the 4th hiroshima workshop on sustainable materials...
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The 4th Hiroshima Workshop on Sustainable Materials Science
November 13-15, 2009, Faculty Club, Hiroshima University,
Higashi-Hiroshima, Japan
SMS2009, Hiroshima University, November 13-15, 2009
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Previous Meetings The 1st Hiroshima Workshop – Transport and Thermal Properties of f-Electron Systems – August 30-September 2, 1992
The 2nd Hiroshima Workshop – Transport and Thermal Properties of Advanced Materials – August 16-19, 2002
The 3rd Hiroshima Workshop – Novel Functional Materials with Multinary Freedoms – November 16-19, 2005
SMS2009, Hiroshima University, November 13-15, 2009
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Preface The 4th Hiroshima Workshop on Sustainable Materials Science (SMS2009) is held in Higashi-Hiroshima city, Japan, November 13-15, 2009, along a series of the Hiroshima Workshop, of which the first, second and third ones have been held in Hiroshima in 1992, 2002 and 2005, respectively. The purpose of this Workshop is to provide a forum for discussion of the latest progress in specific topics listed below. Some of the top experts in these fields will be invited speakers. 1. Regulated Nanospace Materials with 2D and 3D Structures 2. Correlation between Structure and Magnetism in Chiral Magnets and Multiferroics 3. Molecular Electronics 4. Hydrogen Storage Materials 5. Softmaterials 6. Nano Physics Organizing Committee Y. Kojima, chair T. Takabatake S. Yamanaka M. Sera T. Oguchi T. Ichikawa Support Institute for Advanced Materials Research (IAMR), Hiroshima University Graduate School of Advanced Sciences of Matter, Hiroshima University Graduate School of Integrated Arts and Sciences, Hiroshima University
SMS2009, Hiroshima University, November 13-15, 2009
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Workshop Program Friday, November 13, 2009
08:30-10:00 Registration 09:00-09:30 Coffee
Opening
09:30-09:50 Toshiro Takabatake (Director, IAMR, Hiroshima University) Welcome and Introduction
Keynote Lecture [chair: Toshiro Takabatake]
10:00-10:50 Bo Brummerstedt Iversen (Centre for Energy Materials, Department of Chemistry and iNANO, University of Aarhus, Denmark)
“Energy Materials” Session 1．Regulated Nanospace Materials with 2D and 3D Structures [chair: Shoji Yamanaka]
11:00-11:30 Jin-Ho Choy（Ewha Womans University, Korea） “Hybridization of Bio-functional Molecules in Nanospace of 2-D Drug Delivery Carriers”
11:30-12:00 Katsumi Tanigaki（Graduate School of Science, Tohoku University） “Phonons and electronic states in compounds with regulated nanospaces” 12:00-12:30 Shoji Yamanaka (Department of Applied Chemistry, Graduate School of
Engineering, Hiroshima University) “High pressure synthesis of silicon clathrate superconductors”
12:30-14:00 Lunch
Session 2．Correlation between Structure and Magnetism in Chiral Magnets and Multiferroics [chair: Katsuya Inoue]
14:00-14:30 Fernando Palacio (CSIC - Universidad de Zaragoza, Spain) “Multichiral materials: coexistence of molecular, nuclear and magnetic chiralities in molecular magnets”
14:30-15:00 Jun-ichiro Kishine (Department of Basic Sciences, Faculty of Engineering, Kyushu Institute of Technology)
“Strong correlations between itinerant electrons and topological spin texture in a chiral helimagnet”
SMS2009, Hiroshima University, November 13-15, 2009
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15:00-15:30 Katsuya Inoue （Department of Chemistry, Graduate School of Science, Hiroshima University）
“Synthetic and structural studies for chiral magnets”
15:30-15:50 Break
Session 3．Molecular Electronics [chair: Ichiro Imae] 15:50-16:20 Christian Kloc (Nanyang Technological University, Singapore) “Control of defects and dopants in rubrene” 16:20-16:50 Masakazu Nakamura (Department of Electrical and Electronics Engineering,
Chiba University) “Air-Stable Organic ‘Power’ Transistors Fabricated by Spontaneous Patterning of Higher-Order Structures”
16:50-17:20 Ichiro Imae (Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University)
“Anchoring of photo- and electroactive groups on metal-oxide substrates using polysilsesquioxane”
Poster Session (with light meal and drinks)
18:00-21:00 Saturday, November 14, 2009
09:00-09:30 Coffee
Session 4．Hydrogen Storage Materials [chair: Yoshitsugu Kojima]
09:30-10:00 Kevin Ott （Los Alamos National Laboratory, USA） “Advances in hydrogen storage and renewable energy at Los Alamos”
10:00-10:30 Etsuo Akiba（National Institute of Advanced Industrial Science and Technology）
“Crystal structures and hydrogen absorbing properties of (La, Mg)(Ni, Co)3+x “superlattice” alloys”
10:30-11:00 Yoshitsugu Kojima (Institute for Advanced Materials Research, Hiroshima University) “Research and development of nano-composite materials for hydrogen
storage” 11:00-11:20 Break
SMS2009, Hiroshima University, November 13-15, 2009
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Session 5．Softmaterials [chair: Akihiko Toda]
11:20-11:50 Sanjay Rastogi (Department of Materials, Loughborough University, UK) “Crossing borders between natural and synthetic peptides; shielding and mediating of hydrogen bonding in amide-based (macro)molecules”
11:50-12:20 Hajime Tanaka (Institute of Industrial Science, University of Tokyo) “Physical principle of pattern selection in a nonequilibrium process: from phase separation of soft matter to mechanical fracture”
12:20-12:30 Photo 12:30-14:00 Lunch 14:00-14:30 Akihiko Toda (Graduate School of Integrated Arts and Sciences, Hiroshima University) “Crystallization of polymers” 14:30-14:40 Break
Session 6．Nano Physics [chair: Ryuta Yagi] 14:40-15:10 Barbaros Özyilmaz (National University of Singapore) “Gate controlled non-volatile graphene ferroelectric memory” 15:10-15:40 Akinobu Kanda (Tsukuba University) “Spin and cooper-pair transport in single and multilayer graphene devices” 15:40-16:00 Break 16:00-16:30 RyutaYagi (Graduate School of Advanced Sciences of Matter, Hiroshima University)
“Magnetotransport of graphene devices” Closing Session
16:30-17:00 Tamio Oguchi (Graduate School of Advanced Sciences of Matter, Hiroshima University)
“Towards materials design from first principles” MOU Signing Ceremony between IAMR and LANL, USA
17:00-17:30
SMS2009, Hiroshima University, November 13-15, 2009
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Banquet 18:00-21:00
Sunday, November 15, 2009 10:00 - Laboratory Tour
SMS2009, Hiroshima University, November 13-15, 2009
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ABSTRACT Oral Presentations O-00 Toshiro Takabatake, “Institute for Advanced Materials Research” O-01 Bo Brummerstedt Iversen, “Energy Materials” O-11 Jin-Ho Choy, “Hybridization of Bio-functional Molecules in Nanospace of 2-D Drug
Delivery Carriers” O-12 Katsumi Tanigaki, “Phonons and electronic states in compounds with regulated
nanospaces” O-13 Shoji Yamanaka, “High pressure synthesis of silicon clathrate superconductors” O-21 Fernando Palacio, “Multichiral materials: coexistence of molecular, nuclear and
magnetic chiralities in molecular magnets” O-22 Jun-ichiro Kishine, “Strong correlations between itinerant electrons and topological spin
texture in a chiral helimagnet” O-23 Katsuya Inoue, “Synthetic and structural studies for chiral magnets” O-31 Christian Kloc, “Control of defects and dopants in rubrene” O-32 Masakazu Nakamura, “Air-Stable Organic ‘Power’ Transistors Fabricated by
Spontaneous Patterning of Higher-Order Structures” O-33 Ichiro Imae, “Anchoring of photo- and electroactive groups on metal-oxide substrates
using polysilsesquioxane” O-41 Kevin Ott, “Advances in hydrogen storage and renewable energy at Los Alamos” O-42 Etsuo Akiba, “Crystal structures and hydrogen absorbing properties of (La, Mg)(Ni,
Co)3+x “superlattice” alloys” O-43 Yoshitsugu Kojima, “Research and development of nano-composite materials for
hydrogen storage” O-51 Sanjay Rastogi, “Crossing borders between natural and synthetic peptides; shielding and
mediating of hydrogen bonding in amide-based (macro)molecules” O-52 Hajime Tanaka, “Physical principle of pattern selection in a nonequilibrium process:
from phase separation of soft matter to mechanical fracture” O-53 Akihiko Toda, “Crystallization of polymers” O-61 Barbaros Özyilmaz, “Gate controlled non-volatile graphene ferroelectric memory” O-62 Akinobu Kanda, “Spin and cooper-pair transport in single and multilayer graphene
devices” O-63 RyutaYagi, “Magnetotransport of graphene devices” O-71 Tamio Oguchi, “Towards materials design from first principles”
SMS2009, Hiroshima University, November 13-15, 2009
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Poster Presentations P-100 S. Yamanaka, T. Takabatake, M. Udagawa, S. Suzuki, K. Umeo, N. Ogita, K. Inumaru,
K. Shimada, and H. Sato, “Regulated Nanospace Materials with 2D and 3D Structures” P-101 Toshikazu Ekino, Akira Sugimoto, Kazuhiro Shohara, Shoji Yamanaka, and Alexander
M. Gabovich, “Scanning tunneling microscopy/spectroscopy of the superconducting layered nitride halides”
P-102 Takumi Hasegawa, Norio Ogita, Youhei Nagao, Jun-Ichi Yamaura, Zenji Hiroi, and Masayuki Udagawa, “Guest modes in β-pyrochlore osmium oxides”
P-103 Kei Inumaru, K. Koyama, S. Izumi, and Shoji Yamanaka, “Control of the structural transition at the Néel point of CrN epitaxial thin films using epitaxial growth”
P-104 N. Ogita, T. Hasegawa, M. Udagawa, H. Sugawara, D. Kikuchi and H. Sato, ”Crystal Electric Field Study of PrRu4P12”
P-105 T. Onimaru, S. Yamamoto, M. A. Avila, K. Suekuni, and T. Takabatake, “Stabilization of Ferromagnetism in an Off-Center Rattling System Eu8Ga16Ge30 by Si Substitution”
P-106 Yuta Saiga, Koichiro Suekuni, and Toshiro Takabatake, ”Effect of Sb Substitution on Thermoelectric Properties of Type-VIII Clathrate Ba8Ga16Sn30”
P-107 K. Suekuni, Y. Takasu, T. Tanaka, M. A. Avila, K. Umeo, T. Hasegawa, N. Ogita, M. Udagawa, H. Fukuoka, S. Yamanaka, and T. Takabatake, ”Off-center rattling and glass-like lattice thermal conductivity in type-I clathrate Ba8Ga16Sn30”
P-108 Akira Sugimoto, Kazuhiro Shohara, Toshikazu Ekino, Yuji Watanabe, Yukihiro Harada, Satoshi Mikusu, Kazuyasu Tokiwa, Tsuneo Watanabe, ”STM/STS observation on multi-layered apical-fluorine cuprate superconductor Ba2Ca5Cu6O12(O1-x Fx)2”
P-109 T. Tanaka, T. Onimaru, K. Suekuni, S. Mano, H. Fukuoka, S. Yamanaka and T. Takabatake, “Thermoelectric and Structural Properties of Type-Ι Clathrate K8Ga8Sn38”
P-110 Keita Umemoto, Toshihiro Yasunaga, and Shoji Yamanaka, “Preparation and Superconductivity of Electron-Doped Layer Structured Metal Nitride Chlorides MNCl (M = Ti, Zr, Hf)”
P-200 T. Oguchi, T. Suzuki, K. Inoue, T. Jo, S. Hayami, T. Shishidou, M. Akita, F. Nakamura, F. Iga, and A. Kimura, “Properties and Mechanisms of Materials with Multiple Orders”
P-201 Ayaka Kodama, Miki Nagano, Tatsuya Shishidou, and Tamio Oguchi, “First-Principles and Group-Theoretical Study of Surface Rashba Effect”
P-202 Nobuhiro Koga, Jun-ichiro Kishine, and A.S.Ovchinnikov, “Correlated Dynamics of Magnetic Domain Wall and Spin-polarized Current”
P-203 Takashi Goto, Shinsuke Okumura, Masahiro Nakane, Takahiro Fujita, Isao Ishii, Motoko Akita, Katsuya Inoue, Masakazu Ito and Takashi Suzuki, “Thermal and elastic properties of (C2H5NH3)2CuCl4”
P-204 J. V. Yakhmi, S M Yusuf, Amit Kumar, Nidhi Thakur and M. D. Mukadam, “Tuning Magnetic Properties of Prussian Blue based Functional Molecular Materials”
SMS2009, Hiroshima University, November 13-15, 2009
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P-205 Aditee Joshi, Manmeet Kaur, Ajay Singh, S. K. Gupta and J. V. Yakhmi, “Polypyrrole: ZnO-nanowires composite films for gas sensing and memory applications“
P-300 Yutaka Harima, Yousuke Yamamoto, Joji Ohshita, Takeshi Shiono, Tsuneji Sano, Kazuo Takimiya, Atsushi Kawachi, Ichiro Imae, Hiroto Yoshida, Yousuke Ooyama, and Eigo Miyazaki, “Molecular-Assembled Devices Project”
P-301 Atsushi Kawachi, Hiroshi Morisaki, Yohsuke Yamamoto, “Synthesis and Reactions of o-Dihydrosilyl(dimesitylboryl)benzenes”
P-302 Hiroki Mori, Eigo Miyazaki, and Kazuo Takimiya, “Photovoltaic Properties of Organic Thin-Film Solar Cells with Novel Thiophene-Fused Porphyrazines”
P-303 Yuushou Nakayama, Takamichi Inaba, Yosuke Toda, Zhengguo Cai, and Takeshi Shiono, “Synthesis and Properties of Cationic Ionomers from Poly(L-lactide)-based Poly(ester-urethane)s”
P-304 Joji Ohshita, Yosuke Hatanaka, Shigenori Matsui, Yoshihito Kunugi, “Star-Shaped Molecules with Oligothiophene Units and an Organosilicon Core. Effects of the Silicon Core Structures on Their FET Activity”
P-305 Masahiro Sadakane and Wataru Ueda, “Synthesis of Mo-V Oxide by Assembly of Pentagonal Mo6O21 Polyoxometalate Building Blocks”
P-306 Tatsuya Yamamoto, Shoji Shinamura, Eigo Miyazaki and Kazuo Takimiya, “Structure and Thin-Film FET Characteristics of Dinaphthothienothiophenes”
P-400 Yoshitsugu Kojima, “Research and development of nano-composite materials for hydrogen storage”
P-401 Anthony K. Burrell, Himashinie V. K. Diyabalanage, Roshan P. Shestha and Tessui Nakagawa, “Hydrogen from ammonia borane and derivatives”
P-402 Nobuko Hanada, Hiroshi Suzuki, Kenichi Takai, Takayuki Ichikawa and Yoshitsugu Kojima, “Electrochemical properties of Al + 3LiH or AlH3 in Li-ion battery system”
P-403 Shigehito Isobe, Yongming Wang, Akifumi Ono, Hiroko Hirasawa, Yao Hao, Naoyuki Hashimoto, Somei Ohnuki, Takayuki Ichikawa, and Yoshitsugu Kojima, “Microscopic Reaction Mechanism of Hydrogen Storage Materials by TEM”
P-404 A. Michigoe, T. Hasegawa, N. Ogita, M. Udagawa, Y. Teng, M. Tsubota, T. Ichikawa, Y. Kojima, and S. Isobe, “Raman scattering of LiNH2”
P-405 Hiroki Miyaoka, Hikaru Yamamoto, Satoshi Hino, Takayuki Ichikawa and Yoshitsugu Kojima, “Ammonia and Metal Hydride Systems as Recyclable Hydrogen Storage”
P-406 Aki Yamane, Fuyuki Shimojo, Kozo Hoshino, Takayuki Ichikawa, and Yoshitsugu Kojima, “H2 desorption from LiH and NH3 studied by ab initio molecular dynamics simulation”
P-500 Akihiko Toda, “Research and Development of Softmatter: Project of the Institute for Advanced Materials Research”
P-501 Ratan C. Gosh, A. Toda and S. Tanaka, “NaCl effect on the eutectic phase behavior of aqueous poly(ethylene glycol) solutions”
SMS2009, Hiroshima University, November 13-15, 2009
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P-502 Hiroshi Kajioka, Ken Taguchi, and Akihiko Toda, “Branching mechanism of lamellar crystals in poly(butene-1) spherulites”
P-503 Shoko Mishima, Satoru Ueno and Kiyotaka Sato, “Microstructure of High melting fat and functionality of whipped oil without emulsifiers”
P-504 Keisuke Shimamura, Satoru Ueno, Kiyotaka Sato, Yoshiro Miyamoto, Juhei Kuriyama, “Effects of fatty acid compositions of polyglycerol fatty acid esters on fat crystallization”
P-505 Ken Taguchi, Akihiko Toda, Hiroshi Kajioka and Yoshihisa Miyamoto, “The effects of Molecular weight on the crystal growth from isotactic/atactic polymer blend thin films”
P-506 Shinpei Tanaka, “Fluorescence correlation spectroscopy of protein molecular dynamics at crystal-solution interfaces”
P-600 Ryuta Yagi, Yositake Takane, Katsuori Wakabayashi, Toshikazu Ekino and Akira Sugimoto, “Electronics of ultra-small functional materials”
P-601 S. Fukada, Y. Shintani, H. Kobara, N. Ogita, M. Udagawa, and R.Yagi, “Graphene prepared from graphite intercalation compound”
P-602 Yositake Takane, “Charge Imbalance Penetration into a Normal Metal Coupled with Superconductors”
P-603 Kazuki Tsuboi and Ryuta Yagi, “Charge imbalance in non-equilibrium superconductivity due to pair breaking perturbation by magnetic field”