150 Jahre

The Lumina® Royal FamilyMarketing Pigments for Automotive Coatings

150 Jahre

The Lumina® Royal Family at a glance

Mica-based interference pigments with best chromaticity of all competitive products

Improved particle size distribution

2

Lumina® Royal Magenta: Shade between Pyrisma®

Magenta and Violet

Lumina® Royal Copper: Highest chroma in semi-transparent effect pigments

Lumina® Royal Blue: Most chromatic, reddish-blue

Lumina® Royal Aqua: Most chromatic, greenish-blue with high lightness

Lumina® Royal Indigo: Shade betweenPyrisma® Indigo and Violet

2009 2012 2013 2014

150 Jahre

Lumina® Royal Blue

Most chromatic blue interference pigment based on mica

Flat, uniform surfaces for high brilliancy

Prevailed already into Automotive shades

3

150 Jahre

Coloristic properties

Lumina® Royal Exterior Blue 6803H

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Lumina® Royal Exterior Blue 6803HLumina® Exterior Red Blue 6303DBest competitive, blue interference pigment

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15° angle h C* L* DH* DC* DL* DE*

Lumina® Royal Exterior Blue 6803H 285.6 60.1 36.9

Lumina® Exterior Red Blue 6303D 271.6 42.8 38.7 -12.4 -17.3 1.8 21.3

Best competitive, blue interference pigment 278.7 52.7 36.9 -6.8 -7.4 0.0 10.1

Test system90:10 black reduction in a solvent-borne binder (polyester/CAB, medium solid)

150 Jahre

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Coloristic properties

Lumina® Royal Blue 9680H

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Lumina® Royal Blue 9680HLumina® Red Blue 9B30D

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15° angle h C* L* DH* DC* DL* DE*

Lumina® Royal Blue 9680H 284.8 60.7 38.6

Lumina® Red Blue 9B30D 273.4 46.9 42.9 -10.6 -13.9 4.3 18.0

Test system90:10 black reduction in a solvent-borne binder (polyester/CAB, medium solid)

150 Jahre

Coloristic properties

Lumina® Royal Exterior Blue 6803HIn combination with blue organic pigments

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Test system50 parts P.B.60 / Heliogen45 parts blue interference pigment5 parts black pigment FW 200In a solvent-borne CAB/polyester

Royal Blue 6803H / P.B.60 / FW 200Red Blue 6303D / P.B.60 / FW 200Best competitive, blue interference pigment / P.B.60 / FW 200

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Royal Blue 6803H / L 6950 / FW 200Red Blue 6303D / L 6950 / FW 200Best competitive interference pigment / L 6950 / FW 200 L

150 Jahre

Coloristic properties

Lumina® Royal Exterior Blue 6803HImpact on a mid-blue metallic styling

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Styling with Lumina® Royal Exterior BlueStyling with Exterior Mearlin® Super Blue 6303ZStyling with best competitive, blue interference pigment

Mid-blue metallic styling40 parts blue mica (6803H or 6303Z or Pyrisma® Blue)10 parts aluminum37.2 parts P.B.609.9 parts Heliogen® Blue L 69501.2 parts Cinquasia® L 45401.7 parts Cromophtal® D 5800

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260 265 270 275 280 285 290 295

150 Jahre

Coloristic properties

Lumina® Royal Exterior Blue 6803HImpact on a deep reddish-blue styling

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Styling with Lumina® Royal Exterior BlueStyling with Exterior Mearlin® Super Blue 6303ZStyling with best competitive, blue interference pigment

Reddish-blue styling20 parts blue mica (6803H or 6303Z or Pyrisma® Blue)20 parts Mearlin® Super Violet 5303Z50 parts P.B.608 parts Heliogen® Blue L 7081D2 parts Carbon Black FW 200

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292 294 296 298 300 302

150 Jahre

Summary

Lumina® Royal Exterior Blue 6803H and Lumina® Royal Blue 9680H Lumina® Royal Blue is a highly chromatic

reddish-blue (Note: The greenish-blue side is covered by Lumina® Royal Aqua)

Lumina® Royal Blue shows extreme chromain combination with P.B.60, alpha-CuPc(15:1, 15:2) and epsilon-CuPc (P.B., 15:6)

For combination with greenish-blues (beta-Blue, 15:3, 15:4), Lumina® Royal Aqua is the best choice

Brilliant and smooth appearance thanks to optimized particle size distribution

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150 Jahre

Particle size distribution H vs. D-fraction

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The H fraction has an optimized d90 value

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(%)

Particle size (μm)

Lumina® Royal BlueLumina® D-fraction

Masterizer 2000 Version 5.12GS/N: MAL101491

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L d d d

L d d d

Lumina® Royal Blue 6803H and 9680H

Lumina® Royal Hd10 ~ 10 µmd50 ~ 19 µmd90 ~ 34 µm

Lumina® Dd10 ~ 10 µmd50 ~ 21 µmd90 ~ 39 µm

150 Jahre

Technical data

Lumina® Royal Exterior Blue 6803H

* Physical data determined at lot 207553

*** test in a black reduction (pigmentation 90 pts. EH 402 + 10 pts. FW 200) acc. DIN EN ISO 4892-2

**** test in a black reduction (pigmentation 90 pts. EH 402 + 10 pts. FW 200, solventborne basecoat/clearcoat)

** Particle size distribution (Vol %) determined with Mastersizer 2000 Ver 5.12G (Malvern Instruments)

Chemical composition mica 53,7 % by weightTiO2 (Rutile) 27,4 % by weightSnO2 1,6 % by weightSiO2 (amorphous) 14,8 % bei weight

Surface treatment Polymer 2,5 % bei weight Physical form white powder Physical data* pH 7.7 (10 % aq. suspension)

Conductivity 31.6 µS/cm (10 % aq. suspension)Bulk volume 1.8 l/kgDensity 2.84 g/cm3

Total solids > 99.5 % by weight Particle size distribution** d10 10 µm

d50 19 µmd90 34 µm

Fastness to solvents practically insoluble in all solvents Chemical resistance HCl (2%) no change

(in coatings) NaOH (2%) no change Heat stability > 200 °C Weathering data*** 2 years Florida ongoing

accelerated 4000 h ok Humdity resistance**** 24 h, 70°C no whitening

gloss and DOI after 24 h 100 %cross hatch after 1 h 0

10 d, 40°C no whiteninggloss and DOI after 24 h 100 %cross hatch after 1 h 0

11

150 Jahre

Technical data

Lumina® Royal Blue 9680H

* Physical data determined at lot 207468 ** Particle size distribution (Vol %) determined with Mastersizer 2000 Ver 5.12G (Malvern Instruments)

Chemical composition mica 55,1 % % by weightTiO2 (Rutile) 28,1% by weightSnO2 1,6 % by weightSiO2 (amorphous) 15,2 % by weight

Physical form white powder Physical data* pH 9.2 (10 % aq. suspension)

Conductivity 29 µS/cm (10 % aq. suspension)Bulk volume 2.95 l/kgDensity 2.88 g/cm3

Total solids > 99.5 % by weight Particle size distribution** d10 10 µm

d50 19 µmd90 34 µm

Fastness to solvents practically insoluble in all solvents Chemical resistance HCl (2%) no change

(in coatings) NaOH (2%) no change Heat stability > 200 °C FDA-approval yes

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150 Jahre

Lumina® Royal Aqua

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Most chromatic effect pigment

Greenish-blue with high lightness

150 Jahre

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Coloristic properties

Lumina® Royal Exterior Aqua 7803HHigher lightness and higher chroma

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Test systemSolvent-borne base coat / solvent-borne clear coat90 parts blue interference pigment10 parts Pigment Black 7

Lumina® Royal Exterior Aqua 7803HLumina® Exterior Aqua 7303D

150 Jahre

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Coloristic properties

Lumina® Royal Aqua 9780HHigher lightness and higher chroma

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Test systemSolvent-borne base coat / solvent-borne clear coat90 parts blue interference pigment10 parts Pigment Black 7

Lumina® Royal Aqua 9780HLumina® Aqua 9A30D

150 Jahre

Coloristic data

-15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 265,0 51,7 49,9 -4,5 -51,57303D 263,3 42,9 44,1 -5,0 -42,6 -1,4 -8,8 -5,8 -0,5 8,9 10,6

15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 256,5 45,3 51,5 -10,6 -44,07303D 252,0 38,3 43,3 -11,9 -36,4 -3,3 -7 -8,2 -1,2 7,6 11,3

25° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 253,0 31,7 36,3 -9,2 -30,37303D 249,0 26,2 28,8 -9,4 -24,4 -2 -5,5 -7,5 -0,1 5,8 9,5

45° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 251,8 17,1 17,1 -5,4 -16,27303D 250,6 13,3 12,6 -4,4 -12,5 -0,3 -3,8 -4,6 1 3,7 6

75° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 254,7 9,7 7,9 -2,6 -9,37303D 261,0 6,6 6,6 -1,0 -6,5 0,9 -3,1 -1,3 1,5 2,8 3,4

110° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 7803H 263,4 5,2 4,2 -0,6 -5,27303D 271,0 3,4 4,7 0,1 -3,4 0,6 -1,8 0,4 0,7 1,8 2

-15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 9780H 262,8 52,3 52,5 -6,6 -51,99A30D 264,4 45,3 45,8 -4,4 -45,1 1,4 -7,0 -6,7 2,1 6,8 9,8

15° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 9780H 254,1 45,6 54,1 -12,5 -43,99A30D 252,9 39,7 44,5 -11,7 -38,0 -0,9 -5,9 -9,6 0,8 5,9 11,3

25° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 9780H 251,0 31,8 38,0 -10,4 -30,19A30D 249,9 25,9 28,5 -8,9 -24,3 -0,5 -6,0 -9,5 1,5 5,8 11,2

45° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 9780H 249,7 17,0 17,8 -5,9 -15,99A30D 252,8 12,8 12,5 -3,8 -12,2 0,8 -4,2 -5,3 2,1 3,7 6,8

75° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 9780H 252,8 9,7 8,3 -2,9 -9,29A30D 263,1 6,6 6,9 -0,8 -6,5 1,4 -3,1 -1,4 2,1 2,7 3,7

110° h C* L* a* b* ΔH* ΔC* ΔL* Δa* Δb* ΔE* 9780H 262,4 5,4 4,4 -0,7 -5,49A30D 272,3 3,4 4,9 0,1 -3,4 0,7 -2,0 0,5 0,9 2,0 2,2

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Test system90:10 black reduction in a solvent-borne binder (polyester/CAB, medium solid)

150 Jahre

Lumina® Royal vs.best competitive interference pigments

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Lumina® Royal Exterior Blue 6803HBest competitive interference blueLumina® Royal Exterior Aqua 7803HLumina® Royal Exterior Indigo 5803HBest competitive indigoBest competitive violet

Test system90:10 black reduction in a solvent-borne, medium-solid system (polyester/CAB)

150 Jahre

7803Hd10 ~ 9 µmd50 ~ 18 µmd90 ~ 33 µmd100 ~ 60 µm

Particle size distribution

Lumina® Exterior Aqua 7303H vs. Lumina® Royal Exterior Aqua 7803H

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Volu

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Particle size (μm)

Lumina® Exterior Aqua 7303DLumina® Royal Exterior Aqua 7803H

Measured with Masterizer 2000 Version 5.12G

S/N:MAL101491Malvern Instruments Ltd.

7303Dd10 ~ 12 µmd50 ~ 22 µmd90 ~ 44 µmd100 ~ 73 µm

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150 Jahre

Particle size distribution

Lumina® Aqua 9A30D vs. Lumina® Royal Aqua 9780H

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Lumina® Aqua 9A30DLumina® Royal Aqua 9780H

9780Hd10 ~ 9 µmd50 ~ 18 µmd90 ~ 33 µmd100 ~ 60 µm

9A30Dd10 ~ 12 µmd50 ~ 22 µmd90 ~ 44 µmd100 ~ 73 µm

Particle size (μm)

Volu

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Measured with Masterizer 2000 Version 5.12G

S/N:MAL101491Malvern Instruments Ltd.

150 Jahre

Summary

Lumina® Royal Exterior Aqua 7803H and Lumina® Royal Aqua 9780H Greenish-blue interference pigments

with highest chroma and lightness

Improved particle size distribution

Both are standardized

Production process under control with high-quality consistency

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150 Jahre

Lumina® Royal Indigo

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High chroma pigment

Shade between Pyrisma Indigo and Violet

150 Jahre

Majestic effects with Lumina® Royal

Lumina® Royal Exterior Violet 5803H vs. the state of the art in a 90:10 black reduction (PE/CAB-MS)

15°15°

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110°Lumina® Royal Exterior Indigo is designed for extremely chromatic shades in combination with transparent organic pigments such as Paliogen Blue or Cinquasia Violet.

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Mearlin® Super Violet 539ZLumina® Royal Exterior Violet 5803HBest competitive violet

150 Jahre

Particle size distribution

Particle size distribution of Lumina® Royal Exterior Indigo 5803H vs. Mearlin® Exterior Super Violet 5303Z

Lumina® Royal Exterior Indigo 5803H Mearlin® Super Violet 5303Z

Particle size (μm)

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Measured with Mastersizer 2000 Version 5.12GS/N: MAL 101491Malvern Instruments Ltd.

5303Zd10 ~ 9 µmd50 ~ 19 µmd90 ~ 37 µmd100 ~ 73 µm

5803Hd10 ~ 9 µmd50 ~ 18 µmd90 ~ 33 µmd100 ~ 60 µm

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150 Jahre

Lumina® Royal Copper

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Highest chroma in semi-transparent effect pigments

Extraordinary sparkle behavior

150 Jahre

Lumina® Royal Copper

Lumina® Royal effect pigments benefits Better color purity, strength, and brilliancy and sparkle compared to pigments

of the same class

New, extremely high chroma shades can now be created

Extension of color space for new styling options and greater formulation flexibility

The option to use reduced levels in standard effect shade formulations

Areas of application Exterior grades: e.g. aerospace, automotive OEM and refinish coatings,

consumer electronics, building and construction

Standard grades: e.g. consumer electronics, kitchen and major appliances, household goods, sporting goods, cosmetic and personal care packaging, print packaging, powder and coil coatings, wall coverings, and specialty applications

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150 Jahre

Lumina® Royal CopperBenefits

Higher chroma

Pronounced sparkle

Narrower particle size distribution d90 less than 35 µm

Extension of color space Highest chroma Strong sparkle

Higher impact on resulting shade through higher color intensity

Luxurious browns and warm metal tones

New modern styling options to differentiate from competitors

Greater formulation flexibility to optimize formulations

Reduction of pigment load to gain flexibility

Benefit in printing and packaging applications

Primary properties

Properties in application

Customer benefits

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150 Jahre

Coloristic properties

Lumina® Royal Copper vs. state of the art

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45 parts Lumina® Royal Copper50 parts Paliogen® Red L 38855 parts FW 200

45 parts Lumina® Copper50 parts Paliogen® Red L 38855 parts FW 200

90 parts Lumina® Royal Copper10 parts FW 200

90 parts Lumina® Copper10 parts FW 200

150 Jahre

Lumina® Royal Copper has about 60% stronger sparkle effect than Lumina® Copper

Lumina® Royal CopperSparkle characteristics

Total sparkle grade of Lumina® Royal Copper vs. state of the art

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S_G

Illumination angle

45 parts Lumina® Royal Copper50 parts Paliogen® Red L 38855 parts FW 200

90 parts Lumina® Royal Copper10 parts FW 200

45 parts Lumina® Copper50 parts Paliogen® Red L 38855 parts FW 200

90 parts Lumina® Copper10 parts FW 200

150 Jahre

Lumina® Royal Magenta

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Shade between Pyrisma Magenta and Violet

150 Jahre

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Lumina® Royal Magenta Benefits

Primary properties

Properties in application

Customerbenefits

Magenta interference effect pigment

Extreme chroma

Narrower particle size distribution d90 less than 35 µm

Extension of color space

Tinting in blue and red shades Blues go red Reds go blue

Higher impact on resulting shade through higher color intensity

New modern styling options to differentiate from competitors

Greater formulation flexibility to optimize formulations

Reduction of pigment load to gain flexibility and achieve more economical solutions

150 Jahre

Competitive landscape

Lumina® Royal range vs. best competitive interference pigments

Aqua

Blue Indigo

Magenta

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Lumina® Royal is superior in chroma in all shade areas Lumina® Royal Magenta completes the series of “Blue Royals” at the reddish end

Lumina® Exterior Royal Aqua 7803HLumina® Royal Exterior Blue 6803HLumina® Royal Exterior Indigo 5803HLumina® Royal Exterior Magenta EH 5000 (4803H) State-of-the-art blueState-of-the-art indigoState-of-the-art violetState-of-the-art magenta

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Test system90 parts effect pigment10 parts FW 200

150 Jahre

Coloristic properties

Lumina® Royal Magenta exhibits the highest chroma in black reduction

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Lumina® Royal Exterior Magenta EH 5000 (4803H) : FW 20090 : 10State-of-the-art violet : state-of-the-art magenta : FW 20035 : 35 : 20

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Test system90 parts effect pigment10 parts FW 200

Lumina® Royal Exterior Magenta EH 5000 (4803H) vs. best competitive pigments

150 Jahre

Coloristic properties

Lumina® Royal Exterior Magenta EH 5000 (4803H) In a magenta styling

Lumina® Royal Magenta exhibits the highest chroma in pigment combinations

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Lumina® Royal Exterior Magenta EH 5000 (4803H) : L 4540 : FW 200 = 45 : 50 : 5State-of-the-art violet : state-of-the-art magenta : L 4540 : FW 200 = 17.5 : 27.5 : 50 : 5

Test styling45 parts effect pigment50 parts Cinquasia® Magenta L 45405 parts FW 200

150 Jahre

Coloristic properties

Lumina® Royal Exterior Magenta EH 5000 (4803H) More chromatic than the state of the art

Lumina® Royal Magenta unmatched by state-of-the-art effect pigments

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Hue matches based on combinations of Lumina®

Royal Indigo with Lumina® Red have lower chroma

Hue matches based on combinations of state-of-the-art violet and magenta have lower chroma

Test styling45 parts Lumina® Royal Exterior Magenta EH 500050 parts Cinquasia® Magenta L 45405 parts FW 200

EH 5000 : L 4540 : FW 200 = 45 : 50 : 55803H : L 4540 : FW 200 = 45 : 50 : 54303D : L 4540 : FW 200 = 45 : 50 : 55803H : 4303D : L 4540 : FW 200 = 22.5 : 22.5 : 50 : 55803H : 4303D : L 4540 : FW 200 = 27.5 : 17.5 : 50 : 5State-of-the-art violet : state-of-the-art magenta : L 4540 : FW 200 = 17.5 : 27.5 : 50 : 5

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150 Jahre

Styling options

Lumina® Royal Magenta in combination with organic pigments leads to brilliant effect shades between Lumina® Red and Royal Indigo

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Lumina® Red 4303D Lumina® Royal Exterior Magenta EH 5000 (4803H)

50 pts Paliogen® Red L 388545 pts Lumina® Red 4303D5 pts Carbon Black FW 200

50 pts Paliogen® Red L 388545 pts Lumina® Royal Ext. Magenta EH 5000 (4803H)5 pts Carbon Black FW 200

50 pts Irgazin® Rubine L 4025 (TR)45 pts Lumina® Red 4303D5 pts Carbon Black FW 200

50 pts Irgazin® Rubine L 4025 (TR)45 pts Lumina® Royal Ext. Magenta EH 5000 (4803H)5 pts Carbon Black FW 200

50 pts Cinquasia® Magenta L 4540 (RT-355-D)45 pts Lumina® Red 4303D5 pts Carbon Black FW 200

50 pts Cinquasia® Magenta L 4540 (RT-355-D)45 pts Lumina® Royal Ext. Magenta EH 5000 (4803H)5 pts Carbon Black FW 200

50 pts Paliogen® Blue L 648045 pts Lumina® Red 4303D5 pts Carbon Black FW 200

50 pts Paliogen® Blue L 648045 pts Lumina® Royal Ext. Magenta EH 5000 (4803H)5 pts Carbon Black FW 200

P.R. 179

P.R. 264

C.I. n.a.

P.B. 60

150 Jahre Please get in touchwith your local account managerMarketing Pigments for Automotive Coatings

150 Jahre