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Page 1: Third Group of 1993 ACS PRF Grants Approved

ACSNEWSJ

Third Group of 1993 ACS PRF Grants Approved

A cting on recommendations from / % the May meeting of the Petro-

JL J L leum Research Fund Advisory Board, the American Chemical Society Board of Directors approved 139 new or continuing ACS-Petroleum Research Fund grants-in-aid. May commitments total $4,595,099. The recommended grants were selected from 457 proposals and are the last projects to be funded in 1993. ACS-PRF grants are funded by in­come from a trust established in 1944 by seven major oil companies. No ACS member dues income is used for PRF grants or administrative expenses.

The maximum values for ACS-PRF grants in 1994 will not change from 1993. Continuing low interest rates have re­duced income available for new PRF

ACS-PRF Grants for Fundamental Research in the Petroleum Field (Type AC)

Nigel G. Adams, U of Georgia. Structural Forms of Organic Ion Products of Collisional Association Reactions. $50,000

Norman L. Allinger, U of Georgia. Ab Initio Calculation of Heats of Formation. $50,000

Robert J. Angelici, Iowa State U. Phosphorus Analogs of Cyanide and Arylisocyanide Ligands in Transition-Metal Complexes. $50,000

C. Géraldine Bazuin, Université Laval. New Liquid-Crystalline Polymeric Materials through Noncovalent "Grafting." $50,000

Thomas L. Beck, U of Cincinnati. Theory of Liquid Chromatography. $50,000

Han Benjamin, U of California, Santa Cruz. Molecular Dynamics Study of Solvent Effects in Chemical Reactions at the Solid-Liquid In­terface. $50,000

Sam Boggs Jr., U of Oregon. Albitization of Miocene Deep-Sea Sandstones from the Ja­pan Sea Backarc Basin. $19,930

James M. Boncella, U of Florida. Synthesis and Reactivity Studies of Dimeric Group-8-10 Metal Amide Complexes. $50,000

Frederick G. Bordwell, Northwestern U. Structural Effects on Bond Dissociation En­ergies. $50,000

William H. Breckenridge, U of Utah. Spectro­scopic Studies of the Electronic Interactions of Ground- and Excited-State Atoms with Small Molecules. $50,000

grant commitments. New PRF grants declined from $14.4 million in 1992 to $12.9 million in 1993. A further decrease in commitments in 1994 is probable. The reduction in funding has significantly decreased the number of grant commit­ments for type AC grants, from 32% in 1992 to 23% in 1993, and for type Β grants, from 49% to 39%.

The "37th Annual Report on "Re­search under Sponsorship of the Petro­leum Research Fund" is available. To receive a complimentary copy or infor­mation and application forms for ACS-PRF grants to commence in 1994, write to Petroleum Research Fund, American Chemical Society, 1155—16th St., N.W., Washington, D.C. 20036, or call (202) 872-4481.

Joan F. Brennecke, U of Notre Dame. Solvent Effect on Reactivity of Ions and Radicals in Supercritical Water Solutions. $50,000

Carlton E. Brett, U of Rochester. Dynamic Stratigraphy, Physical Sedimentology, and Paleoecology of Mid-Paleozoic Black Shales of the Northern Appalachian Basin. $50,000

Sandra J. Carlson, U of California, Davis. Re­evaluating the Eocene-Oligocene Tempera­ture Decline Using Stable Isotope Profiles from New Zealand Articulate Brachiopods. $50,000

lu-Yam Chan, Brandeis U. Dynamics of Quan­tum Tunneling Reactions under Pressure. $50,000

Russell J. Composto, U of Pennsylvania. Measurement of the Volume Fraction Pro­files of Adsorbed Polymers. $50,000

Valerian T. D'Souza, U of Missouri, St. Louis. Novel Cyclodextrins: Synthesis and Proper­ties. $50,000

Nancy M. Doherty, U of California, Irvine. Ear­ly Transition-Metal Nitrido and Phosphido Compounds. $50,000

Donald B. DuPre, U of Louisville. Macromo-lecular Order in Concentrated Solutions of Semiflexible Polymers. $50,000

Phillip M. Duxbury, Michigan State U. Com­pressive and Shear Failure of Porous Mate­rials. $50,000

Jen-Ho Fang, Hui-Chuan Chen, U of Ala­bama. Inversion of Crosshole Seismic To­mography Data via Neurocomputing. $39,996

Peter M. Felker, U of California, Los Angeles. Rotational and Ground-State Vibrational Spectroscopy of Cold Metal Clusters. $50,000

M. G. Finn, U of Virginia. New Routes to Neo-carzinostatin Model Compounds: Condensa­tion Synthesis of Aliènes. $50,000

Malcolm D. E. Forbes, U of North Carolina, Chapel Hill. Chemical and Magnetic Proper­ties of Radical Pairs and Biradicals at Inter­faces. $50,000

Stephen C. Foster, Florida State U. Infrared Spectroscopy of Reactive Species in a Su­personic Jet. $50,000

Craig R. Glenn, U of Hawaii, Manoa. Environ­mental Factors Controlling Cyclic Carbonate and Sapropel Formation in the Pliocene-Pleistocene Black Sea. $28,259

Lionel Goodman, Rutgers, State U of New Jersey. Two-Photon Rydberg-State Jet Spec­troscopy Involving Torsional Modes. $50,000

Vicki H. Grassian, U of Iowa. Surface Photo­chemistry of Molecules Adsorbed on Metal Particles. $50,000

Mark M. Green, Polytechnic U. Cholesteric Liquid-Crystal State of Polyisocyanates and Other Dynamically Racemic Materials. $50,000

Masanori Hara, Rutgers, State U of New Jer­sey. Deformation and Fracture Behavior of Molecular Composites via Ionic Interactions. $50,000

A. Rashid Hasan, U of North Dakota. Mecha­nistic Model of Phase Redistribution in Well-bores. $50,000

Irving P. Herman, Columbia U. Spatially Re­solved Optical Studies of Chemical Process­es. $50,000

Tito E. Huber, Polytechnic U. Optical Proper­ties of Molecular Hydrogen in Porous Materi­als. $50,000

Karl M. Kadish, U of Houston. Electrosynthe-sis and Electrochemistry of Fullerenes and Fullerene Films. $50,000

Douglas A. Keszler, Oregon State U. Crystal Chemistry and Optical Studies of New Solid-State Borates. $50,000

Donald L. Koch, Cornell U. Kinetic Theory for an Adsorbed Gas. $50,000

Joseph W. Kolis, Clemson U. Synthesis of New Solid-State Compounds in Supercritical Amines. $50,000

Samuel P. Kounaves, Tufts U. Electrodeposi-tion of Catalytic Alloys and Mixed Metals Us­ing Heteropolymetallic Complexes. $50,000

David E. Krantz, U of Delaware. Stable Iso­tope Stratigraphy and Paleoceanography of the Bering Strait Region during the Last In­terglacial. $50,000

Clifford P. Kubiak, Purdue U. Catalytic Deox-ygenation of Phenolic and Alcoholic Func­tional Groups. $50,000

Juhn G. Liou, W. Gary Ernst, Stanford U. Ex­perimental Investigation of Kinetics and Rhe-ology during Diagenesis. $48,564

James M. Lisy, U of Illinois, Urbana-Cham-paign. Effect of Hydrogen Bonding on Vibra­tional Transition Moments. $50,000

Charles M. Lukehart, Vanderbilt U. New Syn­thetic Routes to Nanocomposite Materials. $50,000

Thomas E. Mallouk, Pennsylvania State U. Chemical Sensors Based on Shape-Selec­tive Intercalation Reactions. $50,000

Cynthia K. McClure, U of Delaware. Pentaco-valent Phosphorus in Organic Chemistry: A New Route to Substituted Phosphonates. $50,000

AUGUST 30,1993 C&EN 41

Page 2: Third Group of 1993 ACS PRF Grants Approved

ACS NEWS

George A. McMechan, U of Texas, Dallas. Full-Wavefield Inversion of Seismic Data for the Distribution of Visco-Elastic Parameters in Hydrocarbon Reservoirs. $50,000

J. Casey Moore, U of California, Santa Cruz. Faulting, Dolomitization, and Fluid Migration in the Monterey Formation in the Santa Maria Basin, California. $50,000

Robert H. Morris, U of Toronto. Transition-Metal Complexes with Thiolate and Dihydro-gen Coligands. $50,000

Michael D. Morse, U of Utah. Photofragmen­tation Spectroscopy of Jet-Cooled Metal Cat­ions. $50,000

Ka M. Ng, U of Massachusetts. Separation of a Multicomponent Mixture Based on Frac­tional Crystallization. $50,000

Kenneth M. Nicholas, U of Oklahoma. Chem­istry and Synthetic Utility of Cobalt-Com-plexed Propargyl Radicals. $50,000

Donald R. Peacor, Ben A. van der Pluijm, U of Michigan. Textural Analysis of Diagenetic to Low-Grade Pelites. $50,000

William H. Pearson, U of Michigan. 2-Azaallyl Anions in Organic Synthesis. $50,000

Ralph M. Pollack, U of Maryland, Baltimore County. Effects of Phenyl and Vinyl Groups on Ketone Acidity. $50,000

Gary H. Posner, Johns Hopkins U. Simplified, Improved, and Cost-Effective Cycloadditions Using 2-Pyrones: Multigram Asymmetric Synthesis of Functionalized Cyclohexene Building Blocks. $50,000

Howard Reiss, U of California, Los Angeles. Evaluation of Configurational Entropy. $50,000

Samuel A. Safran, Weizmann Institute of Sci­ence. Surface-Induced Instabilities and Phase Transformations. $50,000

John L. Schmitt, Gary L. Bertrand, U of Mis­souri, Rolla. Binary Homogeneous Nucle-ation of Octane Isomers. $46,000

Gerard T. Schuster, U of Utah. Porosity and Lithology Reconstruction from Crosshole Seismic Data Using a Traveltime and Elastic Wavefield Inversion Method. $50,000

Alan W. Schwabacher, Iowa State U. Self-Or­ganizing Receptors That Orient Substrates. $50,000

Robert J. Silbey, Massachusetts Institute of Technology. Theoretical Studies of Single-Molecule Spectroscopy, Spectral Diffusion, Photon Echoes, and Hole Burning. $50,000

Rex T. Skodje, U of Colorado. Influence of Ro­tational Dynamics in Heavy-Light-Heavy Chemical Reactions. $50,000

Wu-Pei Su, U of Houston. Photoexcitations in Conjugated Polymers. $50,000

Timothy M. Swager, U of Pennsylvania. Syn­thetic Approaches to Graphite Ribbons. $50,000

Eric J. Toonë, Duke U. Pyruvate Aldolases for Stereocontrolled Carbon-Carbon Bond For­mation. $50,000

Wilfred T. Tysoe, U of Wisconsin, Milwaukee. Palladium-Catalyzed Acetylene Cyclotrimer-ization: A Bridge between Ultrahigh Vacuum and Catalysis? $40,000

Arvind Varma, William C. Strieder, U of Notre Dame. Chemical Reaction Engineer­ing Considerations in the Synthesis of Silicon Nitride: Experiments and Theory. $50,000

Lynn M. Walter, U of Michigan. Chemical Mass Transfer between Bedded Evaporites and Sedimentary Basin Brines: Implications for Fluid Migration and Origin of CaCI2

Brines. $50,000 Hyuk Yu, George D. Zografi, U of Wisconsin,

Madison. Two-Dimensional Intrinsic Viscosi­ty. $50,000

Xiangdong Zhu, U of California, Davis. To­ward a Comprehensive Investigation of Quantum Tunneling of Atomic Hydrogen on Metals. $50,000

Hans-Conrad zur Loye, Massachusetts Insti­tute of Technology. Synthesis of Novel Ter­nary Nitrides from Solid-State Precursors. $50,000

ACS-PRF Grants for Fundamental Research in the Petroleum Field (TypeB)

Mark E. Bussell, Western Washington U. Sur­face Science Investigation of Alumina-Sup­ported Hydrodesulfurization Catalysts. $25,000

Ronald Caple, U of Minnesota, Duluth. Exo-glucals as Precursors of 1,1-Dialkyl Gluco-sides. $25,000

Ronald L. Christensen, Bowdoin C. Optical Studies of Linear Polyenes. $25,000

JoAnn P. DeLuca, Illinois State U. Second-Period Ylide Intermediates in Reactions of Singlet Carbenes. $25,000

Michael P. Eastman, Northern Arizona U. Cy-clodextrin Host-Guest Chemistry Including the Tetracyanoquinodimethane Anion Radi­cal. $25,000

Paul A. Flowers, Pembroke State U. Elec-troreduction of Carbon Dioxide in Molten Alkylammonium Salts. $24,500

Jerome E. Haky, Florida Atlantic U. Surface Modification of Alumina by Adsorption with Phosphonic Acids. $25,000

Jerry P. Jasinski, Keene State C. Structural, Photophysical, and Theoretical Studies of Laser Dye Clusters. $25,000

Markes E. Johnson, Williams C. Cretaceous Rocky Shores of Baja California: Coastal Oceanography and Sea-Level Changes. $25,000

Michael Lattman, Southern Methodist U. Fun­damental Studies on "Hypervalent" Main-Group Elements Constrained by Macrocy­cles. $25,000

Albert R. Matlin, Oberlin C. Photochemical Generation and Cycloadditions of Oxyallyl Systems. $25,000

Jerry R. Mohrig, Carleton C. Stereochemical Determinants in Proton Transfer and Elimi­nation Reactions. $25,000

Tetsuo Otsuki, Occidental C. Synthesis and Property of Furocoumarin-Oligonucleotide Complexes as a Sequence-Specific Modifier of DNA via Triple-Helix Formation. $25,000

Michael J. Retelle, Bates C. Environmental Reconstruction from High Arctic Lacustrine and Marine Sediments, Sophia Lake, East­ern Cornwallis Island, Northwest Territories, Canada. $25,000

Rosette M. Roat, Washington C. Oxidation-Reduction Behavior of Platinum(IV) Com­pounds in Reactions with Nucleobases. $24,700

Christopher J. Schmidt, Western Michigan U. Geometry, Fault Displacement, and Internal Strain in a Thrust-Fold Salient, Southwestern Montana. $21,150

Merlyn D. Schuh, Davidson C. Phosphores­cence Probe of Dynamics of Heme Proteins. $25,000

Paul Siders, U of Minnesota, Duluth. Kinetic Model of Modulated Microstructure in Cal-cian Dolomite. $25,000

Lucjan Strekowski, Georgia State U. Novel Chemistries of A/-Fluoropyridinium Salts. $25,000

Jan Tobochnik, Kalamazoo C. Lattice Models for Hydrogen Bonding in Lipid Bilayers. $25,000

Jeffrey R. Walker, Vassar C. Modeling of Dis­order in Chlorite Using Powder X-Ray Dif­fraction Data. $25,000

ACS-PRF Grants for Fundamental Research in the Petroleum Field (TypeG)

John W. Benbow, Lehigh U. Radicals in Or­ganic Synthesis: An Addition-Fragmentation Approach to Butenolide Installation. $20,000

Paul T. Buonora, Lamar U. Studies of the Enantioselective Allylation of Carbonyl Com­pounds by Diorganozinc-Auxiliary Complex­es. $20,000

Long-Qing Chen, Pennsylvania State U. Atom­istic Computer Simulation of Structure and Phase Transformations of Strongly Segre­gated Oxide Surfaces. $20,000

Judith S. Chester, St. Louis U. Accommoda­tion Mechanisms of Crustal Block Rotation and Significance to Transrotational Basin De­velopment in Strike-Slip Regimes. $20,000

Dennis P. Clougherty, U of Vermont. Quan­tum Sticking at Finite Temperature. $20,000

Charles W. S. Conover, Colby C. Rydberg Molecules in External Fields. $20,000

Thomas R. Cundari, Memphis State U. Com­putational Studies of Transition-Metal-Medi­ated Methane Activation. $20,000

Elbio Dagotto, Florida State U. Superconduc­tivity in Doped Fullerenes. $20,000

Bernadette T. Donovan, U of North Carolina, Charlotte. Electrochemical Studies of Steri-cally Crowded Organorhodium Complexes. $20,000

David G. Evans, North Carolina State U. Bifur­cating Solutions to Coupled Groundwater Flow Near Salt Domes. $20,000

Kent S. Gates, U of Missouri, Columbia. Pro-tein-DNA Interactions: A Study of Nonspecif­ic DNA Binding by Type-lls Restriction En­zymes. $20,000

42 AUGUST 30,1993 C&EN

Page 3: Third Group of 1993 ACS PRF Grants Approved

John M. Holbrook, Southeast Missouri State U. Evaluative Analysis of Genetic Interrela­tionships between Sequence-Boundary Mor­phology and Internal Architecture of Overly­ing Fluvially Dominated Strata. $20,000

Sean M. Kerwin, U of Texas, Austin, C of Pharmacy. Aza-Bergman Cyclization Route to 2,5-Didehydropyridines. $20,000

Hyung J. Kim, Carnegie Mellon U. Theoretical Studies of Rotational Dynamics and Dielec­tric Friction: Role of Solute Electronic Struc­ture and Solvation Dynamics. $20,000

Yuzhuo Li, Clarkson U. Photoinduced Redox Reactions on Semiconductor Particles: A New Synthetic Method for the Reduction of Nitro and Azido Compounds. $20,000

Charles R. Marshall, U of California, Los An­geles. Confidence Intervals on Stratigraphie Ranges for Taxa with Nonrandom Distribu­tions of Fossil Horizons. $20,000

Cary J. Miller, U of Maryland. Electronic Prop­erties of Individual Functional Groups within Thiol Monolayers at Au Electrodes. $20,000

Susan M. Miller, U of California, San Fran­cisco. Mechanistic Investigation of the Alter­nating-Sites Hypothesis for Catalysis in the Enzyme Mercuric Ion Reductase. $20,000

David Ritter, Southeast Missouri State U. Re­action Kinetics of Gas-Phase Multiply Charged Transition-Metal Cations. $20,000

Roseanne J. Sension, U of Michigan. Time-Resolved Studies of Energy Redistribution and Disposal in Hydrocarbons. $20,000

Peter C. Sercel, U of Oregon. Investigation of the Optical Properties and Microstructure of Nanometer-Scale Silicon and Germanium Clusters. $20,000

David A. Shultz, North Carolina State U. Para­magnetic Discotic Liquid Crystals. $20,000

Milton R. Smith, Michigan State U. Synthesis, Structure, and Reactivity of Early Transition-Metal Complexes with Direct Bonds to Bo­ron. $20,000

Steven A. Soper, Louisiana State U. Fluores­cence Properties of Near-IR Dyes Bound to dsDNAs and Its Application to the Detection of Single DNA Molecules. $20,000

Wanda J. Taylor, U of Nevada, Las Vegas. Contractional and Extensional Tectonic Evo­lution in the White Pine Range, Central Great Basin. $20,000

John Y. Walz, Tulane U. Effect of Fluid Motion on the Interaction between a Particle and an Interface. $20,000

Lewis E. Wedgewood, U of Washington. LDV Study of the Flow Field in the Aligned and Mis­aligned Cone-and-Plate Rheometer. $20,000

Wuchang Wei, U of California, San Diego. Global Calibration of Paleogene Calcareous Nannofossil Datums with Magnetostratigra-phy. $20,000

Derk A. Wierda, St. Anselm C. Reduction of Dini-trogen by Vanadium Complexes. $20,000

David O. Wipf, Mississippi State U. Pitting Corro­sion Formation and Examination with the Scan­ning Electrochemical Microscope. $20,000

Jin Z. Zhang, U of California, Santa Cruz. Femtosecond Studies of Photoreaction Dy­namics at the Liquid-Solid Interface. $20,000

ACS-PRF Grants for Fundamental Research in the Petroleum Field (Type SE)

William J. Brittain, on behalf of ACS Division of Polymer Chemistry. Synthesis of Con­trolled Polymeric Structures through Living Polymerization and Related Processes, 208th ACS national meeting, Washington, D.C., August 1994. $2000

Joseph M. DeSimone, on behalf of ACS Divi­sion of Polymer Chemistry. Recent Advanc­es on the Synthesis and Characterization of Block and Graft Copolymers, 206th ACS na­tional meeting, Chicago, August 1993. $2000

R. I. Haddad, on behalf of Geochemical Soci­ety Division of Organic Geochemistry. Sedi­mentary Diagenesis of Nitrogen and Sulfur in Organic Matter, GSA meeting, Boston, Octo­ber 1993. $2000

Patrick G. Hatcher, on behalf of ACS Division of Geochemistry. Biopolymers in Sedimenta­ry Systems, 206th ACS national meeting, Chicago, August 1993. $2000

D. Michael Heinekey, on behalf of ACS Divi­sion of Inorganic Chemistry. Chemistry and Spectroscopy of Dihydrogen and Related Hydride Complexes, 206th ACS national meeting, Chicago, August 1993. $2000

William D. Jones, on behalf of ACS Division of Inorganic Chemistry. Alkane Functionaliza-tion at Metal Centers in Natural and Unnatu­ral Systems, 207th ACS national meeting, San Diego, March 1994. $2000

Ronald M. Levy, on behalf of ACS Division of Physical Chemistry. Protein Folding, 206th ACS national meeting, Chicago, August 1993. $1000

Timothy P. Lodge, on behalf of ACS Division of Polymer Chemistry. Block Copolymer Dy­namics, 207th ACS national meeting, San Diego, March 1994. $2000

James E. Mark, on behalf of ACS Division of Polymeric Materials: Science & Engineering. Inorganic-Organic Polymeric Composites, 207th ACS national meeting, San Diego, March 1994. $2000

P. K. Mukhopadhyay, Wallace G. Dow, on behalf of ACS Division of Geochemistry. Re-evaluation of Vitrinite Reflectance as a Matu­rity Parameter: Petrologic, Kinetic, and Geochemical Factors, 206th ACS national meeting, Chicago, August 1993. $2000

Gilbert M. Nathanson, Kenneth B. Eisenthal, on behalf of ACS Division of Physical Chem­istry. Chemistry at Liquid Surfaces: Equilibri­um and Dynamic Properties, 207th ACS na­tional meeting, San Diego, March 1994. $2000

Dudley D. Rice, Martin Schoell, on behalf of ACS Division of Geochemistry. Sources of Natural Gas, 206th ACS national meeting, Chicago, August 1993. $2000

T. L. RobI, on behalf of ACS Division of Geochemistry and the Society for Organic Petrography. Geochemistry and Petrography of Kerogen Macérais, 207th ACS national meeting, San Diego, March 1994. $2000

Kirk S. Schanze, on behalf of Inter-American Photochemical Society. 6th Winter Confer­ence of the Inter-American Photochemical Society, Clearwater Beach, Fla., January 1994. $2000

Alan T. Stone, Bradley M. Tebo, on behalf of ACS Division of Geochemistry. Transformations at the Oxic-Anoxic Interface, 207th ACS nation­al meeting, San Diego, March 1994. $2000

William C. Trogler, on behalf of ACS Division of Inorganic Chemistry. Inorganic Chemistry in Environmental Problems, 207th ACS national meeting, San Diego, March 1994. $1000

Marek W. Urban, on behalf of ACS divisions of Polymeric Materials: Science & Engineering, and Analytical Chemistry. Hyphenated Tech­niques in Polymer Characterization, 206th ACS national meeting, Chicago, August 1993. $2000 Π

Symposium on science, competitiveness The ACS New York Section is present­ing a symposium, "Catalyst for Change: A Dialogue with the Policymakers" on Saturday, Oct. 2, at New York Universi­ty. A panel of speakers from academe, industry, and government will discuss issues of science and technology vital to global competitiveness. Speakers include George Bugliarello, president, Polytech­nic University; Mary L. Good, retired senior vice president, Allied-Signal; Pau­line Newman, U.S. Circuit Court judge; and Arati Prabhakar, director, National Institute of Standards & Technology. The symposium is scheduled to run from 9 AM to 3:30 PM; an afternoon ses­sion will be devoted to defining a role for local sections and ACS in furthering national goals. For further information, call Paul Barkan, program chairman, at (914) 285-6918. Π

ACS ombudsman As a service to members of the Amer­ican Chemical Society, an ACS staff office of ombudsman, which was es­tablished in 1976, provides a focal point for members to voice ideas and concerns, and primarily to solve non-routine customer service problems. For such matters, please contact the ACS ombudsman by phone at (800) ACS-5558, select 8, then 5; or write to 115S—16th St., N.W., Washington, D.C. 20036. Members are also remind­ed that society councilors and direc­tors are available to hear and act upon complaints and requests.

AUGUST 30,1993 C&EN 43