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Handbook of HeterogeneousCatalysisCopyright © 2008 Wiley-VCH VerlagGmbH & Co. KGaA. All rights reserved.Last updated: 14 Mar 2008

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1 Introduction1.1 Principles of Heterogeneous CatalysisStandard ArticleAbstract | Full Text: HTML PDF (201K)

1.2 Development of the Science of CatalysisStandard ArticleAbstract | Full Text: HTML PDF (671K)

1.3 The Development of Industrial Heterogeneous CatalysisStandard ArticleAbstract | Full Text: HTML PDF (256K)

2 Preparation of Solid Catalysts

2.1 Development of Industrial Catalysts1

Standard ArticleAbstract | Full Text: HTML PDF (411K)

2.2 Computer-Aided Design of Solid CatalystsStandard ArticleAbstract | Full Text: HTML PDF (310K)

2.3 Bulk Catalysts and Supports2.3.1 Fused CatalystsStandard ArticleAbstract | Full Text: HTML PDF (187K)

2.3.2 Skeletal Metal CatalystsStandard ArticleAbstract | Full Text: HTML PDF (195K)

2.3.3 Precipitation and CoprecipitationStandard ArticleAbstract | Full Text: HTML PDF (353K)

2.3.4 Sol–Gel Process

Table of Contents : Handbook of Heterogeneous Catalysis : Wiley Int... http://mrw.interscience.wiley.com/emrw/9783527610044/hetcat/toc

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http://mrw.interscience.wiley.com/emrw/9783527610044/hetcat/toc


2.3.5 Hydrothermal Zeolite SynthesisStandard ArticleAbstract | Full Text: HTML PDF (579K)

2.3.6 Ordered Mesoporous MaterialsStandard ArticleAbstract | Full Text: HTML PDF (1262K)

2.3.7 Pillared ClaysStandard ArticleAbstract | Full Text: HTML PDF (412K)

2.3.8 Chemistry and Applications of Porous Metal–OrganicFrameworksStandard ArticleAbstract | Full Text: HTML PDF (461K)

2.3.9 Oxo-Anion Modified OxidesStandard ArticleAbstract | Full Text: HTML PDF (313K)

2.3.10 Catalysis by Ion-Exchange ResinsStandard ArticleAbstract | Full Text: HTML PDF (150K)

2.3.11 Flame HydrolysisStandard ArticleAbstract | Full Text: HTML PDF (379K)

2.3.12 Solid-State ReactionsStandard ArticleAbstract | Full Text: HTML PDF (369K)

2.3.13 Heteropoly CompoundsStandard ArticleAbstract | Full Text: HTML PDF (520K)

2.3.14 Transition Metal Carbides, Nitrides, and PhosphidesStandard ArticleAbstract | Full Text: HTML PDF (281K)

2.3.15 CarbonsStandard ArticleAbstract | Full Text: HTML PDF (3597K)

2.4 Supported Catalysts2.4.1 Preparation of Supported Catalysts by Deposition–PrecipitationStandard ArticleAbstract | Full Text: HTML PDF (779K)

2.4.2 Ion Exchange and ImpregnationStandard ArticleAbstract | Full Text: HTML PDF (280K)

2.4.3 Solid-State Ion Exchange in ZeolitesStandard ArticleAbstract | Full Text: HTML PDF (356K)

2.4.4 Metal Clusters in Zeolites


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2.4.5 Grafting and Anchoring of Transition Metal Complexesto Inorganic OxidesStandard ArticleAbstract | Full Text: HTML PDF (349K)

2.4.6 Supported Catalysts from Chemical Vapor Depositionand Related TechniquesStandard ArticleAbstract | Full Text: HTML PDF (307K)

2.4.7 Spreading and WettingStandard ArticleAbstract | Full Text: HTML PDF (396K)

2.4.8 Mechanochemical MethodsStandard ArticleAbstract | Full Text: HTML PDF (316K)

2.4.9 Immobilization of Molecular CatalystsStandard ArticleAbstract | Full Text: HTML PDF (1024K)

2.4.10 Zeolite-Entrapped Metal ComplexesStandard ArticleAbstract | Full Text: HTML PDF (280K)

2.4.11 Supported Liquid CatalystsStandard ArticleAbstract | Full Text: HTML PDF (240K)

2.4.12 Immobilization of Biological CatalystsStandard ArticleAbstract | Full Text: HTML PDF (438K)

2.5 Formation of the Final Catalyst2.5.1 Reactions During Catalyst ActivationStandard ArticleAbstract | Full Text: HTML PDF (296K)

2.5.2 Catalyst FormingStandard ArticleAbstract | Full Text: HTML PDF (1010K)

2.6 Standard Catalysts2.6.1 Non-Zeolitic Standard CatalystsStandard ArticleAbstract | Full Text: HTML PDF (257K)

2.6.2 Zeolite Standard Catalysts and Related Activities of theInternational Zeolite AssociationStandard ArticleAbstract | Full Text: HTML PDF (144K)

3 Characterization of Solid Catalysts3.1 Physical Properties

3.1.1 Surface Area and PorosityStandard ArticleAbstract | Full Text: HTML PDF (253K)


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3.1.2 Particle Size and Dispersion MeasurementsStandard ArticleAbstract | Full Text: HTML PDF (638K)

3.1.3.1 X-Ray Powder DiffractionStandard ArticleAbstract | Full Text: HTML PDF (191K)

3.1.3.2 Applications of X-ray Absorption Spectroscopy inHeterogeneous Catalysis: EXAFS, Atomic XAFS, and DeltaXANESStandard ArticleAbstract | Full Text: HTML PDF (1179K)

3.1.3.3 Electron Microscopy and DiffractionStandard ArticleAbstract | Full Text: HTML PDF (1692K)

3.1.3.4 Scanning Probe TechniquesStandard ArticleAbstract | Full Text: HTML PDF (1660K)

3.1.3.5 Heterogeneous Catalysis and High Electric FieldsStandard ArticleAbstract | Full Text: HTML PDF (625K)

3.1.3.6 Gamma SpectroscopyStandard ArticleAbstract | Full Text: HTML PDF (430K)

3.1.3.7 Solid-State NMR SpectroscopyStandard ArticleAbstract | Full Text: HTML PDF (390K)

3.1.3.8 Vibrational SpectroscopyStandard ArticleAbstract | Full Text: HTML PDF (592K)

3.1.3.9 Neutron ScatteringStandard ArticleAbstract | Full Text: HTML PDF (300K)

3.1.3.10 Morphological CharacteristicsStandard ArticleAbstract | Full Text: HTML PDF (609K)

3.1.4 Mechanical PropertiesStandard ArticleAbstract | Full Text: HTML PDF (141K)

3.2 Chemical Properties3.2.1 Bulk Chemical CompositionStandard ArticleAbstract | Full Text: HTML PDF (255K)

3.2.2 Surface Chemical CompositionStandard ArticleAbstract | Full Text: HTML PDF (1148K)

3.2.3.1 X-Ray Photoelectron and Auger ElectronSpectroscopyStandard Article


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Abstract | Full Text: HTML PDF (209K)

3.2.3.2 UV–Vis–NIR and EPR SpectroscopiesStandard ArticleAbstract | Full Text: HTML PDF (1510K)

3.2.3.3 Photoluminescence Spectroscopy and Its Applicationto the Characterization of Active Sites and ReactionDynamics in CatalysisStandard ArticleAbstract | Full Text: HTML PDF (245K)

3.2.3.4 Muon Spin Spectroscopy of Transient Radicals inZeolitesStandard ArticleAbstract | Full Text: HTML PDF (278K)

3.2.3.5 Temperature-Programmed Reduction and Oxidation1


3.2.4.1 Concepts and Analysis of Surface Acidity andBasicityStandard ArticleAbstract | Full Text: HTML PDF (378K)

3.2.4.2 Thermochemical CharacterizationStandard ArticleAbstract | Full Text: HTML PDF (216K)

3.2.4.3 Infrared Spectroscopy for the Characterization ofSurface Acidity and BasicityStandard ArticleAbstract | Full Text: HTML PDF (392K)

3.2.4.4 NMR Spectroscopy for the Characterization ofSurface Acidity and BasicityStandard ArticleAbstract | Full Text: HTML PDF (273K)

3.2.5.1 Metal–Support InteractionsStandard ArticleAbstract | Full Text: HTML PDF (274K)

3.2.5.2 Oxide–Support InteractionsStandard ArticleAbstract | Full Text: HTML PDF (457K)

3.2.6 Carbonaceous DepositsStandard ArticleAbstract | Full Text: HTML PDF (451K)

3.3 IUPAC Recommandations3.3.1 Reporting Physisorption Data for Gas/Solid SystemsStandard ArticleAbstract | Full Text: HTML PDF (207K)

3.3.2 Methods and Procedures for Catalyst CharacterizationStandard ArticleAbstract | Full Text: HTML PDF (305K)

4 Model Systems


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4.1 Single Crystal SurfacesStandard ArticleAbstract | Full Text: HTML PDF (524K)

4.2 Supported Metal Cluster CatalystsStandard ArticleAbstract | Full Text: HTML PDF (253K)

4.3 Metallic GlassesStandard ArticleAbstract | Full Text: HTML PDF (347K)

4.4 Bimetallic Model CatalystsStandard ArticleAbstract | Full Text: HTML PDF (338K)

4.5 Ultrathin Oxide FilmsStandard ArticleAbstract | Full Text: HTML PDF (1189K)

4.6 The Reactions of Model Metal Oxide SurfacesStandard ArticleAbstract | Full Text: HTML PDF (886K)

4.7 Microcrystalline Oxides: Bridging the Gap Between SingleCrystals and Dispersed OxidesStandard ArticleAbstract | Full Text: HTML PDF (223K)

4.8 Oxide Solid SolutionsStandard ArticleAbstract | Full Text: HTML PDF (205K)

5 Elementary Steps and Mechanisms5.1 Chemisorption

5.1.1 Principles of ChemisorptionStandard ArticleAbstract | Full Text: HTML PDF (1153K)

5.1.2 Reactivity Index Relations in TheoreticalHeterogeneous CatalysisStandard ArticleAbstract | Full Text: HTML PDF (439K)

5.2 Microkinetics5.2.1 Rates of Catalytic ReactionsStandard ArticleAbstract | Full Text: HTML PDF (263K)

5.2.2 Dynamics of Surface ReactionsStandard ArticleAbstract | Full Text: HTML PDF (382K)

5.2.3 Theoretical Modelling of Catalytic ReactionsStandard ArticleAbstract | Full Text: HTML PDF (455K)

5.2.4 Non-Linear Dynamics: Oscillatory Kinetics and Spatio-Temporal Pattern FormationStandard ArticleAbstract | Full Text: HTML PDF (970K)


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5.2.5 Isotopic Labeling and Kinetic Isotope EffectsStandard ArticleAbstract | Full Text: HTML PDF (455K)

5.2.6 Transient Catalytic StudiesStandard ArticleAbstract | Full Text: HTML PDF (326K)

5.3 Factors Influencing Catalytic Action5.3.1 Substituent EffectsStandard ArticleAbstract | Full Text: HTML PDF (223K)

5.3.2 Spillover EffectsStandard ArticleAbstract | Full Text: HTML PDF (273K)

5.3.3 Ensemble and Ligand Effects in Metal CatalysisStandard ArticleAbstract | Full Text: HTML PDF (244K)

5.3.4 Promoters and PoisonsStandard ArticleAbstract | Full Text: HTML PDF (748K)

5.4 Hydrocarbon Reaction MechanismsStandard ArticleAbstract | Full Text: HTML PDF (237K)

5.5 Computer Simulations5.5.1 Modeling of Structures and Reactivity of SolidCatalystsStandard ArticleAbstract | Full Text: HTML PDF (682K)

5.5.2 Computer Simulation of Sorption and Transport inZeolitesStandard ArticleAbstract | Full Text: HTML PDF (351K)

5.5.3 Computer Simulations of Shape Selectivity EffectsStandard ArticleAbstract | Full Text: HTML PDF (306K)

6 Makrokinetics and Transport Processes

6.1 Rate Procurement and Kinetic Modelling1


6.2 Determination of Diffusion Coefficients in Porous MediaStandard ArticleAbstract | Full Text: HTML PDF (192K)

6.3 Simultaneous Heat and Mass Transfer and Chemical ReactionStandard ArticleAbstract | Full Text: HTML PDF (1056K)

6.4 Magnetic Resonance ImagingStandard ArticleAbstract | Full Text: HTML PDF (922K)


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6.5 11C, 13N and 15O Positron (β+) Emitters in Catalysis ResearchStandard ArticleAbstract | Full Text: HTML PDF (257K)

6.6 Computational Fluid Dynamics Simulation of Catalytic ReactorsStandard ArticleAbstract | Full Text: HTML PDF (433K)

7 Activity Loss7.1 Deactivation and RegenerationStandard ArticleAbstract | Full Text: HTML PDF (261K)

7.2 Recycling of Spent Catalysts7.2.1 Recycling of Spent Catalysts Containing PreciousMetalsStandard ArticleAbstract | Full Text: HTML PDF (234K)

7.2.2 Recycling of Spent Catalysts Containing Base MetalsStandard ArticleAbstract | Full Text: HTML PDF (130K)

8 Special Catalytic Systems8.1 Electrocatalysis

8.1.1 Fundamentals of ElectrocatalysisStandard ArticleAbstract | Full Text: HTML PDF (495K)

8.1.2 Electrochemical Modification of Catalytic ActivityStandard ArticleAbstract | Full Text: HTML PDF (599K)

8.1.3 Industrial ElectrocatalysisStandard ArticleAbstract | Full Text: HTML PDF (425K)

8.2 Photocatalysis: Development of Highly FunctionalTitanium Oxide PhotocatalystsStandard ArticleAbstract | Full Text: HTML PDF (636K)

8.3 Chemical Sensors Based on Catalytic ReactionsStandard ArticleAbstract | Full Text: HTML PDF (596K)

8.4 Heterogeneous Catalysis in Non-Conventional SolventsStandard ArticleAbstract | Full Text: HTML PDF (309K)

8.5 SonocatalysisStandard ArticleAbstract | Full Text: HTML PDF (322K)

9 Laboratory Testing of Solid Catalysts

9.1 Laboratory Catalytic Reactors: Aspects of Catalyst Testing1


9.2 Ancillary Techniques in Laboratory Units for Testing Solid


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CatalystsStandard ArticleAbstract | Full Text: HTML PDF (171K)

9.3 High-Throughput Experimentation in Heterogeneous CatalysisStandard ArticleAbstract | Full Text: HTML PDF (489K)

10 Reaction Engineering10.1 Catalytic Fixed-Bed ReactorsStandard ArticleAbstract | Full Text: HTML PDF (1141K)

10.2 Fluidized-Bed Reactors1


10.3 Slurry Reactors1


10.4 Unsteady-State Reactor OperationStandard ArticleAbstract | Full Text: HTML PDF (320K)

10.5 Short Contact-Time ReactorsStandard ArticleAbstract | Full Text: HTML PDF (257K)

10.6 Catalytic DistillationStandard ArticleAbstract | Full Text: HTML PDF (769K)

10.7 Catalytic Membrane ReactorsStandard ArticleAbstract | Full Text: HTML PDF (1031K)

10.8 Microstructured Reactors1


11 Environmental Catalysis11.1 Catalysis in Environmental ProtectionStandard ArticleAbstract | Full Text: HTML PDF (160K)

11.2 Automotive Exhaust Treatment1Standard ArticleAbstract | Full Text: HTML PDF (1795K)

11.3 Flue Gases from Stationary SourcesStandard ArticleAbstract | Full Text: HTML PDF (815K)

11.4 Catalytic DehalogenationStandard ArticleAbstract | Full Text: HTML PDF (190K)

11.5 Solid Catalysts for the Oxidation of Volatile OrganicCompoundsStandard Article


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11.6 Catalytic CombustionStandard ArticleAbstract | Full Text: HTML PDF (261K)

11.7 Catalytic Routes to Hydro(chloro)fluorocarbonsStandard ArticleAbstract | Full Text: HTML PDF (147K)

11.8 Heterogeneous Catalysis in the TroposphereStandard ArticleAbstract | Full Text: HTML PDF (218K)

11.9 Conversion of Biomass on Solid CatalystsStandard ArticleAbstract | Full Text: HTML PDF (638K)

11.10 Catalysis in Water RemediationStandard ArticleAbstract | Full Text: HTML PDF (281K)

12 Inorganic Reactions12.1 Ammonia SynthesisStandard ArticleAbstract | Full Text: HTML PDF (1392K)

12.2 Ammonia OxidationStandard ArticleAbstract | Full Text: HTML PDF (1096K)

12.3 Hydrocyanic Acid (HCN) ProductionStandard ArticleAbstract | Full Text: HTML PDF (512K)

12.4 Hydrogen Sulfide to Sulfur (Claus Process)Standard ArticleAbstract | Full Text: HTML PDF (229K)

12.5 Oxidation of Sulfur DioxideStandard ArticleAbstract | Full Text: HTML PDF (418K)

12.6 Müller–Rochow Synthesis: The Direct Process toMethylchlorosilanesStandard ArticleAbstract | Full Text: HTML PDF (211K)

12.7 Catalytic Decomposition of Energetic Compounds: GasGenerators and Propulsion1


13 Energy‑Related Catalysis13.1 Perspectives in Oil RefiningStandard ArticleAbstract | Full Text: HTML PDF (383K)

13.2 HydrotreatingStandard ArticleAbstract | Full Text: HTML PDF (385K)


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13.3 HydrodemetalationStandard ArticleAbstract | Full Text: HTML PDF (345K)

13.4 Catalytic ReformingStandard ArticleAbstract | Full Text: HTML PDF (209K)

13.5 Fluid Catalytic CrackingStandard ArticleAbstract | Full Text: HTML PDF (536K)

13.6 Hydrocracking and Catalytic DewaxingStandard ArticleAbstract | Full Text: HTML PDF (595K)

13.7 IsomerizationStandard ArticleAbstract | Full Text: HTML PDF (316K)

13.8 Alkylation of Isobutane with Light Alkenes on Solid CatalystsStandard ArticleAbstract | Full Text: HTML PDF (301K)

13.9 OligomerizationStandard ArticleAbstract | Full Text: HTML PDF (173K)

13.10 EtherificationStandard ArticleAbstract | Full Text: HTML PDF (272K)

13.11 Steam Reforming1


13.12 Water Gas Shift and COS RemovalStandard ArticleAbstract | Full Text: HTML PDF (239K)

13.13 Methanol SynthesisStandard ArticleAbstract | Full Text: HTML PDF (397K)

13.14 Methanol-to-HydrocarbonsStandard ArticleAbstract | Full Text: HTML PDF (381K)

13.15 The Fischer–Tropsch (FT) Synthesis ProcessesStandard ArticleAbstract | Full Text: HTML PDF (338K)

13.16 Gas-to-LiquidsStandard ArticleAbstract | Full Text: HTML PDF (228K)

13.17 Oxidative Coupling of MethaneStandard ArticleAbstract | Full Text: HTML PDF (712K)

13.18 Catalysis in Direct Coal LiquefactionStandard Article


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13.19 Catalysis in Coal and Carbon GasificationStandard ArticleAbstract | Full Text: HTML PDF (167K)

13.20 Fuel Cell Related Catalysis13.20.1 Fuel ProcessorsStandard ArticleAbstract | Full Text: HTML PDF (923K)

13.20.2 Fuel CellsStandard ArticleAbstract | Full Text: HTML PDF (731K)

14 Organic Reactions14.1 Aromatization of Light AlkanesStandard ArticleAbstract | Full Text: HTML PDF (188K)

14.2 Ring Opening of AromaticsStandard ArticleAbstract | Full Text: HTML PDF (303K)

14.3 Alkylation of AromaticsStandard ArticleAbstract | Full Text: HTML PDF (246K)

14.4 Isomerization and Transalkylation of AlkylaromaticsStandard ArticleAbstract | Full Text: HTML PDF (352K)

14.5 Non-Oxidative Activation of AlkanesStandard ArticleAbstract | Full Text: HTML PDF (182K)

14.6 Dehydrogenation of AlkanesStandard ArticleAbstract | Full Text: HTML PDF (272K)

14.7 Dehydrogenation of EthylbenzeneStandard ArticleAbstract | Full Text: HTML PDF (185K)

14.8 Metathesis of AlkenesStandard ArticleAbstract | Full Text: HTML PDF (233K)

14.9 Dehydrogenation of Alcohols: FormaldehydeStandard ArticleAbstract | Full Text: HTML PDF (218K)

14.10 Hydrogenation Reactions14.10.1 Selective Hydrogenation of HydrocarbonsStandard ArticleAbstract | Full Text: HTML PDF (1046K)

14.10.2 Selective Hydrogenation of FunctionalizedHydrocarbonsStandard ArticleAbstract | Full Text: HTML PDF (275K)


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14.10.3 Regioselective HydrogenationsStandard ArticleAbstract | Full Text: HTML PDF (1258K)

14.10.4 Heterogeneous Catalysis in OleochemistryStandard ArticleAbstract | Full Text: HTML PDF (345K)

14.11 Selective Oxidations14.11.1 Fundamentals of Hydrocarbon OxidationStandard ArticleAbstract | Full Text: HTML PDF (391K)

14.11.2 Oxidative Dehydrogenation of AlkanesStandard ArticleAbstract | Full Text: HTML PDF (251K)

14.11.3 Oxyfunctionalization of AlkanesStandard ArticleAbstract | Full Text: HTML PDF (501K)

14.11.4 Oxyfunctionalization of Alkyl AromaticsStandard ArticleAbstract | Full Text: HTML PDF (243K)

14.11.5 Direct Ring Oxidation of Aromatics to PhenolsStandard ArticleAbstract | Full Text: HTML PDF (242K)

14.11.6 Heterogeneous Catalysis of Alkene EpoxidationStandard ArticleAbstract | Full Text: HTML PDF (230K)

14.11.7 Acetoxylation of EthyleneStandard ArticleAbstract | Full Text: HTML PDF (208K)

14.11.8 Oxidation of Low-Molecular-Weight HydrocarbonsStandard ArticleAbstract | Full Text: HTML PDF (426K)

14.11.9 AmmoxidationStandard ArticleAbstract | Full Text: HTML PDF (660K)

14.11.10 AmmoximationStandard ArticleAbstract | Full Text: HTML PDF (121K)

14.11.11 Oxidation of Alcohols with Molecular OxygenStandard ArticleAbstract | Full Text: HTML PDF (274K)

14.11.12 Phenol Hydroxylation and Related OxidationsStandard ArticleAbstract | Full Text: HTML PDF (203K)

14.12 Amination ReactionsStandard ArticleAbstract | Full Text: HTML PDF (233K)

14.13 Halogenation ReactionsStandard Article


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14.14 Acylation of AromaticsStandard ArticleAbstract | Full Text: HTML PDF (203K)

14.15 Elimination and Addition ReactionsStandard ArticleAbstract | Full Text: HTML PDF (178K)

14.16 Stereoselective Reactions14.16.1 Chiral Surfaces and Enantioselective CatalysisStandard ArticleAbstract | Full Text: HTML PDF (440K)

14.16.2 Enantioselective Reactions on Anchored ChiralComplexesStandard ArticleAbstract | Full Text: HTML PDF (284K)

14.16.3 Diastereoselective CatalysisStandard ArticleAbstract | Full Text: HTML PDF (1238K)

14.17 Miscellaneous Catalytic Systems14.17.1 Hydroformylation on Solid CatalystsStandard ArticleAbstract | Full Text: HTML PDF (339K)

14.17.2 Wacker Chemistry with Solid CatalystsStandard ArticleAbstract | Full Text: HTML PDF (252K)

14.17.3 Oxidations on Immobilized Molecular CatalystsStandard ArticleAbstract | Full Text: HTML PDF (230K)

14.17.4 Chemicals from Carbon DioxideStandard ArticleAbstract | Full Text: HTML PDF (202K)

15 Polymerization Reactions15.1 Review of the Phillips Chromium Catalyst for EthylenePolymerizationStandard ArticleAbstract | Full Text: HTML PDF (789K)

15.2 Polymerization on Molecular CatalystsStandard ArticleAbstract | Full Text: HTML PDF (1117K)

16 Reactions on Immobilized Biocatalysts1


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tabla de contenidos handbook of heterogeneous catalysis

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