vapor-liquid equilibrium data collection · 2017. 11. 2. · vapor-liquid equilibrium data...
TRANSCRIPT
J. Gmehling
U. Onken
VAPOR-LIQUID EQUILIBRIUM
DATA COLLECTION
Carboxylic Acids, Anhydrides Supplement 1
Chemistry Data Series
Vol. I, Part Sa
Published by DECHEMA Gesellschaft fur Chemische Technik und Biotechnologie e. V.
Executive Editor: Gerhard Kreysa
Bibliographic information published by Die Deutsche Bibliothek
Die Deutsche Bibliothek lists this publication in the Deutsche Nationalbibliographie; detailed bibliographic data is available on the Internet at http://dnb.ddb.de
ISBN: 3-89746-040-8
© DECHEMA Gesellschaft fOr Chemische Technik und Biotechnologie e. V. Postfach 15 01 04, D-60061 Frankfurt am Main, Germany, 2002
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Technical Production: Mitterweger & Partner, Plankstadt
Vapor-Liquid Equilibrium Data Collection
Sa
Carboxylic Acids, Anhydrides
Supplement 1
Tables and diagrams of data for binary and
multicomponent mixtures up to moderate pressures.
Constants of correlation equations for computer use.
J. Gmehling, U. Onken
Technische Chemie
Universitat Oldenburg
Sa
Carboxylic Acids, Anhydrides
Systems with:
Aliphatic and aromatic carboxylic acids
Acetic Acid
Acrylic Acid
Benzoic Acid
Butyric Acid
Chloroacetic Acid
Dichloroacetic Acid
Formic Acid
Hexanoic Acid
Isobutyric Acid
Acetic Anhydride
Maleic Anhydride
Lauric Acid
Methacrylic Acid
Z -9-0ctadecenoic Acid
3-Pentenoic Acid (isomer not specified)
Propionic Acid
Trichloroacetic Acid
Trifluoroacetic Acid
Valeric Acid
Anhydrides
vii
AUTHORS' PREFACE
With this volume we have pleasure in publishing a new supplement of the Vapor
Liquid Equilibrium Data Collection for carboxylic acids and anhydrides as
DECHEMA Chemistry Data Series Volume I Part 5a.
The data in this book are taken from the Dortmund Data Bank and are available in
electronic form. The Dortmund Data Bank covers a wide range of properties in
addition to the V LE, hE, yoo, for example: data bases of the vapor-liquid equilibria
of low boiling substances (HPV), azeotropic data (AZD), gas solubilities (GLE),
solid-liquid equilibria (SLE) and a pure component property data base (PCP). Data
in electronic form can be obtained from DDBST GmbH, Oldenburg, Germany or
DECHEMA e. V., Frankfurt am Main. Data collections for inhouse use are available
from DDBST GmbH; DECHEMA e.V.; FIZ Chemie GmbH, Berlin, Germany and
Aspen Technology, Inc., Cambridge, Massachusetts, USA. DDBST GmbH can
also supply a large program system well suited to handling the data in the data
banks. Online versions of the database are hosted by STN International
(Columbus, Ohio, USA; Karlsruhe, Germany and Tokyo, Japan) and DECHEMA
e.V. (via the Internet).
We would like to thank J. Krafczyk and J. Menke for computer programming
assistance in order to allow publication of data determined under non-isotherm
and non-isobaric conditions. In addition we would like to sincerely thank all those
colleagues who have both supported and continue to support the endeavours of
the thermodynamic group at the University of Oldenburg by delivering V LE data
from their research. At this juncture we would like to request other colleagues in
this field to send us unpublished data and reprints of their publications on
thermophysical properties.
Oldenburg, November 2002
J. Gmehling U. Onken
viii
EXECUTIVE EDITOR'S PREFACE
The aim of DECHEMA e.V., T he Society for Chemical Technology and Biotechnology when it was founded in 1926 was to improve cooperation between
chemist and engineer. As the importance of mathematical modelling, computer simulation and optimisation became apparent in the mid-nineteen-seventies, this
ideal resulted in the production and publication of collections of basic
thermophysical data in both electronic and book form. This is not data that could
have easily found a publisher outside the engineering societies, because of its
sheer volume and limited circle of interest. By its sponsoring and publication of
the DECHEMA Chemistry Data Series DECHEMA e. V. has been associated with
these endevours for over a quarter of a century. Much of the original work to
determine the values obtained was financed by the German Ministry of Research.
lt is to be hoped that publication of this data collection by DECHEMA e. V. in the
DECHEMA Chemistry Data Series will inspire other authors to consider
publishing their collections of thermophysical data. DECHEMA e.V. is always
pleased to assist colleagues from the thermophysical data community in
preparing their results, their studies, their collections and their assessments for
publication. DECHEMA e.V. is always prepared to enlarge the scope of the
DECHEMA Chemistry Data Series and is thus pleased to hear from readers,
designers, scientists and engineers of areas where thermophysical data is not available or scarce. We hope that the end user finds the data of utility and of
interest.
Frankfurt am Main, November 2002 Gerhard Kreysa
CONTENTS6-Vol. I, Part/a
ix
Subjects of Volume I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VI
Author's Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII
Executive Editor's Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VIII
Contents Volume I, Part Sa .................................. IX
Guide to Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI
List of Symbols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXI
References ............................................ XXIII
Data Tables
Carboxylic Acids
Binary Systems
Formic Acid .............................................. .
Trichloroacetic Acid ........................................ 21
Trifluoroacetic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Dichloroacetic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
Chloroacetic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
Acetic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Acrylic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Propionic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166
Methacrylic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219
Butyric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
Isobutyric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250
3-Pentenoic Acid (isomer not specified) . . . . . . . . . . . . . . . . . . . . . . . 260
Valeric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
Hexanoic Acid ........................................... 267
Benzoic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 270
Lauric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 280
Z-9-0ctadecenoic Acid .................................... 283
Ternary Systems ............................................ 284
Quaternary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
Anhydrides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Maleic Anhydride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 306
Acetic Anhydride ......................................... 312
X
Appendix A: Pure Component Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . 329
Appendix B: Dimerization Constants of Carboxlic Acids 347
Formula Index of Binary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349
Formula Index of Ternary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 362
Formula Index of Quaternary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 364
Alphabetical Index of Binary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 365
Alphabetical Index of Ternary Systems ... . .. . ..... . .. . ...... . ...... 378
Alphabetical Index of Quaternary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . 380
028 Sulfur Dioxide C2H•02 Acetic Acid 36
C•Hs03 Acetic Anhydride 312
HN03 Nitric Acid C2HCI302 Trichloroacetic Acid 21-24
C2H3CI02 Chloroacetic Acid 30
C2H•02 Acetic Acid 37
H20•S Sulfuric Acid C2H3CI02 Chloroacetic Acid 31
CCI4 Tetrachloromethane C2H402 Acetic Acid 38-42R
C3Hs02 Propionic Acid 166-172
C.Hs03 Acetic Anhydride 313-319R
cs2 Carbon Disulfide C.H603 Acetic Anhydride 322
C.Ha02 Butyric Acid 236
C,aH3.o2 Z-9-0ctadecenoic Acid 283 11 CHCI3 Chloroform C2HCI302 Trichloroacetic Acid 25
0 """''
C2H2CI202 Dichloroacetic Acid 28 3 c
C2H3CI02 Chloroacetic Acid 32 Ill
C2H•02 Acetic Acid 43 ::J
C•Hs02 Methacrylic Acid 219 a. CD
CH202 Formic Acid C2H3N Acetonitrile 1 ><
C2H•02 Acetic Acid 2-7 0 -Methyl Formate 8-11 OJ
C3H5CI 3-Chloro-1-Propene 12 ::J Ill
C3Hs02 Methyl Acetate 13 """''
'< Propionic Acid 14-16 (/)
C3H1NO N,N-Dimethylformamide (DMF) 17 '< CIJ ro+
CsHsN Pyridine 18-19 CD
3 U) CsH,002 Valeric Acid 20 � CIJ <0
CH3CI Methyl Chloride C.Hs03 Acetic Anhydride 320 "'T1 Ul c.n
0 0 CH31 Methyl Iodide C2H402 Acetic Acid 44 """'
3 C•Hs03 Acetic Anhydride 321 c
CH3N02 Nitromethane c.H2o3 Maleic Anhydride 306 Ill
C2HCI302 Trichloroacetic Acid HN03 Nitric Acid 21-24 ::::::1
CHCI3 Chloroform 25 a. CD
C2HF302 Trifluoroacetic Acid C2H•02 Acetic Acid 27 X
0 C2H2CI202 Dichloroacetic Acid CHCI3 Chloroform 28 .......
CsHs Benzene 29 llJ
C2H3CI02 Chloroacetic Acid HN03 Nitric Acid 30 ::::::1 Ill
H2o.s Sulfuric Acid 31 � CHCI3 Chloroform 32 (J)
'< CsH1o02 N-Pentanoic Acid 33-35 (/J ro+ CsHs Benzene 26 CD
3 C2H3N Acetonitrile CH202 Formic Acid 1 (/J
C2H402 Acetic Acid 45-47
C3Hs02 Propionic Acid 173-174
C•Hs02 Isobutyric Acid 250-251
C2H4CI2 1,2-Dichloroethane C4H602 Methacrylic Acid 220
C2H•02 Acetic Acid 028 Sulfur Dioxide 36
HN03 Nitric Acid 37
CCI4 Tetrachloromethane 38-42R
CHCI3 Chloroform 43
CH202 Formic Acid 2-7
CH31 Methyl Iodide 44
C2HF302 Trifluoroacetic Acid 27
C2H3N Acetonitrile 45-47
C2H51 Ethyl Iodide 48-49
C2H5NO Acetamide 50-51
C3H5CI 3-Chloro-1-Propene 52-53
C3Ha02 Methyl Acetate 54-57
Propionic Acid 58--64R
C3H7Br Propyl Bromide 65--69R
C3H7NO N,N-Dimethylformamide (DMF) 70-71
C4H5CI302 Ethyl Trichloroacetate 72
C4H60 Methacrolein 73
C4Hs02 Methacrylic Acid 74
Vinyl Acetate 75 'T1 C.Ha03
0 Acetic Anhydride 76-79 �
C•Hs02 Butyric Acid 80-82 3 c:
Ethyl Acetate 83-95 Ill
C.HgNO N,N-Dimethylacetamide 96 ::J
C5H5N Pyridine 97-100 a. CD
C5Hs02 Vinyl Propionate 101-102 ><
C5H,o02 Propyl Acetate 103 0 ...... C6H4CI2 a-Dichlorobenzene 104 ro C6H5CI Chlorobenzene 105-106 ::J
Ill CaHs Benzene 107-112R � C6H1o02 Vinyl Butyrate 113-114 (f) CaH,oO• Acetaldehyde Diacetate 115-117
'< C/) -
Ethylene Glycol Diacetate 118 CD
3 (.,) C6H11NO 6-Caprolactam 119 c.n C/) .....
CsH12 Cyclohexane 12Q-123 "'T1 � 0'1
0 1\) 1-Hexene 124 """�:
3 c.H,2o2 Butyl Acetate 125-126 c
Isobutyl Acetate 127-129R Ol
CsH14 Hexane 130 :::J
CsH15N Triethylamine 131-138 Q. CD
C1Ha Toluene 139 X
0 C7H,20• Diethyl Malonate 140 -
C1H,402 Pentyl Acetate 141-143 OJ
C1H1s :::J
Heptane 144-145 Ol CaH,sN Caprylonitrile 146 � CaH,a Octane 147-148 (/)
'< C9H,o02 Benzyl Acetate 149 CIJ -CsH12 lsopropylbenzene 15Q-151 CD
3 CsH2o Nonane 152 CIJ C10H1s Camphene 153
C,2H2o02 Isobornyl Acetate 154
Methyl Formate CH202 Formic Acid 8-11
C2Hsl Ethyl Iodide C2H402 Acetic Acid 48-49
C2HsNO Acetamide C2H402 Acetic Acid 50-51
CsH•02 Acrylic Acid C4Hs02 Methyl Acrylate 155-158
CsHa02 Ethyl Acrylate 159
C7H1202 sec-Butylacrylate 160
C1H1s Heptane 161
CaH,s 1-0ctene 162
CsH1a Octane 163
CsH2o Nonane 164
C10H22 Decane 165
C3H5CI 3-Chloro-1-Propene CH202 Formic Acid 12
C2H•02 Acetic Acid 52-53
CsHs02 Methyl Acetate CH202 Formic Acid 13
C2H•02 Acetic Acid 54-57
C.H802 Butyric Acid 237
Propionic Acid CCI4 Tetrachloromethane 166-172
CH202 Formic Acid 14-16
C2HsN Acetonitrile 173--174
C2H•02 Acetic Acid 58-MR
C3H7Br Propyl Bromide 175-179 "'T1 C.HsOs Acetic Anhydride
0 180--183 ...,.
C•Hs02 Butyric Acid 184-186 3 c::
Ethyl Acetate 187 Ql Isobutyric Acid 188 :::J
CsH5N Pyridine 189--190 c. CD
C5H,o02 Ethyl Propionate 191-198R ><
CsHs Benzene 199-200R 0 ....... CsH7N Aniline 201-202 OJ CsH,oOs Propionic Acid, Anhydride 203-204 :::J
Ql CsH12 Cyclohexane 205--208R
...,. '<
1-Hexene 209 en CsH1202 Butyl Acetate 210
'< en ......
CaH14 Hexane 211 CD
C7Ha 3 c.u Toluene 212-213 ()1 en c.u
C1H1s Heptane 214-218R .., (,) 01
0 ""' C3H1Br Propyl Bromide C2H•02 Acetic Acid 65-69R �
3 C3Hs02 Propionic Acid 175-179 c
C3H1NO N,N-Dimethylformamide (DMF) CH202 Formic Acid 17 ll>
C2H402 Acetic Acid 70--71 ::J
C4H203 Maleic Anhydride CH3N02 Nitromethane 306 a. CD
C•Hs02 Methyl Acrylate 307 X
0 C•Hs02 Ethyl Acetate 308 ......
CsHs Benzene 309 OJ
CaH,o Xylene (isomer not specified) 311 ::J ll>
o-Xylene 310 -< C4H5CI302 Ethyl Trichloroacetate C2H•02 Acetic Acid 72 (/)
'< C4H60 Methacrolein C2H•02 Acetic Acid 73 (J) -
C•Hs02 Methacrylic Acid 221 CD
3 C4Hs02 Methacrylic Acid CHCI3 Chloroform 219 (J)
C2H.CI2 1,2-Dichloroethane 220
C2H402 Acetic Acid 74
C4H60 Methacrolein 221
CsH5CI Chlorobenzene 222
CsH,. Hexane 223
C1H1s Heptane 224
CaH,o Ethyl benzene 225
m-Xylene 226
C8H1402 Butyl Methacrylate 227-228
CaH,s Octane 229
CsH12 Isopropyl benzene 230
CsH2o Nonane 231
C,oH22 Decane 232-233
c,,H24 N-Undecane 234
c,2H2a Dodecane 235
Methyl Acrylate C3H402 Acrylic Acid 155-158
C4H203 Maleic Anhydride 307
Vinyl Acetate C2H402 Acetic Acid 75
C4Ha03 Acetic Anhydride 02S Sulfur Dioxide 312
CC14 Tetrachloromethane 313-319R
cs2 Carbon Disulfide 322
CH3CI Methyl Chloride 320
CH31 Methyl Iodide 321 .., C2H402 Acetic Acid 76-79
0 """"
C3Hs02 Propionic Acid 18Q-183 3 c
C4Hs02 Butyric Acid 238 Ill
Ethyl Acetate 323 :::J
Isobutyric Acid 252 a. CD
CsH1o02 Isopropyl Acetate 324-325 ><
CsH,o04 Acetaldehyde Diacetate 326-328 0 -C7Hs Toluene 329--330 OJ C7H1s Heptane 331 :::J
Ill CsH1o a-Xylene 332 -< CsH,s 1-0ctene 333-335 (f) CsH,s Octane 336-337
'< rJJ .-+
C4Hs02 Butyric Acid cs2 Carbon Disulfide 236 CD
C2H402 Acetic Acid 3 w 80-82 ()1 rJJ ()1
C3Hs02 Methyl Acetate 237 , VJ 01
0 m Propionic Acid 184-186 """''
3 C.Hs03 Acetic Anhydride 238 s::
CsHsN Pyridine 239-240 Ill
CsHs Benzene 241 :::J
CsH7N Aniline 242-243 a. CD
C7Hs Toluene 244 ><
0 C7H,•02 Pentyl Acetate 245 -+1
Propyl Butyrate 246 lJJ
CaH,s02 Butyl Butyrate 247 :::J Ill
C9H2o Nonane 248 -< c,,H2• N-Undecane 249 (f)
'< Ethyl Acetate C2H402 Acetic Acid 83-95 (JJ r-+
C3Hs02 Propionic Acid 187 CD
3 c.H2o3 Maleic Anhydride 308 (JJ C.Hs03 Acetic Anhydride 323
Isobutyric Acid C2H3N Acetonitrile 250--251
C3Hs02 Propionic Acid 188
c.H603 Acetic Anhydride 252
C.H,o02 tert-Butylhydroperoxide 253
CsH12 Cyclohexane 254-255
C7Hs Toluene 256
C7H,. Methylcyclohexane 257
C7H,s Heptane 258-259
c.HgNO N ,N-Dimethylacetamide C2H•02 Acetic Acid 96
C.H,002 tert-Butylhydroperoxide C•Hs02 Isobutyric Acid 253
CsHsN Pyridine CH202 Formic Acid 18-19
C2H•02 Acetic Acid 97-100
C3Hs02 Propionic Acid 189-190
C•Ha02 Butyric Acid 239-240
CsHa02 Ethyl Acrylate C3H402 Acrylic Acid 159
3-Pentenoic Acid (isomer not CsH,o02 3-Pentenoic Acid Methyl Ester (isomer not 260-262 specified) specified)
Vinyl Propionate C2H402 Acetic Acid 101-102
CsH1002 Ethyl Propionate C3Hs02 Propionic Acid 191-198R
Isopropyl Acetate C.H603 Acetic Anhydride 324-325
N-Pentanoic Acid C2H3CI02 Chloroacetic Acid 33-35
Propyl Acetate C2H•02 Acetic Acid 103
Valeric Acid CH202 Formic Acid 20 , 0
C,oH22 Decane 263 ...... 3
C,H2• N-Undecane 264 c
c,2H2s Dodecane 265 D)
c,3H2a Tridecane 266 ::J a.
C6H.CI2 a-Dichlorobenzene C2H•02 Acetic Acid 104 CD
C6HsCI Chlorobenzene C2H•02 Acetic Acid 105-106 X
0 C•Hs02 Methacrylic Acid 222 -
CsHs Benzene C2H2CI202 Dichloroacetic Acid 29 CD
C2H3CI02 Chloroacetic Acid 26 ::J D)
C2H402 Acetic Acid 107-112R -< C3Hs02 Propionic Acid 199-200R (/)
'< c.H2o3 Maleic Anhydride 309 CJ) -C•Ha02 Butyric Acid 241 CD
3 (.:1 C1Hs02 Benzoic Acid 270 0'1 CJ) -...J
C6H7N Aniline CsHs02 Propionic Acid 201-202 "'T1 c.u ()1
0 (X) C4Ha02 Butyric Acid 242-243 """'l
CsH,o02 3-Pentenoic Acid Methyl Ester C5H802 3-Pentenoic Acid (isomer not specified) 26Q-262 3 c
(isomer not specified) m Vinyl Butyrate C2H402 Acetic Acid 113-114
:::J CsH,oOs Propionic Acid, Anhydride C3H602 Propionic Acid 203-204 a.
CD C6H,o04 Acetaldehyde Diacetate C2H402 Acetic Acid 115-117 X
C4Hs0s Acetic Anhydride 326-328 0 ....... Ethylene Glycol Diacetate C2H402 Acetic Acid 118 OJ
C6H,,NO 6-Caprolactam C2H402 Acetic Acid 119 :::J m
CsH12 Cyclohexane C2H402 Acetic Acid 12Q-123 � CsHs02 Propionic Acid 205-208R (j) C4Ha02 Isobutyric Acid 254-255 '<
CJ) 1-Hexene C2H402 Acetic Acid 124
...... CD
CsHs02 Propionic Acid 209 3 CJ)
C6H,202 Butyl Acetate C2H402 Acetic Acid 125-126
CsHs02 Propionic Acid 210
Hexanoic Acid c,,H24 N-Undecane 267
c,2H2s Dodecane 268
C,4Hso Tetradecane 269
Isobutyl Acetate C2H402 Acetic Acid 127-129R
CsH,4 Hexane C2H402 Acetic Acid 130
CsHs02 Propionic Acid 211
C4Hs02 Methacrylic Acid 223
CsH,sN Triethylamine C2H402 Acetic Acid 131-138
C7H5N Benzonitrile C7H602 Benzoic Acid 271-272
C1Hs02 Benzoic Acid CsHs Benzene 270
C1HsN Benzonitrile 271-272
C1Ha Toluene 273-278
c,.H,2o2 Benzyl Benzoate 279
C1Ha Toluene C2H402 Acetic Acid 139
CaHs02 Propionic Acid 212-213
C.HsOa Acetic Anhydride 329-330
C•Ha02 Butyric Acid 244
Isobutyric Acid 256
C1Hs02 Benzoic Acid 273-278
C7H1202 sec-Butylacrylate CaH•02 Acrylic Acid 160
C7H120• Diethyl Malonate C2H•02 Acetic Acid 140 "'T1
C1H,. Methylcyclohexane C.Ha02 Isobutyric Acid 257 0 ...... C1H,.02 Pentyl Acetate C2H•02 Acetic Acid 141-143 3
C.H802 Butyric Acid 245 c
Propyl Butyrate C•Ha02 Butyric Acid 246 Q,)
C1H1s Heptane C2H•02 Acetic Acid 144-145 :::l a.
CaH•D2 Acrylic Acid 161 CD
CaHs02 Propionic Acid ><
214-218R 0
C4H602 Methacrylic Acid 224 -+.
C4Ha03 Acetic Anhydride 331 CO
C•Ha02 Isobutyric Acid :::l
258-259 Q,)
CsH1o Ethyl benzene C•Hs02 Methacrylic Acid 225 ......
'< Xylene (isomer not specified) c.H2o3 Maleic Anhydride 311 (/)
'< m-Xylene C•HsD2 Methacrylic Acid 226 en r-+ a-Xylene c.H2o3 Maleic Anhydride 310 CD
C.Hs03 Acetic Anhydride 332 3 U) c.n en <0
CaH,.o2 Butyl Methacrylate C•Hs02 Methacrylic Acid 227-228 "'T1 c.;! 0>
0 0 C8H15N Caprylonitrile C2H•02 Acetic Acid 146 �
3 CaH1a 1-0ctene C3H•02 Acrylic Acid 162 c
C.Ha03 Acetic Anhydride 333-335 Ill
CaH,s02 Butyl Butyrate C.Ha02 Butyric Acid 247 ::::J
CaH1a Octane C2H402 Acetic Acid 147-148 a. CD
C3H402 Acrylic Acid 163 ><
0 C•Hs02 Methacrylic Acid 229 ....
C.Ha03 Acetic Anhydride 336-337 OJ
CsH1o02 Benzyl Acetate C2H402 Acetic Acid 149 ::::J Ill
CsH12 lsopropylbenzene C2H402 Acetic Acid 15G-151 -< C•Hs02 Methacrylic Acid 230 CJ)
'< CsH2o Nonane C2H402 Acetic Acid 152 (J) r-+
C3H402 Acrylic Acid 164 CD
C4H602 Methacrylic Acid 231 3 (J)
C•Hs02 Butyric Acid 248
C,oH,s Camphene C2H•02 Acetic Acid 153
C,oH22 Decane C3H•02 Acrylic Acid 165
C.H602 Methacrylic Acid 232-233
CsH1o02 Valeric Acid 263
C11H2• N-Undecane C.Ha02 Methacrylic Acid 234
C.H802 Butyric Acid 249
CsH1o02 Valeric Acid 264
CsH1202 Hexanoic Acid 267
C,2H2o02 Isobornyl Acetate C2H•02 Acetic Acid 154
c,2H2402 Lauric Acid c,.H2a02 Myristic Acid 28G-282
c,2H2s Dodecane C4Hs02 Methacrylic Acid 235
C5H,o02 Valeric Acid 265
CsH1202 Hexanoic Acid 268
C,3H2a Tridecane C5H,o02 Valeric Acid 266
c,4H,2o2 Benzyl Benzoate C7Hs02 Benzoic Acid 279
C,4H2a02 Myristic Acid c,2H2402 Lauric Acid 28Q-282
C,4H3o Tetradecane CsH1202 Hexanoic Acid 269
C,aH3402 Z -9-0ctadecenoic Acid cs2 Carbon Disulfide 283
""Tl 0 ..... 3 c:::
Ill
::::::1 a. CD ><
0 -
� ::::::1 Ill .....
'< en
'< CIJ -CD
3 � m CIJ ......
c,.) CCI4 Tetrachloromethane C2H•02 Acetic Acid C3Hs02 Propionic Acid 289 0>
�
CsHs Benzene 290-291
C3H402 Acrylic Acid C2H•02 Acetic Acid 288
CH202 Formic Acid C2H402 Acetic Acid C3Hs02 Methyl Acetate 284
Propionic Acid 285-286
C5H1002 Butyl Formate CsHsN Pyridine 287
C2H•02 Acetic Acid CCI4 Tetrachloromethane C3H402 Acrylic Acid 288
C3Hs02 Methyl Acetate CH202 Formic Acid 284
Propionic Acid CCI4 Tetrachloromethane 289
CH202 Formic Acid 285-286
C3H1Br Propyl Bromide 293-294 ,
C.H802 Butyric Acid 295 0 '""'( Ethyl Acetate 296 3
CsH12 Cyclohexane 298-299 c
C4H802 Butyric Acid CsH1o02 Pentanoic Acid 300 s:u
Ethyl Acetate C6H,4 Hexane 301 ::I c.
CsHs Benzene CCI4 Tetrachloromethane 290-291 CD ><
C3Hs02 Propionic Acid 297 0 ...... C1H1s Heptane C3H402 Acrylic Acid 292
� CsH1o Ethyl benzene CaHs Styrene 302 '""'( C3H402 Acrylic Acid C2H•02 Acetic Acid CCI4 Tetrachloromethane 288 ::I
s:u C1H1s Heptane 292 -<
C3Hs02 Methyl Acetate CH202 Formic Acid C2H402 Acetic Acid 284 CJ) Propionic Acid CCI4 Tetrachloromethane C2H402 Acetic Acid 289
'< (J) ......
CH202 Formic Acid C2H402 Acetic Acid 285-286 CD
C2H402 Acetic Acid CsHs Benzene 297 3 (J)
CsH7Br Propyl Bromide
C•Ha02 Butyric Acid
Ethyl Acetate
CsH12 Cyclohexane
CsH1Br Propyl Bromide C2H402 Acetic Acid
C4Ha02 Butyric Acid C2H•02 Acetic Acid
CsH1o02 Pentanoic Acid
Ethyl Acetate C2H•02 Acetic Acid
CsH1• Hexane
CsHsN Pyridine CH202 Formic Acid
C5H1002 Butyl Formate C5H5N Pyridine
Pentanoic Acid C2H•02 Acetic Acid
CsHs Benzene CCI4 Tetrachloromethane
CsHs02 Propionic Acid
CsH12 Cyclohexane C2H•02 Acetic Acid
CsH1• Hexane C2H•02 Acetic Acid
C1Ha02 Benzoic Acid c12H10 Biphenyl
C1Ha Toluene C7Hs02 Benzoic Acid
C1H1s Heptane CsH•02 Acrylic Acid
CaHa Styrene C2H•02 Acetic Acid
CsH10 Ethyl benzene CaHa Styrene
C12H1o Biphenyl C1Ha Toluene
C2H•02 Acetic Acid
C2H402 Acetic Acid
C2H402 Acetic Acid
C2H402 Acetic Acid
CsHs02 Propionic Acid
CsHs02 Propionic Acid
C2H•02 Acetic Acid
CsHs02 Propionic Acid
C2H402 Acetic Acid
CsH1o02 Butyl Formate
CH202 Formic Acid
C4H802 Butyric Acid
C2H402 Acetic Acid
C2H402 Acetic Acid
CsHs02 Propionic Acid
C.H802 Ethyl Acetate
C1Ha Toluene
C12H1o Biphenyl
C2H402 Acetic Acid
CaH1o Ethylbenzene
C2H•02 Acetic Acid
C1Hs02 Benzoic Acid
293-294
295
296
298-299
293-294
295
300
296
301
287
287
300
29Q-291
297
298-299
301
303-304
303-304
292
302
302
303-304
'"Tl 0 ....,. 3 c:
Ill
::J a. CD ><
0 .......
roi ....,. ::J Ill ....,.
'< (/)
'< (J) ..... CD
3 (J)
C.:l 0> C.:l
C2H402 Acetic Acid C•Ha02 Butyric Acid CsH1o02 N-Pentanoic Acid CsH1202 lsocaproic Acid 305 (4-Methylpentanoic Acid)
.,c.u 0 0> """'' � 3
C4H802 Butyric Acid CsH,o02 N-Pentanoic Acid CsH1202 lsocaproic Acid C2H•02 Acetic Acid 305 c::
(4-Methylpentanoic Dl Acid)
:::::s
CsH1o02 N-Pentanoic Acid CsH1202 lsocaproic Acid C2H•02 Acetic Acid C.Ha02 Butyric Acid 305 Q. (4-Methylpentanoic Acid) CD
>< CsH1202 lsocaproic Acid (4- C2H•02 Acetic Acid C•Ha02 Butyric Acid CsH1o02 N-Pentanoic Acid 305
Methylpentanoic Acid) 0 .......
0 c:: Dl .-+ CD """'' :::::s Dl """''
'< (J)
'< CIJ .-+ CD
3 CIJ
Acetaldehyde Diacetate CsH,o04 Acetic Acid C2H402 115-117
Acetic Anhydride C4Hs03 326-328
Acetamide C2H5NO Acetic Acid C2H402 50-51
Acetic Acid C2H402 Acetaldehyde Diacetate CsH,o04 115-117
Acetamide C2H5NO 5Q--51
Acetic Anhydride C4Hs03 76-79
Acetonitrile C2H3N 45-47
Benzene CsHs 107-112R
Benzyl Acetate CsH1o02 149
Butyl Acetate CsH1202 125-126 )> Butyric Acid C4Hs02 80-82 "C Camphene C,oH,s
:::r 153 Dl
6-Caprolactam C6H11NO 119 0" CD
Caprylonitrile CsH,sN 146 .-+
(') 3-Chloro-1-Propene C3HsCI 52-53 Dl
Chlorobenzene C6H5CI 105-106 ::::::1
Chloroform CHCI3 43 0. CD
Cyclohexane CsH12 12Q--123 ><
o-Dichlorobenzene C6H4CI2 104 0 .......
Diethyl Malonate C7H1204 140 Ill N ,N-Dimethylacetamide C4H9NO 96 ::::::1
Dl N,N-Dimethylformamide (DMF) C3H7NO 70-71
"""'' '<
Ethyl Acetate C4Hs02 83-95 (j) Ethyl Iodide C2Hsl 48-49
'< C/J .-+
Ethyl Trichloroacetate C4HsCI302 72 CD
3 Ul Ethylene Glycol Diacetate CsH,o04 118 0> C/) 01
Formic Acid CH202 2-7 )> (,) 0'>
"0 0'> Heptane C1H1s 144-145 ::::r
Hexane CaH,4 130 D) o-
1-Hexene CsH12 124 CD !:!':
Isobornyl Acetate C,2H2o02 154 (') Isobutyl Acetate 2oH1202 127-129R
D)
lsopropylbenzene C9H12 150-151 ::::::l 0.
Methacrolein C4H60 73 CD ><
Methacrylic Acid C4Hs02 74 0
Methyl Acetate CsHa02 54-57 ......
Methyl Iodide CH31 44 OJ ::::::l
Nitric Acid HNOs 37 D)
Nonane C9H2o 152 -< Octane CaH,e 147-148 (J)
'< Pentyl Acetate C1H,402 141-143 en -Propionic Acid CsHa02 58-{)4R
CD
3 Propyl Acetate CsH1002 103 en Propyl Bromide CsH1Br 65-{)9R
Pyridine CsHsN 97-100
Sulfur Dioxide 02S 36
Tetrachloromethane CC14 38-42R
Toluene C1Ha 139
Triethylamine CaH,sN 131-138
Trifluoroacetic Acid C2HFs02 27
Vinyl Acetate C4Hs02 75
Vinyl Butyrate CaH,o02 113-114
Vinyl Propionate CsHa02 101-102
Acetic Anhydride C.HsOs Acetaldehyde Diacetate CsH,oO• 326-328
Acetic Acid C2H402 76-79
Butyric Acid C4H802 238
Carbon Disulfide cs2 322
Ethyl Acetate C•Ha02 323
Heptane C7H1s 331
Isobutyric Acid C•Ha02 252
Isopropyl Acetate CsH1o02 324-325
Methyl Chloride CH3CI 320 )> Methyl Iodide CH31 321 "'C
:::J"' Octane CaH1a 336-337 Ill
1-0ctene CaH1s 333-335 C" CD
Propionic Acid CsHs02 .-+
180-183 () Sulfur Dioxide 028 312 Ill
Tetrachloromethane CCI4 313-319R ::J
Toluene C7Ha 329-330 a. CD
o-Xylene CsH1o 332 ><
Acetonitrile C2HsN Acetic Acid C2H•02 45-47 0 -Formic Acid CH202 1 OJ Isobutyric Acid C.H802 25D-251 ::J
Ill
Propionic Acid CsHs02 173-174 -< Acrylic Acid C3H402 sec-Butylacrylate C7H1202 160 (j)
Decane C,oH22 165 '< CJ) .-+
Ethyl Acrylate CsHa02 159 CD
Heptane C7H1s 3 Ul 161 0) CJ) -....!
Methyl Acrylate c.H6o2 155-158 )> (,) 0>
"0 (X) Nonane CsH2o 164 ::::r
Octane CaH1a 163 � 0"'
1-0ctene CaH,6 162 CD �
Aniline C6H7N Butyric Acid C.H802 242-243 (") Propionic Acid C3H602 201-202
�
Benzene C6H6 Acetic Acid C2H•02 107-112R ::J a.
Benzoic Acid C7H502 270 CD ><
Butyric Acid C•Ha02 241 0
Chloroacetic Acid C2H3CI02 26 ......
Dichloroacetic Acid C2H2CI202 29 OJ ::J
Maleic Anhydride c.H2o3 309 � Propionic Acid C3H602 199-200R �
Benzoic Acid C7H602 Benzene C6H6 270 (J) '<
Benzonitrile C7H5N 271-272 C/) ..... Benzyl Benzoate c,.H,2o2 279
CD
3 Toluene C7Ha 273-278 C/)
Benzonitrile C7H5N Benzoic Acid C7H602 271-272
Benzyl Acetate CsH1o02 Acetic Acid C2H•02 149
Benzyl Benzoate c,.H,2o2 Benzoic Acid C7H602 279
Butyl Acetate C6H,202 Acetic Acid C2H402 125-126
Propionic Acid C3H602 210
Butyl Butyrate CaH,602 Butyric Acid C•Ha02 247
Butyl Methacrylate CaH,.o2 Methacrylic Acid c.H6o2 227-228
sec-Butylacrylate C7H1202 Acrylic Acid C3H402 160
tert-Butylhydroperoxide c.H1002 Isobutyric Acid C.H802 253
Butyric Acid C•Ha02 Acetic Acid C2H402 80-82
Acetic Anhydride C•Hs03 238
Aniline C6H7N 242-243
Benzene CsHs 241
Butyl Butyrate CaH1s02 247
Carbon Disulfide cs2 236
Methyl Acetate C3Hs02 237
Nonane CsH2o 248
Pentyl Acetate C1H,.02 245
Propionic Acid C3Hs02 184-186
Propyl Butyrate C1H,.02 246 )>
lJ Pyridine C5H5N 239-240 ::::r
Toluene C1Ha 244 Q) 0"
N-Undecane C,H2• 249 CD r-+ Camphene C,oH,s Acetic Acid C2H402 153 (")
Q) 6-Caprolactam C6H,NO Acetic Acid C2H•02 119
--
Caprylonitrile CaH,sN Acetic Acid C2H•02 146 :::J a.
Carbon Disulfide cs2 Acetic Anhydride C4H603 322 CD ><
Butyric Acid C•Ha02 236 0
Z -9-0ctadecenoic Acid C,aH3402 283 -
3-Chloro-1-Propene C3H5CI Acetic Acid C2H402 52-53 OJ
Formic Acid CH202 12 :::J Q) """�:
Chloroacetic Acid C2H3CI02 Benzene CsHs 26 '< Chloroform CHCI3 32 en
'< Nitric Acid HN03 30 C/J r-+ N-Pentanoic Acid CsH1o02 33-35 CD
Sulfuric Acid H20•S 31 3 U) Ol C/J CO
Chlorobenzene CsHsCI Acetic Acid C2H402 105-106 )> (,) -...j
"0 0 Methacrylic Acid C4Hs02 222 ::r
Chloroform CHCI3 Acetic Acid C2H402 43 Q,) 0"
Chloroacetic Acid C2H3CI02 32 CD -Dichloroacetic Acid CzHzCizOz 28 () Methacrylic Acid C4Hs0z 219
Q,)
Trichloroacetic Acid C2HCI302 25 ::J 0.
Cyclohexane CsH12 Acetic Acid C2H402 120-123 CD ><
Isobutyric Acid C4Ha02 254-255 0
Propionic Acid C3Hs0z 205-208R -+.
Decane C,oH22 Acrylic Acid C3H402 165 OJ ::J
Methacrylic Acid C4Hs0z 232-233 Q,) � Valeric Acid CsH,oOz 263 '<
Dichloroacetic Acid CzHzCI202 Benzene CsHs 29 (/) '<
Chloroform CHCI3 28 en -a-Dichlorobenzene C6H4CI2 Acetic Acid CzH402 104
CD
3 1,2-Dichloroethane C2H4Ciz Methacrylic Acid C4Hs02 220 en Diethyl Malonate C7H1204 Acetic Acid C2H402 140
N,N-Dimethylacetamide C4H9NO Acetic Acid C2H402 96
N,N-Dimethylformamide (DMF) C3H7NO Acetic Acid C2H402 70-71
Formic Acid CH202 17
Dodecane C,zHzs Hexanoic Acid CsH,zOz 268
Methacrylic Acid C4Hs02 235
Valeric Acid CsH,o02 265
Ethyl Acetate C4Ha02 Acetic Acid CzH40z 83-95
Acetic Anhydride C4Hs03 323
Maleic Anhydride C4H203 308
Propionic Acid C3Ha02 187
Ethyl Acrylate CsHa02 Acrylic Acid C3H402 159
Ethyl Iodide C2H51 Acetic Acid C2H402 48-49
Ethyl Propionate CsH1o02 Propionic Acid C3Ha02 191-198R
Ethyl Trichloroacetate C4HsCI302 Acetic Acid C2H402 72
Ethyl benzene CaH1o Methacrylic Acid C4H602 225
Ethylene Glycol Diacetate C6H,o04 Acetic Acid C2H402 118
Formic Acid CH202 Acetic Acid C2H402 2-7
Acetonitrile C2H3N 1 )> 3-Chloro-1-Propene C3H5CI 12 "'0
:::J"' N,N-Dimethylformamide (DMF) C3H7NO 17 Ill
Methyl Acetate C3Ha02 13 0" CD
Methyl Formate C2H402 8-11 -(')
Propionic Acid C3Ha02 14-16 Ill
Pyridine C5H5N 18-19 ::J
Valeric Acid CsH1o02 20 a. CD
Heptane C7H1a Acetic Acid C2H402 144-145 X
Acetic Anhydride C4Ha03 331 0 ....., Acrylic Acid C3H402 161 OJ Isobutyric Acid C4Hs02 258-259 ::J
Ill
Methacrylic Acid C4Ha02 224 -< Propionic Acid C3Ha02 214-218R (J)
Hexane CaH,4 Acetic Acid C2H402 130 '< (/J -
Methacrylic Acid C4Ha02 223 CD
3 (.:> Propionic Acid C3Ha02 211 "'-I (/J .....
Hexanoic Acid CsH1202 Dodecane c,2H2s 268 )> C.:l ""-.I
"'0 1\) Tetradecane C,.Hso 269 :::J'"
N-Undecane C,H2• 267 Q) 0"
1-Hexene CsH12 Acetic Acid C2H402 124 CD .-+
Propionic Acid CsHs02 209 (') Isobornyl Acetate C,2H2o02 Acetic Acid C2H402 154
Q) -
Isobutyl Acetate CsH1202 Acetic Acid C2H402 127-129R :::J a.
Isobutyric Acid C•Hs02 Acetic Anhydride C4H60s 252 CD X
Acetonitrile C2HsN 250-251 0
tert-Butylhydroperoxide C.H,o02 253 .....,
Cyclohexane CsH12 254-255 Ill :::J
Heptane C7H1s 258-259 Q) ""'I Methylcyclohexane C7H,. 257 '<
Propionic Acid CsHs02 188 (J) '<
Toluene C7Ha 256 C/J .-+
Isopropyl Acetate CsH1o02 Acetic Anhydride C.HsOs 324-325 CD
3 Isopropyl benzene CsH12 Acetic Acid C2H402 150-151 C/J
Methacrylic Acid C•Hs02 230
Lauric Acid c,2H2.o2 Myristic Acid c,.H2s02 280-282
Maleic Anhydride c.H20a Benzene CsHs 309
Ethyl Acetate C•Hs02 308
Methyl Acrylate C•Hs02 307
Nitromethane CH3N02 306
Xylene (isomer not specified) CaH,o 311
a-Xylene CsH1o 310
Methacrolein C4H60 Acetic Acid C2H•02 73
Methacrylic Acid C•Hs02 221
Methacrylic Acid C4H602 Acetic Acid C2H402 74
Butyl Methacrylate CaH1402 227-228
Chlorobenzene CsHsCI 222
Chloroform CHCI3 219
Decane C1oH22 232-233
1 ,2-Dichloroethane C2H•CI2 220
Dodecane c12H2s 235
Ethyl benzene CaH1o 225
Heptane C7H1s 224 )>
""0 Hexane CsH1• 223 ::::r
lsopropylbenzene C9H12 230 Ill 0'"
Methacrolein C4H60 221 CD ..... Nonane C9H2o 231 (')
Ill Octane CaH1a 229
N-Undecane C11H2• 234 ::::::1 c.
m-Xylene CaH1o 226 CD X
Methyl Acetate C3Hs02 Acetic Acid C2H402 54-57 0
Butyric Acid C4H802 237 ......
Formic Acid CH202 13 CD
Methyl Acrylate C•Hs02 Acrylic Acid C3H402 155-158 ::::::1 Ill .,
Maleic Anhydride c.H2o3 307 '< Methyl Chloride CH3CI Acetic Anhydride C.Hs03 320 (j)
'< Methyl Formate C2H402 Formic Acid CH202 8-11 en ..... Methyl Iodide CH31 Acetic Acid C2H402 44 CD
C.Hs03 3 Vl Acetic Anhydride 321 -....! en Vl
Methylcyclohexane C7H,. Isobutyric Acid C•Ha02 257 )> (,) -..,J "'0 .j:>.
Myristic Acid c,.H2a02 Lauric Acid c,2H2402 28D-282 :::J"'
Nitric Acid HN03 Acetic Acid C2H402 37 Ill 0"
Chloroacetic Acid C2H3CI02 30 CD .-+
Trichloroacetic Acid C2HCI302 21-24 (") Nitromethane CH3N02 Maleic Anhydride c.H2o3 306
Ill
Nonane CsH2o Acetic Acid C2H•02 152 ::l a.
Acrylic Acid C3H.02 164 CD X
Butyric Acid C.H802 248 0
Methacrylic Acid C•Hs02 231 .......
Z -9-0ctadecenoic Acid C,aH3.02 Carbon Disulfide cs2 283 CD ::l
Octane CaH,a Acetic Acid C2H•02 147-148 Ill """' Acetic Anhydride C.H603 336-337 '<
Acrylic Acid C3H402 163 en '<
Methacrylic Acid C.H602 229 (/) .-+
1-0ctene CaH,s Acetic Anhydride C4H603 333-335 CD
3 Acrylic Acid C3H402 162 en
N-Pentanoic Acid CsH1o02 Chloroacetic Acid C2H3CI02 33-35
3-Pentenoic Acid (isomer not CsHa02 3-Pentenoic Acid Methyl Ester CsH,a02 26Q-262 specified) (isomer not specified)
3-Pentenoic Acid Methyl Ester C6H1002 3-Pentenoic Acid (isomer not CsHa02 26Q-262 (isomer not specified) specified)
Pentyl Acetate C1H,.o2 Acetic Acid C2H•02 141-143
Butyric Acid C•Ha02 245
Propionic Acid C3Hs02 Acetic Acid C2H•02 5!Hl4R
Acetic Anhydride C.Hs03 180-183
Acetonitrile C2H3N 173-174
Aniline C6H7N 201-202
Benzene CaHa 199-200R
Butyl Acetate CaH1202 210
Butyric Acid C.Ha02 184-186
Cyclohexane CaH12 205-208R
Ethyl Acetate C•Ha02 187
Ethyl Propionate CsH1o02 191-198R
Formic Acid CH202 14-16
Heptane C1H1a 214-218R
Hexane CaH,. 211 )> 1-Hexene CaH12 209 "'0
::r Isobutyric Acid C•Ha02 188 Ill
Propionic Acid, Anhydride CaH,oOs 203-204 0" CD
Propyl Bromide C3H7Br r-+
175-179 (") Pyridine C5H5N 189-190 Ill
Tetrachloromethane CCI4 166-172 ::J
Toluene C1Ha 212-213 0. CD
Propionic Acid, Anhydride CaH,oOs Propionic Acid CsHa02 203-204 ><
Propyl Acetate CsH1o02 Acetic Acid C2H402 103 0 -
Propyl Bromide C3H7Br Acetic Acid C2H402 65-69R (JJ Propionic Acid CsHa02 175-179 ::J
Ill
Propyl Butyrate C1H,.o2 Butyric Acid C•Ha02 246 """':
'< Pyridine CsHsN Acetic Acid C2H402 97-100 (J)
Butyric Acid C•Hs02 239-240 '< en r-+
Formic Acid CH202 18-19 CD 3 c.>
Propionic Acid CsHa02 189-190 -....J en ()1
Sulfur Dioxide 028 Acetic Acid C2H•02 36 )> c.u -....J
"'C O'l Acetic Anhydride C•HeOa 312
:::r
Sulfuric Acid H2o.s Chloroacetic Acid C2HaCI02 31 Ill o-
Tetrachloromethane CCI4 Acetic Acid C2H402 38-42R CD r-+ Acetic Anhydride C•HeOa 313-319R ("')
Propionic Acid CaHe02 166-172 Ill
Tetradecane C,.H30 Hexanoic Acid CeH,202 269 ::::J
Toluene C1Hs Acetic Acid C2H•02 139 a. CD
Acetic Anhydride C4H603 329-330 X
Benzoic Acid C1H602 273-278 0 -Butyric Acid C•Hs02 244 CD Isobutyric Acid C•Ha02 256 ::::J
Ill Propionic Acid CaHe02 212-213 -<
Trichloroacetic Acid C2HCia02 Chloroform CHCI3 25 (/) Nitric Acid HN03 21-24 '<
(JJ Tridecane C,aH2s Valeric Acid CsH,o02 266
r-+ CD
Triethylamine C6H,5N Acetic Acid C2H402 131-138 3 Trifluoroacetic Acid C2HF302 Acetic Acid C2H402 27
(JJ
N-Undecane c, , H2• Butyric Acid C•Ha02 249
Hexanoic Acid CeH,202 267
Methacrylic Acid C•He02 234
Valeric Acid CsH,o02 264
Valeric Acid CsH1002 Decane C,oH22 263
Dodecane c,2H2e 265
Formic Acid CH202 20
Tridecane C,3H2s 266
N-Undecane c,,H2• 264
Vinyl Acetate C•Hs02 Acetic Acid C2H402 75
Vinyl Butyrate CsH1002 Acetic Acid C2H402 113-114
Vinyl Propionate CsHa02 Acetic Acid C2H402 101-102
Xylene (isomer not specified) CaH,o Maleic Anhydride C4H203 311
m-Xylene CaH,o Methacrylic Acid C4H602 226
o-Xylene CsH10 Acetic Anhydride C.Hs03 332
Maleic Anhydride C4H203 3 1 0
� "'0 ::::r DJ rr CD z (') DJ
:::J a. CD X
0 -
� :::J DJ .....
'< (/)
'< en ...... CD
3 (1.) -...J en -...J
Acetic Acid C2H•02 Benzene CaHs Propionic Acid C3Ha02 297 )> c.> --..1 "'C (X)
Tetrachloromethane CCI4 29D-291 ::::,-
Butyric Acid C•Hs02 Pentanoic Acid CsH,o02 300 Ill 0"
Ethyl Acetate C•Hs02 Hexane C6H14 301 CD .-+
Ethylbenzene CsH1o Styrene CaHs 302 (')
Heptane C7H1s Acrylic Acid C3H402 292 Ill
Methyl Acetate C3Hs02 Formic Acid CH202 284 ::s c..
Propionic Acid C3Hs02 Butyric Acid C.H802 295 CD
Cyclohexane CsH12 298-299 ><
0 Ethyl Acetate C•Hs02 296 -
Formic Acid CH202 285-286 roi ""'' Propyl Bromide C3H7Br 293-294 ::s
Ill Tetrachloromethane CCI4 289 -<
Tetrachloromethane CCI4 Acrylic Acid C3H402 288 CJ) Acrylic Acid C3H402 Acetic Acid C2H•02 Heptane C7H1s 292 '<
CJJ Tetrachloromethane CCI4 288
.-+ CD
Benzene CaHs Propionic Acid C3Hs02 Acetic Acid C2H402 297 3 CJJ
Tetrachloromethane CCI4 Acetic Acid C2H•02 29D-291
Benzoic Acid C7Hs02 Biphenyl C,2H1o Toluene C7Ha 303-304
Biphenyl C,2H1o Toluene C7Ha Benzoic Acid C7Hs02 303-304
Butyl Formate CsH,o02 Pyridine CsH5N Formic Acid CH202 287
Butyric Acid C•Ha02 Acetic Acid C2H•02 Propionic Acid C3Hs02 295
Pentanoic Acid CsH1002 Acetic Acid C2H•02 300
Cyclohexane CsH12 Acetic Acid C2H•02 Propionic Acid C3Hs02 298-299
Ethyl Acetate C.H802 Acetic Acid C2H•02 Propionic Acid C3Hs02 296
Hexane C6H14 Acetic Acid C2H•02 301
Ethylbenzene CsH1o Styrene CsHs Acetic Acid C2H402 302
Formic Acid CH202 Acetic Acid C2H402 Methyl Acetate CaHs02 284
Propionic Acid CaHs02 285-286
Butyl Formate C5H1o02 Pyridine C5H5N 287
Heptane C1H1s Acrylic Acid CaH402 Acetic Acid C2H•02 292
Hexane CsH1• Acetic Acid C2H•02 Ethyl Acetate C.Ha02 301
Methyl Acetate CaHs02 Formic Acid CH202 Acetic Acid C2H402 284
Pentanoic Acid C5H1o02 Acetic Acid C2H402 Butyric Acid C•Hs02 300
Propionic Acid CaHs02 Acetic Acid C2H402 Benzene CsHs 297
Butyric Acid C4H802 Acetic Acid C2H402 295 )>
Cyclohexane CsH12 Acetic Acid C2H402 298-299 ""0 ::r
Ethyl Acetate C.H802 Acetic Acid C2H•02 296 Pl 0'"
Formic Acid CH202 Acetic Acid C2H402 285-286 CD .-+ Propyl Bromide C3H7Br Acetic Acid C2H402 293-294 (')
Pl Tetrachloromethane CCI4 Acetic Acid C2H402 289
Propyl Bromide C3H7Br Acetic Acid C2H402 Propionic Acid C3Hs02 293-294 :::J a.
Pyridine C5H5N Formic Acid CH202 Butyl Formate C5H1o02 287 CD ><
Styrene CsHs Acetic Acid C2H402 Ethyl benzene CsH1o 302 0
Tetrachloromethane CCI4 Acetic Acid C2H402 Benzene CsHs 290-291 -
Propionic Acid C3Hs02 289 coi """'l Acrylic Acid C3H402 Acetic Acid C2H402 288 :::J
Pl
Toluene C7H8 Benzoic Acid C1Hs02 Biphenyl C12H1o 303-304 -< (J)
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lsocaproic Acid (4-CsH,202 Acetic Acid C2H•02 Butyric Acid Methylpentanoic Acid)
N-Pentanoic Acid C5H,o02 lsocaproic Acid (4-CsH,202 Acetic Acid Methylpentanoic Acid)
CsH,o02 lsocaproic Acid (4-C6H,202 Methylpentanoic Acid)
(4-C6H,202 Acetic Acid C2H402
C•Ha02 N-Pentanoic Acid CsH,o02
C2H•02 Butyric Acid C.Ha02
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