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    AL- FATIHAH

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    Garden of Knowledge & Virtue

    ENGINEERING MATERIALS/

    MATERIALSSCIENCE & ENGINEERING

    MME 2501 MME 2503

    THERMAL PROCESSING OF METAL

    2

    Dr Zahurin Halim Sem 2 1112

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    AS SABAK ( (Surah 34 Verse 10

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    And indeed We bestowed grace on Daud from Us: O

    mountains, glorify with him Allahspurity repeatedly - and

    you too O birds! And We made the iron soft for him.

    [Dan demi sesungguhnya, Kami telah memberikan kepada Nabi Daud limpahkurnia dari Kami (sambil Kami berfirman): "Hai gunung-ganang, ulang-ulangilahmengucap tasbih bersama-sama dengan Nabi Daud, dan wahai burung-burung

    (bertasbihlah bersama-sama dengannya)!" Dan juga telah melembutkan besi

    baginya]

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    Garden of Knowledge & Virtue

    LEARNING OBJECTIVE

    4

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    Garden of Knowledge & Virtue

    AFTER STUDYING THIS CHAPTER

    YOU MUST BE ABLE TO:

    State the purpose of the heat treatments.Describe briefly the following heat

    treatment:

    Annealing

    NormalizingQuenching

    Tempering

    Describe the microstructure differencewith the difference in heat treatment.

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    Garden of Knowledge & Virtue

    HEAT TREATMENT-

    INTRODUCTION

    Modern demands of good quality products have madeheat treatment an important process for mostengineering applications.

    Heat treatment involves the improvement of propertiesof metals and alloys by changing their microstructure.

    Thermal processing of metals is a metallurgy processthat involves heating or cooling

    Heat treatment: heating and cooling procedure tomanipulate structural changes in most metal

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    Heat treatment can be done to accomplish any

    number of objectives:

    To diffuse carbon and alloying elementsTo soften the materialsTo improve machineabilityTo harden the material

    To increase the toughnessTo increase wear resistanceTo relief the stress

    Materials undergo heat treatment with the objective

    of:Before shaping - To softening a metal before formingAfter forming- To relief strain hardeningFinal finish - To achieve final strength and hardness

    HEAT TREATMENT -

    OBJECTIVE

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    HEAT TREATMENT -TYPES

    8

    Annealing

    Normalizing

    Quenching

    Tempering

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    HEAT TREATMENT OF STEEL

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    PROCESS PURPOSE PROCEDURE PHASE(s)

    Annealing

    Quenching

    Normalizing

    Tempering

    To soften

    To harden

    To refine the grain

    structure

    To reduces

    brittleness of

    martensite and to

    reduces internal

    stress caused by

    quenching

    Slow cool from-stable range

    Quench to miss

    I-T curves

    Slow cool from

    -stable range

    Quench,

    followed by

    annealing

    + cementite(PEARLITE)

    Martensite

    + cementite

    (BAINITE)

    Temperedmartensite

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    SUMMARY: PROCESSING

    OPTIONS

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    ANNEALING

    12

    The iron-carbon

    phase diagram in the

    vicinity of theeutectoid, indicating

    heat treating

    temperature rangesfor plain carbon steels

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    Annealing: Heat to Tanneal, then cool slowly.

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    Types of

    Annealing:

    1. Full annealing

    2. Processannealing

    3. Spheroidizing

    1. Full Annealing Steel heated to a hightemperature (10-38C)above the

    upper transformation temperature.

    Upon reaching this temperature

    the steel changes to austenite andbecomes face centered cubic.

    Material then is cooled in the

    oven. Cooling rate 100F per hour.

    A temperature (10-38C) above the

    upper transformation temperatureis normally sufficient to produce

    austenite without generating large

    grain size.

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    2. Process Annealing: Part is heated above 700C. Process annealing is

    frequently used an intermediate heat treating step.Inprocess annealing part is not softening as full annealingbut time required is considerable less. No phase transformation occurs because thetemperature is below A1

    3. Spherodizing:Spheroidizing is a quick annealing method identical to processannealing. Parts are heated to a temperature below or near thelower transfoRmation temperature and then cooled slowly. Thename spheroidizing comes microscopic appearance of the steel.

    A photomicrograph of a pearlite steel has partially

    transformed to spheroidize

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    EFFECT AND PURPOSE OF

    ANNEALING

    Purpose of Annealing The material is easier to machine, after most ofmachining is completed the part is hardened byheating and quenching To provide a material that is easier to form

    To relieve internal stresses To refine the crystal structure

    Effect of Annealing :o More soften

    o Make a material less hardo Make a material less brittle & more ductileo Reduce the amount of internal stresseso Reduce tendency to distort and crack

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    Garden of Knowledge & Virtue16

    NORMALIZING

    Process involves heating the materialabove the upper critical temperature

    and then cooling it slowly at room

    temperature, when the material isremoved from the furnace it is set out to

    cool slowly on a bench or a floor. Effect

    materials on normalizing is same with

    annealing except for a finer grain size.

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    QUENCHING

    Quenching is a controlled cooling process which causes metals to

    harden. Material heated to a high temperature and plunged

    quickly into the quenching medium and submerged until they are

    cool.

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    Garden of Knowledge & Virtue18

    Water quenchingMost commonly used, inexpensive, convenientto use, provides very rapid coolingCan cause internal stresses distortion orcrackingWater quenching should be about roomtemperature for best result.Oil quenchingIs more gentle than water as a quenchingmediaIt is used for more critical parts, such as partswhich have thin sections or sharp edges ex:razor blades and knife.Less change of internal stresses, distortion, orcracking but does not produce as hard orstrong of steel as water does.

    QUENCHING MEDIA

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    Air quenchingLess drastic than either oil or water.Air does not cool as rapidly as either oil or water.Because of slower rate of cooling, there is lesschange of internal stresses, distortion andcracking.Generally used only on steels which have highalloy content. Special alloys such as chromiumand molybdenum are selected because they areknown to cause the material to harden eventhough a slower quenching method is used.Brine quenching

    Brine itself is salt water(5-10%) salt in water.

    Brine will cool the material slightly faster than

    water.

    QUENCHING MEDIA

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    HARDENABILITY--STEELS

    Ability to form martensite Jominy end quench test to measure hardenability.

    24C water

    specimen(heated to

    phase field)

    flat ground

    4

    1

    Adapted from Fig. 11.10,

    Callister 6e. (Fig. 11.10

    adapted from A.G. Guy,

    Essentials of Materials

    Science, McGraw-Hill

    Book Company, New

    York, 1978.)

    Hardness versus distance from the quenched end.

    WHY HARDNESS CHANGES

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    WHY HARDNESS CHANGESWITH POSITION

    The cooling rate varies with position.

    Adapted from Fig. 11.12, Callister 6e.

    (Fig. 11.12 adapted from H. Boyer (Ed.)

    Atlas of Isothermal Transformation

    and Cooling Transformation Diagrams,

    American Society for Metals, 1977, p.

    376.)

    HARDENABILITY VS ALLOY

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    HARDENABILITY VS ALLOYCONTENT

    Jominy end quenchresults, C = 0.4wt%C

    "Alloy Steels"

    (4140, 4340, 5140, 8640)

    --contain Ni, Cr, Mo

    (0.2 to 2wt%)--these elements shift

    the "nose".

    --martensite is easier

    to form.

    Adapted from Fig. 11.13, Callister 6e.

    (Fig. 11.13 adapted from figure

    furnished courtesy Republic SteelCorporation.)

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    Garden of Knowledge & Virtue

    Effect of quenching medium:

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    QUENCHING MEDIUMGEOMETRYMedium

    air

    oil

    water

    Severity of Quenchsmall

    moderatelarge

    Hardnesssmall

    moderate

    large

    Effect of geometry:When surface-to-volume ratio increases:

    --cooling rate increases--hardness increases

    Positioncenter

    surface

    Cooling ratesmalllarge

    Hardnesssmalllarge

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