German Society for Petroleum and CoalScience and Technology

Tagungsbericht 2015-2

Preprints of the DGMK-Conference“Synthesis Gas Chemistry”

October 7 — 9, 2015, Dresden, Germany

(Authors' Manuscripts)

edited by S. Ernst, A. Behr, M. Bender,H. Hager, A. Jess, M. Marchionna

CONTENTS

(T7702

Adding Value to Syngas 7C. Dwyer

Synthesis Gas: A Versatile Key to Petrochemicals, Fuels andPowerM. Marchionna

Synthesis Gas Production via Reverse Water-Gas Shift —Co-Conversion of Gaseous HydrocarbonsA. Wolf, C. Kern, A. Jess

Syngas in the Isocyanate Value ChainW. Mackenroth

Sustainability as Driver for Syngas Innovation 77H. Dialer, M. Estenfelder

Industrial Hydrogen and Syngas Production — State of the Art& 43New DevelopmentN. Schódel

Hierarchical Zeolites as Catalysts for Gasoline Synthesis from ^Dimethyl EtherS. Pitter, T. N. Otto, M. Zimmermann, E. Dinjus, J. Sauer

Methanol to Propylene: A Proven Technology for on-purposePropylene ProductionS. Haag, M. Rothaemel, Lin Lin, F. Castillo-Welter, M. Gorny

CtL/CtG Products as Feedstock for Established Value Added UChainsJ. Hannes, U. Overhoff, T. Liese

Integrated Syngas Cleaning and CO; Removal for Medium-scale 83Coal-to-SNG PlantsP. Treiber, J. Leimert, M. Neubert, J. Karl

Reactions, Thermodynamics, Production and Syntheses:Synthesis Gas (SynGas) via Integrated Ceramic MembraneOxygen-Generator in Multi-Reaction-SynGas-Reactor plusSyntheses-ReactorsH. Klefenz

Direct Synthesis of Dimethyl Ether from Syngas:Catalysts as Enablers of Energy-efficient Process DesignE. Schwab, S. A. Schunk, S. Schuster, A. Peschel, H. Schmaderer,N. Schódel, J. Fendt, H. Klein

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The Kinetics of the Direct Synthesis of Dimethyl Ether (DME)from SyngasT. Henrich, M. Betz, J. Abeln, J. Sauer

Accelerated Catalyst Testing for Synthesis Gas BasedReactionsC. Knobloch, A. Haas, T. Kaltschmitt

Hydroformylation — State of the Art and Perspectives ?R. Franke

Process Development for the 2Hydroformylation/Hydroesterification of Methyl 10-Undecenoate— From Laboratory to Miniplant ScaleA. J. Vorholt, T. Gaide, J. Dreimann, A. Behr

Production of Oxygenate Fuels from Biomass-derivedSynthesis GasU. Arnold, L. Lautenschütz, D. Oestreich, J. Sauer

Higher Alcohol Synthesis over Na-modified Co-Cu Catalysts:Co;C Formation and Effect of Surface CompositionJ. Anton, J. Nebel, C. Froese, R. Kleinschmidt, T. Quandt, H. Ruland,S. Kaluza, M. Muhler

Catalytic Tar Reforming of Biomass-derived Synthesis Gas:Influence of the Catalyst, Gas Composition and SulfurPoisoningC. Hamel, S. Kaluza, C. Unger

Synthesis Gas from Thermo-chemical Difficult BiomassS. Vodegel, F. Müller

How Methane Pyrolysis Can Lead to more Sustainable Syngas (77Production and Carbon for the Steel Industry: The GtF&SConceptS. A. Schunk, K. Büker, A. Bode, V. Góke, U. Janhsen,M. Hensmann, D. Agar

Synthesis of Mixed Low Carbon Alcohols from Syngas overK/Co-MOoS; Catalysts: Influence of Precipitation EnvironmentSu Liu, Qingying Song, Haibo Zhou, Yangdong Wang, Weimin Yang

Direct Single-stage Gasoline Synthesis from SyngasE. Lorenz, P. Wehling, M. Schlereth, B. Kraushaar-Czarnetzki

DGMK-Tagungsbericht 2015-2

Postersession:

Liquid Hydrocarbon Synthesis under Transient Operation inLab-Scale ReactorsH. Eilers, M. Ruf, G. Schaub

Fischer-Tropsch Synthesis: Modelling of Reaction-diffusion ina 187Single Cobalt Catalyst Particle Using CO;-rich Synthesis GasF. Póhlmann, A. Jess

Syngas Generation and Fischer-Tropsch Synthesis in Compact 195Chemical Reactors for a Containerized Gas-to-Liquid ProcessP. Piermartini, L. Bruebach, M. Loewert, R. Duerrschnabel,P. Pfeifer, T. Boeltken

Flame Spray Pyrolysis Synthesized Co and Co/Ru BasedCatalysts for the Thermochemical GTL — Fischer TropschProcessA. Comazzi, C. Pirola, A. Di Michele, M. Compagnoni, F. Galli,S. Cane, F. Manenti, | Rossetti, C. L. Bianchi

Production of Higher Alcohols from Synthesis GasM. Schaller, E. Reichelt, D. Mànnel, M. Jahn

FT Synthesis Catalyst Prepared by Reductive Deposition ofCobalt with NaBH,O. L. Eliseev, M. A. Kamorin, P. E. Davydov, A. L. Lapidus

Thermal and Catalytic Decomposition of Formic Acid forSynthesis Gas Production in Liquid PhaseK. Glowienka, A. Duerksen, C. Kern, A. Jess

Dry Reforming of Methane over a Ni Spinel with BimodalPorosityJ. Titus, J. Kullmann, J. Hill, D. Enke, N. Wilde, R. Gláser

Influence of the Active Metal on the Product Gas Composition :for Dry Reforming of MethaneM. Steib, A. Jentys, J. A. Lercher

Integrated Concept to Utilize Biochemical GeneratedCO; for Thermochemical Fuel ProductionC. Schweitzer

Hydroesterification of methyl 10-undecenoate inThermomorphic Multicomponent Solvent Systems — Designingnew Reaction Systems in Laboratory ScaleT. Gaide, A. Behr, A. J. Vorholt

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Process Development for the Hydroformylation of Long Chain 77Olefins and Renewables Using TMS Systems in a MiniplantJ. Dreimann, T. Gaide, A. Behr, A. J. Vorholt

Hydroformylation Reactor Design Under Model andDesign UncertaintiesN. M. Kaiser, R. J. Flassig, K. Sundmacher

The Jet Loop Reactor as a Versatile Reactor Concept forHomogeneous CatalysisH. Warmeling, A. Hüser, S. Dohrn, A. J. Vorholt

Asymmetric Hydroformylation as an Alternative Access toFunctionalized Chiral PhosphonatesL. Domke, A. Borner, A. Behr

2,7-Octadienol as Starting Material for Potential Value Products 253K. A. Ostrowski, D. Vogelsang, A. J. Vorholt

Rhodium-catalyzed Reductive Carbonylation of lodobenzene 774O. L. Eliseev, T. N. Bondarenko, À. L. Lapidus

Thermodynamic Assessment of HydrocarbonsTransformations, Obtained at the Processing ofAssociated Petroleum GasE. M. Movsumzade, O. Yu. Poletaeva, A. V. Borodin, D. Zh. Latypova,S. A. Vertyagin

Liquefied Petroleum Gas Enrichment by Zeolite Membranes for 273Low-temperature Steam Reforming of Natural GasR. Dragomirova, S. Kreft, G. Georgi, D. Seeburg, S. Wohirab

improved Catalytic Properties of VOX Catalysts Supported on TMetal Functionalized SBA-15 for the Oxidation of Methane toFormaldehydeE. Schónborn, S. Wohlrab, V. N. Kalevaru, P. Wallis, A. Martin

Methanol as the Precursor of the True Electrophilic Reactantin 27°"the Multi-step Methylation of Phenolics Catalysed by MixedMetal Oxides: Superior Performance of FeVO, CatalystT. Tabanelli, S. Passeri, C. Lucarelli, D. Zhambakin, F. Cavani

n-Pentane and n-Hexane Hydro-isomerization over PromotedPd/HZSM-5 CatalystsLuu Cam Loc, Dao Thi Kim Thoa, Nguyen Tri, Ha Cam Anh,N. A.Gaidai, Yu. A. Agafonov, A. L. Lapidus

State of the Art Technologies for a Comprehensive ChemicalCharacterization of Syncrude and Downstream MatricesT. Grôger, À. Sutherland, B. Gruber, M. Mthembu, M. Jennerwein,M. Eschner, T. Wilharm, R. Zimmermann

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