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UNIVERSIDAD DEL TURABO Using Existing Data to Study the Effects of the Trade Winds and Aquifer Vulnerability in Puerto Rico By Ronald T. Richards DISSERTATION Submitted to the School of Natural Science and Technology of the Universidad del Turabo in partial fulfillment of the requirements for the degree of Doctor of Philosophy In Environmental Sciences Management Option Gurabo, Puerto Rico April, 2016

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UNIVERSIDAD DEL TURABO

Using Existing Data to Study the Effects of the Trade Winds and Aquifer

Vulnerability in Puerto Rico

By

Ronald T. Richards

DISSERTATION

Submitted to the School of Natural Science and Technology of the Universidad del Turabo

in partial fulfillment of the requirements for the degree of Doctor of Philosophy

In Environmental Sciences

Management Option

Gurabo, Puerto Rico

April, 2016

UNIVERSIDAD DEL TURABO

CERTIFICATE OF APPROVAL OF DISSERTATION

This dissertation presented by Ronald T. Richards was revised and approved by the

members of the Dissertation Committee. The form certifying Fulfillment of Academic

Requirements for the Doctorate, signed by the members of the committee, has been

filed with the Registrar and with the Center for Doctoral Studies of the Universidad del

Turabo.

MEMBERS OF THE DISSERTATION COMMITTEE

Anastacio Emiliano-Sosa, PhD.

Professor Universidad del Turabo

Chair Dissertation Committee

Teresa Lipsett-Ruiz, PhD.

Dean, Universidad del Turabo

Member

Eddie Laboy-Nieves, PhD.

Professor Universidad del Turabo

Member

Rafael Méndez Tejeda, PhD.

Professor, University of Puerto Rico Campus of Carolina

Member

Jorge R. Ortiz-Zayas, PhD.

Professor, University of Puerto Rico, Río Piedras

Member

©Copyright, 2016

Ronald T. Richards, All Rights Reserved.

iv

Dedication

This dissertation is dedicated to my parents James E. Richards Jr. and

Sherley Richards who instilled in me a love for science.

v

Ronald T. Richards

Curriculum Vitae

Education

BS in Physics from Lewis and Clark College, Portland, Oregon, 1976.

MS in Physics from University of Puerto Rico at Río Piedras, 2003. Thesis: The

barometric efficiency of observation wells in Puerto Rico and the US Virgin

Islands.

Teaching Experience: Physics, Chemistry, Environmental Science, and English

Universidad del Este, Carolina, Puerto Rico, 2015 to 2016.

University of Puerto Rico in Humacao, 2008 to 2010 and 2015.

University of Puerto Rico at Río Piedras, 2009 to 2010.

Edic College in Caguas, 2014

Department of Education

Alejandro Tapia y Rivera Intermediate School, Trujillo Alto, 2015.

Amalia Marín High School, San Juan, 2014.

Benjamin Harrison Vocational School, Cayey, 2011 to 2012.

St. Johns School, San Juan, 1987 to 1988.

Field Experience: Hydrologic Technician

US Geological Survey Florida Caribbean Water Science Center 1988 to 2008 (retired).

vi

Table of Contents

Page

List of Tables ..............................................................................................viii

List of Figures ............................................................................................ix

List of Appendix ..........................................................................................xi

Abstract .....................................................................................................xii

Resumen (in Spanish) ................................................................................xiv

Chapter One. Overall Introduction ..........................................................1

Literature Cited ...............................................................................20

Chapter Two. The Effects of the Trade Winds on the Distribution of

Relative Humidity and the Diurnal Air Temperature Cycle

on Oceanic Tropical Islands .............................................24

Abstract .........................................................................................24

Introduction .....................................................................................24

Materials and Methods ....................................................................29

Results .........................................................................................31

Discussion ......................................................................................33

Conclusion ......................................................................................37

Acknowledgements .........................................................................37

Literature Cited ...............................................................................37

Chapter Three. Using the correlation between ground-water levels and

temperature to study aquifer vulnerability in Puerto Rico ..41

Abstract ..........................................................................................41

Introduction .....................................................................................41

vii

Materials and Methods ....................................................................51

Results ............................................................................................54

Discussion……………………………………………………………….57

Conclusion ......................................................................................64

Literature Cited ...............................................................................65

Chapter Four. Overall Conclusions ..........................................................74

Literature Cited ...............................................................................74

viii

List of Tables

page

Table 1.1 The five wettest years in the San Juan metropolitan

area, Saint Thomas, and Saint Croix ...................................3

Table 2.1 Results of assaying the hypotheses on oceanic

tropical Islands ....................................................................32

ix

List of Figures

Page

Figure 1.1. Map of average annual rainfall in Puerto Rico and

the United States Virgin Islands from 1981 to 2010 .............4

Figure 1.2. Average global daily rainfall versus latitude .........................6

Figure 1.3. The Köppen climate classification system in Puerto Rico ....8

Figure 1.4. Average monthly distribution of rainfall in Puerto Rico ........9

Figure 1.5. Stations with maximum average rainfall in May ...................11

Figure 1.6. Monthly distribution of rainfall from 1981 to 2010 at

Hacienda Constanza, Mayagüez .........................................12

Figure 1.7. Distribution of the wettest and driest months in

Puerto Rico .........................................................................13

Figure 1.8. Wet and dry years in Puerto Rico from 1953 to 2012...........14

Figure 1.9. Discharge on Río Grande de Manatí from

November 21st to 25th, 2013 ................................................15

Figure 2.1 Locations of the oceanic tropical islands used in

this study .............................................................................30

Figure 2.2 Hypothesis #1--Average relative humidity versus longitude

for Hispaniola ......................................................................33

x

Figure 2.3 Hypothesis #2--Average monthly air temperature cycle

versus longitude for Hispaniola and Puerto Rico ......... 34

Figure 2.4 Hypothesis #2--Average monthly air temperature

cycle versus longitude for four Hawaiian Islands ......... 35

Figure 3.1. Location of the observation wells used in this study

and a geologic map of the North Coast Limestone ...... 48

Figure 3.2. Hourly water level and water temperature of the

JBNERR East 1, Salinas observation well ................... 56

Figure 3.3. Hourly water levels and temperature of the Cbgar,

Quebradillas observation well ...................................... 57

Figure 3.4. Distribution of the Pearson correlation coefficients

between the depth-to-water and the water

temperature .................................................................. 58

Figure 3.5. Hourly water levels and water temperature for the

Maguayo 2, Dorado observation well ........................... 59

Figure 3.6. Hourly water levels and temperature for the

Tortuguero 3, Vega Baja observation well ................... 60

Figure 3.7. Cbgar Well on July 14th, 2006 at 0200 ......................... 63

xi

List of Appendix

Appendix 1 Data about the Observations Wells used in the

Study of Aquifer Vulnerability ...............................................79

xii

Abstract

RONALD T. RICHARDS (PhD, Environmental Science)

Using Existing Data to Study the Effects of the Trade Winds and Aquifer Vulnerability in

Puerto Rico (April, 2016)

Abstract of a doctoral dissertation at the Universidad del Turabo. Dissertation supervised by Dr. Anastacio Emiliano

No. of pages in text 74

This goal of this dissertation is to improve the science that is used to manage

water and other natural resources in Puerto Rico. The theme of the first article is that on

many oceanic tropical islands the trade winds blow from the east, as air moves to the

west it loses moisture to rain and becomes drier. Two hypotheses were proposed,

compared to the east of the island, the west is less humid and has a larger diurnal air

temperature cycle. Using data on the Internet, the two hypotheses were assayed seven

times with data from six islands in the Caribbean and the Pacific. The first hypothesis

was tested only in Hispaniola and is valid. The second hypothesis is valid on four out of

six islands. The probability that would occur by chance is six in a million trials.

For the second article, hourly data for 12 to 18 months from 33 observation wells

were used to study the correlation between depth-to-water and temperature in Puerto

Rico. Often rain is colder than ambient conditions. If the rain reaches the observation

well quickly then there will be a correlation between depth-to-water and temperature. If

the water movement is slow, then the water level will rise independently of the

temperature. The hypothesis is that the upper unit of the karst North Coast Limestone

aquifer will on average have a higher Pearson correlation coefficient between depth-to-

xiii

water and temperature than the non-karst South Coastal Plain aquifer. The hypothesis

was not significant. In the karst aquifer, the average Pearson correlation coefficient

between depth-to-water and temperature is 0.29 with a standard deviation of 0.62. In the

non-karst aquifer the average Pearson correlation coefficient is 0.01 with a standard

deviation of 0.50. The p-value is 0.25, the intra-aquifer variability is large enough that the

results are not significant. Two areas in the karst aquifer are at the highest risk from

surficial contaminants. One area is the adjoining municipalities of Quebradillas and

Camuy and the other is in the adjoining municipalities of Manatí and Vega Baja.

xiv

RONALD T. RICHARDS (PhD en Ciencias Ambientales)

El uso de datos existentes para estudiar los efectos de los vientos alisios y la

vulnerabilidad de los acuíferos en Puerto Rico

(abril/2016)

Resumen de una disertación doctoral en la Universidad del Turabo.

Disertación Supervisada por el profesor Dr Anastacio Emiliano.

Núm. de páginas en el texto 74

El propósito de esta disertación es contribuir científicamente a las estrategias de

manejo del agua y otros recursos naturales en Puerto Rico. Este trabajo ha sido

seccionada en dos artículos, el primero de ellos trata sobre el hecho de que en muchas

islas oceánicas tropicales los vientos alisios provienen del este; a medida que el aire se

desplaza al oeste pierde humedad en la lluvia, haciéndose más seco. Se han propuesto

dos hipótesis relacionadas a este hecho: Comparado con el este de las islas, el oeste

es menos húmedo y posee más largo ciclo diurno de temperatura del aire. Utilizando

datos disponibles en la internet, las dos hipótesis se ensayaron siete veces con datos

de seis islas en el caribe y el pacifico; la primera hipótesis fue ensayada sóla La

Española y resulto ser válida. La segunda hipótesis es válida en cuarto de las seis islas;

la probabilidad de que esto ocurra por coincidencia es seis en un millón pruebas.

Para el segundo artículo, datos por hora para 33 pozos de observación durante

12 a 18 meses fueron utilizados para estudiar la correlación entre el nivel de agua y

temperatura en Puerto Rico. A menudo, la lluvia es más fría que las condiciones

ambientales; si esta llega rápidamente al pozo de observación, deberá existir una

correlación entre la profundidad de agua y la temperatura. Si el movimiento del agua

hacia el pozo es lento, entonces el nivel de agua debe incrementar independiente de la

xv

temperatura. La hipótesis formulada para este fenómeno es que en la unidad superior

del acuífero en las rocas calizas del Carso en la costa norte tendrá en promedio más

alto coeficiente de correlación de Pearson entre el nivel del agua y la temperatura que el

acuífero de la zona no caliza la planicie de la costa sur. Esta hipótesis no fue

corroborada de forma significativa; en el acuífero de las rocas calizas, el coeficiente de

correlación de Pearson promedio entre el nivel de agua y temperatura es 0.29 con una

desviación estándar de 0.62. En el acuífero no calizo, el coeficiente de correlación de

Pearson promedio es 0.01 con una desviación estándar de 0.50. El valor p = 0.25, la

variabilidad intra-acuífero es suficiente grandes para que estos resultados no sean

significativos. El propósito particular de este estudio fue determinar la vulnerabilidad de

los acuíferos dependiendo si la lluvia les alcanza rápido, caso en sería más vulnerable a

contaminación desde la superficie o lentamente, caso en que sería menos vulnerable.

Dos áreas en al acuífero del Carso están a más riesgo de contaminación desde la

superficie, una es la que conecta los municipios de Quebradillas y Camuy y la otra es la

que conecta los municipios de Manatí y Vega Baja.

1

Chapter One

Overall Introduction

Water is essential for life and humans are dependent on fresh water provided by

the water cycle. The oceans are the reservoir of water on our planet and cover 71

percent its surface (NOAA 2016). Evaporation from the oceans converts the water from

liquid to gas. With evaporation the salt is left behind and saltwater is turned into fresh

water. The wind transports the water vapor over the land, the humid air is uplifted either

by convection caused by solar radiation heating the land or the orographic effect as the

wind blows over mountains. Condensation converts the water vapor back into a liquid

and clouds are formed, precipitation delivers fresh water to the land at an elevation

above sea level. The water flows back to the ocean to complete the cycle. Before

returning to the ocean the water can be used for power or to provide water for

ecosystems, humans, agriculture, or industry, the water cycle is powered by solar

radiation. From year to year, at a single point, at the top of the atmosphere, solar

radiation is almost constant but precipitation has enormous variability and is inherently

unpredictable. The inherent unpredictability of precipitation means that long term data

and statistics are needed to understand its patterns.

Precipitation includes rain, snow, hail, and other forms of atmospheric water

falling to the land surface. At high latitudes and elevations, winter precipitation can fall as

snow and remain unavailable to plants and animals, until it melts in the spring. In areas

where snowfall remains on the ground for months, rivers typically have peak discharge

in spring. Every year a tiny fraction of the snowfall is incorporated into glaciers where it

may remain in solid form for thousands of years. In the tropics, snow is rare below 3000

m above sea level and, in most areas; rain is the only significant form of precipitation.

2

Residence times of 10,000 years or more have been reported in glaciers

(Delmonte et al. 2002) and in groundwater (Remenda et al. 1994). Below 1.5 m

groundwater is too deep for either evaporation or intake by roots (Bear 2007) and is

unavailable to surficial ecosystems until it returns to the surface in springs or seeps.

Some water can become stagnant in geologic formations, although the majority of

ground water is still moving towards the ocean but at a much slower speed than surface

water. For at least 8000 years, humans have constructed wells to intercept ground water

and return it to the surface faster than it would naturally (Galili 1993). Ground water is

much more common on Earth than glaciers.

Puerto Rico is an oceanic tropical archipelago which has three inhabited islands

known as Puerto Rico, Vieques, and Culebra, the populations of which are 3,656,000;

9,300; and 1,800 respectively (USCB 2014). Vieques and Culebra previously used wells

and desalinization but are now receiving fresh water from the main island in an undersea

pipeline (Agency for Toxic Substances and Disease Registry 2001). The center of the

main island is near 18.2 °N and 66.5 °W, the highest elevation of Puerto Rico is Cerro de

Punta at 1338 m above sea level. San Juan is the capital of Puerto Rico and in the 2010

census it and nine surrounding municipios (Bayamón, Carolina, Caguas, Guaynabo, Toa

Baja, Trujillo Alto, Toa Alta, Canovanas, and Cataño) had a combined population of

1,335,340 people, which was 36 percent of the population of Puerto Rico (USCB 2014).

The most complete discussion of the climate of Puerto Rico was written seven

years ago by José A. Colón-Torres who was the director of the National Weather

Service (NWS) office in Puerto Rico for 23 years (2009). The book has a lot of

information about the history of meteorology in Puerto Rico and discusses what types of

data exist and what types are scarce. At some regional airports wind data are collected

only doing daylight hours when the airport is open for business.

3

The NWS has a vast amount of data on the Internet both about the current

conditions and the climate of Puerto Rico (NWS 2014). On January 1st, 2014, the NWS

announced that with 116 years of data, 2013 was the fourth wettest year for the San

Juan metropolitan area of Puerto Rico. The five wettest years in San Juan; Saint

Thomas; and Saint Croix are shown in table 1.1. Saint Thomas and Saint Croix are in

the United States Virgin Islands and are about 65 km east of Puerto Rico. Three of the

five wettest years in Saint Thomas also are wet years in either San Juan or Saint Croix.

There is no correlation between the five wettest years in San Juan and Saint Croix.

On the Internet, the NWS has 66 stations, in Puerto Rico, with rainfall data from

1981 to 2010. For the station Manatí 2 E, the data are inconsistent and this

Table 1.1. The five wettest years in the San Juan metropolitan area, Saint Thomas, and

Saint Croixa. ________________________________________________________________

San Juan Saint Thomas Saint Croix

Data since 1898 1956 1951

Rank

________________________________________________________________

1 2010b 2010 1979

2 2011 1960 2003

3 1931 2005 1952

4 2013 2013 ` 1996

5 1950 2003 1974

________________________________________________________________

a Data from the NWS (2014).

b Years that correlate with other stations are highlighted in grey.

4

station is excluded from this analysis. The average annual rainfall for the 65 remaining

stations is 1768 mm. The rainiest part of Puerto Rico is El Yunque Mountain in the

northeast corner of the island. The station with the highest rain, Pico del Este, Naguabo

has an average rainfall of 4381 mm, this is an outlier as the second rainiest station Río

Blanco Lower, Naguabo has 2721 mm of rain. There are no stations with rainfall

between 3000 and 4000 mm. The driest station is Ponce City with 737 mm and is along

the south coast. There are five stations with average annual rainfall of less than 1000

mm and they are located on the south-central coast between Guánica and Santa Isabel.

Figure 1.1 is a map of the 1981 to 2010 average annual rainfall in Puerto Rico.

Figure 1.1. Map of average annual rainfall in Puerto Rico and the United States Virgin

Islands from 1981 to 2010. One inch is 25.4 mm. Map provided by NWS (2014).

5

In many parts of the world the windward side of a mountain has more precipitation than

the leeward side. This effect is called a rain shadow. The rain shadow of El Yunque

extends from Gurabo to Ponce.

The National Aeronautics and Space Administration (NASA) has produced a

graph of the global average daily rainfall for each month versus latitude (NASA

2014). The modified graph is shown in figure 1.2. Puerto Rico averages 4.8 mm of rain

per day, which is above average for its latitude. Around 18 degrees north there is a

sharp gradient which means that a small lateral shift in the rainfall peak could

dramatically change the amount of rainfall at this latitude.

There are less than one hundred climate stations for Puerto Rico. Daly et al.

(2003) developed a climate model for Puerto Rico with a gridded output where each

block is 15 seconds or about 450 m on a side. They used a digital elevation model, an

airflow model, data on prevailing winds, distance to the coastline, and expert knowledge

to build the model. In their data set the most common wind was from the east with

northeast being second. The climate stations were used to calibrate the model. The

outputs were minimum and maximum temperatures and mean monthly and annual

precipitation. The model demonstrated that many mountains in Puerto Rico have rain

shadows. At 3098 m above sea level the highest mountain in the Caribbean is Pico

Duarte in Hispaniola and it creates a rain shadow that affects the climate of the

downwind islands of Jamaica and Cuba (Jury 2009).

Malmgren and Winter (1999) used data from 18 stations in Puerto Rico to look

for evidence of climate zonation. Rather than start with preconceived climate zones they

used a computer to analyze the data for clusters that were derived from the data. They

found four zones. The first was extreme coastal where many of the stations were 3m

6

Figure 1.2. Average global daily rainfall versus latitude. The red star

shows the position of Puerto Rico on the graph. Modified from NASA

(2014).

above sea level and this zone covered the northern, eastern, and southern coasts. Two

more zones were inland in the east but touched the coast on the northwest. The last

zone was interior and the west coast. The highest elevation station was around 400 m

and a large section of the southwestern interior had no data.

The Köppen climate classification system is the most commonly used in the

world (Peel et al. 2007) and was developed by Wladimir Köppen in the early part of the

20th century. In this system tropical rainforest is defined as areas where the monthly

average temperature is always at or above 18 °C and the monthly average rainfall is at

or above 60 mm. In Puerto Rico, there are 32 NWS stations that have data for both the

7

temperature and rain criteria. Of these 32 stations, there are 14 stations that fail the rain

criteria. The only stations that fail the temperature criteria are the high elevations

stations of Cerro Maravilla and Pico del Este. There are 33 stations that have rainfall

data but do not have temperature data. Because all of these stations are at low elevation

they were classified only on the basis of rainfall data. The results are shown in figure 1.3.

Of the 65 stations, the Köppen climate classification system classifies 34 as tropical

rainforest, which are more common in the northeast than in the southwest. Much of

northern and eastern Puerto Rico has the climate of a rainforest but has been

deforested. Malhi and Wright (2004) used the Food and Agriculture Organization

definition of a tropical rain forest which is less restrictive. This definition allows up to

three months where the average rainfall in millimeters is less than twice the average

temperature in Celsius, which in the case of Puerto Rico would mean rainfall less than

about 50 mm. With the less restrictive definition of tropical rainforest the number of

stations that are not rainforest drops from 31 to 8. All of the non-rainforest stations are

on the south coast. Helmer et al. (2002) used nine categories to map the island with

similar results. The dryer categories are the southwest and the wetter in the northeast.

The average monthly distribution of rain in Puerto Rico is shown in figure 1.4.

Between January and March the average monthly rainfall is 80 mm. This rises to 200

mm in May and then falls 33 percent to 134 mm in June. The peak for the year is

September at 225 mm and then it falls for the rest of the year. Jones and Banner (2003)

demonstrated that aquifer recharge occurs when monthly rainfall exceeds 200 mm. May,

September, and October average more than 200 mm of rain. Less aquifer recharge

occurs in May because the preceding months are dry and more of the rain goes to

replenish soil moisture. A study of how global climate change will affect Puerto Rico has

8

Figure 1.3. The Köppen climate classification system in Puerto Rico. This

map is based on NWS data (2014). The filled circles are tropical rain forest

and the rings are other classifications. Base map provided by USGS (2014).

raised the possibility that the wet season will become wetter and the dry season dryer.

Aquifers are recharged during extreme events, and thus increased rainfall in the wet

season will increase aquifer recharge (Harmsen et al. 2009).

Many stations have a pattern similar to the average but there are some

variations. The largest number of stations, 26, have a peak rainfall in September and 17

peak in October. There are however 11 stations that peak in May, ten of which are in the

9

Figure 1.4. Average monthly distribution of rainfall in Puerto Rico, n = 65. Data modified

from NWS (2014).

north-central part of the island. The stations that peak in May are shown in figure 1.5.

A different pattern is found in Mayagüez. The average monthly distribution of

Hacienda Constanza, Mayagüez is shown figure 1.6. The May peak is insignificant with

only a 2 percent drop between May and June. The driest month at Constanza is

December. Of all 65 stations, Hacienda Constanza has the least significant May peak

but other nearby stations have similar patterns.

The distribution of driest and wettest months is shown in figure 1.7. One station

has its driest month in June and the other 62 are between December and March. Fifty

two of the stations have their wettest month between July and November, eleven peak in

0

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1 2 3 4 5 6 7 8 9 10 11 12

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AVERAGE MONTHLY RAINFALL IN PUERTO RICO

10

May and there are no overlaps. There are no months which have both driest and wettest

stations. The shape of the graph is similar to figure 1.4 which shows the average

monthly rainfall.

Figure 1.8 shows the pattern of dry and wet years in Puerto Rico between 1953

and 2012. The positive numbers are the number of stations that had record high rainfall

in the year in question. The negative numbers are the number of stations that had record

low rainfall in the year of question. The wettest year for San Juan and Saint Thomas was

2010. Using this island-wide metric, 2010 is in a three-way tie for fourth wettest year. Six

stations had record-high rainfall in1979, 2003, and 2010. The wettest year in Saint Croix

was 1979 which was also the wettest year for six stations in Puerto Rico: Yabucoa, San

Lorenzo, Fajardo, Canovanas, Río Piedras Experimental Station, and Toa Baja, all of

which are in the eastern part of the island. In this metric, the wettest year in Puerto Rico

was 1970 when nine stations had record high rainfall. Two periods of water rationing

occurred in 1994 and 1996. Between 1953 and 2012, the year in Puerto Rico with the

most dry-records was 1967 when 15 stations broke records for the least rainfall. Another

dry period was 1991 to 1997. Over a period of 7 years, 15 stations had record low

rainfall. The 1967 drought was a single year event whereas the drought over the 1990s

was seven years when stations were breaking new records for low rainfall. Water

rationing was more common in the drought of the 1990s than in 1967 which indicates

that the water-supply system had less reserves in 1994 than 1967 (Larsen 2000). The

second driest year was 1976 when 10 stations had record low rainfall. During water

rationing in 1994 and 1996, many homes had water for 12 hours and then were 36 hours

without water (Larsen 2000).

The natural hydrology of Puerto Rico has very little surface-water storage. After a

heavy rainfall, most of the rainwater is back in the ocean in less than 24 hours. The

11

Figure 1.5. Stations with maximum average rainfall in May. Filled circles are

stations with maximum rainfall in May. Rings have maximum rainfall in other

months. Ten of the 11 with maximum rainfall in May are on the north central part

of the island. Data from NWS (2014) and the base map is from the USGS (2014).

largest undammed river in Puerto Rico is the Río Grande de Manatí. The United States

Geological Survey (USGS) discharge data for two stations for five days beginning

November 21st, 2013 are shown in figure 1.9 (USGS 2014). The upstream station is Río

Grande de Manatí near Morovis (50031200) and the downstream station is Río Grande

12

Figure 1.6. Monthly distribution of rainfall from 1981 to 2010 at Hacienda Constanza,

Mayagüez. At this station the driest month is December and the May rainfall is only 2

percent more than June. Compare with figure 1.4 which is the average of all stations.

Data from NWS (2014).

de Manatí at Hwy 2 near Manatí (50038100). The direct distance is 21 km. On the first,

second, and third days the percentage of the total discharge above base flow that

passed by the lower station was 76, 20, and 4 percent respectively. Most of the

discharge pattern is natural but at Morovis on November 24th, 2013 there is a small peak

followed by an immediate valley. This pattern probably represents a tank being emptied

and then refilled.

0

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HACIENDA CONSTANZA, MAYAGUEZ

13

Figure 1.7. Distribution of the wettest and driest months in Puerto Rico. Data from NWS

(2014).

Combined Lago Carraizo and Lago La Plata provide 40 percent of the water

used in Puerto Rico. Lago Carraizo has a supply of only 50 days (Ortiz-Zayas et al.

2006). In Puerto Rico, and on other islands, one of the biggest problems in water

resources is lack of storage (Hophmayer-Tokich and Kadiman 2006).

-40

-30

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-10

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Negative values are the number of statiionsthat are the driest. Positive values are the

number of stations that are the wettest.n = 63.

14

Figure 1.8. Wet and dry years in Puerto Rico from 1953 to 2012. A positive

(negative) number is the number of stations that hit record high (low) rainfall in that

year. The six driest years of the 20th century in Puerto Rico fall between 1964 and

1997 (Larsen 2000). The number is parenthesis is the rank. The red arrows

indicate periods of water rationing. Data modified from NWS.

Reservoirs in Puerto Rico store water on the time scale of months. Aquifers are

natural systems that, when there is heavy rain, capture a tiny fraction of the runoff and

store it, in some cases, for years. The natural discharge of aquifers are springs and

seeps where the water discharges at a different location, at lower elevation, at a later

time, and with higher dissolved solids then when it fell as rain. As an oceanic island both

-15

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-5

0

5

10

1945 1955 1965 1975 1985 1995 2005 2015

NU

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YEAR

WET AND DRY YEARS IN PUERTO RICO, 1953-2012

1967 (1)

1976 (5)

1994 (3)

1997 (2)1991 (6)1973

1960

19701979

19812003 2010

1964 (4)

15

Figure 1.9. Discharge on Río Grande de Manatí from November 21st to 25th, 2013.

The small rise and fall of discharge at Morovis on November 24th, 2013 probably

represents a tank above the station that was emptied and then refilled. Data from

USGS (2014).

the rivers and the aquifers of Puerto Rico have shorter residence times for water than

continental areas.

Is rainfall in Puerto Rico increasing or decreasing? If long-term rainfall is

decreasing then it makes it more likely that the Island will need to build a desalination

plant. It is useful to look at the Carlsbad Desalination Plant that is currently under

0

10

20

30

40

50

60

70

80

21 22 23 24 25 26

DIS

CH

AR

GE,

IN C

UB

IC M

ETER

S P

ER S

ECO

ND

NOVEMBER 2013

RÍO GRANDE DE MANATÍ

The red line is Río Grande de Manatí near Morovis (50031200) and the black line isRío Grande de Manatí at Hwy 2 nearManatí (50038100). The peak at highway#2 is 8 hours after Morovis. The directdistance between the stations is 21 km.

Data from USGS.

16

construction in San Diego, California, USA. When completed in 2016 it will be the largest

such plant in the Americas.

The San Diego County Water Authority provides water to 3.2 million people. The

authority has signed a contract to buy water from the privately owned Carlsbad

Desalination Plant. The plant will provide 7 percent of the water for the county and over

the life of the thirty-year contract the cost will be 3 billion dollars. The water is twice as

expensive as the currently used surface water, which is from northern California or the

Colorado River. With expected price increases, the desalination water will be less

expensive than surface water by 2024. The plant will produce 48,000 acre-feet of water

(one acre-foot is 1233 cubic meters) per year. Each acre-foot of water requires 5000

kilowatt-hours of electricity (1 kWh is 3.6 MJ) (Barringer 2013). On an island that

produces 98 percent of its electricity by burning fossil fuels (PREPA 2013), desalination

would increase air pollution and the emission of climate-changing gasses.

In Puerto Rico, the six driest years of the 20th century were between 1964 and

1997 (Larsen 2000). If there was no long-term trend in rainfall, then the probability that

the six driest years of a century would be in the last half is the same as flipping a coin

and having it land on heads six times in a row which is 1:26 or 0.016. In Puerto Rico, in

the 20th century the drying trend is significant. Tropical rainfall has declined in the last

third of the 20th century (Diaz 1996). Several climate change models predict that rainfall

in the Caribbean in June, July, and August will decrease by the end of the 21st century

(Neelin et al. 2006). Climate change models need to be used with care because the

mountains of the Caribbean create sharp gradients in climate on a scale that are poorly

represented in climate change models (Jury 2009).

The Caribbean was getting dryer and this was supported by both theory and

empirical data. This was the state of scientific knowledge in the first few years of the 21st

17

century. The rains in the first 14 years of the 21st century have broken records. In Puerto

Rico, 14 stations have set rainfall records between 2003 and 2012. In the San Juan

metropolitan area, with 116 years of data, three of the four wettest years are 2010, 2011,

and 2013. The NWS has 59 rainfall stations, which have data for the wettest and driest

years. If the driest year is subtracted from the wettest year the result will be either

positive or negative. Zero is impossible because the same year cannot be both the

wettest and the driest. Of the 59 stations, 39 are positive. If the average annual rainfall

was stationery, then there should be equal positive and negative results. The binominal

distribution can be used to calculate the probability of this occurring by random chance,

and the result is 0.0092. Between 1953 and 2013 the increase in rainfall is significant.

Is the rainfall in Puerto Rico increasing or decreasing? Depending on the data

sets and the endpoints both can be shown to be significant. The data are not consistent

with a linear increase or decrease in rainfall. The data are consistent with rainfall that

rises and falls on the scale of decades for reasons that cannot be explained. There are

large uncertainties in any prediction about the future of rainfall in Puerto Rico. This view

is not held by all scientists writing on the subject, Torres-Valcarcel (2014) states that the

Caribbean has seen a century of declining rainfall.

There are multiple definitions of the tropics. One is based on astronomy and this

is the definition that will be used in this dissertation. The tropics are the regions of the

Earth between the Tropics of Cancer and Capricorn. The axis of the daily rotation of the

Earth is tilted 23.4 degrees from the plane of its yearly revolution around the Sun. Every

year on the summer solstice, about June 22nd, the Sun is 23.4 degrees north of the

equator and at local noon at 23.4 degrees north latitude, the Sun is directly overhead.

On the winter solstice, about December 22nd, the sun is overhead at 23.4 degrees south.

This is how the Tropics of Cancer and Capricorn are defined. The tropics cover 40

18

percent of the Earth and have almost half the world’s population (Wong and Chen 2009).

This tilt is what causes the seasons of the Earth. The climate of the tropics is

characterized by consistency. Compared to the temperate parts of the world, the tropics

show less variation in length of day, temperature, wind velocity, and relative humidity.

Oceanic tropical islands are surrounded by oceans which further moderates extremes in

temperature.

This dissertation was born in Puerto Rico with the intention that the science can

be used locally. At the same time the science in this dissertation is important not

because Puerto Rico is unique but because what is learned here can be applied in other

parts of the world. On many oceanic tropical islands environmental data are from sparse

to non-existent. Puerto Rico is one of the most data-rich places on Earth. The political

ties to the United States have given the island the wealth and the mandate to collect and

archive environmental data.

Temperature data are underutilized in environmental sciences. Many physical,

biological, and chemical processes create thermal signatures. Because water is slow to

reach thermal equilibrium with its environment, water often has a thermal memory of

where it has been. Ground water that descends deep into the Earth and then rises

quickly without mixing, will have geothermal heat and will be warmer than other nearby

ground or surface water. There are large existing temperature data bases. The

instruments used to collect temperature data are the least expensive environmental

sensors.

The warmest thermal spring of four in Puerto Rico is the Baños de Coamo in

Coamo, in the south central part of the island. The USGS has measured the temperature

of the Baños de Coamo (USGS ID# 180219066222500) 13 times between 1960 and

2005. The average temperature is 42 °C, with a standard deviation of 2.3 °C (USGS

19

2014). The site has engineered pools and the variation in temperature may be a result

not of geology but of different measuring points. After years, when the public could use a

rustic pool at no charge, the site has been remodeled and is operating as a spa with an

admission fee.

What is the probability that there is an undetected spring in Puerto Rico with

water hotter than the Baños de Coamo? Hot springs have been recognized as important

natural resources for thousands of years. In the past, people went to rivers to take water,

bathe, bathe animals, look for food, and wash clothes. Rivers were often the easiest

path between different points. Prior to the 21st century there was far more local

knowledge about rivers than there is today. The probability of undetected hot springs in

Puerto Rico is very low.

The core of this dissertation is contained in two chapters that have been written

as independent journal articles to be submitted for publication. Each article takes a

relatively simple temperature-related idea and explores its implications for understanding

the environment and the management of water and other natural resources. On oceanic

tropical islands all over the world, the trade winds blow consistently from the east. The

consistency of the wind causes the eastern part of the island to be humid and the west

to be dry. The western part of the island is in the rain shadow of the eastern end. Dryer

air is more transmissive of infrared radiation. The hypotheses supposed in the study are

that compared to the eastern part of the island the west will have lower relative humidity

and a larger diurnal air temperature cycle. The Earth has an estimated 45,000 tropical

islands larger than 5 hectare (0.05 km2) (Arnberger and Arnberger 2001), but only 6

have enough data on the Internet to verify the hypotheses.

The second study examines the correlation between groundwater level and

temperature in Puerto Rico. The hourly data from 33 observation wells were collected by

20

the author when he was an employee of the USGS and these data have never been

published. Large amounts of groundwater temperature data are the unintended, free

byproduct of the switch from measuring groundwater levels with floats and

counterweights to pressure transducers. Rain is colder than ambient conditions and the

idea is that the correlation between groundwater level and temperature is a proxy for

travel time from rain drops to aquifer recharge. If the rain water reaches the aquifer in a

few hours there will be a high correlation between depth-to-water and temperature, both

will decrease after a rain event. If the rain water takes months to reach the aquifer then it

will have warmed to ambient conditions, the water level will rise and the temperature will

be constant. The correlation between groundwater levels and temperature can be used

to produce a map identifying areas in Puerto Rico at high risk from the movement of

contaminants from the surface to the aquifer. In a study in Canada, the most common

hazardous material transported was gasoline (Verter and Kara 2001). In the advent that

a truck carrying hazardous material has an accident in a rain storm the map will identify

areas where the contaminant will reach the potable water system the fastest.

Literature Cited in Chapter One

Agency for Toxic Substances and Disease Registry. 2001. Vieques, Puerto Rico—Fact

Sheet—Public Health Assessment Ground and Drinking Water [Internet].

Available from

http://www.atsdr.cdc.gov/sites/vieques/ground_drinking_water_factsheet.html.

(Cited on 14 April 2014).

Arnberger H, Arnberger E. 2001. The tropical islands of the Indian and Pacific Oceans.

Austrian Academy of Sciences Press. Vienna, Austria. ISBN3-7001-2783-3.

Barringer F. 2013. In California, what price water. New York Times Business Day Energy

and Environment February 28th [Internet]. Available from http://www.nytimes.com

21

http://nytime.com/2013/03/01/business/energy-environment/a-costly-california-

desalination-plant-bets-on-future-affordability.html?pagewanted=1&_r-0 (Cited on

1 March 2014).

Bear J. 2007. Hydraulics of Groundwater. Dover Publications, Mineola NY.

Colón-Torres JA. 2009. Climatología de Puerto Rico. La Editorial Universidad de Puerto

Rico. San Juan, PR.

Daly C, Helmer EH, Quiñones M. 2003. Mapping the climate of Puerto Rico, Vieques

and Culebra. International Journal of Climatology. 23:1359-1381.

Delmonte B, Petit JR, Maggi V. 2002. Glacial to Holocene implications of the new

27000-year dust record from the EPICA Dome C (East Antarctica) ice core.

Climate Dynamics 18: 647-660. Doi:10.1007/s00382-001-0193-9.

Diaz HF. 1996. Precipitation monitoring for climate change detection. Meteorology and

Atmospheric Physics 60:179-190.

Galili E. 1993. The submerged pre-pottery Neolithic water well at Atlit Yam, northern

Israel, and its palaeoenvironmental implications. The Holocene 3:265-270.

Harmsen EW, Miller NL, Schlegel NJ, González JE. 2009. Seasonal climate change

impacts on evapotranspiration, precipitation deficit and crop yield in Puerto Rico.

Agricultural Water Management 96:1085-1095.

Helmer EH, Ramos O, López TM, Quiñones M, Díaz W. 2002. Mapping the forest types

and land cover of Puerto Rico, a component of the Caribbean Biodiversity

Hotspot. Caribbean Journal of Science. 38(3-4):165-183.

Hophmayer-Tokich S, Kadiman T. 2006. Water management on islands—Common

issues and possible actions. CTSM Studies and Reports number 27 ISSN 1381-

6357. P 1-30. [Internet] Available on

22

http://www.utwente.nl/mb/cstm/reports_downloads/watermanagement_on_island

s.pdf (Cited on 8 April 2014).

Jones IC, Banner JL. 2003. Estimating recharge thresholds in tropical karst island

aquifers: Barbados, Puerto Rico and Guam. Journal of Hydrology. 278:131-143.

Jury MR. 2009. An intercomparison of observational, reanalysis, satellite, and coupled

model data on mean rainfall in the Caribbean. Journal of Hydrometeorology.

19:413-430.

Larsen MC. 2000. Analysis of 20th century rainfall and streamflow to characterize

drought and water resources in Puerto Rico. Physical Geography. 21(6):494-521.

Malhi Y, Wright J. 2004. Spatial patterns and recent trends in the climate of tropical

rainforest regions. Philosophical Transactions of the Royal Society. 359:311-329.

Doi:10.1098/rstb.2003.1433.

Malmgren BA, Winter A. 1999. Climate zonation in Puerto Rico based on principal

component analysis and on artificial neural networks. Journal of Climate. 12:977-

985.

National Aeronautics and Space Administration (NASA). 2014. Zonal Global

Precipitation. [Internet] Available on

http://gmao.gsfc.nasa.gov/research/merra/sci_archive/GPCP_zonal_all.gif (Cited

on 20 January 2014).

National Oceanic and Atmospheric Administration (NOAA). 2016. Ocean Facts.

[Internet] Available on http://oceanservice.noaa.gov/facts (Cited on 11 January

2016).

National Weather Service (NWS). 2014. National Weather Service Weather Forecast

Office, San Juan, PR [Internet] Available on http://www.srh.noaa.gov/sju/ (Cited

on 20 January 2014).

23

Neelin JD, Mūnnich M, Su H, Meyerson JE, Holloway CE. 2006. Tropical drying trends in

global warming models and observations. Proceedings of the National Academy

of Sciences. 103(16):6110-6115.

Ortiz-Zayas JR, Cuevas E, Mayol-Bracero O, Donoso L, Trebbs I, Figueroa-Nieves D,

McDowell WH. 2006. Urban influences on the nitrogen cycle in Puerto Rico.

Biogeochemistry. 79:109-133. Doi:10.1007/s10533-006-9005y.

Peel MC, Finlayson BL, McMahon TA. 2007. Updated world map of the Köppen-Geiger

climate classification system. Hydrology and Earth System Science. 11:1633-

1644.

Puerto Rico Electric Power Authority (PREPA). 2013. [Internet] Available on

http://www.aeepr.com/ (Cited on 20 August 2013).

Remenda VH, Cherry JA, Edwards TWD. 1994. Isotopic composition of old groundwater

from Lake Agassiz: Implications for late Pleistocene climate. Science. 266: 1975-

1978.

Torres-Valcarcel A, Harbor J, González-Avilés C, Torres-Valcarcel A. 2014. Impacts of

urban development on precipitation in the tropical maritime climate of Puerto

Rico. Climate. 2:47-77. Doi:10.3390/cli2020047.

United States Census Bureau (USCB). 2014. [Internet] Available on www.census.gov

(cited 18 January 2014).

United States Geological Survey (USGS). 2014. Water resources of the Caribbean.

[Internet] Available on http://pr.water.usgs.gov (Cited 18 January 2014).

Verter V, Kara BY. 2001. A GIS-based framework for hazardous materials transport risk

assessment. Risk Analysis 21(6):1109-1120.

Wong NH, Chen Y. 2009. Tropical urban heat islands: Climate, buildings, and greenery.

Taylor and Francis, New York.

24

Chapter Two

The Effects of the Trade Winds on the Distribution of Relative Humidity and the

Diurnal Air Temperature Cycle on Oceanic Tropical Islands1

Abstract

On many oceanic tropical islands the trade winds blow from the east and as the

air passes over the island it loses moisture to rain. The two hypotheses for this study are

that the western part of the island is less humid and has a larger diurnal air temperature

cycle. Using data available on the Internet, the two hypotheses were assayed 7 times on

6 different islands in the Pacific and Caribbean. The islands used in this study are Puerto

Rico, Hispaniola, the Big Island of Hawaii, Maui, Oahu, and Kauai. The first hypothesis

was tested only on Hispaniola and is true. The second hypothesis was tested on all the

islands and is true on all the islands except on the Big Island of Hawaii and Maui. Using

a p-value of 0.05, these hypotheses are as predicted five of the seven times, which has

a p-value of 6 x 10-6. These findings should apply to thousands oceanic tropical islands

where data are sparse.

Keywords: rain shadow, oceanic, tropical, islands, trade winds

Introduction

The Earth has an estimated 45,000 tropical islands larger than 0.05 km2 (5

hectares) (Arnberger and Arnberger 2001). The populations of these islands range from

1 This chapter was published as: Richards RT, Emiliano A, Méndez-Tejeda R. 2015. The effects of the trade winds on the distribution of relative humidity and the diurnal air temperature cycle on oceanic tropical islands. Journal of Climatology and Weather Forecasting. 3:137. Doi:10.4172/2332-2594.1000137.

25

zero to 143 million on the Indonesian island of Java. Oceanic tropical islands often have

environmental problems that include high population densities, water scarcity, and

extinctions (Olson and James 1984). Data are often sparse (Arnberger and Arnberger

2001) but because inputs and processes are similar, many oceanic tropical islands have

commonalities including climate and in general vegetation. This study will look for

patterns on data-rich islands. Nothing in this study will prove that these patterns apply to

data-sparse islands but it will generate hypotheses that can help guide future research

on other oceanic tropical islands.

This study has two parts. First a simple theoretical approach, that examines how

on many oceanic tropical islands, the easterly trade winds shape the distribution of the

two variables of this study. And second, searching for available data to test the

hypotheses generated from the theoretical approach. This is a pilot study. The vast

majority of oceanic tropical islands do not have any available data to verify these

hypotheses.

Over open water, upwind of an oceanic tropical island the relative humidity is

typically around 80 percent (Emanuel 1984). The average value of relative humidity is an

equilibrium between evaporation which, on a daily basis, is almost constant and frequent

but light rain storms that remove moisture out of the air. As a parcel of air moves over

land it is disconnected from its source of moisture and from upwind to downwind it loses

moisture to rainfall and becomes drier. When the winds are consistent, the interaction

between the wind and the land creates a region with a reduced water vapor

concentration in the atmosphere. The western part of the island is in the rain shadow of

eastern end of the island. This structure in the atmosphere is a permanent feature even

as the air in it is being constantly replaced. The exact patterns of climate will be affected

by many factors including topography, the shape of the coastline, distance from the

coast, and anthropogenic factors such as urban heat islands. The existence of this area

26

of reduced water vapor content can be predicted solely on the basis of longitude and is

independent of the specifics of the other factors. The distance from the eastern tip of the

island can be measured either in degrees of longitude or kilometers and it would not

change the results. The rates of rainfall and runoff are typically much higher in the humid

tropics than in temperate regions (Bonell et al. 2005) and the higher rainfall will increase

the contrast between upwind and downwind areas.

There are at least three methods to study the interaction between the prevailing

trade winds and the land mass. Large numbers of temporary instruments can be

deployed to provide a large amount of data over the span of a few weeks. Such an

experiment is described for the Big Island of Hawaii by Chen and Nash (1994). A second

approach is to use digital elevation models, complex mathematical algorithms, and

expert knowledge to generate detailed maps of climate variables and this is the

approach used in the Parameter-elevations Regression on Independent Slope Model

(PRISM) (Daly et al. 2002). The application of PRISM to the island of Puerto Rico is in

Daly et al. (2003). A third approach is used in this study. This study looks at data-rich

islands and uses simplified mathematical relationships to look for generalized patterns

that probably exist on thousands of oceanic tropical islands where data are sparse. The

simplified relationship will require less data than more complex patterns.

On many oceanic tropical islands the trade winds consistently blow from the east.

This has been documented for Hawaii (Chen and Nash 1994), Hispaniola (Izzo et al.

2010) and Puerto Rico (Carter and Elsner 1996). The eastern two-thirds of Hispaniola is

the Dominican Republic while the western one-third is Haiti. In Puerto Rico, the wind

blows between northeast and southeast at least 65 percent of the time (Colón-Torres

2009). A detailed study of the trade winds in Hawaii is in Giambelluca and Nullet (1991).

Data-rich islands have studies but there are few studies that compare the environments

of widely separated islands.

27

The structure of the atmosphere in the Caribbean is important locally for the

islands and is connected to continental scale patterns. The North Atlantic Oscillation

(NAO) is derived from the difference in barometric pressure between Iceland and

Portugal. High levels of the NAO index are associated with high precipitation in northern

Europe and low precipitation in southern Europe and Puerto Rico (Malmgren et al.

1998). In late summer in the northern Antilles rainfall is associated with a negative NAO

index combined with warm conditions in the El Niño Southern Oscillation in the eastern

Pacific Ocean (Gouirand et al. 2012). The Caribbean Low Level Jet (CLLJ) transports

moisture to Central America and the eastern part of North America. Variability in the

CLLJ is associated with variability of precipitation in the downwind areas (Wang 2007).

Several studies have analyzed the inter-annual variability of Caribbean rainfall (Enfield

and Alfaro 1999, Giannini et al. 2000, Giannini et al. 2001, and Taylor et al. 2002). The

mean, annual, and monthly rainfall in Haiti is a complex function of fixed factors including

the topography and shape of the country, as well as the annual cycle of regional-scale

oceanic and atmospheric factors. The atmosphere in the northern Antilles is dominated

by the permanent Azores high, which induces permanent easterlies across the

Caribbean islands (Moron et al. 2014).

The variables in this study are affected by multiple factors such as elevation,

distance from coast, the shape of mountain ranges, and anthropogenic factors such as

urban heat islands. The central question of this study is if longitude is needed to be

added to the list to explain the observed data. The basic idea is that the consistency of

the trade winds creates a rain shadow in the western parts of oceanic tropical islands.

Mountains in Puerto Rico create a rain shadow (Daly et al. 2003). At 3098 m, Pico

Duarte is the highest mountain in Hispaniola and the Caribbean. The rain shadow of this

mountain affects the climate of Jamaica and eastern Cuba (Jury 2009). Data are

extremely limited for most oceanic tropical islands and this study will use simple patterns

28

with limited data requirements to see if the results are useful and can then be extended

to other islands.

The trade winds blow from the east and the air loses water to rain as it passes

over the land. This concept generated two hypotheses. The second hypothesis derives

from the first. In numerical form, the hypotheses will be stated for the western

hemisphere; in the eastern hemisphere the correlations are reversed. Each hypothesis

will be stated as a correlation with longitude. Longitude has an arbitrary datum in

Greenwich, United Kingdom but it would not affect the correlations of this study if the

datum were the eastern tip of the island or any other location. The hypotheses, for

oceanic tropical islands, are:

First: the western part of the island is in the rain shadow of the east and there will

be an inverse correlation between longitude and relative humidity.

Second: the diurnal air temperature cycle is the average difference between the

daily highs and the lows at night and will be correlated with longitude. Dry air is more

transmissive of infrared radiation (Pierrehumbert 2011), and with the same amount of

solar radiation, the days will be hotter and the nights will be colder, as occurs in deserts

(McGregor and Nieuwolt 1998). There is a published map of the diurnal air temperature

cycle in Puerto Rico (Colón-Torres 2009). The correlation with longitude is visible on the

map but the interpretation is based on distance from the coast.

The vast majority of the oceanic tropical islands on Earth have no data to assay

these hypotheses. There are other islands that have data but they are not readily

available. This study uses data collected by government meteorological agencies and

made available on the Internet. At least one hypothesis was tested on 6 islands. The two

Caribbean islands in this study are Hispaniola and Puerto Rico. All data from Hispaniola

are from the Dominican Republic as no data are available for the Haitian side of the

29

island. The Hawaiian Islands used in this study are the Big Island of Hawaii, Maui, Oahu,

and Kauai. Puerto Rico and Hawaii are part of the United States.

The six islands in this study are not representative of the 45,000 tropical islands

on Earth. All are in the northern hemisphere and all are in the western hemisphere. All

are near the Tropic of Cancer and none are in the deep tropics. None of the islands are

in the Indian Ocean. The largest concentration of tropical islands on Earth is between

Asia and Australia and none of the islands in this study are in this part of the world.

These are the islands for which data are available on the Internet and if the hypotheses

work on these islands it can guide the work of future researchers on other islands. The

islands of this study are well separated from continental landmasses. Future work will be

needed to understand the relationship between distance and the effect of continents on

the climate of tropical islands. The large masses of ocean water around the islands of

this study buffers the climate and reduces the annual air temperature cycle.

The location of the islands are in figure 2.1. The data were collected by the

National Weather Service (NWS), except in the Dominican Republic where they were

collected by the Oficina Nacional de Meteorología (ONAMET). NWS data are at the

Southeast Regional Climate Center (SERCC) (2014) and the Western Regional Climate

Center (WRCC) (2014). The data from the Dominican Republic are at World Climate

(2014) and were submitted to the World Meteorological Organization and edited by the

National Climate Data Center (NCDC). Both the NWS and the NCDC are part of the

National Oceanic and Atmospheric Administration of the United States.

Materials and Methods

The hypotheses were tested for every oceanic tropical island for which data

could be found on the Internet. Typically for each station the metadata includes latitude,

longitude, and elevation. For each hypothesis assayed, each island has between 15 and

30

Figure 2.1. Locations of the oceanic tropical islands used in this study.

68 data points. The data were plotted versus longitude and visually examined for

outliers, which were excluded. The Pearson correlation coefficient was calculated, the p-

value used was 0.05.

The hypotheses were assayed with climate stations that had at least 7 years of

data and in many cases 30 or more years. The first hypothesis, which states that the

western ends of oceanic tropical islands have lower relative humidity than the eastern

parts, was assayed only for the island of Hispaniola. The data were the monthly average

relative humidity, which were averaged to produce the average relative humidity. The

second hypothesis, stating that the diurnal air temperature cycle is larger in the western

parts of the islands was assayed for all of the islands. The monthly air temperature cycle

is the average high temperature in a month less the average low temperature in the

month. In the tropics, the diurnal air temperature cycle is 65 percent of the monthly cycle

(Watterson 1997), so the monthly average high and low temperature was used as a

Tropic of Capricorn

Tropic of Cancer

Hawaii

Maui

Oahu

Kauai

Puerto Rico

Hispaniola

Location of the islands used in this study

31

proxy for the diurnal cycle. A proxy was needed because data on the diurnal air

temperature cycle are not readily available. Each station has a value for the monthly

difference between high and low temperature and these were averaged to produce a

single value for the station over the course of a year.

The hypotheses were also assayed for north-south differences. If the trade winds

are converging on the equator then it would be logical that the low latitude part of the

island would be dryer and have a larger diurnal air temperature cycle.

Results

The results are in table 2.1. The graph of average relative humidity versus

longitude for Hispaniola is shown in figure 2.2. There are 15 data points. The 13 data

points from stations below 200 m above sea level showed a clear trend from 83 to 63

percent relative humidity. The two stations higher than 400 m above sea level were more

humid and were excluded as outliers. The Pearson correlation coefficient was -0.74

which had a p-value of 0.0019.

Hypothesis number two predicts that the western parts of oceanic tropical islands

will have a larger diurnal air temperature cycle and this was tested with monthly air

temperature data. The average monthly air temperature cycles for Hispaniola and Puerto

Rico are shown in figure 2.3, while figure 2.4 has the same data for the four Hawaiian

Islands. All six islands had a larger diurnal temperature cycle in the western parts of the

islands but the correlations were not significant in the Big Island of Hawaii and Maui.

The hypotheses of this study were assayed 7 times on 6 oceanic tropical islands

in two groups in two oceans. The hypotheses were as predicted 5 of the 7 times. The

binomial distribution was used to calculate the p-value for this to occur by random

chance and the result is six times in a million trials. The testing of the north-south

hypotheses produced no significant results.

32

Table 2.1. Results of assaying the hypotheses on oceanic tropical islands.

_____________________________________________________________________________________________

Relative Humidity Diurnal Air Temperature Cycle

Hypothesis #1 Hypothesis #2

Island ma bb rc nd p-value m b r n p-value

_____________________________________________________________________________________________

Puerto Rico e 2.47 -154 0.54 44 <0.001

Hispaniola -4.05 362 -0.74 13 0.0019 1.00 -60 0.52 68 <0.001

Hawaii 0.379f -50 0.091 37 0.29

Maui 2.87 -439 0.37 20 0.054

Oahu 7.23 -1130 0.65 30 <0.001

Kauai 9.01 -1430 0.90 16 <0.001

a m is slope e blank cells represent no data

b b is intercept f highlighted in gray are insignificant

c r is Pearson correlation coefficient

d n is sample size

33

Figure 2.2. Hypothesis #1--Average relative humidity

versus longitude for Hispaniola. The excluded data are

from stations over 400 m in elevation while the rest of the

data are from stations within 200 m of sea level. Data

modified from World Climate (2014).

Discussion

The correlations in this study are based on the consistency of the easterly trade

winds. In parts of south Asia and the island-rich region between Asia and Australia, the

climate is dominated by the monsoon pattern which can include abrupt changes in wind

direction and precipitation (Chang et al. 2002). Understanding how the Asia monsoon

affects the climatology of tropical islands is crucial in the extension of this study to other

areas such as Indonesia and the Philippines; however none of the islands in this study

are affected by the monsoon pattern.

34

Figure 2.3. Hypothesis #2--Average monthly air temperature cycle

versus longitude for Hispaniola and Puerto Rico. Data modified from

World Climate (2014) and Southeast Regional Climate Center

(2014).

In Maui the hypothesis on the correlation between longitude and the monthly air

temperature cycle has 20 data points, a Pearson correlation coefficient of 0.37, and a p-

value of 0.054. It was classified as insignificant but it is right on the edge and with one

more station the correlation would be significant. The Big Island of Hawaii is a different

story. With 37 data points the Pearson correlation coefficient is 0.091, and the p-value is

0.29. To be significant a Pearson correlation coefficient of 0.1 requires more than 250

data points.

The largest and most populated island used in this study is Hispaniola, which has

an area of 76,500 km2, a maximum elevation of 3098 m above sea level, and a

35

Figure 2.4. Hypothesis #2--Average monthly air temperature cycle versus

longitude for four Hawaiian Islands. The monthly air temperature cycle is a

proxy for the diurnal air temperature cycle. Dashed lines are used when the

correlation is not significant. The Big Island of Hawaii and Maui slightly

overlap in longitude. Data modified from Western Regional Climate Center

(2014).

population of over 20 million people, split almost evenly between the Dominican

Republic and Haiti. The population density of Hispaniola is 259 people per km2. Kauai is

the smallest and least populated island in this study. Kauai has an area of 1430 km2, a

maximum elevation of 1598 m above sea level, a population of 67,000, and a population

density of 47 people per km2. Oahu is the lowest and most densely populated island in

the study. Oahu has an area of 1545 km2, an elevation of 1220 m, a population of

154155156157158159160AV

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AG

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ON

TH

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AIR

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TU

RE

CY

CL

E,

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DE

GR

EE

S C

EL

SIU

S

LONGITUDE, IN DEGREES WEST

HAWAIIAN ISLANDS

Hawaii

Maui

Oahu

Kauai

0

8

16

0

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12

36

953,000, and a population density of 617 people per km2. The Big Island of Hawaii is the

highest in elevation and has the lowest population density. The Big Island of Hawaii has

an area of 10,432 km2, an elevation of 4205 m, and a population of 185,000 with a

population density of 18 people per km2.

The wind blows from the east, and as the air mass moves over land from east to

west it loses moisture to rain and becomes drier. The pattern is simplistic but it produced

two hypotheses which could be tested with data that are available on the Internet. The

hypotheses were successful in predicting observations on widely separated oceanic

tropical islands. The variables used in this study are affected by multiple factors like

elevation, proximity to the coast, the shape of mountains, and anthropogenic factors like

urban heat islands, the consistency of the easterly trade winds adds longitude to the list.

A simple correlation with limited data requirements produced useful results even though

the distance between Puerto Rico and Hawaii is more than 9,000 km.

Oceanic tropical islands are tiny specks of land spread out over vast distances of

ocean. On thousands of these islands, the easterly trade winds shape the environment

in predictable ways. This study is the first part of a larger effort to identify these

underlying physical processes that can help improve the management of water and

other natural resources on these islands. The easterly trade winds affects not only the

humidity and diurnal air temperature cycle but probably also the temperatures of sea

surface, rivers, and groundwater. These abiotic conditions shape the environment for

plants, animals, bacteria and fungi. Puerto Rico is a good place to start because its

political relationship with the United States has made it one of the most data-rich places

on Earth. The goal is science that can improve the management of water and other

natural resources in Puerto Rico while at the same time providing insights that can help

in the environmental management of thousands of islands where data are sparse.

Puerto Rico is an island but the viewpoint should not be insular but rather one that is

37

inclusive of the tens of thousands oceanic tropical islands with similar climates and

environmental problems.

Conclusion

The consistency of the easterly trade winds on oceanic tropical islands leads to

two predictions which can be assayed with data that are available on the Internet. The

hypotheses that were verified on two islands in the Caribbean and four in the Pacific are

that on the western end of the island the relative humidity is lower and the diurnal air

temperature cycle is larger. These patterns probably exist on thousands of islands for

which there are no readily available data. With more data it should be possible to

observe these patterns much more widely.

It has been observed that on islands, the topography of the island can act as an

obstacle or barrier to the wind causing an unequal distribution of humidity and diurnal air

temperature cycle. This study establishes the difference between the east (windward)

and the west (leeward) part of the islands. The east side benefit from the moisture of the

trade winds, while the west slope receives dryer wind. This generates microclimates that

also depend on elevation and large differences can occur across small horizontal

distances.

Acknowledgements

This study was possible because of the effort of observers and employees of

different agencies who for more than 50 years have collected, processed, and archived

the data used in this study. Their names are unknown, but their work is appreciated.

Literature Cited in Chapter Two

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Austrian Academy of Sciences Press. Vienna, Austria. ISBN3-7001-2783-3.

38

Bonell, M, Hufschmidt, MM, Gladwell JS. 2005. Hydrology and Water Management in

the Humid Tropics: Hydrological Research. Edited by Cambridge University

Press.

Carter MM, Elsner JB. 1996. Collective rainfall regions of Puerto Rico. International

Journal of Climatology 16: 1033-1043.

Chang C-P, Wang Z, McBride J, Liu CH. 2005. Annual cycle of Southeast Asia –

Maritime Continent rainfall and the asymmetric monsoon transition. Institutional

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Chen YL, Nash AJ. 1994. Diurnal variation of surface airflow and rainfall frequencies on

the island of Hawaii. Monthly Weather Review 122: 34-56.

Colón-Torres JA. 2009. Climatología de Puerto Rico. La Editorial Universidad de Puerto

Rico Sun Juan, PR.

Daly C, Gibson WP, Taylor GH, Johnson GL, Pasteris P. 2002. A knowledge-based

approach to the statistical mapping of climate. Climate Research 22: 99103.

Daly C, Helmer EH, Quiñones M. 2003. Mapping the climate of Puerto Rico, Vieques

and Culebra. International Journal of Climatology. 23:1359-1381.

Emanuel KA. 1987. The dependence of hurricane intensity on climate. Nature. 326:483-

485.

Enfield DB, Alfaro EJ. 1999. The dependence of Caribbean rainfall on the interaction of

the tropical Atlantic and Pacific Oceans. Journal of Climate 12: 2093–2103.

Giambelluca TW, Nullet D. 1991. Influence of the trade-wind inversion on the climate of

a leeward mountain slope in Hawaii. Climate Research 1:207-216.

Giannini A, Kushnir Y, Cane MA. 2000. Interannual variability of Caribbean rainfall,

ENSO, and the Atlantic Ocean. Journal of Climate 13: 297–311.

Giannini A, Chiang JCH, Cane MA, Kushnir Y, Seager, R. 2001. The ENSO

teleconnection to the tropical Atlantic Ocean: Contribution of the remote and local

39

SSTs to rainfall variability in the tropical Americas. Journal of Climate 14: 4530–

4544.

Gouirand I, Jury MR, Sing B. 2012. An analysis of low- and high frequency summer

climate variability around the Caribbean Antilles. Journal of Climate 25: 3942-

3952. doi:10.1175/JCLI-D-11-00269.1.

Izzo M, Rosskopf CM, Aucelli PPC, Maratea A, Méndez R, Pérez C, Segura H. 2010. A

new climatic map of the Dominican Republic based on the Thornthwaite

classification. Physical Geography 31(5): 455-472. doi:10.2747/0272-

3646.31.5.455.

Jury MR. 2009. An intercomparison of observational, reanalysis, satellite, and coupled

model data on mean rainfall in the Caribbean. Journal of Hydrometeorology.

19:413-430.

Malmgren BA, Winter A, Chen D. 1998. El Niño-Southern Oscillation and North Atlantic

Oscillation control of climate in Puerto Rico. Journal of Climate 11: 2713-2717.

McGregor GR, Nieuwolt S. 1998. Tropical climatology: an introduction to the climate of

the low latitudes (2nd edition). John Wiley and Sons. Hoboken, NJ.

Moron V, Frelat, R, Jean-Jeune PK, Gaucherel C. 2014. Interannual and intra-annual

variability of rainfall in Haiti. Climate Dynamics 45(3-4): 915-932.

Olson SL, James HF. 1984. The role of Polynesians in the extinction of the avifauna of

the Hawaiian Islands. Quaternary extinctions: A prehistoric revolution. Martin PS.

Klein RG. (editors). The University of Arizona Press. Tuscon, Arizona. 760-780.

Pierrehumbert, RT. 2011. Infrared Radiation and Planetary Temperature. Physics

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Southeast Regional Climate Center (SERCC). 2011. [Internet] Available on

http://www.sercc.com (Cited on 11 March 2011).

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Taylor MA, Enfield DB, Chen AA. 2002. Influence of the tropical Atlantic versus the

Tropical Pacific on Caribbean rainfall. Journal of Geophysical Research 107:

3127. doi:10.1029/2001JC001097.

Wang C. 2007. Variability of the Caribbean Low-Level Jet and its Relations to Climate.

Climate Dynamics 29: 411–422. doi:10.1029/006GLO28579.

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and doubled CO2 climates. Climate Dynamics. 13:533-545.

Western Regional Climate Center (WRCC). 2011. [Internet] Available on

http://www.wrcc.com (Cited on 11 March 2011).

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October, 2012).

41

Chapter Three

Using the Correlation between Ground Water Levels and Temperature to Study

Aquifer Vulnerability in Puerto Rico

Abstract

Hourly data for 12 to 18 months from 33 non-pumping observation wells were

used to study the correlation between depth-to-water and water temperature in Puerto

Rico. This correlation was used to identify areas where the groundwater is at higher risk

from superficial contamination. The hypothesis of this study is that in Puerto Rico, the

upper unit of the karst North Coast Limestone aquifer will on average have a higher

Pearson correlation coefficient between depth-to-water and water temperature and is at

higher risk from superficial contamination than the alluvial South Coastal Plain aquifer.

The result of this study is that the hypothesis is not proven. In the upper unit of the karst

North Coast Limestone aquifer, the average Pearson correlation coefficient between

depth-to-water and water temperature is larger than in the alluvial South Coastal Plain

aquifer but the intra-aquifer variability is large enough to prevent the results from being

significant. Two areas in the upper unit of the North Coast Limestone aquifer,

Quebradillas-Camuy and Manatí-Vega Baja, have the highest correlation between

depth-to-water and water temperature and are at higher risk from superficial

contaminants both compared to the rest of the karst North Coast Limestone aquifer and

the alluvial aquifers.

Keywords: aquifer vulnerability, groundwater temperature, Puerto Rico

Introduction

In many environments, rainfall is colder than ambient conditions. If the rain water

becomes recharge water and reaches an observation well quickly, then there will be a

42

correlation between depth-to-water and water temperature. If the water reaches the

observation well slowly, then it will have warmed to ambient conditions and the water

level will rise independently of the temperature. The correlation between water level and

water temperature can be used to study the travel time from the surface to the aquifer

and the intrinsic vulnerability of the aquifer.

“Intrinsic vulnerability represents the inherent hydrogeological and geological

characteristics which determine the sensitivity of groundwater to contamination by

human activities; the term refers essentially to risk associated to non-point sources.

Intrinsic vulnerability considers all kind of contaminants, opposed to specific

vulnerability” (Doerfliger et al. 1999)

In both the United States and Europe a variety of schemes have been developed

to rank aquifer vulnerability. These schemes are usually based on the geographical

distribution of characteristics like depth-to-water, aquifer media, and recharge. There is

no consensus about which scheme works better (Gogu and Dessargues 2000). This

study will use the correlation between groundwater levels and water temperature to

examine the intrinsic vulnerability of aquifers in Puerto Rico.

Heat can be used as a tracer (Anderson 2005); in many environments, rainfall is

colder than ambient conditions. In Kentucky, USA, a spring was instrumented; after a

rain event, the discharge rose rapidly but the water temperature declined only after a lag.

The water that discharged between the rise in discharge and the fall in temperature was

interpreted as the storage in the aquifer that drains into the spring (Ryan and Meiman

1996).

In the Alps, wells are often drilled next to rivers, and government regulations in

Switzerland and Germany require a travel time between the river and the production well

of 10 and 50 days respectively. The transmission of the diurnal water temperature cycle

43

of the river into the aquifer was used to measure the travel time from river to monitoring

equipment located within one to two meters of the river (Hoehn and Cirpka 2006). At

mid-latitudes, which have a large annual air temperature cycle the seasonal cycle can be

detected up to 50 m away from the river (Molina-Giraldo et al. 2011). These techniques

will probably not be useful in Puerto Rico where both the diurnal and annual temperature

cycles are smaller than in temperate, continental regions.

Organic contaminants degrade over time and the longer the travel time from the

surface to the aquifer the lower is the risk of contamination. The degradation can be

caused by chemical or microbial processes. Pesticides are broken down faster in soils

than in aquifers because the soil has more dissolved oxygen, minerals, organic material,

surface area, and microbes than aquifers. The herbicide alachlor has a degradation half-

life of around 4 years in aquifers but only 20 days in soil (Sampat 2000). The median

degradation half-life in soil of 11 pesticides detected in groundwater in Santa Isabel,

Puerto Rico is 60 days (Rodríguez 2012). Atrazine is a pesticide that degrades to

deethylatrazine at a predictable rate and the ratio of these two chemicals was used to

identify a region in western Santa Isabel where the groundwater is older than average

(Rodríguez 2012).

High frequency groundwater temperature data are the unintended free byproduct

of the switch from floats to pressure transducers. Globally, many hydrologic agencies

have switched to pressure transducers and probably have large amounts of unused

groundwater temperature data. In the case of the United States Geological Survey

Caribbean-Florida Water Science Center (USGS-CFWSC) in Puerto Rico, the data

frequency is hourly. This study will determine if, in a tropical environment the

groundwater temperature data can be used to identify areas at high risk from superficial

contaminants. A tropical environment with a reduced annual and diurnal air temperature

cycles simplifies some aspects of this work.

44

Puerto Rico is a 9,104 km2 oceanic tropical island with an estimated population of

3,656,000 (USCB 2013) and a population density of 418 people/km2. More than 80

percent of the water used on the island is from surface water (Molina-Rivera and

Gómez-Gómez 2008). Puerto Rico has one desalinization plant that produces 7600

cubic meters of water per day (Ecoeléctica 2012), which represents about 0.3 percent of

total water usage. Desalination is energy intensive, and on an island where 98 percent of

the electricity is produced by burning fossil fuels (PREPA 2013), increased use of

desalination will increase air pollution and emissions of climate changing gasses. The

goals of this study are to demonstrate a new use for existing groundwater temperature

data and to enhance the science that is used to manage groundwater resources in

Puerto Rico. It is also expected that the techniques developed here will be useful in

other parts of the world.

In Puerto Rico, groundwater is an important backup when surface water is

unavailable due to drought. The two major aquifers on the island are the karst North

Coast Limestone (NCL) aquifer and the alluvial South Coastal Plain (SCP) aquifer

(Renken et al. 2002). Lugo et al. (2001) describes the geology, biology, and land use of

the karst of Puerto Rico and calls for it to be set aside for conservation. In this study a

group of smaller discontinuous alluvial aquifers are called Rest of Puerto Rico (ROP).

The journey of a rain drop that will recharge an aquifer has three components:

First as runoff the water quickly moves across the land surface until an increase in the

hydraulic conductivity allows it to drop underground. The second leg is downward until it

reaches the water table. In the third and longest section, it recharges the aquifer and the

water slowly moves horizontally to its discharge point in a spring, seep, or pumping well.

The speed of the water is slower with each of the three legs of the journey.

When the rain drop hits the land surface it is relatively cold, saturated with

oxygen, and low in dissolved solids. There has been little use of tracers in Puerto Rico

45

(Ghasemizadeh et al. 2012). In Puerto Rico there are a small number of studies that

document the water quality of rain (Osborne 1986) and more that document the water

quality of runoff (Rodríguez 1996, Conde-Costas and Gómez-Gómez 1999, Rodríguez

1999, and Rodríguez 2001). As it crosses the land surface the runoff picks up

sediments, organic material, and microbes. Runoff water in Puerto Rico often has the

color of coffee with milk.

The second leg of the journey is transient, occurs underground, and is almost

undocumented. In the NCL the closed depressions where the runoff goes underground

are often clogged with mats of decomposing leaves and logs mixed with inorganic

sediments. The only study that looks at the connection between the surface and the

aquifer is Rodríguez-Martínez (1997) which classified 58 springs as conduit and nine as

diffuse. Conduit springs are well connected to the surface and during rainfall events

conduit springs undergo a rapid change in discharge and water quality including

sediment load. Diffuse springs integrate water over a long period and do not undergo

dramatic changes during rainfall events. Heat can be used as a tracer to study the water

as moves vertically towards the water table.

Unlike the transient conditions in the flow of runoff and the vertical stage of

recharge water movement, the third leg of the journey, the horizontal flowing

groundwater below the water table is a permanent feature and is easier to study. In

Puerto Rico thousands of wells have been drilled and the vast majority is not pumped.

According to the USGS (2015), the National Water Information System (NWIS) for

Puerto Rico, has on the Internet 2492 wells with at least one water level and 79 with 100

or more. At 87 wells water level data have been collected in the past year.

Compared to some parts of the world, Puerto Rico has vast amounts of

groundwater data and much of it is available on the Internet. At the same time there are

limitations to the groundwater data that exists for Puerto Rico. NWIS has 1487 wells in

46

Puerto Rico or the U.S. Virgin Islands with at least one water quality sample but the first

sampling of groundwater quality at regular intervals began in 2011 (USGS 2015). Some

published groundwater models have been based on limited amounts of data. Data are

sparse for the model of northwest Puerto Rico from Aguadilla to the Río Camuy (Tucci

and Martínez 1995). The calibration of the groundwater model in Santa Isabel is almost

entirely based on data from the Alomar 1 observation well (Kuniansky et al. 2003).

Groundwater models have used hydraulic conductivity data generated from slug tests or

specific capacity data that only measure the aquifer properties within a few meters of the

test well (Ghasemizadeh et al. 2012). Multi-well aquifer tests which could provide data

over hundreds of meter are more expensive but have seldom been performed.

Kuniansky and Rodríguez (2010) is a study using a groundwater model in the SCP in

Salinas and noted the lack of multi-well aquifer tests.

Karst aquifers are dominated by solution processes. Dissolution occurs more

rapidly in environments that are warm, wet, and have high levels of carbon dioxide.

Puerto Rico is tropical and is warmer than non-tropical areas. The average annual

rainfall in Puerto Rico is 1654 mm (Larsen 2000) and this is more than in most places in

the world. In the humid tropics the biomass density is higher than in non-tropical areas

and the decomposition of this biomass raises the concentration of carbon dioxide in the

soil. In the tropics, secondary porosity will develop in limestone more rapidly than in non-

tropical areas.

The NCL is a northward sloping sedimentary wedge that was laid down during

the Oligocene and Miocene. The five geologic units of the NCL, from oldest to newest,

are the San Sebastian Formation, the Lares Limestone, the Cibao Formation, the

Aguada Limestone, and the Aymamón Limestone. The dip is northward and averages

five degrees. The list above is also the order that the formations outcrop from south to

north. In places, particularly in the east, the NCL is overlain by unconsolidated

47

Quatenary deposits. A geologic map of the North Coast Limestone is shown in figure

3.1. Hydrogeologically, the NCL is divided into two limestone dominated productive units

with high hydraulic conductivity. The productive units are separated and underlain by

clay-rich units of low hydraulic conductivity (Renken et al. 2002). The upper part of the

Cibao Formation is high in clay and low in hydraulic conductivity. This part of the Cibao

supports surface streams while the rest of the NCL is dominated by subsurface flow. The

upper unit of the NCL includes the Aguada and Aymamón Limestones. The lower unit of

the NCL includes the Lares Limestone and in some areas permeable parts of the Cibao

formation such as the Montebello Limestone. The lower unit has a longer travel time

between rainfall and aquifer recharge and the methods of this study would probably be

less useful. In this study, there is more data from the upper unit than from the lower unit.

In Puerto Rico, there is a longstanding discussion about how to digitally model

the mix of low-hydraulic conductivity matrix interspersed with fractures and conduits of

higher hydraulic conductivity. Digital groundwater models have been developed for the

NCL in the area of Barceloneta (Torres-González 1985), in the north central coast

between the Río Camuy and Río Grande de Manatí (Torres-González et al. 1996), and

in the Manati-Vega Baja area (Cherry 2001) and all of these models have estimated an

equivalent hydraulic conductivity. In the opinion of Ghasemizadeh et al. (2012) there are

not enough data to do a good job of modeling the NCL.

There are no studies on the travel time from the surface to the aquifer. The upper

unit of the NCL is recharged almost exclusively by direct rainfall. The lower unit of the

NCL is recharged by direct rainfall and also by streams that form on the volcanic rocks to

the south and then disappear underground when they cross onto the karst rocks. In the

karst NCL, aquifer recharge occurs when the monthly rainfall exceeds 200 mm

48

Figure 3.1. Location of the observation wells used in this study and a geologic map of

the North Coast Limestone. The upper panel is a map of Puerto Rico. The circles with

black centers are the stations with a Pearson correlation coefficient between the depth-

to-water and temperature above 0.85 and the circles with white centers have a Pearson

correlation coefficient below 0.85. The lower panel is a geologic map of the North Coast

49

Limestone aquifer. The base map of the upper panel is from the USGS and the lower

panel is modified from Olcott 1999.

(Jones and Banner 2003). In all the studied aquifers the generalized direction of flow is

towards the ocean. The volcanic core of the island has fractured-rock systems that

contribute to maintaining base flows in the rivers but there is little groundwater

production or data. It is commonly assumed that the karst NCL aquifer is at greater risk

from the rapid movement of superficial contaminants than the alluvial SCP aquifer.

However the intrinsic vulnerability of the NCL aquifer has not been tested. A key

question is if the NCL aquifer has consistent vulnerability or needs to be broken down

into smaller units.

The SCP aquifer is the most important aquifer in southern Puerto Rico, which is

drier than the north of the island (Colón-Torres 2009). The SCP aquifer is 70 km long

and 3 to 8 km wide. It consists of a series of fan deposits that have coalesced. The size

of the particles ranges from boulder to silt. The depositional environment is complex and

has included downward moving grabens (Renken et al. 2002). The SCP aquifer is

recharged both by direct rainfall and from intermittent streams that flow out of the

mountains that are north of the coastal plain. Often these streams are kilometers long

and permanent in the mountains and then the water sinks when the stream crosses onto

the alluvium. Some of the streams may not flow into the ocean for months during the dry

season.

Much of what we know about groundwater in Puerto Rico is from the observation

wells maintained by the USGS-CFWSC and the data in this study is from a subset of

these wells. Typically in a groundwater study, the USGS-CFWSC drills some

piezometers, after the short-term project, some of these piezometers become part of the

long-term network. The USGS-CFWSC constructed piezometers used in this study in

50

Naguabo (Graves 1989), Dorado (Troester 1999), Fajardo (Pérez-Blair 1996), and

Salinas (Kuniansky and Rodríguez 2010). These stations have been used to study the

water-level fluctuations in observation wells (Richards 2003). Long-term water level data

from these observation wells has been used to calibrate groundwater models in Santa

Isabel (Kuniansky et al. 2003) and Salinas (Kuniansky and Rodríguez 2010). A second

source of observation well is wells that were drilled to be production wells but then

abandoned.

Two of the observation wells used in this study Hill 2, Manatí and Palo Alto 2,

Vega Baja, are part of a group of six wells that were sampled for pesticides. The wells

had been drilled to study nitrate contamination near pineapple fields (Conde-Costas and

Gómez-Gómez 1999). Pineapples were grown in the area for many years but by 2008

production had stopped. The herbicide Bromacil was detected in all six wells with the

highest level, of 30 μg/L, at Hill 2 in February 1997 (Dumas 1999).

The United States Environmental Protection Agency has classified the most

contaminated sites in the United States and its territories in the National Priority List,

better known as “Superfund” sites. Puerto Rico has 16 sites of which 8 involve

contaminated groundwater. Bosque (2011) looked at three of these sites and

demonstrated that the benefits of remediation exceed the costs.

This study will look at the correlation between depth-to-water and water

temperature in observation wells. The hypothesis is that the average Pearson correlation

coefficient between depth-to-water and water temperature for the observation wells in

the karst upper unit of the NCL aquifer will be higher than in the observation wells in the

alluvial SCP aquifer. If this hypothesis is correct, then the karst upper unit of the NCL

aquifer as a whole is at greater risk from superficial contaminants than the alluvial SCP

aquifer. The null hypothesis is that the average Pearson correlation coefficient in the

karst upper unit of the NCL is not significantly different than the alluvial SCP aquifer. If

51

the null hypothesis cannot be rejected then it would mean that, in terms of intrinsic

vulnerability, there are no significant differences between the upper unit of the NCL and

the SCP aquifer. The hypothesis will fail if the ratio of intra-aquifer to inter-aquifer

differences is large. Either result is useful to improve the management of groundwater

resources in Puerto Rico. In terms of aquifer vulnerability it is important to know if the

upper unit of the NCL is one unit or needs to be managed on a smaller length scale. The

hypothesis applies to stations were the water level is controlled by rainfall and not tides

nor the cycling of production wells.

Materials and Methods

Globally, in the 20th century most water levels in observation wells were recorded

with a float-counterweight system. Early in the 21st century the USGS-CFWSC converted

its water-level recorders from floats-counterweights to pressure transducers. Pressure

transducers produce more reliable data and are less expensive because they need less

labor power to install, operate, and process the data.

Float-counterweights and pressure transducers do not measure the same

geophysical variable. The float detects the elevation of the density difference at the air-

water interface while the pressure transducer measures the pressure and the

temperature at a fixed point below the water surface and then calculates the water level.

An assumption is made that the water column is thermally homogenous; this assumption

is seldom violated in observation wells.

As of May 2015, the 33 stations used in this study have been visited by USGS-

CFWSC employees 5317 times. The complete data for each station are in Appendix I.

The daily and monthly water level data, and metadata such as location and well depth,

are available on the Internet (USGS 2015). The hourly data, both water level and water

temperature, are unpublished.

52

Between 1963 (Carter et al. 1963) and 2002 the USGS used the Automatic Data

Recorder (ADR). In Puerto Rico, for many years, this was the only equipment used to

record water levels in observation wells. At a regular time interval, the ADR punched

holes in a paper tape that represented the rotational position of the float wheel.

By 1998, the USGS-CFWSC was testing two ADR replacements (Richards

2003). One system still used the float-counterweight system but the digital electronic file

was created in the field and transported to the office on a data card. The second unit

being tested was a pressure transducer with an integrated data logger, the DH-21 made

by Design Analysis. The use of brand names is for identification purposes only and does

not constitute endorsement by the Universidad del Turabo. All of the data used in this

study were collected with the DH-21. This system has no moving parts and no display; it

must be read in the field with a computer.

The USGS-CFWSC had layoffs in 2002 and between 2003 and 2008 the

emphasis was less but higher quality data. Documentation was improved and protocols

were standardized. By 2006 the groundwater network was again standardized using the

pressure transducer in all non-telemetry stations.

All of the groundwater levels in this study were originally measured to the nearest

0.01 feet (3 mm). A pressure transducer is mounted at a fixed location, usually about 1.5

m, below the record low water level. The pressure transducer measures the pressure

and the temperature, and then calculates the water level. The unit is calibrated and then

on revisits the water level is independently measured to verify the calibration.

A one part per thousand (ppt) change in the calibration of the pressure sensor

changes the reported height of the water column above the sensor by one ppt. The

density of water is only slightly a function of temperature. A fractional change in

temperature is meaningful only in the Kelvin temperature scale. The ambient

temperature of groundwater in Puerto Rico is almost exactly 300 K. and a change of one

53

ppt is 0.3 K, which equals 0.3 °C. A one ppt increase in water temperature results in a

0.08 ppt reduction in water density (CRC Handbook of Chemistry and Physics 1989). A

typical station has 7 m of water above the sensor and would require a 7.2 K change in

the calibration of the temperature sensor to create an error of 15 mm, which would lead

to a reset of the DH-21, which has a resolution of 0.01 °C and an absolute accuracy of 1

°C (Fletcher 2010). In this study the relative is more important than the absolute

accuracy. About once a year, the in-situ water temperature of the observation well was

measured with an YSI model 85 digital temperature sensor with a 30 meter cable

between the sensor and the display. The unit has a resolution of 0.1 °C and in the

laboratory was always within 0.1 °C of a certified thermometer.

In this study, 39 percent of the observation wells were piezometers that had been

drilled by the USGS-CFWSC for scientific studies, 61 percent were abandoned

production wells drilled for public supply, agriculture, industry, or an orphanage. About

90 percent of all the production water wells drilled in Puerto Rico are abandoned.

Piezometers are designed to obtain data from a specific point in the aquifer, while

production wells are designed to maximize production. Compared to piezometers,

production wells tend to be larger diameter, deeper, and tend to be open to the aquifer

over a larger distance, the construction details of piezometers are better documented

than production wells. There are many things about a well that cannot be predicted

before its construction. The unknowns include its productivity, its response time to rain

events, and what will be the range in water level over time.

If a production well is producing large quantities of clean water, it will not be

abandoned and made available to be an observation well. Compared to operating

production wells, abandoned production wells tend to have lower hydraulic conductivity

or are contaminated. Tiburones, Barceloneta is a production well that was abandoned

after it became contaminated with carbon tetrachloride from a nearby spill (Hunter and

54

Arbona 1995). The 33 observation wells used in this study range in diameter from 50 to

510 mm, well depth ranges from 6 to 178 m, and average depth-to-water ranges from

0.4 to 127 m.

This study used raw hourly water level and temperature data from 33 non-

pumping observation wells located throughout the aquifers of the main island of Puerto

Rico. The locations are shown in figure 3.1. The upper unit of the NCL, the lower unit of

the NCL, SCP, and the ROP have 12, four, 13, and four stations respectively. Each

station has 12 to 18 months of data. Most years have 8760 hours, leap years have 8784.

If available, data from 2005 were used because this was when many observation wells

set new record highs. All of the data were collected with DH-21 pressure transducers

and are courtesy of the USGS-CFWSC. During bimonthly site visits, the water levels

calculated by the pressure transducer were compared to the water levels measured

independently. At the office, the raw data are subject to several corrections, and the

noon values are published. These corrections will not change the correlations presented

here.

Using a p-value of 0.05 and a sample size of 250, a Pearson correlation

coefficient of around 0.12 is significant. When the sample size reaches 10,000, a

Pearson correlation coefficient of 0.02 is significant. With large sample sizes even

relationships with very low correlation can be significant.

Results

Between 2002 and 2008, in 575 site visits, 85 percent of the time the DH-21 was

within the accepted error tolerance and was not reset to the measured water level. The

unit at Florida 1, Florida operated for five years with no reset. The other extreme was at

Alomar 1, Santa Isabel, where the equipment drifted on average, 36.9 millimeters per

month and was reset on 16 consecutive visits.

55

On 112 visits the water temperature was measured and compared to the live

instrument reading. The live temperature was within 1 °C of the temperature measured

by the electronic thermometer 77 percent of the time. A large temperature error that is

stable is not an obstacle to collecting high quality water level data. Paso Seco 7, Santa

Isabel, operated for a year with an error of 4 °C. It was eventually changed not because

of differences with the measured water level but when it would no longer communicate

with the computer.

The correlations between depth-to-water and water temperature are shown in

Appendix I. There are five stations were the depth-to-water and water temperature have

a Pearson correlation coefficient above 0.85 and four of these are in the upper unit of the

karst NCL. The water level and water temperature data of JBNERR East 1, Salinas are

in figure 3.2. This station has a Pearson correlation coefficient of 0.92. This is the only

station in the SCP that has a Pearson correlation coefficient above 0.85. The area

around the station is mudflats and mangrove swamps. The water level is within one

meter of the land surface and the hydrograph clearly shows that it is affected both by

tides and the cycling of production water wells. Because the water level is controlled by

tides and production wells, this station was excluded from the study.

The hypothesis is not significant. The average Pearson correlation coefficient of

the 12 stations in the upper unit of the karst NCL aquifer is 0.29 with a standard

deviation of 0.62. With the removal of JBNERR East 1, the average of the 12 stations in

the SCP is 0.01 and the standard deviation is 0.50. The p-value is 0.25. The difference

of the average Pearson correlation coefficients between the karst upper unit of the NCL

and the alluvial SCP aquifer is not significant and the null hypothesis cannot be rejected.

56

Figure 3.2. Hourly water level and water temperature of the JBNERR East 1,

Salinas observation well. This station was excluded because the water level is

controlled by the tides and the cycling of production water wells. Data courtesy of

USGS.

The Cbgar, Quebradillas observation well is the more highly correlated station

and the data are in figure 3.3. The four stations in karst NCL aquifer with the highest

correlation between depth-to-water and water temperature are not randomly distributed.

All are in the upper unit of the NCL. The two most highly correlated stations are in the

adjoining municipalities of Quebradillas and Camuy. Municipalities are the equivalent of

counties in the United States. The stations ranked 3rd and 4th are in the adjoining

municipalities of Manatí and Vega Baja. These two areas are at highest risk from

27.1

27.2

27.3

27.40.0

0.5

1.0

1.5

WA

TE

R T

EM

PE

RA

TU

RE

, IN

CE

LS

IUS

WA

TE

R L

EV

EL

, IN

ME

TE

RS

IN

BE

LO

W L

AN

D

SU

RF

AC

E

TIME, FROM 1 OCT 06 TO 30 SEP 07

JBNERR EAST 1, SALINAS, PUERTO RICO

Water Level (Black)

Water Temperature (Gray)

r = 0.92

57

Figure 3.3. Hourly water levels and temperature of the Cbgar, Quebradillas observation

well. This station is the most highly correlated in Puerto Rico. Data courtesy of USGS.

superficial contamination compared both to other parts of the karst NCL and the alluvial

aquifers.

Discussion

In this case it is important to publish the results because it is useful information

for water resource managers. In terms of aquifer vulnerability the upper unit of the NCL

cannot be viewed as a single unit at high risk, instead it needs to be divided and

managed in smaller pieces. This study documents two hot spots that are at higher risk to

superficial contaminants than the upper unit of the NCL as a whole.

Figure 3.4 shows the histograms of the distribution of Pearson correlation

coefficients for the upper unit of the NCL and all other aquifers combined. The width of

21.5

22.0

22.5

23.0

23.5

24.0

24.5121

122

123

124

125

126

127

WA

TE

R T

EM

PE

RA

TU

RE

, IN

CE

LS

IUS

WA

TE

R L

EV

EL

, IN

ME

TE

RS

BE

LO

W L

AN

D S

UR

FA

CE

TIME, FROM 1 JUL 05 TO 31 DEC 06

CBGAR WELL, QUEBRADILLAS, PUERTO RICO

Record High Water Level, 23 years of data

Temperature (Grey)

Water Level (Black ) r = 0.99

58

Figure 3.4. Distribution of the Pearson correlation coefficients between the depth-

to-water and the water temperature.

the bins is 0.4. The hypothesis failed because of the large intra-aquifer variability. For

the upper unit of the NCL 58 percent of the stations are in the two extreme bins, either

the most highly correlated or the least correlated. Outside of

the upper unit of the NCL only 20 percent of the stations are in these two categories.

The model is simplistic. The model predicts that there will be stations with

correlation or no correlation between depth-to-water and water temperature. It cannot

explain stations with an inverse correlation between depth-to-water and water

temperature. Maguayo 2, Dorado is an example of no correlation and the data are

shown in figure 3.5. Tortuguero 3, Vega Baja is an example of an inverse correlation

0.0

0.1

0.2

0.3

0.4

0.5

-1.2 -0.8 -0.4 0 0.4 0.8 1.2

FR

AC

TIO

N

PEARSON CORRELATION COEFFICIENT

DISTRIBUTION OF PEARSON CORRELATION COEFFICIENTS

The solid line is the upper unit of the North Coast Limestone. The dashed line is all other aquifers combined.

59

Figure 3.5. Hourly water levels and water temperature for the Maguayo 2, Dorado

observation well. This is an example of an observation well that has no correlation

between depth-to-water and temperature. Data courtesy of USGS.

between depth-to-water and water temperature and the data are shown in figure 3.6. In

a study with 32 observation wells the municipality of Vega Baja has stations that rank 4th

and 32nd in correlation between depth-to-water and water temperature. Palo Alto 2 has

the fourth highest correlation between water level and water temperature and is 2.6 km

from Tortuguero 3 which is ranked 32nd.

25.2

25.3

25.4

25.56.6

7.0

7.4

7.8

WA

TE

R T

EM

PE

RA

TU

RE

, IN

CE

LS

IUS

WA

TE

R L

EV

EL

, IN

ME

TE

RS

BE

LO

W L

AN

D

SU

RFA

CE

TIME, FROM 1 JAN 05 TO 31 MAR 06

MAGUAYO 2, DORADO, PUERTO RICO

Record High Water Level,13 years of data

r = -0.009

Water Temperature (Gray)

Water Level (Black)

60

Figure 3.6. Hourly water levels and temperature for the Tortuguero 3, Vega Baja

observation well. This is an example of an observation well that has an inverse

correlation between depth-to-water and temperature. Data courtesy of USGS.

The model predicts that non-correlated stations will have a constant temperature

which is clearly not the case. Apparently there are changes in groundwater temperature

that have a period of more than a year that are not associated with changes in water

level. No mechanism has been identified that can explain these long-period patterns

observed in the water-temperature data.

The Cbgar and Zanja 4, Camuy stations are both highly correlated. They are

about 7.4 km apart and they have different connections to the surface. In 18 months

Cbgar had five events that caused the water level to rise, while Zanja 4 had 26. Near

Zanja 4 there are two production wells, Zanja 2 and Zanja 3, which combined pump 31

24.0

24.5

25.0

25.56.8

6.9

7.0

7.1

7.2

7.3

7.4

WA

TE

R T

EM

PE

RA

TU

RE

, IN

CE

LS

IUS

WA

TE

R L

EV

EL

, IN

ME

TE

RS

BE

LO

W L

AN

D

SU

RF

AC

E

TIME, FROM 1 JUL 05 TO 31 DEC 06

TORTUGUERO 3, VEGA BAJA, PUERTO RICO

Record High Water Level, 12 years of data

r = -0.83

Water Temperature (Gray)

Water Level (Black)

61

liters per second (Tucci and Martínez 1995). Both at-risk areas are rolling terrain with no

surface drainage. The Quebradillas-Camuy area was traditionally dairy farms, and the

Manatí-Vega Baja area had pineapple production, but because of access to good

highways, housing construction has increased in both areas in recent years.

Construction of houses and roads will increase the impermeable areas and the runoff

which should cause less water to be returned to the atmosphere via evapotranspiration.

The increased runoff will increase the water that recharges the aquifer but the reduced

travel time may lower the quality of the water that reaches the aquifer.

It is too late to protect the aquifer in Manatí-Vega Baja. Both Hill 2 and Palo Alto

2 were drilled by the USGS-CFWSC to study nitrate contamination. The source of the

nitrates was the fertilizer that was used on the now-abandoned pineapple fields (Conde-

Costas and Gómez-Gómez 1999). Hill 2 sits about 10 m from an ephemeral channel that

terminates in a nearby sinkhole. At both of these observation wells, the correlation

between depth-to-water and water temperature is higher in large rain events than in

small rain events. In addition to the nitrate contamination, between the two observation

wells there is an abandoned pesticide warehouse that has been added to the Superfund

list (Puerto Rico Department of Health 2005). A description of the pesticide warehouse

as having a “semi-confined aquifer” (Puerto Rico Department of Health 2005) is in

conflict with this study, which finds that it is one of the most vulnerable areas in Puerto

Rico. The groundwater flow in this area was modeled by Cherry (2001) and there is no

correlation between the high risk area and a zone of high transmissivity identified in the

modeling study. The utility of the methodology of this study is demonstrated by the fact

that by studying the physics of the aquifer, areas with high intrinsic vulnerability can be

identified. One of the two highest at-risk areas is already contaminated and this confirms

the validity of the technique.

62

Heat can be moved by conduction, convection, or radiation, in an underground

environment there is no radiation, conduction is the transfer of heat between two

materials at different temperatures that are in contact with each other, and convection

uses moving fluids, either liquids or gasses, to move the heat. On July 14th, 2006 at

0200 at the Cbgar well the water level was 121.337 m below land surface, and the water

temperature was 22.48 °C. With 23 years of data, this was the record high water level up

to that point. The sensor for the pressure transducer was 140 m below land surface. A

heavy rain event in Puerto Rico is typically less than 200 mm of rain, and it would be

impossible for conduction alone to affect the temperature of the 19 m of water above the

sensor, convection is needed. There should be an operating mechanism that will cause

the cold recharge water to flow past the sensor.

The Cbgar well is classified as being in an unconfined aquifer (USGS 2015).

Suppose that in fact the aquifer has a layer with a lower hydraulic conductivity, although

not low enough to be classified as a confining layer. After a heavy rain event, the

recharge water would be moving downward and slowly crossing the less permeable

layer. An open well would act as a short circuit, and become the easiest route for the

water to cross the less permeable layer. This well is 168 m deep and is open hole to

within 2 m of the land surface. The rain event would cause radial flow inward towards the

well above the less permeable layer, vertical flow downward in the well to cross the

layer, and radial outward flow below the layer. This is shown in figure 3.7.

A pressure transducer installed too high in an observation well will hang dry in

the air if the water level drops below its level. For this reason, the pressure transducer is

normally installed about 1.5 m lower than the record low water level at the station. The

63

Figure 3.7. Cbgar Well on July 14th, 2006 at 0200. The open hole of

the well allows water to bypass the hypothesized confining layer and

flow by the sensor and would make it more sensitive to the

temperature of the rain event.

methodology of this study, which consists of a sensor at the bottom of the well looking

for changes in temperature that will occur on top of the saturated zone should detect

nothing, unless there is a preferential vertical flow path that brings the water from the top

to deeper into the aquifer. At the two stations with the highest rankings, Cbgar and Zanja

4, the preferential vertical flow path is probably the open-hole well itself. The two stations

ranked 3rd and 4th, Hill 2 and Palo Alto 2, are piezometers that were drilled as part of a

scientific study of nitrate contamination. Both stations are cased with PVC and have

screened intervals only over short distances. Hill 2 is near a sinkhole that is filled with

64

sediments deposited from an ephemeral stream with a drainage basin of 18 ha (0.18

km2) (Conde- Costas and Gómez-Gómez 1999). This station is correlated during heavy

rain events but not during small rain events. The preferential vertical flow path for Hill 2

is probably not the well but sinkhole. In the case of Palo Alto 2, it is not clear where the

preferential vertical flow path is located. The areas at high risk from the movement of

superficial contaminants have only thin soils above the limestone. Further to the east like

in Dorado, the observation wells are drilled in the flat valleys where the limestone is

overlain by alluvium. The presence of the alluvium above the limestone slows the

movement of rain from the surface to the aquifer, and these observation wells show little

or no correlation between depth-to-water and temperature. This is the variability within

the NCL that causes the hypothesis to fail.

This study identified areas in the NCL aquifer that are at high risk from superficial

contaminants. The next stage would be to identify production wells in the high risk areas

and install instrumentation to measure the amount and temperature of the rainfall and

the temperature of the water pumped out of the aquifer. In this manner it should be

possible to directly measure how quickly the rain water reaches the potable water

system. Temperature has the potential to be a useful tool to increase our knowledge of

groundwater resources of Puerto Rico.

Conclusion

This study demonstrated new things can be learned from existing data at stations

that have been visited thousands of times. Using USGS-CWSC data, a comparison was

made between depth-to-water and water temperature with hourly data from 33 non-

pumping observation wells in Puerto Rico. Rainfall is cold, and if it reaches the

observation well before it has reached thermal equilibrium, then there will be a

correlation between depth-to-water and water temperature. The longer the travel time

between the surface and the observation well, the less correlation there will be between

65

groundwater level and water temperature. The hypothesis was that the upper unit of the

karst NCL will have significantly higher correlations between depth-to-water and water

temperature than the alluvial SCP aquifer. The hypothesis is not in agreement with

experimental observations. The observation wells with the highest correlation between

depth-to-water and water temperature are in the upper unit of the NCL but the difference

is not significant because of the size of the intra-aquifer variations. This conclusion can

improve the management of groundwater resources in Puerto Rico because it

demonstrates that the NCL cannot be managed as a single unit but must be divided and

managed in smaller sections. In Puerto Rico, the two regions at the highest risk from

surficial contamination are the sections of the NCL aquifer in Quebradillas-Camuy and

Manatí-Vega Baja. In the hydrogeological literature of Puerto Rico the scarcity of data is

a recurring theme. This study demonstrates that existing groundwater temperature can

be used with new techniques to learn useful things about the water resources of the

island. The authors would like to thank the USGS for the use of the hourly water level

and water temperature data.

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71

Chapter Four

Overall Conclusions

Globally, the management of freshwater resources will be extremely important in

the 21st century. As this is being written in January 2014, drought-related emergencies

have been declared in parts of 11 states in the western United States (Daniel 2014).

Human emissions of greenhouse gasses will cause the average temperature of the

Earth to rise. Global climate change will affect water supply in many parts of the world,

the exact nature of these changes is impossible to predict.

Is the average annual rainfall in Puerto Rico increasing or decreasing? If the

analysis is restricted to the 20th century (1900 to 1999), then there are significant

decreases in rainfall in Puerto Rico. When the analysis includes the first 14 years of the

21st century (2000 to 2013) then there are significant increases in rainfall. Rainfall in

Puerto Rico has decadal-scale patterns that are not fully understood.

The management of fresh-water resources requires data collected in a consistent

manner. Data need to be internally consistent at the same location for decades and to

be externally consistent with data collected in other parts of the world. Data are more

valuable if they are available to the public in all parts of the world. In the early 21st

century the best method to make data available is the Internet.

In the last six years the world has had the largest economic crisis in 70 years. All

over the world governments are looking for places to cut expenses. Globally the largest

provider of hydrologic data on the Internet is the USGS, which has about 8000 gaging

stations in the United States and 712 that have or will be closed due to funding problems

(USGS 2014).

One way to do high quality but cost-effective science is to learn new things from

existing data sources. The core of this doctoral dissertation is two articles that were

designed to be submitted for publication. The first article starts with a simple model,

72

develops two hypotheses, and then tests them seven times on six islands with data that

are publically available on the Internet. The article predicts patterns on thousands of

islands were publically-available data are from sparse to non-existent. The trade winds

blow from the east on thousands of oceanic tropical islands, the hypotheses are that the

consistency of the easterly winds means that compared to the eastern part of the same

island, the western part will have lower relative humidity and a larger diurnal air

temperature cycle.

The hypotheses were verified five of the seven times. The probability that this

would occur by chance is six in a million trials. The western part of oceanic tropical

islands are drier and a have a larger diurnal air temperature cycle. These conditions

affect other aspects of the environment which can be manifested in many ways. In dry

air clouds will form at higher elevation. It may be possible to use NWS radar data to

demonstrate that clouds from at higher elevation in western Puerto Rico. The east-west

gradients in climate may affect the distribution of flora, fauna, bacteria, and fungi. There

may be trees that grow at higher elevation in the western part of the island. One such

tree may be the water-loving common bamboo (Bambusa vulgaris).

Compared to the eastern end of the island, the western end of islands have a

larger diurnal air temperature cycle and are cooler at night. It may be possible to build

buildings that capture this coolness at night and release it during the day. The net result

would be a building that is a comfortable place for human beings but uses less electricity

for air conditioning. On many oceanic tropical islands virtually all electricity is produced

by burning fossil fuels that emit contamination and greenhouse gasses.

The second article uses the correlation between ground-water level and

temperature to identify the areas in Puerto Rico at the highest risk to surficial

contamination. The hypothesis of the study is that the karst upper unit of the NCL as a

unit would be at more risk than non-karst aquifers. Compared to the non-karst SCP

73

aquifer, the upper unit of the karst NCL aquifer does have a higher Pearson correlation

coefficient between ground-water levels and temperatures but the intra-aquifer variability

prevents it from being significant. The area at highest risk is not the karst NCL as a

whole but two smaller areas within it. The two areas at high risk are in the adjoining

municipalities of Quebradillas-Camuy and Manatí-Vega Baja. In areas where the karst

aquifer is overlain by unconsolidated alluvium then the travel time from raindrop to

aquifer recharge is longer and the risk is lower.

The data for the second study was the unpublished hourly ground-water levels

and temperature that the USGS-CWSC collected with pressure transducers. The

temperature data was never intended to be used except with the pressure data to

calculate the water level. The temperature data are the free unintended byproduct of the

switch from floats and counterweights to pressure transducers. The methodology of this

study can probably be applied to other parts of the world. Over the past 20 years, many

hydrologic agencies have switched from floats and counterweights to pressure

transducers. Many of the hydrologic agencies probably have unused temperature data.

In many karst areas of the world there are probably aquifers similar to the NCL of Puerto

Rico. The tropical karst of Puerto Rico has often been compared to China and Southeast

Asia where similar conditions exist on a much larger scale.

This dissertation has been successful in demonstrating how existing data can be

analyzed in new ways to learn new things about water and other natural resources. The

model of how the easterly trade winds shapes the climate should be useful in other

oceanic tropical islands which have less data than Puerto Rico. There are probably are

karst areas in the world where hydrologic agencies already have the temperature data

that can help them determine areas where the ground-water resources are most at risk

from superficial contamination.

74

Literature Cited in Chapter Four

Daniel M. 2014. Major drought for U.S. west, including California. [Internet] Available on

http:earthsky.org/earth/drought-for-u-s-west-including-California (Cited 20

January 2104).

United States Geological Survey (USGS). 2014. USGS threatened and endangered

stations. [Internet] Available on

http://streamstatsags.cr.usgs.gov/ThreatenedGages/ThreatenedGages.html

(Cited 20 January 2014).

75

76

Appendix I Data about the observation wells used in the study of aquifer vulnerability.

______________________________________________________________________

Rank Name ID Cata Munb Aqc Begin Months rd Depth- Visits

to-water

mm/yy (m)

1 Cbgar 182647066552400 pse Quebradillas NCLuf 7/05 18 0.99 127 238

2 Zanja 4 182723066511200 ps Camuy NCLu 8/99 18 0.92 94 169

g JBNERR

East 1 175711066143600 scih Salinas SCPi 10/06 12 0.92 1 87

3 Hill 2 182506055280200 sci Manatí NCLu 12/06 18 0.92 83 83

4 Palo

Alto 2 182614066261500 sci Vega Baja NCLu 6/02 18 0.89 73 47

5 Jobitos 175843066244100 agj Santa Isabel SCP 4/05 16 0.77 12 209

6 Cabo

Rojo P1 180542067084000 ps Cabo Rojo ROPk 7/04 18 0.73 8 145

7 Albergue

de Ninos 180045066381600 orl Ponce SCP 7/05 18 0.67 6 157

8 Griv 182737066370900 ag Arecibo NCLu 4/05 12 0.65 16 276

9 Pampanos

2 182330066185700 ps Vega Alta NCLlm 2/00 18 0.62 14 23

77

Appendix I (continued page 2)

Rank Name ID Cat Mun Aq begin months r Depth- Visits

to-water

(m)

10 Constancia

3 175934066364800 ag Ponce SCP 5/06 12 0.57 3 158

11 Restaurada

8A 175950066344200 ps Ponce SCP 11/05 16 0.34 7 198

12 Bar 1 182657066454700 ag Arecibo NCLu 1/02 18 0.33 49 52

13 Bldg 652 182531066075900 sci Guaynabo NCLu 1/05 18 0.16 2 132

14 A RASA 175833066145800 sci Salinas SCP 8/05 14 0.15 15 224

15 Tiburones 182626066345100 ps Barceloneta NCLu 12/06 18 0.10 89 156

16 Alomar

Oeste 175734066233300 sci Santa Isabel SCP 12/06 18 0.10 5 240

17 Higuillar 4 182620066163403 sci Dorado NCLu 5/05 17 0.06 11 109

18 Gmar 182308066260400 ag Vega Baja NCLl 10/01 12 0.04 13 285

19 Maguayo 2 182548066164401 sci Dorado NCLu 1/05 15 -0.01 7 145

20 Saltos 182422067015100 ps Isabela NCLl 2/07 16 -0.08 12 230

21 Coqui 1 Btr 175809066133100 ps Salinas SCP 8/05 18 -0.09 2 97

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Appendix I (continued page 3)

Rank Name ID Cat Mun Aq Begin Months r Depth- Visits

to-water

(m)

22 Rio

Fajardo 12 181817065382701 sci Fajardo ROP 7/05 12 -0.13 2 97

23 Lve 180156066434000 ps Peñuelas ROP 1/00 18 -0.17 7 166

24 Aguadilla Cement

North 182442067091700 indn Aguadilla NCLl 7/06 12 -0.17 1 233

25 CA-1 181217065453000 sci Naguabo ROP 4/05 18 -0.18 2 127

26 Alomar 1 175829066232200 ag Santa Isabel SCP 9/05 18 -0.36 12 313

27 RASA D 175910066155500 sci Salinas SCP 4/06 12 -0.43 11 148

28 JBNERR

West 1 175721066151400 sci Salinas SCP 8/06 12 -0.47 0.4 86

29 Villodas 175841066102200 ps Guayama SCP 11/99 17 -0.51 7 36

30 Cab 1 180002066261500 ag Juana Díaz SCP 4/00 18 -0.62 11 182

31 Campanilla

Navy 182530066135800 ps Toa Baja NCLu 5/05 18 -0.72 3 255

79

Appendix I (continued page 4)

Rank Name ID Cat Mun Aq Begin Months r Depth Visits

32 Tortuguero

3 182712066251700 sci Vega Baja NCLu 7/05 18 -0.83 7 85

______________________________________________________________________

a Cat is category. h sci is scientific.

b Mun is municipality. i SCP is South Coastal Plain

c Aq is aquifer. j ag is agricultural.

d r is Pearson correlation coefficient. k ROP is rest of Puerto Rico

e ps is public supply l or is orphanage

f NCLu is the upper unit of the North Coast Limestone m NCLl is the lower unit of the North Coast Limestone

g This station was not ranked because the water level is n Ind is industrial

controlled by tides and the pumping of nearby

production wells and not rainfall.