thermogravimeteric analyzer measures weight loss upon heating, cooling, or when held at a constant...
TRANSCRIPT
RET 2008 – Week 2
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Making Slime
Making Nylon
TGA
Thermogravimeteric Analyzer
• Measures weight loss upon heating, cooling, or when held at a constant temperature.
• The machine is basically a furnace with a microbalancer that is used to characterize materials with regard to their composition.
Procedure1. Cut out piece of
polymer with hole punch and put in aluminum crucible.
2. Place in platinum microbalancer.
Procedure (Continued)3. Set the computer for rate of heating (10⁰/min).4. Set computer for type of gas (air for nylon 6,6 and nitrogen for PETE and PP)
Thermal events and processes that can be determined by TGA
• Absorption/desorption of gases/moisture.
• Thermal stability.• Identification of
decomposition products, solvents, solvates.
• Pseudopolymorphism.
• VOCABULARY• Solvate- an aggregate
that consists of a solute ion or molecule with one or more solvent molecules.
• Pseudopolymorphism-different crystal types are the result of hydration or solvation.
TGA degradation for two differentHDPE bottles due to filler material.
Decomposition kinetics- changes in maximum temperature of decomposition due to changes in heating rate.
DSC
DSC - Differential Scanning Calorimeter
measures temperatures and heat flows associated with thermal transitions in a material
Glass Transition Temperature - Tg
the temperature at which a solid, such as glass or a polymer,becomes brittle (crystalline) on cooling, or soft (amorphous) on heating
Punching
Filling Pan
Crimping
Cooling
Heating
Cooling
Heating
NMR
Demo with Tony
Glass Blowing with Ron Kemp
AcknowledgmentsAnthony CondoIvan Keresztes
Ron KempNevjinder Singhota
Kevin DilleyJane Earle
Cornell Center for Materials ResearchNational Science Foundation