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Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 1
Thermoelectric applications
Thermoelectric generators
Université de Pau et des Pays de l'Adour France
Laboratoire des Sciences de l’Ingénieur Appliquées à la Mécanique
et au Génie Electrique (SIAME EA4581),
Fédération IPRA FR2952
CHAMPIER Daniel
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 2
Thermoelectric (TE) Generators TEG
Heat
Generator Heat
sink
TE modules
Electrical power
(<5%)
exchanger exchanger
Electronic
converter
Storage Battery
convert directly a very small part of the heat moving through them into electricity
Module efficiency
.TEWe T 1 zT 1
TcQh Th 1 zTTh
Th Tc Tsh Tsc
.TE
H C TE
RT Ts
R R R
efficiency, generator maximum power
.
. . .Max 2 2elec
NSW T
8L
Dependence upon the temperature
difference across the thermoelements
Construction :
number of thermoelements
cross-sectional area
length of each element.
‘‘power factor’’ :
type of TE material
Maximum Power
DC DC
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 3
3 International Energy Agency publication :2013 Keyworld energy statistic
World total final consumption from 1971 to 2011
by fuel (Mtoe)
***Other includes geothermal, solar, wind, etc
1Toe=tonne of oil equivalent =41.8 GJ =11.6 MWh = 1 Tep (français)
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 4
4 Gail Tverberg http://ourfiniteworld.com/2012/03/12/world-energy-consumption-since-1820-in-charts
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 5
173,000 terawatts
2014 Perez Massachusetts Clean Energy Center
Energy is not a problem
Sustainability is the problem
<0.00001 TW.y
TEG
y
Ocean Thermal Energy
0.005 TW.y
1 Billion cars with
a 250W TEG
I have a dream
Yes we can
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 6
6
Roadmap for climate and energy policies
2008 European Concil new environmental targets : "three 20 targets”
by 2020
To reduce emissions of greenhouse gases by 20%.
To increase energy efficiency to save 20% of EU energy consumption
To reach 20% of renewable energy in the total energy consumption in the EU.
January 2014 European Concil new environmental targets
by 2030
To reduce emissions of greenhouse gases by 40%.
To continue improvements in energy efficiency
To reach 27% of renewable energy in the total energy consumption in the EU.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 7
7
Some Efficiency
. L’objectif « 20-20-20 » vise pour 2020 à :
Diminuer de 20 % les émissions de Gaz à
Effet de Serre (GES) par rapport aux
missions de 1990 ;
Réduire de 20 % la consommation
d'énergie par le biais de l'amélioration de
l'efficacité énergétique;
Atteindre 20 % d'énergies renouvelables
dans le bouquet énergétique.
Efficiency in Electricity Generation 2003
Union of the electricity industry
2013
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 8
The carbon footprint of Energy-Technologies
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 9
TE efficiency
.TEWe T 1 zT 1
TcQh Th 1 zTTh
Thermoelectricity has a chance only where other forms of energy production
are not cost effective.
Thermoelectricity : no chance for big power plant
0 50 100 150 200 250 3000
5
10
15
20
25
30
35
40
45
50
difference of temperature Th-Tc K
eff
icie
nc
y %
Carnot efficiency
ZT=3
ZT=2
ZT=1
ZT=0.8
ZT=0.5
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 10
Classification of generators
• recovery of thermal energy lost: optimization of wasted heat
• production in extreme environment: sources dedicated to TEG
• decentralized power generation: renewable energy sources
• microgeneration: all heat sources are acceptable
• thermoelectric solar: energy source : the sun.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 11
Waste heat
1 quad=2.93 1011kWh=1.055x1018J
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 12
Secteur automobile
Thermoelectric technology
for automotive Waste Heat Recovery
Prototypes :
- FIAT
- FORD
- GM
- BMW
- Amerigon
- Renoter (Renault truck Volvo …)
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 13
Thermoelectric technology for automotive Waste
Heat Recovery
Opportunity for Waste
Heat Recovery with
Thermoelectrics
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 14
Thermoelectric technology for automotive Waste
Heat Recovery
Sankey diagram for diesel vehicle
light duty trucks
3% efficiency
mean 0.9kW
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 15
Economic context European Union
Emission target for passengers cars
130g/km for 2012
drastically reduced to 95g/km for 2020
Emission target for light duty trucks
175g/km for 2014
135g/km for 2020.
Fine and penalties to be paid by car
manufacturers that exceed EU CO2 limits
20€ per exceeding gram starting from 2012
95€ per exceeding gram starting from 2020
New CO2 emission performance standards
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 16
Comparison Alternator - TEG
400-500Wel means 6-7g/km CO2 reduction (Fiat Research Center)
small-medium gasoline engine at motorway driving condition is
characterized by a thermal power, in its exhaust gases, of 10kW at 600°C,
4-5% system conversion efficiency, which can be feasible with ZT=1-1.2
is enough to guarantee 400-500 Wel.
Conversion efficiency from fuel chemical energy to mechanical energy 25-27%
alternator efficiency from mechanical to electrical energy 60%
conversion efficiency from fuel chemical energy to electrical energy 15-16%
Electricity produced by alternator
Electricity produced by TEG
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 17
Automotive Requirements for a TE Generator
•Backpressure limit in TEG
•Exchanger must not disturb too much exhaust gases: pressure
drops very low (tens of a few millibars).
•Temperature limit for TE materials (add bypass for exhaust gases)
•Durability test requirements
•Assembly requirements
•Control and sensor requirements
•Power conditioning (DC/DC converter)
•Recycling
•Price and Performance
Requirements
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 18
Alternator Replacement by a TEG
A TEG must be able to provide necessary power ( about 3kw 220A
14V) to the vehicle under extremely challenging conditions:
• Idle
• City drive cycle (Start-Stop)
• +50°C to -30°C ambient conditions
• Full accessory loads, including current spikes
• Reduce TOTAL fuel consumption, weight, and cost compared to
an alternator/battery system
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 19
Ford
Half-Heusler + Bi2Te3segmented TE elements
Anticipated power: ~500 Watts (peak)
TEG on a Ford Fusion with 3.0L V-6 Engine
the exhaust
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 20
Ford Packaging for Prototype TEG
TEG
FlexCoupling
Underfloor Catalyst
To Exhaust
To Exhaust
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 21
FORD
C. Maranville “ Thermoelectric opportunities for light-duty vehicles.” Ford Motor Company 2012
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 22
FORD : TEG performances for a 100km/h cruise
C. Maranville “ Thermoelectric opportunities for light-duty vehicles.” Ford Motor Company 2012
A bypass is necessary to protect the TEG
Anticipated power: ~500 Watts (peak) !!!
Temperature of gas
Welec
105km/h
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 23
General Motor
2011Meisner advanced thermoelectric material and generator technology for automotive waste heat at GM.pdf
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 24
GM project may 2011
This module could capture waste heat in car's exhaust and convert it to energy, improving fuel economy in a
Chevy Suburban by 3%.
Computer models show the device could generate 350 to 600 watts for city and highway driving, respectively.
General Motors Thermoelectric Generator
Vehicle Selection : Chevy Suburban
2011Meisner advanced thermoelectric material and generator technology for automotive waste heat at GM.pdf
Finalize design of prototype TEG
only Bi2Te3 modules by-pass valve set point temperature
for the heat exchanger is about 250°C.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 25
GM : Instrumented TEG and Results
Temperature of the heat exchanger is
250°C for a temperature of exhaust gas
around 400°C
2011Meisner advanced thermoelectric material and generator technology for automotive waste heat at GM.pdf
150°C
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 26
GM : Instrumented TEG and Results
Temperature variation along the Teg //
to the exhaust gas flow is significant
Front 250° Middle 178° Rear 148°
Temperature variation transverse to
the exhaust gas flow is low < 3°C
2011Meisner advanced thermoelectric material and generator technology for automotive waste heat at GM.pdf
Coolant
50°C
1,3 W avec
un HiZ20
209$ !!!!
150°C
11 W avec
un HiZ20
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 27
2011Meisner advanced thermoelectric material and generator technology for automotive waste heat at GM.pdf
GM : Instrumented TEG and Results
Open circuit voltage are consistent with a 50°C smaller ΔT than
measured between the heat exchanger and the coolant
Computer models show the device could
generate 350 to 600 watts
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 28
G. P. Meisner, “Skutterudite thermoelectric generator for automotive waste heat recovery,” in 3rd Thermoelectrics Applications Workshop 2012
GM : future work
Expected Output power 425 Watts !
Improved skutterudite TE materials
Refine TEG design :thermal and electrical interface, bonding …
Electrical power conditioning (avoid impedance mismatch)
First experiment 19W with few modules and small ΔT
extrapolated to 235 Watts in optimum conditions
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 29
BMW
BMW 2008
BMW 535i (US)
Bi2Te3TEG (2007)
High-temperature TEG
Pmax=300W (2009)
2012 Boris Mazar State of the Art Prototype Vehicle with a Thermoelectric Generator
Bi2Te3
Bi2Te3
PbTe
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 30
BMW
BMW 2008
BMW 535i (US)
Bi2Te3TEG (2007)
High-temperature TEG Pmax=300W (2009)
2011 Dr. Andreas Eder Efficient and Dynamic –The BMW Group Roadmap for the Application of Thermoelectric Generators
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 31
Possibles locations for TEG
Integration into the EGR (Exhaust Gas
Recirculation) for a diesel engine:
Advantages
Easier to integrate (existing exchanger)
Control for mass flow (EGR valve)
Cooling water already there
Disadvantages
Reduced recuperation potential (5 à 35%)
Integration in the exhaust system:
Advantages
•Highest recuperation potential
Disadvantages
•Exchangers : high integration effort
•Connection to cooling system
•Bypass : (flat possible but expensive)
A. Eder, BMW group, thermoelectrics applications 2011
Exhaust Gas Recirculation reduces
NOx emissions by reducing the
combustion temperature in Diesel
engines.
EGR works by recirculating a portion
of an engine's exhaust gas back to
the engine cylinders.
Gas must be cooled
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 32
BMW
The EGR-TEG unit consists of a TEG
section and a conventional cooler section.
conventional
cooler section.
TEG section
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 33
Renault Trucks, Volvo … Projet RENOTER
“Récupération d'ENergie à l'échappement d'un mOteur par ThERmoélectricité”
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 34
Renault Trucks, Volvo
Choice of Silicide's
- N-type : Mg2Si
- P-type : MnSi1.77
Advantages disadvantages
Non-toxic materials Moderate ZT
Light density (2-4) Mg2Si type P not
available
Abundant raw materials Current doping of Mg2Si
in project
Support high exhaust
temperature (> 600°C)
P and N have different
mechanical properties
Successful lab. production of the legs for
the project prototype
2012 Luc Aixala RENOTER project presentation
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 35
Renault Trucks Joint Company -Volvo Group
•original Design of TEG compatible with different TE materials
•aim 1kW (Truck) and 300W (car) possible this year (2011)
Results 350W 250W
Renoter2 10 000 cars equipped for 2018 100 000 for 2020
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 36
HeatReCar first light commercial vehicule equipped with a TEG
Vehicle
IVECO Daily, 2.3l Diesel engine
Design reference condition Vehicle @130kph
Exhaust gas temperature: 450°C
Gas flow : 70g/s (max torque), 140g/s (full load)
Target performance TEG electrical output 1kW
D. Magneto 3rd International Conference Thermal Management for EV/HEV Darmstadt 24-26 June 2013
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 37
HeatReCar first light commercial vehicule equipped with a TEG
D. Magneto 3rd International Conference Thermal Management for EV/HEV Darmstadt 24-26 June 2013
Cross Flow architecture.
Material considered
•TAGS
•Segmented Bi2Te3-PTe
•Skutterudites: developed and manufactured at
Module level
•Bi2Te3: used for the full scale prototype
manufacturing with specific Module design
16 x 16 mm
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 38
HeatReCar first light commercial vehicule equipped with a TEG
D. Magneto 3rd International Conference Thermal Management for EV/HEV Darmstadt 24-26 June 2013
Core size 500x100x100mm
Core weight 4kg
TEG architecture.
Air tank outlet
Air tank inlet .
By pass valve
Water
tank
Water
tank
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 39
HeatReCar first light commercial vehicule equipped with a TEG
D. Magneto 3rd International Conference Thermal Management for EV/HEV Darmstadt 24-26 June 2013
Hot gaz flow: 90g/s
ΔP hot gaz: 30mbar
T hot gaz: 450°C
Cold liquid flow: 1200l/h
ΔP liquid flow: 0.15 bar
T cold flow 60°C
U: 32.1V
I : 15A
P: 482W
TEG performances on the test bench
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 40
HeatReCar first light commercial vehicule equipped with a TEG
D. Magneto 3rd International Conference Thermal Management for EV/HEV Darmstadt 24-26 June 2013
TEG on board installation On board vehicle results summary
the WLTP test is expected to replace the
European NEDC procedure for testing of
light-duty vehicles
•Cycle NEDC, the TEG electric output is provided
mainly in the extraurban part of the Cycle.
•Cycle WLTP, the System reached a peak of about
220 W.
•In the last part of WLTC TEG power is sufficient
to provide the on-board electric need, thus
completely replacing the alternator
• 4% fuel economy improvement over the WLTP
cycle has been achieved
www.dieselnet.com/standards/cycles/wltp.php
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 41
GENTHERM ex AMERIGON ex BSST + BMW et Ford
Cylindrical TEG
TEGs were installed in a BMW X6 and a Ford Lincoln MKT with at least
450W of power output achieved in road tests for both vehicles.
D. Crane, “Thermoelectric generator performance for passenger vehicles” 2012
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 42
GENTHERM ex AMERIGON ex BSST + BMW et Ford
Bell, L.E. and Crane, D.T. and LaGrandeur, J. and van Heerden, D,
Thermoelectric-based power generation systems and methods, US Patent App. 12/843,804
cooling fluid
cold side
shunt
Hot side
shunt
ceramic
honeycomb Hot Exhaust
gas
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 43
AMERIGON BSST (BMW et Ford)
Tenneco’s booth at the 2013 Frankfurt IAA Motor Show
Hot side
Larger area
Best
exchange
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 44
AMERIGON BSST (BMW et Ford)
Tenneco’s booth at the 2013 Frankfurt IAA Motor Show
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 45
Aircraft Thermoelectric Applications
Aircraft engine waste heat harvesting has large potential payoffs
How can Thermoelectric Contribute?
Turboprop Turbine à gaz + hélice
Turboshaft Turbine à gaz + arbre de transmission
Turbofan Moteur à réaction
2009 James Huang,Boeing Research & Technology
Fuel Reduction
Preliminary analysis showed that 0.5% or more fuel reduction is achievable
Operating Cost Reduction
Average monthly fuel costs for U.S. commercial planes is $2.415B for the first
4 months of 2009 (Source: EIA)
A 0.5% fuel reduction : $12M monthly operating cost reduction
Advantages Disadvantages
•Provides electrical power from waste heat – no fuel
burn and no moving parts
• Operates over the entire aircraft flight envelope
• Operates independent of engines and does not
affect engine operations
•New technology and unproven
•Cost & efficiency; further development is needed
•Power output limited by available waste heat, space,
device efficiency.
Watt per kilo?
Acceptable 0.15 kW/kg
Tuyère adiabatique hélicoptère
Champier : 0.04kW/kg
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 46
Usage of Thermoelectric Generators on Ships
Ship transport generates a large amount of
waste heat
main engine (8-15 MW)
(heavy fuel oil)
auxiliary engines
incinerator
(waste oil : sludge representing 2% of oil
consumption of the main engine)
Workers at heavy cost .
Cold sink between 5°C and 28°C
available (seawater)
no problem with space and weight
Wasted heat used for
heating of heavy fuel oil
•Heating of accommodation areas
•freshwater generation
Work intermittently
Working time : 12h to 20h /day
Steam engine :
Needs a worker at
start and stop : heavy
cost
Thermoelectric
genrator
Kristiansen : incinerator 850kW, calculation : 38kW electric cost 2,7US$/W.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 47
Usage of Thermoelectric Generators on Ships
Significant potential:
powerful engines
Cold source available
The weight is not a constraint
costly maintenance
Use of the systems developed for the
automotive or aircraft without weight
constraints.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 48
Waste heat recovery : conclusion
Automotive
Alternator + TEG : imminent
Replacement of alternator : challenge
Airplanes
More research is necessary …
ships
Promising
Car 20€/kg Pizza 30€/kg!
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 49
Electricity production in extreme environment
critical applications: a power source extremely reliable over very long periods.
extreme climatic conditions:
• very hot
• very cold
• very wet
• very dry.
Maintenance as low as possible
• helicopter access
•several hour trip
Maintenance does not exist in the case of space expeditions.
operation in a vacuum
vibrations.
insensitive to radiation
The cost of watt is not essential
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 50
Space applications
First use of a thermoelectric generator (Pb -Te) : 1961
navigation satellite Transit (1961) of the U.S. Navy.
SNAP-3 (Space Nuclear Auxiliary Power)
Electrical power~2,7 watts
worked for more than fifteen years
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 51
Space applications
RTG Radioisotope Thermoelectric Generator
Radioisotope Thermoelectric Generators, or RTGs convert the heat generated by
the decay of plutonium-238 (plutonium dioxyde 238PuO2) fuel into electricity using
devices called thermocouples.
http://solarsystem.nasa.gov/rps/rtg.cfm
GPHS : General Purpose Heat Source module
238Pu fuel pellet
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 52
Space applications
T. Caillat et al 23rd rd Symposium on Space Nuclear Power and Propulsion STAIF 2006Jet Propulsion Laboratory/California Institute of Technology
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 53
Space applications
T. Caillat et al 23rd rd Symposium on Space Nuclear Power and Propulsion STAIF 2006 Jet Propulsion Laboratory/California Institute of Technology
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 54
Space applications
http://solarsystem.nasa.gov/rps/rtg.cfm
Cassini’ RTG before mounting
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 55
Space applications
http://solarsystem.nasa.gov/rps/rtg.cfm
Curiosity’s Radioisotope Thermoelectric Generator
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 56
Space applications
Radioisotope Thermoelectric Generator RTG
Electric Power at beginning
of mission per RTG
Number of RTG
Mission destination year design
lifetime lifetime
Space Nuclear Auxiliary Power SNAP-3 PbTe
2,7 Watts 1 Transit Navigation satellite 1961 15 years
SNAP-19B RTG PbTe-Tags 28.2 Watts 2 Nimbus III meteorological satellite 1969
SNAP-19 RTG PbTe-Tags
42.6 Watts 2 Viking 1 Mars landers 1975 90 days 6 years
2 Viking 2 Mars landers 1975 90 days 4 years
40.3 Watts 4 Pioneer 10 Jupiter, asteroid belt 1972 5 years 30 years
4 Pioneer 11 Jupiter Saturn 1973 5 years 22 years
SNAP-27 RTG PbSnTe
70 Watts Apollo 12, 14,
15, 16 , 17 Lunar Surface
1969-72
2 years 5-8 years
Multi-Hundred Watt (MHW) RTG SiGe
158 Watts 3 Voyager 1 & 2 edge of solar system 1977 still operating over 30 years
General Purpose Heat Source (GPHS) RTG
SiGe 292 Watts
2 Galileo Jupiter 1989 14 years
3 Cassini Saturn 1997 still operating after 14 years
1 Ulysses Jupiter 1990 21 years
1 New Horizons Pluto, Kuiper Belt 2006 still operating after 6 years
Multi-Mission Radioisotope Thermoelectric Generator
MMRTG PbTe-Tags 110 Watts 1 Curiosity
Mars Surface 5 Aug 2012
2011 Expected 14
years
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 57
Space applications
Radioisotope Thermoelectric Generator
• compact
• Continuous power sources
• Used in deep space for several decades
• reliable
• Use nuclear fuel relatively easy to manipulate Curium-244
and Plutonium-238
• Materials used: PbSnTe, PbTe, TAGS, SiGe
Conclusion
Current research:
Improved performance of materials: reduced thermal conductivity of the
network
Zintl, skutterudites, couples segmented.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 58
Remote Power Solutions
REJECTED
HEAT
500 Watts 24 Volts
Natural Gas 48m3/day
Propane 76L/day or 38kg/day
COOLING
FINS
EXHAUST
OUT
LOAD
FUEL IN
T
E
G
F
L
A
M
E
Oil or gas pipelines
Well sites
Offshore platforms
Telecommunications sites
Communications systems
….
Critical application requiring highly reliable power
Low maintenance required
Long life
Extreme climatic conditions (hot, cold, wet, dry)
Remote locations
Propane 38kg/day
Heating Value 50MJ/kg Energy per day= 1900MJ=527kW.h
500 W electric Energy per day= 12 kW.h Efficiency : 2.2 %
April 1, 2014
Engine generator: efficiency 16 % and price …!
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 59
Remote Power Solutions
500 Watts 24 Volts
Natural Gas 48m3/day
Propane 76L/day or 38kg/day
Pipeline: 550 watts
communications system
Andes Mountains, Chile
Off shore: 200 watts
communications and safety
equipement, multiple systems
- Thailand
Critical application requiring highly reliable power
Low maintenance required
Long life
Extreme climatic conditions (hot, cold, wet, dry)
Remote location Telecommunications:50 watts
helicopter access only,
emergency communications system
- Rocky Mountains, Canada
Pipeline:
5000 watts for SCADA
communications and cathodic
protection of gas pipeline - India
Niche market for TEG
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 60
Remote Power Solutions
electrical output of a Model 5060 TEG
Maximum Power for an
electrical load between
0.4 and 0.9 ohm
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 61
Biomass stoves
Combined Heat and Power (CHP)
Decentralized electricity generation
Developing countries
Biomass primary energy source
(cooking, heating, domestic hot water)
Developed countries
Connection to the network is not always
economically attractive
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 62
• Biomass energy is used for basic needs : cooking and heating
• They needs electricity for light, cellular phone and radio
• Biomass is burnt through open fire stoves – low efficiency forest destruction and global warming contribution
– high emissions of air pollutants health damaging
• “Planète Bois” is developing an improved multifunction biomass fired stove. combustion chamber is designed to achieve almost complete combustion of wood
A fan is necessary to increase the air/fuel ratio
Smoke can be extracted with a horizontal pipe avoiding the building of a vertical chimney
• Connecting these households to the power grid cost of building new landlines from US$300 to more than US$4000
cost of distribution of electricity from US$0.07 to US$5.1 per kWh
• thermoelectric generators are cost-effective options for these specific off-grid households.
1.2 billion people
without electricity
in developing countries
Thermoelectric power generator for Biomass
Stoves
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 63
Review of thermoelectric generators
for cooking stoves
Author Heat sink (cold side) Type of module * Power per
module
Nuwayhid 2003 Natural air cooling Peltier 1W
Nuwayhid 2005 Natural air cooling Seebeck 4.2W
Nuwayhid 2005 Heat pipes cooling Seebeck 3.4W
Lertsatitthanakorn 2007 Natural air cooling Seebeck 2.4 W
Mastbergen 2007 Forced air cooling (1W) Seebeck + 4W regulated
“BioLite” 2009 Forced air cooling (1W) Seebeck + 2 W
Champier “TEGBioS “ 2009 Water cooling Seebeck 5W
Champier “TEGBioS II“ 2010
Water cooling
Seebeck
9.5W
7.5 W regulated
Rinalde 2010 Forced water cooling (?W) Seebeck 10 W
O'Shaughnessy 2014 Forced air cooling (?W) Seebeck 5.9W regulated
Bismuth Tellurid (Bi2Te3)
* Peltier :
The temperature difference is limited due to the maximum temperature supported by the solder
The geometry is optimized for cooling and not for power generation.
* Seebeck
The hot side work at a temperature as high as 300°C continuously.
The geometry is optimized for power generation
Heat source : hot gas
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 64
Open fire vs cooking stove
Open fire
very low efficiency (5-10%)
emission of harmful black fumes
increase pressure on natural forests
85 % global efficiency
maxi CO level of 200 g/GJ
reduce the fuelwood consumption by two
uses cut branches (length 40 cm, diameter between 4 and 8 cm)
Simultaneous cooking of 2 dishes
Important production of domestic hot water:
showering, cleaning, laundry, dishes.
Cumulus effect: available hot water between 2 sessions
available hot water for morning ablutions.
low temperature radiant heating
mechanical extraction (electric fan) no chimney
less expensive and easier installation
Planète bois
cooking stove
clean household
woodstove
Rocket stove
T-LUD (Top Lid UpDraft)
efficiency (40%) efficiency (35%)
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 65
“Planète Bois” Cooking stove and TEG
Biomass stove
A) pyrolyzing chamber
B) hot incoming combustion gas
D) cooking plate
E) water tank 18 liters
F) fan
Electric fan
Pyrolysis
chamber
Mixing zone
(shaker)
Flaming
chamber
Water
tank
TEG
Smoke
box
Forced draft
Primary air
entrance
Secondary air
entrance
Power 6 kW
Domestic hot water production
30L each 30 min
Wood consumption 1,5kg per hour
Outside Dimensions (L,w,h) 110x60x85 cm
Life expectancy 15 years
Average efficiency More than 80% 10 kW wood consumption
2.4 kW are used in heating the water 4.5 kW are used in heating the room and inertia
0.9 kW is used for cooking
The idea is to put the TEG in a cogeneration system which
simultaneously provides electric power and heat for the hot water
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 66
“Planète Bois” Cook stoves
Primary air
entrance Secondary air
entrance
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 67
TEG for stoves
T2
T1
T3
T8
T4 T5
T9 T7 T6
Heat flow
TE
module
Aluminium heat exchanger
Water tank
Thgi1
Thgo
Tw2
Thgi2
TE modules
Heat exchanger
TE modules
Tank Wall
Thermocouple Aluminum
Water
Water tank
67
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 68
Maximum Power Point Tracking Boost converter.
Converter
+ -
Battery
DC
DC TE modules
Heat exchanger
Tank
Hot gas
Water
Vin
Iin
MPPT
Microcontroller
MC9SO8
Vout
Iout
Eoc
Ri
TE
Generator DC/DC convertor Battery + Load
Virtual load
Pulse Width Modulation
Ri
Eoc
T Cold
THot
R v
TE module
Virtual Load
V in
I in
0
1
2
3
4
5
6
7
8
0 1 2 3 4 5 6 7
Po
wer
(
W)
Voltage Vin (V)
Thot=250 ° C Thot=200 ° C Thot=150 ° C Thot=100 ° C
Tcold =50 °C
E oc /2 E oc
Maximum power point Vin est contrôlé par le rapport cyclique dc
Fraction de période pendant laquelle l’interrupteur est ouvert
Vin=Vout (1-dc)=Vbatterie (1-dc)
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 69
Maximum Power Point Tracking Boost converter.
Converter
+ -
Battery
DC
DC TE modules
Heat exchanger
Tank
Hot gas
Water
Choix correct de l’incrément de Dc
0,988
0,990
0,992
0,994
0,996
0,998
1,000
0 5 10 15 20
effic
ienc
y
Input Power Pe
Measured efficiency of the MPPT algorithm
Efficiency : Pin/Pmax
Measure Iin
Measure Vin
Calculate Pin
Change duty cycle
Compare with
previous Pin
Vin and Iin change
Measure Iin
Measure Vin
Calculate Pin
Change duty cycle
Compare with
previous Pin
Vin and Iin change
Algorithm Perturb and Observe
On est sur d’être au moins à 99% de la
puissance max
Avec les pertes du convertisseur :90%
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 70
“Planète Bois” Cooking stove and TEG
Temperatures fluctuate a lot
A) pyrolyzing chamber
B) hot incoming combustion gas
D) cooking plate
E) water tank 18 liters
F) fan
Power 6 kW
Domestic hot water production
30L each 30 min
Wood consumption 1,5kg per hour
Outside Dimensions (L,w,h) 110x60x85 cm
Life expectancy 15 years
Average efficiency More than 80%
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 71
“Planète Bois” Cooking stove and TEG
Output Electrical Power : 23.7 W.h
Fan consumption : 15.3 W.h
A) pyrolyzing chamber
B) hot incoming combustion gas
D) cooking plate
E) water tank 18 liters
F) fan
Power 6 kW
Domestic hot water production
30L each 30 min
Wood consumption 1,5kg per hour
Outside Dimensions (L,w,h) 110x60x85 cm
Life expectancy 15 years
Average efficiency More than 80%
Heat flow
B
Aluminium heat exchanger
Water tank
Thgi1
Tgo
Thgi2
B
A
A
D
C
C
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 72
TEG results. Cycle one cooking
1h30min
Day 1
2 cookings
Electrical energy
produced
23.7Wh 47,4Wh
Average electric Power 15.8 W
Fan consumption 15.3Wh 30,6Wh
Extra Use
Use’s exemple*
one phone charge
1 hours of light
1 phone charge almost
4 hours of light
Major Advantage - Wood consumption divided by two
- Healthy (less black fumes)
- More comfort for women
- low CO
* Phone battery of 3.7V, 1050mAh and light consummation of 4W
TE generators are cost-effective solutions for off-grid households with low income.
Cost one sample Big quantity
Aluminium 60€ 30€
electronic part 31€ 15€
TE modules 75€ x6 27€ x 6
TE generator 541€ 207€
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 73
Advantages of TEG’s
The advantages of thermoelectric generator are :
It does not need extra energy from the stove.
• It will use the heat flux between the gas and the water tank
• It will only convert a small part into electrical energy.
It is incorporated into the cook stove:
• it requires no electrical link with the outside world, unlike solar panels, or
manipulation of battery.
The maintenance is very light:
• nothing is moving,
• everything is inside the house,
• only the battery needs to be changed at the end of its life.
The generator produces when the stove is on, day and night in good or in rainy
weather (monsoon period) unlike solar panel.
The battery does need to be oversized as each use of the stove recharges the battery
unlike solar system where you need to store energy for the cloudy days.
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 74
Today Tomorrow
with TEG
Somewhere in a village
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 75
thermoelectric generators for cooking stoves
Biolite
USB
2W 5V
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 76
Biolite
HomeStove and CampStove
Ghana
Lake Brassua (Maine)
129$
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 77
Combined Heat and Power (CHP) with TEG
Automatic Pellet Furnaces, especially Small Scale Combustion Units
Market
East of Europe and North-America
because of unreliable Electric Power Grids
Stove with TEG 400
Max: 8 kWth, 100 Wel
Air cooling
Boiler with TEG 400
Max: 12 kWth, 300 Wel
Water cooling
Outlook BIOENERGY 2020+
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 78
Combined Heat and Power (CHP) with TEG
Module 8cmx8cm
TEG
Biomass CHP
(pellets)
BIOENERGY 2020+
Location Wieselburg 100km from Vienna !
Decentralized production for decentralized utilization
Production of electricity during periods of high heat demand
and low offer of other renewable energies:
• During winter
• Whilst twilight or night
• During times without sun and wind
Fuel heat output: 10 kW
Nominal electric power: 200 - 400 W
• 8 plates, each with 2 modules
• Positioned around flame
• Heated from inside, cooled from outside
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 79
Autonomous Gas Heaters
2011 M. Codecasa Design and development of a teg cogenerator device integrated in self standing gas heaters
Heater 8kW
Thot 305°C
Tcold 125°C
Power 7.8W
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 80
Energy Harvesting for Low Power Electronics
http://www.micropelt.com
Modern wireless sensor modules require only ~100 W -10mW
Micropelt thermogenerator offers a high density of up to 100
thermoelectric leg pairs per mm2
200 C max.
Electrical:
•Thermo-Voltage: uTEG = 0.14 V/K
•Electrical Resistance: RTEG ~ 350
•Thermal Resistance: Rth = 12,5 K/W
Take a small portion of a lost flow of ‘primary’ energy, and convert it into a small flow of USEFUL
electrical energy.
Every technical process produces waste heat
4.2mmx3.3mmx1mm
5mW is enough for most microsensor
Micropelt MPG-D751
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 81
Energy Harvesting for Low Power Electronics
http://www.micropelt.com
Emerson WiHART
Differential Pressure Transmitter
ABB Technology Demonstrator
•Self-powered WirelessHART temperature
transmitter
•Fully integrated thermogenerators
•Powered by Micropelt TEG & boost technology
Applications :
Wireless sensors
Data loggers
Direct valve control
Wireless pneumatic control
Use heat from 15 mm pipe
Output power 3.5mw
at 60°C and ambiant 25°C
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 82
Energy Harvesting for Low Power Electronics
www.nextreme.com
thermobility™ wpg-1
wireless power generator
D. Samson, “Aircraft-specific thermoelectric
generator module, 2010
Phase changing material
H2O
40 minutes of electrical
power after take-off !!
Temperature outside -20°
Laird technology
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 83
Solar Thermal to Thermoelectricity
Solar Thermoelectricity STEG
5 21001 10 W/m
0.001
q Tk
A L
-1 -11 W.m Kk
100T K
0.001L m
Heat flux through a thermoelectric leg
Solar insulation: ~ 1 000 W/m2
Need to concentrate heat by ~100 times
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 84
Solar Thermoelectrics
1000°C
SiGe
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 85
Solar Thermoelectrics STEG
Kraemer High-performance flat-panel solar thermoelectric generators with high thermal concentration Nat mat 2011
The developed solar thermoelectric generators (STEGs) achieved a peak
efficiency of 4.6% under AM1.5G (1 kW m−2) conditions.
Photovoltaic: efficiency 20 %
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 86
Design of thermoelectric generator
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 87
An example of TEG
Hot exchanger
Cold exchanger
87
Thermoelectric modules
Bi2Te3 Thermonamic
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 88
Thermoelectric Generator
TEG
Hot fin exchanger Cold exchanger
88
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 89
Numerical model
Diagram of a half exchanger
• Standard equations of thermoelectricity, heat
transfers
Steady state
89
Convective exchange correlations
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 90
Numerical model
-Electrical equivalent model calculated for each k secondary cutting.
-All parameters are temperature
dependent.
- Newton-Raphson method for convergence.
90
Daniel CHAMPIER applications de la thermoélectricité GDR Thermoélectricité 2014 91
-0.1 -0.05 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35
300
320
340
360
380
400
420
440
460
480
500
y (en mètres)
T (
en
K)
T hot gas
Thot wall
Thot couple
Tcold couple
Tcold wall
Tcold liquid
Results and Experiment
Puissance
mesurée (W)
Puissance
estimée (W)
37 W 38,8 W
T TEcouple T system