t- ). , , · 2018-10-14 · 72 1. ( ) ( ) . 2. . 3. . . 1. allcock, h.r.; lampe, f.w. contemporary...
TRANSCRIPT
68
7
:
( -t- )
,
( ). ( )
( -t- ).
.
, ,
.
, .
.
,
.
,
.
.
�
� .
.
.
69
( 1).
RC
O
OR'O
C OH + ROH
H2O
NaOH / H3O+
1:
( )
( ) ( )
2.
2: ( ) (
)
.
H2C C
C
CH3
O
NH2
n
H2OH2C C
C
CH3
O
O-
base/acid
n
+ n NH3
CH2 C
C
H
O
O
R
n
H2O
base/acidCH2 C
C
H
O
O-
n
+ n ROH
70
( -), ( 3).
.
3:
( )
.
. .
( )
.
( -t- ),
( )
( -t- ) ( 4)
H2C
C O
OH
C
CH3
H2C
C O
C
C
CH3
H3C
CH3
CH3
OH-
4: ( -t- )
H2C C
C
H
O
O-
H2C C
C
H
O
O
R
H2C C
C
H
O
O
ROH-
71
A
( -t- )
(TFA)
100 ml 1 g o ( -t-
), 10 ml .
10 .
(
moles). 3 h.
,
.
3 3 ml 10
. ,
, , : , ,
, . 5
0,05 g ( )
5 0,05 g ( -t- ) .
.
72
1. ( ) ( )
.
2.
.
3.
.
.
1. Allcock, H.R.; Lampe, F.W. Contemporary Polymer Chemistry, 2nd ed., Prentice
Hall, Englewood Cliffs, 1990.
2. Sandlet S. R., Karo W., Bonesteel J., Perace E. M., Polymer Synthesis and
Characterization, A Laboratory Manual, Academic Press,1998.
3. Sanjua S., Tran Y., Journal of Polymer Science: Part A: Polymer Chemistry, 4305-
4319, 2008.
4. Storey R.F., Scheuer,A.D., Achord B.C., Polymer 46 (2005) 2141�2152.
5. Andre´X., Zhang M., Muller A. H., Macromol. Rapid Commun ., 26, 558�563, 2005.