time-resolved synchrotron x-ray computed … › ... › t3_14-50-nathaly-lopes-archila.pdf ·...
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TIME-RESOLVED SYNCHROTRON X-RAY COMPUTED
TOMOGRAPHY AS A TOOL FOR GROUNDWATER
REMEDIATION
Nathaly Lopes Archilha1
Gabriel Schubert Costa1, Tannaz Pak2
1Brazilian Synchrotron Light Laboratory (LNLS/CNPEM) and 2Teesside University
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Agenda
- The Brazilian Center for Research in Energy and Materials (CNPEM)
- The Brazilian Synchrotron Light Source and the Sirius Project
- Time resolved X-ray tomography
- Application for Groundwater remediation: in-situ reaction between
TCE and nZVI
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National Laboratory - Free for academic users- Partnership with private company
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Relativistic Model
Cone emission
P. Willmot Introduction to Synchrotron Radiation Science
1
𝜸= 1 − Τ𝒗2 𝒄2 ~ 10−3 deg
The Brazilian Synchrotron Light Sourcea particle accelerator
Classic Model
Isotropic emission
Centripetal acceleration
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Wavelength?
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And what is the impact?
http://www.chemistryland.com/CHM107/Final/FinalWritten.html
NEAR IR VISIBLE UV X-RAYRADIO WAVE
MICROWAVE SHORTWAVE IR
LONGWAVE IR
Higher energy, smaller wavelength
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Incident photon
Sample
Photoemission Fluorescence
Transmission
ElasticScattering
InelasticScattering
Electromagnetic Radiation
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The Sirius Project
Ago, 2018
3 GeV, 250 pm rad
IPÊ
(AP-RIXS/AP-XPS)
90 eV - 1600 eVCARNAÚBA
(nanoprobe/ptychography)
2 -15 keV
MOGNO
(Cone beam CT)
30/90keV
Short period undula t or
Long per iod undulat or
3 .2T Superb end
SABIÁ
(ARPES/XMCD)
90 eV - 1600 eV
MANACÁ
(micro and nano MX)5 - 20 keV
CATERETÊ
(pw-CDI/XPCS)
3- 15 keV
HARPIA
(TR-XPD)
5 - 24 keV
IMBÚIA
(IR-SNOM)
0.001 - 1 eV
HERA
(XTMS)
40-120 keV
SAGUI
(SAXS)
4-24 keV
XARU
(EXAFS)
4- 45 keV
3 - 35 keV
EMA
(Extreme Conditions)
COLIBRI
(CDI/PEEM)
90 eV - 1600 eV
Large Microscope: most interesting/challenging materials, with nanometricresolution and several contrast mechanisms
Experimental ProgramsTender nano-probe for spectro-ptychography; Large FOV (40 mm) coherent diffraction imaging; Bragg CDI/XRD/XAFS under extreme conditions; Serial micro and nano MX; Tender x-ray RIXS; Time resolved powder diffraction; High-throughput SAXSARPES/XMCD; AP-RIXS/XPS; CDI/PEEMCone beam high energy tomography; EXAFS; High energy X-Ray diffraction; Nano-FTIR
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X-ray computed tomography
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Mogno Beamline @SiriusCone beam x-ray imaging
Energy Range ˜20, 40 and 70 keV
Resolution ˜ 100 nm to 55mm
Field of View up to 85 mm (zoom-in)
Contrast Electron density, phase contrast
Dose Very efficient
Speed Fast (~1 mCTs/s)
Equivalent to parallel beam with:
Magnification:
1.5” rock and soil samples
A 3D image in 1 second
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~1 mm ~20 mm
Applications – zoom tomographyfrom hundreds of nm to dozens of micrometers
- Zoom tomography: reveal unresolved connections between pores
- Truly non destructive scans (cone beam)
- No special sample preparation required
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Application: time-resolved XCT
More extreme conditions
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Application: In-situ degradation of TCE using nZVI nanoparticles
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Application: In-situ degradation of TCE using nZVI nanoparticles