the chemical resistance of plastics...this chart gives general guidelines on the chemical resistance...

1
LDPE HDPE PP PMP (TPX) PVC PC PS SAN PMMA PTFE POM PBT Temperature ºC 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 Acetaldehyde 3 1 3 22 1 2 111 2 1111111 3333 Acetic Acid (Glacial) 2 1 333 222 3 111111111 33 111 Acetic Anhydride 11 2222 3 2 1111111111 22 11 Acetone 2 111 2 1 33 1111111111 3333 2 Ammonium Chloride (10%) 333333333 222 3333 22 33 Ammonium Hydroxide (30%) 333333333 11 2222222 3333 Amyl Acetate 2 1 3 22 1 3 2 11111111 3333333 Aniline (Phenylamine) 3 2 33333 2 1111111111 33 222 Aqua Regia 11111111111111 2 111 3333 1 Benzaldehyde 3 22 11 2 3 2 1111111111 3333 Benzene 111111111111111111 333 2 3 Benzoic Acid 33333 2 333 2 3 222 333333 1 Boric Acid (10%) 33333333333333333333333 Butyl Acetate 22222222 3 111111111 333 22 Butyric Acid (Butanoic acid) 11 2 11111 3 111111111 33 3 Calcium Hydroxide (Saturated) 3333333333 11 22 33 2 1 33333 Carbon Disulphide 111111111111111111 3333 Carbon Tetrachloride 2 1 2 1 2 111 3 11111 2 111 33 22 Chloroform 2 1 2 111111111111111 33 111 Citric Acid (1M) 33333333333333333 33 Cresol 11 2 1 22 111111 2 11111 33 1 Cyclohexane 2 1 2 1 2 11111 3 2 11 2 1 2 3333 Dibutyl Phthalate 2 1 2 1 2 1 22 11 2 1111111 33333 Dichlorobenzene 2 1 2 1 2 1111111111111 33 11 Diethyl Ether 11 2 1 2 111 3 111111111 33333 Diethylene Glycol 33333333 2 1 22 3333 11 3333 1 Dimethyl Formamide (DMF) 33333333 1111111111 33333 Dimethyl Sulfoxide (DMSO) 33333333 1111 2 1111 33 3 Dioxane 2222 11 22 1111111111 33 222 1 Ethyl Acetate (Ethyl Ester) 3333 2 1 2 11111111111 22 1 Ethyl Alcohol (Absolute Ethanol) 3 2 33333 2 333 2 3 2 1111 33333 Ethyl Chloride (Chloroethane) 2 111 2 1 2 11111111111 33 Ethylene Chloride 2 111 2 1 2 1 2 111111111 33 11 Ethylene Oxide (Pure) 22222 1 2 111 2 11111 333333 2 Ethylene Oxide (Gas) 22 3333 2222 333 222 3333 Formaldehyde (Formalin) 40% 3 2 3 2 33333333 222 1 3 2 33333 Formic Acid (50%) 22 333 2 333 1 2222 3 2 33 2 Formic Acid (100%) 22 333 2 333 1 2 1 22 11 33 11 Glycerine (Glycerol) 33333333333333333333 22 3 LDPE HDPE PP PMP (TPX) PVC PC PS SAN PMMA PTFE POM PBT Temperature ºC 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 Hexane 11 22222 1 3 1 2 111 333 33333 Hydrobromic Acid (69%) 333 2 3 2 3333 222222 11 33 111 Hydrochloric Acid (5%) 3333333333333333 2 33 111 Hydrochloric Acid (35%) 33333 2 3 2 33 2 1 333 2 11 33 111 Hydrofluoric Acid (48%) 33333 2 3 2222 111 3 2 11 33 11 2 Hydrogen Peroxide (30%) 33333 2 3 2 33333 2 33 2 1 333 1 3 Lactic Acid (85%) 33333 2 3 2 3 2 3 2 333333333 1 3 Methyl Acetate 3 1 333 22 111111111 33 1 Methyl Alcohol (Methanol) 3 2 33333 2 33 2222 1111 33333 Methyl Ethyl Ketone (Butanone) 1111 333 11111111111 33 3 Methylene Chloride (Dichloro Methane) 11 3 1 3 1 3 11111111111 33 111 Mineral Oil 2 3333 2 3 2 333333333333333 Nitric Acid (10%) 33 2222222 33 22 3 22 3 33 11 2 Nitric Acid (70%) 3 1 3 111 3 11111111111 33 11 2 Nitrobenzene 111111 3 11111111111 33 2 1 3 Oxalic Acid (10%) 33333333333333333333333 Perchloric Acid (70%) 2 1 2 1 2 1 2 1 2 111 2222 33 22 11 Phenol (100%) 111111111111111111 33 111 Phosphoric Acid (85%) 3 1 333 2 3 2 3 2 3 2 3 2 33 2 1 333 1 Picric Acid 111111 33 1111 22 33 33 Potassium Hydroxide (30%) 3333333333 11 22 33333333 1 Potassium Permanganate 33333 2 333 2 333 2222 1 33 22 3 Propylene Glycol 33333333 2222 3333 3333 Pyridine 1111 33 2 11111111111 333 2 Salicylic Acid 33333333 22 3 2 3 2 3 2 33 11 3 Silver Nitrate 3 2 3333333 2 33333 2 33 22 Sodium Hydroxide (50%) 22 33333333 11 3 2 3 2 3 1 3333 1 Sodium Hypochlorite (15%) 3 2 3 22 1 3333 22 3 2 333333 1 Sulphuric Acid (20%) 333333333 2 3 2 333 2 3333 Sulphuric Acid (60%) 3 2 3 222 3 2 3 222 3 2 1111 33 11 Sulphuric Acid (98%) 22222 3 222 111 22 1111 33 111 Tetrahydrofuran (THF) 2 1 2 3 2222 1111111111 33 22 3 Toluene 2 11111 22 1111111111 33 11 3 Trichloroacetic Acid 2 1 2 1 22 33 2 1 2 1 2 111 33 1 Trichloroethylene 111111111111111111 33 1111 Turpentine 2 1 2 1 2 1 2 1 222 111 2 1 2 1 33333 Xylene 11 2 111 2 11111111111 3333 1 Zinc Chloride (10%) 333333333333333333333 2 3 Zinc Sulphate (10%) 33333333333333333333 2 1 2 Good resistance: continuous exposure to the substance causes minor damage within 7 - 30 days. 1 Poor resistance: not suitable for continuous exposure to the substance. Immediate damage may occur. 3 Excellent resistance: continuous exposure to the substance does not cause damage within 30 days. The physical properties of plastics * Permeability (cc-mm/m 2 -24hr.Bar). Polymer may be malleable at temperatures above 80ºC if the product is under structural stress. †† Material may become brittle at low temperatures. Max usage Temp. ºC Min usage Temp. ºC Transparency Flexability Specific Gravity Microwaveable Autoclavable Gas Dry Heat Radiation (Gamma) Disinfection N2 O2 CO2 Water Absorbtion (%) Cytotoxic LDPE HDPE PP PMP (TPX) PC PS PMMA PTFE PFA 80 120† 135 145 135 90 50 260 260 -50 -100 -20†† 0†† -135 -40 -60 -200 -260 Translucent Translucent Translucent Clear Clear Clear Clear Opaque Translucent Flexible Rigid Rigid Rigid Rigid Rigid Rigid Rigid Flexible 0.92 0.95 0.9 0.83 1.2 1.05 1.2 2.2 2.15 Yes No Yes Yes Marginal No No Yes Yes No No Yes Yes Yes No No Yes Yes Yes Yes Tes Yes Yes Yes No Yes Yes No No No Yes No No No Yes Yes Yes Yes No No Yes Yes Yes Yes No Yes Yes Yes Yes Yes Some Some Yes Yes 180 42 48 8,000 50 25 3 Unknown 291 500 185 240 32,000 300 400 12 308 881 2,700 580 800 115,000 1,075 1,500 68 Unknown 2,260 <0.01 <0.03 <0.2 0.01 0.35 0.05 0.35 <0.01 <0.02 No No No No No No No No No Sterilisation Permeability* Polytetrafluoroethylene, PTFE l Opaque rigid polymer l Wide temperature range –200 to +260ºC l Autoclavable at 121ºC l Unrivalled resistance to almost all chemicals l Extremely low friction coefficient l Typically used for bottles, beakers and stirrers Polyfluoroalkoxy, PFA l Translucent flexible form of PTFE l Wide temperature range -260 to +260ºC l Autoclavable at 121ºC l Excellent chemical resistance l Typically used for trace metal analysis bottles Polymethylmethacrylate, Acrylic (PMMA) l Transparent rigid polymer l Narrow temperature range -60 to +50ºC l Not autoclavable at 121ºC l Moderate chemical resistance l Very tough and high clarity l Typically used for radiation shields Polystyrene, PS l Transparent rigid polymer l Narrow temperature range -40 to +90ºC l Not autoclavable at 121ºC l Moderate chemical resistance l Brittle yet has excellent clarity l Typically used for container ware Polyvinylchloride, PVC l Rigid polymer l Narrow temperature range -25 to +70ºC l Not autoclavable at 121ºC l Moderate chemical resistance l Rigid or flexible, coloured or clear l Typically used for trays and troughs Polypropylene, PP l Translucent rigid polymer l Temperature range -20 to +135ºC l Autoclavable at 121ºC l Good to excellent chemical resistance l Resistant to fatigue making it tough l Typically used for beakers, bottles and cylinders Low Density Polyethylene, LDPE l Translucent flexible polymer l Narrow temperature range of -50 to +80ºC l Not autoclavable at 121ºC l Good to excellent chemical resistance l Robust and virtually unbreakable l Typically used for wash bottles High Density Polyethylene, HDPE l Translucent rigid polymer l Broad temperature range of -100 to +120ºC l Not autoclavable at 121ºC l Good to excellent chemical resistance l High tensile strength making it very tough l Typically used for bottles Polymethylpentene, PMP (TPX) l Transparent rigid polymer l Broad temperature range -180 to +145ºC l Autoclavable at 121ºC l Good to excellent chemical resistance l Has a low density and a high clarity l Typically used for beakers and cylinders Polycarbonate, PC l Transparent rigid polymer l Broad temperature range -135 to +135ºC l Autoclavable at 121ºC l Moderate chemical resistance l High impact strength l Typically used for safety shields SciLabware Limited, Unit 4, Riverside 2, Campbell Road, Stoke-on-Trent, Staffordshire, ST4 4RJ, wUK +44 (0) 1782 444406 This technical information is provided in good faith by SciLabware Limited for the safety of its customers. Please note that the advice given is for general laboratory applications and may not necessarily apply to all tests or procedures. The A-Z of reusable plastic labware SciLabware Limited, Unit 4, Riverside 2, Campbell Road, Stoke-on-Trent, Staffordshire, ST4 4RJ, wUK +44 (0) 1782 444406 This technical information is provided in good faith by SciLabware Limited for the safety of its customers. Please note that the advice given is for general laboratory applications and may not necessarily apply to all tests or procedures. The A-Z of reusable plastic labware SciLabware Limited, Unit 4, Riverside 2, Campbell Road, Stoke-on-Trent, Staffordshire, ST4 4RJ, wUK +44 (0) 1782 444406 This technical information is provided in good faith by SciLabware Limited for the safety of its customers. Please note that the advice given is for general laboratory applications and may not necessarily apply to all tests or procedures. www.scilabware.com [email protected] The A-Z of reusable plastic labware The chemical resistance of plastics This chart gives general guidelines on the chemical resistance of plastics. There are many factors that influence chemical resistance, we therefore recommend that you test for your own application before selecting the appropriate product. If you have any doubts please contact us for assistance. No information available.

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Page 1: The chemical resistance of plastics...This chart gives general guidelines on the chemical resistance of plastics. There are many factors that influence chemical resistance, we therefore

LDPE HDPE PP PMP (TPX) PVC PC PS SAN PMMA PTFE POM PBT

Temperature ºC 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50

Acetaldehyde 3132212111211111113333Acetic Acid (Glacial) 21333222311111111133111Acetic Anhydride 1122223211111111112211Acetone 21112133111111111133332Ammonium Chloride (10%) 33333333322233332233Ammonium Hydroxide (30%) 3333333331122222223333Amyl Acetate 21322132111111113333333Aniline (Phenylamine) 32333332111111111133222Aqua Regia 11111111111111211133331Benzaldehyde 3221123211111111113333Benzene 11111111111111111133323Benzoic Acid 33333233323222333333 1Boric Acid (10%) 33333333333333333333333Butyl Acetate 22222222311111111133322Butyric Acid (Butanoic acid) 11211111311111111133 3Calcium Hydroxide (Saturated) 33333333331122332133333Carbon Disulphide 1111111111111111113333Carbon Tetrachloride 2121211131111121113322Chloroform 21211111111111111133111Citric Acid (1M) 33333333333333333 33Cresol 11212211111121111133 1Cyclohexane 21212111113211212 3333Dibutyl Phthalate 21212122112111111133333Dichlorobenzene 2121211111111111113311Diethyl Ether 11212111311111111133333Diethylene Glycol 33333333212233331133331Dimethyl Formamide (DMF) 33333333111111111133333Dimethyl Sulfoxide (DMSO) 333333331111 2111133 3Dioxane 222211221111111111332221Ethyl Acetate (Ethyl Ester) 33332121111111111122 1Ethyl Alcohol (Absolute Ethanol) 32333332333232111133333Ethyl Chloride (Chloroethane) 21112121111111111133Ethylene Chloride 2111212121111111113311Ethylene Oxide (Pure) 22222121112111113333332Ethylene Oxide (Gas) 22333322223332223333Formaldehyde (Formalin) 40% 32323333333322213233333Formic Acid (50%) 2233323331222232 33 2Formic Acid (100%) 2233323331212211 3311Glycerine (Glycerol) 33333333333333333333223

LDPE HDPE PP PMP (TPX) PVC PC PS SAN PMMA PTFE POM PBT

Temperature ºC 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50 20 50

Hexane 11222221312111333 33333Hydrobromic Acid (69%) 3332323 3332222221133111Hydrochloric Acid (5%) 333333 3 3333333332 33111Hydrochloric Acid (35%) 33333232332133321133111Hydrofluoric Acid (48%) 33333232222111321133112Hydrogen Peroxide (30%) 33333232333332332133313Lactic Acid (85%) 33333232323233333333313Methyl Acetate 3133322111111111 33 1Methyl Alcohol (Methanol) 323333 32332222111133333Methyl Ethyl Ketone (Butanone) 111133 31111111111133 3Methylene Chloride (Dichloro Methane) 11313131111111111133111Mineral Oil 23333232333333333333333Nitric Acid (10%) 33222222233223223 33112Nitric Acid (70%) 31311131111111111133112Nitrobenzene 11111131111111111133213Oxalic Acid (10%) 333333 3 3333333333333333Perchloric Acid (70%) 2121212121112222332211Phenol (100%) 11111111111111111133111Phosphoric Acid (85%) 3133323232323233213331Picric Acid 1111113311112233 33Potassium Hydroxide (30%) 333333 3 3331122333333331Potassium Permanganate 3333323 3323332222133223Propylene Glycol 333333 3 322223333 3333Pyridine 1111332111111111113332Salicylic Acid 333333 3 322323232 33113Silver Nitrate 323333 3 332333332 3322Sodium Hydroxide (50%) 223333 33331132323133331Sodium Hypochlorite (15%) 3232213 3332232333333 1Sulphuric Acid (20%) 333333 3 3323233323333Sulphuric Acid (60%) 3232223232223211113311Sulphuric Acid (98%) 22222322211122111133111Tetrahydrofuran (THF) 21232222111111111133223Toluene 21111122111111111133113Trichloroacetic Acid 2121223 321212111 33 1Trichloroethylene 111111111111111111331111Turpentine 21212121222111212133333Xylene 11211121111111111133331Zinc Chloride (10%) 333333 3 3333333333333323Zinc Sulphate (10%) 333333 3 333333333333321

2Good resistance:continuous exposure to the substance causes minor damage within 7 - 30 days.

1Poor resistance:not suitable for continuous exposure to the substance. Immediate damage may occur.

3Excellent resistance:continuous exposure to the substance does not cause damage within 30 days.

The physical properties of plastics

* Permeability (cc-mm/m2-24hr.Bar).† Polymer may be malleable at temperatures above 80ºC if the product is under structural

stress.†† Material may become brittle at low temperatures.

Max usage Temp. ºC

Min usage Temp. ºC

Transparency

Flexability

Specific Gravity

Microwaveable

Autoclavable

Gas

Dry Heat

Radiation (Gamma)

Disinfection

N2

O2

CO2

Water Absorbtion (%)

Cytotoxic

LDPE HDPE PPPMP (TPX) PC PS PMMA PTFE PFA

80 120† 135 145 135 90 50 260 260

-50 -100 -20†† 0†† -135 -40 -60 -200 -260

Translucent Translucent Translucent Clear Clear Clear Clear Opaque Translucent

Flexible Rigid Rigid Rigid Rigid Rigid Rigid Rigid Flexible

0.92 0.95 0.9 0.83 1.2 1.05 1.2 2.2 2.15

Yes No Yes Yes Marginal No No Yes Yes

No No Yes Yes Yes No No Yes Yes

Yes Yes Tes Yes Yes Yes No Yes Yes

No No No Yes No No No Yes Yes

Yes Yes No No Yes Yes Yes Yes No

Yes Yes Yes Yes Yes Some Some Yes Yes

180 42 48 8,000 50 25 3 Unknown 291

500 185 240 32,000 300 400 12 308 881

2,700 580 800 115,000 1,075 1,500 68 Unknown 2,260

<0.01 <0.03 <0.2 0.01 0.35 0.05 0.35 <0.01 <0.02

No No No No No No No No No

Ster

ilisa

tion

Perm

eabi

lity*

Polytetrafluoroethylene, PTFEl Opaque rigid polymer

l Wide temperature range –200 to +260ºC

l Autoclavable at 121ºC l Unrivalled resistance to almost all chemicals l Extremely low friction coefficientl Typically used for bottles,

beakers and stirrers

Polyfluoroalkoxy, PFA

l Translucent flexible form of PTFE

l Wide temperature range -260 to +260ºCl Autoclavable at 121ºC l Excellent chemical resistancel Typically used for trace metal

analysis bottles

Polymethylmethacrylate, Acrylic (PMMA)

lTransparent rigid polymer

l Narrow temperature range -60 to +50ºCl Not autoclavable at 121ºC l Moderate chemical resistancel Very tough and high clarityl Typically used for radiation

shields

Polystyrene, PS

l Transparent rigid polymer

l Narrow temperature range -40 to +90ºCl Not autoclavable at 121ºC l Moderate chemical resistancel Brittle yet has excellent clarityl Typically used for container ware

Polyvinylchloride, PVC

l Rigid polymer

l Narrow temperature range -25 to +70ºCl Not autoclavable at 121ºC l Moderate chemical resistancel Rigid or flexible, coloured or clear l Typically used for trays

and troughs

Polypropylene, PP

lTranslucent rigid polymer

l Temperature range -20 to +135ºCl Autoclavable at 121ºCl Good to excellent chemical resistance l Resistant to fatigue making it toughl Typically used for beakers,

bottles and cylinders

Low Density Polyethylene, LDPEl Translucent flexible polymer l Narrow temperature range

of -50 to +80ºC

l Not autoclavable at 121ºCl Good to excellent chemical resistancel Robust and virtually unbreakable l Typically used for wash bottles

High Density Polyethylene, HDPE

l Translucent rigid polymer l Broad temperature range

of -100 to +120ºC

l Not autoclavable at 121ºCl Good to excellent chemical resistancel High tensile strength making

it very tough

l Typically used for bottles

Polymethylpentene, PMP (TPX)

l Transparent rigid polymer

l Broad temperature range -180 to +145ºC l Autoclavable at 121ºCl Good to excellent chemical resistance l Has a low density and a high clarityl Typically used for beakers and cylinders

Polycarbonate, PC

l Transparent rigid polymer

l Broad temperature range -135 to +135ºC l Autoclavable at 121ºC l Moderate chemical resistancel High impact strength l Typically used for safety shields

SciLabware Limited, Unit 4, Riverside 2, Campbell Road, Stoke-on-Trent, Staffordshire, ST4 4RJ, wUK +44 (0) 1782 444406

This technical information is provided in good faith by SciLabware Limited for the safety of its customers. Please note that the advice given is for general laboratory applications and may not necessarily apply to all tests or procedures.

The A-Z of reusable plastic labwareSciLabware Limited, Unit 4, Riverside 2, Campbell Road, Stoke-on-Trent, Staffordshire, ST4 4RJ, wUK +44 (0) 1782 444406

This technical information is provided in good faith by SciLabware Limited for the safety of its customers. Please note that the advice given is for general laboratory applications and may not necessarily apply to all tests or procedures.

The A-Z of reusable plastic labwareSciLabware Limited, Unit 4, Riverside 2, Campbell Road, Stoke-on-Trent, Staffordshire, ST4 4RJ, wUK +44 (0) 1782 444406

This technical information is provided in good faith by SciLabware Limited for the safety of its customers. Please note that the advice given is for general laboratory applications and may not necessarily apply to all tests or procedures.

www.scilabware.com [email protected]

The A-Z of reusable plastic labware

The chemical resistance of plasticsThis chart gives general guidelines on the chemical resistance of plastics. There are many factors that influence chemical resistance, we therefore recommend that you test for your own application before selecting the appropriate product. If you have any doubts please contact us for assistance.

No information available.