the influence of the new emission standard on the cfb ... emissions.pdfstandard on the cfb boiler in...
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The 64th IEA Fluidized Bed Conversion Meeting
3rd, June 2012 Naples, Italy
The influence of the new emission standard on the CFB boiler in China and
the solutions
Hairui Yang, Hai Zhang Lv Junfu Guangxi Yue
Dept. of Thermal EngineeringTshinghua University
P.R. China
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Content
Up to date of CFB boilers in China
The new emission standard
The challenges and the solutions
Dust
SO2
NOx
Technical measures
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1 Up to date of CFB boilers in China
Key position of CFB combustion in the clean coal technologies
Among CFB, IGCC, PFBC, PC+FGD, CFB and PC+FGD are the most applicable
Over 3000 units of CFB boilers in operation in China; 112 units of 300MWe CFB
30 units of Alstom technology; 42 units of domestic technology; Other 40 units under construction
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10
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30
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t ot al oper at i on al st om domest i c
Unit
Num
ber
Dongf angShanghaiHaer bi n
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600MWe SCCFB in construction
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2 New emission standards (21st, Sept, 2011)
Emission limits of different pollutions (mgm-3)
Pollutions Boiler limits
dust total 30
SO2Newly build 100(200*)
Existing 200(400*)
NOx(base on NO2 ) total 100(200**)
Mercury and other total 0.03
*
Note: ** W flame PC boiler and existing CFB boiler, the units under construction before 1st , Jan. 2012
0
50
100
150
200
250
Chi na USA JPN Eur o
Emis
sion
, mg
/Nm3
dust NOx SO2
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3 the gap and the solutions
Dust emission survey of 300MWe CFBs
For coal with high ash content, the separation efficiency is required as high as 99.85%.
Bag house dust collector (BH)
Electric bag dust collector (EB)
0 10 20 30 40 50 600
20
40
60
80
100
dust
dust
em
mis
ion,
mg/
Nm
3
ash content, %
New standard
China Electricity Council, 2011
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Comparison of BH and EB for 300MW CFB
BH EH (2E+B)
Gas rate, m3/h 1 074 400 1 074 400
Design efficiency, % 99.92 99.92
Resistance, Pa <1500 <1000
No. of electric fields / 2Area of bag 29470 25613
Service life, year 3 4
Investment cost ,% 100 129
Operation cost, % 100 118
maintain cost ,% 100 60
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Performance of emission from CFBs
SO2 emission survey of 300MWe CFBs
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.50
100
200
300
400
500
SO2
SO
2 em
issi
on, m
g/N
m3
sulfer content, %
New Standard
0
2
4
6
8
10
Ca/S
Ca/
S
China Electricity Council, 2011
SOx
排放
/mg
Nm
3 (6%
O2)
Low quality coal with high S content?
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Solutions for desufurizaiton
Coal with low S content <1.5%
Furnace limestone injection
Optimization, >90%
Limestone size
Injection points optimization
More and quick contact with oxygen
Temperature
Ruzhou 150MW CFB, S= 1.0%, limestone consumption 40 tone/day
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Solutions for desufurizaiton
Coal with high S content:
FGD------disadvantage
High efficiency, low limestone cost , high investment cost, high desufurization cost
Seriously decreasing the competition of CFB boiler
or Flash dyer absorber (FDA)
Alstom flash dyer absorber
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Counteraction between DeSOx and DeNOx
FDA Decreasing the limestone comsuption
increase in boiler efficiency
decrease in CO2 emission
decrease in ash flow
A few percent decrease in ammonia consumption
SO2
NOx
Ruzhou 150MW CFB
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Effect of CaO on NO
CaO (CaCO3 ,CaSO4) catalyze the oxidation and reduction of NH3
Pure furnace limestone Injection is not enough
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Low NOx emission feature of CFB boilers
Low combustion temperature
No thermal NOX
Mainly fuel NOx
High carbon content
Reducing atmosphere : air staging
N2 O should be considered in the future
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Volatile influence
For low volatile coals, anthracite, lean coal, coke, can meet the new emission standard with furnace temperature <900oC
0
200
400
600
800
1000
0 10 20 30 40 50
Volatile Dry ash free basis, Vdaf /%
NO
x/m
g.N
m3
CFB boilerPC boilerNew standard 200mg/Nm3
0 10 20 30 40 50 600
50
100
150
200
250
300 NOx
NO
x em
issi
on, m
g/N
m3
Volatile content, Vdaf, %
0
2
4
6
8
10
12
carbon content
Car
bon
cont
ent i
n fly
ash
, %
NOx emission survey of 300MWe CFBs
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For high volatile coals, DeNOx is needed
SCR: is too expensive and decreasing the advantage of CFB comparing with PC boiler
SNCR is more feasible and more economic
Lower investment
Simple and compact
Suitable for the relative low emission of NOx from CFB
Benefit for the desufurizaiton efficiency
M.C.Stewart, Fuel 2012
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Key factors for SNCR with ammonia or urea
Temperature:800- 900oC
Good mixing
temperature
mixing
800~900℃, optimum temperature for SNCR
Longer residence time(1.5~2.5s
Turbulence
3 2 2 2
3 2 2 2 2
2 2 2 2 2 2
4NH + 4NO+O = 4N +6H O
4NH +2NO +O = 3N +6H O
2CO(NH ) + 4NO+O = 4N +2CO + 4H O
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Optimization of the injection points
DG480/13.7-Ⅱ2 CFB
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Technical measures to meet new standard
coals Low volatile <12% High volatile
Low S content<1.5%
Furnace limestone injection
Furnace limestone injection + SNCR
High S content
Furnace limestone injection + FDA
Furnace limestone injection + SNCR+ FDAor never used in CFB
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More challenges and more opportunities