unit vi: chemical reactions i.5. types of chemical reactions

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Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

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Page 1: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Unit VI: CHEMICAL REACTIONS

I.5. Types Of Chemical Reactions

Page 2: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Types of Reactions

1. Synthesis2. Decomposition3. Single Replacement4. Double Replacement

Neutralization (Water Forming)

5. Combustion1. Combustion of hydrocarbons2. Combustion of metals

Page 3: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

Two or more substances combine to form a compound

A + B → AB

Page 4: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

Page 5: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

Often: elements a compound

2Al + 3F2 2AlF3

Page 6: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

Examples 2H2 + O2 → 2H2O

2Mg + O2 → 2MgO

CaO + CO2 → CaCO3

Page 7: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

potassium + oxygen

calcium + phosphorous

Page 8: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

A special type of synthesis

CoCl2 + 6H2O CoCl2● 6H2O

Page 9: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis

A compound + an element a “bigger” compound

2SO2 + O2 2SO3

Page 10: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Synthesis - Overview

Always more more than 1 reactantthan 1 reactant

Usually forms only 1 productonly 1 product

Page 11: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

One substance breaks down into more than one substance

AB → A + B

Page 12: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

Page 13: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

EXAMPLES: 2HgO → 2Hg + O2

2H2O → 2H2 + O2

MgCl2→ Mg + Cl2

Page 14: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

Note: Unless otherwise told, break all compounds COMPLETELY down to its elements. (Even break up PAIs)

Page 15: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

Note: Unless otherwise told, break all compounds COMPLETELY down to its elements. (Even break up PAIs)

Page 16: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

Note: Unless otherwise told, break all compounds COMPLETELY down to its elements. (Even break up PAIs)

Page 17: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

A special type of decomposition

CuSO4● 5H2O CuSO4 + 6H2O

Page 18: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Decomposition

AlsoA Bigger Compound Smaller Compound + An Element

2KClO3 2KCl + 3O2

Page 19: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

One substance replaces another in a compound Metals replace metals Non-metals replace non-metals

AB + C → A + BC

Page 20: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Page 21: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Two Types1. Metal Single Replacement

2. Non-metal Single Replacement

Page 22: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Examples of Metal SR

Zn + CuSO4 → Cu + ZnSO4

Fe + 3AgNO3 → 3Ag + Fe(NO3)3

Page 23: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Metal SRs

Page 24: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Metal SRs

Page 25: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Some Non-Metal SRs

Page 26: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

Some Non-Metal SRs

Page 27: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Single Replacement

The catch some elements are not strong enough to replace others

Plan:1. Predict Products2. Fix Formulas3. Balance Equation4. Determine from Activity Series if

Reaction will Proceed

Page 28: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions
Page 29: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions
Page 30: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Both compounds change partners

Again refer to the activity series to see if reaction will proceed

AB + CD → AD + BC

Page 31: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Page 32: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Refer to the activity series to determine the relative reactivity of elements. For example, calcium is more reactive than hydrogen; therefore, calcium can replace hydrogen in a reaction.

Ca(s) + 2 HOH(l) Ca(OH)2(s) + H2(g)

Page 33: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions
Page 34: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Examples: 2KI(aq) + Pb(NO3)2(aq) → 2KNO3(aq) + PbI(s)

AgNO3 + KCl → AgCl(s) + KNO3

Page 35: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Page 36: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Page 37: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Double Replacement

Page 38: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Neutralization

Sub-type of Double Replacement Reaction

Sometimes called water forming

ACID + BASE → WATER + SALT

Page 39: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Neutralization

Page 40: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Neutralization

Page 41: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion (aka Burning Stuff)

Substance reacts with oxygen (fast enough to produce heat and light)

Two Types of Combustion1. Combustion of hydrocarbons

2. Combustion of metals

Page 42: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

Hydrocarbons NOTE: O2 is ALWAYS A REACTANTALWAYS A REACTANT! When burning hydrocarbons ASSUMEASSUME

the products are

CO2 + H2O

Page 43: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

CxHy + O2 → CO2 + H2O

Page 44: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

Page 45: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

Page 46: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

Combustion of Metals = Synthesis

Page 47: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

Combustion of Metals = Synthesis

Page 48: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Combustion

Combustion of Metals = Synthesis

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Assignments

Do Problem Set #3 and #4 on page in your Student Workbook

Do Exercises 65 (a, c, e), 66 (b, d, f, h, j, l, n, p, r, t, v, x), 67 (a, c, e, h, j, l, n, p, r) on page 118 [Hebden]

Do Hand-In Assignment # 8

Page 50: Unit VI: CHEMICAL REACTIONS I.5. Types Of Chemical Reactions

Lab

Do Experiment 5C – page 71-73[Heath] This experiment will take most of the

class your pre-lab must be complete beforebefore the lab begins

Fill in the Blank Lab Format you are only responsible for the questions asked in the lab handout