test report: 17 - benetton groupstatic.benettongroup.com/wp-content/uploads/2018/03/... ·...

TEST REPORT: 17.27813

of 2

*17.27813* 17.27813

This report is composed by 7 pages, of which: 2 pages for the summary 5 pages for the Report 17.27813a APPLICANT OLIMPIAS GROUP SRL

LAB NO: (IT) 17.27813

Via delle Tezze, 1 DATE IN: 16/6/2017 31050 Ponzano Veneto (TV) DATE OUT: 7/7/2017 PAGE: 2

Facility: CROATIA: OLIMPIAS TEXTILE D.O.O. Vukovarska, 219 - 31000 Osijek

Sample Description:

INCOMING WATER Date and hour of sampling: June, 13th 2017 at 09:40 Sampling location: Well Water Sampling method: Single grab Sampling by: Client Sampling Record N°: //

TEST REPORT: 17.27813 dated 7/7/2017

of 2

TEST PERFORMED CONCLUSIONS

Alkylphenol and Alkylphenol ethoxylates (AP / APEOs) //

Organotin compounds //

Metals //

Sulfide //

Sulfite //

Chemical Laboratory Supervisor Claudio Sironi

REMARKS 1. It is prohibited the partial reproduction, any changes or modifications of this test

report. The results are exclusively referred to the samples tested.

Issue date:23 Jun 2017

201707 Jul 2017

Test beginning:

DATES APPLICANT

OLIMPIAS GROUP SRL

TEST REPORT: 17.27813a dated 7 July 2017

T F A RD

This section is an integral part of the TEST REPORT 17.27813

17.27813a

SulfideIdentification Parts

INCOMING WATER - CROATIA: OLIMPIAS TEXTILE D.O.O. Vukovarska, 219 - 31000 Osijek

SAMPLE DESCRIPTION (no. 356499)

Sulfide

Method: According to APAT CNR IRSA 4160 MAN 29 2003

Instrument: Laboratory equipment

Incoming water 0,07

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is lower than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to APAT CNR IRSA 4160 MAN 29 2003 Sulfide

Note:

page 1 of 5MD Standard Report CH_v5/14

SulfiteIdentification Parts

TEST REPORT: 17.27813a dated 7 Jul 2017

Sulfite

Method: According to APAT CNR IRSA 4150B MAN 29 2003


T F A RD

52029

Incoming water 0,4




Legend:

Requirements:


Reference: According to APAT CNR IRSA 4150B MAN 29 2003 Sulfite

Note:


Identification Parts

52003


Alkylphenol and Alkylphenol Ethoxylates

Method: According to ISO 18857-2 and ISO 18254-1

Instrument: H.P.L.C.with DAD/MSD detectors and Gaschromatograph with mass detector (GC-MS)

T F A RD

Nonylphenol (NP)

Octylphenol (OP)

Octylphenol ethoxylates, (OPEO)

Nonylphenol ethoxylates(NPEO)

104-40-511066-49-225154-52-384852-15-3140-66-91806-26-427193-28-89002-93-19036-19-568987-90-69016-45-926027-38-337205-87-168412-54-4127087-87-0

< 5

< 5

< 5

< 5

Incoming water

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 18857-2 and ISO 18254-1 Alkylohenol and Alkylphenol EthoxylatesRequirements:

Conclusion: See results.Reference:

Note:


Identification Parts Results

52008


Organotin Compounds

Method: According to ISO 17353

Instrument: Gas - Chromatograph with Mass Detector (GC-MSD)

T F A RD

METDMTTMTMBTDBTTBTMPTDPTTPTMOTDOTTOT

MultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultiple

< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01

Incoming water

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)MET : Monomethyltin; - DMT: Dimethyltin; - TMT : Trimethyltin; MBT : Monobutyltin; - DBT : Dibutyltin; - TBT :Tributyltin; - MPT : Monophenyltin; - DPT : Diphenyltin; - TPT : Triphenyltin; - MOT : Monooctyltin; - DOT : Dioctyltin; -TOT : Trioctyltin.

Legend:

According to ISO 17353 Organotin CompoundsRequirements:


Note:



52024


Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,010,132

< 0,01< 0,25< 0,05

3,68< 0,05

< 0,005

Incoming water

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:


Note:

page 5 of 5MD Standard Report CH_v5/14 ••• END OF REPORT •••


Page 1 of 2

*17.27814* 17.27814


LAB NO: (IT) 17.27814



Sample Description:

RAW WASTEWATER Date and hour of sampling: June, 13th 2017 at 10:40 Sampling location: Homogenization Tank Sampling method: Single grab Sampling by: Client Sampling Record N°: //


Page 2 of 2



Chlorinated Benzenes and Toluenes //

Chlorophenols //

Azo-dyes //

Colourants - Carcinogenic //

Colourants – Disperse //

Flame Retardants //

Glycols //

Halogenated solvents //


Perfluorinated compounds (PFCs) //

Phthalates //

Polycyclic aromatic hydrocarbons //

Organic Volatile compounds //

Metals //

Cr (VI) - Hexavalent Chromium //

Sulfide //

Sulfite //

Cyanide //




Issue date:19 Jun 2017201707 Jul 2017

Test beginning:

DATES APPLICANT

OLIMPIAS GROUP SRL


T F A RD


17.27814a

Cr VIIdentification Parts

RAW WASTEWATER - CROATIA: OLIMPIAS TEXTILE D.O.O. Vukovarska, 219 - 31000 Osijek


Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

Raw wastewater < 0,001




Legend:

Requirements:


Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:




Sulfide



T F A RD

52028

Raw wastewater 2,0




Legend:

Requirements:



Note:




Sulfite



T F A RD

52029

Raw wastewater 13,6




Legend:

Requirements:



Note:


CyanideIdentification Parts


Cyanide


Instrument: UV-Visible Spectrophotometer

T F A RD

52040

Raw wastewater < 0,05


The symbol < followed by a number indicates that the concentration of the substance is less than the limit of


Legend:

Requirements:


Reference:According to APAT CNR IRSA 4070 MAN 29 2003 Cyanide

Note:


Identification Parts Result

52000


Chlorobenzenes and Chlorotoluenes

Method: According to USEPA 8260B, 8270D

Instrument: Gaschromatograph with Mass detector

T F A RD

Monochlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,3,5-trichlorobenzene1,2,3,4-tetrachlorobenzene1,2,3,5-tetrachlorobenzene1,2,4,5-tetrachlorobenzenePentachlorobenzeneHexachlorobenzene2-chlorotoluene3-chlorotoluene4-chlorotoluene2,3-dichlorotoluene2,4-dichlorotoluene2,5-dichlorotoluene2,6-dichlorotoluene3,4-dichlorotoluene3,5-dichlorotoluene2,3,4-trichlorotoluene2,3,6-trichlorotoluene2,4,5-trichlorotoluene2,4,6-trichlorotoluene3,4,5-trichlorotoluene2,3,4,5-tetrachlorotoluene2,3,5,6-tetrachlorotoluene2,3,4,6-tetrachlorotoluenePentachlorotoluene

108-90-795-50-1541-73-1106-46-787-61-6120-82-1108-70-3634-66-2634-90-295-94-3608-93-5118-74-195-49-8108-41-8106-43-432768-54-095-73-819398-61-9118-69-495-75-025186-47-47359-72-02077-46-56639-30-123749-65-721472-86-676057-12-029733-70-8875-40-1877-11-2

< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8260B, 8270D Chlorobenzenes and ChlorotoluenesRequirements:


Note:



52001


Chlorophenols

Method: According to USEPA 8270D

Instrument: Gas Chromatograph with Mass Detector (MS)

T F A RD

2-Chlorophenol3-Chlorophenol4-Chlorophenol2,3-Dichlorophenol2,4-Dichlorophenol2,5-Dichlorophenol2,6-Dichlorophenol3,4-Dichlorophenol3,5-Dichlorophenol2,3,4-Trichlorophenol2,3,5-Trichlorophenol2,3,6-Trichlorophenol2,4,5-Trichlorophenol2,4,6-Trichlorophenol3,4,5-Trichlorophenol2,3,4,5-Tetrachlorophenol2,3,4,6-Tetrachlorophenol2,3,5,6-TetrachlorophenolPentachlorophenol

95-57-8108-43-0106-48-9576-24-9120-83-2583-78-887-65-095-77-2591-35-515950-66-0933-78-8933-75-595-95-488-06-2609-19-84901-51-358-90-2935-95-587-86-5

< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5

Raw wastewater


Legend:

According to USEPA 8270D ChlorophenolsRequirements:


Note:



52002


Dyes - Azo

Method: According to EN 14362-1 , EN 14362-3

Instrument: Liquid chromatograph with Mass selective detector (HPLC -MS); Gas chromatograph with Mas selective detector (GC -MS).

T F A RD

4,4’-methylene-bis-(2-chloro-aniline)4,4’-methylenedianiline4,4’-oxydianiline4-chloroaniline3,3’-dimethoxylbenzidine3,3’-dimethylbenzidine6-methoxy-m-toluidine2,4,5-trimethylaniline4,4’-thiodianiline4-aminoazobenzene4-methoxy-m-phenylenediamine4,4’-methylene-di-o-toluidine2,6-xylidineo-anisidine2-naphthylamine3,3’-dichlorobenzidine4-aminodiphenylBenzidineo-toluidine2,4-xylidine4-chloro-o-toluidine4-methyl-m-phenylenediamineo-aminoazotoluene5-nitro-o-toluidine

101-14-4101-77-9101-80-4106-47-8119-90-4119-93-7120-71-8137-17-7139-65-160-09-3615-05-4838-88-087-62-790-04-091-59-891-94-192-67-192-87-595-53-495-68-195-69-295-80-797-56-399-55-8

< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration for every Aromatic Amines detected (See listbelow) is lower than the limit of quantification (LOQ).

Legend:

According to EN 14362-1 , EN 14362-3 Dyes - AzoRequirements:


Note:



52003





T F A RD

Nonylphenol (NP)

Octylphenol (OP)



104-40-511066-49-225154-52-384852-15-3140-66-91806-26-427193-28-89002-93-19036-19-568987-90-69016-45-926027-38-337205-87-168412-54-4127087-87-0

18,3

< 5

< 5

< 5

Raw wastewater


Legend:



Note:


Identification Parts Result

52004


Dyes Carcinogenic and Disperse

Method: According to DIN 54231

Instrument: Liquid cromatograph with DAD and MS detector

T F A RD

Compound

Disperse DyesCarcinogenic Dyes

< 50< 500

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to DIN 54231 Dyes - Carcinogenic and DisperseRequirements:


List of Disperse Dyes detected (Which are classified to be allergenic) - CAS Number––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Disperse Yellow 1 119-15-3 11 Disperse Red 17 3179-89-32 Disperse Blue 102 12222-97-8 12 Disperse Blue 7 3179-90-63 Dipserse Blue 106 12223-01-7 13 Disperse Blue 26 3860-63-74 Disperse Yellow 39 12236-29-2 14 Disperse Yellow 49 54824-37-25 Disperse Orange 37/76/59 13301-61-6 15 Disperse Blue 35 12222-75-26 Disperse Brown 1 23355-64-8 16 Disperse Blue 124 61951-51-77 Disperse Orange 1 2581-69-3 17 Disperse Yellow 9 6373-73-58 Disperse Yellow 3 2832-40-8 18 Disperse Orange 3 730-40-59 Disperse Red 11 2872-48-2 19 Disperse Blue 35 56524-77-710 Disperse Red 1 2872-52-8

List of Dyes detected (Which are classified to be carcinogenic) - CAS Number–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Acid Red 26 3761-53-3 9 Disperse Blue 3 2475-46-92 Basic Red 9 569-61-9 10 Basic Blue 26 2580-56-53 Basic Violet 14 632-99-5 11 Basic Green 4 569-64-2/2437-29-8/10309-95-24 Direct Black 38 1937-37-75 Direct Blue 6 2602-46-26 Direct Red 28 573-58-07 Disperse Blue 1 2475-45-88 Disperse Orange 11 82-28-0

Note:



52005


Flame Retardants

Method: According to USEPA 8270

Instrument: Gaschromatograph with mass detector (GC-MS)

T F A RD

Compound

TCEPdecaBDETRISpentaBDEoctaBDEBISTEPAPBBTBBPAHBCDDBBMPTDCPSCCP

115-96-81163-19-5126-72-732534-81-932536-52-05412-25-9545-55-159536-65-179-94-73194-55-63296-90-013674-87-885535-84-8

< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)The substances determined are:TCEP : Tris(2-chloroethyl)phosphate; - DecaBDE : Decabromodiphenyl ether; - TRIS : Tris(2,3-dibromopropyl)-phosphate; - PentaBDE : Pentabromodiphenyl ether; - OctaBDE : Octabromodiphenyl ether; - BIS : Bis(2,3-dibromopropyl)phosphate; - TEPA : Tris(1-aziridinyl)phosphine oxide; - PBB : Polybromobiphenyls; - TBBPA :Tetrabromobisphenol A; - HBCDD : Hexabromocyclododecane; - BBMP : 2,2-bis(bromomethyl)-1,3-propanediol ; -TDCP : Tris(1,3-dichloro-isopropyl)phosphate ; - SCCP : Short-chain chlorinated paraffins

Legend:

According to USEPA 8270 Flame RetardantsRequirements:


Note:



52006


Glycols


Instrument: Gaschromatograph with Mass Detector

T F A RD

Bis(2-methoxyethyl)-ether2-ethoxyethanol2-ethoxyethyl acetateEthylene glycol dimethyl ether2-methoxyethanol2-methoxyethylacetate2-methoxypropylacetateTriethylene glycol dimethyl ether

111-96-6110-80-5111-15-9110-71-4109-86-4110-49-670657-70-4112-49-2

< 50< 50< 50< 50< 50< 50< 50< 50

Raw wastewater


Legend:

According to USEPA 8270 GlycolsRequirements:


Note:



52007


Halogenated Solvents

Method: According to USEPA 8260B

Instrument: Gaschromatograph with FID and Mass Detector

T F A RD

1,2-DichloroethaneMethylene chlorideTrichloroethyleneTetrachloroethylene

107-06-275-09-279-01-6127-18-4

< 1< 1< 1< 1

Raw wastewater


Legend:

According to USEPA 8260B Halogenated SolventsRequirements:


Note:



52008


Organotin Compounds



T F A RD



< 0,01< 0,01< 0,010,020

< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01

Raw wastewater


Legend:



Note:



52009


Perfluorinated and Polyfluorinated Chemicals (PFCs)

Method: According to DIN 38407-42

Instrument: Liquid Chromatograph with Mass detector and Gas Chromatography with mass detector

T F A RD

PFOS

PFOAPFBS

PFHxA8:2 FTOH6:2 FTOH

355-46-4432-50-7335-67-129420-49-329420-43-3307-24-4678-39-7647-42-7

< 0,01

< 0,01< 0,01

< 0,01< 1< 1

Raw wastewater


Legend:

According to DIN 38407-42 Perfluorinated and Polyfluorinated Chemicals (PFCs)Requirements:


Note:



52010


Phthalates

Method: According to USEPA 8270D

Instrument: Gascromatograph with Mass Detector - Liquid Cromatograph with DAD and Mass detector

T F A RD

DEHPBBPDBPDEPDNOPDINPDIDPDIBPDnHPDMEPDPRPDIOPDCHPDNPDHNUPDIHP

117-81-785-68-784-74-284-66-2117-84-028553-12-026761-40-084-69-584-75-3117-82-8131-16-827554-26-384-61-784-76-468515-42-471888-89-6

< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the analyte is lower than the limit ofquantification (LOQ)

The phthalates determined are:DEHP : Bis (2-ethylhexyl) phthalate ; - BBP : Butyl benzyl phthalate ; - DBP : Di-n-butyl phthalate ; - DEP : Diethylphthalate; - DNOP : Di-n-octyl phthalate; - DINP : Di-isononyl phthalate; - DIDP : Di-iso-decyl phthalate ; - DIBP : Di-isobutyl phthalate ; - DnHP : Di-n-hexyl phthalate; - DMEP : Dimethoxyethyl phthalate; - DPRP : Di-n-propyl phthalate;- DIOP : Di-iso-octyl phthalate; - DCHP : Di-cyclohexyl phthalate; - DNP : Dinonyl phthalate; - DIHP : Di-isoheptylphthalate; - DHNUP : 1,2-Benzene-di-carboxylic acid, di-C7-11-branched and linear alkyl esters.

Legend:

According to USEPA 8270D PhthalatesRequirements:


Note:



52011


Polycyclic Aromatic Hydrocarbons (PAH)


Instrument: Gascromatograph with Mass Detector

T F A RD

Compound

Benzo(a)pyreneBenzo(e)pyreneBenzo(a)anthraceneBenzo(b)fluorantheneBenzo(j)fluorantheneBenzo(k)fluorantheneChryseneDibenzo(a,h)anthracene

AcenaphteneAcenaphthyleneAnthraceneBenzo(g,h,i)peryleneFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthrenePyrene

50-32-8192-97-256-55-3205-99-2205-82-3207-08-9218-01-953-70-3

83-32-9208-96-8120-12-7191-24-2206-44-086-73-7193-39-591-20-385-01-8129-00-0

< 1< 1< 1< 1< 1< 1< 1< 1

< 1< 1< 1< 1< 1< 1< 1< 1< 1< 1

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number inicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270 Polycyclic Aromatic Hydrocarbons (PAH)Requirements:


Note:



52012


Volatile Organic Compounds

Method: According to ISO 11423-1

Instrument: GC-MS headspace

T F A RD

BenzeneXyleneo-cresolp-cresolm-cresol

71-43-21330-20-795-48-7106-44-5108-39-4

< 1< 1< 1< 1< 1

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 11423-1 Volatile Organic Compounds (VOC)Requirements:


Note:



52024


Metals



T F A RD

Compound


< 0,01< 0,01

< 0,001< 0,010,036

< 0,01< 0,25< 0,05

3,07< 0,05

< 0,005

Raw wastewater


Legend:



Note:



Page 1 of 2

*17.27816* 17.27816


LAB NO: (IT) 17.27816



Sample Description:

TREATED WATER Date and hour of sampling: June, 13th 2017 from 9:00 to 14:00 Sampling location: Clarifying Well (Purifier Exit) Sampling method: Composite Sample Sampling by: Client Sampling Record N°: //


Page 2 of 2




Metals //

Sulfide //

Sulfite //




Issue date:23 Jun 2017

201707 Jul 2017

Test beginning:

DATES APPLICANT

OLIMPIAS GROUP SRL


T F A RD


17.27816a


TREATED WATER - CROATIA: OLIMPIAS TEXTILE D.O.O. Vukovarska, 219 - 31000 Osijek


Sulfide



Treated water 0,01




Legend:

Requirements:



Note:




Sulfite



T F A RD

52029

Treated water 0,2




Legend:

Requirements:



Note:



52003





T F A RD

Nonylphenol (NP)

Octylphenol (OP)



104-40-511066-49-225154-52-384852-15-3140-66-91806-26-427193-28-89002-93-19036-19-568987-90-69016-45-926027-38-337205-87-168412-54-4127087-87-0

< 5

< 5

< 5

< 5

Treated water


Legend:



Note:



52008


Organotin Compounds



T F A RD



< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01

Treated water


Legend:



Note:



52024


Metals



T F A RD

Compound


< 0,01< 0,01

< 0,001< 0,010,005

< 0,01< 0,25< 0,05

1,46< 0,05

< 0,005

Treated water


Legend:



Note:


test report: 17 - benetton groupstatic.benettongroup.com/wp-content/uploads/2018/03/... ·...

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