Use and Management of Energy Sources Efficiently

Fossil fuelFossil fuels are fuels formed by natural processes such as anaerobic decomposition of buried dead organisms. The age of the organisms and their resulting fossil fuels is typically millions of years, and sometimes exceeds 650 million years. Fossil fuels contain high percentages of carbon and include coal, petroleum, and natural gas. They range from volatile materials with low carbon:hydrogen ratios like methane, to liquid petroleum to nonvolatile materials composed of almost pure carbon, like anthracite coal. Methane can be found in hydrocarbon fields, alone, associated with oil, or in the form of methane clathrates. The theory that fossil fuels formed from the fossilized remains of dead plants by exposure to heat and pressure in the Earth's crust over millions of years (see biogenic theory) was first introduced by Georg Agricola in 1556 and later by Mikhail Lomonosov in the 18th century.Strictly speaking, fossil fuels are a renewable resource. They are continually being formed via natural processes as plants and animals die and then decompose and become trapped beneath sediment. However, fossil fuels are generally considered to be non-renewable resources because they take millions of years to form, and known viable reserves are being depleted much faster than new ones are being made.The use of fossil fuels raises serious environmental concerns. The burning of fossil fuels produces around 21.3 billion tonnes (21.3 gigatonnes) of carbon dioxide (CO2) per year, but it is estimated that natural processes can only absorb about half of that amount, so there is a net increase of 10.65 billion tonnes of atmospheric carbon dioxide per year (one tonne of atmospheric carbon is equivalent to 44/12 or 3.7 tonnes of carbon dioxide). Carbon dioxide is one of the greenhouse gases that enhances radiative forcing and contributes to global warming, causing the average surface temperature of the Earth to rise in response, which the vast majority of climate scientists agree will cause major adverse effects. A global movement towards the generation of renewable energy is therefore under way to help reduce global greenhouse gas emissions.Oil refinery

The oil refinery in Haifa, Israel is capable of processing about 9 million tons (66 million barrels) of crude oil a year. Its two cooling towers are landmarks of the city's skyline.An oil refinery or petroleum refinery is an industrial process plant where crude oil is processed and refined into more useful products such as petroleum naphtha, gasoline, diesel fuel, asphalt base, heating oil, kerosene and liquefied petroleum gas. Oil refineries are typically large, sprawling industrial complexes with extensive piping running throughout, carrying streams of fluids between large chemical processing units. In many ways, oil refineries use much of the technology of, and can be thought of, as types of chemical plants. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot (tank farm) at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products.Raw or unprocessed crude oil is not generally useful in industrial applications, although "light, sweet" (low viscosity, low sulfur) crude oil has been used directly as a burner fuel to produce steam for the propulsion of seagoing vessels. The lighter elements, however, form explosive vapors in the fuel tanks and are therefore hazardous, especially in warships. Instead, the hundreds of different hydrocarbon molecules in crude oil are separated in a refinery into components which can be used as fuels, lubricants, and as feedstocks in petrochemical processes that manufacture such products as plastics, detergents, solvents, elastomers and fibers such as nylon and polyesters.Petroleum fossil fuels are burned in internal combustion engines to provide power for ships, automobiles, aircraft engines, lawn mowers, chainsaws, and other machines. Different boiling points allow the hydrocarbons to be separated by distillation. Since the lighter liquid products are in great demand for use in internal combustion engines, a modern refinery will convert heavy hydrocarbons and lighter gaseous elements into these higher value products.Oil can be used in a variety of ways because it contains hydrocarbons of varying molecular masses, forms and lengths such as paraffins, aromatics, naphthenes (or cycloalkanes), alkenes, dienes, and alkynes. While the molecules in crude oil include different atoms such as sulfur and nitrogen, the hydrocarbons are the most common form of molecules, which are molecules of varying lengths and complexity made of hydrogen and carbon atoms, and a small number of oxygen atoms. The differences in the structure of these molecules account for their varying physical and chemical properties, and it is this variety that makes crude oil useful in a broad range of several applications.Once separated and purified of any contaminants and impurities, the fuel or lubricant can be sold without further processing. Smaller molecules such as isobutane and propylene or butylenes can be recombined to meet specific octane requirements by processes such as alkylation, or less commonly, dimerization. Octane grade of gasoline can also be improved by catalytic reforming, which involves removing hydrogen from hydrocarbons producing compounds with higher octane ratings such as aromatics. Intermediate products such as gasoils can even be reprocessed to break a heavy, long-chained oil into a lighter short-chained one, by various forms of cracking such as fluid catalytic cracking, thermal cracking, and hydrocracking. The final step in gasoline production is the blending of fuels with different octane ratings, vapor pressures, and other properties to meet product specifications.Oil refineries are large scale plants, processing about a hundred thousand to several hundred thousand barrels of crude oil a day. Because of the high capacity, many of the units operate continuously, as opposed to processing in batches, at steady state or nearly steady state for months to years. The high capacity also makes process optimization and advanced process control very desirable.Fossil-fuel power stationA fossil fuel power station burns fossil fuels such as coal, natural gas or petroleum (oil) to produce electricity. Central station fossil-fuel power plants are designed on a large scale for continuous operation. In many countries, such plants provide most of the electrical energy used. Fossil-fuel power stations have rotating machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating internal combustion engine. All plants use the energy extracted from expanding gas - steam or combustion gases. Very few MHD generators have been built which directly convert the energy of moving hot gas into electricity.Byproducts of thermal power plant operation must be considered in their design and operation. Waste heat energy, which remains due to the finite efficiency of the Carnot, Rankine, or Diesel power cycle, is released directly to the atmosphere, directly to river or lake water, or indirectly to the atmosphere using a cooling tower with river or lake water used as a cooling medium. The flue gas from combustion of the fossil fuels is discharged to the air. This gas contains carbon dioxide and water vapor, as well as other substances such as nitrogen oxides (NOx), sulfur oxides (SOx), mercury, traces of other metals, and, for coal-fired plants, fly ash. Solid waste ash from coal-fired boilers must also be removed. Some coal ash can be recycled for building materials.Fossil fueled power stations are major emitters of CO2, a greenhouse gas (GHG) which according to a consensus opinion of scientific organisations is a contributor to global warming as it has been observed over the last 100 years. Per unit of electric energy, brown coal emits about 3 times as much CO2 as natural gas, and black coal emits about twice as much CO2. Carbon capture and storage of emissions is not expected to be available until technology is safe and deployable.In a fossil fuel power plant the chemical energy stored in fossil fuels such as coal, fuel oil, natural gas or oil shale and oxygen of the air is converted successively into thermal energy, mechanical energy and, finally, electrical energy. Each fossil fuel power plant is a complex, custom-designed system. Construction costs, as of 2004, run to US$1,300 per kilowatt, or $650 million for a 500 MWe unit. Multiple generating units may be built at a single site for more efficient use of land, natural resources and labour. Most thermal power stations in the world use fossil fuel, outnumbering nuclear, geothermal, biomass, or solar thermal plants.Heat into mechanical energyThe second law of thermodynamics states that any closed-loop cycle can only convert a fraction of the heat produced during combustion into mechanical work. The rest of the heat, called waste heat, must be released into a cooler environment during the return portion of the cycle. The fraction of heat released into a cooler medium must be equal or larger than the ratio of absolute temperatures of the cooling system (environment) and the heat source (combustion furnace). Raising the furnace temperature improves the efficiency but complicates the design, primarily by the selection of alloys used for construction, making the furnace more expensive. The waste heat cannot be converted into mechanical energy without an even cooler cooling system. However, it may be used in cogeneration plants to heat buildings, produce hot water, or to heat materials on an industrial scale, such as in some oil refineries, plants, and chemical synthesis plants.Coal as fuelCoal is the most abundant fossil fuel on the planet. It is a relatively cheap fuel, with some of the largest deposits in regions that are relatively stable politically, such as China, India and the United States. This contrasts with natural gas and petroleum, the largest deposits of which are located in the politically volatile Persian Gulf. Solid coal cannot directly replace natural gas or petroleum in most applications, petroleum is mostly used for transportation and the natural gas not used for electricity generation is used for space, water and industrial heating. Coal can be converted to gas or liquid fuel, but the efficiencies and economics of such processes can make them unfeasible. Vehicles or heaters may require modification to use coal-derived fuels. Coal can produce more pollution than petroleum or natural gas.As of 2009 the largest coal-fired power station is Taichung Power Plant in Taiwan. The world's most energy-efficient coal-fired power plant is the Avedre Power Station in Denmark.

Taichung coal-fired power plant in Taiwan, the world's largest carbon dioxide emitterGas turbine plants

Currant Creek Power Plant near Mona, Utah is a natural gas fired electrical plant.One type of fossil fuel power plant uses a gas turbine in conjunction with a heat recovery steam generator (HRSG). It is referred to as a combined cycle power plant because it combines the Brayton cycle of the gas turbine with the Rankine cycle of the HRSG. The thermal efficiency of these plants has reached a record heat rate of 5690 Btu/(kWh), or just under 60%, at a facility in Baglan Bay, Wales.The turbines are fueled either with natural gas, syngas or fuel oil. While more efficient and faster to construct (a 1,000 MW plant may be completed in as little as 18 months from start of construction), the economics of such plants is heavily influenced by the volatile cost of fuel, normally natural gas. The combined cycle plants are designed in a variety of configurations composed of the number of gas turbines followed by the steam turbine. For example, a 3-1 combined cycle facility has three gas turbines tied to one steam turbine. The configurations range from (1-1), (2-1), (3-1), (4-1), (5-1), to (6-1)Simple-cycle or open cycle gas turbine plants, without a steam cycle, are sometimes installed as emergency or peaking capacity; their thermal efficiency is much lower. The high running cost per hour is offset by the low capital cost and the intention to run such units only a few hundred hours per year. Other gas turbine plants are installed in stages, with an open cycle gas turbine the first stage and additional turbines or conversion to a closed cycle part of future project plans.Greening of fossil fuel power plantsSeveral methods exist to improve the efficiency of fossil fuel power plants. A frequently used and cost-efficient method is to convert a plant to run on a different fuel. This includes conversions for biomass and waste. Conversions to waste-fired power plants have the benefit of reducing landfilling. In addition, waste-fired power plants can be equipped with material recovery, which is also beneficial to the environment.Regardless of the conversion, a truly green fossil fuel power plant implements carbon capture and storage (CCS). CCS means that the exhaust CO2 is not released into the environment and the fossil fuel power plant becomes an emissionless power plant. A 2006 example of a CCS fossil fuel power plant is the pilot Elsam power station near Esbjerg, Denmark.Low NOx BurnersA common retrofit in fossil fueled power stations is the replacement of original burners with Low NOx burners. Careful consideration of fluid dynamics and flame thermodynamics has enabled substantial reduction in flame temperature, leading to reduced formation of Nitrous Oxides.Clean coal"Clean coal" is the name attributed to a process whereby coal is chemically washed of minerals and impurities, sometimes gasified, burned and the resulting flue gases treated with steam, with the purpose of removing sulfur dioxide, and reburned so as to make the carbon dioxide in the flue gas economically recoverable. The coal industry uses the term "clean coal" to describe technologies designed to enhance both the efficiency and the environmental acceptability of coal extraction, preparation and use, but has provided no specific quantitative limits on any emissions, particularly carbon dioxide. Whereas contaminants like sulfur or mercury can be removed from coal, carbon cannot be effectively removed while still leaving a usable fuel, and clean coal plants without carbon sequestration and storage do not significantly reduce carbon dioxide emissions. James Hansen in an open letter to U.S. President Barack Obama has advocated a "moratorium and phase-out of coal plants that do not capture and store CO2". In his book Storms of My Grandchildren, similarly, Hansen discusses his Declaration of Stewardship the first principle of which requires "a moratorium on coal-fired power plants that do not capture and sequester carbon dioxide".

Hydropower

The 22,500 MW Three Gorges Dam in the People's Republic of China, the largest hydroelectric power station in the world.Hydro-power or water power is power derived from the energy of falling water and running water, which may be harnessed for useful purposes. Since ancient times, hydro-power has been used for irrigation and the operation of various mechanical devices, such as watermills, sawmills, textile mills, dock cranes, domestic lifts, power houses and paint making.Since the early 20th century, the term has been used almost exclusively in conjunction with the modern development of hydro-electric power, which allowed use of distant energy sources. Another method used to transmit energy is by using a trompe, which produces compressed air from falling water. Compressed air could then be piped to power other machinery at a distance from the waterfall. Hydro power is a renewable energy source.Water's power is manifested in hydrology, by the forces of water on the riverbed and banks of a river. When a river is in flood, it is at its most powerful, and moves the greatest amount of sediment. This higher force results in the removal of sediment and other material from the riverbed and banks of the river, locally causing erosion, transport and, with lower flow, sedimentation downstream.Generating methodsHydropower is used primarily to generate electricity. Broad categories include:Conventional (dams)

Turbine row at Los Nihuiles Power Station in Mendoza, ArgentinaMost hydroelectric power comes from the potential energy of dammed water driving a water turbine and generator. The power extracted from the water depends on the volume and on the difference in height between the source and the water's outflow. This height difference is called the head. The amount of potential energy in water is proportional to the head. A large pipe (the "penstock") delivers water to the turbine.Pumped-storageThis method produces electricity to supply high peak demands by moving water between reservoirs at different elevations. At times of low electrical demand, excess generation capacity is used to pump water into the higher reservoir. When there is higher demand, water is released back into the lower reservoir through a turbine. Pumped-storage schemes currently provide the most commercially important means of large-scale grid energy storage and improve the daily capacity factor of the generation system. Pumped storage is not an energy source, and appears as a negative number in listings.Run of the riverRun of the river hydroelectric stations are those with small or no reservoir capacity, so that the water coming from upstream must be used for generation at that moment, or must be allowed to bypass the dam. In the United States, run of the river hydropower could potentially provide 60,000 MW (about 13.7% of total use in 2011 if continuously available).TideA tidal power plant makes use of the daily rise and fall of ocean water due to tides; such sources are highly predictable, and if conditions permit construction of reservoirs, can also be dispatchable to generate power during high demand periods. Less common types of hydro schemes use water's kinetic energy or undammed sources such as undershot waterwheels. Tidal power is viable in a relatively small number of locations around the world. In Great Britain, there are eight sites that could be developed, which have the potential to generate 20% of the electricity used in 2012.

The world's first commercial-scale and grid-connected tidal stream generator SeaGen in Strangford Lough. The strong wake shows the power in the tidal current.UndergroundAn underground power station makes use of a large natural height difference between two waterways, such as a waterfall or mountain lake. An underground tunnel is constructed to take water from the high reservoir to the generating hall built in an underground cavern near the lowest point of the water tunnel and a horizontal tailrace taking water away to the lower outlet waterway.

Geothermal energy

Steam rising from the Nesjavellir Geothermal Power Station in Iceland.Geothermal energy is thermal energy generated and stored in the Earth. Thermal energy is the energy that determines the temperature of matter. The geothermal energy of the Earth's crust originates from the original formation of the planet (20%) and from radioactive decay of minerals (80%). The geothermal gradient, which is the difference in temperature between the core of the planet and its surface, drives a continuous conduction of thermal energy in the form of heat from the core to the surface. Earth's internal heat is thermal energy generated from radioactive decay and continual heat loss from Earth's formation. Temperatures at the coremantle boundary may reach over 4000 C (7,200 F). The high temperature and pressure in Earth's interior cause some rock to melt and solid mantle to behave plastically, resulting in portions of mantle convecting upward since it is lighter than the surrounding rock. Rock and water is heated in the crust, sometimes up to 370 C (700 F).From hot springs, geothermal energy has been used for bathing since Paleolithic times and for space heating since ancient Roman times, but it is now better known for electricity generation. Worldwide, 11,400 megawatts (MW) of geothermal power is online in 24 countries in 2012. An additional 28 gigawatts of direct geothermal heating capacity is installed for district heating, space heating, spas, industrial processes, desalination and agricultural applications in 2010.Geothermal power is cost effective, reliable, sustainable, and environmentally friendly, but has historically been limited to areas near tectonic plate boundaries. Recent technological advances have dramatically expanded the range and size of viable resources, especially for applications such as home heating, opening a potential for widespread exploitation. Geothermal wells release greenhouse gases trapped deep within the earth, but these emissions are much lower per energy unit than those of fossil fuels. As a result, geothermal power has the potential to help mitigate global warming if widely deployed in place of fossil fuels.The Earth's geothermal resources are theoretically more than adequate to supply humanity's energy needs, but only a very small fraction may be profitably exploited. Drilling and exploration for deep resources is very expensive. Forecasts for the future of geothermal power depend on assumptions about technology, energy prices, subsidies, and interest rates. But as a result of government assisted research and industry experience, the cost of generating geothermal power has decreased by 25% over the past two decades. In 2001, geothermal energy cost between two and ten US cents per kWh.As Thermal energy

Ground source heating and coolingLower temperature sources produce the energy equivalent of 100M BBL per year. Sources with temperatures from 30-150 C are used without conversion to electricity for as district heating, greenhouses, fisheries, mineral recovery, industrial process heating and bathing in 75 countries. Heat pumps extract energy from shallow sources at 10-20 C in 43 countries for use in space heating and cooling. Home heating is the fastest-growing means of exploiting geothermal energy, with global annual growth rate of 30% in 2005 and 20% in 2012.Approximately 270 petajoules (PJ) of geothermal heating was used in 2004. More than half went for space heating, and another third for heated pools. The remainder supported industrial and agricultural applications. Global installed capacity was 28 GW, but capacity factors tend to be low (30% on average) since heat is mostly needed in winter. Some 88 PJ for space heating was extracted by an estimated 1.3 million geothermal heat pumps with a total capacity of 15 GW.Heat for these purposes may also be extracted from co-generation at a geothermal electrical plant.Heating is cost-effective at many more sites than electricity generation. At natural hot springs or geysers, water can be piped directly into radiators. In hot, dry ground, earth tubes or downhole heat exchangers can collect the heat. However, even in areas where the ground is colder than room temperature, heat can often be extracted with a geothermal heat pump more cost-effectively and cleanly than by conventional furnaces. These devices draw on much shallower and colder resources than traditional geothermal techniques. They frequently combine functions, including air conditioning, seasonal thermal energy storage, solar energy collection, and electric heating. Heat pumps can be used for space heating essentially anywhere.Iceland is the world leader in direct applications. Some 92.5% of its homes are heated with geothermal energy, saving Iceland over $100 million annually in avoided oil imports. Reykjavk, Iceland has the world's biggest district heating system. Once known as the most polluted city in the world, it is now one of the cleanest.As Electrical energyGeothermal electricity is electricity generated from geothermal energy. Technologies in use include dry steam power plants, flash steam power plants and binary cycle power plants. Geothermal electricity generation is currently used in 24 countries, while geothermal heating is in use in 70 countries.Estimates of the electricity generating potential of geothermal energy vary from 35 to 2,000 GW. Current worldwide installed capacity is 10,715 megawatts (MW), with the largest capacity in the United States (3,086 MW). El Salvador, Kenya, the Philippines, Iceland and Costa Rica generate more than 15 percent of their electricity from geothermal sources.Geothermal power is considered to be sustainable because the heat extraction is small compared with the Earth's heat content. The life cycle greenhouse gas emissions of geothermal electric plants are on average 45 grams of CO2 per kilowatt-hour of electricity, or less than 5 percent of that of conventional coal-fired plants.Geothermal power stations are similar to other steam turbine thermal power stations heat from a fuel source (in geothermal's case, the earth's core) is used to heat water or another working fluid. The working fluid is then used to turn a turbine of a generator, thereby producing electricity. The fluid is then cooled and returned to the heat source.Dry steam power plantsDry steam plants are the simplest and oldest design. They directly use geothermal steam of 150C or greater to turn turbines.Flash steam power plantsFlash steam plants pull deep, high-pressure hot water into lower-pressure tanks and use the resulting flashed steam to drive turbines. They require fluid temperatures of at least 180C, usually more. This is the most common type of plant in operation today.Binary cycle power plantsBinary cycle power plants are the most recent development, and can accept fluid temperatures as low as 57C. The moderately hot geothermal water is passed by a secondary fluid with a much lower boiling point than water. This causes the secondary fluid to flash vaporize, which then drives the turbines. This is the most common type of geothermal electricity plant being constructed today. Both Organic Rankine and Kalina cycles are used. The thermal efficiency of this type plant is typically about 1013%.Wind power

Burbo Bank Offshore Wind Farm, at the entrance to the River Mersey in northwest England.Wind power is the conversion of wind energy into a useful form of energy, such as using wind turbines to produce electrical power, windmills for mechanical power, windpumps for water pumping or drainage, or sails to propel ships.Large wind farms consist of hundreds of individual wind turbines which are connected to the electric power transmission network. For new constructions, onshore wind is an inexpensive source of electricity, competitive with or in many places cheaper than fossil fuel plants. Offshore wind is steadier and stronger than on land, and offshore farms have less visual impact, but construction and maintenance costs are considerably higher. Small onshore wind farms can feed some energy into the grid or provide electricity to isolated off-grid locations.Wind power, as an alternative to fossil fuels, is plentiful, renewable, widely distributed, clean, produces no greenhouse gas emissions during operation and uses little land. The effects on the environment are generally less problematic than those from other power sources. As of 2011, Denmark is generating more than a quarter of its electricity from wind and 83 countries around the world are using wind power to supply the electricity grid. In 2010 wind energy production was over 2.5% of total worldwide electricity usage, and growing rapidly at more than 25% per annum.Wind power is very consistent from year to year but has significant variation over shorter time scales. As the proportion of windpower in a region increases, a need to upgrade the grid, and a lowered ability to supplant conventional production can occur. Power management techniques such as having excess capacity storage, geographically distributed turbines, dispatchable backing sources, storage such as pumped-storage hydroelectricity, exporting and importing power to neighboring areas or reducing demand when wind production is low, can greatly mitigate these problems. In addition, weather forecasting permits the electricity network to be readied for the predictable variations in production that occur. Wind power can be considered a topic in applied eolics.Wind farmsA wind farm is a group of wind turbines in the same location used for production of electricity. A large wind farm may consist of several hundred individual wind turbines distributed over an extended area, but the land between the turbines may be used for agricultural or other purposes. A wind farm may also be located offshore.Almost all large wind turbines have the same design a horizontal axis wind turbine having an upwind rotor with three blades, attached to a nacelle on top of a tall tubular tower.In a wind farm, individual turbines are interconnected with a medium voltage (often 34.5 kV), power collection system and communications network. At a substation, this medium-voltage electric current is increased in voltage with a transformer for connection to the high voltage electric power transmission system.Feeding into gridInduction generators, often used for wind power, require reactive power for excitation so substations used in wind-power collection systems include substantial capacitor banks for power factor correction. Different types of wind turbine generators behave differently during transmission grid disturbances, so extensive modelling of the dynamic electromechanical characteristics of a new wind farm is required by transmission system operators to ensure predictable stable behaviour during system faults (see: Low voltage ride through). In particular, induction generators cannot support the system voltage during faults, unlike steam or hydro turbine-driven synchronous generators. Doubly fed machines generally have more desirable properties for grid interconnection. Transmission systems operators will supply a wind farm developer with a grid code to specify the requirements for interconnection to the transmission grid. This will include power factor, constancy of frequency and dynamic behavior of the wind farm turbines during a system fault.Offshore wind powerOffshore wind power refers to the construction of wind farms in large bodies of water to generate electricity. These installations can utilise the more frequent and powerful winds that are available in these locations and have less aesthetic impact on the landscape than land based projects. However, the construction and the maintenance costs are considerably higher.Siemens and Vestas are the leading turbine suppliers for offshore wind power. DONG Energy, Vattenfall and E.ON are the leading offshore operators. As of October 2010, 3.16 GW of offshore wind power capacity was operational, mainly in Northern Europe. According to BTM Consult, more than 16 GW of additional capacity will be installed before the end of 2014 and the UK and Germany will become the two leading markets. Offshore wind power capacity is expected to reach a total of 75 GW worldwide by 2020, with significant contributions from China and the US.At the end of 2012, 1,662 turbines at 55 offshore wind farms in 10 European countries are generating 18 TWh, which can power almost five million households. As of August 2013 the London Array in the United Kingdom is the largest offshore wind farm in the world at 630 MW. This is followed by the Greater Gabbard Wind Farm (504 MW), also in the UK. The Gwynt y Mr wind farm (576 MW) is the largest project currently under construction.

BiomassBiomass is biological material derived from living, or recently living organisms. It most often refers to plants or plant-based materials which are specifically called lignocellulosic biomass. As an energy source, biomass can either be used directly via combustion to produce heat, or indirectly after converting it to various forms of biofuel. Conversion of biomass to biofuel can be achieved by different methods which are broadly classified into: thermal, chemical, and biochemical methods.Wood remains the largest biomass energy source to date; examples include forest residues (such as dead trees, branches and tree stumps), yard clippings, wood chips and even municipal solid waste. In the second sense, biomass includes plant or animal matter that can be converted into fibers or other industrial chemicals, including biofuels. Industrial biomass can be grown from numerous types of plants, including miscanthus, switchgrass, hemp, corn, poplar, willow, sorghum, sugarcane, bamboo, and a variety of tree species, ranging from eucalyptus to oil palm (palm oil).Plant energy is produced by crops specifically grown for use as fuel that offer high biomass output per hectare with low input energy. Some examples of these plants are wheat, which typically yield 7.58 tonnes of grain per hectare, and straw, which typically yield 3.55 tonnes per hectare in the UK. The grain can be used for liquid transportation fuels while the straw can be burned to produce heat or electricity. Plant biomass can also be degraded from cellulose to glucose through a series of chemical treatments, and the resulting sugar can then be used as a first generation biofuel.Biomass can be converted to other usable forms of energy like methane gas or transportation fuels like ethanol and biodiesel. Rotting garbage, and agricultural and human waste, all release methane gasalso called "landfill gas" or "biogas." Crops, such as corn and sugar cane, can be fermented to produce the transportation fuel, ethanol. Biodiesel, another transportation fuel, can be produced from left-over food products like vegetable oils and animal fats. Also, biomass to liquids (BTLs) and cellulosic ethanol are still under research.The biomass used for electricity generation varies by region. Forest by-products, such as wood residues, are common in the United States. Agricultural waste is common in Mauritius (sugar cane residue) and Southeast Asia (rice husks). Animal husbandry residues, such as poultry litter, are common in the UK.

A cogeneration plant in Metz, France. The station uses waste wood biomass as an energy source, and provides electricity and heat for 30,000 dwellings.Biomass conversion process to useful energyThermal conversionThermal conversion processes use heat as the dominant mechanism to convert biomass into another chemical form. The basic alternatives of combustion (torrefaction, pyrolysis, and gasification) are separated principally by the extent to which the chemical reactions involved are allowed to proceed (mainly controlled by the availability of oxygen and conversion temperature).Energy created by burning biomass (fuel wood) is particularly suited for countries where the fuel wood grows more rapidly, e.g. tropical countries. There are a number of other less common, more experimental or proprietary thermal processes that may offer benefits such as hydrothermal upgrading (HTU) and hydroprocessing. Some have been developed for use on high moisture content biomass, including aqueous slurries, and allow them to be converted into more convenient forms. Some of the applications of thermal conversion are combined heat and power (CHP) and co-firing. In a typical dedicated biomass power plant, efficiencies range from 727% (HHV basis). Biomass cofiring with coal, by contrast, typically occurs at efficiencies near those of the coal combustor (3040%, HHV basis).Chemical conversionA range of chemical processes may be used to convert biomass into other forms, such as to produce a fuel that is more conveniently used, transported or stored, or to exploit some property of the process itself. Many of these processes are based in large part on similar coal-based processes, such as Fischer-Tropsch synthesis, methanol production, olefins (ethylene and propylene), and similar chemical or fuel feedstocks. In most cases, the first step involves gasification, which step generally is the most expensive and involves the greatest technical risk. Biomass is more difficult to feed into a pressure vessel than coal or any liquid. Therefore, biomass gasification is frequently done at atmospheric pressure and causes combustion of biomass to produce a combustible gas consisting of carbon monoxide, hydrogen, and traces of methane. This gas mixture, called a producer gas, can provide fuel for various vital processes, such as internal combustion engines, as well as substitute for furnace oil in direct heat applications. Because any biomass material can undergo gasification, this process is far more attractive than ethanol or biomass production, where only particular biomass materials can be used to produce a fuel. In addition, biomass gasification is a desirable process due to the ease at which it can convert solid waste (such as wastes available on a farm) into producer gas, which is a very usable fuel.Conversion of biomass to biofuel can also be achieved via selective conversion of individual components of biomass. For example cellulose can be converted to intermediate platform chemical such a sorbitol, glucose, hydroxymethylfurfural etc. These chemical are then further reacted to produce hydrogen or hydrocarbon fuels.Biomass also has the potential to be converted to multiple commodity chemicals. Halomethanes have successfully been by produced using a combination of A. fermentans and engineered S. cerevisiae. This method converts NaX salts and unprocessed biomass such as switchgrass, sugar cane, corn stover, or poplar into halomethanes. S-adenosylmethionine which is naturally occurring in S. cerevisiae allows a methyl group to be transferred. Production levels of 150 mg L-1H-1 iodomethane were achieved. At these levels roughly 173000L of capacity would need to be operated just to replace the United States need for iodomethane. However, an advantage of this method is that it uses NaI rather than I2; NaI is significantly less hazardous than I2. This method may be applied to produce ethylene in the future.Biochemical conversionAs biomass is a natural material, many highly efficient biochemical processes have developed in nature to break down the molecules of which biomass is composed, and many of these biochemical conversion processes can be harnessed.Biochemical conversion makes use of the enzymes of bacteria and other microorganisms to break down biomass. In most cases, microorganisms are used to perform the conversion process: anaerobic digestion, fermentation, and composting.

Solar energy

Part of the 354 MW SEGS solar complex in northern San Bernardino County, California, USASolar energy is radiant light and heat from the sun harnessed using a range of ever-evolving technologies such as solar heating, solar photovoltaics, solar thermal electricity, solar architecture and artificial photosynthesis.Solar technologies are broadly characterized as either passive solar or active solar depending on the way they capture, convert and distribute solar energy. Active solar techniques include the use of photovoltaic panels and solar thermal collectors to harness the energy. Passive solar techniques include orienting a building to the Sun, selecting materials with favorable thermal mass or light dispersing properties, and designing spaces that naturally circulate air.In 2011, the International Energy Agency said that "the development of affordable, inexhaustible and clean solar energy technologies will have huge longer-term benefits. It will increase countries energy security through reliance on an indigenous, inexhaustible and mostly import-independent resource, enhance sustainability, reduce pollution, lower the costs of mitigating climate change, and keep fossil fuel prices lower than otherwise. These advantages are global. Hence the additional costs of the incentives for early deployment should be considered learning investments; they must be wisely spent and need to be widely shared".Solar thermalSolar thermal technologies can be used for water heating, space heating, space cooling and process heat generation.Water heatingSolar hot water systems use sunlight to heat water. In low geographical latitudes (below 40 degrees) from 60 to 70% of the domestic hot water use with temperatures up to 60 C can be provided by solar heating systems. The most common types of solar water heaters are evacuated tube collectors (44%) and glazed flat plate collectors (34%) generally used for domestic hot water; and unglazed plastic collectors (21%) used mainly to heat swimming pools.As of 2007, the total installed capacity of solar hot water systems is approximately 154 GW. China is the world leader in their deployment with 70 GW installed as of 2006 and a long term goal of 210 GW by 2020. Israel and Cyprus are the per capita leaders in the use of solar hot water systems with over 90% of homes using them. In the United States, Canada and Australia heating swimming pools is the dominant application of solar hot water with an installed capacity of 18 GW as of 2005.

Solar water heaters facing the Sun to maximize gain.Heating, cooling and ventilationIn the United States, heating, ventilation and air conditioning (HVAC) systems account for 30% (4.65 EJ) of the energy used in commercial buildings and nearly 50% (10.1 EJ) of the energy used in residential buildings. Solar heating, cooling and ventilation technologies can be used to offset a portion of this energy.Thermal mass is any material that can be used to store heatheat from the Sun in the case of solar energy. Common thermal mass materials include stone, cement and water. Historically they have been used in arid climates or warm temperate regions to keep buildings cool by absorbing solar energy during the day and radiating stored heat to the cooler atmosphere at night. However they can be used in cold temperate areas to maintain warmth as well. The size and placement of thermal mass depend on several factors such as climate, daylighting and shading conditions. When properly incorporated, thermal mass maintains space temperatures in a comfortable range and reduces the need for auxiliary heating and cooling equipment.A solar chimney (or thermal chimney, in this context) is a passive solar ventilation system composed of a vertical shaft connecting the interior and exterior of a building. As the chimney warms, the air inside is heated causing an updraft that pulls air through the building. Performance can be improved by using glazing and thermal mass materials in a way that mimics greenhouses.Deciduous trees and plants have been promoted as a means of controlling solar heating and cooling. When planted on the southern side of a building in the northern hemisphere or the northern side in the southern hemisphere, their leaves provide shade during the summer, while the bare limbs allow light to pass during the winter. Since bare, leafless trees shade 1/3 to 1/2 of incident solar radiation, there is a balance between the benefits of summer shading and the corresponding loss of winter heating. In climates with significant heating loads, deciduous trees should not be planted on the Equator facing side of a building because they will interfere with winter solar availability. They can, however, be used on the east and west sides to provide a degree of summer shading without appreciably affecting winter solar gain.Water treatmentSolar distillation can be used to make saline or brackish water potable. The first recorded instance of this was by 16th-century Arab alchemists. A large-scale solar distillation project was first constructed in 1872 in the Chilean mining town of Las Salinas. The plant, which had solar collection area of 4,700 m2, could produce up to 22,700 L per day and operated for 40 years. Individual still designs include single-slope, double-slope (or greenhouse type), vertical, conical, inverted absorber, multi-wick, and multiple effect. These stills can operate in passive, active, or hybrid modes. Double-slope stills are the most economical for decentralized domestic purposes, while active multiple effect units are more suitable for large-scale applications.Solar water disinfection (SODIS) involves exposing water-filled plastic polyethylene terephthalate (PET) bottles to sunlight for several hours. Exposure times vary depending on weather and climate from a minimum of six hours to two days during fully overcast conditions. It is recommended by the World Health Organization as a viable method for household water treatment and safe storage. Over two million people in developing countries use this method for their daily drinking water.Solar energy may be used in a water stabilisation pond to treat waste water without chemicals or electricity. A further environmental advantage is that algae grow in such ponds and consume carbon dioxide in photosynthesis, although algae may produce toxic chemicals that make the water unusable.

Solar water disinfection in IndonesiaProcess heatSolar concentrating technologies such as parabolic dish, trough and Scheffler reflectors can provide process heat for commercial and industrial applications. The first commercial system was the Solar Total Energy Project (STEP) in Shenandoah, Georgia, USA where a field of 114 parabolic dishes provided 50% of the process heating, air conditioning and electrical requirements for a clothing factory. This grid-connected cogeneration system provided 400 kW of electricity plus thermal energy in the form of 401 kW steam and 468 kW chilled water, and had a one hour peak load thermal storage.Evaporation ponds are shallow pools that concentrate dissolved solids through evaporation. The use of evaporation ponds to obtain salt from sea water is one of the oldest applications of solar energy. Modern uses include concentrating brine solutions used in leach mining and removing dissolved solids from waste streams.Clothes lines, clotheshorses, and clothes racks dry clothes through evaporation by wind and sunlight without consuming electricity or gas. In some states of the United States legislation protects the "right to dry" clothes.Unglazed transpired collectors (UTC) are perforated sun-facing walls used for preheating ventilation air. UTCs can raise the incoming air temperature up to 22 C and deliver outlet temperatures of 4560 C. The short payback period of transpired collectors (3 to 12 years) makes them a more cost-effective alternative than glazed collection systems. As of 2003, over 80 systems with a combined collector area of 35,000 m2 had been installed worldwide, including an 860 m2 collector in Costa Rica used for drying coffee beans and a 1,300 m2 collector in Coimbatore, India used for drying marigolds.CookingSolar cookers use sunlight for cooking, drying and pasteurization. They can be grouped into three broad categories: box cookers, panel cookers and reflector cookers. The simplest solar cooker is the box cooker first built by Horace de Saussure in 1767. A basic box cooker consists of an insulated container with a transparent lid. It can be used effectively with partially overcast skies and will typically reach temperatures of 90150 C. Panel cookers use a reflective panel to direct sunlight onto an insulated container and reach temperatures comparable to box cookers. Reflector cookers use various concentrating geometries (dish, trough, Fresnel mirrors) to focus light on a cooking container. These cookers reach temperatures of 315 C and above but require direct light to function properly and must be repositioned to track the Sun.

The Solar Bowl in Auroville, India, concentrates sunlight on a movable receiver to produce steam for cooking.Electricity productionSolar power is the conversion of sunlight into electricity, either directly using photovoltaics (PV), or indirectly using concentrated solar power (CSP). CSP systems use lenses or mirrors and tracking systems to focus a large area of sunlight into a small beam. PV converts light into electric current using the photoelectric effect.Commercial CSP plants were first developed in the 1980s. Since 1985 the eventually 354 MW SEGS CSP installation, in the Mojave Desert of California, is the largest solar power plant in the world. Other large CSP plants include the 150 MW Solnova Solar Power Station and the 100 MW Andasol solar power station, both in Spain. The 250 MW Agua Caliente Solar Project, in the United States, and the 221 MW Charanka Solar Park in India, are the worlds largest photovoltaic plants. Solar projects exceeding 1 GW are being developed, but most of the deployed photovoltaics are in small rooftop arrays of less than 5 kW, which are grid connected using net metering and/or a feed-in tariff.Concentrated solar powerConcentrating Solar Power (CSP) systems use lenses or mirrors and tracking systems to focus a large area of sunlight into a small beam. The concentrated heat is then used as a heat source for a conventional power plant. A wide range of concentrating technologies exists; the most developed are the parabolic trough, the concentrating linear fresnel reflector, the Stirling dish and the solar power tower. Various techniques are used to track the Sun and focus light. In all of these systems a working fluid is heated by the concentrated sunlight, and is then used for power generation or energy storage.PhotovoltaicsA solar cell, or photovoltaic cell (PV), is a device that converts light into electric current using the photoelectric effect. The first solar cell was constructed by Charles Fritts in the 1880s. In 1931 a German engineer, Dr Bruno Lange, developed a photo cell using silver selenide in place of copper oxide. Although the prototype selenium cells converted less than 1% of incident light into electricity, both Ernst Werner von Siemens and James Clerk Maxwell recognized the importance of this discovery. Following the work of Russell Ohl in the 1940s, researchers Gerald Pearson, Calvin Fuller and Daryl Chapin created the silicon solar cell in 1954. These early solar cells cost 286 USD/watt and reached efficiencies of 4.56%. By 2012 available efficiencies exceed 20% and the maximum efficiency of research photovoltaics is over 40%.Fuel productionSolar chemical processes use solar energy to drive chemical reactions. These processes offset energy that would otherwise come from a fossil fuel source and can also convert solar energy into storable and transportable fuels. Solar induced chemical reactions can be divided into thermochemical or photochemical. A variety of fuels can be produced by artificial photosynthesis. The multielectron catalytic chemistry involved in making carbon-based fuels (such as methanol) from reduction of carbon dioxide is challenging; a feasible alternative is hydrogen production from protons, though use of water as the source of electrons (as plants do) requires mastering the multielectron oxidation of two water molecules to molecular oxygen. Some have envisaged working solar fuel plants in coastal metropolitan areas by 2050- the splitting of sea water providing hydrogen to be run through adjacent fuel-cell electric power plants and the pure water by-product going directly into the municipal water system. Another vision involves all human structures covering the earth's surface (i.e., roads, vehicles and buildings) doing photosynthesis more efficiently than plants.Hydrogen production technologies been a significant area of solar chemical research since the 1970s. Aside from electrolysis driven by photovoltaic or photochemical cells, several thermochemical processes have also been explored. One such route uses concentrators to split water into oxygen and hydrogen at high temperatures (2300-2600 C). Another approach uses the heat from solar concentrators to drive the steam reformation of natural gas thereby increasing the overall hydrogen yield compared to conventional reforming methods. Thermochemical cycles characterized by the decomposition and regeneration of reactants present another avenue for hydrogen production. The Solzinc process under development at the Weizmann Institute uses a 1 MW solar furnace to decompose zinc oxide (ZnO) at temperatures above 1200 C. This initial reaction produces pure zinc, which can subsequently be reacted with water to produce hydrogen.