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THERMAL PROTECTION SYSTEMS

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Page 1: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION

SYSTEMS

Page 2: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

BRING NATURE INTO SPACE

Efficient & Easy integration

THERMAL PROTECTION SYSTEMS

Page 3: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Amorim Cork Composites has been manufacturing and supplying Cork

based materials to be used in Thermal Protection Systems (TPS) for the

Aerospace industry, since the beginning of space exploration.

Amorim Cork Composites is part of

Amorim Group, world leader in cork

products, dedicated to industrial

customers, with production sites in

Portugal, Spain and United States.

Our History

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

“Cork is the bark of the Cork Oak tree (Quercus Suber), is nature's foam,

a foam with a unique combination of properties”,

In NASA Report : “Moldable Cork ablation material”.

Sample of P50 collected from the

Space Shuttle SRB

Perfection, by Nature

Cork cells structure

Page 5: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Cork cells are small, irregular pentagonal or hexagonal prisms.

Fifty per cent of cork is an air-like gas enclosed in the cork cells.

Cork retains unique qualities of flexibility, elasticity and compressibility.

Copyright 2002 by APCOR

Suberin makes the cork cell membrane

impermeable and the cell airtight

Perfection, by Nature

Very low heat transfer:

• Low solid fraction

• Gas enclosed in the cells has low

conductivity

• No convection between cell struture

• Radiation is reduced through the

repeated absorption and reflection at the

cell walls

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Product range

Cork chemical constituents and structure, make it an ideal ablative

material with excellent insulating properties, maintaining low weight

to low thermal conductivity results.

Page 7: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Customer Specification Approvals:

•Boeing STM0585-02

P45 Sheets

Cork composition material

made with 10/20 cork

granule and a special binder

for high heat resistance.

P50 Sheets

Cork composition material

made with 20/40 cork

granule and a special binder

for high heat resistance.

Customer Specification Approvals:

•Pratt & Whitney TS10433

•Pratt & Whitney CMS0041C

•Thiokol SP733

•Navy WS16603

•Navy WS24865

•Hercules S13034

•Boeing STM0585-01

•Boeing BMS8-70M

•Lockheed 0-06125

A/B: Magnification 50x

A

B

Product range

Page 8: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Main Advantages

Page 9: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Apollo Command Module

APOLLO Spacecraft Systems

“A series of five flight experiments was conducted aboard the

NASA Scout, RAM, and four-stage research vehicles for the

purpose of testing lightweight phenolic cork as a thermalprotection material. “…” .

in NASA report :“Free-flight test results on the performance of Cork as a thermalprotection material”, from Sept. 1964

SCOUT Rockets

The boost-protective cover protects the command module from

aerodynamic heating during boosted flight and from heat and

soot from the launch escape and Jettison motors of the launch

escape system.

It is made of ablative Cork and Teflon-impregnated glass cloth,

supported by glass honeycomb in the upper portion.

Success Records

Page 10: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Today“90’s”“80’s”“70’s”“60’s”

Scout

Since the begining of the space age Amorim Cork Composites is

supplying sheet materials or specially graded cork granules for

European and USA customers. Here’s where we have been present…

Success Records

Space

Shuttle

Delta IV

Mars

Rovers Beagle

Apollo

Ariane 5

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

“..... materials made by Amorim were used in the

Delta IV for thermal insulation of the rocket's

engines.”

Our involvement in this project is the result of a joint strategy that

we have been working on in this market for a number of years. With

our involvement in this and other similar projects, Amorim has

revealed its full potential in Research & Development and, above all,

the capacity to develop and engineer products for critical

applications. This capacity is the result of the large investment in R &

D that Amorim began back in the 1990's and has continued into this

decade. Cork as a raw material is, in fact, unique and allows infinite

applications.

Amorim Products on the DELTA IV rocket

Our “CV”

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

P45 and P50 are used has TPS materials in several locations of Delta IV

Rocket, where the thermal requirements are necessary, like:

• Booster Nose Cone

• Frustum

• Forward Skirt & Aft skirt

• Tunnel covers

• ETR ring covers

Applications

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

P45 and P50 are used has TPS materials in several locations on the SRB

of Space Shuttle, like:

• Booster Nose Cone

• Frustum

• Bolt catcher

• External Skirt insulation

• ETR ring covers

Applications

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE STUDIES

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE I – Cork behaviour

• Thermal expansion (down to -160°C)

• Thermal conductivity (down to -160°C)

• Thermal decomposition

• Loss factor

Thermal behaviour of cork,

together with it’s stable

damping response in a

wider temperature range,

makes it possible to

integrate in non-critical

structural elements in

CFRP composites

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE I – Cork behaviour

Thermal Conductivity of a cork

composition material at -160°C

A escrever escrever escre

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE I – Cork behaviour

Thermal Expansion of a cork

composition material at -160°C

A significant dependence of the

thermal expansion coefficient

from the direction of the axis was

not observed0,65

0,75

0,85

0,95

1,05

1,15

1,25

1 min 2 min 3 min 5 min 10 min 15 min 20 min

x-direction

y-direction

z-direction

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Mass loss of cork is relatively

small (6% of initial mass) until

200ºC

It increases until complete

carbonization at about 450ºC

The structure of the cork cells

however are now completely

destroyed

CASE I – Cork behaviour

Thermal decomposition

0,0

0,2

0,4

0,6

0,8

1,0

1,2

0 100 200 300 400 500 600

M/Mo

ºC

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Loss Factor of a cork

(temperature sweep)

CASE I – Cork behaviour

Loss factor of cork is about 0.1

with a weak dependence on

frequency up to 10KHz, but

increasing to nearly 0.3 for high

strain amplitudes

Cork Tg is located around 20ºC

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

P45 applied to:

• Chamber

• Main Skirt

• Lower Skirt

• Exit closure

CASE I I – Titan IV

P45 coated with white silicone

rubber on engine of the Titan IV

rocket.

A

BC

D

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE I I – Titan IV

P45 coated with white silicone rubber on

engine of the Titan IV rocket.

Depending of the location of the ablative

protection, 50% to 70% is transformed in to

char/recession after the flight

A B C D

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE III – SRB, Skirt Joint System

Forward and aft skirt JPS is primarily to provide thermal

protection, weather protection and to retain the pins

Cork

Cork is bonded with adhesive and

painted

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

CASE III –SRB, Skirt Joint System

The purposes of the FJPS are to

maintain an optimal temperature

for O-ring tracking and to prevent

environmental contaminants such

as rainwater from entering the joint

area

Cork

Heater Retainer Strap and Thermal

Barrier

Joint Temperature

Sensor

Joint Heater

Pin Retainer Band

RT-455 Ablative

RT-455 Ablative

Cork

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

During ascent phase, there is

the need to separate the tanks

from the rocket at a precise

time. That must be

accomplished at the same time

by exploding the nuts that

connect the tanks to the body.

CASE III – SRB, Bolt Catcher

Any debris of the explosion is caught by a structure that contains

cork to protect all the pyrotechnic system to avoid any damage

during the ascent phase.

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

MCC1 from NASA is an formulation and

method of spray deposition of a cork-

and-glass-filled epoxy ablative thermal-

insulation material.

Used by Boeing on Sea Lunch

Programme:

•Delta IV

• Air force Titan IV

Applied to SRB in:

• nose cap

• forward skirt

• aft skirt

• tunnel covers

CASE IV – Specially graded Cork Granules

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

SLA-561 from Lockheed Martin,

is a low density, low

conductivity ablator/ insulator.

It is a highly filled elastomeric

silicone composition

containing cork as one filler

ingredient.

The material is available in moulded panels with or without

honeycomb support.

The panels can be bonded with silicone adhesive using vacuum

bag processes.

Used in the Mars Rovers.

CASE IV – Specially graded Cork Granules

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THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

This thermal protection material is used on parts

of Ariane 5, space probes and on ARD, especially

on large surfaces.

Norcoat Liege from EADS, is an ablative material

based on phenolic resin and cork

CASE IV – Specially graded Cork Granules

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COMUNICATION & TOOLS

Page 29: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Page 30: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

ENVIRONMENTAL RESPONSABILITY

Page 31: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry

THERMAL PROTECTION SYSTEMS

Bringing Nature into Space Amorim ablative materials for the space industry

Environmental Responsability

Page 32: THERMAL PROTECTION SYSTEMS - 最齊全的軟木資訊,在亞朋 · 2020-03-18 · THERMAL PROTECTION SYSTEMS Bringing Nature into Space Amorim ablative materials for the space industry