0%

40.0%

20.0%

0.0%0 10 20 30 40 50 60

min.

YEL K-HLRED K-HLBLU K-HL

80.0%

100.0%

60.0%

40.0%

20.0%

0.0%0 10 20 30 40 50 60

min.

2min 5min 10min 20min 45min 60minFixation time

Cotton

Rayon

Exha

ust d

yein

g

Synozol K-HL dyes are specially designed for pale shade dyeing,

giving improved benefits in terms of reproducibility and good light

fastness for both exhaust and continuous dyeing.

In the past, difficult shades (earth tones, greys, olives) gave problems of leveling and

light fastness in exhaust dyeing and tailing /listing issues when dyed continuously.

Vat dyes were invariantly the only alternative UNTIL NOW!

Shade (1/6 Standard Depth) in Exhaust dyeing

Synozol K-HL dyes

Yellow K-HL0.67%

Red K-HL1.00%

Blue K-HL0.58%

EXHAUST DYEING

For Cotton For Rayon

Flexible Application methods(Exhaust & Continuous dyeing)

PERFECT CONSISTENCY & REPRODUCIBILITY!

Yellow K-HL 0.33%Red K-HL 0.33%Blue K-HL 0.33%

Recipe Yellow K-HL 0.50%Red K-HL 0.25%Blue K-HL 0.25%

Yellow K-HL 0.25%Red K-HL 0.25%Blue K-HL 0.50%

Combination

Brown Olive Grey

Fastness

Low Sensitivity For Right First Time

Soda ash & Glauber’s salt

-1Da

Db

1

0.5

-0.5

-1

0

1

4

5926 8

3

-0.5 0.5 1

Soda ash(g/ ) 10 15 20

Glauber’s Salt (g/ )

20 1 2 3

30 4 5(Std) 6

40 7 8 9

Time & Temperature

-1Da

Db

1

0.5

-0.5

-1

0

17

15

141318

12

16

1011

-0.5 0.5 1

Time(min) 30 40 50

Temperature(C˚)

55 10 11 12

60 13 14(Std) 15

65 16 17 18

Exha

ust d

yein

g

Low Sensitivity to Dyeing Factors in PDPS

CONTINUOUS DYEING

3

4

5

6

7

2

1 standard condition Salt 200g/ Soda ash 20g/ NaOH 10ml/ Time 60sec

Soda(g/ ) / NaOH(ml/ )

+5/5

+60Time(sec)

Salt(g/ )

+50-5/5

-50

-30

5

3

6

7

4

2 1

duller brighterDC

gree

ner

redd

erDH

-1.5 -1

1.5

1

0.5

-0.5

-1

-1.5

-0.5 1 1.5

0.5

2 34

5

6 17

Continuous and cold pad batch dyers major problems come from tailing and side/center

shade difference when pale shades are produced. Even when light fastness is achieved the

shade continuity remained an issue UNTIL NOW!

Shade (1/6 Standard Depth) in Continuous dyeing

Synozol K-HL dyes

Yellow K-HL6.67g/

Red K-HL6.67g/

Blue K-HL6.67g/

Cont

inuo

us d

yein

g

Light Oxidativebleach damage Washing Water

ISO 105-B02 AATCC 16E 20AFU M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01

Ch Ch Ch Ch CO Ch CO Ch CO

Brown 4 4 4 4-5 5 4-5 5 4-5 5

Olive 4 4 4 4-5 5 4-5 5 4-5 5

Grey 4 4 4 4-5 5 4-5 5 4-5 5

Synozol Violet K-HL and Synozol Grey K-HL were developed to achieve easily, critical Violet and Grey pale shades with

excellent light fastness properties, good reproducibility which are difficult to dye level with trichromatic combinations.

Homogeneous dyes

Combination

Shade (1/6 Standard Depth)

Light Oxidative bleach damage Washing Water

ISO 105-B02

AATCC16E 20AFU M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01

Ch Ch Ch Ch CO Ch CO Ch CO

Recipe1 4 4 4 4-5 5 4-5 5 4-5 5

Recipe2 4 4 4 4-5 5 4-5 5 4-5 5

Recipe3 4-5 4-5 4 4-5 5 4-5 5 4-5 5

Recipe4 4 4-5 4 4-5 5 4-5 5 4-5 5

Recipe1 4 3-4 4 4-5 5 4-5 5 4-5 5

Recipe2 4 4 4-5 4-5 5 4-5 5 4-5 5

Recipe3 4-5 4-5 3-4 4 5 4-5 5 4-5 5

Recipe4 4 4-5 3-4 4 5 4-5 5 4-5 5

Cont

inuo

us d

yein

g

No Tailing & Listing

Yellow K-HL 1.10g/Red K-HL 0.90g/Blue K-HL 0.78g/

Recipe Yellow K-HL 4.05g/Red K-HL 3.12g/Blue K-HL 2.40g/

Yellow K-HL 3.20g/Red K-HL 2.50g/Blue K-HL 4.00g/

Combination

LT. Stone

Exhaust dyeing

Exha

ust d

yein

g

Continuous dyeing

Cont

inuo

us d

yein

g

Violet K-HL 0.10%Yellow K-HL 0.02%

Violet K-HL 1.0g/Yellow K-HL 0.2g/

Recipe1

Violet K-HL 0.10%Blue K-HL 0.02%

Violet K-HL 1.0g/Blue K-HL 0.2g/

Recipe2

Grey K-HL 0.10%Yellow K-HL 0.02%

Grey K-HL 1.0g/Yellow K-HL 0.2g/

Recipe3

Grey K-HL 0.10%Violet K-HL 0.02%

Grey K-HL 1.0g/Violet K-HL 0.2g/

Recipe4

LT. Brown Steel Grey

Fastness

Light OliveSynozol Yellow K-HL 2.62g/Synozol Red K-HL 2.89g/Synozol Blue K-HL 3.19g/

Left102%CMC DE= 0.2

Center100% (STD)CMC DE= 0.0

Right98%CMC DE= 0.2

Listing PropertyTailing Property

Start100% (STD)CMC DE= 0.0

End97%CMC DE= 0.3

Violet K-HL0.67%

Violet K-HL7.5g/

Grey K-HL1.00%

Grey K-HL10.0g/

Exha

ust

dyei

ngCo

ntin

uous

dy

eing

Light Oxidativebleach damage Washing Water

ISO 105-B02 AATCC 16E 20AFU M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01

Ch Ch Ch Ch CO Ch CO Ch CO

LT. Stone 4 4-5 4-5 4-5 5 4-5 5 4-5 5

LT. Brown 4 4 4-5 4-5 5 4-5 5 4-5 5

Steel Grey 4 4 4 4-5 5 4-5 5 4-5 5

60˚C10

,30

,30

,40

,30,

Auxiliary Dye Glauber's salt addition Soda ash addition Washing off

* Applicable in : - Cold Pad Batch (minimum 24hours batching time for Grey K-HL) - Pad-dry-thermofix - E-control

Exha

ust d

yein

g

Cont

inuo

us d

yein

g

Trichromatic Combination

Recommended dyeing process Recommended dyeing process

Trichromatic CombinationEXHAUST DYEING

Dye(%o.w.f) <0.1% 0.1-0.5% 0.5-1.0%

Glauber’s salt g/ 20 30 40

Soda ash g/ 10 15 15

Unmercerized Cotton

Washing offPad Dry SteamPad

Chemical Amount

Padding

Synozol Dyes Xg/

Migration Inhibitor 10g/

Wetting Agent 1g/

Reduction Inhibitor 1g/

Liquor Temperature 25˚C

Liquor Pick up 60%

DryingTemperature 120˚C

Time 1min

Alkali Padding

Soda ash 20g/

Caustic soda(38˚Be) 10m /

Glauber’s salt 200g/

Liquor Temperature 25˚C

Liquor Pick up 80%

Steaming (Fixation)

Temperature 102˚C

Time 1min

CONTINUOUS DYEING

Yellow K-HL 1.0%o.w.f

Y + R + B 0.67+0.17+0.17%o.w.f

Y + R0.67+0.33%o.w.f

Y + B0.67+0.33%o.w.f

Y + R + B 0.33+0.33+0.33%o.w.f

Y + R + B 0.33+0.50+0.17%o.w.f

Y + R0.33+0.67%o.w.f

Y + R + B 0.33+0.17+0.50%o.w.f

Y + B0.33+0.67%o.w.f

R + B0.50+0.50%o.w.f

R + B0.67+0.33%o.w.f

R + B0.83+0.17%o.w.f

Red K-HL1.0%o.w.f

R + B0.33+0.67%o.w.f

R + B0.17+0.83%o.w.f

Blue K-HL1.0%o.w.f

Yellow K-HL10.0g/

Y + R + B 6.7+1.7+1.7g/

Y + R6.7+3.3g/

Y + B6.7+3.3g/

Y + R + B 3.3+3.3+3.3g/

Y + R + B 3.3+5.0+1.7g/

Y + R3.3+6.7g/

Y + R + B 3.3+1.7+5.0g/

Y + B3.3+6.7g/

R + B5.0+5.0g/

R + B6.7+3.3g/

R + B8.3+1.7g/

Red K-HL10.0g/

R + B3.3+6.7g/

R + B1.7+8.3g/

Blue K-HL10.0g/

30,