unit 2: nomenclature, intermolecular forces and properties of solutions
DESCRIPTION
Unit 2: Nomenclature, Intermolecular Forces and Properties of Solutions. Nomenclature Intermolecular Forces Phase Changes and Phase Diagrams Saturated Solutions Solubility Concentration Units Colligative Properties. Nomenclature. - PowerPoint PPT PresentationTRANSCRIPT
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Unit 2: Nomenclature, Intermolecular Forces and Properties of Solutions
Nomenclature Intermolecular Forces Phase Changes and Phase
Diagrams Saturated Solutions Solubility Concentration Units Colligative Properties
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Nomenclature You are responsible for reviewing the
conventions for naming and writing formulas for ionic compounds, binary molecular compounds, and acids that were presented in Chem I.
This material will not be covered in lecture but will represent about 20% of the Unit 2 Exam.
You will be responsible for ionic compounds that contain any of the ions given in the Ion Chart handout.
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Nomenclature Resources for reviewing nomenclature:
Chapter 2 of your text
Nomenclature slides on KMB’s website under Unit 2 Powerpoint lectures.
Ion chart handout
General Chemistry Tutorial for naming and writing formulas for ionic compounds on KMB’s website.
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Intermolecular Forces
The fundamental difference between states of matter is the distance between particles.
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Intermolecular Forces
The solid and liquid states are referred to as condensed phases because the particles are closer together.
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Intermolecular forces The physical state of a substance at a
particular temperature and pressure depends on two antagonistic entities:
The kinetic energy of the particles
The strength of the intermolecular forces between the particles the attractive forces between particles in a
solid, liquid, or gas
Converting from one physical state to another requires the molecules to gain enough kinetic energy to overcome the intermolecular forces
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Intermolecular Forces
Intermolecular forces are not nearly as strong as the intramolecular attractions (ionic or covalent bonds) that hold compounds together.
Intermolecular forces, however, have a significant impact on the physical properties of compounds: boiling point melting point vapor pressure solubility
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Intermolecular Forces
There are four types of intermolecular forces: Dipole-dipole interactions (forces)
polar molecules London dispersion forces
all molecules Hydrogen bonding
molecules with H-F, O-H, or N-H bonds
Ion-dipole forces An ion and a polar molecule
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Intermolecular Forces
Polar Molecules contain polar covalent bonds which
are asymmetrically distributed within the moleculecontain a “positive” end and a “negative”end
Examples:HClH2OCH3OH
-+
OH H
-
+ +
OHC
H
H H
-
++
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Intermolecular Forces
To determine if a molecule is polar, identify all polar covalent bonds:
0 polar covalent bonds = nonpolar molecule
1 polar covalent bond = polar molecule
>2 polar covalent bonds = polar or nonpolar
Must use the electron domain geometry to determine polarity
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Intermolecular Forces
If a molecule has two or more polar covalent bonds, it may be either a polar or nonpolar molecule: Draw the molecule in 3 dimensions
using its electron domain geometry
Draw the bond dipole moments for the polar covalent bonds
Nonpolar if they are symmetrical or offset each other
Polar if they are asymmetrically arranged
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Intermolecular Forces
Example: Identify each of the following molecules as a polar or nonpolar molecule.
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Intermolecular Forces
Example: Which of the following molecules are polar: CHCl3, CO2, Br2, HF, CH3OH, CH3OCH3?
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Intermolecular Forces
Polar molecules have large dipole moments A measure of the separation
between the positive and negative charges in polar molecules.
+ -
H – F
+ -
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Intermolecular Forces Dipole-dipole interactions (forces) are
found between polar molecules. attractive intermolecular forces
resulting from the attraction of the positive and negative ends of the dipole moments of polar molecules
The most stable arrangement of polar molecules is the one in which the positive end of one molecule is oriented toward the negative end of the other molecule.
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Intermolecular Forces
For example, molecules of CH3Cl are held together by dipole-dipole interactions:
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Intermolecular Forces
When a liquid vaporizes, the intermolecular forces must be overcome. As polarity increases, the strength of
the dipole-dipole interactions increase.Large Hvap
High BP
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Intermolecular Forces
London dispersion forces are present in ALL molecules. Temporary dipole moments lasting
for fractions of a second are induced in one molecule by other nearby moleculeselectrons in molecules are displaced from symmetrical arrangement
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Intermolecular Forces
London dispersion forces require close surface contact between two (or more) molecules. The strength of the London
dispersion forces is roughly proportional to surface area.As surface area increases, LDF increase and BP increases
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Intermolecular Forces
For molecules with similar molecular formulas: Long, skinny (unbranched)
molecules have greater surface areahigher BP
Shorter, branched molecules are more spherical and have less surface arealower BP
C C
H
H
H
H
H
C
H
H
C
H
H
C
H
H
H
CH3C
CH3
CH3
CH3
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Intermolecular Forces
The strength of dispersion forces tends to increase with increasing molecular weight. Larger atoms have larger electron
clouds, which are easier to polarize.
In general, as MW increases, BP increases.
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Intermolecular Forces
Although BP tends to increase with increasing MW, there are some exceptions.
Why is the BP of water so much higher than expected?
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Intermolecular Forces
Compounds containing H-F, O-H, and/or N-H bonds exhibit hydrogen bonding: a strong dipole-dipole interaction
between a hydrogen atom that is covalently bonded to either O, N, or F and a lone pair of electrons on a different O, N, or F atom
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Intermolecular Forces
Due to the large difference in electronegativity, O-H, N-H, and F-H bonds are highly polar H has a partial positive charge in
such bonds
The H atom is strongly attracted to the nonbonding electrons on other N, O or F atoms.
O - H N - H- +-+
F - H +-
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Intermolecular Forces
Example: Which of the following compounds can form hydrogen bonds with another molecule of the same substance?
C C
H
H
H
H
H
N
H
C
H
H
C
H
H
H
C C
H
H
H
H
H
C
H
C
H
H
C
H
F
H
H
C C
H
H
H
H
H
O C
H
H
C
H
H
H
C C
H
H
H
H
H
C
H
C
H
H
C
H
OH
H
H
C C
H
H
H
H
H
N
CH3
C
H
H
H
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Intermolecular Forces Impact of hydrogen bonding
on BP: Hydrogen bonding leads to
higher BPH2O forms H-bondsH2S, etc cannot form H-bonds
As the number of hydrogens capable of forming hydrogen bonds increases, the boiling point increases.
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Intermolecular Forces Impact of hydrogen bonding on BP:
Due to greater differences in electronegativity, OH forms stronger hydrogen bonds than NH
Compounds with OH have higher BP’s than similar compounds with NH
CH3CH2CH2CH2NH2
BP = 77-78oC
CH3CH2CH2CH2OH
BP = 117-118oC
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Intermolecular Forces
Example: Consider each pair of compounds separately. Which compound in each pair has the higher BP? Explain why.
C C
H
H
H
H
H
O C
H
H
C
H
H
HC
H
H
C
H
C
H
H
C
H
OH
H
H
H vs.
CH3CCH3
O
vs. CH3CCH3
CH3
H
HOCH2CH2OH vs. CH3CH2OH
CH3CH2CH2CH2CH3 vs. CH4
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Intermolecular Forces and Solubility
Intermolecular forces also determine the solubility of organic compounds. “Like dissolves like”
polar compounds dissolve in polar solvents
nonpolar compounds dissolve in nonpolar solvents
Ionic compounds generally dissolve readily in water because water hydrates or solvates the individual ions
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Intermolecular Forces and Solubility
Ionic compounds tend to dissolve in polar solvents like water because of ion-dipole forces attractive force between an ion and
the partially “charged” end of a polar molecule.
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Intermolecular Forces and Solubility
An aqueous solution of an ionic compound such as NaCl contains solvated cations and anions:
- +
Solvation of anion
Solvation of cation
Examples of ion-dipole forces
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Intermolecular Forces and Solubility
Polar compounds dissolve in polar solvents due to: dipole-dipole interactions H-bonding
Hydrogen bonding between methyl amine and water. H
H
N
OH
HCH3
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Intermolecular Forces and Solubility
Nonpolar compounds do not dissolve appreciably in water because they cannot break the hydrogen-bonding network that exists.
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Intermolecular Forces and Solubility
Example: Will each of the following vitamins be water soluble or fat soluble?
O
OHO
HO
CH2OHHO
O
OH
CH3H3C
H3C
H3C
CH3 CH3 CH3