{

n - 7 //." ,.:c-/

RESTRICTED USE PESTICIDE DUE TO ACUTE TOXICITY

For retail sale to and use cnlll' by Certified Applicators, or persons under their direct supervisial, and cnly for those uses =ered by the Certified Applicator's certification.

TRICAL

METHYL BROMIDE 98% FOR USE ONLY BY PROFESSIONAL FUMIGATORS

ACTIVE INGREDIENTS.

Revised Label

Oct. 1987

Methyl Bromide .................. 98"/. Chloropicrin ...... . ............ 2"/.

ACCEPTED lIaao-1/ SEP 6 1989

UND£II tHE FtDERAL IIISECTrCID£ fUUGICJ!J[ AND HUl>E~TI(;Wt.: ACT FOR ECOffOllo1JC PoiSON Jtl.G15TtH to UNDER "0. __________ SUBlEct

T:J ATTACHED COIIMf.HTS.

1 1 1 , 1 ,

• •• • •• • • ~ .. , , .

• • • • .. · . , .. • • • • •• C I.

· . · ..... •

.. . · .. ... ... · .. '. ,

FRONT PANEL

fOCie I ~ ' •. '2- - •. I .,

(

. .

Methyl Blomide 9St· Column 1

KEEP OUT OF REACH OF CHILDREN

PELIGRO~

POISON

I PruDlLCI<N AL USARIO:. S1 usted ro lc~ Ingles, ro use este pro1ucto hasta que 1a etlqueta le haya sido explicada ampl1amente. _

IN ALL O\SES OF 0VDIDa'0SURE. GET MEDIOIL ATI'ENl'I<N JM1EDIJ\TD..Y. 11.KE PmscN 'ro A OOCI'OR OR AN ~Ci nmI'IMENl' F1ICILITi

STATEMENT OF PRACTICAL TREATMENT

IF lNHM.D): Get expJsed person to fresh air. Keep 1<'""--­warm. t-'.ake sure person can breathe freely. If breathinq has stopped. give artificial respira-tion. Give oxygen if~. Do rot giV9 fln'j-thing by IIOUth to arTl l.lI"lC01SCioos persoo. Seek medical attention. IF (N SKlN: Imnediately rmOl1e ccntaminated cloth­ing, sl-oes and other items covering the skin. Wash contaminated skin area troroughly with soap and water. IF IN EYES: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. N3I'E'ro PHYSICIAN: Early ~'I1'¢ans of ~ are dizziness, headache, nausea and van1tinq, weakness and collapse. Lung eOema may develop In 2 to 48 hours after exposure, accorpanied by car­diac irregularities; these effects are the usual cause of del'th. Repeated overexposures can result in blurred vision, staggering gait and mental isn­balance, with probable rec::Nery after a period 'c.!' . , ro exp::>sure. Blood brcrnide l_ls suggest the: , cx:currenc:e, b.Jt rot the degree, of exposu:t.v. ' Treabnent ~s synptanatic. ":' :

s~. Slde 'anel For AddJtJon.l 'recautianert St.t~"t.

TRICAL •• 0_ .oX 1317 • HOLLISTER. c~ 95014

E.P.A. EST. 11220-CA-l,2,3,4;FL-l E.P.A. REG. NO. 11220-RT

Nlr CONTINTS .••••••••••.•••••• LIS.:

, . j.' •

FRONT PANEL

Mellly! Bromide 98% ~

(

Col ur.;n 2

PRECAUTIONARY STATEMENTS HAZARD TO HUMANS

AND DOMESTIC ANIMALS:

DANGER EXTREMELY HAZARDOUS LIQUID AND

VAPOR UNDER PRESSURE. INHALATION MAY BE FATAL OR CAUSE

SERIOUS ACUTE ILLNESS OR DElAYED LUNG OR NERVOUS SYSTEM INJURY.

DO NOT BREATH VAPORS. LIQUID OR EXCESSIVE VAPOR CAN CAUSE

SERIOUS SKIN OR EYE INJURY WHICH MAY HAVE A DElAYED ONSET.

DO NOT GET LIQUID ON SKIN, IN EYES, OR ON CLOTHING.

THIS PRODUCT CONTAINS CHLOROPICRIN AS A WARNING ODORANT. CHLOROPICRIN MAY IE IRRITATING TO THE UPPER RESPIRATORY TRACT. AND EVIN AT LOW LEVElS CAN CAUSI

PAINfUL IRRITATION TO THE JYIS. PRODUCING TEARING. IF THESE SYMPTOMS OCCUR. LEAVE THE FUMIGATION

ARIA IMMEDIATElY.

OBSERVE THE FOllOWING PRECAUTIONS:

0- ••

• ,

•

•

Methyl Bromide.,. Column 2 • Page 41.: ~

GENERAL PRECAUTIONS I. D. not tet 1ft ".'. eft akin. or en cl.'h'~ •. J. ~. ftO\ _,Ill er .lach.r •• COfttaftte ~~.ld. ., ara.. cent In ••

tar tr •• tec.nl. 3. eoa,l, with .11 l,cal r"~l""~' .~ .r4Iftanc •• , 4. It ,. advl •• bl. t. au,." Jeur ph",ct.n with ,"fer-a,lon eft

Hath,l .r •••••. L1teratur. 1 •••• 11abl. 'ro. ,o~r 4 •• 1ar .1' .hU"utor.

I. a.t •• n •• dlcea ••••• t.nc •• t .nce 1ft c •••• 1 111ft •••• rt.r ••• • '.~r.. .ft.~. not allow co"~lt.o". which eould ace.4aft,.'1, cav •• further •• ,.aure untIl .. aco •• r, I. coa,leta. Is •• Ma,a ,. 'h,elU.".,

RESPIRATORY PROTECTION " the con~."tr.tSon of •• th,) bro.ld. In the wo~~ln9 ar ••••• •••• ured b, • dS,..ct-, ••• Sn. d.t,ctar d •• 1ca (.~ch ••• Dra,a,. , •• datactor) do •• not •• e •• d, ,p. (20.,/eu .• ). no , ••• Sra'~r, .~ot.c~loft 1. r.~ulred. It thl' concentr.'Ion I ••• c ••••• at anr tl ••. all F.~.or'la In the lu.l,.ttoft ar.a auat "'a." protectS ... clothl~. and a _lctH/h,KA appro.... ..It-centalned br.athln, apparat~_. C'CI~) or co.bSnatlCft .Sr-.upplS.d/SCIA r •• plrato,. lauch.. • U.S. Dl •• ~.· Surwt-.Sr or Co.parabl. .._ .. tc.) . Under noraal _011 f~I,.'l~n conditione. the conc.ntratlon 01 .ethyl ~rD.ld. In ,h. vorklh. ar.. viii not $an.r.llr •• c ••• ! p, •••• tl •• -ve •• hte •••• ~e.e an' no , ••• 1ratorT ,rat.ctlon ,_ re~u'r.d. Mow ••• r. thare ,. the poeelbtlltr.'. aptl1 or l.ak 4urln, .011 Iw.SI.tlon. ~h'r.fo... • .CIA _r co.~tna'l.n alr~,u,plled/SClk ~e_plrator au.t be a •• llabl. an, vIII ,_ require. for ontry Into an .tt.ct.d ara. In ~h ••• _nt oC • 1.aK or .,111

CLOTHING PRECAUTIONS 1.\I<l:ar Icc •• clo·.hlh. an4 aock. that ara claan.. .tt.r •• eta

~.arl",. ~o ~O~ ~ •• r J.~.l,. .10 •••• o~ tl,ht Clothln, wh.n handltn,. Heth,l .ro.ld. Sa h ••• i.r th.n ,ir an4 •• , ,. trapp.d In_1do clothln9 .nd CA~.' akIn tftJ~ry. It full-Cac. t't"aplratory protection i. hot ,. • .,..Irad. v •• r ,e"l.. .r full '.co .h'.l. tor .7. prot.ction ~.n h."4Ll~, 111Vl.~

2. rolloYl~. application. 1 ... dl.t.ly re.o.. clothtn •• aho ••• and aocke. D. n.t raua. con, •• tn., •• clo~hln. or Aho •• ~\l\ thorovlhly cl.an.d .nd •• rated. Dr.nch.. clothing c~ot ,. ad.quatel, decont •• lneted.

3. bo ftot v.at Ilov •• of eny ttre. or rubb.r ,rotectlw. clo~In, or ""bber boau.

WARNING SIGNS 'Itructu~.l. Tranaportatlon •• ?&ca r~.t,.tion'

a~ ~n. a"alc.tor .v.t ,j.~ar. or ,oae all entranC •• to tfta Cv.I­•• t •• ar •• »Ith' .I,n. ~a.rln. In ~n.l1.h an. _ •• nt.hl (I) Th •• I,n.l VOl" DAHC""ELIO.O an. tha .kull an.

cro.a~On.a .,.bol. (21 Th. .tat •• ent. ·a~a. ~.r tu.'.atlon. DO .~T cwtl.'NO

rNTRE-. (l~ 'h. d.t_ .t t~".tton. t4) .a .. ot t~l'aft' we.d. t~) •••••••• r •••• an. tal •• hefta ftu.~.~ .t .tha a.'~te.ta'.

2. Do not re~~e a placard unt1l tbe treated apace 1. ca.­pl~tely aerated. to deteralne whether aeratlon 1. co.plete, each fUD1aated .lte .us, be .on1tored and .hown to contain le •• than S ppe .. th71 br~1d.. If lea. than S ppe .. th71 b~~lde 1. detected, the pl.card .'7 be re~~ed.

I. I •• cere .~.t ~. ,l.e.r4 •• v.,~ •. o.i: _,ecjli •• v'~'ft' .llfta. ~arnlft' .1-" •• r. ~ •• 11.~'. 'w .. ,.ur ••• l.r .~ .i.trt~u,ar.

SPILL OR LEAK PROCEDURE 1. Iw.~.'. th4 1 ... 41.t •• re •• t the a,lll .r I.ak. v •• lela .~

c""ftetl8ft .1~-aw,.I' •• I.CIA ,e.,Irater tar .ntrr In'. the 'CI.ct •• are. t_ carre.' .re'I... ~.. 1 ••• ln, 'F ••••••• c,I'n'e.a.r cent.Ifter. aut"". ar I. a~ ' •• I.te. ).c.'l~. ~ •• ~ln. .trlt~ •• '.ty ,raceutlan •• V.r. ~.wCn' If ••••• ~I •• a.l .. _,III , •••••• r.t.. • ... , •• ralt ."trr In' •• ,111 .re. ~y ~,r.'.ct.' •• ,.~. ~ti' c.ftCeft,r.,t~.I .athr' " .. , •• 1 ••• t.~'n.' ,. ,. 1.a. thIn' ,,. CJO .,/ew .• ,.

2. Ceftt .. lft.'.' •• ". _a'.r~ .ft4 .'~.r cl.4ft~ ••• r._ 'e • t •••• h ••• r'._' v •• t •••• ,." _.111 ,. thl •• tl.ft.' •••• ~_. Can tar Cloo-424-"OJ, II the ra •• rt.~l. 4Y.~"" .1 1000 1'_. ,_ •• e ••••••

.1. ' •• CAVTI~. COK'I~I' 7"' •• COL~

L ~ •• _ ....

..

Hethyl

•

I

l ~ ." , " ':,,'"

~. ~.

<

...

Bromide 981. • Column 3 • PRECAtrrIONS FOR STRUCTURAL,

TRANSPORTATION, OR SPACE FUMIGATION USE

GENERAL PRECAUTIONS: 1. " •• p .,.1>001 •• child .... Oftd .... uthodlod _1. _,. rr_ ....

under tr •• ~t until ace. t. certlfl.4 tr.. of "-thyl • lram16e. (See aeration .t.t~nt.'

3. "".n u •• ' '.r '\I.I.,.UOft .t ."cl ••••••• c... (hou ••• an' othor atTUctVr... v.r.h.u •••• •• ult •• ch •• bara •• r •• nhou •••• truck •••• "* .•• acara. ohlp •• a .. ' other tra".port •• hlel •••• n' tar,aul1,.'"'co •• rad ar ••• ' two •• r.on. traS"a. In the \I._ of thl. product .\IIat b. pro.ont durSn, '"trDducCion ., the lua',a"t. 1,.1tlatlon 01 •• "atlon, and .ttar .... at1on whan te.tln, tor .... "tI'7. T ... paraona 40 not n_.4 to _. ,r ••• nt 11 .0nStorl". s. conduct •• .... 0'017 (out.S •• the .~ •• b.S", 1\I •• ,a'ad).

3. Do not '"algete ~Ith thl. product vhen te.per.ture 1. belov 40 degree. r.

4. Whenever po.albl •• apply Methyl IrCRdd. I~ out.ida 01 atruc­ture or ~.r being f~g.ted. "-ke aura the f~O.ted area la properlY ae.l" an4 poeted.. Do not 1IO'W. tone"_. t"aUer.. or van. dudn; fwdg.t1on. They ...,.t be CCIIIpletaly •• rated berota ~~nt 1a allowed.

AERATION AND REENTRY: 1. After f~Dat1on.tr.ated ar ••• auat ~ •• reted until the level

,.., Meth"l hr~d. 1. belCM 5 ~ ,20 JIIIO/aa •• ). Z. Do not .110" ann., Into th. tr •• t.d .1'.. bJ' .nr p.raon

berore \hl. tl •• \11'11 ••• 100 •• clothSn. _nd • r •• plret01'J' protectSon 4e.lc. ,.CIA or coabin.tton .Ir-aupplled/SC •• ' I. "01'1'1.

Pase

•

(

Methyl Bromide 98% \ Column 3

PRECAUTIONS FOR SOIL FUMIGATION USE

PRIOR TO FUMIGATION: 1. ~ly wlth all local regulation. and ordinance •. Obtain an ap­

plication pel"lldt t"" Agricultural I'e-gulatory Agcncit:. •• required.

2. Never fumd;ate alone. It 1. ~r.tlve always to have an a •• ta­tant and Fro~r ~rotectlve equl~nt In c •• e of accident •.

l. Drivers of aFplicatlon equl~nt ~.t advi •• other worker. at all precautIon. and procedure.. In .~tlon. driver. ~.t instNct lMir helper. in tM IMchan1cal operation of the tractor and ~ to •• fe1y work with the tractor and driver while f~S.ti"i'

•• HanCUe this f~iant In the open. with the operator ·up wind­rr~ the contaIner Where there 1. good ventilation.

5. Cleek fU!I"JgL"\t pre •• ure systen for leak. before begiMino operatior..

6. TWo trained persons ~,t be pre.ent during introduction of the fUlidgant.

7. When f~;ating a011 from a tractor. 5 gallon. of water ~.t be carried on the tractor and placed where it 1. readily accessible. In addition to water available on the tractor. at least 5 gallons of addi~ional water ~.t be available f~ the service truck. Thi. water ~.t be potable and in containera ~rked ~Decont~nation water not to be uaed for drinking.-

I. Field _hould be rea.onably free of tra.h before atarting the fWl'ligation.

DURING FUMIGATION: 1. This fundgant .hould not be applied when there ia an at...,.­

pheric inversJon. Since unca-fortabl. concentration. ot chloro­picrin Ny drift to nearby .re.... 1JmtedJately cover treated area with pla.tic tarpeulin for a ~ of 48 hour. When the injection de~th 1. Ie •• than 10".

2. Do not lift lnjection _hanks to turn at the end ot a p ••• until t\Ml1gant ha. drained tren ayat .. following closure of .hutoff valve.

3. If tn.h 18 1n.dvertently ",,11e<! by the .honl<. to the entia of the field ""en f_gating. it .... t be COlIne<! by lUting the ahanks. then covering the tr •• h with polyethylene filM befora lMking the tum for the next pe.s •

.t. When changing the cylindera. be certaln they are turned off and luwigant aya;t8ft i. not under pr .. aura. Do not open the ayet .. ~~en there are people or .tructure. downWind where exposure. above the penda.able ~ura level. CO\a.ld occur.

FOLLOWING FUMIGATION: 1. Post all tre.ted .rea. with ~~inn aian.. av.ilabl. fra.

YOUr' dealer 2.. tao cMl4ren. W\.ut.horh." people. or an1Jnals ahoo..a14 be 1ft tM

lundoation are. foe 41 hours. 3. When tarpeulin is _ad. two trained penona .".t be pr •• eftt

!luring r...,..l of the t''P''ulin.

SPILL AND LEAK PROCEDURE: 1. In ca •• of a rupture of hoe. or fitting while :3fng !Uldgant

~dJately atop tractor and MOtor. EVacuate ate area of .pill or 1._. U.e SCM or caob1 ... Uon .1r-.uppliod/SCM r •• pirator lor *btrr into .rrected ara. to correct the probl ... ~roach lraw updnC1 to _k.. nKft •• ry repai n.

Z. Do not reenter .... without rnp1 .. tory protection ...,Ul .p111 ha. evapor.ted or le ....... been rbad.

NOTE CAREFULLY: FIaodIl'U", .. y t_nrUy rolo. the 1 ..... 1 of _10 nitrogen ...., eolub!e aaUa in the eoU. ft1a i • ..,.t 11kely to occur ...... n .... vy rat .. of fertilizer and f~v-nt .ra applied to a011. that are either cold. wet. acid. or high 1n ocganic .. tter. To avoid injury to plant roots. fertilize .1 Indic.ted by .011 t.at. ..de .lter tUlldvaUon. To avoid ..... i. injury eitd/or nitr.te .tarvaUOft to crope. avoid vaj~ fertililer. containino ~i~ a.lt. and us. only lertililers containing nitrat .. until atter the crop i. w11 e.tabU_Met and the 1IO~.1 t .... r.tur. 1. at:.:wa ., degr ... ,. lJodng highly .cid 0011. before fu.teotlon .t~lote. nltrl" flcotl ... ...., reduc •• the poo.lbl11t, of ..-.nl. toaicity.

Page 6/'1.- '),

•

'.

~,

Hethyl l)l:,o,mid~, .9bZ . • ____ colu:;;n 4 .' ENVIRONMENTAL HAZARD

Tht •••• Ucl~. 1. teaSe to vsldl11 •. =0 not dt.char,a .flluent contaSnln, th!a Froduct 1nto !ak... .tr..... poncs.. ..tyarS ••. oC.an.. or p"bHc vaten \ln1... "hi. pro~1.Ict 1. .pecUSedl, ld."tltled an' .d~r •••• d In an ,,'OIS par.l t.. Do not. .U.char •• • ftluent conta!t:.!n, thi. pro4!uct tD •• ",.r .,.t ••• vithout ,r.­.10u.17 not!:J'!~1 the •• va,. tr •• t •• ~t p:ant ."thcrity. for ,uld­.nc. contact J'c~r St.ate ~.!.r Ic.r~ or '.~!on.l effte. ot the I,A.

For _Plica r~f.t1on " ••• fIIIOnltor ar.. s..-edlat.ly aurTOUn41ng th. t~O.Uon. t. with • haUd. detector dudno .~ur. and .eratton per1~ to .atabUah that dangercu. level. or the r~gant are not pre.ent , •• e aeraticn .talenent toe halide cletKlor \lilt). '!!Ie high whtUHy or tho fumigant penllit. it to l>o vonted r .... ap8ca betng t\ft1,lted end to cUstlipate rapidly with no hlzard to lurrounding are •• ~lth correct monitoring.

omuCAL HAZAllD

Methyl Bromide I, practicilly nonrl~ble. There 1, no danger tcaw fire or ~loslOft in \ltle concentration,. However. n __ can change the ch~~c.l to prod~c. acme ccrroelv. damagl to It~ in the apace being r~O.ted. Pilot lighta and glowing vira heater. ahould be turned ott. . Do not apply 031 directly to Met,l IUft'ce. becau.. of poea1bIa corrosive effect on certain Metal •• Do not u •• container. or application et;\llpMnt _de or Ngneab ... • 1~n~ or their allaya. The following "~terl.1. can 6evelcp undelirabl. odor when encoun­tered 1n Itructural f\llo1,'tlon and should be rlllOVed reeR tbe 'r.ca being furdoated:

• FoodotuC.: (0) Iodized .olt Ib) FUll-rat .oya Clour Ie) Any kinds or ll\ateriala that contain r.actlve sulfur ~. such •• 10'IIII' soap poWiden. acne baking ,ocS., and .cne •• It. blockl u.ed for cattl. lick ••

2. CertaJn n;bber oooda: (a' Sponge I'\Ibber (bJ Fo ... ",bber. a •• ft rug paddJ.ng. plllOW'l. cushiONl. and _ttres.ea ec) I'ubber at...,. and other .Wlar fo"" of reclaJ..ed nabber.

3. Fur •• horsohair and pillowa IEopecially reotho. pillows). 4. Leather vood-~-part1cularly white kid or any other l.ather

gooda tanned with aulfuC' proce •• ea. 5. Woolenl--otnrne caution ahould be uaed in the f\lldo-tion of

an,. angora woolen.. and.c::rae adYen. effect ha. been noted on the rumlgation of __ len .uit.. coo... blanl<ot.. hand-luUt ~len lOCka. 8Weaterl. ahawl. an4 woolen yarn.

,. Vi.eea. rayon.- .. thoae rayoMl proc:Haed or -..nuhctured br • procea. In which carbon blaulphlde 1. v.ed.

7. 'aper: la) SHyer-poU.hing papeu Ib) C ... toin writing pape ... cured bJ .lIlphido proco.... leI Cori:loftlo .. papar Id) 11 ... -prln.t ••

I. Photo;r.pldc ch .... c.l. a. uaed in photo pnJee •• lng derk~. (dote not include c .. ra fllJl'.

t. illig podding. 10. Clndor blocko. 11. lUJIed concrete. ""ich occedonaUy pick. up _no 12. ~ .. tert.l. th.t _y cantaSn r •• ctl". lui fur £LCt __ .. 'ft",do.

It ~ IVIr N~ EFFEI:I'IVDlESS ~ T1IE llnICNtr: Ch.rcoal _t.rl.1 ..... c:harcoal abaGrbe the ... thyl lraft1da r .. ""clng t... erroctiva c:oncantutiOD and cont_noting t ... dI.rco.l.

13. It tlMr. 1. 0 _U ... ""ather 0 .todol _, _lop OIl _f. o teat r..tgaU_ -r 100 """ "ith 0 -.11 _tit, of \Joe _tadol. ' '

~. ...

Page

(

-~.,

.' DXRECTXONS FOR USE

It i. • v!nlatlon of F~r.l Law to u.. thl. p~t in any ~:r 1neonaiatent with it. labeling.

STORAGE A..'ID DISPOSAL STORAGE AND HANDLING: Store In dry. cool. well-ventilated area under Jock and key. ~.t IS • pe.ticlde atorage area. Do not cont~n.te vlter. food. or reed by .torloe. 'eBon. IIIOYlng or handling cont.lne~ .hould wear p~otcctlve clothing. ~ container only in • well-ventilated ar.a wearing protective clothing. and reaplratory proteclton it neee.­•• ry. Store eyl1n6er. upright. aecdred to • rack or well to prevent Upping. CYUnder. ahould not be lubJected to f1?Ugh handl1ng or lltechanicil lhoc:lc luch I. 4copp1nO. bwIIp1"G'. dcagglno. or 811cU"O'. Do not UI. rope .Ung.. hOok •• tonp. or alJidl.r device. to unload cyltftder •. Trantport cyl1nderl UIlftg hand truck. fork tnack or other device to which the cylinder C'M be findy •• cured. Do not remove v.lve ~~teet1on bonnet and •• rety c.p until ~d1ately beroce u.e. ~epl.c ••• rety cap .nd valve protec­tion bonnet when cylinder 1_ not In u.e. When cylinder- 1. .-.pty. close val .. e. .cr~ •• rety cap OI\to ..,el". outlet. ....s replace protection bonnet before r-etu('fting to .hipper. Oftl! t,.. reglatrent l' .~lhorlze4 to refill qUnftra. Do not va. C'J Inden (or any other- pu~.. Follow reglatrant·. inatructlona for return of eopty or partially eopty cylinder.

RETURN OF CYLXNDERS: CYUnder. ne the property of:

Trlcel Trtc.l 1770 Hwy.25 102' ~all<Oad St.

HoIUaUr. CII '5023 Corona. CII '1720

.nd .hould be returned praoptly by collect auto freight. Do not ship cylinder. vithout .atetl c.~ or v.ly~ protection bonnets. ~en a cylinder t. partially ull and there i. PO further r~tr.­.. nt tor the product. contact ~~ ror r.tYrn lnatructlona.

SHXPPXNG: Thl. r~oant i. cla •• tried 1n the U.S. Depert.ent of Trana~rt.~ lion Ha ••• cIou .... tuhl. ~egulaUona aa !!ethyl l.-1do Uquld or ... thyi IIr<l'llldo ani! HoftU_bi.. ,.,.,-llqulfied """'IIcea.ed lI.a IIliJrture. Uquld. cl ••• ·1· poleon (inh.laUon hazard) and no ~...,tlons fl'Cft speciflcatSOft •. pac".glng~ _t'kl"8 or l.belina .r. aUQIIIIitOd. o..cribe ...,tr cyUndera •• ,..vi .. 1 •• t CCftt.i".. ...thyl .r<l'llld. l.lquld or ""hyl l.....,.tIoo.nd _U_l.. _-UquUhd """'II .. a .. d V' • ..ut .. r.. Liquid (inh.laU .... h .... d). Do not ahlp wllh (DOdo. (ee4a. or clothlno.

DISPOSAL: Do not conl..tMte ".t«I'. rood or fled '" .torage 01' 41aposal • ••• tlclde va.te •• re to.!e. ~roper 4i.poe.l or &Ke.'. pe.tiet,« • • p~ay ~tur •• or cln •• t. 1 •• ylol.tlOft of Federal Law. If the •• "a.t •• cennot be 4lapoa'" or '" tIII.e 'CCOl'41,.. to label 1 ... trvc­U.on •• COftt.ct youI' State 't.tlclda or ",,,lRlNJlllfttal Cofttrol ~ncy. or the "'I.r~ V •• t. ~.pr •• cntatl •• at the n •• re.t EPA ~evlon.l Offlc. for auldenc ••

,.

\

Methyl Bromide 98% Column 5

GENERAL INSTRUCTIONS nils FUUCoWT IS 1\ KIGKl.Y IIII2AADWS I'IIInllJAL HID SMCAlIJ) M lISt!) OfLY BY IIIIlIVItJJN5 1'1'JW«]) III ITS PIIOI'D\ USE. ~ USlllC. RENI I\HD FOu.ow IILL ~Il. I'REOIlIrIONS NIl) D1lIE:CTIONS. 1NCWDlIIC l1I£ IIlTACIIm IWUIL. AU. rDlSONS wtIIUWIc; IImt nils FUUCoWT ItJST 1£ ~LE ¥Off lIfE 11II2NU>S. HOD 11U\lHED III 1IIE ust or NOJ1N:D NS'lMwa 1011_ NIl) DETtCroII. DEVICES. ~ "-.II\Es. NIl) I'ROPOt U!''' or 1lIE FUUCIIHT.

Page ~!.,~

(

Methyl bromide 981 column 5

..,.... SPACE FUMIGATION DIRECTIONS.\:~ .. When using methyl bromld' .1 • aplce . furn",.nt.lhe appUcator "'Ult ~ .• t, peac.rd or post .U enlrane'!, to Ih' fumigated .r •• wUh Ilgn. ~'rlnQ. 'n EftQlI,h '.~' and Soanish: • '.

t. The signal word O.c.NGER/PELIGRO and Ih. Iku. and (rOllbon" Iyrnbol 2. Th •• ,.,.,..n,. -A ••• undor 'umlg.llon. DO NOT ENTE/IINO ENTIlE". . .• .;. 3. lMda,.oI lumit;"ion. . : "" '" ",1~~:!{l~I~';:~'" :.. , ... . •. Ha",. ollumiClnl uSeod. 'R'''';.':~:;.~, ~. . .... ! 5. Name, address. and telephcnl number of Ih. apptlca'or. ~ , .' ~.~

,,"YPlrSOfl who ".nslels a hl.ted c.ommOdlty to ano'''-' slta without ... rationmu,t : •. :'.: _"IUr, Iha. th, "tow $.1, II placarded untlllha commocUry I, I.tlt,d below the .. ~:: thr'ShOld concentration. " . ..: ·\.:·:.~··j~··l··· .T: Only a cel111ieO .pp1icato' may remOve placarda, and on'Ywh.n thec.one.nU.Uonof. , ~ a

mel"yl bromide in Ihe trealed sile or com~~i;IY I~ ~~~)~-p.~;:{t~~.~.:.~ .. ' .~, ~~:_{ . .o!"'.. . "\ A. CHAMBER FUMIGATION ' .->' ..... ' ...

Selare inbOdyC,"" !~~ fYm-loant, plac.e w"nlng signs :" Q.. \ \ doorS. Two p~ople lhou'd be pre,.nt_hln . inhOducing the 'uMi;anl and open1ng the door .ner iumlgaUon. A.M c.on\fols Should be OutSide ttle Ch,mber, ' '. :.

load Ihl chamber lWith the materlalto be fl.'mig.ted.close'lIhaustporta.'urnon CirCulating Ian and close chamber door. Oet.,m.". trol PfOP4f r.'. Of appllc.aUo" .nd e .. poSUte 1irne Item the approprla,. lable. V.porl'l Ihe liQuid In the chamber by sprayi"" II in10 the air slr •• m In front of • blow.r or f.n. paning" through a vaporizer. 0' .nOwing II to evaporate from a shallo. pan. '

"Iltle end ollhe eaDesu'e Dertod. ae,ale byoP81nlngthe ... haust port. turning on the ellhaus' 'an and ooening the chambe, door Slightly to pe,mlt ".ah ai, 1o en1e,. NO~E: .tways chec,," completeness 01 •• '.tlon with d.t~lon devlc •• before allowing un~,otecled perSons 10 .nte~ I~~ c._~.m~.r..f~~~~.:~l '.,

,',., :"';':"':':- .. ~,!:t:~":. ~~ ....... B. VACUUM CHAM€ER FUMIGATION . - L'!;.'.:.:," ,1,.;,:,

1. Place mate,ial to be fumigated in th. It.el chamber and d,aw the de,'red: { . .. acuum. ., ,. ~. • ..•. ~

2.. Re'''I'. fumi;ant Into the Chamber (utually lhrougha h •• tlng unit toen,u,. ")1 eomplete ..... POrlzatiOn). . ' ! : . ;:

3. See Table a for lpectfic cornrnodiUes. "'.:ot .Ipplbtlon .nd. e.posure tim!. . ,... .. .:.~., ..

... "t the end of the e,posure tim .. 'e ..... the vacuum and change'''' Itt In the c.hamb«' at 'ealt two timaL A "1C,UUrft of , 5 In. Hg. IhOYId be drawn.or thla. . purpose. :~~;;.F!.i~'::'":':~:' . '.~

' .. ~..p.:.'~ .. .t!..1 : . '. :~. C. TRUCK, VAN OR TRAILER FUMIGATION : ,,'::.:,'.. ..

1. Sear the olf's,oje door, ven'ilator. and other openlttgl from the Inlld .. 2a Use I closed·ended. perforated lube 10 distribute 'um)glnt avenly. Secu,.

'''''ube 10 the ceiling 10 th. periorlUo", dirK' fumlga,1 'owa,d Ih.1Joot and P'evenl it f,om sDfaylng I". ceiling. Atwaya .ppty fum.~.nt from out.1de thl tNC .... "'8n or 'fa, .. ,.

3. Sell 'he door .nd place warnln; aignl on both ald •• of the 'ruck- VI" or 'rai ..... Fumigated .rea. mu •• b.- plaelrded on an e"'"nelL Do nol r."'O¥e ..,.,ning stant "nlill .... fumiQated Irea I. com"' .... ., ..... Ied and •••• for enlry. al Indic.ted by I ."Uable delKlor.

~. 00 rot tum'O.,. while 11'0"0 wlnet. ,f. blowtno. ,. s. Co' JII lobi. II 'or lpo<WIc <ommOdI" ... ",. '" ,appilailion .ncI ... ~au,. time, .

.. Aller 12 to 1 e hour .. open the unUlrwt •• 'I,.,to 1 ~h~O~U~"':~T~:"':~~~~~g 'railer m.,. ,h." be,el.al':'~~~~~~~fE~ DO OR TRAilERS DURING 8ElOW 5 PPM BEFORE AlI.O¥VEC'.-.'

7. Ad.I •• <on'lg ... ,O <h.ek I". .. - __ .. ,~.:~,' :l'~~~~!J _&I.

D. RAILROAD CAR FUMIGATION 1. S.at th. OIt'IIde dOor ... n'5II'or. and othe, OPlnlftol Irom , .... "'Ilde. 2. U •• aclo •• d'.ndOd po"Ofal.d'ubeIOd;.,,'bul.'umlgonlo .. "". Sacu'o.'"

'ube 10 .h. co!fino .0 Ihe porfOf.'Ion. d"ac"umlga.,'_d the 'Ioor .ncI ", .... , II "om .",.,lng.IIa c.lIIng. AIwe,. .POI1I .... Ig.'" "OfIIOU,.Ida.IIa car, .~ ...

3. Sea' th. doo, and place wa,nlng .Iont on both 'kI •• 011 .... U'. Furntga'.ct . I

Ma •• fftUS' be placarded Oft el ."hlree. _Hh WI'" .Igna. Do not '.mowe • ..... fIInt ''V.I unll Ih. ,,,",IgoI.d ., •• II <_laloly •• '.'04 .ncI II'. lor :.:: . • ntry. I, mdtclt.d br 1.IUnabie d.tec'or. ~·f •. :.~.~·", •• - ."~: .. ',';:' ~ .. ~'.~~!.;.

.. Do nol fumigate wttlla "'ono wll'd. Ir. bIow1no.· .~' .•. "., .

.. Cotoovl Tobie II lor • . 1I1 ••. "',.",,"11on .ncI,: :'~r:;', a"po''''. U~. , . . .-!." ,;,. .. : .. All.,. 2 10 'I ...... , .. Opo. I". ..... ' •• d ,.'.11'", "0 11\ 1Iout .. T". c., may I".. be ....... d'o. .hIp_"" 00 NCT MOW ""'''tARS, DUlliNG rUM' ••

. GATION. lHfT MUST BE AEIlATEO TO 8ELOW~' PPM IEFOIIE MOVEMENT IS "'UOWED. . • .,... 'i' ~ •

1. """""" COOl ...... 10 chac ... ,he CIt '''' ""_, ••• 1I1on orr .""'.L .....

Page 100- -~~

(

Methyl Bromide 98% Column 6

"

;j~·i·~ -.~ ~ ... ~ .. -~ ··!··'oIf~I!1'·'~':''''.''. ';~~<:-!I

TARPAULIN FUMIGATION " , "~S{(, :,',," ':" . );'"'~;:l .'~~. .

TIle .11.ked _I.rlillhould be placed Oft I concrel. "- or oilier .lr-tlght ':, .; .urf.c., ~fl"'f_ .. '"" Ik·llght. H _, be _cleoo by laying SIMI Kraft Piper, '.' la, Pipe, or __ IIIfPluiln or pOIyIlhyllne ..... 1..., on H. Cenler • or I , nc:u on lop 01 Ih. aleck 10 ...- __ for 0" • __ PIKe In':" __ .. ...,Pin wIIh.n.nc:hored.flll\lCalorlubl ... l ... ce"'eroll .... "".nolon _,,7. dome, (;oft, Ind ••• 1 I'" .Ieck wllh • 01. light .. ....- or pOIyIlhyIen. ' ..... 1..., 01 • 111ft Of or ..... Ihlcknea .. COMIC! thllubl to .... III' qIIncIer. . ........ Ih.furnlpn\. u. ...... nd •• __ 1 ..... .-"'T_, " When "'rnlpllon .. comDleI •• PIfI .. .,' ............ I.",.u ... end ...... 1or30_ ... Thla _ PI""I .. ,"11on befor ..... c_ to corn .... t..,. .. _

page 1 liz '_

•

{

(

Methyl Bromide 9~ Column 6

WAREHOUSE. STRUCTURAL" FOOD PLANT FUMIGATION Cheek vith appropri .. e .unlclpd an~ county allthorith. before fll.lgating to b. eo.plealy f ... iliar vith locd regulations. Ordinance ••• y t'eq~lr • ..,atcu.en, pad locke., or .... rnln'l1 poat.era during and. after fu.lgaUon an~/or notification of the Mareat fire s .. tlon. Notify anyone .. ho .. ould nor .. ally be in the area before fumigating. 1. Re.ove food and f •• d coc.oditle. be for. fumigation. 2. Se. Table II for rat. of application and pest. con~rolle~. l. S.al the bull~lng by clOSing all .xt.rnal opening •• Including roof vent.il.torl, chlaney., drain pipes. tunnels, et;. Fum1gateO are •• _uat be placarded on all entranc •• with algna containing at least the slgn.l .. ord DANGER and the Skull and Crossbon ••• and the wor~. -Ar.. under fu.lgatlon, do not enter until completely •• rateeS·, the data of fu.to_tion, nllll. of fumigant u •• d, •• ergency telephone nuaber for contact, Ind the n ... and addr ••• of the tu.lg .. or. Do not reMove .. arnlng algna until the fIlMlg.t.d .... Is coapletely a.r.te~ and sata for .ntry. as Indlcat.d by a suitable d.tector. 4. S •• l all floor and roof cr.c~ •• nd around •• v ••• S. Take apeclal care to a.al partltlona to adjac.nt atorag. or work areaa In the building. Wh.n ualng tarps. the aoll aurface ahould b. a .. led by using aand or ..... r snak.a or by trenching and burying th. edge of t~, tarp In the trench and cov.rlng .. Ith aol1 or aand folloyed by ,he application of "ater. "".n using aand anak.a. the aoll aurface ahould be pr •• olatened It n.c •••• ry. ,. Door. and hatch •• on ~Illing Machlnory ahould be opened prior to fualgatlon. Theae lnclu~ •• l.vator boota. conveyor llda. •• ttllng chaMber doora. dust trunk.. and any other openinga that

.vill allow fu.ioant into the equip .. nt. 7. Cl.ar adjOining buUdlnga aharlng a cOlllllOn .. aU. If th.y tannot be clearod. check frequently .. Ith an approved det.ctor to Inaur. the aafety of the occupanta.

page 12,1:::.-

t

•

(

(

Hethyl Bromide 98% Column 7 l

........... , ... • SHIPBOARD, IN-TRANSIT SHIP OR SHIPHOLD FUMIGATION ~,~: '::'1

IMPORTANT. Shipboard. ""trlnsit ship or shlphold fumigation ... I.oooverned' .• ' • by Ihe U.S. COUI GUlrd Regulations. Ref.r to and compl,whh tho •• regulation. ~.: .', prior 1o fumlgaUon. ,·;,:(~~'~;:t"il":~·'·'''>:~·.

:.~ ,':, ".: " .. :t o :;-~~.''';'''- ••

PREFUMlr .• IO.N PROCEDURES r:" .... , ~: .. 1. Pr60f 10 fumigating. 'l'els81 for In·trlnsit cargo lumigaUon. the ma.t.r of the

.e"el Of hiS 'epreserfalive, and Ih, fumigator must de,.rmlne whath.r the wessel is suitably designed and configured so I' to .now'or •• ,. occupancy by ttl_ ship', crew U'IfOughoullhe dur,lIon of'he fumigation. If It II determlnad t"lt Ih. des'on and confiGuration of '''e vessel does not allow for .It. occupancy by the ship', c'e#ll throughoul the durllion of Ihe fumigation, then the vess.lwill not be fumiglted unless an crew member. Ir. removed from the vess.l Th. crew members will not be anowed 10 r.occupy th. v,ss,l until the vell.1 hal beln propertt ,er'tedand a determin'tlon hal beln mid. by the m'ltlrof the v ••• " and the lumtgator that ,h. velsel i, saf. for occupancy (5 ppm or below).

2. The person responlible IOf th' fumigation mUlt nouty th. ma".r of thl ¥l1I.I, or hiS represenl,liv,: 1 J of the requirement. rel.t"'o to the UII of oa, ml.k. Of ,esp; •• lora lor Ih. lumig.nl ",Inlly .PP.oved by NIOSHIMSHA: 2) delecllon equipmenl; and 3) that • person Qu,lifi,d In the USI of thl' eQulpm.nt mUit accomPlny the vessel wilh Clrgo under fumigltion. Emerg.ncy procedure .. c.rgo v.ntililfon, periodic monitoring and "'.peCliOns, and nrlt aid "".Iur •• mUlt b. dlsculled with Ind undlrstood by tha malt.r of 'hi "pal or hi. repr.lenllti" •.

3. During fur..igltion. Of until a mlnned y .... 1 "IV" pori or thl targo I. laratld. the perlon In ch"O' 01 the '1.Imig.tion Ihallln.url tha', Qualified peraon ullng gOi or v._ delocllon .Qulpm.nll .... IP.C.llo. lumlg.lion I'.kage.II I •• kage 011111 lumlg.nlll delOCled.lhfo pe,"on In charge 011111 lumlg.11on Iha.l.k •• cllon to corrlct the ",kaO', Of Ihall inform 'hi mllte' of IhI vIIHI. or his rllKe.,nta­Ii ... of Ihl "a"age 10 thll cor'.ctive action can bI laker'l •

• , It the fum'Valion .. not comp'eted and thl ... 111 •••• '.d blfor. the ml"n" ve .. llit'YeI POrt. the .,.rson In Charge of the .. 11.11"'. (Inaur. ttllt 1) at "'It IwO NIOSH/MSHA .~.o .. d ""-conl.lned bf •• lhlng .P ..... lu. (SCBAI or cornbiflalion .1r·luppliedISCBA .. spI •• IOro; 2)_ g.1 or ....... d.locIlon_: .nd3'._QUaIiIledlnlh.if_ •• lion,boonbO .. d"" ...... clurlnglhl_ Uling 1111 ."",cpr"". g.1 dOiocUon oqulpmon~ rnonllor .... C .. odIK.nl 10 ... 11 containInG 'umlgat.d cargo .nd •• '.gutarty occupied "'" tor 1v"'.lnt ... kag •. M ... kag •• _. 5 _II delecl .... lh ..... 1_ 110 evacueled 01 •• poraon",l ".IMaled •• nd ecllon I.kan 10 corr.clllll "akage, 1101_ .-ntI "" .... 10 110 ,,,,",,,,,,11. Do noI.nl •• lumlgaled ....... alP!"""" -'1IIftC)' condillon.. If noc .... ry 10 ... Ior a lumlg.l.d ..... w'ar • NIOSHIMSHA awoved I •• -conl • ....., bro.lhIng • .,.,. .. IUlISCBAI or~11on __ ppIIodI SCIIA .. lpI,."" (po ........ prol.cllon 'Q_.I~ N .......... I-'!Ieled ..... lloftt. A, .... , one oth.r pa'aon. ., .. .,. pe'lona' protlCtlon ... u~ IhouId I .. '.

be avenabla 10 ... la' In el •• of In .,.,Iroancy. .' : .~;: t:~ ': .• ~

" nee.allty to .n'" "0'" pt'iof to dllc .... 'OI. 'Iat apace. dlrecllr ebcwe cargo \' ,:. " . • Uffec.lorlumlganlconc.nl •• Uon,UIIr.g.PP'"",lel.g.ldoI_ancI_I·.:,'·' .' prol.CIIon oqul_nl. Do not ... 1 .. wIIhoul .. splrelory prolocllort. _ •• Iumlgallonconc.nl •• IIonII .... lorbolowe-. •• _led"' ......... doI_ •

.. Io.T.b .. lorllllor.pocll1c:cornrnodlll ....... oI.ppllcallonancl._.I_

Page lY:-::..

(

Methyl Bromide 98% Column 7

.... _.b '. d, N_locIo •• Includmo lO'>I,knoI'pp .• rylancliuhn.l'rfty/lncliua. . Xlphl".",.. C';co".moid ... • M ,..,.ryI.flChulo. " ..... _ fungI, ........ /'rthium. I/hi,octoni., Pttyropli,hote. ~nodi •• ,., S'~I'fJ,;um. Ann;I1",., ,net the clubfoot orgtnilm. PI.'modiop~.

w_ .nd ..... ...." ••• do, 10011 .• Iolon ••• nd bulbi '" b_dl.oI_.d •• nd Girl .... including Qu.d;r ..... nnuel blu.g,. ... brootn,.pe. common 18mb.· QUIll .... loopo<Iog ..... nd blrmudog ..... Nol .!llClMI .g.iNt _11ow. dodd ... -:=, .... ·11_.~ . 1M lorn. Ipt:C'" oJ clov.r. .; ", :1. -: .' .' _ "_00II nt ... ,._of __ ........... :_eJun. booll.

. ,-··-···~··t··:, .. ···j, .. ···· . laM •• wh". grub.,.nd v,teSln .ymphylln. :: : ... .;.Ii,.:.";.~~ .. ,~ ... ~·r~f ... ~ .

. ." ~":~. ":,': . ,. .

PAETI'EATMENT SOIL ""EPARATION : .. Plow Of rip lho 10illO Ihl ~pIh 10 which .!locI'" \/tI.",,"'" il rwquired. The eoU.lIould be _ad until , ... 01 clod. Of "'rvllumpe. IIlIid ... !ram pwioua ClOp •• houId bo _ad inlO lho .oiI 10 .11ow I .... docompolilion prior 10 fum;g.lion. Soil moio ...... houfd bo optimum 10/ .. ad gormi"'lion. eo ... . I ........ oil. Cln bo fumigat.d with h;glllt moil ..... ,onIOn!!"'" r ... I ....... d .oill. Fo. bl.! ... ullI. .oil ohould bo k.pl moill 1:If II ..... lour days prior 10 1 .... _" .. Do not fIHnloll. K tho .oil 1t<npeI1i\urti il bllow 5O"F; For boll ••• ullI. Iumig ... whon .oil lempo ....... il 5O"F. II Ih. d.pIh '" e inch .. ,

Non: r umigllion rnoy IImporari1y .oduc. hitril"OC:llion in tho ooil lhul inc .... ing ..... 1. 01 .rnmonium nk"'ll'" and oolub" aminOftium .. III 10 pOto ... ill:y phytotoxic _I .. Ac<.vmuillion '" _ium it moot 1iIt.1y 10 occur whon mo ......... ,.1 .. '" bnig."1 and I.ililizor .... oppiiod 10 ooi .. Ihll a .. Kidic. _ .. cold. or high in org",ic moner. AwIy 0IIIy 11ftiGJ .. canlalninv II I .... ~ Nt .... until \he COOp II _II .Itablilhod and aoiI I""""" ....... • 1ioIro 6S·F.1hIn IIf1iIj.a .. indicalad by aoiIl"~ To otImuIate nlbtriCItion atld 10 radvc. _ibIo ,,,,,,,,,,,,,,", _icity. IC~ ...o,·t'-Id. be IWnad bof_ fumlgllion. . .:'.!: 1.'.:~~J~h'"'d:~' ~ " .' , '.:. .r··~~·~~lf~.1· .

FIELD FUMIGATION . . .. \ '7.1':::·" . ~Ot -.II .pp\iCltiOft of Mil"" 8rorIlido 91" injOCl'" potIdvct WidI. chi .. 1 twPI oppIicolOf ..... '" lho chio ... lpoeod no mote \he .. 12 IMho, aporI .nd injecting lho r..m;g'''11O • d."", '" ... ItIc .... be ..... tho IoU .... IC .. The aoiI ."".e. _11 bo c_rwd ...... 1M .. " .It., tr .. """,1 wlih """""'- r~m

Ioyfng ",.Ip""'1 Ot by '"1itIg with ........ 0/ cuhipockor.nd c_rwd within 2<! _II willi poI)oetltrlonl film or Olher oultoble c_:· Co-.It Table 1110/ . _ .... "'"POfIcllion. For _ applic.tIorw .... tho __ .... "'application • per OCII H _ .. ed .. T.bIe t. Tho octuaI_· .... per __ -", •

.. .~. ·~;;Ii· " . wil bo _1onoI1o \he - .... \/tI.Ied. •..•. '-: ;{"~: 'Po;.; '., ~: '.' .

page l~ ...

(

(

Methyl Bromide 98% \ Column 8

IIAIIED TAIIP FUMIGATlON METHOD ., ···T."'r.~-:-;··' : .. :--. 11' 5-, "'" c.nlt, of the c ..... ,o ~ 'de ....... OIl cIOme. InIIIled pI"'Ic"~: bogt. crumpled IoniU ... bego, burIop bool _!ted bo.k.lI. IIowerpota or boIIf ... ""~'!:I' euppotl .." ." , ~

Ev'~ling PO"' ....... ndellot IN wletilizotlon 1ft!! uniform d~po .. ion fumtgont. Shollow pono-or bo ......... do of pI .. tIe or tin ..... ,io!Ktory for tNI.1 .. . ·,.. ...... ::.w· .• '. ., purpoe.. : :.' ,"- ~,,",~~~ .... ' . -: ,' .. ": 1. U .. _ ",pc ~Ior pon 'or .ech 300 to .. 00 _ 'H' of ..... 2. Anchor 0'" .nd of .och poIywlhyleno ...... Into an _1IOf8IIng pon with .

IOpo or. '''lOblt -iOht. ThIo '"'_ thaI tile Ilquidwill be cIirKIod Into 'he. • • ", ... :.: ..... ,,-if .alf'\"';~~~ .. ,;;t-, . ,;

wv.por.ung pen. .:. ..-:::-;!" 1.·:':ff"=1~~ ... " .- ~

3. &land "'" I •••• ndo of tho polyethylene ...... OUIIide·of.tho .... to u.~ cowNd. ' "~.' :}'-~ • .' .. <l8:.;'!~ ... ~~~~ ~-.' .• :

... All., "'" .up_ .nd tubing ... In pIac .......... .". .... to be fu' ~

with I OIl""",, c_ of poIywtltyteno Of coated fIbrIC 1iIrn" •... 5. 5 ... "" _ide edgel with 0 ~ 1~ Inc ....... of ~l=~g'.~ ~ ~:, ... WI'll not pull _.. ,. "" :t·~;:'f ." .. '1':...:' .:'

O. AlIOch. polyethylene lube 10 the cyllnde, ...... oudot··and op.,,:.UI •• :; u:fh· ..... ···· •.. ~

cylinder dio_ or ... 11 to .... .., ..... lllmoUIIII. ... ·'.r:: ... :. .'., :." HOT GAS METHOD . ,. ,'.':' :,.; ~'~;/i.w~{:::":' "f

The -hoi OIl .... !hod" C""".IO of Uling I ~Iy monufactt;rod hall lachangar. or • c_ 1 coil !mma.-od In I ....... -!t:tInv' hoi _lOr. 10 VlpoNe the fumigant beforw " •• ,,,,",cliol'i." : :';':-'~~'~,~;~. t~-: nit .... thod "'" be .. ""' ....... 1Itge ._11 of~' IN ,.quirod.nd -Loll .• ; .... ·.:1":.,-··_ .. ·$-'·L· . . ~ wporiuUon II edtM\tlglDI& : .: !·? .. 'i-:::'·;r~·~4!·' ...

. • : ~_." 'C.\- " •• ".. •• ~

DOSAGE '; .'. U .. _ to ___ of MethvI .......,.,. 1ft .... 100 1qUI" 1 .. , lot .n •• ' ... _ of 24 ........... hen II1II ......... _. 00"1'. or hIghef. Me'IIyI

........... ,.. .. _ ... tOIl to the cIIpth k hal ...... pIowIlI Of ripped. When Il0l ........ _. be_ &O'F.andOO'F.lJIIIndthe. " ... *"'to"l ......... Do ftCII _!"*' IlOl _ope_ .

Page 15/_

•

•

(

(

. ' .. , ~ ..

Methyl Bromide 98% ~ . Column 8

• ·.-.·.-., .. -;"I'''IIr.''~·~~~'''-I·~ •. _; )' .... "'21"S:~1 •.. ". .." . ',~ .•• :- .... f"!" ... ~ ~:.: .. , . "J "f l'

A. TR£llm FUMIOAl1ON DlRECT1ON8 (Few U .. In Aotfda Only) , .. ~ or .. pie", "'mlg.don 01 citJu. 00II for control 0I1'ttytop/1f1l« Ind . citJuo ... ..,.tod .. 1n F10ride IOncty lGiIa. 'Tr ... whlcl .... planteelln "'II .. .,eeI .on will nol boor hoMlllblo INk for. porleY' :.r.I ..... 24 montho. Apply with cilia'" lpoceell2 inc"'" IpIII 10' cIopth of '10 I ........ Seal """Ig'"t with • drog or cvltipock .. "'-owino mmediltotv behind cllia.IL.;AppIy MllhlI aror,.'Je!ln It tho .... of 1 pound pI<'OO oquaN fMt.',ImmodIo .. 1y ~ willi • 4 Mil", Ind "_. 10 fllmlgolion· for II hourL~'ThII irootmonl will conllOl d"1I •••• to. cIopth of 4 fMt. Ro_ COWl Ind _ 2.-'<1 bof_

, , if,'·'·· ''' .. ~ •• ' ~1'1'\J"' . •• tIing _pi .... In _leeI ..... ':, ~"., :,'.~' .. "~~1l ~;'t'~"·' : . ~::·,_ .. ~;~:··.~·;~t~~ '~\' '~'.~' _~ .. '~ . ~

.. SPECIAL INSTRUcnGNS FOR neE CON1'ROL OF ARMILlARIA MELLEA (OAK ROOT FUNGUS) ON DEClDU~~)!,!,U~ AND NUTS. CrrRUS AND VINEYARDS _ .",.';-.' . ,. ""~,~;,, .. ~' .

. - ) .. ;.~ ..• :~~/.~:.: "".cab"'" SaIl Ptwpendoft ", . To obIIin \hi mellimum conlrol oIA1mi".ti. moIIo. with Methyl 1_ ""­.oiI musl bo cloy 10. cIoplh ~ .... -..L ThII.,." bo ICCompiiohle' by.., pIontino aud.no .... In \hi oprIng. InIgeting lint. \hi .... hi. HllblilhId Ito ........ wiIh/IoIding fuothlt IIrIgotlon: til N\InIIf • ..., olIowIne pIonli 10 _ """-1r.IgaIIon. When 00111 cloy. cut ..... _ --. pIenta.nd '-'1IIp MIl to. dIpth 01 H ............. dIec to emoothMI .. ;'

. :",! :~~~?:~::" .

(

(

. Methyl Bromide 981 l Column 9

'. DOSAGE AND METHOD OF APPUCAnON

TlIio io • ptep".' or .. pIo., , ... _l Ctopo which ......... ,~ in Ihio , .... ~

......... "'" bell """, ... '. Jill",. poriocI 01., IoHl24.rnonthL Me'_ ' . '.':. i"I~""'''' ,.' .

end ,.t, of .pplellion~. 411 foIIowa: • .~: . I. Non·"111 Chi ... "ppl;e .. ion (no, lor us. in C.lilomio). M •• 'hi .oiI hat

b ... P'operty p'opa.od. injoc.~OO·870 poundl aI M.1hyI B<omi'" 9ex par .... by .hi •• 1 .ppI;e.,ion with .hi .... spoc.d up .0 &e inch .. Ip." '0 • dep.h of 2.· 30 inohe •. In.ho row .ViPo .... tm.n .. .....;~. ma'" by using. . .inglo ." •• k. Chisol •• hould h ...... wing w.lded on tho .... k 2"-,_ : the chemic.1 Dutl"to p."illty tRlk,1M chit" ma,.(To fill "in th' chi"' : mlr\ .nd le.1 the sUrfIC'. disc .nd ringroll invnedi'I~!, aft~, fumig.nt~ injection. B, Iur. ,h •• thl dilc .nd ringroller.cCMlr:,t" .re. lutricitnt)y. wyond thl chisillinel to ,ffeet. good "IL"V4~:.!~~~"::-··~'·4·· ~

2. T.'P ChiNI '-'ppliulion. AfIe, lh, loil hu btln prope..., prepe,.d •• ppty .

• 00-870 poundo of "'mig •• , por It .. by chi .... SPIC'" up '0 ee inchl •• : .port. •• described .boII •• _ .""". with adequo" poay.thvton. film ... l .

3. Doep Injec,ion .-..g .. ·Proba Tre.tment. U •• on. pound 01 M.1hyI Bromide' 9'"' in ligh' .oil. ( .... 0 pounds in fi .... ",., .... d .... ,.).0 .. cIopth 0138 inch ... Of mot, below the soa surltee. ABu""," one in;.ction lite per 100 tJqUI'" I

I .. , (on I 10 It. x 10 It. grid ",n.m)

'''' to be ""'Ied. >:-;j.:~~~\~'.: :~.~'a:~~~~ .... 1.:".: ., •••. . . . ,. : -

EXPOSURE ANO AERAnON PERIOD . ,. To in,ur. lhe proper timtl~onc.ntralion reretionahip to control 01" root

fungus lor.hi"'lpplic .. ",no- _ ............ nd •• _n cloy •• poau .. poriod btl", ... ...,..;ng ,he poty.thyt ... film CCMlr •• nd •. _ cloy intl",,1 with Deep Injec.ion Auger· Probe T ........ '" lit. which plenling or .. pa.ming 01 , ..... vine .... o,he, "'.p-_,.d.""", ""y begin 14 dIyto ""r.

2. M .. hyI Irorniclo 9" wi. noC USUlily ~on,"" wood ... '" und .. vary dry ._'ionl. H-, •• ome con"'" may be _~;;""·· __ t~ • PIN~".uch •• mo"*~~r(b~MM'~I~~~~~'~~~~~~~~NL

... ...., .'''' .. ,", . '.'

C. NON-TARP NEMATODE CONTROL For controf 01 nematode. InctudIng ..... ...... .pp. cn.-........ ,.,.,...ttcIw.. and ,..,.1'fItNtc/IW an clec:ido'atli ...... _ •. c .... end Wini,.rd.. . '.:. : .. ~ .. :~~:~Ji.~~~.: .

. : ~ ~·~~.!fl,!l.l' ....... b"ent Sol .............. . . . .~~ ~ 1:.~

Plow. lip tho aoiIto tho "'''''' to wIIkh. __ ... _, ... --.s. The.oI .houIcI be _od until ... of c_ or ~ Iumpo _ PIIIduo fnm pte.I .... __ .houId be woo\ocI Into ...... to allow lor cIoc~1\Ioft polar to

furnIoaliDn. To Inaur. maximum 1umIgaftI ......... 1ian "" "'" ,he point of 1njectIon.-..,. ._in mote tho .. 1-1 ", ......... ".po,MII: ... an.oII typo. 1l0i ...... to ""- 'flllng.tho ..... NfIc:. may be ........ ~ by ....... of. Ip<InI:Iot oppIica'ion aI IHl Inch 01 __ prior to ,..... PN ..... tlon Ind .,p;u'lon.

F ..... ' ......................... ""_'-" ..... II Oh"e.,,· •• """'Plholl......... . ........ 10",. , .. :, .;.

..

Page 1 !/: '_

•

•

•

Methyl Bromide 98% • column 9 •

DooMtIe ..... ModlOlf of~_ .. -... ," ..

TNI •• powplonl Of ,eplonl "._n~ Do nol.ppIr 10 .oiI ..... '" _ Of ......

wi ...... _~ , ... 1 willlin 2. monUII. A waiting period of.I I ... , 14 doyI

.houId ... obs_ "',-en .pplicolion .IId pIIonU!'V. Method. Ind 1111 01 . ..~ ..•.. ~: ... ..,... -, .. ~lton .,. .. follows: ~ • .: ., ';;4 .' .

1. CII;s.1 Awlict.;"n. All" tho 1Oi1 .......... properly p.-pored ini«l400-S70 peur.dt at Mt'hyt 1Irom~ _ ~ •• ~ .. by ~hIs.I .pPlic.1ion "';11\ ~,",.I.

'plcltd up to 66 iMIte. 'pln 10 • deptll of I,';:'-! tnc .... ~ In the nHI.,,;p. '. "utmenu moy IHI mide by using. lingle .hlnk. •

To Ii. in.he chis.I ....... nd .... "'" """"' •• dioc: .ndringn>_ ~ _dit •• 1y .~., lurniU-nl injection. Be ..... tIIIi Ihi' di.c _ rinQroI1« . cow. on .... luffoci.nlly beyond "'" chit., ..... 10 .f!ecI • QOOCI H.L

Z. Deep Injection Aug., ... """ T ... _~ U •• _ ~ 0' Melhrl ~ . sex Po' injoe.ion Ii .. in 1ig/d .. 1Oi1o; two poundt in ~ tllIIIIIred "';/1. th. . _ injection IiI' po"CO_, .. I(on.l01t" IOltgridptltlm/with "'" . injecl"",in 11te •• n ... "'IIII .... IO ... _* TI!'!P'or~""lOiIot : "'" po;nt 01 injoelion. ., ; . '.' ~.' ::"!!' .• ~~~'?~';.. . '<i .. . .. ~. .' .. Methyl 8romCIt 98X ... Itd without ... rp wiII __ 1Iy conlrol_..-Itd : . • HdI. I4owewr. 10 .... control moy ..... Ned on dup ,,,,,,ltd -,",I :

.uch '" mon,; .. QuI...." (bioIdN"cI) .IId rhi2_ of lt1t"*,,oono": .,!"', '~"" '. ~;..}:6"-~~":-'Io _..: ,'-, ~ ;

D. POTTING MIX FUMIGATION DlRECT10NS ::,.!'1~~~~: ... :;. , POft" ....... ineluding dee_ltd eOtl\POllI. .oiI m ..... ,nd ......... un be fu!nIoIl." .. ;!h Metlltf 8ft>mid1 ~ F .... ~lion.hauId ..... !Me. ~ . Of In • _ .. "tlIIlld _. _ ""'" d.liroble "'""'" Of occuDiod buIIdinv" Tho .... _110 ... ","1011 s/IouId _ • '-lII"_ 01 et¥'F. Of ._. be ""'".Ind __ ' ......... fo<good_dpnnlnation. To Ins ..... good ... t .... the _11"-' 10 I doPIh of 18"-on I _1.'-0<011_ ~ ,,"-I _10 thta. f.lt high een.1to "'1re.1Id ", ... 11Ied JMHfOtlIIona ... modi In the pk """Ie. II _ fool Inf ....... 'o .nlll ... ".IrriooI.' Onel .... pH. .... bItII

""'."""'_10 1IoId"'_. , ........... .a.-..... ".. ........ '0 .Id '" _ .......... '" diIIuolon. PItce the -'I, of ... .,.,.. ....... ", ..... 1 1n_1Int_. __ IbOUI30f.II-' ........ IUIfac.:c-twhh. pot"." ...... """""' Of oIItIr III conr ....... _1IIaI·.,· .. ,....:' ...... , .. • hIe ....... a • ., ""' ..... by buIvIng. ._ .......... .".... ... ;.".", ..... '" W. __ of _.-..In-. ... fumIgant In .... ~1Ine" .... . liquid. by .... - of ... hoi til .... \hod. CorIIUII T ..... ta:;1I'!'t*'" .IId _ limo. Ae<ell for 24·72. houra ~ ~d~ , ............ " In .... "'"Y ..... lot n .. ed. AIrIngt" """'100M CIIoa-c_ .1Kb ... _ INn .... , ............. _ w NIl .. cfelCllbld ._,

In ......................... ::~:~:~':::~:::!.:~~:;:::: ,..,.. ., '" .... _ of l1li hoi ... _tIIod ... _ of . '"' Ut. _1njIc1ion po/nI for MC11IOCI eullII 4' ~ AetwtI for 24 ,.".. '.' '. " ' •. . ; .~:. : •. :..;,.:

•

l • I f

L ..

'Methyl Bromide 98% ~ Column 10 •

TAaLEI "" METHYl BROMIOE ... SOIL f!J1"'G."nc~jusE"s,i:;

TRIA TMENr 1m "

TUII . ."...,.. ............ ":I.:::~~ .... iftt .. ~ enota ft:::4J . . 0..__ " "":" .... fOOIIlWIPI 1"

T_ . '.:

SeH. '''''''' .... fftOII 'Ac4 . T_

' ...... -• III ................... _Ior_ .............. _ ... L •

•• 0... ........... , •• """ ..

••• T.,... 3; Salie ...

""

Page

...

~ .

•

•

Methyl Bromide 98%

w_ l.....-wl' ... -le_ ~ ... l~"';"f)

...........w ... --

.. .. e ....... -. ---.... , .... •

• Column 11

~""".df·"'" ...... -...ce ...... .-..cc. -....................... • ............ .,.,..,...,..ac.....,... Jr-.._

..... WJ. :.~.'

... • ..... be as

lOt _~pa.27' -..... ........ t.e4 .w __ ... n~.". __ "':~!.'!''!I

9-; eo '. :' ~: :' . '.'.\":.j'.'~ ]:1 . {

... '

• Page 20/2..'':'-

t

•

•

•

'Methyl Bromide 98% • Column 11 •

~ .. ':.' • Itr '

AERATION AND REENTRY lit tb • ..,d of tile _r. pedod, r_ .11 •• el. _ _n .11 doon .... ,,1,..,.,. thitt ar. optrational. Allow tor ca-plete venti­lation. u.. ventilation fana wh.,.ever poealbla to r..::IIVe tWIJ.gant f~ dead all' pocket ••

Afte,. r"~V-t1on. treated ar ... ..,.t be Hrated untU lht level or .. thyl bn:n1de h bel .... ~ _. Do not .11 ... entry into th. treoted area by 811., pe:raon before t.hl. tt.e unlo. provided wUh. reapl­ratorr p~tection device (SClY' or ca.blnetlon air-supplied SCBA).

Cert.tn .. terl.1. abeorb "-thy1 .~4e during fundgation. and de­aorbt Ion during •• ,.8t101'1 IMy call for utende4 ... 1toring and aeration period..

DRAEGER GAS DETECTOR,BENDIX GASTEOi DETECTOR

Hond "'"'" and Detector Tllbe: ... thyl 8n:n1de _y be detected at the 11'Irc.hold UA1t Value CT .L.V.) or 5 ppiI. DetectOR are available t~ Soil Choodeol. COrporotion.

HALIDE LAMP DETECTOR

Color of the n .. 1. an index or the concentration or Ptethyl 8rc::n1cSe present. 1be fo11owl,.g tabulated lntonMtlon provides an index of U .. color and concentration ot .... thyl eE'Clft1de preaent:

I'I:I1IYL BI\lJ'IlDE P.P.H

o 25 50

125 250 500 ~oo

1000

lJI/1000 (lJ. n. o 0.00625 0.0125 0.01l 0.0625 0.125 0.20 0.25

None Non. I1oderat. Creen Cr ..... Strong Creen Strong l1ue-Creen Fringe Strong Blue-Green 81 ...

• Night tt.. color 1. identical. but allowance ..... t be .. de lor the blulah c •• t of' the f1_ It •• 1f •

.. u.s. la"'P detKtOr' 1a eultabl. tor locating l.ake an4 tor deter­aining e.'III~<ent or aecation down to .~tely 50 ppiI. It 1. not aultable ·01' clearing a etructure tor reentry •

Page 21/-:':.-

Methyl Bromide 98% l Column 12 Page 2~

WARRANTY