uranium deposit types and classifications€¦ · uranium deposit types and classifications ......
TRANSCRIPT
Uranium deposit types and classifications
Michel CUNEY
UNIVERSITE DE LORRAINE – GEORESSOURCES CREGU – CNRS54 506, Vandoeuvre les NANCY France
� In the late 80’s, a collect of information was organized by the
IAEA with the collaboration of a panel of experts to produce a
geological classification which could be internationnally used
� 15 deposit types were defined and listed in the 1991 Red Book
� The IAEA classification was largely inspired by the work of
F.J.Dahlkamp
The « Red Book »
Joint report OECD -IAEA
Every two years
First publication in 1970
1991 IAEA uranium deposits classification
� 1) Unconformity-related 23� 2) Sandstones 250� 3) Quartz-pebble conglomerates 22� 4) Veins 128� 5) Breccia complexes 1� 6) Intrusive 13� 7) Phosphorites 10� 8) Collapse breccia pipes 10� 9) Volcanic 43� 10) Surficial 16� 11) Metasomatites 12� 12) Metamorphic 10� 13) Lignite-coal 22� 14) Black shales 9� 15) Other types (carbonates) 13 (582)
Deposits were conventionally listed in order of econ omic ranking
� In 1993, Dahlkamp, in his book, “Uranium Ore Deposits”, recognizes 16principal types of uranium deposits and occurrences based on host environment and/or geometry
� More than 40 subtypes and classes were defined
� 1) Unconformity-related (McArthur, Ranger)� 2) Sandstones (Mynkuduk, Arlit)
� 3) Hematite breccia complexes (Olympic Dam)� 4) Quartz-pebble conglomerates (Witwatersrand)
� 5) Veins (Limousin, Czech Republic)
� 6) Intrusive (Rossing, Ilimaussaq)� 7) Volcanic and caldera-related (Streltsovska)
� 8) Metasomatites (Michurinskoye, Lago Real)� 9) Surficial (Yeelirrie, Langer Heinrich)
� 10) Collapse breccia pipes (Arizona Strip)
� 11) Phosphorites (Uncle Sam, Gantour)� 12) Other types (metamorphic, limestones, coal)
� 13) Rock types with elevated U content (pegmatites, granites,black shales)
2012 « Red Book » uranium deposits classification
�In 2009, Dahlkamp indicates in his last book “Uranium
deposits of the world – Asia” that recent information on
uranium deposits and new research data on earlier
established and defined types of uranium deposits justify a
rearrangement and refinement of the classification scheme
which was proposed in 1993 by the author.
�The terminology selected for types and subtypes refers
primarily to the host environment or geotectonic setting of
the types. On this basis, 20 principal types of Udeposits
including some 40 subtypes and classes are separated
2009 Dahlkamp’s classification� 1. Proterozoic unconformity-contact deposits� 2. Proterozoic subunconformity-epimetamorphic deposits� 3. Sandstone deposits� 4.Granite-related deposits � 5. Volcanic deposits � 6. Metasomatite-related deposits � 7. Undifferentiated (meta-)sediment hosted deposits � 8. Collapse breccias pipe deposits� 9. Polymetallic hematite-breccia complex deposits � 10. Paleoproterozoic quartz-pebble conglomerate deposits� 11. Surficial deposits� 12. Intrusive deposits� 13. Uraniferous carbonaceous shale-related stockwork deposits � 14. Uraniferous bituminous cataclastic limestone deposits� 15. Uraniferous carbonaceous lutite (lacustrine) deposits� 16. Uraniferous organic phosphorous deposits � 17. Uraniferous minerochemichal phosphorite deposits � 18. Uraniferous lignite/coal deposits � 19. Uraniferous stratiform black shale deposits � 20. Uraniferous synmetamorphic and contact metamorphic deposits
2009
2010
1. Intrusive 2. Granite-related 3. Polymetallic iron-oxide breccia complex 4. Volcanic-related 5. Metasomatite 6. Metamorphite 7. Proterozoic unconformity 8. Collapse-breccia pipe 9. Sandstone
10. Paleo-quartz-pebble conglomerate 11. Surficial 12. Lignite and coal 13. Carbonate 14. Phosphate 15. Black shale
IAEA uranium deposits classification (2012)
The most commonly used
The deposits are regrouped in 15 types
mainlydefined on the nature of host rock lithology& 39 sub-types
� Sediment/sedimentary basins associations� 9. Sandstone� 10. Paleo-quartz pebble conglomerate� 11. Surficial � 8. Collapse breccia pipe � 7. Proterozoic unconformity � 12. Coal-lignite � 13. Carbonate � 14. Phosphate � 15. Black shales
� Igneous plutonic and volcanic � 2. Granite-related � 4. Volcanic-related� 1.2. Intrusive plutonic� 3. Polymetallic hematite breccia complex
� Metamorphic� 1.1. Intrusive anatectic� 5. Metasomatite� 6. Metamorphite
9. Sandstone (“hosted”) 615
2. Granite-related 128
4. Volcanic-related 117
6. Metamorphite 106
7. Proterozoic unconformity 84
1. Intrusive anatectic - plutonic 81
5. Metasomatite 74
11. Surficial 66
10. Paleo-quartz pebble conglomerate 62
12. Coal-lignite 32
14. Phosphate 41
15. Black shales 43
8. Collapse breccia pipe 16
3. Polymetallic hematite breccia complex 12
13. Carbonate 8
Number of deposits by type
1486 deposits ranked into 15 types:� 1. Intrusive deposits
� anatectic pegmatite-alaskite (1.1) such as those of Rossing (Namibia) and the Bancroft District (Canada), � plutonic (1.2) hosted by quartz monzonite (Bingham Canyon, USA; Chuquicamata, Chile), peralkaline complexes
(Kvanefjeld, Greenland; Pocos de Caldas, Brazil), or carbonatites (Palabora, South Africa; Catalao, Brazil),
� 2. Granite-related deposits (186 over 1486) � endogranitic (2.1): the Crouzille District (France), � perigranitic (2.2) Niederschlema-Alberoda deposit (Germany)
� 3. Polymetallic iron-oxide breccia complex (12 over 1486), Olympic Dam (Australia)� 4. Volcanic-related deposits (119 over 1486)
� (4.1) structure-bound with the Streltsov-Antei deposit (Russia), � (4.2) strata-bound with the Dornod 7 ore zone (Mongolia), � (4.3) volcano-sedimentary with the Anderson Mine (USA).
� 5. Metasomatic deposits (75 over 1486) � Na-metasomatites (5.1) Kirovograd District (Ukraine) and at Lagoa Real (Brazil),� K-metasomatite (5.2) Elkon District (Russia) � skarns (5.3) as at Mary Kathleen in Australia.
� 6. Metamorphite hosted deposits (106 over 1486) � (6.1) stratabound (Forstau, Austria), � (6.2) structure-bound � (6.3) shear zone-bound (Rozna, Czech Republic), � (6.4) Marble-hosted phosphate (Itataia, Brazil).
� 7. Proterozoic unconformity (84 over 1486)� (7.1) unconformity-contact (Cigar Lake, Canada)� (7.2) basement-hosted (Jabiluka, Australia)� (7.3) stratiform fracture-controlled (Chitrial, India
� 8. Collapse -breccia pipe (16 over 1486) Arizona Strip (USA)
IAEA classification
� 9. Sandstone deposits (615 over 1486) � (9.1) basal channels Dalmatovskoye in Russia, � (9.2) tabular bodies (Arlit type, Niger OR Grants type, USA), � (9.3) rollfronts (Wyoming type, USA. Chu-Sarysu, Kazhakstan? South Texas, USA)� (9.4) Tectonic-lithologic Lodève Basin (France)� (9.5) mafic dykes or sills in Proterozoic sandstone, Westmoreland District, Australia)
� 10. Paleo-quartz-pebble conglomerates (62 over 1486) � (10.1) Elliot Lake District (Canada) � (10.2) polymetallic Witwatersrand Basin (South Africa).
� 11. Surficial deposits (63 over 1486) � (11.1) peat-bog (Kamushanovskoye, Kyrgyzstan)� (11.2) Fluvial valley (Yeelirrie, Australia)� (11.3) Lacustrine-playa (Lake Maitland, Australia)� (11.4) Karst cavern (Tyuya-Muyun, Kyrgyzstan)� (11.5) Pedogenic and fracture fill (Beslet, Bulgaria)
� 12. Lignite and coal associated deposits (32 over 1486), � (12.1) stratiform bodies Koldzhat (Kazakhstan), � (12.2) fracture-controlled Freital (Germany).
� 13. Carbonate hosted deposits (9 over 1486) � (13.1) stratabound Tumalappalle (India)� (13.2) cataclastic at Mailuu-Suu (Kyrgyzstan)� (13.2) paleokarst Sanbaqi (China).
� 14. Phosphate deposits (41 over 1486) � (14.1) organic phosphorite at the Mangyshlak Peninsula, Kazakhstan) � (14.2) minerochemical phosphorite Phosphoria Formation, USA),� (14.3.) continental phosphates Bakouma District (Central African Republic)
� 15. Black shale deposits (43 over 1486) � (15.1) stratiform ore bodies (Ranstad, Sweden; Chattanooga Shale, USA)� (15.2) stockworks Ronneburg, Germany; Dzhantuar, Uzbekistan)
IAEA classification (suite)
UDEPO-IAEA database: 1488 uranium deposits/districts from 74 countries
2011 world production: 54.670 t U from about 45 mines for 63.900 t U required
IAEA-NEA Red Book (2003): a mass of naturally occurring
mineral from which uranium could be exploited at present
or in future economic conditions
IAEA-UDEPO: a geological concentration of uranium
no economic connotation, >300 t U, no grade restrictions
Definition of a deposit :
UDEPO database (IAEA)� (UDEPO) http://www-nfcis.iaea.org
� >1,800 Uranium deposits, 74 countries
IAEA classification
�Based essentialy on the nature of the enclosing rocksand the morphology of the deposits,
�Regroup in the same category deposits :
* formed by very different genetic processes* localized in very contrasted geologic environments
�ex.: U deposits disseminated in plutonic rocks comprise:
� those resulting from partial melting, in deep setting with high degree of metamorphism (alaskites from Rössing, Namibia)
� those resulting from extreme crystal fractionation, in surficial setting : apex of peralcaline complexes (Kvanfjeld, Groënland)
Toward a genetic classification
Difficulty to obtain a reliable genetic classification :
� Unsufficient knowledge of the genetic conditions
� Succession of concentration episodes within a single deposit
.with very different mechanisms spanning over a long period of time
�Secondary processes may obscure the primary U .concentration
mechanisms : • metamorphism, ex. : Lagoa Real district in Brazil,
• remobilisation by supergene fluids, ex. : Poços de Caldas, Brésil
The genetic classification proposed here is based on the dominant mechanism supposed to be at the origin of the primary U concentration
A GENETIC CLASSIFICATION OF U-DEPOSITS
I - (M) MAGMATIC
II - (H) HYDROTHERMAL
III - (M) METEORIC WATER INFILTRATION
IV - (S) SYNSEDIMENTARY
V - (E) EVAPOTRANSPIRATION
VI - (O) OTHER TYPES
5 MAIN TYPES
A GENETIC CLASSIFICATION OF U-DEPOSITS (i)- I (M) MAGMATIC
• I.1 (MFC) fractional crystallization peralkaline Kvanefjeld, Greenland 135,000t@ 220ppm
• I.2 (MPM) partial melting granitic pegmatoids Rössing Namibia 246,500tU @300ppm
- II (H) HYDROTHERMAL
• II.1 (HV) hydrothermal-volcanic Streltsovkoye caldera (Russia): 250,000 t U at 0.10%
• II.2 (HG) hydrothermal-granitic Aue-Niederschlema, Germany 100,000 t U
• II.3 (HD) hydrothermal-diagenetic diagenetic brine circulation 3 sub-categories:
•II.3a (HDIa) with intraformational redox control:
o(HDIaTb) tabular Grants region, Colorado >240,000 t U @ 0.09-0.21 % mined
o(HDIaTl) tectonolithologic Lodève basin, France.
o(HDIaCb) dissolution-collapse breccias pipes Gd Canyon Arizona, USA
• II.3b (HDBb) with basement/basin redox control Athabasca, E Alligator River
• II.3c (HDIr) interformational redox boundary, Oklo, Gabon 27,[email protected]%
• II.4 (HMp) hydrothermal-metamorphic Shinkolobwe DRC 25 500tU, 0.40%
A GENETIC CLASSIFICATION OF U-DEPOSITS (ii)
• II.5 (HMt) Hydrothermal-metasomatic• II.5a (HMtNa) Na-metasomatism central Ukraine 180,000 t U
• II.5b (HMtK) K-metasomatism Elkon (Aldan, Russia) > 324,[email protected] % U±Au
• II.5c (HMtSk) Skarn-related contact/regional met. Mary Kathleen [email protected] %
- III (M) METEORIC WATER INFILTRATION with two sub-types:
• III.1 (MB) Basal-type paleovalley or infiltration-type in Russia, Vitim district
• III.2 (MRf) Roll fronts Kazakhstan with over 1 M t U resources
- IV (S) SYNSEDIMENTARY subdivided into 4 major types
• IV.1 (SMs) Mechanical sorting Quartz Pebble Conglomerates (QPC)
• IV.2 (SRtm) Redox trapping in marine environments black shales. Sweden > 1 M t U
• IV.3 (SRtc) Redox trapping in contin envir coal, lignite, peat bog, swamp, anoxic lake
• IV.4 (SCcr) Crystal-chemical and redox trapping phosphorites up to 15-22 M t U
- V (E) EVAPOTRANSPIRATION = calcretes Langer Heinrich, Namibia 63 520 tU @ 510 ppm
- VI (O) OTHER TYPES Olympic Dam Fe-ox Cu-Au(U-Ag) (IOCG) S. Aust. 1.9 MtU @340ppm
I - (M) U deposits related to magmatic processes
I.1 – (MFC) Deposits related to extreme fractional crystallization� All related to peralkaline magmas (granite, syenite, carbonatites)
� Strong incompatible behaviour of U continuously enriched in the residual
liquids together with : Th, Zr, Nb, REE
� Complex and highly refractory U mineral host
� Peralkaline complexes intruded at shallow structural levels
� Located in the apical and most fractionated parts of the plutons
� Main physical-chemical parameters controlling ore body :� (i) Degree of partial melting in the mantle
� (ii) Degree of fractional crystallization
� (iii) Degree of enrichment by late magmatic fluids.
� Ilimausaq (Greenland), 250 000t U @ 300 ppm
60°57’
61°
Kange
rluar
suk
Nunasamaasaq
Kringl
erne
Lakseelv
Naajakasik
Tunulliafik
Nunasamaq
Ilimmaasaq
47°
61°
0 10 20 30 km
GARDAR INTRUSIONS
GARDAR SUPRACRUSTALS
BASEMENT
NARSSÂRSSUKNaNunarssuit
Grennedat-Ika
Inland Ice
Kûngnât Ivigtut
Igaliko
Na
TugtutôqIllimaussaqNarsaq
Kvanefjeld
NunnarsuatsiaqFAULT
M-J LUJAVRITE
ARFVEDSONITE LUJAVRITE
LUJAVRITE TRANSITION ZONE
AEGIRINE LUJAVRITE
KAKORTOKITE &MARGINAL PEGMATITE
NAUJAITE
SODALITE FOYAITE
PULASKITE FOYAITE
ALKALI GRANITE, Qz-SYENITE
AUGITE SYENITE
SUPERFICIAL DEPOSITS
NARSSAQ INTRUSION
GARDAR SUPRACRUSTALS
BASEMENT GRANITE
3 km0 60°57’
61°
Kange
rluar
suk
Nunasamaasaq
Kringl
erne
Lakseelv
Naajakasik
Tunulliafik
Nunasamaq
Ilimmaasaq
47°
61°
0 10 20 30 km
GARDAR INTRUSIONS
GARDAR SUPRACRUSTALS
BASEMENT
NARSSÂRSSUKNaNunarssuit
Grennedat-Ika
Inland Ice
Kûngnât Ivigtut
Igaliko
Na
TugtutôqIllimaussaqNarsaq
47°
61°
0 10 20 30 km
GARDAR INTRUSIONS
GARDAR SUPRACRUSTALS
BASEMENT
NARSSÂRSSUKNaNunarssuit
Grennedat-Ika
Inland Ice
Kûngnât Ivigtut
Igaliko
Na
TugtutôqIllimaussaqNarsaq
Kvanefjeld
NunnarsuatsiaqFAULT
M-J LUJAVRITE
ARFVEDSONITE LUJAVRITE
LUJAVRITE TRANSITION ZONE
AEGIRINE LUJAVRITE
KAKORTOKITE &MARGINAL PEGMATITE
NAUJAITE
SODALITE FOYAITE
PULASKITE FOYAITE
ALKALI GRANITE, Qz-SYENITE
AUGITE SYENITE
SUPERFICIAL DEPOSITS
NARSSAQ INTRUSION
GARDAR SUPRACRUSTALS
BASEMENT GRANITE
3 km0 3 km0
Ilimausacq (Greenland)peralkaline complexe
U mineralization in the most fractionated
part where fluid oversaturation occured:
Simultaneous enrichment in :
U, Th, Zr, REE, Nb,Ta, F …
U in steenstrupine
I.2 – (MPM) Deposits related to partial melting (Rössing)� Fine- to coarse-grained to pegmatitic granites
� Leucocratic (< 2% biotite) and high alkali content (alaskites)
� Anastomosing and vein-like intruded in high grade metasedimentary rocks
� Uraninite >> disseminated in the granites (±betafite)
� Rössing (Namibia) 250 000t U @ 300 ppm
Four main physical-chemical parameters controlling ore body size/grade:
� (i) Structural (collection of the anatectic melt and fluids)
� (ii) Chemical: Skarns PCO2, PH2O� High T shift granite solidus
� (iii) Physical : low redox (graphite, sulfides Rössing F.) prevent U oxd.
� (iv) Supergene enrichment (hexavalent U minerals)
I - (M) U deposits related to magmatic processes
Cross-section of the Rössing deposit
NOSIB ROSSING
after Berning, 1986drill section zero
II - (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• II.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• II.3b (HDBb) with basement/basin redox control
• II.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• II.5a (HMtNa) Na-metasomatism• II.5b (HMtK) K-metasomatism Elkon
• II.5c (HMtSk) Skarn-related
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• II.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• II.3b (HDBb) with basement/basin redox control
• II.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• II.5a (HMtNa) Na-metasomatism• II.5b (HMtK) K-metasomatism Elkon
• II.5c (HMtSk) Skarn-related
Variscan granite
U-deposit projection
Caledonian granite
Marbles
GEOLOGIC MAP OF THE STRELTSOVSKY ORE FIELD
1. Shironoskoye2. Streltsovskoye3. Antei4. Oktabraskoye5.6. Martoskoye7. Malo-Tulukuyev8.9. Yubilenoye10. Vesenney11. 12. Pyatletneye13. KranyKamen14.15. Zherlovoye16. Argunskoye17.18. Dalnee
280 000t U in 18 deposits
5 km
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• II.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• II.3b (HDBb) with basement/basin redox control
• II.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• II.5a (HMtNa) Na-metasomatism• II.5b (HMtK) K-metasomatism Elkon
• II.5c (HMtSk) Skarn-related
BOHEMIANMASSIF
CASTELO BRANCO
U
U
U
HERCYNIAN GRANITES
LIMITS PRETRIASSIC BASEMENT
SHOWINGS
MEDIUM
LARGE
200 400 km0
U VERY LARGE
URANIUM DEPOSITS
MORVAN
VENDEE
LIMOUSIN
MARCHE
MILLEVACHES
FOREZ
MARGERIDE
PONTIVY
KRUTH
WITTICHEN
WÖLSENDORF
BOR
JACHYMOV HORNISLAVKOV
PRZIBRAM
FRIOL . . .
MONTEDERRANO
GUARDASALAMANCA
AVILA
ALBALA
MONESTERIO
VENTA
ANDUJAR
U
U
UU
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
UU
U
UU U
U
ARMORICANMASSIF
BLACK FOREST
U
VIZEU
ALBUQUERQUE
VILLA NUEVADEL FRESNO
CORNWALL U
PENARAN
U
AUE-NIEDERSCHLEMA
CENTRALMASSIF
MENZELSCHWAND
GRANITES & U-DEPOSIT IN THE
EUROPEAN
VARISCAN
BELT
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• II.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• II.3b (HDBb) with basement/basin redox control
• II.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• II.5a (HMtNa) Na-metasomatism• II.5b (HMtK) K-metasomatism Elkon
• II.5c (HMtSk) Skarn-related
(HDTb) –Tabular deposits Grants Uranium Belt
Reduced sandstone
Primary ore lenses
Distribution of primary and remobilized uranium ores in the Morrison FormationThe primary mineralization form tabular elongated lenses suspended within reduced sandstone
N
Oxidized sandstone
Remnant primary ore
Redistributedore
Recaptured Member
Brushy Basin Member
II-3 (HD) Hydrothermal Diagenetic system
Modified from Turner Patterson and Fihman 1986
Intraformational redox boundary
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• II.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• II.3b (HDBb) with basement/basin redox control
• II.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• II.5a (HMtNa) Na-metasomatism• II.5b (HMtK) K-metasomatism Elkon
• II.5c (HMtSk) Skarn-related
Ore-forming fluids
observed in sphalerite, calcite & dolomite :
T : 80°C to 173°C
salinities >9 wt. % NaCl equiv.
most commonly >18 wt. % NaCl equiv.
II-3a (HDIaCb) dissolution-collapse breccias pipes
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• II.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• II.3b (HDBb) with basement/basin redox control
• II.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• II.5a (HMtNa) Na-metasomatism• II.5b (HMtK) K-metasomatism Elkon
• II.5c (HMtSk) Skarn-related
Conceptual fluid percolation model for ATHABASCA unconf. related U-deposits
1 1dolomitizationCa <=> Mg
○○○○○
○○○○○○
○○○○○○
○○○○○
2Na brine 3a
3b3c
4
5-6k
m
EVAPORITES ?
Basin/basementRedox
boundary
II-3BbHydrothermal-Diagenetic
System
Basin/BasementRedox control
Diagenetic brines
150-200°C
30-35 % eq NaCl
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• 2.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• 2.3b (HDBb) with basement/basin redox control
• 2.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• 2.5a (HMtNa) Na-metasomatism• 2.5b (HMtK) K-metasomatism Elkon
• 2.5c (HMtSk) Skarn-related
Oklo - Okélobondo the first redox controlled U-depositsOklo - Okélobondo the first redox controlled U-deposits
100 m
W E
Okélobondo mine
151-2
3-67-9
13
10-16
OK84bis
FA sandstone
MineralizedC1 layer
FB black shales
ArcheanBasemen
t
+ Reactionzones
InterformationalRedox
boundary
II.3 (HD) Hydrothermal - Diagenetic2.3b (HDBb) with basement/basin redox control
Diagenetic fluids :
same T, same
salinities as
unconformity
related deposits
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• 2.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• 2.3b (HDBb) with basement/basin redox control
• 2.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• 2.5a (HMtNa) Na-metasomatism• 2.5b (HMtK) K-metasomatism Elkon
• 2.5c (HMtSk) Skarn-related
� synmetamorphic deposits :U deposit generated during metamorphism, by metamorphic fluids
Criteria for recognition :
� evidences of relation between ore deposition and deformation
� age of metamorphism = age of the ore
� P,T cdts of metamorphism = P,T cdts of ore deposition
� fluid composition reflects host rock composition
II.4 (HMp) hydrothermal-metamorphic
≠ metamorphosed deposits≠ intrametamorphic deposits
II.4 (HMp) hydrothermal-metamorphic
Lufilian Belt
RDC & Zambia
(Shinkolobwe)
II (H) DEPOSITS RELATED TO HYDROTHERMAL FLUIDS• II.1 (HV) hydrothermal-volcanic
• II.2 (HG) hydrothermal-granitic
• II.3 (HD) hydrothermal-diagenetic• 2.3a (HDIa) with intraformational redox control:
• (HDIaTb) tabular
• (HDIaTl) tectonolithologic
• (HDIaCb) dissolution-collapse breccias pipes
• 2.3b (HDBb) with basement/basin redox control
• 2.3c (HDIr) interformational redox boundary
• II.4 (HMp) hydrothermal-metamorphic• II.5 (HMt) Hydrothermal-metasomatic
• 2.5a (HMtNa) Na-metasomatism• 2.5b (HMtK) K-metasomatism Elkon
• 2.5c (HMtSk) Skarn-related
Na-metasomatism is a widespread geological process
occurs in a large variety of conditions,
but only some specific occurrences are associated with U ore genesis.
Affects large volume of rocks, along deep regional structures (several 10s km)
Mainly granites but also metasediments and metavolcanics.
U deposits associated with Na-metasomatism mainly between 2.0 and 1.5 Ga
as best exemplified by central Ukraine (180,000 t U) and Lagoa Real, Brazil
(100,000 t U, 0.12%).
Another Na-U event is associated with the Pan-African–Brazilian orogenesis
(500 ± 50 Ma) with much smaller deposits.
II.5 (HMt) Hydrothermal-metasomatic II.5a (HMtNa) Na-metasomatism
A GENETIC CLASSIFICATION OF U-DEPOSITS
- III (M) METEORIC WATER INFILTRATION with two sub-types:
• III.1 (MB) Basal-type paleovalley or infiltration-type in Russia
• III.2 (MRf) Roll fronts
- IV (S) SYNSEDIMENTARY subdivided into 4 major types
• IV.1 (SMs) Mechanical sorting Quartz Pebble Conglomerates (QPC)
• IV.2 (SRtm) Redox trapping in marine environments black shales. Sweden > 1 M t U
• IV.3 (SRtc) Redox trapping in contin envir coal, lignite, peat bog, swamp, anoxic lake
• IV.4 (SCcr) Crystal-chemical and redox trapping phosphorites up to 15-22 M t U
- V (E) EVAPOTRANSPIRATION = calcretes Langer Heinrich, Namibia 63 520 tU @ 510 ppm
- VI (O) OTHER TYPES Olympic Dam Fe-ox Cu-Au(U-Ag) (IOCG) S. Aust. 1.9 MtU @340ppm
Zonality with Se behind thefront and Mo beyond U and V
III-2 (MRf) Intraformational meteoric fluid infiltration (roll front)
A GENETIC CLASSIFICATION OF U-DEPOSITS (ii)
- III (M) METEORIC WATER INFILTRATION with two sub-types:
• III.1 (MB) Basal-type paleovalley or infiltration-type in Russia, Vitim district
• III.2 (MRf) Roll fronts Kazakhstan with over 1 M t U resources
- IV (S) SYNSEDIMENTARY subdivided into 4 major types
• IV.1 (SMs) Mechanical sorting Quartz Pebble Conglomerates (QPC)
• IV.2 (SRtm) Redox trapping in marine environments black shales. Sweden > 1 M t U
• IV.3 (SRtc) Redox trapping in contin envir coal, lignite, peat bog, swamp, anoxic lake
• IV.4 (SCcr) Crystal-chemical and redox trapping phosphorites up to 15-22 M t U
- V (E) EVAPOTRANSPIRATION = calcretes Langer Heinrich, Namibia 63 520 tU @ 510 ppm
- VI (O) OTHER TYPES Olympic Dam Fe-ox Cu-Au(U-Ag) (IOCG) S. Aust. 1.9 MtU @340ppm
A GENETIC CLASSIFICATION OF U-DEPOSITS
- III (M) METEORIC WATER INFILTRATION with two sub-types:
• III.1 (MB) Basal-type paleovalley or infiltration-type in Russia
• III.2 (MRf) Roll fronts Kazakhstan
- IV (S) SYNSEDIMENTARY subdivided into 4 major types
• IV.1 (SMs) Mechanical sorting Quartz Pebble Conglomerates (QPC)
• IV.2 (SRtm) Redox trapping in marine environments black shales.
• IV.3 (SRtc) Redox trapping in contin envir coal, lignite, peat bog, swamp, anoxic lake
• IV.4 (SCcr) Crystal-chemical and redox trapping phosphorites
- V (E) EVAPOTRANSPIRATION = calcretes
- VI (O) OTHER TYPES Olympic Dam Fe-ox Cu-Au(U-Ag) (IOCG) S. Aust.
A GENETIC CLASSIFICATION OF U-DEPOSITS
- III (M) METEORIC WATER INFILTRATION with two sub-types:
• III.1 (MB) Basal-type paleovalley or infiltration-type in Russia
• III.2 (MRf) Roll fronts Kazakhstan
- IV (S) SYNSEDIMENTARY subdivided into 4 major types
• IV.1 (SMs) Mechanical sorting Quartz Pebble Conglomerates (QPC)
• IV.2 (SRtm) Redox trapping in marine environments black shales.
• IV.3 (SRtc) Redox trapping in contin envir coal, lignite, peat bog, swamp, anoxic lake
• IV.4 (SCcr) Crystal-chemical and redox trapping phosphorites
- V (E) EVAPOTRANSPIRATION = calcretes Langer Heinrich, Namibia
- VI (O) OTHER TYPES Olympic Dam Fe-ox Cu-Au(U-Ag) (IOCG) S. Aust.
Granitebreccia
Geologic Map of the
Olympic DamIron Oxide
Copper-Gold+U (REE)(IOCG)deposit
2 U-richsources
Roxby Dawnsgranite
melting
MELTS / FLUIDS MANTLE
melting
SURFACE WATERSMeteoric
DIAGENETICFLUIDS
Calcretes /Lignite/Coal
Black shalesRollfront
TabularTectonolithologic
Unconformity
-
Breccia Pipes
U deposits relatedto sedimentary
basins
SkarnsAlaskites
Crust PartialMelting
Volcanic
U deposits relatedto magmatic SURFACE WATERS
Meteoric
DIAGENETICFLUIDS
Metamorphicfluids
Calcretes /Lignite/Coal
Tabular
Unconformity
Metamorphic H.T.
Na-metasomatism
Breccia Pipes
Metamorphic L.T.
Silicatemelts
SkarnsAlaskitesCrust partial
to magmatic
Crustal
MA
GM
ATIC
FR
AC
TIO
NAT
IONMAGMATIC
FLUIDS
rocks
MAGMATICFLUIDS
Magmatic-Hydrothermal
Fluids
rocks
Fract. cryst.
IOCG(U)
Veins
/Sea
Groundwaters
Formationwaters
/Sea
Groundwaters
Formationwaters
PhosphatesConglomerates
FluidMIXING
to metamorphismmelting
Subductionfluids
Mantle
U deposits related